Wacker VAE

VINNAPAS VAE DISPERSIONS IDEAL BINDERS FOR INTERIOR PAINTS STATE OF THE ART TRENDS.
Dr. Udo Kotschi, WACKER POLYMERS, April 2011
CREATING TOMORROW'S SOLUTIONS
AGENDA Who are we? Raw materials and manufacturing process VINNAPAS VAE Dispersions are the preferred technology for environmentally friendly paints in Europe Trends Requirements / Eco-labels VINNAPAS VAE Dispersions for conventional and environmentally friendly interior paints
VINNAPAS VAE Dispersions Dr. Udo Kotschi, WACKER POLYMERS, April 2011, Slide 1
WACKER CHEMIE AG
Founded in 1914 by Dr. Alexander Wacker Headquartered in Munich
WACKER Group (2009) Sales: EBITDA: R&D: Investments: Employees: 3.72 billion 607 million 164 million 740 million 15,618
WACKER: HIGHLY INTEGRATED OPERATIONS BASED ON THREE KEY RAW MATERIALS

Raw material Upstream
SILOXANE PYROGENIC SILICA SILICON WAFERS POLYSILICON SOLAR CRYSTALS
Downstream
SILICONES
Customers industries
CONSTRUCTION AUTOMOTIVE PAINTS & COATINGS TEXTILES PRINT & PAPER, PERSONAL CARE HYPERPURE SILICON WAFERS SEMICONDUCTORS SOLAR MODULES COATINGS, ADHESIVES, NONWOVENS CONSTRUCTION (TILE ADHESIVES, DRY-MIX MORTARS, EIFS) AUTOMOTIVE, FOOD FOOD, LIFE SCIENCES, HOUSEHOLD
SILICON METAL
VAE ETHYLENE VAM MICROBIAL FERMENTATION
DISPERSIBLE POLYMER POWDERS PVAc
STARCH/ DEXTROSE
THERAPEUTIC PROTEINS,
FOOD INGREDIENTS
VAM = Vinyl acetate monomer, VAE = Vinyl acetate ethylene, PVAc = Polyvinyl acetate, EIFS = Exterior insulation and finishing system
A WELL-BALANCED PORTFOLIO
Group sales in 2009: 3.719 billion Total divisional sales in 2009 (incl. internal sales): 3.846 billion**
* including internal sales ** balance of internal sales/ "other" -127 million
SILTRONIC WACKER SILICONES WACKER POLYMERS WACKER POLYSILICON WACKER BIOSOLUTIONS

(formerly WACKER FINE CHEMICALS)
Source: Wacker Chemie AG
WACKER OWNS MORE THAN 50% OF THE WORLDS VAE TECHNOLOGY PRODUCTION CAPACITY
WACKER POLYMERS production set up
Moscow Adrian Allentown Cologne
Burghausen
Beijing
Calvert City
Dubai India
Nanjing
Ulsan Shanghai Zhangjiagang
US
Acetic Acid VAE VAM Key Markets Dispersion Powders
Europe
Silicone Acetic Acid VAE VAM Key Markets Dispersion Powders
ASIA
Ethylene
Singapore
Acetic Acid VAE VAM Key Markets Dispersion Powders
Ethylene
Ethylene
Sao Paulo
Melbourne Production Powder Production Dispersion Technical Center
FOR OPTIMUM SERVICE CLOSE TO OUR CUSTOMERS OUR TECHNICAL CENTERS

Technical Centers located in
Australia (Melbourne) Brazil (Jandira) China (Shanghai; Beijing) Germany (Burghausen) Russia (Moscow) Singapore USA (Adrian; Allentown) United Arab Emirates (Dubai) India (Mumbai)
Service
Customer support for technical questions New product developments based on leadingedge technology and expertise Formulations developed for local climates and country-specific standards
VINNAPAS VAE TECHNOLOGY RAW MATERIALS & PRODUCTION PROCESS
RECIPE COMPONENTS OVERVIEW Water (Main) monomers (vinyl acetate, ethylene, vinyl chloride, acrylics, vinyl esters etc.) Functional monomers Stabilizers Initiator system pH adjust (buffer) Defoamer Biocide
EMULSION POLYMERIZATION PROCESS Monomers, surfactants / stabilizers, and water are the main components of the vinyl acetate/ethylene dispersions Functional monomers can be added for a variety of purposes, including stabilization or crosslinking pH and buffers are important variables in emulsion polymerization, influencing both kinetics and stability Additives like defoamers and biocides have specific functions, and are used in small quantities bearbeiten The right choice and amount are critical for handling and the final performance
EFFECT OF MONOMERS, FUNCTIONAL MONOMERS AND STABILIZING SYSTEMS ON COHESION & WATER RESISTANCE
VC High S
MMA
PVAL AA VAC
Cohesion
NMA Surfa. Low BA E Low EHA High M HEC
MAA Monomer Func. Monomer Stab. System
Influence on water solubility

FUNCTIONING OF SURFACTANTS / EMULSIFIERS

- -- -
Polymer particle
--
- -
Repulsio
n
-
- --
- -
-- -- -
- -
Surfactant
anionic, or cationic group
Hydrophobic
--
- -
EMULSION POLYMERIZATION PROCESS OVERVIEW The process and apparatus used depend on the kind of monomers Ethylene gas Open vessel does not work Autoclave Apparatus is under ethylene pressure Vinyl acetate / ethylene dispersions (VAEs) are sometimes also called pressure polymers Result: dispersion of polymer VAE particles in water Removal of the residual monomers and other volatile ingredients by different chemical and/or physical measures
VINNAPAS VAE DISPERSIONS ARE THE PREFERRED TECHNOLOGY FOR ENVIRONMENTALLY FRIENDLY PAINTS IN EUROPE
GLASS TRANSITION TEMPERATURE (Tg)

Influence of vinylic comonomers on glass transition temperature of vinyl acetate copolymers
Ethylene is the ideal internal softener for vinyl acetate polymer dispersions!
MINIMUM FILM FORMING TEMPERATURE (MFFT) The process of film formation only occurs over a defined temperature. This temperature is called minimum film forming temperature. Above this temperature, the dispersion builds a homogeneous, crack-free film The MFFT depends on Tg of the polymer Polymer type Coalescing agents
VINNAPAS VAE DISPERSIONS HAVE OUTSTANDING COALESCING PROPERTIES Tg / MFFT correlation

MFFT [C]
VAE DISPERSIONS VERSUS STYRENE ACRYLIC DISPERSIONS Tg / MFFT CORRELATION In VAE, water functions as a coalescing aid (hydroplastification!) High scrub resistance No additional coalescing agent No migration (no fogging) Film formation at low temperatures (<5 C)
TREND ENVIRONMENTALLY FRIENDLY INTERIOR PAINTS Many different regulations to limit VOC in architectural coatings (governmental / labeling) Blue Angel / TV-Siegel / EU Ecolabel / VOC Decopaint Directive Indoor air quality (dangerous substances construction products directive CPD) / SREP for interior wall paints Manufacturing without APEOs Low-Formaldehyde (<10 ppm) Odorless Free of sensitizing additives (CIT ) What is next?
ENVIRONMENT
UV NOx VOC
Ground-level ozone summer smog

HUMAN HEALTH / OVERALL COMPETITIVENESS Zero VOC paints contain no solvents or plasticizers Therefore no fogging of active substances like solvents or plasticizers No black precipitations
CHALLENGES Rising crude oil prices / energy prices Raw material availability Value of sustainability is recognized in the coatings industries Interior wall paints are recognized as the most suited segment for renewable raw materials (IRA report 2009)
MEGA TREND SUSTAINABLE DEVELOPMENT DECORATIVE PAINTS Sustainability

Sustainable development is to meet the needs of present generations without jeopardizing the ability of future generations to meet their own needs (source: EU) Society Topics for decorative coatings VOC reduction / co-solvents Tolerable Equitable Low formaldehyde APEO absence Sustainable Low energy consumption Environment Economy Viable Low carbon footprint Higher efficiency (less binder) Longer lifetimes Eco-friendly packaging Renewable raw materials The aim is to balance economic, Since 1999: Dow Jones Sustainability Index environmental and social goals.
IMPACT OF RISING OIL PRICES ON MANUFACTURING COSTS OF POLYMER DISPERSIONS

Cost comparison relative cost advantages O-Content No. Synthesis Steps Energy Consumption / step Process yield / byproducts 35-0% 4-10% 1-10% 1-10%
VINNAPAS DISPERSIONS BASED ON RENEWABLE RAW MATERIALS

CHEMICAL WEEK MAGAZINE :: NEW CONSTRUCTION PROJECTS
Wacker Eyes Green Polymers Production
10:09 AM EDT | April 9, 2010 | Natasha Alperowicz in Burghausen
Wacker Chemie is developing renewable bio-based technologies to produce vinyl acetate monomer (VAM) and ethylene vinyl acetate (EVA) precursors, and ultimately green polymers. The company is the leading producer of VAM-based dispersible polymer powders and a leading maker of EVA-based dispersions. Fridolin Stary, senior v.p./corporate R&D, said at a recent press briefing at Burghausen, GermanyWackers main manufacturing sitethat Wacker has been operating a bioethanol-based pilot plant producing acetic acid at Burghausen since last year and is ready to scale up the process as soon as the economics prove viable. The size and timing of the scale up would depend on the price of bioethanol compared with the price of petrochemical feedstock, Stary says. The company is also preparing to produce bioethylene. We would use some of the quantities of the feedstocks to produce green VAM, and from this green polymers, but so far we have no timeline by when this would be achieved, Stary says.
Stary: Assessing the economics but no firm timeline is set.
Wacker buys bioethanol from a local distillery, which it uses at the 500-m.t./year acetic acid pilot plant. We are ready to build an industrial plant but are waiting to assess whether the economics to produce biogenic acetic acid on an industrial scale are justified, Stary says. No decision has been made on the capacity of the bigger plant but sources say that it could be about 10,000 m.t./year. Wacker would be willing to license the acetic acid process to third parties, he says.
POSSIBLE WACKER-BIO-ROUTE ETHANOL HAS A MILLENNIUM LONG PROVEN HISTORY OF INCREDIBLE DIVERSITY AND PERSISTENT INNOVATION
CelluHoney lose Corn Wheat Barley Grape Potato Cane Ethanol Mead Jim Beam
- Water
Scotch Ethylene end use VAM Vinegar VAE Beer Wine
+ Oxygen
Vodka Rum
VINNAPAS VAE DISPERSIONS FOR CONVENTIONAL AND ENVIRONMENTALLY FRIENDLY DECORATIVE PAINTS
VINNAPAS RANGE FOR SOLVENT- AND PLASTICIZER-FREE INTERIOR PAINTS

Type Monomer base Emulsifier System APEO-free MFFT Preservation Specification Solids Content Viscosity pH Application
60 1 55 1 50 1 800 400 46 interior 56 1 1000 850 3.5 4.5 interior 55 1 4300 1600 4.5 5.5 interior 50 1 12000 3000 45 interior / exterior
EP 3360
Vac/E PVAL+E yes +2C BIT/MIT
EP 3355
EP 3888
EF 3777
Vac/E E yes +1C BIT/MIT
EZ 3010
Vac/E CD+E yes 0C CIT/MIT
CEZ 18
Vac/E/VC CD+E yes +2C BIT/MIT
4000 1000 1750 750 46 interior 46 interior
VINNAPAS VAE DISPERSIONS APPLICATIONS

All kinds of interior applications: (with exception of silicate systems) Solvent-free and plasticizer-free interior paints Matt paints (wall and ceiling paints) Glossy paints Latex paints Silicone paints Matt and glossy full-shade paints Interior plasters Scratched plasters Plasters with a worm structure Textured coatings Primers Fillers Glue for glass, fabrics, and wallpapers
VINNAPAS VAE DISPERSIONS PROPERTIES Dispersion properties Low total VOC content MFFT = 0C Solvent-, plasticizer-free and low-formaldehyde dispersion Manufactured without APEOs No or low odor Preservation < 200 ppm BIT / MIT or < 15 ppm CIT / MIT
VINNAPAS VAE DISPERSIONS FORMULATION AND FILM PROPERTIES Good compatibility with a wide range of raw materials MFFT approx. 0C Excellent film forming properties at low temperatures Good film formation without the addition of coalescing agents No solvents or plasticizers required Very high binding power High scrub resistance in matt paints (high PVC paints) Excellent gloss / blocking behavior Excellent thickener response
VINNAPAS VAE DISPERSIONS FORMULATION AND FILM PROPERTIES Complies with European environmental standards and labeling Blue Angel TV-Siegel EU Ecolabel
VINNAPAS VAE DISPERSIONS APPLICATIONS Exterior decorative paints We do not recommend the pure VINNAPAS VAE dispersions (without vinyl chloride, vinyl laurate, acrylics etc.) for exterior applications Please address any questions concerning the use of VINNAPAS VAE dispersions for exterior applications directly to our Application Development & Technical Service (+49 8677 83-4094) in Burghausen
VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING High scrub resistance Tested in a matt paint according to RR 53 523 09 PVC = 45 - 85%
Water Dispex N 40 Natrosol plus 430 Rheolate 208 NaOH 10% Addid 800 Kronos 2300 Mistron 754 G Omyalite 90 Omyacarb 2 GU Arbocel BE 600/30 PU Parmetol DF 12 Dispersion Total
x 5 2 2 1 1 71 71 142 261 40 2 x 1,000
EQUIPMENT FOR THE DETERMINATION OF SCRUB RESISTANCE
DIN 53 778 part 2
EN ISO 11 998
RESULTS OF THE DETERMINATION OF SCRUB RESISTANCE
VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING

High scrub resistance Scrub resistance of VINNAPAS EP 3888 and VINNAPAS EZ 3010 as a function of the PVC (RR 53 523 09 test procedure)
Loss of Thickness [m]
PVC [%]

Excellent film forming properties at low temperatures Scrub resistance of VINNAPAS EP 3888 as a function of the PVC and temperature (RR 53 523 09 test procedure)
Loss of Thickness [m]
PVC [%]
VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING Excellent hiding power
VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING Hiding power VINNAPAS EP 3888 versus SA
Contrast ratio
6,0
6,5
7,0
7,5
8,0
8,5
9,0
9,5
Spreading rate in m2/liter

EQUIPMENT FOR THE DETERMINATION OF SHEEN RESPECTIVELY GLOSS EN ISO 13 300 Mat < 10 units at 85 Dead mat < 5 units at 85

Low sheen in matt paints Sheen (Gloss 85) as a function of the PVC Sheen (85)
PVC [%]
VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING Excellent color strength
After 6 weeks on the window
Excellent color stability, even in matt interior paints
Competitor binder
VINNAPAS EP 3888
VINNAPAS CEZ 18 APPLICATIONS All-purpose binder interior and exterior applications All kinds of interior applications (including silicate systems) Solvent and plasticizer-free interior paints / plasters, etc. All kinds of exterior applications Exterior paints, crack-bridging paints, etc. Thermal insulation systems Special applications Dispersion-modified silicate paints Concrete paints Roof coating compounds Flame retardant systems
VINNAPAS CEZ 18 KEY PERFORMANCE IN INTERIOR PAINTS MFFT < 0C Excellent film forming properties at low temperatures No solvents or plasticizers required High binding power Low VOC No or low odor Manufactured without APEOs
VINNAPAS CEZ 18 KEY PERFORMANCE IN EXTERIOR PAINTS Excellent resistance against saponification Excellent weathering resistance Excellent durability Low dirt pick-up Low chalking
VINNAPAS CEZ 18 KEY PERFORMANCE IN PLASTERS Interior / exterior applications Excellent resistance against saponification Excellent durability Crack-free Pinhole-free Good storage stability Fire protection classification B1 according to DIN 4102 (Fire Behavior of Building Materials and Elements) in respect of thermal insulation systems
ONGOING MONITORING OF DIFFERENT VINNAPAS CEZ 18 EXTERIOR COATINGS ON OUR TEST FENCE
Different exterior coatings series based on VINNAPAS CEZ 18 have been applied to our test fence in Burghausen (Germany) over a period of several months Our objective is to compare the new system with our VINNAPAS CEZ 16 standard Beside classical exterior coatings, we are also testing silicon resin emulsion paints silicate paints So far, the coatings performance of VINNAPAS CEZ 18 APEO-free looks good and is comparable with our VINNAPAS CEZ 16 standard
THANK YOU!!

Wacker VAE

Hochgeladen von

Dokumentinformationen

Originalbeschreibung:

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Wacker VAE

Hochgeladen von

Copyright:

Verfügbare Formate

VINNAPAS VAE DISPERSIONS IDEAL BINDERS FOR INTERIOR PAINTS STATE OF THE ART TRENDS.

Dr. Udo Kotschi, WACKER POLYMERS, April 2011

CREATING TOMORROW'S SOLUTIONS

Founded in 1914 by Dr. Alexander Wacker Headquartered in Munich

WACKER: HIGHLY INTEGRATED OPERATIONS BASED ON THREE KEY RAW MATERIALS

VAE ETHYLENE VAM MICROBIAL FERMENTATION

DISPERSIBLE POLYMER POWDERS PVAc

* including internal sales ** balance of internal sales/ "other" -127 million

SILTRONIC WACKER SILICONES WACKER POLYMERS WACKER POLYSILICON WACKER BIOSOLUTIONS

Moscow Adrian Allentown Cologne

Ulsan Shanghai Zhangjiagang

Melbourne Production Powder Production Dispersion Technical Center

FOR OPTIMUM SERVICE CLOSE TO OUR CUSTOMERS OUR TECHNICAL CENTERS

VINNAPAS VAE TECHNOLOGY RAW MATERIALS & PRODUCTION PROCESS

CREATING TOMORROW'S SOLUTIONS

NMA Surfa. Low BA E Low EHA High M HEC

MAA Monomer Func. Monomer Stab. System

Influence on water solubility

Source: Wacker Chemie AG

FUNCTIONING OF SURFACTANTS / EMULSIFIERS

anionic, or cationic group

Source: Wacker Chemie AG

CREATING TOMORROW'S SOLUTIONS

GLASS TRANSITION TEMPERATURE (Tg)

Source: Wacker Chemie AG

VINNAPAS VAE DISPERSIONS HAVE OUTSTANDING COALESCING PROPERTIES Tg / MFFT correlation

Source: Wacker Chemie AG

Ground-level ozone summer smog

Source: Wacker Chemie AG

MEGA TREND SUSTAINABLE DEVELOPMENT DECORATIVE PAINTS Sustainability

IMPACT OF RISING OIL PRICES ON MANUFACTURING COSTS OF POLYMER DISPERSIONS

Source: Wacker Chemie AG

VINNAPAS DISPERSIONS BASED ON RENEWABLE RAW MATERIALS

Wacker Eyes Green Polymers Production

10:09 AM EDT | April 9, 2010 | Natasha Alperowicz in Burghausen

Stary: Assessing the economics but no firm timeline is set.

Scotch Ethylene end use VAM Vinegar VAE Beer Wine

CREATING TOMORROW'S SOLUTIONS

VINNAPAS RANGE FOR SOLVENT- AND PLASTICIZER-FREE INTERIOR PAINTS

4000 1000 1750 750 46 interior 46 interior

VINNAPAS VAE DISPERSIONS APPLICATIONS

x 5 2 2 1 1 71 71 142 261 40 2 x 1,000

EQUIPMENT FOR THE DETERMINATION OF SCRUB RESISTANCE

DIN 53 778 part 2

Source: Wacker Chemie AG

EQUIPMENT FOR THE DETERMINATION OF SCRUB RESISTANCE

Source: Wacker Chemie AG

EQUIPMENT FOR THE DETERMINATION OF SCRUB RESISTANCE

Source: Wacker Chemie AG

RESULTS OF THE DETERMINATION OF SCRUB RESISTANCE

Source: Wacker Chemie AG

VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING

VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING

Spreading rate in m2/liter

VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING

Source: Wacker Chemie AG

VINNAPAS VAE DISPERSIONS KEY PERFORMANCE IN PAINTS / BENCHMARKING

Excellent color stability, even in matt interior paints

Das könnte Ihnen auch gefallen