Vidyamandir Classes

VMC/Chemical Bonding 38 HWT/Chemistry

DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : C. Bond [1]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. In which of the following compounds are the bond angles close to 90 ?
(A)
3
PH (B)
6
SF (C)
2
H S (D) All of these
2. Which of the following molecules has the maximum value of bond energy ?
(A)
2
F (g) (B)
2
N (g) (C) CO(g) (D) HF(g)
3. The species which has a liner structure is :
(A)
2
NO (B)
2
NO
+
(C)
2
NO

(D)
2
PbCl
4. Which of the following has a geometry different from the other three species (having the same geometry) ?
(A)
4
BF

(B)
2
4
SO

(C)
4
XeF (D)
4
PH
+
5. Which of the following species is isoelectronic with
2
CO ?
(A)
3
N

(B) CNO

(C)
2
NCN

(D) All of these
6. In
2
Be the bond order is
(A) one (B) zero (C) two (D) one- half
7. Which of the following molecules has an S S bond ?
(A)
2 2 8
H S O (B)
2 2 7
H S O (C)
3 3
(SO ) (D)
2 2 6
H S O
8. The p d t t back bonding occurs between oxygen and :
(A) phosphorus in
4 10
P O (B) fluorine in HFO
(C) nitrogen in
2 5
N O (D) carbon in
2
CO
9. The hybridization and geometry of BrF
3
molecules are :
(A)
3
sp d and T shaped (B)
3 2
sp d and tetrahedral
(C)
3
sp d and bent (D) None of these
10. The shape of
3
NH is very similar to that of :
(A)
3
BH (B)
3
CH

(C)
3
CH
+
(D)
2
4
SO

Vidyamandir Classes
VMC/Chemical Bonding 39 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : C. Bond [2]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. In
2 2
CH CH CH C CH = , the
2 3
C C bond involves the hybridization of the type :
(A)
2
sp sp (B)
3 3
sp sp (C)
3
sp sp (D)
2 3
sp sp
2. The hybridization of the centre atom will change when :
(A)
3
NH combines with H
+
(B)
3
AIH combines with H

(C)
3
NH forms
2
NH

(D)
4
SiF froms
4
SiCl
3. The shape of
2
NH

is like that of :
(A)
2
CS (B)
2
SnCl (C)
2
NO
+
(D)
2
BeCl
4. In the linear
3
I

(tri-iodide ion), the central iodine atom contains :

(A) no unshared pair of electrons (B) four unshared pairs of electrons
(C) three unshared pair of electrons (D) two unpaired electrons
5. The benzene molecule contains :
(A) 6o bonds and 3t bonds (B) 12o bonds and 3t bonds
(C) 6o bonds and 6t bonds (D) 9o bonds and 3t bonds
6. In an sp-hybridized carbon atom,
(A) two p orbitals remain unhybridized and one p orbital gets hybridized
(B) all the three p orbitals get hybridized
(C) one p orbital remains unhybridized and two p oribitals get hybridized
(D) None of the above is true
7. Which of the following hybrid orbitals has the highest value of electronegativity ?
(A)
3
sp (B)
2
sp (C) sp (D)
2
sd
8. By hybridization, we mean hybridization of :
(A) orbitals (B) electrons
(C) both orbitals and electrons (D) None of these
9. The octet rule is not obeyed in :
(A)
2
CO (B)
2
Zn
+
(C)
4
SiCl (D) CO
10. Which of the following ions has an (18 + 2) electronic configuration ?
(A) Cu
+
(B)
3
Fe
+
(C)
2
Pb
+
(D)
2
Xe
+
Vidyamandir Classes
VMC/Chemical Bonding 40 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : C. Bond [3]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following ions has a pseudo-inert-gas configuration?
(A)
2
Zn
+
(B) Cu
+
(C) Ag
+
(D) All of these
2. Which of the following statements is incorrect?
(A) A sigma bond has no free rotation around its axis.
(B) Two p orbitals always overlap laterally.
(C) There can be more than one sigma bond between two atoms.
(D) All of these
3. The number of nonbonding electrons in
2
N is
(A) 4 (B) 10 (C) 12 (D) 14
4. Which of the following compounds is expected to be the most ionic?
(A)
2
PbCl (B)
4
PbCl (C)
4
CCl (D)
4
SiCl
5. Which of the following pairs can form a compound with the maximum ionic character ?
(A) Na and Cl (B) Cs and F (C) Cs and I (D) Na and F
6. A
2
CaC molecules has
(A) one o bond and one t bond (B) one o bond and two t bonds
(C) one o bond and one and a half t bonds (D) one o bond
7. What would be the hybridization state of the two resulting carbon atoms after the C C bond
2 6
C H undergoes heterolytic fission ?
(A)
2
sp both (B)
3
sp both (C)
2 3
sp and sp (D) sp and
2
sp
8. A simplified alpplication of MO theory to the hypothetical molecule OF would give its bond order as :
(A) 2.0 (B) 1.5 (C) 1.0 (D) 0.5
9. Which of the following pairs have identical values of bond order?
(A)
2
2 2
N and O

(B)
2
NO and N
+
(C)
2
CN and O

(D)
2
CO and O
10. Which of the following hydrogen halides has the lowest value of dipole moment ?
(A) HF (B) HCl (C) HBr (D) HI
Vidyamandir Classes
VMC/Chemical Bonding 41 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : C. Bond [4]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Among the following, the species which has the lowest value of bond angle is :
(A)
2
NO

(B)
2
NO (C)
2
NO
+
(D)
2
N O
2. In which of the following pairs do the molecules have identical shapes ?
(A)
2 3
SO and SO (B)
2 3
SnCl and O (C)
4 4
SnCl and XeF (D)
3 3
XeO and I

3. Which of the following species is planar and has a bond angle very close to 120 ?
(A)
3
BF (B)
3
NO

(C)
2
3
CO

(D) All of these
4. Which of the following elements can form both ionic and covalent bonds ?
(A) Argon (B) Hydrogen (C) Iron (D) Neon
5. In which of the following compounds are the molecules joined by intermolecular hydrogen bonds ?
(A) 4-Nitrophenol (B) 2-Nitrophenol
(C) 2-Nitrobenzoic acid (D) None of these
6. Which of the following molecules is formed without following the octet rule ?
(A) BeCl
2
(B)
7
IF (C)
6
SF (D) All of these
7. Water can form a maximum of :
(A) four hydrogen bonds (B) two hydrogen bonds
(C) one hydrogen bond (D) six hydrogen bonds
8. The
2 4
N H molecule contains :
(A) 2 unpaired electrons (B) 3 unpaired electrons
(C) 4 unpaired electrons (D) No unpaired electron
9. During the formation of an ionic bond, the cation may achieve :
(A)
2 2 6
ns or ns np configuration (B) pseudo noble gas configuration
(C) inert-pair configuration (D) All of these configurations
10. In diborane
2 6
(B H ) , the bond formed between B and B is called :
(A) sigma bond (B) 2-centre 2-electron bond
(C) banana bond (D) coordinate bond
Vidyamandir Classes
VMC/Chemical Bonding 42 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : C. Bond [5]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. A covalent bond is formed between :
(A) An electronegative element and an electropositive element
(B) An electronegative element and an electronegative element
(C) An electropositive element and an electropositive element
(D) None of these
2. In a
4
P molecule, the P P P bond angle is :
(A) 120 (B) 109 (C) 60 (D) between 60 and 90
3. The total number of covalent bonds present in the
2
NO
+
ion is :
(A) three (B) two (C) four (D) six
4. Paramagnetism is observed in :
(A)
2
N (B)
2
O (C) He (D)
2
2
O

5. In
3
H O
+
the formal charge on the oxygen atom is :
(A) +1 (B) 1 (C) zero (D) +2
6. Which of the following molecules has a square pyramidal structure ?
(A)
2 2
XeO F (B)
2
XeOF (C)
3 2
XeO F (D)
4
XeOF
7. In the solid state
2 5
N O , exists as
2 3
NO NO
+
. The hybridizations around the N atoms in
2
NO
+
and
3
NO

are, respectively :
(A) sp and sp
2
(B) sp and sp
3
(C)
2 3
sp and sp (D) sp and sp
8. Which of the following pairs of species have identical structures and shapes ?
(A)
2 2
NO and NO
+
(B)
5 5
PCl and BrF (C)
4 4
XeF and ICl

(D)
4 4
XeF and XeO
9. Which of the following ions has resonating structure ?
(A)
2
3
SO

(B)
3
4
PO

(C)
2
4
SO

(D) All of these
10. Which one of the following statements is correct ?
(A) Molecular hydrogen is paramagnetic (B) Molecular nitrogen is paramagnetic
(C) Molecular oxygen is paramagnetic (D) Molecular oxygen is diamagnetic