w w w e tr .

X m ap eP
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education 0620/01
May/June 2007 45 minutes Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

s er om .c

CHEMISTRY Paper 1 Multiple Choice

*3849119746*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16. You may use a calculator.

This document consists of 16 printed pages.

IB07 06_0620_01/2RP UCLES 2007

[Turn over

2 1 When there is no wind, the scent of flowers can be detected more easily on a warm evening than on a cold evening. This is because the molecules of the scent 1 Which words correctly complete gaps 1 and 2? gap 1 A B C D 2 condense condense diffuse diffuse gap 2 nearer to the flowers further from the flowers nearer to the flowers further from the flowers 2 than in colder conditions.

A student investigates if, at 30 oC, the concentration of acid affects how rapidly it reacts with a known mass of magnesium. The student has a beaker, concentrated acid, water and the apparatus below. P Q R S a balance a clock a measuring cylinder a thermometer

Which of these pieces of apparatus does the student use? A B C D 3 P, Q and R only P, Q and S only Q, R and S only P, Q, R and S

The boiling point of liquid X is lower than that of water. To test a student, a teacher covers up the numbers on a thermometer. The student places the thermometer in boiling liquid X. The diagram represents part of the stem of this thermometer.

mercury

What could the temperature on the thermometer be? A 75.5 C B 84.5 C C 104.5 C D 105.5 C

UCLES 2007

0620/01/M/J/07

3 4 Which mixture can be separated by adding water, stirring and filtering? A B C D 5 barium chloride and sodium chloride copper and magnesium diamond and graphite silver chloride and sodium nitrate

p X. An atom has the symbol q

Which value determines the position of the element in the Periodic Table? A B C D 6 p q pq p+q

Element Y is in the second Period of the Periodic Table. An atom of element Z has six more protons than an atom of element Y. Which statement must be correct? A B C D Elements Y and Z are in the same Period. Elements Y and Z have the same number of electrons in the first shell. Element Z has six more electrons in its outer shell than element Y. The nucleon number of element Z is six more than that of element Y.

The diagram shows the structure of methane.

H H C H
What is the total number of electrons used for bonding in this molecule? A 2 B 4 C 8 D 10

UCLES 2007

0620/01/M/J/07

[Turn over

4 8 The diagram shows the structure of a substance.

What is represented? A B C D 9 diamond ethane graphite poly(ethene)

In the diagrams, circles of different sizes represent atoms of different elements. Which diagram can represent hydrogen chloride gas?
A B C D

10 Boron, B, forms an oxide. Which equation is correctly balanced? A B C D 2B + 3O2 B2O3 2B + 3O2 2B2O3 4B + 2O2 2B2O3 4B + 3O2 2B2O3

UCLES 2007

0620/01/M/J/07

5 11 Students are asked to state the number of atoms in one molecule of ethanoic acid, the relative molecular mass, Mr, of this acid.

Which line is correct? number of atoms A B C D 8 8 9 9 Mr 32 60 26 46

12 A molten compound is electrolysed. Two atoms of X are deposited at the negative electrode at the same time as three atoms of Y are deposited at the positive electrode. These results show that: X is a 1; Y is a 2; the formula of the compound is 3 . How are gaps 1, 2 and 3 correctly completed? 1 A B C D metal metal non-metal non-metal 2 non-metal non-metal metal metal 3 X3Y2 X2Y3 X3Y2 X2Y3

13 In which electrolyses are chlorine, hydrogen and sodium hydroxide all produced? aqueous sodium chloride A B C D     molten sodium chloride    

UCLES 2007

0620/01/M/J/07

[Turn over

6 14 The diagram shows a match.

By striking the match, a chemical reaction takes place. Which statements about the chemical reaction are correct? type of reaction A B C D endothermic endothermic exothermic exothermic reason because energy is used to strike the match because energy is given out as the match burns because energy is used to strike the match because energy is given out as the match burns

15 Which process is not exothermic? A B C D burning a fossil fuel obtaining lime from limestone radioactive decay of 235U reacting hydrogen with oxygen

16 Three reactions used in the manufacture of sulphuric acid are shown. 1 2 3 S + O2 SO2 2SO2 + O2 2SO3 SO3 + H2O H2SO4

Which of these reactions are redox reactions? A B C D 1 only 3 only 1 and 2 only 2 and 3 only

UCLES 2007

0620/01/M/J/07

7 17 In an experiment using dilute acid and a metal, the speed at which hydrogen is released is measured (curve X on graph). The experiment is repeated but with one of the conditions changed (curve Y on graph).

total volume of hydrogen

Y X

0 0 time

Which changes in condition could result in curve Y? increase in concentration of acid A B C D     increase in particle size of metal     increase in temperature    

18 Aqueous sodium hydroxide and aqueous ammonia each give a white precipitate when added to aqueous zinc sulphate. What happens when an excess of each of these reagents is added? excess NaOH(aq) A B C D precipitate dissolves precipitate dissolves precipitate does not dissolve precipitate does not dissolve excess NH3(aq) precipitate dissolves precipitate does not dissolve precipitate dissolves precipitate does not dissolve

UCLES 2007

0620/01/M/J/07

[Turn over

8 19 Aqueous sodium hydroxide is added to two different solutions with the results shown.
X Y

green precipitate formed

light blue precipitate formed

What are the cations present in X and Y? X A B C D copper(II) copper(II) iron(II) iron(III) Y iron(II) iron(III) copper(II) copper(II)

20 In which experiment does the limewater not turn milky?

suction pump acid limewater ethanol limewater

magnesium carbonate

acid limewater iron filings limewater

UCLES 2007

0620/01/M/J/07

9 21 Two indicators, bromophenol blue and Congo red, show the following colours in acidic solutions and in alkaline solutions. indicator bromophenol blue Congo red acid yellow violet alkali blue red

A few drops of each indicator are added to separate samples of a solution of pH 2. What are the colours of the indicators in this solution? in a solution of pH 2 bromophenol blue is A B C D blue blue yellow yellow Congo red is red violet red violet

22 Aqueous lead(II) nitrate is added to a solution containing iodide ions. Lead(II) iodide is formed. Which type of reaction takes place? A B C D neutralisation oxidation precipitation reduction

23 The diagram shows an outline of part of the Periodic Table.

W Y Z

Which two elements could form a covalent compound? A W and X B W and Y C X and Y D X and Z

UCLES 2007

0620/01/M/J/07

[Turn over

10 24 Which substances react with aqueous potassium bromide to form bromine? chlorine A B C D     iodine    

25 Why are some weather balloons filled with helium rather than hydrogen? A B C D Helium is found in air. Helium is less dense than hydrogen. Helium is more dense than hydrogen. Helium is unreactive.

26 The table shows the densities of some Group I metals. Which of these metals sinks in benzene (density = 0.88 g / cm3) but floats in nitrobenzene (density = 1.2 g / cm3)? metal A B C D lithium sodium potassium rubidium density, in g / cm3 0.53 0.97 0.86 1.53

27 The diagram shows the properties of four substances. Which one could be magnesium?
Does it bend or break easily?

bends Does it react with dilute hydrochloric acid?

breaks Does it react with dilute hydrochloric acid?

yes A

no B

yes C

no D

UCLES 2007

0620/01/M/J/07

11 28 In native copper, the element occurs as the metal, not as a compound. Gold is below copper in the reactivity series. Which can be deduced about the properties of gold? it occurs native A B C D     it reacts with dilute sulphuric acid    

29 The diagram shows a method for displacing a metal from its oxide.
excess of hydrogen burning

metal oxide hydrogen

heat

Which metal can be displaced from its oxide by using this method? A B C D calcium copper magnesium potassium

30 Stainless steel is used to make cutlery. Aluminium is used to make food containers. Which property do both metals have that makes them suitable for these uses? A B C D They are good conductors of electricity. They are good conductors of heat. They are resistant to corrosion. They are very strong.

UCLES 2007

0620/01/M/J/07

[Turn over

12 31 Which process takes place in the conversion of iron into steel? A B C D Basic oxides are removed. Carbon is converted to carbon dioxide. Iron is oxidised. Iron oxide is reduced.

32 In which industrial process is the presence of water not essential? A B C D the electrolytic purification of copper the production of ethanol from ethene the production of ethanol by fermentation the production of iron in the Blast Furnace

33 The pie chart represents the composition of air.

What is gas X? A B C D carbon dioxide hydrogen nitrogen oxygen

UCLES 2007

0620/01/M/J/07

13 34 The diagram shows an experiment in which ammonia is released.

damp litmus paper

ammonia mixture of solution X and aqueous ammonium sulphate

heat

Which line in the table is correct? solution X A B C D aqueous sodium hydroxide aqueous sodium hydroxide dilute sulphuric acid dilute sulphuric acid final colour of litmus paper blue red blue red

35 A bag of fertiliser Watch it grow contains ammonium sulphate and potassium sulphate. Which of the three elements N, P and K does Watch it grow contain? N A B C D     P     K    

UCLES 2007

0620/01/M/J/07

[Turn over

14 36 When limestone is heated very strongly in air, lime is made. What is the formula of limestone and of lime? limestone A B C D CaCO3 CaCO3 CaO Ca(OH)2 lime CaO Ca(OH)2 CaCO3 CaCO3

37 Bromine and steam each react with ethene. Which of these reactions need a catalyst? Br2 / ethene A B C D     steam / ethene    

38 What are formed when glucose is fermented? A B C D ethanol and carbon dioxide ethanol and oxygen ethene and carbon dioxide ethene and oxygen

39 Which formula represents a compound that dissolves in water to form an acidic solution?
A H H C H H C H H C H H H H C H B H C H C H H H C H H C H C H C H H C H O H H H C H D H C H C O H O

UCLES 2007

0620/01/M/J/07

15 40 Butane reacts as shown.

butane catalyst and heat butene + hydrogen

What is this type of reaction? A B C D combustion cracking polymerisation reduction

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

UCLES 2007

0620/01/M/J/07

DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulphur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
49 201 204 50 207 51 209 52 53 54

0620/01/M/J/07

Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

79

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).