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4-Chloropyridine hydrochloride
C70223 7379-35-3 Laboratory chemicals, Manufacture of substances
1.2 2. 2.1
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 4) Skin irritation (Category 2) Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3)
2.2
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Supplemental Hazard Statements Hazard symbol(s) R-phrase(s) R36/37/38 R22 S-phrase(s) S26
Irritating to eyes, respiratory system and skin. Harmful if swallowed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
2.3 3. 3.1
4-Chloropyridine hydrochloride
CAS-No.
EC-No.
230-946-1
4. 4.1
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2
4.3 5. 5.1
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Further information
no data available
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
6.4 7. 7.1
EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm
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Break through time: > 480 min Material tested:Dermatril? ( Z677272, Size M) Splash protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 30 min Material tested:Dermatril? ( Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
a) Appearance b) Odour c) Odour Threshold d) pH e) Melting point/freezing point f) Initial boiling point and boiling range g) Flash point h) Evaporation rate i) j) Form: solid no data available no data available 2 at 100 g/l at 20 C Melting point/range: 210 C no data available 198 C - closed cup no data available
Flammability (solid, gas) no data available Upper/lower no data available flammability or explosive limits no data available no data available no data available no data available no data available no data available
k) Vapour pressure l) Vapour density m) Relative density n) Water solubility o) Partition coefficient: noctanol/water p) Autoignition
no data available no data available no data available no data available 550 kg/m3 at 20 C
9.2
Skin corrosion/irritation
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Aspiration hazard
no data available
May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Causes respiratory tract irritation. Harmful if swallowed. Causes burns. May be harmful if absorbed through skin. Causes skin burns.
Additional Information
RTECS: Not available
12.
ECOLOGICAL INFORMATION
12.1 Toxicity
Toxicity to fish no data available LC50 - Oncorhynchus mykiss (rainbow trout) - > 10 mg/l - 96 h
Contaminated packaging
Dispose of as unused product.
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
C70223 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
16.