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4.1 4.1.1
Viscosity is a property that is exhibited by all material that is capable of flow (fluids). The range of these fluids is from gases, which are not covered here, through thin hydrocarbons to gelatinous and sticky gels. Viscosity is the property that generates a resistance (internal friction) to relative movement between adjacent layers. The internal friction manifests itself in a velocity gradient D perpendicular to the direction of flow, i.e. adjacent layers have different velocities v and in such laminar flow a force t acts between these layers in the direction x. The velocity gradient D is defined as the ratio of the velocity difference vx = vx2 vx1 between two positions 1 and 2 and the distance between them y: D = lim vx dvx y > 0 () = y dy
Fig. 4.1.01
Simple diagram showing viscous flow, velocity gradient and shear stress.
By plotting the velocity gradient D over the shear stress , the fluidity curve of the fluid is generated.
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The viscosity curve is obtained by plotting the ratio of shear force / velocity gradient /D over the shear force or the velocity gradient D. From the characteristic of the curve the fluidity and / or viscosity properties of the fluid can be read off and the type of fluid differentiated as follows: 4.1.1.1 Newtonian fluids A Newtonian fluid is an isotropic linear viscous fluid which satisfies the following conditions: a) Shear stress t and velocity gradient D are directly proportional b) In the simple shear flow (see fig. 4.1.01) the normal stresses in the directions of the x axis, the y axis and vertical to that are equal. Examples of Newtonian fluids are water and light oils. The relationship between the shear stress and the velocity gradient D is given as: = D The proportionality constant denotes this characteristic property of a liquid and is called the dynamic viscosity. The value of the viscosity is dependent on temperature, i.e. by rising temperature the viscosity reduces. The ratio of dynamic viscosity divided by the density is known as the kinematic viscosity . = / 4.1.1.2 Non-Newtonian fluids Non-Newtonian fluids are fluids and materials which have non-linear viscosity and materials (e.g. plastics) with linear and non-linear elasticity. Fluids and materials which have non-linear viscosity are: Pseudo-plastic fluids Non-linear pure viscous fluids, for which the viscosity reduces with increasing velocity gradient (see fig. 4.1.02a). Examples of pseudo-plastic fluids are fats, molasses, paint, soap, starch and many emulsions. Dilatant fluids Non-linear pure viscous fluids, for which the viscosity increases with increasing velocity gradient (see fig. 4.1.02b). Examples of dilatant fluids are suspended solids, especially clay / water suspensions and dissolved sugars.
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Plastic materials
The behaviour of this material is characterised by limiting value, i.e. the material only begins to flow above the limit value, (see fig. 4.1.02 c). Below the limit value the material is either not deformed at all or only elastic deformation occurs. There are several rheological models for this behaviour. The best known is the Bingham model. An example of a Bingham fluid is tomato ketchup.
Fig. 4.1.02 Typical flow curves (top) and viscosity curves (bottom) The flow behaviour of non-Newtonian fluids described above is always independent of time. However flow behaviour can be time dependent and these fluids are known as thixotropic or rheopectic. Thixotropic is a time dependent flow behaviour in which the viscosity reduces from the stationary value to a lower limit as a result of a constant mechanical force. After removal of the force the viscosity is restored. An example of a thixotropic fluid is non-drip paint. Rheopectic is a time dependent flow behaviour in which the viscosity increases from the stationary value to a higher limit as a result of a constant mechanical force. After removal of the force the viscosity is restored.
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Fig. 4.1.03 Dependence of the viscosity on the shear velocity 4.1.2 4.1.2.1
The performance of centrifugal pumps with radial impellers pumping viscous liquids General
The performance of centrifugal pumps will vary when viscous liquids are pumped. For medium and high viscosities, the power requirement increases considerably, whilst the head and to a lesser extent the flowrate, is reduced. With the aid of diagram fig. 4.1.06, (section 4.1.2.3), the characteristics of a centrifugal pump pumping viscous liquids can be calculated providing the characteristic for pumping water is known. Conversely, the diagram may also be used to select a pump for given requirements. The correction factors established from the diagram are sufficiently accurate for general application within the limits given. If more accurate values are required, then a test should be performed with the particular liquid. Due to the considerable loss of efficiency when pumping viscous liquids when using centrifugal pumps, it is recommended that other types of pump be considered (e.g. rotary positive displacement pumps), which could give more economical running costs. The limits for centrifugal pumps are: For discharge nominal diameter: < 50 approx 120 to 300 mm/s < 150 approx 300 to 500 mm/s > 150 approx 800 mm/s
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Limitations and tips on the use of the diagram fig. 4.1.06: The diagram should only be used for centrifugal pumps with open or closed radial impellers within their normal Q-H range. The diagram must not be used for pumps with mixed flow or axial flow impellers, or for special pumps for viscous or heterogeneous liquids. For side channel pumps use section 4.1.3. The diagram should only be used if there is sufficient (NPSH) available (NPSHA) to prevent the influence of cavitation. The diagram can only be used for homogeneous Newtonian fluids. For gelatinous and sludgy liquids, liquids containing fibrous material and other heterogeneous liquids, widely scattered results are obtained in practice, depending on the special properties of the liquid. With multistage pumps, the head per stage must be used in the calculation. For pumps with double entry impellers, half the flowrate must be used in the calculation. Selection of pump size for a viscous liquid vis w Given : Required: Hvis in m, viscous liquid water kinematic viscosity in mm/s, vis in kg/dm