Major Test - 2 - Main - Solution

MAJOR TEST 2 MAIN
CENTERS: MUMBAI /DELHI/ AKOLA /KOLKATA /LUCKNOW/ NASHIK /GOA # 1

MAJOR TEST 2 (MAIN) ANSWERS KEY

Que. 1 2 3 4 5 6 7 8 9 10
Ans. [2] [3] [4] [4] [2] [2] [3] [3] [1] [4]
Que. 11 12 13 14 15 16 17 18 19 20
Ans. [1] [2] [2] [3] [3] [2] [4] [3] [4] [1]
Que. 21 22 23 24 25 26 27 28 29 30
Ans. [1] [1] [2] [2] [1] [2] [2] [1] [2] [2]
Que. 31 32 33 34 35 36 37 38 39 40
Ans. [1,3,4] [2,4] [1] [2,3,4] [1,2,3,4] [2] [2] [1] [2] [4]
Que. 41 42 43 44 45 46 47 48 49 50
Ans. [3] [2] [3] [1] [3] [1] [2] [4] [2] [4]
Que. 51 52 53 54 55 56 57 58 59 60
Ans. [4] [3] [3] [3] [3] [1] [1] [2] [1] [3]
Que. 61 62 63 64 65 66 67 68 69 70
Ans. [3] [3] [2] [3] [1] [4] [1] [4] [1] [1]
Que. 71 72 73 74 75 76 77 78 79 80
Ans. [2] [1] [2] [2] [1] [4] [4] [4] [1] [2]
Que. 81 82 83 84 85 86 87 88 89 90
Ans. [2] [4] [1] [4] [2] [1] [1] [4] [2] [2]
Que. 91 92 93 94 95 96 97 98 99 100
Ans. [3] [3] [2] [2] [1] [3] [2] [4] [2] [4]
Que. 101 102 103 104 105
Ans. [2,4] [1,3] [1,2,4] [1,2,3,4] [2,4]

1. (2)
The exponent of an exponential function is a number, so it has no dimension.

aV RT
Number a
RT V
= =
Dimension of b is volume.
So, pressure =
RT
volume

RT =Pressure volume

pressure volume
a Pressure
RT
= =

2. (3)
Momentum =mass velocity =
Force
Velocity
Acceleration

Force
velocity Force time
velocity
time
= =
MAJOR TEST 2 MAIN

Velocity
L L
T
T V
= =
As both L and V are doubled, time remains unchanged.
So, Momentum becomes double.

3. (4)
P =Pressure =
2
Force F
Area L
=

P F L
2
P F L
A A A | |
= +
|
\ .

4% 2 2% = +

P
8%
P
A | |
=
|
\ .

4. (4)

Fk
mg
N

The force exerted by ground on the block will be resultant of normal reaction force and friction
force.
( ) ( )
2 2
2 2
F N Fk 20 0.25 20 = + = +
( )
2
2
20 5 425 20.6 N = + = =

5. (2)
As there is no friction between M and
0
m . There is no horizontal force acting on
0
m , so the
acceleration of
0
m is zero.

6. (2)

M
Mg
2
N
1
N
s,max 1
f N =
T
0
m
0
mg
2
N
m
mg
T=mg ....(1)
T

( )
1 2 0
N N Mg Mg mg = + = + ...(2)

s,max
T f = ( )
0
mg Mg mg = +

mn
0
m
M m
=
+

MAJOR TEST 2 MAIN

7. (3)
If
min
<
mg T ma =
( )
0
T M m g Ma + =
( ) ( )
0
mg M m g m M a + = +

( )
0
m m M
a g
m M
( +
=
(
+

8. (3)

3 2
V x =

2/3
V x =

2 4/3
V x =

2 4/3 1/3
d d dv 4
v x 2v .x
dx dx dx 3
= =

1/3
dv 2
v x a
dx 3
= =
When
1/3 2
2 4
x 8 a 8 m/s
3 3
= = =

9. (1)

2m
8 m/s
v
12 m
vcosu
vsinu
u

Let the man crosses the road of an angle u with the horizontal.
Let the man crosses the width 2m in t seconds.
So ( ) ( ) 8 t vcos t 12 = u + (1)
And ( ) 2 vsin t = u (2)

2
t
vsin
=
u

8t vcos t 12 = u +

2 2
8 vcos 12
vsin vsin
= u +
u u

8
cot 6
vsin
= u+
u

( ) ( )
8 8
v
sin cot 6 cos 6sin
= =
u u + u + u

Now for the speed to be minimum,

dv
0
d
=
u

d 8
0 tan 6
d cos 6sin
| |
= u =
|
u u+ u
\ .

MAJOR TEST 2 MAIN


6
sin
37
u =
Substituting the value of u
1
cos
37
u =
In the expression of
8
V m/s
37
=

10. (4)
In the case of elastic collision, momentum remains constant through out but kinetic energy of the
system may change during collision. That is why we always equate the KE of the system just before
and just after collision and not during collision.

11. (1)
As
k c
T T 273.15 = +

k
T Tc A = A

12. (2)

R

As train is an extended body, we have to apply the concept of COM to deal it as a point mass.

CM
Y of an semi-circular ring =
CM
2R 2R
, V w
| | | |
=
| |
t t
\ . \ .

cm
V 2R 2V
V
R
= =
t t

Linear momentum =
cm
2V
MV M
| |
=
|
t
\ .

13. (2)

u
wall
Line of impact

As the line of impact is along the x-axis, the y-component of velocity will remain unchanged.
And as
1
e
2
=

( )
x
x
V 0
e v e 2 1m/ s
2 0
= = =

So the final velocity will be =
( )

i 2j +

MAJOR TEST 2 MAIN

14. (3)
The area under the graph will give momentum change.

15. (3)

mg
vy
V
m
u
vsinu
mgsinu
( ) 90u

When the string becomes slack, tension =0

2
mv
mgsinu =

2
v gsin = u (1)
Applying energy conservation,
( )
2 2
1 1
mu v mg 1 sin
2 2
= + + u
( )
2 2
u v 2gl 1 sin = + + u
( )
2 2
v u 2gl 1 sin = + u
( )
2 2 2
y x
v u 2gl 1 sin v = + u
2
v gsin = u
( )
2 2
u 2g 1 sin V sin
2
= + u u
( )
2 2 3
y
v u 2g 1 sin gsin = + u u
( )
2 3
y
v u 2g 1 sin gsin = + u u
For
y
v to be maximum,
y
d
v 0
d
=
u

2
2 2
sin sin
3 3
u = u = (2)
Substituting the value of sin u

2
2
v g
3
=
And
y
2 1 2g
V vcos g
3 3 3 3
= u = =

16. (2)

2m
u
m
u=0

Applying momentum conservation,
( )
2
2mu 2m m v u v
3
= + =
MAJOR TEST 2 MAIN

( )
2
i
1
KE 2m u
2
=
( ) ( )
2 2 2
f i
1 1 4 1 2 2
KE 3m v 3m u 2m u KE
2 2 9 2 3 3
| |
= = = =
|
\ .

Frictional Loss
( ) ( )
( )
i f
i
KE KE
1
KE 3
= =

17. (4)

L/2
2m
M
t

cm
L
m 2m O
L
2
Y
3m 6
+
= =

18. (3)

19. (4)
Acceleration of train 1
2
4 m/s =
Acceleration of train 2 =
2
5
m/s
2

( )
2
2 2
f 1
40
v u 2as 0 s 200m
2 4
= = = =
+

( )
2
2
20
s 80m
2 5/ 2
= =

So the gap will be = ( ) 300 200 80 20m + =

20. (1)

x
y
u
o
30
y
v
o
30

u 2gh 2 10 5 10m/s = = =

o
y
u 10cos30 5 3 m/s = =
So,
y y
5
v eu 3 m/s
2
= =
MAJOR TEST 2 MAIN

Time of flight =
y
o
y
5
2 3
2V
5 3
2
1sec
a gcos30 3
10
2

= = =
.

21. (1)

2
n n
v
a kt kt
R
t
= =

( )
1/ 2
n n/ 2
v kRt v t =
Power is only due to tangential component of force,
P =(F
t
) V =(m a
t
) V , a
t
=
dv
dt
=k
n
2

n
-1
2
n
t
2

( )
n 2 n 2n 2
n 1
2 2 2
P t P t P t

+

o

22. (1)

N =10 N
Mg 9.8 N
Text

As the normal reaction force forms an action-reaction pair and the block experiences an upward
force of 10N due to table that means the block must be pushing the table with a force of 10N.

23. (2)
Energy supplied to the system =100cal 240 24000cal = .
Let the final temperature =u
Heat absorbed =100 0.2 20 200 0.5 20 200 80 100 0.2 200 1 + + + u+ u
By equaling heat supplied =Heat absorbed

o
25.5 C u =

24. (2)
As the scale is calibreated at
o
20 C, at
o
0 C the gas p between the divisions of the scale will
decrease, so if the scale reading is 25 cm then the real length will be less than 25 cm

25. (1)
The loss in potential energy is used for melting of ice.
So,
m L
mgh L h
5 5g
= =

26. (2)
Q ms = Au
In differential forum
Q msdT =
}

MAJOR TEST 2 MAIN

Mass is one unit. So
2
3
1
15a
Q aT dT units
4
= =
}

27. (2)

8 cm

Applying the concept to negative mass,
If Y =com of the remaining part

1
A =Area if semi-circular disc

2
A =Area of the circular disc

1 1 2 2
1 2
A Y A Y
Y
A A

1 2
1 2
4R
A A 8
3
,R 6
A A

t
= = t

( )
( )
1 2
1 2
A A 8
Y 8cm
A A
= =

28. (1)
The no. of Least significant digits is 2 in the given data. So the final answer should have only two
significant digits.

29. (2)

mu
monkey
m+m v
B+monkey

The minimum value final velocity of the ball B after the monkey jumps on to it must be 5gL
So,
mu =(2m) V
u 2v 2 5gl = =
So speed of A is
Also 2 5gl

m
A
u
m
u

Relative speed of jump of the monkey costA 2u 4 5gl = =
20gl =

30. (2)

u
m
m

MAJOR TEST 2 MAIN

Taking the wedge and the particle as a system. There is no net force acting in the horizontal direction
on the system.

m
m
2
v
1
v

So,
2 1
mu mv mv = (1)

2 2 2
2 1
1 1 1
mu mv mv
2 2 2
= + (2)
Solving these too equations,
2
V 2u =

31. (1, 3, 4)
Given
D
100% 0.2%
D
A
= As
R
D =
2

A =Area =
2
R t

D R
D R
A A
=

A R
2
A R
A A
=
So,
A
100% 2 0.2 0.4%
A
A | |
= =
|
\ .

3
4 V R
V R 3 0.6%
3 V R
A A
= t = = .

R
100 0.2
R
A
=

4 1
R 0.2 0.2
0.25 10 c
R 100 100 80

o Au
= o = =

32. (2, 4)

o
45
R
(x,y)
R

As the x and y coordinates of the rod are equal,
So,
1 2
cm cm
1 2
R
M O M
R
2
X X
M M 2
+
= <
+
and
CM
R
Y
2
<
And the value of
CM
X and
CM
Y will always be equal.
So, (B) and (D) cannot be true.

33. (1)

( )
2
F 2x 3x 2 =
MAJOR TEST 2 MAIN

For equilibrium, F =0

2
1
2x 3x 2 x 2and
2
=
For stable equilibrium

dF
0
dx
| |
<
|
\ .

( )
dF
4x 3
dx
=
For x =2

dF
0
dx
| |
>
|
\ .

So x 2 = is unstable equilibrium & x=-1/2 is stable equilibrium.

34. (2, 3, 4)

mg
M
kx

When the net force is zero,

0
mg kx =

0
mg
x
k
=
By that time the block has achieved some downward velocity, so it will keep on starching the spring
till it comes to rest.
Applying energy conservation

2
1
mgx kx
2
=

2mg
x
k
=

35. (1, 2, 3, 4)

( )

F 3yi 3xj = +

( ) ( )
( ) ( )

w 3yi 3xj . dxi dyj 3 ydx xdy 3 d xy 3xy c = + + = + = = +
} } }

36. (2)

3 3 2 2
Ag 2HNO AgNO NO H O
108
+ + +

MAJOR TEST 2 MAIN


3 3
AgNO NaCl AgCl NaNO
143.5
+ +

143.5 gm of silver chloride would be precipitated by 108 g of silver.
Or 14.35 g of silver chloride would be precipitated 10.8 g of silver
11.34 g of silver coin contain 10.8 g of pure silver
100 g of silver coin contain
10.8
100
11.34

=95.2 %
37. (2)
moles of CO
2
=0.1 and mole of H
2
=0.1

38. (1)

hc
= 2.41x10
12
5.42x10
12
( )

39. (2)

40. (4)
Cations are always smaller than their parent atoms and anions are always larger then their parent
atom.

41. (3)
In isoelectronic ions, the atomic size decreases as z/e ratio increases.

2
z 16 z 17 z 18
S ;Cl ;Ar ;
e 18 e 18 e 18

= = =

2
z 19 z 20
K ;Ca
e 18 e 18
+ +
= =

42. (2)
Symmetrical with linear structure will have zero dipole moment

43. (3)

3 2
H O
species H bonding in
2
H O
(a)
O H.........O H
|
H
(
(

(
(
(

I
(b)
O H.......O H
H
H

5 2
H O
+
(H bonding )
3
H O
+
(no H bonding)
(c)
O.......H O
H
H H
H
(
(
(
(
+
(d)
O H
H
H
(
(
(
(
+

44. (1)
CH
4
will have zero dipole moment and in NF
3
bond moments are in opposite directions

45. (3)
MAJOR TEST 2 MAIN


dry gas
P 773 13 760 torr = =

760
1 atm
760
= =
PV nRT =

171 0.333
1 0.0821 288
1000 M.wt.
=

M =46 g. per mol.

46. (1)
No. of moles of gas 1 =
1
1
1
w 0.45
n
m 60
= =
0.0075 =
No. of moles of gas 2 =
2
2
2
w 0.22
n
m 44
= =
0.0050
Total no. of moles =
1 2
n n +
0.0075 0.0050 0.0125 = + =

2
P partial pressure of gas 2 =
0.0050
75
0.0125

=30 cm of Hg.

47. (2)
Let OQ =x cm so QP =(40 x) cm
Diffused volume of
3
NH gas =Area if T. S. if tube Distance travelled by
3
NH gas

3
NH
V A OQ Ax = =
{Where A is area of T.S. of tube}
Similarly in the same time,
Diffused volume of HCl gas =Area of T. S. of tube Distance travelled by HCl gas
( )
HCl
V A QP A 40 x = =
From Grahams Law of diffusion

3
3
NH
HCl
HCl NH
r
M
r M
=

3
NH / t
HCl / t
V
36.5
1.46
V 17
= =

( )
x
1.46
40 x
=

x 23.74cm =
OQ 23.74cm =

48. (4)

49. (2)

AH = AE+ An
g
RT
Given

3
H 651 10 cal.,R 2cal A = = ,
MAJOR TEST 2 MAIN

T 290K and n 6 6 6 6 = A = + =

3
E 651 10 6 2 290 A =
654480cal =
654.5Kcal =

50. (4)

( ) ( )
o o o
f products f Reactants
H H H A = A A

( ) ( ) ( ) ( ) 2 2 2
o o o o
f H O f CO f CO f H
H H H H
( (
= A + A A + A

| | | |
o
H 241.8 110.5 393.5 0 A = +
352.3 393.5 41.2KJ = + = +

51. (4)

2CO(g)+O
2
(g)2CO
2
(g) An
g
=2 3=1
AH AU=An
g
RT AH AU<0

52. (3)
by Hesss law

53. (3)
Select the longest chain having more substitutes.

54. (3)
The N of nitro group will be attached from carbon chain so alternate 2
nd
& 4
th
are wrong in this way
& the alternate 1
st
is 3-nitro-1-propane amine

55. (3)
The IUPAC name of compound

3 3
CH C CH CH CH CH
3 3
CH CHO CH
O
5 4 3 2
is -

2 Isopropyl 3 methyl 4 oxo pentanal
In this compound the principal functional group is CHO.

56. (1)
Boiling will be non spontaneous at low temperature and high pressure

57. (1)

Bondordervalues O
2
+2
=3,O
2
+
=2.5,O
2
=2,O
2
=1.5, O
2
2
=1
SinceBondorder+,Bondlength|

58. (2)
By second law,

AS
system
+AS
surrounding
>0 forirreversiblechange

MAJOR TEST 2 MAIN

59. (1)
By inert pair effect stability of lower oxidation states increases down the group

60. (3)
let at exactly half work done, volume =x L, Hence

nRTln
3
1
|
\
|
.
|
2
= nRTln
x
1
|
\
|
.
|
So,x= 3L

61. (3)

O
S
Cl
Cl

62. (3)

63. (2)
As heat of formation increases, stability decreases

64. (3)

dU=1000.25(2x10
5
)x10
3

65. (1)

(300)V
1.331
=T
2
(8V)
1.331
, T
2
=150K
W=AU=1x3Rx(150300)

66. (4)

AH
ionisation
H
2
O
( )
=H
2
OH
+
+OH
AH
neut
of HClandNaOH= H
+
+OH
H
2
O

67. (1)

68. (4)

P
Cl
Cl
Cl
Cl
Cl

Br
f
f
f
f
f

69. (1)

70. (1)

MAJOR TEST 2 MAIN

71. (2)
Sum of ( ) ( )
n n
AP 2a n 1 d a
2 2
= + = + (

| |
100
1 100
2
= + 50 101 5050 =

72. (1)

( )
2
x 2: x 2 x 4x 3 0 > + =
x2=0 or
2
x 4x 3 0 + =

x =2 or x =1, 3

73. (2)
x intercepts put y=0
1
st
line : x intercepts: 3x =6, x =2
2
nd
line: 2x=4, x=2
sum of x=intercepts =2+2=0

74. (2)
(GP)
3
T 4 =
2
ar 4 =
a.ar.ar
2
.ar
3
.ary=a
5
r
10
=4
5

75. (1)

2
R 7 1 25
tan 1
2 l 25
u +
= = =
2
t
u =

76. (4)

77. (4)

78. (4)

1
mline 3x2g5=0

3x-2y-5=0
x
-
2
y
-
3
=
0
m-slope
m-slope
1
u
u

1
2
m
3
=

1 2 2
m
2 3 3
tan
1 2 2
1 1 m
2 3 3
+ +
u = =

7 3m 2
4 3 2m
+
=

7(3-2m)=4(3m+2) or 7(3-2m)=4(3m+2)
2114m=12m+8 & 2114m=12m8
26 m =13 2m =29
MAJOR TEST 2 MAIN


1
m
2
=
29
m
2
=

79. (1)

3
log 2x 7 1 =
2x 7 3 =

2x7=3 & 2x7=3
2x =10 & 2x=4 x =5 x =2

80. (2)

3
log17 log2 log0.2
P log 17
log2 log0.2 log3
= = =E(2,3)

81. (b)

(0,4)
(1,3)
(2,0)

x y
1
2 4
+ = 2x+y=4

82. (4)

( ) ( ) ( )
s 2 1 3 2 A 8 80 = + = +
81 1 9 1 8 = = =

83. (1)
( ) ( )
2 1
2n n
s s 1 2n 1 n
2 2
= + +
| |
n
2 4n 1 n
2
= +
( )
n
3n 1
2
= +
( ) ( )
n 3n
3n 1 c H 3n
2 2
+ =
C =3

84. (4)
p r s xy+k=0
c(3,2)r=5 2

3 2 k
5 2
2
+ +
s
( )
2
k 5 100 + s
(k+510)(k+5+10)s0
(k+15)(k5)s0
KE(15,5)
MAJOR TEST 2 MAIN

85. (2)
a =1; b =1; c =0
a >C >b

86. (1)

D
0
4a
> Here, a =1

( )
2
4 a 6a 8
0
4
+
>
2
D b 4ac =
| | ( )
2
2
4 4a 1 4 10 2a 7 +
(a2)(a4)<0
2
4 a 8 ( = +

6a+8
a(2,4)

87. (1)

1 2 1 2 1 1
2gg 2f f c c + = +
2(3).(2)+2(2).(3)=1212
12+12=24+
1 2
c c +
Is correct
(b)
( )
1
c 3,2 = ( )
2
c 2,3 =

1
r 5 =
2
r 5 =

1 2 1 2
cc 2 r r = >
Intersect2 common tangents

88. (4)
L:3x5ya=0

1 2
L .L 0 >
(3.15.2a)(3.35.4-a)>0
(7a)(11a)>0
(a+7)(a+1)>0

89. (2)
3
GM 1.3.9 3 = =

90. (2)

1
1
5
S
1
4
1
4
= =

91. (3)

10
log x 0 x 1 > >

10
log x 4 =

4
x 10 =

MAJOR TEST 2 MAIN

92. (3)

1 4a a
1 3b b 0
1 2c c
=

1.bc4a(cb)+a(2c3b)=0
bc 2ac +ab =0

1 1 2
c a b
+ =

93. (2)

4 P
tan
3 B
-
0 = = ; H =5
sin u 2
nd
or 4
th
quod.
2
nd
Q : sinu =
4
5

4
th
P : sinu =
4
5
-

94. (2)
7 cos x +5 sin x =2k +1

2 2
7 5 8 + +
2KH t[8, 8]
2Kt[9, 7]
Kt[4.5, 3.5]

95. (1)

7
5
3 LOG 3 3
5 1 7 1 8 2 + = + = =

96. (3)
c (3, 1)

97. (2)
c
1
(0, 0) c
2
(3, 4)
r
1
=2 r
2
=7
c
1
c
2
=5 =|r
1
=r
2
|
touch internally.

98. (4)
T =3
hx +ky 3 (x +h) 2(y +k) 11 =h
2
+k
2
6h 4k
[passes three (1, 8)]
h +8k 3(1 +h) 2(8 +k) =h
2
+k
2
6b 4k
h +8k 3 3h 16 2k =h
2
+k
2
6b 4k
Replacing (h, k) (x, y)
x
2
+y
2
4x 10y +19 0

MAJOR TEST 2 MAIN

99. (2)
both time pass through centre of circle
x +2x +4 +5=0
3x = 9
x = 3 and y =2x +4
= 2
c (3, 2)
p (1, 2) on the circle
radius = distance cp 4

100. (4)
sec
2
u tan
2
u =1
(secu +tanu)(secu tanu) =1
secu tanu =
1
p

secu +tanu =P

secu =
1
p
p
2
( `
(
+
(
'
and tanu =
1
p
p
2
-

secu . tanu =q

1 1
p p 4q
p p
( ` ( `
( (
+ - =
( (
' '

p
4
1 =4pq

101. (2, 4) 102. (1, 3)

103. (1, 2, 4)
3x +4y 13 =0 P(1, 0)
Perp. distance =
3 13
2
5
( `
-
( =
(
'

104. (1, 2, 3, 4)
x
2
+y
2
=25 centre perp. distance from center to line
Here center is (0, 0) r =0
Tangent if p =r
a) x =5 p =| 5| =5 =

b) y =5 p =|5| =5 =

c) 3x +4y =25 P =
25
5
-
=5 =
d) 3x +4y =25 P =
25
5
-
=5 =

MAJOR TEST 2 MAIN

105. (2, 4)
Assumed a, b, C eR

Major Test - 2 - Main - Solution

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MAJOR TEST 2 MAIN

CENTERS: MUMBAI /DELHI/ AKOLA /KOLKATA /LUCKNOW/ NASHIK /GOA # 1

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