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Anhydrous sodium pyrophosphate

Solution at 85 above 75% of the food grade phosphoric acid neutralization reaction with soda ash in proportion, control and liquid to the density of 1.4 ~ 1.45;15 min and then boil, add caustic soda, make the solution Ph value of 8.9 ~ 9.0;Again gave away and liquid spray dryer spray drying, control the inlet temperature of 300 , the outlet temperature of 110 ~ 120 .Finally after drying of disodium hydrogen phosphate into polymerization in furnace, under 450 polymerization products.

Na2CO3 + H3PO4 - Na2HPO4 + H2O + our fleet and write 2 Na2HPO4 Na4P207 + H2O;Disodium hydrogen phosphate method will eat first disodium hydrogen phosphate (Na2HPO4? H2o) heating to 115 ~ 130 water of crystallization, off into anhydrous disodium hydrogen phosphate, and then the anhydrous disodium hydrogen phosphate to aggregate heating to 160 ~ 240 in the furnace melt polymerization, after cooling, crushing, consumption of anhydrous sodium pyrophosphate was finished.Its Na2HPO4?12 H2O [delta] - > Na2HPO4 + 12 h2o2na2hpo4 [delta] - > Na4P2O7 + H2O;

Dry two-step polymerization adding soda ash to neutralizer, melted under stirring, adding phosphoric acid neutralization reaction generation disodium hydrogen phosphate.Control the reaction end point Ph 8.2 ~ 8.6, shall Be not less than 40 when the concentration of the solution Be relative density (1.383).Decolorizing filtration.Disodium hydrogen phosphate solution concentration to 48 Be relative density (1.498).To the mechanism of smears into anhydrous disodium hydrogen phosphate slice.Disodium hydrogen phosphate chip to box-type polymerization in the furnace heating polymerization, control the material temperature is between 160 ~ 240 .Polymerization of sodium pyrophosphate completely after cooling, crushing, usually by 60 mesh, anhydrous sodium pyrophosphate was finished.

In two-step production technology of anhydrous sodium pyrophosphate, can change the disodium hydrogen phosphate drying equipment to spray drying tower, furnace, change the aggregation device to rotary polymerization is more suitable for large-scale continuous production.

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Its H3PO4 + Na2CO3 to write 2 na2hpo4 N2HPO4 + H2O + CO2 [delta] - > Na4P2O7 + H2O Dry aggregate one-step polymerization with high temperature gas from boiling access to the bottom of the furnace, through sieve plate into the furnace chamber of fixed material layer, material layer by dry after preliminary calcination of disodium hydrogen phosphate solid particle aggregation.Material in this further heat polymerization, generate sodium pyrophosphate finished products, continuously from the upper sieve plate discharging mouth eduction.

Heating gas to continue upward, through the furnace chamber fluidized bed.By preliminary drying of disodium hydrogen phosphate, and has not yet dry disodium hydrogen phosphate in the floating up and down, mixing, drying, polymerization process, anhydrous sodium pyrophosphate was finished.Exhaust gas entrainment some little grain of solid materials from the top and tail gas by cyclone separator, collect part of solid materials, return to the boiling layer.Its Na2HPO4?2 + 2 H2O [delta] - > Na2HPO4 h2o2na2hpo4 [delta] - > Na4P2O7 + H2O;