Beruflich Dokumente
Kultur Dokumente
60 Spring 2005
Lecture #6
page 1
Reversible Adiabatic Expansion (or compression) of an Ideal Gas 1 mole gas (V1,T1) = 1 mole gas (V2,T2) adiabatic q = 0 Ideal gas Reversible dU = Cv d T w = -pd V
dU = -pd V
CV dT dV = R T V
T2 V1 = T1 V2
R CV
CV dT = pdV
CV
T2
p =RT V
2
T1
V dV dT = R V V T
1
C p CV =R for i.g.
T2 V1 CV = T1 V2
Cp
Define
Cp CV
T2 V1 = T1 V2
5 ( > 1 generally) = 5 3 Cp = R 2
CV = R 2
In an adiabatic expansion (V2 > V1), the gas cools (T2 > T1). And in an adiabatic compression (V2 < V1), the gas heats up. For an ideal gas (one mole)
pV
pV T = R
p2 V1 = p1 V2
pV 1 1 = pV 2 2
T = constant
pV = constant
Lecture #6
page 2
p p1 V2adiabat < V2isotherm because the gas cools during reversible adiabatic expansion V2ad V2iso
p2 V1
Irreversible Adiabatic Expansion of an ideal gas against a constant external pressure 1 mol gas (p1,T1) = 1 mol gas (p2,T2) adiabatic Constant pext = p2 Ideal gas 1st Law Integrating: Using pV = RT Note q = 0 w = -p2d V dU = Cv d T dU = -p2 dV (pext=p2)
Cv d T = - p2 dV Cv ( T2 - T 1 ) = - p2 ( V2 - V1 )
T2 (CV + R ) =T1 CV +
p2 R p1
p2 < p1
T2 < T1
Lecture #6
page 3
p p1 p2 p3
(I)
(T 1)
p p1 p2
(T 1)
(II) D (const. p ) A
(isotherm) (T 3)
A (isotherm) B
(rev. adiabat) (T 1) (T 2)
E (const. V)
(T 1)
C (const. V)
V1
V2
const. T
V1
V2
[A]
U A = 0
V qA = RT1 ln 2 V1
rev.adiabat
=R ln
V2 V1
[B]
UB = CV (T2 T1 ) HB = C p (T2 T1 )
wB = CV (T2 T1 )
1st Law:
qB
=0
Lecture #6
reversible const. V
page 4
[C]
UC = CV (T1 T2 ) H C = C p (T1 T2 )
qC = CV (T1 T2 )
T = CV ln 1 T2
qC
[A]
UA = 0 H A = 0
V qA = RT1 ln 2 V1 V w A = RT1 ln 2 V1
vs.
[B] + [C]
UB + UC = 0 = UA H B + H C = 0 = H A
qB + qC = CV (T1 T2 ) qA w B + w C = CV (T2 T1 ) w A
qA
= R ln
V2 V1
qB
qC
T
V q = R ln 2 = A T V1
[D]
UD = CV (T3 T1 ) HD = C p (T3 T1 )
qD = C p (T3 T1 )
wD = R (T3 T1 )
qD
T = C p ln 3 T1
Lecture #6
page 5
[E]
UE = CV (T1 T3 ) HE = C p (T1 T3 )
wE = 0
qE = CV (T1 T3 )
T
[A]
UA = 0 H A = 0
V qA = RT1 ln 2 V1 V w A = RT1 ln 2 V1
qE
T = CV ln 1 T3
vs.
[D] + [E]
UD + UE = UA HD + HE = HA
qD + qE = R (T3 T1 ) qA wD + w E = R (T3 T1 ) w A
qA
= R ln
V2 V1
qD
qE
T
V q = R ln 2 = A T V1