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ICS 7
PART A 1. According to Lewis concept during the formation of chemical bond. (a)Decrease in the number of electron in the outermost orbit. (b) Attain electronic configuration of an inert gas. (c) Increase number of electron in the outermost orbit (d)attain 18 electron in the outermost orbit. 2. Which molecule is polar and posses zero dipole moment. (a)HCl (b)BF3 (c)NH3 (d)Cl2 3. The most covalent nature is present in (a)AlBr3 (b)AlF3 (c)AlI3 (d)AlCl3 4. For atom with atomic number 10 which statement is true? (a)Its molecules are monatomic (b)It form a covalent bond in solid state (c)It has high electron gain enthalpy with negative sign. (d)It has very low ionisation enthalpy. 5. In XeF6, XeF4, XeF2 the number of lone pair on Xe is respectively. (a)2,3,1 (b)1,3,2 (c)3,2,1 (d)1,2,3 6. The hydrogen bond is strongest in (a)O-H----S (b)O-H----H (c)F-H----F (d)O-H----O 7. Which of the following is paramagnetic with bond order 0.5? (a)F2 (b)H2+ (c)N2 (d)O28. Which of the following forces is of van-der Waals type? (a)Dispersion forces (b)Dipolar-dipolar forces (c)Dipolar induced dipolar forces (d)All of them 9. To what temperature the gas should be heated so as to make 20% increase in the volume at constant pressure and 273K temperature? (a)327K (b)320K (c)345K (d)377K 10. The density of a gaseous oxide having 0C temperature, 2 bar pressure becomes equal to that of N2 at that temperature and 5 bar pressure. What will be the molecular mass of this oxide? (a)84u (b)28u (c)70u (d)54u S. K. VAKHARIA INSTITUTE OF CHEMISTRY Page 1

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11. which gas will have maximum volume at STP for 1 gram weigh of it? (a)CO (b)H2O (c)CH4 (d)NO 12. What will be the total pressure if 8gram O2 and 4 gram H2 are filled in a vessel having 1 dm3 volume at temperature 300K (a)56 bar (b)44 bar (c)68 bar (d)38 bar 13. What will be the value of n of hydrocarbon having formula CnH2n-2 if the diffusion rates is 33 times that of hydrogen under similar condition of temperature and pressure? (a)1 (b)3 (c)4 (d)8 14. To increase the pressure of a gas by 10% at constant temperature the pressure (a)to be decrease by 10% (b) to be increase by 10% (c) to be decrease by 1% (d) to be increase by 1% 15. A system absorbs 230 joule heat from atmosphere and does the work equal to 150 joule then what will be the change in internal energy? (a)380 joule (b)80 joule (c)-80 joule (d)-380 joule 16. In all spontaneous reaction : (a)the entropy of universe decrease (b)the free energy of the system decrease (c)the free energy of system increases (d)the enthalpy of universe increases 17. what will be the value of free energy change when the value of cell potential of chemical cell is negative? (a)negative (b)positive (c)negative or positive (d)zero 18. what will be the change in entropy of the system when 9 gram of water is boiled at 373K temperature and converted to its vapour having the same temperature? heat of vapourisation of water is 2.26K joule gram-1? (a)54.53 joule Kelvin-1 (b) 2.26 joule Kelvin-1 (c) 0.54 joule Kelvin-1 (d) 6.05 joules Kelvin-1 19. For the reaction CO2(s) CO2(g), which of the following statement is correct? (a)H and S both are negative (b) H and S both are positive (c) H is positive and S is negative (d) H is negative and S is positive 20. if the value of fH for H2O2 and H2O are -188 and -286 kj mole-1 then H for the following reaction 2H2O2 2H2O + O2 (a)196 (b)-494 (c)146 (d)-98 S. K. VAKHARIA INSTITUTE OF CHEMISTRY Page 2

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21. the isothermal expansion of 5 litre gas at one bar pressure results into 15 litre gas at one bar what will be the work done during this ? (a)-1013.2 joule (b)1013.2 joule (c)506.6 joule (d)-506.6 joule 22. Kp for the reaction NH4HS NH3 + H2S (a)p/2 (b)p2/4 (c)p3/8 (d)p3/27 23. which of the following is not included in the requirement of chemical equilibrium? (a)chemical reaction should be reversible (b)chemical reaction should take place in close reaction (c)the factor like temperature, pressure and concentration should remain constant (d)all the properties of system which can be measured are not contant. 24. Kc = 9 for the forward reaction for H2 + I2 2HI then Kc = ? (a)9.0 (b)1/9 (c)4.5 (d)-9.0 25. What will be the pH of the solution having pH 4 when its concentration is made five times by the addition of water? (a)3.5 (b)4.5 (c)3.3 (d)4.7 26. what will be the pH of the mixture of CH3COOH + CH3COONa? (a)<7 (b)>7 (c)7 (d)none 27. which of the following substance is insoluble in water? (a)NaCl (b)HCl (c)NaOH (d)CdS 28. pH of 0.1 M HCl = (a)<1 (b)>1 (c)7 (d)1 29. which is the most stable oxidation state of thallium? (a)+3 (b)+2 (c)+1 (d)0 30. which of the following statement is correct for boron? (a)boron hydride is monomeric in nature (b)oxides of boron are basic (c)boron reacts with water (d)boron trihalide acts as dimeric molecule 31. which of the following elements form compound having maximum co-ordination number 4? (a)Pb (b)Si (c)Ge (d)C 32. what is the use of WC? (a)it is used for welding (b)it is used as refractory (c)it is used for making tools and dies for making can and coines. S. K. VAKHARIA INSTITUTE OF CHEMISTRY Page 3

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(d)it is used as shield against radioactive radiation 33. which of the following compound give silicones by condensation polymerisation? (a)dimethyl chloro silane (b)dimethyl silanol (c)trimethyl silanol (d)trimethyl chloro silane 34. which of the following compound converts alcohol in to gasoline by dehydration? (a)ZSM-5 (b)asbestos (c)silica (d)trimolyte 35. which kind of silicate is talc? (a)layer (b)three dimensional (c)chain (d)cyclic 36. which of the following has higher boiling point? (a)2,3-dimethyl butane (b)pentane (c)neopentane (d)isopentane 37. possible structural isomers of C4H8 are (a)4 (b)3 (c)5 (d)6 38. which substance can prepare alkene by elimination reaction? (a)Haloalkane (b)dihaloalkane (c)alcohol (d)all 39. number of alkyene isomers having molecular formula C5H8 are (a)2 (b)4 (c)3 (d)5 40. ratio of and bond in benzaldehyde is (a) 3:5 (b)2:7 (c)2:5 (d)5:7 41. chlorination of toluene in the presence of light and heat followed by treatment with aqueous Ca(OH)2 gives (a)m-chloro toluene (b)benzoic acid (c)o and p chloro benzoic acid (d)o-cresol 42. with which reagent ethyene gives sihaloethane in addition reaction? (a)NaBr (b)HBr (c)Br2 (d)MgBr2 43. which o0f the following is nondegradable pollutant? (a)glass (b)plastic (c)heavy metal (d)all 44. how many kilometre stratosphere is extended? (a)500 (b)800 (c)1500 (d)1800 45. what is pH of acid rain? (a)5.6 (b)7 (c)6.5 (d)4.5 46. what is the approximate proportion by volume of CO2 gas in the atmosphere? (a)3% (b)0.3% S. K. VAKHARIA INSTITUTE OF CHEMISTRY Page 4

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(c)0.03% (d)33% 47. how many molecules of CFC present in stratosphere posses the efficiency of deplting one lac molecule of ozone? (a)1 (b)2 (c)3 (d)4 48. which deseases is caused by depletion of ozone layer? (a)cancer of blood (b)cancer of lungs (c)cancer of skin (d)cancer of chest 49. the drinking water having more than how many ppm of sulphate proportion produce effect of diarrhoea and irritation in stomach? (a)50ppm (b)100ppm (c)200ppm (d)300ppm 50. which of the following is not a biofertilizer? (a)risobium (b)azobacter (c)algal (d)compost fertilizer PART B ANSWER IN SHORT: 1 2 3 4 5 6 7 8 2 MARKS EACH Mention main postulates of VSEPR theory. Explain kinetic energy and molecular speed. Explain with example the enthalpy of neutralization. Deduce the formula Kp = P2/4 for decomposition of solid NH4HS in closed vessel. How boric acid is prepared from colemanite? Give names, symbols, atomic numbers and electron configurations of carbon group elements. Give Conversion: 2-Chloropropane from propan-2-ol. Give Conversion: 3-Bromo benzoic acid from toluene. 3 MARKS EACH

ANSWER IN DETAIL: 9 10 11 12 13 14

Draw molecular orbital diagram of CO and explain bond order and magnetic property. State Grahams law and derive its mathematical form and state its importance. Will 90 gram of ice having temperature 237 K kept in a room having temperature 300 K melt on its own and give wate at 237 K? Why? The molar enthalpy of fusion of ice at 237 K temperature is 6.025 kilo joule mole-1. Ksp of CaF2 at 298 K temperature is 1.7x10-10. If a person drinks 2.5 litre of water saturated with this salt every day, how much CaF2 will enter in his body every day? (Molecular mass of CaCl2 = 78 mol-1. Explain different types of methods for preparation of benzene. Write a short note on green chemistry. 4 MARKS EACH

ESSAY TYPE ANSWER: 15 Write a short note on valence bond theory. 16 Explain importance of Hesss law. 17 Explain structure of SiO2 and its uses. 18 Explain peroxide effect by mechanism of free radical addition reaction.

S. K. VAKHARIA INSTITUTE OF CHEMISTRY

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