History of the periodic table

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The history of the periodic table reflects over a century of growth in the understanding of chemical properties, and culminates with the publication of the first actual periodic table by Dmitri Mendeleev in 1869.[1] While Mendeleev built upon earlier discoveries by such scientists as Antoine-Laurent de Lavoisier and Stanislao Cannizzaro, the Russian scientist is generally given sole credit for development of the actual periodic table itself. The table itself is a visual representation of the periodic law which states that certain properties of elements repeat periodically when arranged by atomic number. The table arranges elements into vertical columns (groups) and horizontal rows (periods) to display these commonalities.

A modern periodic table with (colored) discovery periods.

Contents
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1 Elemental ideas from ancient times 2 Age of Enlightenment

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2.1 Antoine-Laurent de Lavoisier 2.2 Johann Wolfgang Dbereiner

3 Classifying elements

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3.1 Alexandre-Emile Bguyer de Chancourtois 3.2 John Newlands

4 Dmitri Mendeleev

4.1 Lothar Meyer

4.2 William Odling

5 Refinements to the periodic table

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5.1 Henry Moseley 5.2 Glenn T. Seaborg

6 Main discovery periods 7 The periodic table as a cultural icon 8 See also 9 References 10 External links

[edit]Elemental

ideas from ancient times

People have known about some chemical elements like gold, silver and copper from antiquity, as these can all be discovered in nature in native form and are relatively simple to mine with primitive tools. [2] However, the notion that there were a limited number of elements from which everything was composed originated with the Greek philosopher Aristotle. About 330 B.C Aristotle proposed that everything is made up of a mixture of one or more of four "roots" (originally put forth by the Sicilian philosopher Empedocles), but later renamed elements by Plato. The four elements wereearth, water, air and fire. While the concept of an element was thus introduced, Aristotle's and Plato's ideas did nothing to advance the understanding of the nature of matter.

[edit]Age

of Enlightenment

Hennig Brand was the first person recorded to have discovered a new element. Brand was a bankrupt German merchant who was trying to discover the Philosopher's Stone a mythical object that was supposed to turn inexpensive base metals into gold. He experimented with distilling human urine until in 1649[3] he finally obtained a glowing white substance which he namedphosphorus. He kept his discovery secret, until 1680 when Robert Boyle rediscovered it and it became public. This and related discoveries raised the question of what it means for a substance to be an "element". In 1661 Boyle defined an element as a substance that cannot be broken down into a simpler substance by a chemical reaction. This simple definition actually served for nearly 301 years (until the development of the notion of subatomic particles), and even today is taught in introductory chemistry classes.

[edit]Antoine-Laurent

de Lavoisier

Antoine Laurent de Lavoisier

Lavoisier's Trait lmentaire de Chimie (Elementary Treatise of Chemistry, 1789, translated into English by Robert Kerr) is considered to be the first modern chemical textbook. It contained a list of elements, or substances that could not be broken down further, which included oxygen, nitrogen,hydrogen, phosphorus, mercury, zinc, and sulfur. It also forms the basis for the modern list of elements. His list, however, also included light andcaloric, which he believed to be material substances. While many leading chemists of the time refused to believe Lavoisier's new revelations, theElementary Treatise was written well enough to convince the younger generation. However, as Lavoisier's descriptions only classified elements as metals and non-metals, it fell short of a complete analysis.

[edit]Johann

Wolfgang Dbereiner

In 1817, Johann Wolfgang Dbereiner began to formulate one of the earliest attempts to classify the elements. In 1828 he found that some elements formed groups of three with related properties. He termed these groups "triads". Some triads classified by Dbereiner are: 1. chlorine, bromine, and iodine 2. calcium, strontium, and barium 3. sulfur, selenium, and tellurium 4. lithium, sodium, and potassium In all of the triads, the atomic mass of the second element was almost exactly the average of the atomic weights of the first and third elements.[4]

[edit]Classifying

elements

By 1869,[3] a total of 63[3] elements had been discovered. As the number of known elements grew, scientists began to recognize patterns in the way chemicals reacted and began to devise ways to classify the elements.

[edit]Alexandre-Emile

Bguyer de Chancourtois

Alexandre-Emile Bguyer de Chancourtois, a French geologist, was the first person to notice the periodicity of the elements similar elements seem to occur at regular intervals when they are ordered by their atomic weights. He devised an early form of periodic table, which he called the telluric helix. With the elements arranged in a spiral on a cylinder by order of increasing atomic weight, de Chancourtois saw that elements with similar properties lined up vertically. His chart included some ions and compounds in addition to elements. His paper was published in 1862, but used geological rather than chemical terms and did not include a diagram; as a result, it received little attention until the work of Dimitri Mendeleev.[5]

[edit]John

Newlands

John Newlands was an English chemist who in 1865 classified[6][7] the 56 elements that had been discovered at the time into eleven groups which were based on similar physical properties.

J. A. R. Newlands' law of octaves

Newlands noted that many pairs of similar elements existed which differed by some multiple of eight in atomic number. However, his law of octaves, likening this periodicity of eights to the musical scale, was ridiculed by his contemporaries. It was not until the following century, with Gilbert N. Lewis' valence bond theory (1916) and Irving Langmuir's octet theory of chemical bonding[8][9](1919) that the importance of the periodicity of eight would be accepted.

[edit]Dmitri

Mendeleev

Mendeleev's 1871 periodic table

Dmitri Ivanovich Mendeleev

Dmitri Mendeleev, a Russian chemist, was the first scientist to make a periodic tablemuch like the one we use today. Mendeleev arranged the elements in a table ordered by atomic mass, corresponding to relative molar mass as defined today. It is sometimes said that he played "chemical solitaire" on long train journeys using cards with various facts of known elements.[10] On March 6, 1869, a formal presentation was made to the Russian Chemical Society, entitled The Dependence Between the Properties of the Atomic Weights of the Elements. His table was published in an obscure Russian journal but quickly republished in a German journal, Zeitschrift fr Chemie (Eng., "Chemistry Magazine"), in 1869. It stated: 1. The elements, if arranged according to their atomic mass, exhibit an apparent periodicity of properties. 2. Elements which are similar as regards to their chemical properties have atomic weights which are either of nearly the same value (e.g., Pt, Ir, Os) or which increase regularly (e.g., K, Rb, Cs). 3. The arrangement of the elements, or of groups of elements in the order of their atomic masses, corresponds to their so-called valencies, as well as, to some extent, to their distinctive chemical properties; as is apparent among other series in that of Li, Be, Ba, C, N, O, and Sn (should be Li, Be, B, C, N, O, and F). 4. The elements which are the most widely diffused have small atomic weights. 5. The magnitude of the atomic weight determines the character of the element, just as the magnitude of the molecule determines the character of a compound body. 6. We must expect the discovery of many yet unknown elementsfor example, elements analogous to aluminium and siliconwhose atomic weight would be between 65 and 75.

7. The atomic weight of an element may sometimes be amended by a knowledge of those of its contiguous elements. Thus the atomic weight oftellurium must lie between 123 and 126, and cannot be 128. (This was based on the position of tellurium between antimony and iodine whose atomic weight is 127. However Moseley later explained the position of these elements without revising the atomic weight values see below.) 8. Certain characteristic properties of elements can be foretold from their atomic masses.

This version of Mendeleev's periodic table from 1891. It is lacking the noble gases

Scientific benefits of Mendeleev's table

Mendeleev predicted the discovery of other elements and left space for these new elements, namely eka-silicon (germanium), eka-aluminium (gallium), and eka-boron (scandium). Thus, there was no disturbance in the periodic table.

He pointed out that some of the atomic weights being used at the time were incorrect. He provided for variance from atomic weight order.

Shortcomings of Mendeleev's table

His table did not include any of the noble gases, which were discovered later. These were added by Sir William Ramsay as Group 0, without any disturbance to the basic concept of the periodic table.

A single position could not be assigned to hydrogen in the periodic table. Hydrogen could be placed in the alkali metals group as well as in the halogens group.

[edit]Lothar

Meyer

Unknown to Mendeleev, Lothar Meyer was also working on a periodic table. Although his work was published in 1864, and was done independently of Mendeleev, few historians regard him as an equal cocreator of the periodic table. For one thing, Meyer's table only included 28 elements. Furthermore, Meyer classified elements not by atomic weight, but by valence alone. Finally, Meyer never came to the idea of predicting new elements and correcting atomic weights. Only a few months after Mendeleev published his periodic table of all known elements (and predicted some new elements to complete the table, plus some corrected atomic weights), Meyer published a virtually identical table. While a few people consider Meyer and Mendeleev the co-creators of the periodic table, most agree that, by itself, Mendeleev's accurate prediction of the qualities of the undiscovered elements lands him the larger share of credit. In any case, at the time Mendeleev's predictions greatly impressed his contemporaries and were eventually found to be correct.

[edit]William

Odling

An English chemist, William Odling, also drew up a table that is remarkably similar to that of Mendeleev, in 1864. Odling overcame the tellurium-iodine problem and he even managed to get thallium, lead, mercury and platinum in the right groups something that Mendeleev failed to do at his first attempt.

[edit]Refinements [edit]Henry

to the periodic table

Moseley

In 1914 Henry Moseley found a relationship between an element's X-ray wavelength and its atomic number (Z), and therefore resequenced the table by nuclear charge rather than atomic weight. Before this discovery, atomic numbers were just sequential numbers based on an element's atomic weight. Moseley's discovery showed that atomic numbers had an experimentally measurable basis. Thus Moseley placed argon (Z=18) before potassium (Z=19) based on their X-ray wavelengths, despite the fact that argon has a greater atomic weight (39.9) than potassium (39.1). The new order agrees with the chemical properties of these elements, since argon is a noble gas and potassium is an alkali metal. Similarly, Moseley placed cobalt before nickel, and was able to explain thattellurium occurs before iodine without revising the experimental atomic weight of tellurium (127.6) as proposed by Mendeleev. Moseley's research also showed that there were gaps in his table at atomic numbers 43 and 61 which are now known to be Technetium and Promethium, respectively, both radioactive and not naturally occurring. Following in the footsteps of Dmitri Mendeleev, Henry Moseley also predicted new elements.

[edit]Glenn

T. Seaborg

During his Manhattan Project research in 1943 Glenn T. Seaborg experienced unexpected difficulty isolating Americium (95) and Curium (96). He began wondering if these elements more properly belonged to a different series which would explain why the expected chemical properties of the new elements were

different. In 1945, he went against the advice of colleagues and proposed a significant change to Mendeleev's table: the actinide series. Seaborg's actinide concept of heavy element electronic structure, predicting that the actinides form a transition series analogous to the rare earth series of lanthanide elements, is now well accepted in the scientific community and included in all standard configurations of the periodic table. The actinide series are the second row of the f-block (5f series) and comprise the elements from Actinium to Lawrencium. Seaborg's subsequent elaborations of the actinide concept theorized a series of superheavy elements in a transactinide series comprising elements 104 through 121 and a superactinide series inclusive of elements 122 through 153.

[edit]Main

discovery periods

The history of the periodic table is also a history of the discovery of the chemical elements. IUPAC[11] suggests five "main discovery periods", and a sixth has been added here for very recently synthesised elements (discovered 2000 or later).

Periodic table by era of discovery

V

Group 1 Period 1 2 3 4 5 6 7 1 H 3 Li

10

11

12

13

14

15

16

17

18 2 He

4 Be

5 B 13 Al 21 Sc 39 Y * 22 Ti 40 Zr 72 Hf 23 V 24 Cr 25 Mn 43 Tc 75 Re 26 Fe 44 Ru 76 Os 27 Co 45 Rh 77 Ir 28 Ni 46 Pd 78 Pt 29 Cu 47 Ag 79 Au 30 Zn 48 Cd 80 Hg 31 Ga 49 In 81 Tl

6 C 14 Si 32 Ge 50 Sn 82 Pb

7 N 15 P 33 As 51 Sb 83 Bi

8 O 16 S 34 Se 52 Te 84 Po

9 F 17 Cl 35 Br 53 I 85 At

10 Ne 18 Ar 36 Kr 54 Xe 86 Rn

11 12 Na Mg 19 K 37 Rb 55 Cs 87 Fr 20 Ca 38 Sr 56 Ba 88 Ra

41 42 Nb Mo 73 Ta 74 W

** 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo 57 La 89 Ac 58 Ce 90 Th 59 Pr 91 Pa 60 Nd 92 U 61 62 Pm Sm 93 Np 94 Pu 63 Eu 64 Gd 65 Tb 66 Dy 98 Cf 67 Ho 99 Es 68 Er 69 Tm 70 Yb 71 Lu

* Lanthanoids ** Actinoids
Legend

95 96 97 Am Cm Bk

100 101 102 103 Fm Md No Lr

Antiquity to Middle Ages (14 elements): unrecorded discoveries up into the Middle Ages Middle Ages 1800 (20 elements): discoveries during the age of enlightenment 18001849 (24 elements): scientific and industrial revolutions 18501899 (26 elements): the age of classifying elements; application of spectrum analysis techniques: Boisbaudran, Bunsen, Crookes, Kirchhoff, and others "hunting emission linesignatures" 19001949 (13 elements): development of old quantum theory and quantum mechanics