Beruflich Dokumente
Kultur Dokumente
Intensity s s s m m m s s m s w w m w w w w w
Assignment CH stretch CH2 and CH3 bending modes =C-H stretch C=C stretch =CH out of plane =C-H stretch C=C stretch =CH out of plane =C-H stretch C=C stretch =CH out of plane C=C stretch " " " "
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(f) 8-ring
1653 3020
E- RCH=CHR
=C-H stretch C=C stretch =CH out of plane C=C stretch CH stretch CC stretch C-H bend C C stretch C-F stretch C-Cl stretch C-Br stretch C-I stretch OH stretch C-O stretch OH stretch C-O stretch OH stretch C-O stretch C=O stretch C=O stretch
2/5
R2C=CHR
1670 790-840
R2C=CR2
1670 3300
Alkynes
RC CH
2100-2140 600-700
2190-2260 1000-1350 750-850 500-680 200-500 3400-3600 1050 3400-3600 1100 3400-3600 1070-1150 1725 1685
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ArCHO All aldehydes Ketones R2CO (a) 4-ring (b) 5-ring (c) 6-ring C=CCOR ArCOR
1700 2720, 2820 (both) 1715 1780 1745 (doublet) 1715 1675 1690 3400
C=O stretch CHO out of plane C=O stretch " " " " " monomer OH monomer C=O dimer OH dimer C=O monomer OH monomer C=O dimer OH dimer C=O C-O stretch " C=O stretch " " " " NH stretch (free)
3/5
Carboxylic Acids
RCO2H
C=CCO2H
2800-3400 1690
s s s s s m
chemistry.umeche.maine.edu/CHY251/IR-Table.html
6/3/13
1690 Amides RCONH2 3400 1650 1600-1640 3440 1680 RCONHR 3330 1650 1530-1550 (a) 4-ring (b) 5-ring (c) 6-ring RCONR2 Anhydrides Acid Chloride RCO2COR RCOCl 1745 1700 1640 1650 1760, 1820 (both) 1800 3400, 3500 (both) Amines RNH2 1560-1640 1030-1230 R2NH 3310-3350 1030-1230 3450 1250-1360 730-770 690-710
s m s s m s m s m s " " m s s w s m w m w s m m
C=O stretch (free) NH str. (H-bond) C=O str. (H-bond) NH out of plane NH stretch (free) C=O stretch (free) NH str. (H-bond) C=O str. (H-bond) NH out of plane C=O stretch " " C=O stretch C=O stretch; symm., unsymm. C=O stretch NH stretch NH2 in plane bend C-N stretch NH stretch C-N stretch NH stretch Ar-N stretch CH out of plane bending
4/5
Ar2NH
Benzenes
monosubst.
chemistry.umeche.maine.edu/CHY251/IR-Table.html
6/3/13
735-770 750-810 690-710 810-840 760-780 705-745 810-865 675-730 805-825 870-885 800-810 855-870 840-850 870 References
m m m m m m m m m m m m m w
1,3,5-trisub.
"
1. Bellamy, L. J., "The Infrared Spectra of Complex Molecules", 2nd edition, John Wiley & Sons, New York, 1961. 2. Nakanishi, K. "Infrared Absorption spectroscopy - Practical", Holden-Day, Inc., San Francisco, 1962.
This page last modified 11:18 AM on Thursday October 1st, 2009. Webmaster, Department of Chemistry, University of Maine, Orono, ME 04469
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