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STUDENT MANUAL
CASE STUDY It is easier to learn how to use PROVISION by doing a simple case study. Let's start by looking at a simple compression system. 1000 lb. moles per hour of gas mixture containing 5% methane, 20% ethane, 25% propane, 30% n-butane, and 20% n-pentane at 14.7 PSIA and 90F is to be compressed first to 50 PSIA, then to 200 PSIA using a two-stage compressor system. An inter-stage cooler is used to cool the compressed gas from each stage to its original temperature. A knockout drum is installed after the first cooler to remove any liquid present in the compressed gas before feeding it to the second compressor. Let's solve this case step by step using PROVISION.
STEP 1: Identifying the Case Before starting PROVISIo'N,. it would be a good idea to draw a process flow diagram (PFD) on a piecq of paper. When drawing a PFD, try to label each unit and stream systematically, so you can easily identifY them. The purpose of a PFD is to visualize the process and to roughly understand the case. A rough sample PFD should look like this:
r---IS2 !---<:>,
noo lbmol.>W
14.7 p:s:i1l
lOF
Methene Ethane
D..GS
lOF
W'lllter
1.80
GiL>
It would be a good idea to write down all the known data for to do any calculations by yourself, because PROVISION does
STEP 2 Starting PROVISION Once the basic PFD is drawn and the problem has been identified, you are ready to start PROVISION. To start PROVISION, double click on the PrOlision 1.02 icon in SimSci group. You will be greeted with a welcome menu. Read the menu. It tells you some basic things you need to know when using PROVISION.
E9
1.2 .....
User'supplied dala. entry satisfied Caulion. usersupplied dala outside normal fimils
To bypa.. (or reslore)lhis window for fulure PROVISION sessions. select OptionslWelcome to PROVISION from the menu bar.
OK
Click on the I
0<
There are many boxes, icons, or buttons that have color coded borders. In PROVISION each color code tells the user about that box, icon, or button. RED border Data or action is required. The calculation may only be performed when all of these red bordered conditions are met. Default data or action, user may override. Used for fine tuning the process to meet your specification. User supplied data, entry satisfied. Caution, user supplied data outside normal limits
5
GREEN border
The first step for approaching a case is to draw a complete process flow diagram. To draw a PFD, follow these steps. 1 Click on New on File menu to start a new case. 2 Move the mouse to the palette showing units. For list of units available in PROVISION, refer to Appendix B. 3 Using the figure drawn as a guide, select needed units and place them on the PFD one by one. Click on the Compressor button and thenbutton click and on the space Pressure Change/Compressor then clickin onthe thePFD space in the PFD Heat Exchanger/Simple HX(1) where you wish to place the compressor. Follow the same steps for Simple HX (1), Flash, Compressor (2), and Simple HX (2). You will notice that each unit is named by PROVISION, automatfcally. You will also notice that each name has a red border meaning that the condi/ions have to be supplied. Click on the stream button on the build palette to draw the stream lines. All the possible EXIT ports appear on each unit as soon as the stream button is selected. The required outlet ports are colored red, while the optional exits are given in green. Add streams by clicking on the origin of the stream (either a unit exit port or an ex1:ernal feed stream, on a unoccupied part of the PFD), then click again at the destination of the stream. Continue until all streams have been added to the PFD.
Example: To apply a feed stream to Cl, click on PFD that's not occupied by any unit, then click again at compressor. Notice the name is give as S1.
5 Connect all the streams in order shown in Figure I. Pay special attention to the number of streams. Each stream is numbered in the order they are created.
STEP 4: Defining the Component List Now that the process flow diagram is drawn, you need to specifY the components that are used in the case. To enter the components, follow these steps.
(j)
Click on the IQl icon on the menu bar to specifY components. Enter the names of the components in the Component: window. Click on the I Add, I button to add each component. Type in Methane in the Component: window. Click on the I ADd., ! button. Notice the box has a blue border as soon as you click on the I ADd' I button, meaning that you have supplied the information. Add. the remaining Ethane, Propane, N-butane, Pentane, and Water, and components clicking onfhe button after each component. You can also choose components from a list. To choose from a list, click on the I s"""'" he. LAt.... I button. If you accidentally added an incorrect component to the list, you can remove the component by clicking on the component and clicking on I .- I button.
i
(2)
Cit>
List of Selected Component.: COal'Oli"'" Selection - - - - - - - - - - - - , ';W;;E""T';;HAN;';':;;:;E;======:""_--"'" F,OIIl Sy:t_ Of U.."-genet,,,ed O"'abanlt . ETHANE C"",pouelit IWATER Add -)
II
1 . I
PENTANE
STEP 5: Choosing a Thermodynamic System In order for PROVISION to perform any kind of calculation, a thermodynamic system must be supplied. The thermodynamic system lets the program know which calculation method to use. Since Peng-Robinson is most commonly used, lets choose Peng-Robinson by following these steps.
Click on Most Commonly Used under Category: to select from most comm'only used systems. Click on Peng-Robinson in Primary Method: box and then click on the I Add ., I button to select Peng-Robinson for thermodynamic system.
(3)
All Prima.y Methods Equations 01 Stale liquid Activity Generalized Cooelalions Special Packages
User-added Methods
NRTl
IPR01
m
Renaaeml
I I
calculation em
OJ:
Cancel
Click on the I
Ibutton.
It's always safe to save frequently. To save, click on File on the menu bar and click on Srwe on the File menu. Type in the file name, Case 1, and click on the I 0< I button to go back to PFD.
Feed Stream: S1 <D You can select a stream or unit by double clicking on the name in PFD. Let's first start by completing the beginning feed stream, Sl. Double click on Sl to select that
stream.
<ZJ You can give it a name, Feed Stream, by typing it in the box next to Description:.
(] Click on the 'Fiowtale and CD!!lposilion... 1 button to supply the flow rate and compositions.
Since we know the total flow rate, click on Total Fluid FlowTate and type in 1000 LB-MOLfHR. The border becomes blue as soon as you input the data.
121 Fill in the composition since they have red borders. (0.05,0.2,0.25,0.3,0.2)
Composition
METHANE THANE
PROPANE
(]) To satisfY the phase rule, you need two more variables. For this case you know temperature and pressure To enter temperature, click on the red box named First Specification:. Choose Temperature. Type in the temperature, 90 OF. To enter the pressure, click on the red box named Second Specification: Choose Pressure and type in 14.7 PSIA.
Sbo-;
==1
-l
ToUnc.
Sh_ @
o p_"""",
!FIoMIlle
._ ...
C
...._.
'f ....
o Aehwencod to Stre.a
_..
IT__.....
Socond Specification;
IProuue
1'11,-_ _---'9IJ=."'oo,,1 F
I II
,..7001 PSlA
0<
I button since all the requirements are met. 81 now has a black
f
Compressor: Cl
Change the Adiabatic Efficiency to 80%. Default is 100%, Notice the box is green, meaning that this data can be supplied by the user.
T""""""'"
PlOSlUfI!l. 'Work. [
Of
s_
u..: 10
1
I
If
loutl., "on.,.
Effi:l:i=:m::J'
Of
1.1 I
50.000 PSIA
[1- Ellicieftcy
mI
oo.oooolp......
Click on the I
0<
Heat Exchanger: EJ
the ProlII - Heat CD Double click on the heat exchanger, E1, on the PFD. You will see Excha nger window. s and which Click on the I PNms SWa.. I button to see which streams are hot stream S9 should be streams are cold streams. S2 and S3 should be hot streams, and S8 and clicking on the cold streams. If the sides are not set correctly, you can correct it by appropriate circle.
o HoI
Specify
foe.
@Cold
rs";ds
Specify Informalton for.
@Hot
Cold
'fS";ds
OK
Select the
oduct:!
Click on the I
:,1; Click on the I
13)
(6)
0<
Click on the red box. out of the heat Choose Hot Product Temperature which is the process stream going exchanger. Type in 90 OF for the value.
ill
9O.oo1F
1
V......:
Relative Tofefence:
Alea:
U-Value: W _ Allowabl8 U"A:
I I I I I
OK
0.0010001
IOTUIH IOTUIHR-F
I I
l:ancel
Ct
eciticGtion data
II
D<
<ID Input 3 PSI for Hot Side Pressure Drop: and 2 PSI for Cold Side Pressure Drop:.
Unit
IEl
Proce"u Stream.. _
HDISide
.
P,cnure DJQtJ:
.',
_.
2.0000IpSI
.'
..- ..
!Z....... AnalJ...... !
I S peeiic!l!ion. .. I I Configuration. I
PJeuwc OrllP:
Thermodynamic System:
l0elaull(PROl J
ill
Cancel
Choose Total Fluid Flowrate. Since the set unit is LB-mol/hr, and you have mass flow rate, LBIItr, you must do the conversion. Instead of doing it by yourself, click on the DOM button on the menu bar. Click on Mass and choose LB. Click on I';" I to change the unit.
o long de:cJiption:
B....:
Mole
1(6
VOf/). Vol.
Liq. Vol.
OZ TON
TONM
MIN
\IIJ::
SEC
DAY YR
TONI.
NON
ChMge Unit:
II
ConYert Value
II
Cancel
I
12
Now enter 420000 LBIHR for the f1owrate. Enter 1.00 for the water composition.
(Q) Click on I
(l)
0<
I when done.
Click on I
0<
I to go back to PFD.
Flash: FJ
(2) Click on I Plodutll'll=...1 to'make sure the phases of streams, S4 and S5, are correctly set.
S4 should be apor and S5. should ?e Liquid. Make necessary changes by clicking on mcorrect boxes and selectmg the nght phase.
PIOducb:
F i
f'hMco:
) I
Ellit the "indo" afte< "".
Cancel
all data
<3l Click on I
0<
Input 3 PSI for the Pressure Drop. Click in the Unit Specification: box.
since it's an adiabatic flash drum. Select Duty and type in 0.00 for the value
13
Unot c.IF.:.'
-J
0__
Ic.""""='-
.-J
F.d S p e c i f i e a t i o f ' l - - - - - - - - - - - - , [
D,op
I l
3.oooolpsl
10...... (1'A01)
S,uCC"
1'1
Second SpoccifiCJlltion
L-
-lI F
or
<liJ Click on I or
I
I when
t
Second Compressor: C2
CD Double click on the compressor, C2, on the PFD. (]) Supply the Outlet Pressure as 200 PSIA in the red box.
Unit:
1C2
0"""""",,,
Is......J eo-.....
I
O _ T _..... E......'"
1o.....' "'=e
Elficianq
Of
1_/ IF
.1
I I
I_II
Specification
2IJO.OO PSIA
IA........, Efficie...,.
1-/ I
llIl.OOIJOI_
I
or eonc.,
EnlCf the
(j)
Click on I
0<
to go back to PFD.
14
Check for hot and cold streams by clicking on the I - - . I button. 56 and 57 should be hot, and S I0 and S II should be cold streams. Correct the sides as needed.
o Hot
@ Cold
rsC;-:'
Specif, Infarsation for.
@ Hot
Cold
F;;...
--,
IS6
OK
W
7
I I
Canc<tI
(] Click on I
0<
I when done.
VoIue:
Relolive ToIeJance:
Alea:
I I
I I
ffi
9O.001r
0.0010001
1m
IOTUIH IOTu/HR.r
I I
Q) Click on
0<
I
15
Input 3 PSI for Hot Side Pressure Drop: and 2 PSI for Cold Side Pressure Drop:.
I.::.E::,2
.......JI
I I
."
PIoce:: Sbeaa. ..
:;:<>
I Confll!U'alion...
SpecifICation...
PrenUJe Drop:
PIe.....e Drop:
3.ooool p SI
2.oooolpsl
Thermodynamic System:
Thermodjmamic S,.lem:
l0efault (PR01)
Enter the heat exchan
f
(!]
IDefauM (PROl)
(!]
Cancel
mUNt..d;agta
iiIll
(9) Click on I
OK
Choose Total Fluid F/owrate. Change the unit (UOM-mass-Ib-Cbange Units) and enter 420000 LB/HR
I
Temperature and type in 70 oF.
16
Step 6 Running the Calculation Before running this save it in your user directory. Since you have supplied all the required data to all red bordered areas, you are ready to begin the calculation. To do the calculation follow these steps
"', PROVISION starts the calculation from the beginning of the simulation and goes through every unit operation one by one. During the calculation, each unit goes through color changes. Yellow Red Green Blue Dark Blue Purple
@)
-no calculation performed -unit operation has not been solved -calculation is being performed -unit operation has been solved -unit operation has been calculated -indicates the breakpoint
When the calculation is finished, all the unit operations should be blue, indicating that all the calculations are finished for the entire case. Once the calculations are performed, you do not need to run the calculations again as long as you do not change anything.
17
Step 7: Reviewing and Printing the Results Once the calculations are performed, you are ready to check the results by generating a report. To generate a report, follow these steps: CD Click on Output on the menu bar in main PFD.
(2)
Click on Generate Report on the Output menu to bring up Programmer's File Editor window. You can scroll up and down the report by using the scroll bars. The report lists various information like PROm keyword input commands, component properties, unit operation results and stream results. You can also edit the report by using the Edit menu. You can print the entire report or part of the report by selecting Print in File menu.
<II[>
Generated by Keyword Generation systen <version 2.59 Generated on: 'Sun Jan 08 80:55:32 1995 TITLE DIMENSION ENGLISH SEQUENCE SINSCI OMPOMEHT DATA LIBID 1,METHAME/2,ETHAHE/3,PROPAHE/4,H-BUTAHE/5,PEHTAHE/6,vATER THERMODYNAMIC DATA METHOD SYSTEM-PR, SET-PRIM,DEFAULT STREAM DATA PROPERTY STREAMFS1, TEHPERATURE=90, PRESSURE=14.7, PHASE=", RATE(M)=1UUO, COHPOSITIOH(H)=1,U.05/2,O.2/3,U.25/4,U.3/5,U.2 PROPERTY STREAMFSB, TEHPERATURE=7U, PRESSURE=1UU, PHRSE=", RATE(WT)=420900, COHPOSITIOH(H)=6,1 PROPERTY STREAl4=S10, TEHPERATURE=70, PRESSURE=100, PHASE=H, & RATE(VT)-420000, COHPOSITIOH(H)-6,1 NAME S1,Feed Strean HIT OPERATIONS COMPRESSOR UID=C1, NAME=First CORpressor FEED 51 PRODUCT U=S2 OPERATIOH PRE5=50, EFF=BO COMPRESSOR UID=C2, NAME=Second CORpressor FEED S4 PRODUCT 0-S6
..
. ..
To exit the Programmer's File Editor window, double clicking on the bar,EI, located in the top, left comer of the screen.
Step 8 Review results from PFD Point cursor to stream or unit operation and click on the right button of your mouse and choose view results
GJ Click on New List button in Deline Property List window to name the new list Type CASEl for the List Name:
list N....:
Copy list:
"'ICA:..;S;;.:E:..;l
"'IN:.:on:.:.:.......
-'1 ill
raeen.
OK
Cancel
@)
Click on the I 0< I button to go back to Define Property List window. Choose the properties to include in the list from Select Properties box. Click on Stream Name,
Phase, Total Molar Rate, Temperature, Pressure, Enthalpy, and Molar Compo Fractions. Click on button to add the selected properties into
==...::::.':===______,
ForllWl
I r'' ';q,: . :iT.; .. ...... :r=;;;R.. :i:.:---,"':"I. r. . .... 5k .... =---...s"' ..... =ii' .... =-----i:,..c=::., s2
liquid Wolet:J.licf Weight liquid Sp. EnIh.a!pf Uquid CP liquid DomiI, Weight COI:q). RotCI
liquid Rde
R.
TotelY. Rde
Pha:t:o
.t.Jf
t.a
Preuure
l:!o!l!If Co:np. frac:til:zru
Pteuure
t:.31
%.31
%.31 %.41
'--
-.J
19
I.
the-list te CASEl.
The
tQl
911
Once the property list has been defined, you can now place the material and energy balance on the PFD. Follow these steps to place property table on the PFD.
(j)
Q)
Click on Output on the menu bar in main PFD window. Click on Stream Properly Table. on the Output menu.
(] Click on PFD fhere you want to place the property table to place the table.
@)
(9 Choose
CASEl in Property List to be used: box. PROVlSION will use the CASEl property list generated earlier.
(/i) You can select the streams you want by clicking on each stream
by clicking on I ... AI
ASlAI
T_ _......
L........
_c:Im
I Define C
StreeD
0 ....
90Md 6roup:L..
11_"_
..-., .
.
Boulet Yrdh:
o.:m
Saoction---------------------,
Avaieb!o
: 51
52
..
SDUICS/sink 5tJN5aI:
'--
. . . . . . III-AB!
: 53 , 54 .. S5
-, 56
'- .. ,,_.,
57
20
T..... T ...
.... ....
;,
"'...
..
"v_ .,." """"'" _roo ,..., "'''', , ""'" 'MOO """" '''00 '''''' ,= ,
v_, .. "
02000
... -. .
"..... .,."'" uroo " ,moo ,moo ''''''' ,
v_ " ,n.\:::I.
"".,
....
0,2000
(I
'''''''
0,2000
.... ,....
"oro
v_ ..... " " ",'" """ ,."'" ..... .uu ""." nr.ooo .,,'" u"" ,.,"" lun '" .,., .m ""'" """" ",oro ''''''' ,",," ..... ...... """ or," ,.,., , ..,., ,,,,, ,.,. ,.,. , "'" , , .... ."'" ."''''
n",
Z1:nl.1I01
2:l:'1UGI
"
:!IO,COO
C.20U
0.0"1 00121
"",
... ,021"
Q,lS*!
.'" , .... .... ..... .... , ..... ,... ..... ..,... ,..... ...... .... .....
0,0000
"'." .. oro
....
...
'00'"
''''''''
Printing PFD
Printing the PFD can be done easily following these three steps.
(j) Click on Fife on the menu bar in mainPFD window. Q) Click on Print .. on the Fife menu
Gl Click on the I
Ill>
You can draw or print text on PFD by choosing Draw menu on the menu bar.
Placing Text on PFD Go to main menu click Drawltext. After typing text in the box, use mouse to place on PFD
21
22
Side Column
l.p . ..!::JJ I
. HX
Mullivariablt: Conboller
Calculator
Healing Curves
[;1;J
Conversion Reactor
Gibbs Reactor
Piug Flow
tL8IJ
Reactor
Pol Reactor
CST /Boiling
lB
User-added Unit
Sheam PrOPerties
23
Ched Daia
'--
1
..J -
Slatu; J _____J- Lets you to view the results of the Check Data button
__ R_un _ _l_ Starts the simulation (Check Data is automatically performed) Run INo Color:)
Slep
'--
j-
--J -
I....l -
'--
Golo
View Convergern:e
'--_---'=-_....l -
Re:uft:
Show
Breakpoint:
24