106inter 1st Year Chemistry T

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CHEMISTRY - I (T/M)
PAPER - I
SECTION - A
Marks : 10 X 2 = 20
o
30 Cbardm3

NaHSo4 HuP2 O9

IUPAC
SECTION - B
6 X 4 = 24
rms

Cr(OH)3 + IO3 OH
I + Cro4-2
H2OCO N (CH3)3
NH3 SP3 HNH 109o28

N2 O2
SECTION - B
8 X 2 = 16
KMnO4
O2
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o
30 Cbardm3
P1 V1 = P2 V2
P1 = 1 bar
V1 = 500 dm3
V2 = 200 dm3
P2 = ?
1 X 500 = P2 X 200
P2 = 5/2 = 2.5 bar

NaHSo4 H4P2 O9
NaHSo4
1(1) + 1(1) + X + 4(-2) = 0
x=+6
H4P2 O9
4(1) + 2x+7(-2) = 0
4 +2 x-14 = 0
x = +5
H+, BF3, Sncl4
mgo mg3 N2

CO N2
2mg + O2
3mg + N2
2mgo
mg3N2
N2 O2
IUPAC
rms

rms
rms
rms4rms rms
4av
mp RT
M
av
RT
RT
rmsrms
M T R

n
av
n
n
rms rms n
RT
M
mp : av : rms
:
RT
RT
M
rms
T
RT
Rmsrms
M
M
Rmsrms
3Pv
M
Rmsrms

Cr(OH)3 + IO3 OH
3P
d
I + Cro4-2
Cr (OH )3 Cr 0 42
Cr (OH )3 H 2 O Cr 0 42
Cr (OH )3 H 2 O Cr 0 42 5 H
(0)
(0)
( 2)
( 5)
IO3 I
IO3 I 3H 2O
IO3 6 H I 3H 2O
(0) (6) (1)
1 6 1 0
(0)
5 x 1
X 1 5 6
6
Cr(OH)3 H2O 3C Cro42 5H IO3 6H I 3H2O

2 0.H.R 2Cr(OH)3 2H2O 6e 2Cro42 10H
IO3 6H 6e I 3H2O
2Cr(OH)3 IO3 2H2O 6H 2CrO42 I 3H2O 10H
2Cr(OH)3 IO3 2CrO42 I 10H 6H 3H2O 2H2O
2Cr(OH)3 IO3 2CrO42 I 4H H2O
4OH
Cr (OH )3 H 2O 3C Cro42 5 H IO3 6 H I 3H 2O

2 0.H .R 2Cr (OH )3 2 H 2O 6e 2Cro42 10 H
IO3 6 H 6e I 3H 2O
2Cr (OH )3 IO3 2 H 2O 6 H 2CrO42 I 3H 2O 10 H
2Cr (OH )3 IO3 2CrO42 I 10 H 6 H 3H 2O 2 H 2O
2Cr (OH )3 IO3 2CrO42 I 4 H H 2O
2Cr (OH )3 IO3 4OH 2CrO42 I 4 H 4OH H 2O
2Cr (OH )3 IO3 4OH 2CrO42 I 4 H 2O H 2O
2Cr (OH )3 IO3 4OH 2CrO42 I 5 H 2O
A
A A D, H Q
A B, H Q1
q = Q1 Q2 Q3
B C , H Q2
C D, H Q3
B
g1
g2
g3
Co2 C o2
Co2 H = - 393.5
Co2 Co H = - 110.5
Coo2Co2 H = - 283.02
H =
H

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for any inadvertent error that may have crept in the guess paper
responsible

N2 H22NH3

NH3

(2NH3N2 H2

N2 H2 2NH3

NH3

NH3 NH3

CNG

H2O
CO
N (CH3)3
H2O
B2 H6
B2 H6 + 6H2O 2H3 BO3 + 6H2
B2 H6 CO2
C
B2 H6 + 2CO
1000oC
2(BH3.Co)
N (CH3)3
B2 H6 + N (CH3)3
2BH3 (CH3)3
NH3 SP3HNH 109o28

any

may
have
crept
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inadvertent
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in
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paper

N2
O2

N2
O2
152 152 252 2 P2 2 P2
y
h = h
= mv
P
=
P =

X
P
X(P)
H
nr
n =1, 2, 3, 4....

Ao, nm, m, cm
Ao

Ao
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inadvertent
error that may
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for
have
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in
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guess paper

Ao

KMnO4
O2

H H
1 1
H C C H
KOH
H2C = CH2 + KBr + H2O
1 1
H Br
C C H
H2C = CH2 + 2nBr2
BrBr

Zn /H2O
CH 2 CH 2 O3
Zn + H2O
2CHCHO + H2O2
HOCL HOCL
H2C = CH2 + HDCL
CH2
- CH2
OH
CL

KMnO4
CH2 - CH2

H2C = CH2 + H2O + (O)
KMnO4
OH
OH

Chave
CO2for
any
error

crept
O2
guess paper
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notresponsible
inadvertent
that may
in
the
O

nCH2 = CH2
O2/200oC
(CH2
CH2)n

106inter 1st Year Chemistry T

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H+, BF3, Sncl4

Cr(OH)3 H2O 3C Cro42 5H IO3 6H I 3H2O

Cr (OH )3 H 2O 3C Cro42 5 H IO3 6 H I 3H 2O

NH3 SP3HNH 109o28

H2C = CH2 + KBr + H2O

H2C = CH2 + 2nBr2

H2C = CH2 + HDCL

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