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1(4)
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AS Experiment 2.1(4) RESULTS EXPERIMENT 1 Mass of calcium metal Mass of empty cup Mass of cup plus acid Mass of acid 1 (M1) EXPERIMENT 2 Mass of calcium carbonate Mass of empty cup Mass of cup plus acid Mass of acid 2 (M2)
TIME (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
FINDING THE TEMPERATURE CHANGES Plot two separate graphs of temperature against time, one for each experiment. Use a large scale to enable you to find the temperature change more accurately. Extrapolate the points find out the instantaneous temperature change at the 4th minute in each reaction. Call these T1 and T2.
T1 = OC
T2 = OC
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AS Experiment 2.1(4) CALCULATING THE ENERGY CHANGES Take the Specific Heat Capacity (c) for the solutions to be 4.18 J.g-1.OC-1 Take the mass of the solutions to be the mass of acid used in each experiment Ignore the sign of the temperature change (rise or drop) just use the numerical value
1) For Ca metal Heat change = (mass of solution 1) c T1 = . J = kJ Moles of Ca = mass of Ca Ar (Ar for Ca = 40.1) = Energy per mole = Heat change number of moles = . kJ.mol-1 Now decide whether the reaction was exothermic (temperature rise) or endothermic (temperature drop). Use the correct sign convention to write your value for the enthalpy change for this reaction below:H1 = .. kJ.mol-1
2) For CaCO3 Heat change = (mass of solution 2) c T2 = . J = kJ Moles of CaCO3 = mass of CaCO3 Mr (Mr = 100.1) = Energy per mole = Heat change number of moles = . kJ.mol-1 Now decide whether the reaction was exothermic or endothermic. Use the correct sign convention to write your value for the enthalpy change for this reaction below:H2 = .. kJ.mol-1
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AS Experiment 2.1(4) 3) Draw a Hess Law cycle incorporating your values for H1 and H2 and the enthalpies of formation for water and carbon dioxide to calculate the enthalpy of formation for CaCO3 H2 (g) + O2 (g) C (s) + O2 (g) H2O (l) CO2 (g) Hf = -285.8 kJ.mol-1 (call this H3) Hf = -393.5 kJ.mol-1 (call this H4) 1 O2 (g) CaCO3 (s)
Ca (s) + C (s) +
Hf for CaCO3 = kJ.mol-1 4) Compare your calculated value for the standard enthalpy of formation of CaCO3 with the accepted data book value of -1206.9 kJ.mol-1. Work out your experimental error and estimate the apparatus errors to see how accurate your experiment was. What are the main sources of error (other than apparatus errors) in your method? . . . . . . . . . . .
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