Beruflich Dokumente
Kultur Dokumente
as generation in landfills and the risks it represents for the environment have been well documented since the 1970s (Farquhar and Rovers, 1973; EMCON Associates, 1980). Landfill gas contains mainly CH4, approximately 50 to 60% by volume, and CO2 makes up the remaining 40 to 50% (Farquhar and Rovers, 1973). Methane is lighter than air, with a density of 0.7 kg m3 at 10C. Carbon dioxide is a denser gas (1.9 kg m3 at 10C), and it is quite soluble in water. Methane poses serious problems, as it is explosive in concentrations between 5 and 15% by volume and in the presence of O2. Both gases contribute to the greenhouse effect. Moreover, landfill gas usually contains several harmful trace components such as vinyl chloride, benzene, or sulfur dioxide. The latter is responsible for the characteristic unpleasant odor of landfill waste. Due to all these inconveniences, it is very important to control the migration of gas generated in landfills, particularly if they are located in urban areas (Nastev, 1998). The term waste in the following text refers to average domestic waste, that is, household refuse which contains readily, moderately, and inert biodegradable fractions.
H. Vigneault and R. Lefebvre, Institut National de la Recherche Scientibec, fique, INRS-Eau, Terre et Environnement, 490 de la Couronne, Que G1K 9A9, Canada; M. Nastev, Geological Survey of Canada, Natural bec, G1K 9A9, Canada. Resources Canada, 490 de la Couronne, Que Special Section: Research Advances in Vadose Zone Hydrology through Simulations with the TOUGH Codes. *Corresponding author (hvigneau@nrcan.gc.ca). Published in Vadose Zone Journal 3:909916 (2004). Soil Science Society of America 677 S. Segoe Rd., Madison, WI 53711 USA
The physical properties of waste (e.g., density, porosity, saturation, permeability) largely influence gas migration rates. Several studies treat physical properties of waste under saturated flow conditions (Sowers, 1973; Findikakis and Leckie, 1979; Schroeder et al., 1983, 1994; Blais, 1996). There is a general agreement that these properties are highly variable within each landfill site. However, unsaturated hydraulic properties of waste are poorly known, mainly due to the difficulties related to their measurement under field or laboratory conditions. Because of the absence of such data, it is necessary to relate unsaturated waste properties to those of soils assumed to have similar properties. In his model, Nastev (1998) used the unsaturated properties of sandy-silt soil as analogous to those of the waste and applied corresponding capillary parameters, an approach we adopt here. Landfill characterization studies were followed by the development of suitable methods for controlling gas migration and performing active gas recovery (EMCON Associates, 1980; Lofy, 1983; USEPA, 1997). One of the most important parameters to consider during the design of a landfill gas recovery system is the radius of influence of the recovery wells. The definition used here for the radius of influence is the average radial distance from a recovery well defining a volume within which 90% of the landfill gas generated in the waste is recovered at the well. The radius of influence varies with time. Its magnitude is primarily a function of the imposed pumping rate (suction) in the well, but it depends also on other properties, such as the gas generation rate in the waste, the age of the waste, the waste physical properties, the thickness of the waste, and variations in atmospheric pressure. This subject has been so far poorly treated in the literature. In traditional designs, the radius of influence is arbitrarily set at 30 m and the number of wells required at a given site is consequently calculated. However, field tests have shown that the radius of influence may be greater or smaller than 30 m (Lofy, 1983; McBean, 1993). Lofy (1983) indicated that the minimal requirement to establish the radius of influence is the knowledge of the waste permeability and the gas generation rate in the waste. The screened section of the well and the pumping rate are adjusted consequently. The USEPA (1997) established a method to estimate the volume of gas extracted from a well and its radius of influence. However, this study was conducted for a specific landfill site, recovery well design, and waste decomposition rate. Thus, the results obtained are not readily transferable to other landfill sites with different recovery conditions. Our objective is to present a general method for the estimation of the radius of influence of a landfill gas recovery well that at the same time accounts for the site geometry and considers the physical properties of waste, its age, and the rate at which landfill gas is generated in the 909
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
910
waste. For this purpose, we used numerical simulation to predict the radius of influence for typical recovery conditions (more details are provided by Vigneault, 1999). The results presented should assist landfill site managers in the design of suitable gas recovery systems (well spacing, imposed suction) for varying recovery conditions.
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
strongest landfill gas generation rate occurs in the first years following waste disposal. The landfill gas generation rate decreases steadily with time afterwards. TOUGH2-LGM also allows the use of a constant landfill gas generation rate. To simplify the computational efforts and allow a better understanding of the problem, a constant gas generation rate of 7.2 m3 t1 yr1 is used in the first set of simulations. This is equivalent to the gas generation rate of 5-yr-old waste in the Montreal landfill. For the second and third sets of simulations, different constant gas generation rates are used to study their effect on the radius of influence of recovery wells.
[1] t1),
where Gg is the gas generation rate (m Gi is the initial gas generation potential (m3 t1), c is the overall biodegradation coefficient for the combined types of waste found in landfill (yr1), and t is time (yr). In Eq. [1], the values used in the simulations for the initial generation rate Gi with a value of 9.5 m3 t1 and the coefficient c equal to 0.055 yr1 were computed using pumping data measured at the Montreal landfill site, Canada (Nastev, 1998). The exponential function defined with Eq. [1] is depicted in Fig. 1. It shows that the
where Sr is the residual water saturation, Sm is the maximum water saturation, and Sl is the current water saturation. Mualem (1976, modified by Parker 1989) proposed a relationship for the effective permeability kg (m2) of the gas (nonwetting) phase of the porous medium as a function of the effective water saturation Se using the van Genuchten capillary model parameter m:
1/m 2m kg k1 Se [1 Se ]
[4]
From Eq. [2], [3], and [4], we can plot Fig. 2, which shows the gas phase relative permeability and effective saturation against the thickness of the waste column above the water table. The steady-state effective saturaTable 1. Waste properties of the Montreal landfill.
Porosity Maximum saturation Residual saturation van Genuchten capillary parameters m n , m1 Saturated hydraulic conductivity, m s1 Absolute permeability, m2 Permeability anisotropy ratio (kv/kh) 0.5 1.0 0.03 0.11 1.12 5.0 6 105 6 1012 0.17
www.vadosezonejournal.org
911
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
tion profile was obtained for an imposed constant water infiltration rate of 400 mm yr1, based on the prevailing temperature and precipitation conditions in the Montreal region (Nastev, 1998). Under such relatively high liquid-phase saturation conditions, the gas-phase relative permeability is limited to a maximum value of about 0.45 (Fig. 2). The dashed part of the relative permeability curve shown in Fig. 2 cannot actually occur in the waste.
well by a factor of approximately 1.5. Thus, the horizontal length of the grid elements varies from 0.5 m at the recovery well to 30 m at the edge of the grid. The total thickness of the simulated waste column considered was 10, 20, 30, 40, and 50 m. As the total number of layers in the numerical grid remained constant at 20, the vertical thickness of the grid elements varied between 0.5 and 2.5 m depending on the overall thickness of waste column considered. The vertical boundary opposite the extraction well at the outer edge of the numerical grid is assumed to be a no-flow boundary. It actually represents the imaginary surface at the approximate mid-point between neighboring recovery wells installed in a regular grid where wells are equidistant from each other. Because a twodimensional radial model is used, this is a simplification of actual field conditions, where the volume influenced by a pumping well can depart from this simple cylindrical geometry. The boundary conditions applied to the upper model elements are assigned as a constant temperature, equivalent to the mean annual temperature for Montreal of 6.6C, constant atmospheric pressure of 100 kPa, and zero CH4 and CO2 concentrations. At the upper boundary, the model elements are in direct contact with atmospheric conditions, and gas emission to the atmosphere occurs there. The base of the model coincides with the water table in the waste, representing an impermeable barrier to gas phase migration. The temperature at the base was fixed arbitrarily to 20C. The constant infiltration rate from precipitation of 400 mm yr1 is simulated by 13 injection sources in the top row of elements. To allow faster convergence, an initial simulation was performed without any gas generation or pumping but with water infiltration occurring from the top elements. The model was run until a steady-state water saturation profile was obtained, the one presented in Fig. 2. This saturation distribution was used as the initial condition in the subsequent simulations.
RESULTS
Modeling was divided in three main simulation scenarios summarized in Table 2. The results obtained from
Fig. 3. Vertical two-dimensional radial conceptual model and grid elements for radial flow to a landfill gas recovery well.
912
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
Fig. 4. Recovery rate as a function of the horizontal length of the model (equivalent to one-half of the spacing between wells) for three suctions at the production well. The radius of influence of a well is defined as the radial distance for which 90% of the CH4 produced in the waste is recovered by the well (shown by arrows).
Fig. 5. Examples of CH4 concentration and gas flow direction for model lengths of 30 and 50 m (suction is 4.5 kPa and waste thickness is 20 m).
are lower for the model length of 30 m, implying higher CH4 recovery.
www.vadosezonejournal.org
913
fraction remains high for a longer time for model lengths 30 m. Thus, whenever higher energy values of the recovered landfill gas are required, it is necessary that the CH4 volumetric fraction and flow rate remain as high as possible. This is more readily achieved for thick waste accumulations.
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
to adjust the pumping rate to optimize the CH4 content in the gas recovered. The pumping rate, dependant on the suction imposed in the well, should be sufficiently high to recover most of the generated CH4 and, at the same time, sufficiently low to prevent the penetration of O2 from the surface. The presence of O2 in the waste reduces the anaerobic biodegradation processes taking place in the waste and CH4 generation. The last series of simulations was conducted to study the CH4 content in the recovered gas by comparing the fraction of the recovered CH4 and the CH4 mass flow (kg s1). The horizontal model length was varied in 10-m intervals from 10 to 110 m. Similarly to the previous simulations, three suctions were applied to the recovery well: 1.5, 3, and 4.5 kPa. Finally, two different waste column thicknesses were assumed, 20 and 40 m. Figures 7 and 8 show the results for a model thickness of 20 and 40 m, respectively. Both figures indicate increased CH4 volumetric fractions for increased horizontal model lengths. The CH4 volumetric fraction remains at nearly 50% (the same as the CH4 proportion in the gas generated in the waste) for a longer time period for the 40-m waste column thickness compared with what is observed for a 20-m thickness. As the generation of the landfill gas decreases with time in the waste, whatever the thickness of the site, the CH4 mass flow will also decrease gradually with time. Figures 7 and 8 also demonstrate that a higher suction in the recovery well results in a rapidly decreasing CH4 volumetric fraction in the gas produced by the recovery well. The graphs for a 40-m-thick waste column with an applied suction of 1.5 kPa show that the CH4 volumetric
The steps to be followed for the design of the landfill gas recovery system for the hypothetical landfill can be described as follows: Step 1: At this stage, the landfill gas generation constant c is determined. This can be done either with field experiments (EMCON Associates, 1980) or by using data reported in the literature. Equation [1] should then be used to represent the gas generation kinetics. For this example we used data reported for the Montreal landfill site (Nastev, 1998). The initial generation rate is Gp0 9.5 m3 t1 yr1, and the generation constant is c 0.055. The construction of the recovery wells is assumed to be made during the deposition of waste in each cell. The pumping rate is gradually increased as waste is buried in each cell and the well reaches its full pumping capacity after the cell closure, assumed at 5 yr after the beginning of waste disposal in each cell. It is now possible to determine the generation rate with the graph displayed in Fig. 1. For this example, the generation rate at 5 yr is Gp 7.2 m3 t1 yr1. Step 2: The generation of the landfill gas starts after waste disposal, immediately after the initial O2 content in the waste gas phase is completely depleted. Thus, it is important to start gas pumping in the early stage of waste disposal. Another point favoring early gas recovery is that the construction of a gas recovery well is less expensive when it is done during waste disposal. Imposing a low suction in the well is important during this period to avoid air intrusion in the waste, since there is no impermeable cover on top of the waste. Step 3: The number of recovery wells in a landfill site is a function of the suction applied in the recovery wells, the generation rate, and the surface occupied by landfilling. Figure 9 shows that the radius of influence of the recovery well is a function of the gas generation rate in the waste and of the suctions imposed in the well. These curves were extracted from Fig. 6. Using
914
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
Fig. 7. Volumetric fraction of CH4, CH4 mass flow rate, and total landfill gas flow rate in the well vs. the generation rate of landfill gas in the waste for three suctions applied to the recovery well and a 20-m waste thickness.
Fig. 9, it is possible to estimate the appropriate suction according to the number (distance) of the recovery wells. Figure 9 shows that for 5-yr-old waste the radius of influence is 35 m when the suction imposed is 4.5 kPa. For each cell, three pumping wells should then be sufficient to recover the gas generated by the waste disposed in each cell. The waste volume corresponding to each recovery well is approximately 77 000 m3. For the imposed suction of 3 kPa, the radius of influence is smaller, at 27 m, and it would take four recovery wells with a corresponding waste volume of 45 000 m3 for each cell. With these results, it is possible to determine the suction and the number of recovery wells required for each disposal cell. With time, the suction in the recovery wells can be changed to maintain the radius of influence around 30 m. In our example, the suction could be readjusted from 4.5 to 3 kPa after 10 yr (generation rate of 5.2 m3 t1 yr1). With such a lowered suction, there is an increase of the volumetric fraction of CH4, and a landfill gas of better quality is recovered. Step 4: As the gas generation decreases with time, the radius of influence increases and reaches 40 m after 30 yr (generation rate of 1.92 m3 t1 yr1). It is thus important to evaluate again the recovery system and to adjust the suction according to the age of the wastes in each cell. From an economic point of view, installing more recovery wells means higher initial costs for the gas recov-
ery system. However, if fewer recovery wells are to be installed, the suction imposed on each well has to be higher, which implies more energy to run the system and higher maintenance fees. Obviously, the design of the recovery system must be based on what is the most advantageous for the owner and for the environment. If the landfill gas recovered is to be used for energy production purposes, it is important to have a good quality gas with higher CH4 content. For such cases, the suction imposed in the recovery wells must be adjusted according to the age of the waste and to allow higher CH4 volumetric fraction and flow rate.
www.vadosezonejournal.org
915
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
Fig. 8. Volumetric fraction of CH4, CH4 mass flow rate, and total landfill gas flow rate in the well vs. the generation rate of landfill gas in the waste for three suctions applied to the recovery well and a 40-m waste thickness.
Depending on the thickness of the waste, the radius of influence evolved in different ways. Specifically, the radius of influence was almost constant for a waste column thickness of 10 m, whereas it became very large for a thickness of 50 m (Fig. 6). With higher imposed suction in the recovery well, the volumetric fraction of the recovered CH4 tends to decrease. This is due to air intrusions in the upper waste layers. Another point that affects the volumetric fraction of CH4 recovered is the distance
between recovery wells. This result is displayed in Fig. 7 and 8. The well suction or the number of wells must be adjusted with the evolution of the gas generation rate (Fig. 9). A systematic approach for the design of a landfill gas recovery system was proposed based on the numerical simulation results. The adequacy of the results still has to be validated with field measurements. In our opinion, the results presented are the first necessary step to help landfill managers and engineers in the design of a recovery system. From a scientific point of view, it would be interesting to study other simulation scenarios such as the influence of an impermeable cover installed on top of the waste. These scenarios would provide a more complete picture for the evolution of the radius of influence under postclosure conditions.
ACKNOWLEDGMENTS We thank Curt Oldenburg, an anonymous reviewer, and the special section editor Stefan Finsterle for their thorough reviews and constructive comments that helped improve the initial manuscript significantly. This work was supported in part by an operating grant from the Natural Science and Engineering Research Council of Canada to R. Lefebvre. We are also thankful to the personnel of the Montreal municipal land-
Fig. 9. Radius of influence for a recovery well for three imposed suctions and for a waste column thickness of 20 m (based on results of Fig. 6).
916
roux, for their help and collaborafill site, especially Martin He tion in the completion of this study.
REFERENCES
Blais, C. 1996. Characterization of hydraulic properties at the Montreal oressources, Canada. City CTED. (In French.), M.S. thesis. INRS-Ge EMCON Associates. 1980. Methane generation and recovery from landfill. Ann Arbor Science, Ann Arbor, MI. Farquhar, G.J., and F.A. Rovers. 1973. Gas generation during refuse decomposition. Water Air Soil Pollut. 2:483495. Findikakis, A.N., and J.O. Leckie. 1979. Numerical simulation of gas flow in sanitary landfill. J. Environ. Eng. Div. ASCE 105:927945. Lofy, R.J. 1983. Zones of vacuum influence surrounding gas extraction wells. p. 320454. In T.H. Christensen et al. (ed.) Landfilling of waste: Biogas (1996). Chapman and Hall, London. McBean, E.A. 1993. Landfill gas and leachate management. Course notes. University of Waterloo, Ontario, Canada. Mualem, Y. 1976. A new model for predicting the hydraulic conductivity of unsaturated porous media. Water Resour. Res. 12:513522. Nastev, M. 1998. Modeling landfill gas generation and migration in sanitary landfills and geological formations. Ph.D. diss. Laval University, Quebec, Canada. linas. 2000. NumeriNastev, M., R. Lefebvre, R. Therrien, and P.J. Ge tienne-des Gre `s cal modelling of landfill gas migration at the St-E landfill site. p. 6572. In Proceedings, 1st Joint AIH-CNC and CGS Groundwater Specialty Conference, Montreal, Canada. 1518 Oct. 2000. AIH-CNC and CGS, Alliston, ON, Canada. linas. 2003. NumeriNastev, M., R. Lefebvre, R. Therrien, and P.J. Ge
Reproduced from Vadose Zone Journal. Published by Soil Science Society of America. All copyrights reserved.
cal modeling of lateral landfill gas migration. J. Solid Waste Technol. Manage. 29:265276. linas. 2001. Landfill Nastev, M., R. Therrien, R. Lefebvre, and P.J. Ge gas generation and migration in landfills and geological materials. J. Contam. Hydrol. 52(14):187211. Parker, J.C. 1989. Multiphase flow and transport in porous media. Rev. Geophys. 27:311328. Pruess, K. 1991. TOUGH2A general-purpose numerical simulator for multiphase fluid and heat flow. Rep. LBL-29400. Earth Sciences Division, Lawrence Berkeley Natl. Lab., Berkeley, CA. Schroeder, P.R., A.C. Gibson, and M.D. Smolen. 1983. The hydraulic evaluation of landfill performance (HELP) model. 2. Documentation for Version 1. Municipal Environmental Research Laboratory, Cincinnati OH. Schroeder, P.R., R.L. Peyton, B.M. McEnroe, and J.W. Sjostrom. 1994. The hydraulic evaluation of landfill performancce (HELP) model. 3. Users guide for Version 3. Hazardous Waste Engineering Research Laboratory, Cincinnati, OH. Sowers, G.F. 1973. Settlement of waste disposal fills. p. 207210. In Proceedings of the Eighth International Conference on Soil Mechanics and Foundation Engineering, Moscow Russia, Vol. 2. USEPA. 1997. Method 2ELandfill gas production flow rate. Available at http://www.epa.gov/ttnemc01/methods/method2e.html (verified 30 June 2004). USEPA Office of Air Quality Planning and Standards, Research Triangle Park, NC. van Genuchten, M.Th. 1980. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. Soil Sci. Soc. Am. J. 44:892898. lisation nume rique du rayon dinfluence Vigneault, H. 1999. Mode dun puits de captage des biogaz dans un site denfouissement. oressources, Canada. M.S. thesis. INRS-Ge