CLASS XII 36 marks

CHEMISTRY NUMERICAL TEST 60 min

1. A certain reaction is 50% complete in 20 min at 300 K and the same reaction is again 50% complete in 5 min t 350 K. Calculate the activation energy if it is a first order reaction. [R = 8.314 JK-1 mol-1;log 4 = 0.602] OR 2. The first order rate constant for the decomposition of ethyl iodide by the reaction, C2H5I (g) C2H4 (g) + HI (g) at 600K is 1.60 x 10-5 s-1. Its energy of activation is 209 kJ/mol. Calculate the rate constant of the reaction at 700 K. 3. Prove that the time required for the completion of of the first order is twice the time required for the completion of half of the reaction. 4. Calculate the equilibrium constant for the reaction, Fe(s) Cd 2 (aq) Fe 2 (aq) Cd (s) 3Cd (s) (Given, E
Cd 2 / Cd

= -0.4 V,

Fe 2 / Fe

= -0.44 V)

5. Given that the standard electrode potentials (E ) of metals are K+/K = - 2.93 V, Ag+/Ag = 0.80 V, Cu2+ / Cu = 0.34 V , Mg2+ = - 2.37 V, Cr3+ / Cr = -0.74 V, Fe2+ / Fe = - 0.44 V Arrange these metals in an increasing order of their reducing power. 6. A strip of nickel is placed in a 1- molar solution of Ni(NO3)2 and a strip of silver metal is placed in a 1- molar solution of AgNO3. An electrochemical cell created when the two solutions are connected by a salt bridge and the two strips are connected by wires to a voltammeter (i) Write the balanced equations for the overall reactions occurring in the cell and calculate the cell potential. (ii) Calculate the cell potential, E, at 25 for the cell if the initial concentration of Ni(NO3)2 is 0.100 molar and the initial concentration of AgNO3 is 1.00 molar[E Ni2 / Ni = -0.25 V; E+ Ag / Ag =0.80 V log10-1 = -1] OR 7. a) The resistance of a conductivity cell filled with 0.1 M KCl solution is 100 ohm. If the resistance of same cell when filled with 0.02 m KCl solution is 520 ohms, calculate the conductivity and molar conductivity of 0.02 M KCl solution. Conductivity of 0.1 M KCl solution is 1.29 S m-1. b) Calculate for acetic acid, Given that (HCl) = 426 S cm2 mol-1 (NaCl) = 126 S cm2 mol-1

(CH3COONa) = 91 S cm2 mol-1 8. The freezing point of a solution containing 0.2 g of acetic acid in 20 g of benzene is lowered by 0.45 . Calculate (i) the molar mass of acetic acid from this data (ii) vant Hoff factor. (For benzene, Kf = 5.12 K kg mol-1) what conclusion can you draw from the value of vant Hoff factor obtained? 9. Calculate the amount of sodium chloride which must be added to one kg of water so that the freezing point of water is depressed by 3 K.[Given, Kf = 1.86 K kg mol-1, atomic mass of Na = 23, Cl = 35.5]. 10. Copper crystallizes in face centered cubic lattice and has density of 8.930 g cm-3 at 293 K. Calculate the radius of copper atom. [At. Mass of Cu = 63.55 u, NA = 6.02 x 1023 mol-1] 11. The density of cooper metal is 8.950g cm-3. If the radius of copper atom is 127.8 pm, is the copper unit cell a simple cubic, a body centered cubic or face centered cubic structure (Given at. Mass of Cu = 63.54 g mol-1 and NA = 6.02 x 1023 mol-1) 12. The edge of the face centered cubic unit cell of almunium is 404 pm. Calculate the radius of almunium atom

SUDEEPS CHEMISTRY FOR CLASS XI-XII & JEE AND MEDICAL EXAMINATIONS