Chemistry 134 General Chemistry I

Fall 2010 Instructor: Prof. D. Lawson Office: 111C-SB Phone: 313-593-4921 Email: dblawson@umich. du Course Website: C!ools " Ch mis#r$ 134 Office hours: % 2"3& #o 3"3& in m$ offic or b$ a''oin#m n#. ecture !ection "1 ! ( ) 9"55 * 11"1& )oom 1+9,LB ecture !ection "2 ! ( ) 1"&5 * 2"2& )oom 19-,LB E#aminations: You must reserve Fridays 3:00 to 4:30 pm for 3 regular term examinations. This is a course requirement, no exceptions. $aserin%Chemistry Course I& ' $C (W!O)2*00+ Course Ob,ecti-es: !o in#roduc s#ud n#s #o #h 'rinci'l s of ch mis#r$ wi#h m'hasis on d . lo'in/ an und rs#andin/ of #h fundam n#als of ch mical 'roc ss s. !h 'rimar$ conc '#s #o b 0'lor d ar ch mical r ac#ions1 #h rmod$namics1 /as s1 a#omic and mol cular s#ruc#ur . Course $aterials" !vaila"le at the #oo$store% 1. 2Ch mis#r$" !h C n#ral Sci nc 3 b$ Brown1 L 4a$1 Burs# n and 4ur'h$1 11 #h ,d. 2. S#ud n# Solu#ions 4anual. &ot required% 3. Ch mis#r$ 134 labora#or$ 'ac5 #. 6a.ailabl onlin 7 4. ) /is#ra#ion card for 4as# rin/ 8 n ral Ch mis#r$ 6www.mas# rin/ch mis#r$.com7 %i#h #h 'urchas of a n w boo5 from our boo5s#or 1 $ou will r c i. a r /is#ra#ion card /ood for 2 semesters wi#h an addi#ional card us ful for s#ud n#s #a5in/ Ch mis#r$ 139. :nlin 'urchas for us of #h s$s# m is ;45 and is onl$ /ood for 1 semester. 5. < non-'ro/rammabl sci n#ific calcula#or wi#h a ma0imum of a #wo lin dis'la$. 8ra'hin/ calcula#ors will no# b ' rmi## d durin/ 0amina#ions. Prere.uisites for Chemistry 134 :n $ ar of hi/h school ch mis#r$ Pr .ious or concurr n# nrollm n# in 4a#h 1&4 or 1&5 or =ui.al n#

This is not a typical introductory course' (f you have not had high school chemistry or )it*s "een a +hile, you should "e prepared to s+itch to -hemistry 0.0' This course requires memori/ation of empirical facts along +ith comfort in alge"raic manipulation.

!tu/ents on the Waitlist: L c#ur 1 r ci#a#ion and labora#or$ s c#ions ar lin5 d. ,nrollm n# in a labora#or$ s c#ion is limi# d b$ #h s'ac s a.ailabl in #h labora#or$. >f $our wai#lis# d1 i# is li5 l$ b caus a 'ar#icular labora#or$ s c#ion is fill d. B$ #h #hird l c#ur m #in/ > should 5now who has dro'' d or swi#ch d s c#ions and who can mo. off of #h wai#lis#. >n ord r #o b add d #o a s c#ion1 you must atten/ the recitation an/ laboratory in 0hich you 0ish to enroll1 and $ou mus# a## nd ach #im #ha# s c#ion m #s. !h labora#or$?r ci#a#ion ins#ruc#or canno# add s#ud n#s #o a class. @our labora#or$ and r ci#a#ion ins#ruc#or will r 'or# a## ndanc #o #h l c#ur ins#ruc#or who will #h n ma5 #h n c ssar$ d cisions. :nc $ou ar nroll d in a 'ar#icular labora#or$?r ci#a#ion s c#ion $ou mus# a## nd #h l c#ur s c#ion associa# d wi#h #ha# 'ar#icular s c#ion. Du #o #h lar/ nrollm n#s1 > canno# /uaran# #ha# an$on can / # in#o an$ 'ar#icular s c#ion. Point 1rea2 &o0n L c#ur L c#ur ,0 rcis s Aom wor5 S$s# m 1& Probl m S #s ) ci#a#ion BuiCC s 61& 'oin#s ach7 8rou' ,0 rcis s 61& 'oin#s ach7 >ns#ruc#or 'oin#s 6tentative point schedule% 3& 15& usually 0 per chapter% 4& 9& 1&

Labora#or$ Lab ) 'or#s 619 'oin#s ach7 Pr -Lab BuiC 64 'oin#s ach7 >ns#ruc#or 'oin#s ,0am 3 ! rm ,0ams Dinal ,0am SLC 4odul s 9 ma#h modul s61& 'oin#s ach7 L c#ur r <ssi/n d Poin#s

1+9 44 1& 2+& .0 pts. per exam% 15& 9& 3& 1&9& Minimum !o#al

Gra/in%: !h maEori#$ of $our /rad will b bas d on #h 1&9& or so 'oin#s as lis# d abo. " !h #o#al numb r of 'oin#s ma$ .ar$ d ' ndin/ on #h numb r and l c#ur 0 rcis s and hom wor5 assi/nm n#s. !h r is no 0#ra cr di#. Gra/e !cale: @our final /rad will b bas d on a ' rc n#a/ of #h #o#al 'oin#s. 1&& F - 9& F <G1 <1 <-& F - +& F CG1C1 CB low 9&F , 9& F - -& F BG1 B1 B+& F - 9& F DG1 D1 D< coll / l . l / n ral ch mis#r$ cours is 0' c# d #o ha. #h o. rall class a. ra/ fall n ar #h B-?CG di.idin/ lin . Dor som ' rs' c#i. 1 #ha# m ans 5&F will r c i. a final /rad b low a B- H ecture: !h 'ur'os of l c#ur is #o co. r im'or#an# #o'ics and #o h l' clarif$ som of #h mor difficul# ar as of #h subE c#. !h ins#ruc#or will )O3 co. r all of #h ma# rial n d d #o und rs#and ch mis#r$. Consid r l c#ur as a /uid #o $our own disco. r$ of #h subE c# of ch mis#r$. ># is $our r s'onsibili#$ #o do 0#ra 'robl ms from #h boo51 s 5 h l' wh n $ou ha. #roubl und rs#andin/1 and mos# im'or#an#l$1 rea/ the boo2. E#ams" !h r ar #hr # rm 0ams1 wor#h a ma0imum of 9& 'oin#s ach and a final 0am1 wor#h 15& 'oin#s. !h final is cumula#i. . )oom assi/nm n#s for #h 0ams will b announc d 'rior #o ach 0am. @ou ar r =uir d #o ha. $our s#ud n# >.D. a.ailabl durin/ #h 0amina#ion. @ou can b as5 d a# an$ #im durin/ an 0amina#ion #o 'r s n# $our id n#ifica#ion. Dailur #o show 'ro' r id n#ifica#ion ma$ r sul# in $our no# r c i.in/ a /rad for #ha# 0am. !h 0am sch dul is as follows" ,0am 1 ,0am 2 ,0am 3 Dinal ,0am Drida$ 3"&& #o 4"3& 'm - :c#. 1 Drida$ 3"&& #o 4"3& 'm - :c#. 29 Drida$ 3"&& #o 4"3& 'm - D c. 3 Drida$ 9"3& #o 9"3& 'm - D c. 1+

,. r$ a## m'# will b mad #o ha. # rm 0ams /rad d and r #urn d b for #h Drida$ followin/ #h 0am. Pl as no# #ha# #h final 0am is n#ir l$ mul#i'l choic 1 will b l c#ronicall$ /rad d and #h ori/inal bubbl sh # will no# b r #urn d. @ou can ma5 arran/ m n#s #o s $our bubbl sh # in m$ offic durin/ #h followin/ s m s# r. @ou ha. on w 5 af# r an$ # rm 0am is r #urn d #o r sol. an$ =u s#ion abou# #h /radin/ of #ha# 0am. <f# r #his #im > will no# acc '# an 0am for r -/radin/ no ma## r how .alid #h =u s#ion?obE c#ion. B$ #a5in/ #his cours 1 $ou a/r #o #a5 #h 0ams accordin/ #o #h abo. sch dul . :nl$ und r #h mos# 0#r m circums#anc s will a s#ud n# b allow d #o miss an 0amina#ion. >lln ss1 m'lo$m n#1 #ra. l and d a#h ar not n c ssaril$ r asons for missin/ an 0amina#ion. Docum n#a#ion will b r =uir d #o . rif$ #h l /i#imac$ of an$ r ason for missin/ a r /ular # rm 0am. !h r sul#in/ /rad from a miss d 0amina#ion will r sul# in an 0am /rad #ha# is an a. ra/ of #h o#h r 2 r /ular # rm 0ams and #h final. 4issin/ a s cond r /ular 0am will r sul# in a /rad of & and an$ s#ud n# who miss s #h final 0am will r c i. a /rad of I, as a final /rad 1 r /ardl ss of 0cus . <l# rin/ #h /rad of I, r =uir s #h s#ud n# #o r #a5 #h cours . 4ome0or2" <ll hom wor5 assi/nm n#s will b com'l # d usin/ #h w b-bas d s$s# m 4as# rin/ 8 n ral Ch mis#r$. !h r will b on assi/nm n# associa# d wi#h ach cha'# r and #h r for 1& 'robl m s #s wor#h 15 'oin#s ach. !h =u s#ions 'ro.id d in 1asteringchemistry ar #hos a# #h nd of #h cha'# r in $our

# 0#boo5. Pac5a/ d wi#h #h # 0#boo5 'urchas d a# #h boo5s#or is a card con#ainin/ r /is#ra#ion informa#ion allowin/ $ou #o us 1asteringchemistry. &o not thro0 this car/ a0ay5 @our r /is#ra#ion cod can b us d for as man$ as #wo s m s# rs 6i. . Ch mis#r$ 139 or Ch mis#r$ 1497. Probl m s #s will ha. a s' cific da# and #im b$ which #h $ mus# b com'l # d. 1asteringchemistry will no# allow $ou #o do #h assi/nm n# af# r #h d adlin . 6ecitation" ) ci#a#ion r 'r s n#s an o''or#uni#$ #o wor5 on 'robl ms1 bo#h in /rou's and indi.iduall$1 #o as5 =u s#ions1 r .i w conc '#s. D #ails of how r ci#a#ion wor5s will b /i. n b$ $our r ci#a#ion ins#ruc#or1 bu# in / n ral #h r will b /rou' wor5 and 4 =uiCC s. !h =uiCC s and r ci#a#ion /rou' wor5 will amoun# #o a #o#al of 13& 'oin#s. < ma0imum of 1& addi#ional 'oin#s1 bas d on #h ins#ruc#orJs .alua#ion of $our a## ndanc 1 class 'ar#ici'a#ion1 and coo' ra#ion wi#hin $our /rou'1 will also b assi/n d. !h focus of r ci#a#ion will b on ma# rial co. r d in l c#ur . < sch dul of r ci#a#ion assi/nm n#s and =uiCC s will b 'ro.id d w 5l$. % 5 of ) ci#a#ion S '#. 2& BuiC K1 :c#. 1BuiC K2 Lo.. 15 BuiC K3 D c. 9 BuiC K4 aboratory" Dor . r$ 0' rim n#1 ach s#ud n# will #a5 a 'r -lab =uiC for #h lab 0' rim n# #o b don #ha# da$ #h =uiC will co. r bo#h #h in#roduc#ion #o #h 0' rim n# and #h 'roc dur in.ol. d. !h labora#or$ wor5 i#s lf will b don in /rou's1 unl ss o#h rwis s#a# d. ,ach lab?r 'or# is wor#h a ma0imum of 19 'oin#s. <n addi#ional 4 'oin#s can b arn d for #h =uiC for ach of #h nin lab 0' rim n#s. Dinall$1 1& 'oin#s will b award d a# #h labora#or$ ins#ruc#orMs discr #ion1 bas d on" a## ndanc 1 'ar#ici'a#ion1 and coo' ra#ion. :bs r.anc of saf #$ rul s1 'ar#icularl$ w arin/ /o//l s1 and l a.in/ $our s#a#ion cl an and #id$ ar 0' c# d. !his is a l c#ur and labora#or$ cours . <## ndin/ labora#or$ is a r =uir m n#. S#ud n#s mus# ' rform #h 0' rim n# #o r c i. 'oin#s on #h labora#or$ r 'or#. <n$ s#ud n# who miss s mor #han #wo labora#or$ 0' rim n#s will au#oma#icall$ fail #h cours . ! C $o/ules: Si0#$ 'oin#s ma$ b arn d b$ com'l #in/ s lf-'ac d 0 rcis s1 call d modul s1 in #h Sci nc L arnin/ C n# r1 loca# d in room 1129 SBC%. <l# rna#i. l$1 on ma$ N'ass ou#N of ha.in/ #o do som or all of #h modul s b$ corr c#l$ answ rin/ #h r l .an# =u s#ions on a 'r -# s# adminis# r d durin/ #h firs# labora#or$ ' riod. D #ails ar /i. n in an accom'an$in/ sh #. @ou will no# #ha# all of #h modul s ha. du da# s" in ord r #o / # #h 1& 'oin#s for a modul 1 $ou must com'l # #h modul b$ #h du da# . < modul don la# ma$ arn 5 'oin#s. @ou should com'l # #h modul s as arl$ in #h # rm as 'ossibl * donM# wai# un#il #h du da# . Calculators: ># is our #h Ch mis#r$ Disci'lin Js 'olic$ #ha# onl$ #h followin/ calcula#ors ma$ b us d in 0ams and =uiCC s"

!hos #a5in/ Ch mis#r$ 139 ar r comm nd d #o 'urchas #h C<S>: 115 4S or ,S. :#h rwis 'urchas a Shar' ,L-531L or ,L-531)B Sci n#ific Calcula#or wi#h a 2-lin dis'la$O :r a ! 0as >ns#rum n#s !>-25P or !>-39P. :r an$ similar #$' of non-/ra'hin/1 non-'ro/rammabl calcula#or wi#h limi# d m mor$ is also acc '#abl . 2tudents using other calculators during any qui/ or exam may receive a /ero. Electronic &e-ices inclu/in% la7to7s8 cell 7hones9te#t messa%in%: C ll 'hon s1 la' #o's1 /amin/ s$s# ms or an$ o#h r l c#ronic #ool of dis#rac#ion ar no# b us d durin/ l c#ur 1 0ams1 r ci#a#ions or labora#ori s. S#ud n#s ar 0' c# d #o #urn c ll 'hon s off b for comin/ #o l c#ur . !h rin/in/ or us of a c ll 'hon 1 'a/ r or an$ o#h r communica#ion d .ic durin/ an 0amina#ion will cons#i#u# imm dia# 0'ulsion from #h 0amina#ion. !h con#inuous dis#rac#ion of # 0# m ssa/in/ and?or la'#o's ha. b n 'ro. n #o r duc #h ' rformanc of s#ud n#s. &o not 0aste your time in lecture :or 0hile /ri-in%; 0ith such /e-ices5

S!<!,4,L! :D <C<D,4>C >L!,8)>!@ !h Ini. rsi#$ of 4ichi/an-D arborn .alu s acad mic hon s#$ and in# /ri#$. ,ach s#ud n# has #h r s'onsibili#$ #o und rs#and1 acc '#1 and com'l$ wi#h #h Ini. rsi#$Js s#andards of acad mic Conduc# as s # for#h b$ #h Cod of <cad mic Conduc#1 as w ll as 'olici s s#ablish d b$ #h schools and coll / s. Ch a#in/1 collusion1 misconduc#1 fabrica#ion1 and 'la/iarism ar consid r d s rious off ns s. Qiola#ions will no# b #ol ra# d and ma$ r sul# in ' nal#i s u' #o and includin/ 0'ulsion from #h Ini. rsi#$. Ch a#in/ will no# b #ol ra# dH Ch a#in/ on 0amina#ions will r sul# in a /rad of , for #h cours . !h ) /is#rar1 Qic Chanc llor1 and #h <ssocia# D an of $our coll / will b inform d of #h incid n#. !h r will b a no# abou# #h incid n# add d #o $our uni. rsi#$ r cord1 and $ou will no# b allow d #o dro' #h cours . <s ch a#in/ has b com a som wha# common occurr nc 1 i# is 0' c# d #ha# s#ud n#s mus# 'olic ach o#h r. <n$ sus'icious ac#i.i#$ should b r 'or# d #o $our ins#ruc#or. Dailur #o r 'or# ch a#in/1 collabora#i. or o#h rwis 1 ma$ r sul# in loss of a cur. #hus r ducin/ #h final /rad of s#ud n#s no# in.ol. d. <c#s of ch a#in/ on 0amina#ions includ " <n$ addi#ional informa#ion not 'ro.id d b$ #h ins#ruc#or. i. . crib sh #s1 'ro/rammabl calcula#ors1 wri#in/ on #h s5in or a ha#1 l a.in/ informa#ion on #h floor1 #c. <n$ form of communica#ion r la$in/ informa#ion abou# #h 0am durin/ #h 0amina#ion ' riod. Communica#ion of an$ 5ind whil an 0amina#ion is in 'ro/r ss could r sul# in an accusa#ion of ch a#in/. Do no# #al5 i#h r durin/ #h 0amina#ion or wh n submi##in/ $our answ rs. <c#s of ch a#in/ in labora#or$" Isin/ informa#ion from labora#or$ r 'or#s of 'r .ious s m s# rs. Isin/ answ rs #o =u s#ions from o#h r labora#or$ /rou's. Pla/iarism of an$ 5ind. 4a5in/ u' or falsif$in/ da#a. 4ome0or2: ># is 0' c# d #ha# s#ud n#s will wor5 #o/ #h r on #h hom wor5. >n fac#1 wor5in/ #o/ #h r is ncoura/ d. Aow . r1 if $ou1 or som on $ou ma$ b h l'in/ do no# und rs#and #h answ rs1 #h n som on is failin/ #o l arn. %h n wor5in/ in /rou's1 5 ' #h m small. 8rou's of 2 or 3 wor5 b s#. %h n #h /rou' siC / #s #oo lar/ 1 ' o'l # nd #o wai# for answ rs ra#h r #han sol. #h ir own 'robl ms. D):P <LD <DD D<@ !u sda$1 S '# mb r 21 is #h las# da$ #o dro' #h cours wi#hou# r cord. ># is also #h final da$ #o add #h cours . Lo. mb r 9 is #h final da$ #o s l c#i. l$ dro' a cours . L<B:)<!:)@ A,<L!A C:LS>D,)<!>:LS Subs#anc s which ar us d or handl d durin/ #h # rm ma$ carr$ h al#h ris5s for c r#ain s#ud n#s d s'i# our ffor#s #o minimiC 'o# n#ial haCards. Dor 0am'l 1 c r#ain s#ud n#s ma$ ha. all r/i s r la# d #o som ch micals. >f $ou ha. 'ar#icular h al#h conc rns1 'l as con#ac# $our lab ins#ruc#or or m and s 5 m dical ad.ic in ord r #o d # rmin wh #h r or no# #o con#inu #h cours . Pl as no# " $ou must a## nd #h labora#or$ in ord r #o 'ass Ch mis#r$ 134. Ind r an$ circums#anc 1 missin/ mor #han 2 0' rim n#s is /rounds for failur . !ummary 4as# rin/8 nCh m* usin/ #h r /is#ra#ion card from $our boo5 'ac5a/ 1 /o onlin and r /is# r. ,0ams* 4a5 room in $our sch dul s for 0amina#ion da# s and #im s and ha. #h 'ro' r calcula#or. ) ci#a#ions * <## nd r ci#a#ions1 brin/ =u s#ions. Labora#or$ * r ad 0' rim n#s in ad.anc and b 'r 'ar d for #h lab =uiC.

Chem 134 ecture sche/ule<s: Fall 2010

Lecture Topic
Matter and Measurement Atoms, Molecules Stoichiometry Exam I A"ueous )eactions ,ases Exam II !hermochemistry .lectronic Structure o( Atoms 0eriodic 0roperties o( .lements Exam III /o Lecture (Thanksgiving Day) %hemical 7ondin3 Molecular ,eometry87ondin3 FINAL EXAM Fr !a" 6#30 $m t% 9#30 $m Ions

Chapter
1 2 3 Ch. 1,2,3 4 1$ Ch. 4, 10 5 1 ' Ch. 5, 6, 7

Dates*
Sept. 9 Sept. 16 Sept. 23 Oct. 1

Laboratory
Introduction to the Laboratory Lab !echni"ues and #ata Analysis Mass %onser&ation and %omposition Stoichiometry o( )eactions

Week of
Sept. 13 Sept. 2$ Sept. 2'

*ct. 4 *ct. 11 *ct. 1*ct. 25 /o&. 1 /o&. /o&. 15

Oct. 5 Oct. 14 Oct. 29 Oct. 26 Nov. 2 Nov. 11 Dec. 3 Nov. 25

%hemistry o( %opper+ A Series o( )eactions Solutions .udiometry !hermodynamic Measurements 0eriodic 0roperties .mission Spectroscopy and Atomic *rbitals !han2s3i&in3 4ee2 5no labs6 Spectrophotometry Molecular ,eometry

/o&. 22 /o&. 29 #ec. 1

9 Ch. 1 & 10

Nov. 23 Dec. 7 Dec. 17

*Dates associate !ith "ect#$es a$e tentative !he$eas e%a& ates a$e 'i%e . (n the event o' schoo" c"osing (i.e. inc"e&ent !eathe$) a $eg#"a$ te$& e%a& !o#" )e postpone to the 'o""o!ing *$i ay.