Chemistry 2006 p1p2p3 MRSM Qa

SULIT
4541/1
Kimia
Kertas 1
September
2006
1 jam
PEPERIKSAAN PERCUBAAN SPM 2006

MAKTAB RENDAH SAINS MARA
http://cikguadura.wordpress.com/
KIMIA
Kertas 1
Satu jam lima belas minit
JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1.
Kertas soalan ini adalah dalam dwibahasa.
2.
Soalan di halaman kiri adalah dalam bahasa Melayu. Soalan di halaman kanan
adalah yang sepadan dalam bahasa Inggeris.
3.
Calon dikehendaki membaca maklumat di halaman 2 atau halaman 3
Kertas soalan ini mempunyai 47 halaman bercetak
INFORMATION FOR CANDIDATES

1.
This question paper consists of 50 questions.
2.
Answer all questions.
3.
Answer each question by blackening the correct space on the answer sheet.
4.
Blacken only one space for each question.
5.
If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.
6.
The diagrams in the questions provided are not drawn to scale unless stated.
7.
You may use a non -programmable scientific calculator.
4541/1 2006 Hak Cipta MARA
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Question 1 to Question 50, are followed by four options A, B, C, and D. Choose the best
option for each question and blacken the corresponding space on the objective answer sheet.
1
The diagram shows the apparatus set up to investigate Process X.
Gas jar cover
Process
X
nitrogen dioxide
(brown)
nitrogen dioxide
(brown)
What is P rocess X?
Diffusion
Condensation
Evaporation
Sublimation
Which of the following is the common characteristic for isotope s of an element?

A
Physical properties
Chemical properties
Nucleon number
Number of neutrons
What is the definition of a mole?

A
The volume occupied by 6.02 X 1023 particles
The atomic mass of a substance which consist of 6.02 X 1023 atoms
The molecular mass of a substance which consist of 6.02 X 1023 molecules
The quantity of a substa nce which has the same number of particles as the
number of atoms in 12.00 g of carbon-12
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The diagram shows an electrochemical cell.
What is the energy conversion involved?
Electrical energy heat energy
Chemical energy electrical energy
Electrical energy chemical energy
Chemical energy heat energy
The diagram shows the flow of ammonia gas into distilled water which contains a few
drops of phenolphthalein
Which of the following is the correct observation?

A
Solution remains colourless
Solution turns from red to purple
Solution turns from green to red
Solution turns from colourless to pink
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Which of the following is the main usage of the product in Haber Process?
A
To produce pesticides
To produce paint
To produce detergent
To produce fertilizers
Propane and propene are members of different homologous series.

Which of the following is the general formulae representing the two compounds?
Propane
Propene
CnH2n
CnH2n+2
CnH2n+2
CnH2n
C2nHn+2
CnH2n+1
CnH2n+1
CnH2n+2
The equation below represents the fermentation reaction

C6H12O 6 ?
Y + CO2
What is substance Y?
Ethanol
Glucose
Glycerol
Ethanoic acid
Penicillin is used for

A
reducing anxiety
reducing pain
controlling the level of glucose in blood
destroying or preventing the growth of bacteria
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10
The diagram shows a label on a bottle of Orange Juice XYZ.

Orange Juice XYZ
Ingredients:
water, sugar, ascorbic acid, sulphur dioxide,

aspartame, E110, E102, vitamin A and D.
Best before: 15 Dec 2006
What is the function of sulphur dioxide?
11
12
To make the drink more concentrated
To give colour to the drink
To give orange flavour to the drink
To make the drink last longer
Which of the following substance consists of free atoms?

A
Nitrogen gas
Xenon gas
Glucose powder
Sodium chloride
The diagram shows the molecular formula for glucose.
C6H12O6
Which of the following substance has similar empirical formula as that of glucose?
A
B
Substance
Ethanol
Ethanal
Molecular Formula
C 2H6O
C 2H4O
C
D
Ethanoic acid
Methyl ethanoa te
C 2H4O2
C 3H6O2
11
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13
The table shows observations for the reaction between ethanoic acid and magnesium.
Reaction
Observation
Magnesium powder + glacial ethanoic acid
No changes
Magnesium powder + glacial ethanoic acid + water
Effervescence
Which of the following explains the observation?
14
Acetic acid dissolves in water producing hydrogen gas
Acetic acid ionises to produce hydrogen ions in the presence of water
Water ionises to hydrogen ions and react with magnesium
Acetic acid ionises to hydrogen ions which combine with each other to form
hydrogen gas
The table shows information about two acids

Acid
Sulphuric acid
Hydrochloric acid
Concentration
0.01 mol dm -3
pH
1.1
0.01 mol dm -3
2.0
.
Which of the following statement is true?
A
Sulphuric acid is more concentrated than hydrochloric acid
Sulphuric acid is a strong acid while hydrochloric acid is a weak acid
Concentration of H + ions in sulphuric acid is higher than that of

hydrochloric acid
Sulphuric acid ionises completely while hydrochloric acid ionizes partially in

water
13
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15
Figure shows the atomic arrangement in an alloy.

X Atom
Y Atom
Z Atom
This alloy is harder than its pure metal because
16
arrangement of atoms in alloy is more orderly
vibration of atoms in alloy is more vigorous
layers of atoms in alloy is less able to slide
absence of empty spaces between atoms in alloy
The diagram shows vases made from pewter.
Which of the following is the main metal used to produce pewter?

A
Tin
Copper
Antimony
Aluminium
15
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17
The diagram shows the chemical cha nge that occurs to compound G.
H
Br
Br
H
H - C - C - C - C - H
H
H
H
H
Bromine in CCl4
Which of the following is compound G?
18
n- butane
But - 1 - ene
But - 2 - ene
Butan - 2 - ol
Below is a list of chemicals used by a student to prepare ethyl ethanoate.

2 cm3 concentrated sulphuric acid
10 cm3 aqueous solution of ethanoic acid 2.0 mol dm-3
15 cm3 pure ethanol
The mixture was heated under reflux for 30 minutes. At the end of the preparation the
student failed to detect the presence of ethyl ethanoate.
Which of the following causes the failure?
19
Pure ethanoic acid is not used
The amount of sulphuric acid used is not enough
30 cm3 of pure ethanol should have been used
Longer duration of heating under reflux is needed
Rusting causes a lot of financial loss.

Which of the following is rust?
A
Zink oxide
Iron(II) oxide
Iron(III) oxide
Lead(II) oxide
17
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20
The diagram shows the structure of a soap ion.
Which of the following is true about M when soap is used to clean greasy stain?
21
M is alkaline
M is hydrophilic
Soluble in grease
Reduce the surface tension of water
The diagram shows the particle arrangement of substance X at 100O C.
Particle of X
Which is the most probable melting and boiling points for X?

Melting point / O C
-123
Boiling point / O C
-78
-17
135
78
111
400
A
B
19
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22
The diagram shows the position of elements P, Q, R and S in the Periodic Table of
Elements.
R
P
S
Q
What characteristics of P, Q, R and S?

P
A
B
C
D
23
Metal
Non-metal
Metal
Inert gas
Q
Non-metal
R
Inert gas
Inert gas
Transition
element
Non-metal
Metal
Non-metal
Transition
element
S
Transition
element
Transition
element
Inert gas
Metal
Element T has the following characteristics :
High melting and boiling points.

Forms compounds with various oxidation numbers.
T oxide acts as catalyst.
Element T could be
24
Rubidium
Silicon
Manganese
Magnesium
The table shows information about atoms of elements X, Y and Z.

Element
X
Proton Number
11
Y
Z
14
17
Based on the information given, it can be expected that

A
the atomic radius decreases from X to Z
the density of atom decreases from X to Z
elements X, Y and Z are in Period 2 of the Periodic Table
X oxide is acidic, Y oxide is amphoteric and Z oxide is basic
21
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25
The diagram shows the formation of a compound.
Carbon
Chlorine
Tetrachloromethane
The bond in the compound is formed by
26
27
donation of electrons
sharing of electrons
receiving of electrons
exchanging of electrons
M is an ionic compound and dissolves in water to form a solution that conducts

electricity.
Which of the following could be compound M?
A
Sodium chloride
Hydrogen chloride
Carbon disulphide
Lead(II) chloride
Which of the following equation represents the most suitable reaction to prepare an
insoluble salt?
A
Pb(OH)2 + 2HCl PbCl2 + 2H2O
Pb +
AgNO3 + NaCl AgCl + NaNO3
CaO + H2SO 4 CaSO4 + H 2O
H2SO4 PbSO 4 +
H2
23
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28
The diagram shows the set-up of the apparatus for a Voltaic cell.
Which of the following is true about the Voltaic cell?
29
The aluminium strip becomes thinner
II
Aluminium is the positive terminal
III
Brown solid deposited at the copper strip
IV
Bubbles of colourless gas formed at the copper strip
I and IV only
II and IV only
I and III only
I, II and III only
The diagram shows a sports equipment in which the frame is made from a composite
material.
Which of the following is the property of the composite material?

A
High tensile strength
Hard and brittle
Heat resistant
Transparent
25
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30
The chemical equation shows a reaction between calcium carbonate with hydrochloric
acid.
CaCO 3 + 2HCl ?
CaCl2 + CO2
+ H2O
Which of the following changes cannot be used to determine the rate of reaction?
31
Change in the pH of the mixture
Decrease in mass of calcium carbonate
Increase in mass of calcium chloride
Change in volume of carbon dioxide released
The equation shows the reaction between zink and hydrochloric acid.
Zn (p) + 2HCl (ak) ZnCl2(ak) + H2(g)
Which of the following statements are true about the reaction?
I
The mass of zinc decreases with time
II
pH of hydrochloric acid increases with time
III
Rate of hydrogen gas released increases w ith time
IV
Frequency of collisions between H + ions and zinc atoms decreases with time
I and III only
III and IV only
I, II and IV only
II, III and IV only
27
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32
In an experiment, 100 cm3 of 1.0 mol dm-3 hydrochloric acid reacts with excess
magnesium to produce hydrogen gas.
The graph of the volume of hydrogen gas against time is drawn and curve X is
obtained.
Volume of hydrogen, cm 3
If the experiment is repeate d using another solution, which solution will produce
curve Y?
33
50 cm3 of 1.0 mol dm-3 nitric acid
50 cm3 of 1.0 mol dm-3 ethanoic acid
25 cm3 of 1.0 mol dm-3 sulphuric acid
25 cm3 of 1.0 mol dm-3 hydrochloric acid
The diagram shows the structural formula for a compound extracted from pineapple.
Which of the following are needed to produce the compound synthetically?

Alcohol
Carboxylic acid
n- butanol
Propanoic acid
Ethanol
Butanoic acid
Ethanol
Propanoic acid
n- butanol
Ethanoic acid
29
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34
The diagram shows the apparatus set-up of an experiment to study redox reaction.
After 20 minutes, the colourless solution around electrode X changes to brown while
the solution around electrode Y changes from orange to green.
Which of the following statement explains the observation of the experiment?
35
Iodide ions are oxidized to iodine molecules.
Oxidation number of iodine increases from 0 to +1.
Electron flows from electrode Y to electrode X through the external circuit
Oxidation number of chromium decreases from +6 to +2
The table shows the observations of an experiment involving heating of two

substances.
Substances
Observation
Carbon powder and metal P oxide
Glow
Hydrogen gas and metal Q oxide
Glow
Hydrogen gas and metal P oxide
No changes
Which of the following is in ascending order for the reactivity of elements towards
oxygen?
A
Carbon, P, hydrogen, Q
Q, hydrogen, P, car bon
Hydrogen, P, carbon, Q
Hydrogen, Q, carbon, P
31
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36
Diagram shows an experiment carried out for iron(II) sulphate.
Which of the following is solution X?
37
Potassium chloride solution
Potassium bromide solution
Sodium hydroxide solution
Acidified potassium manganate(VII) solution
The diagram shows the energy profile for the formation of T from R and S.
Energy
x kJ mol-1
R+S
y kJ mol-1
What is the activation energy for the reaction?

A
y kJ mol-1
(x + y) kJ mol-1
x kJ mol-1
(x-y) kJ mol-1
33
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38
The diagram shows the electron arrangement in an atom of elements P and Q.
What is the formula and type of bond for the compound formed when P reacts with
Q?
39
Formula
PQ 2
Bond
Ionic
B
C
PQ 4
PQ
Ionic
Covalent
PQ 4
Covalent
The equation represents the redox reaction between ammonia and copper(II) oxide.
2 NH3 + 3CuO ?
N2 + 3 Cu + 3H 2O
Which of the following is true about the reaction?
40
Ammonia is an oxidizing agent
Nitrogen is a reducing agent
Oxidation number of copper decreases from +2 to 0
Oxidation number of hydrogen increases from -1 to +1
The table shows two experiments carried out to investigate the reaction between
calcium nitrate and sodium carbonate solution.
Calcium nitrate
Sodium carbonate
solution
solution
Decrease in
Experiment
0
Volume Concentration Volume Concentration, temperature, C
3
-3
3
-3
(cm )
(mol dm )
(cm )
(mol dm )
I
100.0
1.0
100.0
1.0
6.0
II
50.0
2.0
50.0
2.0
What is the value of X?

A
1.5 0 C
3.0 0 C
6.0 0 C
12.0 0 C
35
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41
The diagram shows an electron arrangement of R2- ion.

2
How many protons and electrons does an atom of R contain?
42
Protons
Electrons
10
10
10
Nitrogen exists as diatoms.

What is the mass of one nitrogen molecule?
Given that the relative atomic mass of N = 14; Avogadro constant = 6 x 1023 mol-1
A
2.1 x 10-23 g
2.3 x 10-23 g
4.7 x 10-23 g
28 x 10 -23 g
37
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43
An experiment is carried out to study the effect of concentration on the rate of

reaction between sodium thiosulphate and hydrochloric acid.
Graph of the concentration of sodium thiosulphate against 1/time is as shown.
Based on the graph, what is the value of t if the experiment is repeated using sodium
thiosulphate solution 0.025 mol dm -3.
44
32.3 s
50.0 s
0.020 s
0.031s
What is the volume of distilled water required to be added to 25.0 cm3 of

0.5 mol dm -3 sulphuric acid in order to produce a solution of 0.1 mol dm -3 ?
A
75.0 cm3
100.0 cm3
125.0 cm3
150.0 cm3
39
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45
The following shows the energy level diagram of a reaction.

Energy
Zn +
Cu2+
H = - 190 kJ/mol
Zn2+
+ Cu
Which of the following statements are true about the reaction?
46
Zinc is oxidized
II
The reaction is exothermic
III
The temperature decreases during the reaction
IV
95 kJ of heat is released when 0.5 mole of copper is displaced
I and III only
II and IV only
III and IV only
I, II and IV only
4.60 g of sodium is burnt in excess chlorine gas. The equation for the reaction is as
follows:
2Na (p) + Cl2 (g) 2NaCl (p)
The product is dissolved in water to produce 250.0 cm3 of solution.
What is the molarity of the solution?
Given that the relative atomic mass of Na = 23.
A
0.05 mol dm -3
0.20 mol dm -3
0.40 mol dm -3
0.80 mol dm -3
41
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47
The table shows the voltmeter readings when a pair of different metal electrodes are
dipped into the copper(II) nitrate solution.
Metal electrode
Voltmeter reading (V)
Positive terminal
Negative terminal
2.8
0.8
1.2
What is the value of Y?
48
0.8
1.0
1.6
2.0
Copper(II) carbonate decomposes when heated strongly as represented by the

following equation.
CuCO3 CuO + CO2
What is the volume of carbon dioxide gas released when 0.62g copper(II)
carbonate is heated?
Given that the relative atomic mass of Cu = 64, C = 12, O = 16 and 1 mol of gas
occupies 24 dm 3 at room temperature and pressure.
A
120 cm3
240 cm3
480 cm3
640 cm3
43
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49 The diagram shows the set-up of apparatus for the electrolysis of sodium chloride
solution 1.0 mol dm -3.
Which of the following observations are true about the electrolytic cell?
I
Shiny grey solid deposited at the cathode
II
Colourless gas is collected in the test tube at the cathode
III
A greenish-yellow gas is collected in the test tube at the anode
IV
A damp blue litmus paper decolourised when put into the test tube at the
anode
I and II only
I and III only
I, III and IV only
II, III and IV only
45
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50
Information on methane and butane is shown in the following table.
Fuel
Relative
molecular
mass
Methane
16
CH4 + 2O 2 CO2 + 2H 2O
-890 kJ mol-1
Butane
58
C4H10 + 13/2 O2 4CO 2 + 5H 2O
-2882 kJ mol-1
Chemical equation
Heat of
Combustion
Based on the information shown in the table, the conclusions are

I
butane is more combustible than methane
II
combustion of 1 g of methane produces more heat than 1 g of butane
III
energy content of butane is higher than methane
IV
combustion of 1 mole of butane produces more carbon dioxide than 1 mole of

methane
I and III only
I, II and IV only
II, III and IV only
I, II, III and IV
47
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Kertas 2
Sept
2006
2 jam
NAMA: .
ANGKA GILIRAN: .

Kod Pemeriksa
KIMIA
Kertas 2
Dua jam tiga puluh minit
JANGAN BUKA KERTAS SOALAN INI
SEHINGGA DIBERITAHU
1. Tuliskan nama dan angka giliran anda
pada ruang yang disediakan.
2. Kertas soalan ini adalah dalam
dwibahasa.
Bahagian Soalan Markah

Penuh
1
09
2
09
A
3
10
4
10
5
11
6
11
1
20
B
2
20
3
20
C
4
20
Jumlah
3. Soalan di halaman kiri adalah dalam

bahasa Mela yu. Soalan di halaman
kanan adalah dalam bahasa Inggeris.
4. Calon dibenarkan menjawab
keseluruhan atau sebahagian soalan
sama ada dalam bahasa Melayu atau
bahasa Inggeris.
5. Calon dikehendaki membaca maklumat
di halaman 2 dan halaman 3.
Kertas soalan ini mengandungi 51 halaman bercetak
4541/2 2006 Hak Cipta
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MAKLUMAT UNTUK CALON

1. Kertas soalan ini mengandungi tiga bahagian : Bahagian A, Bahagian B dan
Bahagian C.
2. Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam
ruang yang disediakan dalam kertas soalan .
3. Jawap satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C.
Tuliskan jawapan bagi Bahagian B dan Bahagian C pada halaman bergaris di
bahagian akhir kertas soalan ini. Jawab Bahagian B dan Bahagian C dengan
terperinci. Anda boleh menggunakan persamaan, gambar rajah, jadual, graf dan
cara lain yang sesuai untuk menjelaskan jawapan anda.
4. Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.
5. Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan
itu.
6. Rajah yang mengiringi soala n tidak dilukiskan mengikut skala kecuali dinyatakan.
7. Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan
dalam kurungan.
8. Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B
ialah 30 minit dan Bahagian C ialah 30 minit.
9. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.
10. Serahkan semua kertas jawapan anda di akhir peperiksaan.
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Bahagian A
[60 markah]
Jawab semua soalan dalam bahagian ini.
Masa yang dicadangkan untuk menjawab bahagian ini ialah 90 minit.
1
Rajah 1 menunjukkan simbol atom bagi unsur karbon dan oksigen.
RAJAH 1
Berdasarkan Rajah 1, jawab soalan-soalan berikut:
1(a)(i)
(a)
Apakah yang diwakili oleh :

(i)
nombor 12 bagi atom unsur C?

..................................................................................................................
[1 markah]
1(a)(ii)
(ii)
nombor 8 bagi atom unsur O ?

..................................................................................................................
[1 markah]
1(b)(i)
(b)
(i)
Apakah yang dimaksudkan dengan isotop?

..................................................................................................................
..................................................................................................................
[1 markah]
1(b)(ii)
(ii)
Nyatakan atom-atom yang merupakan isotop isotop bagi unsur yang

sama .
..................................................................................................................
[1 markah]
1(b)(iii)
(iii)
Tuliskan simbol atom bagi isotop lain untuk unsur yang dinyatakan
di (b)(ii).
..................................................................................................................
[1 markah]
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1(c)(i)
(c)
(i)
Berapakah bilangan elektron bagi atom
4541/2
.................................................................................................................
[1 markah ]
1(c)(ii)
(ii)
Tuliskan susunan elektron bagi atom di (c)(i).

..
[1 markah ]
(d)
Karbon dan oksigen terletak dalam kala yang sama dalam Jadual Berkala.
Nyatakan kala tersebut dan jelaskan jawapan anda.
1(d)
.............................................................................................................................
.............................................................................................................................
[2 markah ]
JUMLAH
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2
Rajah 2 menunjukkan susunan radas bagi satu eksperimen untuk menentukan formula
empirik bagi satu oksida kuprum.
RAJAH 2
Berikut adalah data yang diperolehi daripada eksperimen tersebut:
Jisim kuprum oksida
Jisim logam kuprum
2(a)
(a)
=
=
2.00 g
1.60 g
Apakah yang dimaksudkan dengan formula empirik?

......
[1 markah]
2(b)
(b)
Namakan satu bahan yang boleh digunakan untuk mengeringkan gas hidrogen.
..
[1 markah]
2(c)
(c)
Mengapakah gas hidrogen kering perlu dilalukan ke dalam tabung pembakaran

selama beberapa minit sebelum pemanasan dimulakan?
......
[1 markah]
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Bagaimanakah anda boleh memas tikan tindak balas ini telah lengkap?
2(d)
.....
[1 markah ]
(e)
Berdasarkan keputusan di atas,

(i)
hitungkan bilangan mol atom kuprum dan bilangan mol atom oksigen
yang bertindak balas.
Diberi jisim atom relatif bagi O = 16 dan Cu = 64.
[2 markah ]
(ii)
Tentukan nisbah teringkas bilangan mol atom kuprum kepada bilangan

mol atom oksigen.
[1 markah ]
(iii)
Apakah formula empirik bagi oksida kuprum ini?
2(e)(i)
2(e)(ii)
2(e)(iii)
..................................................................................................................
[1 markah ]
2(f)
(f)
Mengapakah formula empirik oksida magnesium tidak boleh ditentukan

dengan kaedah di atas?
...
[1 markah ]
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3
Rajah 3 menunjukkan susunan radas bagi eksperimen penentuan haba peneutralan.

25.0 cm3 larutan asid nitrik 2.0 mol dm-3 ditindakbalaskan dengan 25.0 cm 3 larutan
kalium hidroksida 2.0 mol dm-3.
Termometer
Sebelum
tindak balas
Larutan asid nitrik

Suhu awal = 30.0 oC
Larutan kalium hidroksida

Suhu awal = 30.0 oC
Termometer
Selepas
tindak balas
Cawan
polistirena
Campuran
larutan
Suhu maksimum = 43.5 oC

RAJAH 3
3(a)
(a)
Cadangkan satu langkah berjaga-jaga yang perlu diambil semasa eksperimen

ini dijalankan.
..............................................................................................................................
[1 markah ]
3(b)
(b)
Nyatakan jenis tindak balas yang berlaku dari segi perubahan haba.
..............................................................................................................................
[1 markah ]
[lihat sebelah
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14
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Untuk
Kegunaan
Pemeriksa
3(c)
(c)
Tuliskan persamaan kimia bagi tindak balas yang berlaku.

..............................................................................................................................
[1 markah ]
(d)
Hitungkan
(i)
bilangan mol asid nitrik dan bilangan mol ka lium hidroksida
3(d)(i)
[1 markah ]
(ii)
perubahan haba dalam eksperimen itu.

Diberi muatan haba tentu larutan ialah 4.2 Jg-1 oC -1 dan ketumpatan
larutan ialah 1 g cm -3
3(d)(ii)
[1 markah ]
(iii)
haba peneutralan bagi tinda k balas itu.
3(d)(iii)
H = _________________
[ 2 markah ]
[lihat sebelah
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16
SULIT
4541/2
Untuk
Kegunaan
Pemeriksa
(e)
Lukiskan gambar rajah aras tenaga bagi tindak balas itu.
3(e)
[2 markah ]
(f)
3(f)
Ramalkan nilai haba peneutralan sekiranya asid nitrik digantikan dengan asid
etanoik untuk bertindak balas dengan kalium hidroksida.
..............................................................................................................................
[1 markah ]
JUMLAH
[lihat sebelah
SULIT
Untuk SULIT
Kegunaan
Pemeriksa
4
18
4541/2
Jadual 4 menunjukkan data yang diperoleh oleh seorang pelajar daripada satu
eksperimen untuk mengkaji kadar penguraian hidrogen peroksida menggunakan
mangkin mangan(IV) oksida.
Masa (s)
Isipadu gas
oksigen (cm3)
0.00
30
60
90
120
18.00 31.00 39.00 43.00
150
46.00
180
210
240
270
48.00 49.00 50.00 50.00
JADUAL 4
(a)
Lukiskan gamba r rajah berlabel susunan radas bagi eksperimen itu.

[2 markah ]
4(a)
4(b)
(b)
Tuliskan persamaan kimia bagi penguraian hidrogen peroksida.

..............................................................................................................................
[1 markah ]
(c)
2.0 g serbuk mangan(IV) oksida telah digunakan pada awal eksperimen dan
didapati jisim mangan(IV) oksida tidak berubah pada akhir tindak balas.
Terangkan mengapa.
4(c)
..............................................................................................................................
..............................................................................................................................
[1 markah ]
4(d)
(d)
Mengapakah mangan(IV) oksida digunakan dalam bentuk serbuk?

..............................................................................................................................
[1 markah ]
[lihat sebelah
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Untuk
Kegunaan
SULIT
Pemeriksa
20
4541/2
(e) (i) Gunakan data dalam Jadual 4 untuk melukis graf isipadu gas oksigen melawan
masa pada kertas graf di bawah.
[ 3 markah ]
Graf isipadu gas oksigen melawan masa
4(e)(i)
[lihat sebelah
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Untuk
Kegunaan SULIT
Pemeriksa
22
(ii)
4541/2
Berdasarkan graf di (e)(i), hitungkan kadar tindak balas pada masa 90 saat
dan tunjukkan tangen pada graf di (e)(i).
4(e)(ii)
[ 2 markah ]
JUMLAH
[lihat sebelah
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Untuk
Kegunaan
Pemeriksa
24
SULIT
5
4541/2
Rajah 5 menunjukkan susunan radas tindak balas melibatkan pemindahan elektron

pada suatu jarak antara larutan kalium iodida dengan air bromin.
RAJAH 5
Merujuk kepada tindak balas di atas, jawab soalan berikut:
5(a)
(a)
Nyatakan warna air bromin.

..............................................................................................................................
[1 markah ]
5(b)
(b)
Namakan bahan yang dioksidakan dalam tindak balas.

..............................................................................................................................
[1 markah ]
5(c)
(c)
Nyatakan arah pengaliran elektron bagi tindak balas ini.

..............................................................................................................................
[1 markah ]
(d)
Nyatakan perubahan nombor pengoksidaan bagi

(i)
iodin
.................................................................................................................
5(d)
(ii)
bromin
.................................................................................................................
[2 markah ]
[lihat sebelah
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Untuk
Kegunaan SULIT
Pemeriksa
5(e)
26
(e)
4541/2
Tuliskan persamaan ion keseluruhan bagi tindak balas ini.

..............................................................................................................................
[1 markah ]
(f)
Satu larutan berwarna perang terbentuk di sekitar elektrod P.

(i)
Terangkan dengan ringkas bagaimana anda menentusahkan larutan itu.
..................................................................................................................
5(f)(i)
..................................................................................................................
..................................................................................................................
[2 markah ]
(ii)
5(f)(ii)
Terangkan bagaimana larutan tersebut dihasilkan.
..................................................................................................................
..................................................................................................................
..................................................................................................................
[2 markah ]
5(g)
(g)
Apakah yang akan diperhatikan pada bacaan galvanometer jika air bromin
pada bahagian Q digantikan dengan air klorin?
..............................................................................................................................
[1 markah ]
JUMLAH
[lihat sebelah
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Untuk
SULIT
Kegunaan
Pemeriksa
6
28
4541/2
Rajah 6 menunjukkan carta alir bagi penukaran propena kepada polipropena, propana
dan propanol.
Polipropena
Proses
I
Propana
Proses II
Propena
Proses III
Propanol
RAJAH 6
(a)
Namakan siri homolog bagi propena.
6(a)
.............................................................................................................................
[1 markah ]
(b)
Lengkapkan persamaan kimia untuk Proses I dengan me lukis formula struktur

bagi polipropena
6(b)
[1 markah ]
6(c)
(c)
Tuliskan persamaan kimia bagi mewakili pr oses II.

..............................................................................................................................
[1 markah ]
(d)
6(d)(i)
Propena dan propana terbakar dalam oksigen.

(i)
Tuliskan persamaan kimia bagi salah satu tindak balas pembakaran ini
dalam oksigen berlebihan.
..................................................................................................................
[1 markah ]
[lihat sebelah
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Untuk
Kegunaan
Pemeriksa
30
SULIT
(ii)
4541/2
Bandingkan kejelagaan pembakaran propena dan propana.

Terangkan jawapan anda.
Diberi jisim molekul relatif: propena = 42 dan propana = 44.
..................................................................................................................
6(d)(ii)
..................................................................................................................
..................................................................................................................
[3 markah ]
(e)
(i)
Terangkan bagaimana anda menjalankan Proses III.

..................................................................................................................
6(e)(i)
..................................................................................................................
..................................................................................................................
[3 markah ]
6(e)(ii)
(ii)
Tuliskan persamaan kimia bagi Proses III.

..................................................................................................................
[1 markah ]
JUMLAH
[lihat sebelah
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32
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Bahagian B
[20 markah ]
Jawab mana-mana satu soalan .
Masa yang dicadangkan untuk menjawab bahagian ini ialah 30 minit
7
(a)
Unsur-unsur dalam kumpulan yang sama dalam Jadual Berkala Unsur

mempunyai kereaktifan yang berbeza.
Tindak balas kalium dengan oksigen lebih cergas daripa da
tindak balas litium dengan oksigen
Terangkan mengapa dua logam ini mempunyai kereaktifan yang berbeza.
[4 markah ]
(b)
Rajah 7.1 menunjukkan susunan radas satu eksperimen yang dijalankan untuk
mengkaji perubahan kimia yang berlaku ke atas logam kalium.
Logam kalium dibakar

dalam balang gas berisi
oksigen
Hasil tindak balas

dicampur air
Larutan X terhasil
RAJAH 7.1
(i)
Persamaan kimia di bawah menunjukkan tindak balas antara logam

kalium dengan gas oksigen.
4K +
O2
2K2O
Diberi, jisim atom relatif K = 39, O = 16.

Hitungkan jisim kalium oksida yang terhasil jika 3.9 g kalium
bertindak balas dengan gas oksigen berlebihan pada keadaan bilik.
[4 markah ]
(ii)
Namakan larutan X dan tuliskan persamaan kimia bagi

pembentukannya.
[lihat sebelah
SULIT
34
SULIT
(c)
(i)
4541/2
Jadual 7.2 menunjukkan keputusan ujian untuk membezakan

kekonduksian dua sebatian yang berlainan.
Sebatian
Kekonduksian Elektrik
Tetraklorometana ( CCl4 )
Tidak mengalirkan arus elektrik
Larutan natrium klorida( NaCl)

Boleh mengalirkan arus elektrik
JADUAL 7.2
Terangkan mengapa terdapat perbezaan kekonduksian elektrik itu.
[4 mark ah ]
(ii)
Jadual 7.3 menunjukkan keputusan proses elektrolisis ke atas dua

larutan yang berlainan menggunakan elektrod karbon.
Larutan
Hasil di katod
Hasil di anod
Natrium klorida 1.0 mol dm -3
Hidrogen
Klorin
Kuprum(II) klorida 1.0 mol dm -3
Kuprum
Klorin
JADUAL 7.3
Terangkan mengapa terdapat perbezaan hasil di katod.
[6 markah ]
[lihat sebelah
SULIT
36
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4541/2
Steroid anabolik sering digunakan oleh para atlit untuk meningkatkan prestasi
(a)
Terangkan fungsi steroid anabolik dan nyatakan tiga kesan sampingan yang
mungkin timbul akibat penyalahgunaan bahan ini.
[4 markah]
(b)
Rajah 8.1 menunjukkan penghasilan baja Z dalam makmal dari tindak balas
antara gas ammonia dan asid sulfurik cair.
RAJAH 8.1
(i)
Namakan baja Z.
[1 markah]
(ii)
Tuliskan persamaan kimia yang seimbang bagi penghasilan baja Z.

[2 markah]
(iii)
Hitungkan isipadu gas ammonia yang bertindak balas lengkap dengan

asid sulfurik jika 13.2 g baja Z dihasilkan,
Diberi jisim molar Z = 132 g mol -1 dan isipadu molar gas ialah
24.0 dm3 mol -1 pada suhu dan tekanan bilik.
[3 markah]
[lihat sebelah
SULIT
38
SULIT
(c)
4541/2
Jadual 8.2 menunjukkan dua eksperimen yang telah dijalankan ke atas lateks.
Eksperimen
Susunan radas
Pemerhatian
I
Pepejal putih
terhasil
II
Tiada perubahan
JADUAL 8.2
Huraikan dengan ringkas tentang perbezaan pemerhatian itu.
[5 markah ]
(d)
Rajah 8.3 menunjukkan penggunaan beberapa polimer sintetik dalam

kehidupan harian.
RAJAH 8.3
Terangkan punca dan kesan pencemaran penggunaan polimer sintetik secara
berlebihan.
[5 markah ]
[lihat sebelah
SULIT
40
SULIT
4541/2
[5 marks]
Bahagian C
[ 20 markah ]
Jawab mana-mana satu soalan .
Masa yang dicadangkan untuk menjawab bahagian ini ialah 30 minit
9
Kandungan alkohol dalam udara hembusan pemandu yang mabuk

boleh dikesan menggunakan sejenis alat pengesan yang
mengandungi kalium dikromat(VI)
(a)
Terangkan proses kimia yang berlaku dalam alat itu dan tuliskan persamaan
bagi tindak balas yang terlibat.
[4 markah ]
(b)
Rajah 9 menunjukkan dua persamaan bagi tindak balas yang berbeza.
R +
Br2
Tindak balas I
Q + Br2
Q + Br2
+ HBr
Tindak balas II
+ HBr
RAJAH 9
(i)
Namakan sebatian R dan Q.
(ii)
Banding dan bezakan tindak balas I dan tindak balas II.

[ 6 markah ]
(c)
Persamaan berikut menunjukkan pembentukan ester hasil daripada tindak

balas antara asid etanoik glasial dengan suatu alkohol.
ALKOHOL + ASID ETANOIK GLASIAL
ESTER + AIR
Huraikan satu eksperimen bagaimana anda menyediakan suatu ester yang

dinamakan .
Nyatakan bagaimana anda mengesan ester yang terhasil dan tuliskan
persamaan kimia bagi tindak balas itu.
[10 markah ]
[lihat sebelah
SULIT
42
SULIT
10
(a)
4541/2
Cuka merupakan larutan asid etanoik cair.

Rajah 10 menunjukkan tindak balas apabila sebiji telur ayam dimasukkan ke
dalam cuka.
RAJAH 10
Terangkan pemerhatian ini dan sertakan persamaan bagi tindak balas yang
terlibat.
[4 markah ]
(b)
Label pada satu botol reagen yang mengandungi larutan X telah tertanggal.
Larutan X disyaki larutan plumbum(II) nitrat atau kalsium nitrat.
Huraikan ujian kimia yang sesuai untuk menentusahkan ion-ion yang terdapat
dalam larutan X itu.
[6 markah ]
(c)
Anda dikehendaki menyediakan garam zink sulfat yang kering.

Bahan kimia yang dibekalkan ialah:
larutan zink klorida

asid sulfurik cair
larutan natrium karbonat
Huraikan satu eksperimen makmal bagaimana anda dapat menyediakan garam

tersebut. Dalam huraian anda sertakan persamaan yang terlibat.
[10 markah ]
KERTAS SOALAN TAMAT

[lihat sebelah
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Use
44
SULIT
4541/2
RUANG JAWAPAN / SPACE FOR YOUR ANSWER

BAHAGIAN / SECTION: .........................
NO. SOALAN / QUESTION NO.: ............
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[lihat sebelah
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Nama : .....
No Giliran : ..
Kelas : ..
SULIT
Kimia
Kertas 3
September
2006
1 jam

KIMIA
Kertas 3
Satu jam tiga puluh minit
JANGAN BUKA KERTAS SOALAN INI

SEHINGGA DIBERITAHU
1.
Tuliskan nama, angka giliran dan kelas

anda pada ruang yang disediakan.
2.
Kertas soalan ini adalah dalam dwibahasa
3.
4.
5.
Soalan di halaman kiri adalah dalam

bahasa Melayu. Soalan di halaman kanan
adalah yang sepadan dalam bahasa
Inggeris.
Calon dibenarkan menjawab keseluruhan
atau sebahagian soalan sama ada dalam
bahasa Melayu atau bahasa Inggeris.
Calon dikehendaki membaca maklumat di
halaman 2 dan halaman 3.
Kod
Pemeriksa
Soalan
Markah
Penuh
15
18
3
Jumlah
Markah
Diperoleh
17
50
Kertas soalan ini mempunyai 20 halaman bercetak.

INFORMATION
FOR
CANDIDATES
4541/3 2006 Hak
Cipta MARA
[Lihat sebelah
SULIT
-3 -
SULIT
4541/3
INFORMATION FOR CANDIDATES

1.
This question paper consists of three questions. Answer all questions.
2.
Write your answers for Question 1 and Question 2 in the spaces provided in the
question paper.
3.
Write your answers for Question 3 on the lined pages at the end of the question
paper in detail. You may use equations, diagrams, tables, graphs and other suitable
methods to explain your answers.
4.
Show your working, it may help you to get marks.
5.
If you wish to cancel any answer, neatly cross out the answer.
6.
The diagrams in the questions are not drawn to scale unless stated.
7.
Marks allocated for each question or part question are shown in brackets.
8.
The time suggested to complete Question 1 and Question 2 is 45 minutes and

Question 3 is 45 minutes.
9.
You may use a non-programmable scientific calculator.
10.
Hand in all your answer sheets at the end of the examination.
Marks awarded:
Score
4541/3
Description
Excellent: The best response
Satisfactory: An average response
Weak : An inaccurate response
No response or wrong response
SULIT
-5 -
SULIT
4541/3
For
Examiners
Use
Answer all questions.

The time suggested to answer Question 1 and Question 2 is 45 minutes.
1
A student has carried out an experiment to compare the products for electrolysis of
aqueous copper(II) chloride of different concentrations.
Figure shows the product at each electrode after the electrolysis has been carried out
for 20 minutes.
Cell I
Cell II
(a)
Cell
Complete the following table by stating the observation at the anodes and its
corresponding inferences.
Observation at the anode
Inference

II

[6 marks]
4541/3
SULIT
1(a)
1(a)
-7 -
SULIT
(b)
4541/3
For
Examiners
Use
Identify the variables involved in this experiment.

Manipulated variable:
Responding variable:
1(b)
Controlled variable:
[3 marks]
(c)
State the hypothesis for this experiment.
1(c)
[3 marks]
(d)
What will be observed at the anode of Cell II if the exper iment is carried out
for three hours?
[3 marks]
4541/3
SULIT
1(d)
-9 -
SULIT
2
4541/3
For
Examiners
Use
A student carried out an experiment to determine the concentration of sodium

hydroxide. 20.00 cm3 of aqueous sodium hydroxide and a few drops of
phenolphthalein is titrated using hydrochloric acid 0.50 mol dm -3 from a burette.
Titration is stopped when the solution in the conical flask changes colour from pink
to colourless.
Experiment was repeated three times.
Figure shows the readings of the burette during titration.
Experiment 1
Experiment 2
Experiment 3
.. cm3
.. cm3
.. cm3
.. cm3
.. cm3
.. cm3
Initial
reading s
of burette
End point
readings
2(a)
(a)
Record the burette readings in the spaces provided.

[3 marks]
4541/3
SULIT
- 11 -
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(b)
4541/3
For
Examiners
Use
Construct a table and record the initial reading, end point rea ding and
volume of hydrochloric acid used.
2(b)
[3 marks]
(c)
What is meant by the end point in the above experiment?
2(c)
[3 marks]
(d)
The chemical equation for the reaction is

NaOH + HCl ?
NaCl + H2O
(i)
What is the average volume of hydrochloric acid used?
(ii)
Calculate the concentration of sodium hydroxide used in the

experiment.
2(d)
[3 marks]
4541/3
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(e)
4541/3
For
Examiners
Use
The experiment is repeated using aqueous barium hydroxide, Ba(OH)2.

Predict the volume of hydrochloric acid required to reach the end point.
2(e)
[3 marks]
(f)
The table shows the concentrations and the pH values of four different acids.
Based on the information, classify the acid into strong acid and weak acid .
Acid
Nitric acid
Concentration / mol dm-3

0.10
pH
1.1
Oxalic acid,
0.05
3.2
Sulphuric acid
Methanoic acid
0.05
0.10
1.0
3.5
2(f)
[3 marks]
4541/3
SULIT
SULIT
- 15 -
4541/3
3
A heavy duty glove which is made of vulcanized rubber is more
durable than a surgical glove which is made of unvulcanized rubber.
Refering to the situation above, plan a laboratory exper iment to compare the
elasticity of prepared vulcanized and unvulcanized rubber.
Your planning must include the following items:
(i)
Statement of the problem
(ii)
All the variables
(iii)
Hypothesis
(iv)
Lists of substances and apparatus
(v)
Procedure
(vi)
Tabulation of data
[17 marks]
END OF QUESTION PAPER

4541/3
SULIT
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- 17 -
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Untuk
RUANG JAWAPAN/SPACE FOR YOUR ANSWERS
Kegunaan
Pemeriksa /
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For
Examiners
__________________________________________________________________________
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4541/3
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SULIT
- 19 -
4541/3
Untuk
RUANG JAWAPAN/SPACE FOR YOUR ANSWERS
Kegunaan
Pemeriksa
/
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For
__________________________________________________________________________ Examiners
Use
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4541/3
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SULIT

PEPERIKSAAN PERCUBAAN SPM 2006

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

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INFORMATION FOR CANDIDATES

This question paper consists of 50 questions.

Answer all questions.

Blacken only one space for each question.

You may use a non -programmable scientific calculator.

4541/1 2006 Hak Cipta MARA

The diagram shows the apparatus set up to investigate Process X.

Gas jar cover

Which of the following is the common characteristic for isotope s of an element?

What is the definition of a mole?

The volume occupied by 6.02 X 1023 particles

The atomic mass of a substance which consist of 6.02 X 1023 atoms

The molecular mass of a substance which consist of 6.02 X 1023 molecules

4541/1 2006 Hak Cipta MARA

The diagram shows an electrochemical cell.

What is the energy conversion involved?

Electrical energy heat energy

Chemical energy electrical energy

Electrical energy chemical energy

Chemical energy heat energy

Which of the following is the correct observation?

Solution remains colourless

Solution turns from red to purple

Solution turns from green to red

Solution turns from colourless to pink

4541/1 2006 Hak Cipta MARA

Propane and propene are members of different homologous series.

The equation below represents the fermentation reaction

Penicillin is used for

controlling the level of glucose in blood

destroying or preventing the growth of bacteria

4541/1 2006 Hak Cipta MARA

The diagram shows a label on a bottle of Orange Juice XYZ.

water, sugar, ascorbic acid, sulphur dioxide,

What is the function of sulphur dioxide?

To make the drink more concentrated

To give colour to the drink

To give orange flavour to the drink

To make the drink last longer

Which of the following substance consists of free atoms?

The diagram shows the molecular formula for glucose.

4541/1 2006 Hak Cipta MARA

Magnesium powder + glacial ethanoic acid

Magnesium powder + glacial ethanoic acid + water

Which of the following explains the observation?

Acetic acid dissolves in water producing hydrogen gas

Acetic acid ionises to produce hydrogen ions in the presence of water

Water ionises to hydrogen ions and react with magnesium

The table shows information about two acids

Sulphuric acid is more concentrated than hydrochloric acid

Sulphuric acid is a strong acid while hydrochloric acid is a weak acid

Concentration of H + ions in sulphuric acid is higher than that of

Sulphuric acid ionises completely while hydrochloric acid ionizes partially in

4541/1 2006 Hak Cipta MARA

Figure shows the atomic arrangement in an alloy.

arrangement of atoms in alloy is more orderly

vibration of atoms in alloy is more vigorous