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1. The document contains 8 problems related to diffusion calculations. It provides information on conditions like temperature, pressures, diameters, lengths, and material properties like diffusivities. It asks the reader to use this information to calculate fluxes, rates, times, and other diffusion-related quantities.
2. The problems provide real-world examples of diffusion including gases diffusing through tubes, evaporation of liquids, diffusion of water vapor and other chemicals. Diffusion concepts like steady-state, equimolar counterdiffusion, and diffusion through multiple phases are covered.
3. Solutions require use of the diffusion equation and transport fundamentals, along with unit conversions and material property values provided. The problems progress from simpler to
1. The document contains 8 problems related to diffusion calculations. It provides information on conditions like temperature, pressures, diameters, lengths, and material properties like diffusivities. It asks the reader to use this information to calculate fluxes, rates, times, and other diffusion-related quantities.
2. The problems provide real-world examples of diffusion including gases diffusing through tubes, evaporation of liquids, diffusion of water vapor and other chemicals. Diffusion concepts like steady-state, equimolar counterdiffusion, and diffusion through multiple phases are covered.
3. Solutions require use of the diffusion equation and transport fundamentals, along with unit conversions and material property values provided. The problems progress from simpler to
Copyright:
Attribution Non-Commercial (BY-NC)
Verfügbare Formate
Als DOCX, PDF, TXT herunterladen oder online auf Scribd lesen
1. The document contains 8 problems related to diffusion calculations. It provides information on conditions like temperature, pressures, diameters, lengths, and material properties like diffusivities. It asks the reader to use this information to calculate fluxes, rates, times, and other diffusion-related quantities.
2. The problems provide real-world examples of diffusion including gases diffusing through tubes, evaporation of liquids, diffusion of water vapor and other chemicals. Diffusion concepts like steady-state, equimolar counterdiffusion, and diffusion through multiple phases are covered.
3. Solutions require use of the diffusion equation and transport fundamentals, along with unit conversions and material property values provided. The problems progress from simpler to
Copyright:
Attribution Non-Commercial (BY-NC)
Verfügbare Formate
Als DOCX, PDF, TXT herunterladen oder online auf Scribd lesen
1. The gas CO 2 is diffusing at steady state through a tube 0.20 m long having a diameter of 0.01 m and containing N 2 at 298 o K. The total pressure is constant at 101.32 kPa. The partial pressure of CO 2 at one end is 456 mmHg and 76 mm Hg at the other end. The diffusivity D AB
is 1.6710 -5 m 2 /s at 298 o K. Calculate the flux of CO 2 in cgs and SI units for equimolar counterdiffusion.
2. Helium and nitrogen gas are contained in a conduit 5 mm in diameter and 0.1 m long at 298 o K and a uniform constant pressure of 1.0 atm abs. The partial pressure of He at one end of the tube is 0.060 atm and 0.020 atm at the other end. The diffusivity of Helium in nitrogen at 298 o K is 6.8710 -5 m 2 /s. Calculate the following for steady-state equimolar counterdiffusion. a) Flux of he in kmol/sm 2 . b) Flux of N 2 . c) Partial pressure of He at a point of 0.05 from either end.
3. A long glass capillary tube, of diameter 0.01 cm, is in contact with water at one end and dry air at the other. Water vapor evaporates at the wet end within the capillary, and the vapor diffuses through the capillary toward the dry end. How long is required for one gram of water to evaporate through this system? The vapor pressure of water is 17.5 mmHg at 20 o C, the temperature at which the entire system is maintained. Take the diffusivity of water vapor in air at 20 o C to be 0.3 cm 2 /s, and assume that the dry air is at a pressure of 760 mmHg. Assume that the distance from the wet interface within the capillary to the dry end is always 10 cm. Gas constant R = 82.057 cm 3 atm/(molK)
4. 2 Find the initial evaporation rate of water, in units of centimeters per second of surface velocity, for the Arnold cell operating at 1 atm and 25 o C as shown. The inside diameter of the tube is 1 mm. Dry air is blow over the top of the tube. The saturated humidity of water in air at 25 o C is 0.0189 lb H 2 O/lb dry air. Diffusivity of water vapor in air at 25 o C is 0.22 cm 2 /s.
5. 2 A process is carried out under ultrahigh vacuum in a reactor whose walls are a glass tube of inside diameter 10 cm and wall thickness 1 cm. We do not want H 2 to leak across the tube wall by diffusion and there by reduce the quality of the vacuum environment for the process. The diffusivity of H 2 in glass at the process temperature, 700 o K, is 10 -8 cm 2 /s. The molar solubility ratio of H 2 in glass is 0.2 (mol/cm 3 ) H 2 in glass/(mol/cm 3 ) H 2 in air. Suppose the tube is one meter long, and the end plates and fittings of the tube are impermeable to hydrogen. Suppose further that at some instant of time the vacuum pump had bought the system to a pressure of 10 -6 torr. The glass tube is surrounded by atmospheric air, and the partial pressure of hydrogen in air is 3.810 -4 torr. Estimate the partial pressure of H 2 inside the glass tube after 1 hour.
Pure water 10 cm 6. 2 A liquid A evaporates at one end of a capillary tube and the vapor diffuses toward the other end, which is open to a large gas space B that is essentially free of A. Assume that the gas B is insoluble in liquid A, and work with the following conditions and properties: Total pressure P = 1 atm Vapor pressure of A P vap = 550 torr Temperature T = 25 o C Capillary length L = 10 cm Molecular weights Mw A = 100, Mw B = 28 Binary diffusivity D AB = 0.25 cm 2 /s a) Find the magnitude of the molar average velocity v M . b) What is the factor by which you would be in error if you assume that y A << 1? c) Is v M constant along the capillary axis? Explain your answer. d) Is v m (the mass average velocity) constant along the capillary axis? Explain your answer.
7. A water droplet having a diameter of 0.16 mm is suspended in still air at 50 o C, 1.013210 5
Pa (1 atm), and 30% relative humidity. The droplet temperature can be assumed to be at 50 o C and its vapor pressure at 50 o C is 7.38 kPa. 1) Calculate the initial rate of evaporation of water if D AB of water vapor in air is 0.288 cm 2 /s. 2) Determine the time for the water droplet to evaporate completely.
8. A lime (CaO) slurry droplet having a diameter D d of 0.20 mm is suspended in a gas containing SO 2 at 50 o C, 1.013210 5 Pa (1 atm). The mole fraction of SO 2 in the gas phase is 10 -4 . Rate of diffusion of SO 2 from the gas to the droplet surface is given by
N s = k d (D d 2 ) c (y g,s y d,s )
In this equation c is the total gas concentration and k d is the mass transfer coefficient for SO 2
in the gas phase given by
k d = 2 2 SO gas d D D
Rate of diffusion of SO 2 from the droplet surface into the interior droplet is given by
N s = k L | (D d 2 ) C * SO2
In this equation C * SO2 is the equilibrium SO 2 concentration at the droplet surface k L | is the mass transfer coefficient for SO 2 in the liquid phase given by
k L | = k L 2 2 * lime lime * SO SO 1 D C D C | | + | | \ . , where
k L = 2 SO D o and the liquid film thickness at the surface is estimated to be 1 m. | = 2 2 * lime lime * SO SO 1 D C D C | | + | | \ . = the enhancement factor of the liquid film coefficient k L due to the very fast reaction of dissolved SO 2 with dissolved lime in the bulk liquid.
The gas- and liquid-phase surface concentrations are related by Henrylaw as follows:
c y d,s = HC * SO2
The Henrylaw constant for the solubility of SO 2 in water at 50 o C is given by
H = 0.054 3 3 mol/cm in gas phase mol/cm in liquid phase
Other data at 50 o C: Equilibrium concentration of lime, C * lime = 1.3510 -5 mol/cm 3 . Diffusivity of SO 2 and lime in water: D lime = D SO2 = 210 -5 cm 2 /s. Diffusivity of SO 2 in gas: D SO2-gas = 0.20 cm 2 /s