CARACTERIZACIN

FSICO-QUMICA DE
SISTEMAS
ORGNICO - ACUOSO
Y ACUOSO - ACUOSO
ANEXOS

Ana Mara Gayol Gonzlez

ndice
8

ANEXOS EN SOPORTE INFORMTICO ............................................................. 193

A

Tablas de Propiedad.

Curvas binodales.

Rectas de reparto.

Propiedades derivadas .

Tablas de parmetro de ajuste de ATPs con Tween 20.

Tablas de parmetro de ajuste de ATPs con Triton X-102.

Grficas.

Anexo A
Tablas
de
Propiedad

A.

A.

Tablas de Propiedad.

PROPIEDAD ............................................................................................................. 3

A 2 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

A. PROPIEDAD
Tabla A.1. Influencia de la composicin sobre los ndices de refraccin, las variaciones de
ndices de refraccin de la mezcla binaria x1 etanol (1) x2 agua (2) en el intervalo de
temperaturas (318.15- 288.15) K.
x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.00000
0.09156
0.19936
0.27951
0.37014
0.50426
0.60280
0.69912
0.80778
0.90075
1.00000

1.32985
1.34163
1.34940
1.35215
1.35372
1.35457
1.35436
1.35393
1.35300
1.35173
1.35031

1.33130
1.34432
1.35280
1.35602
1.35780
1.35872
1.35869
1.35825
1.35733
1.35616
1.35477

1.33250
1.34641
1.35602
1.35959
1.36127
1.36261
1.36267
1.36231
1.36171
1.36050
1.35915

1.33338
1.34818
1.35915
1.36302
1.36502
1.36665
1.36709
1.36691
1.36600
1.36505
1.36347

0.00000
0.00991
0.01547
0.01658
0.01630
0.01440
0.01218
0.00978
0.00662
0.00345
0.00000

0.00000
0.01086
0.01681
0.01815
0.01781
0.01558
0.01324
0.01054
0.00707
0.00372
0.00000

0.00000
0.01146
0.01819
0.01962
0.01888
0.01663
0.01406
0.01113
0.00763
0.00393
0.00000

0.00000
0.01204
0.01977
0.02123
0.02051
0.01810
0.01558
0.01251
0.00833
0.00458
0.00000

Tabla A.2. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad

del sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de
mezcla para x1 etanol (1) x2 agua (2) en el intervalo (318.15-288.15) K.
x1

VE

kgm

-3

cm mol

u
-1

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

990.21
969.24
954.86
918.36
893.85
869.64
840.39
822.41
807.17
791.78
779.82
773.95
768.48

0.00000
-0.25138
-0.45944
-0.81097
-0.93727
-0.99251
-0.97914
-0.89553
-0.76796
-0.54902
-0.29844
-0.13769
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481

991.24
970.36
956.29
920.28
895.85
871.77
842.57
824.60
809.38
793.98
781.99
776.11

0.00000
-0.24815
-0.45939
-0.81619
-0.94151
-0.99879
-0.98443
-0.90031
-0.77266
-0.55281
-0.30003
-0.13965

-1

ms
318.15 K
1536.6
1580.6
1588.3
1499.6
1422.9
1350.6
1270.5
1222.8
1183.2
1141.8
1109.1
1092.2
1075.9
315.65 K
1533.2
1581.3
1592.1
1506.6
1430.2
1358.5
1278.5
1231.1
1191.6
1150.5
1117.7
1100.8

TPa

-1

S
TPa

-1

424.3
408.8
409.5
474.4
540.2
615.3
718.5
792.0
861.3
942.4
1013.9
1053.3
1093.3

0.0
-49.2
-76.0
-83.3
-71.1
-56.6
-43.2
-35.6
-30.7
-22.3
-13.0
-5.2
0.0

426.4
408.7
408.0
470.9
535.9
609.6
711.2
783.3
851.3
930.7
1001.1
1039.9

0.0
-50.5
-78.2
-85.6
-73.0
-58.4
-44.4
-36.7
-31.5
-23.1
-13.4
-5.5

A 3 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.2. Continuacin

x1

VE

1.0000

kgm
770.62

cm mol
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

992.21
971.52
957.75
922.24
897.99
873.96
844.86
826.90
811.67
796.25
784.24
778.36
772.84

0.00000
-0.24637
-0.46032
-0.82233
-0.94955
-1.00573
-0.99260
-0.90727
-0.77879
-0.55697
-0.30280
-0.14164
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

996.19
975.76
962.21
927.17
903.02
879.08
849.97
832.02
816.78
801.35
789.28
783.37
777.84

0.00000
-0.24514
-0.45900
-0.82400
-0.95065
-1.00734
-0.99242
-0.90754
-0.77928
-0.55839
-0.30287
-0.14175
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

994.03
973.83
960.58
926.16
902.18
878.33
849.32
831.41
816.21
800.75
788.69
782.79
777.23

0.00000
-0.24533
-0.46262
-0.83696
-0.96502
-1.02166
-1.00607
-0.92035
-0.79073
-0.56533
-0.30720
-0.14476
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795

994.86
974.85
961.94
928.03
904.22

0.00000
-0.24354
-0.46411
-0.84346
-0.97302

A 4 | A. GAYOL

-3

-1

-1

ms
1084.3
313.15 K
1529.3
1581.4
1595.5
1513.2
1437.3
1365.8
1286.6
1239.3
1200.1
1158.9
1126.2
1109.1
1092.7
310.65 K
1525.0
1581.3
1598.8
1519.7
1444.3
1373.2
1294.4
1247.5
1208.5
1167.4
1134.6
1117.5
1101.0
308.15 K
1520.3
1581.0
1602.1
1526.5
1451.3
1380.7
1302.2
1255.7
1216.8
1175.9
1143.1
1125.9
1109.4
305.65 K
1515.1
1580.3
1605.0
1532.7
1458.1

-1

S
-1

TPa
1079.3

TPa
0.0

428.8
409.0
406.7
467.7
531.7
604.5
704.0
774.9
841.6
919.6
988.7
1027.1
1065.7

0.0
-51.9
-80.4
-88.1
-75.1
-60.1
-45.9
-37.8
-32.5
-23.6
-13.8
-5.6
0.0

431.5
409.4
405.6
464.7
527.8
599.4
697.4
766.8
832.1
908.8
976.7
1014.5
1052.6

0.0
-53.3
-82.8
-90.7
-77.3
-62.0
-47.3
-39.1
-33.7
-24.4
-14.2
-5.8
0.0

434.5
410.0
404.5
461.5
523.9
594.4
690.7
758.8
823.0
898.2
965.0
1002.1
1039.6

0.0
-55.0
-85.5
-93.7
-79.8
-64.1
-48.9
-40.4
-34.5
-25.0
-14.5
-6.0
0.0

437.9
410.7
403.6
458.7
520.1

0.0
-56.8
-88.3
-96.6
-82.4

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.2. Continuacin
x1

VE

-3

0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

kgm
880.46
851.52
833.61
818.42
802.97
790.87
784.97
779.40

cm mol
-1.02941
-1.01362
-0.92611
-0.79592
-0.57008
-0.30884
-0.14645
0.00000

-1

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

995.65
975.85
963.27
929.95
906.29
882.59
853.72
835.84
820.67
805.20
793.09
787.17
781.59

0.00000
-0.24201
-0.46546
-0.85135
-0.98146
-1.03698
-1.02040
-0.93227
-0.80190
-0.57349
-0.31164
-0.14798
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

996.37
976.78
964.53
931.81
908.31
884.69
855.89
838.02
822.86
807.38
795.27
789.33
783.73

0.00000
-0.24042
-0.46667
-0.85957
-0.99056
-1.04551
-1.02791
-0.93879
-0.80769
-0.57760
-0.31453
-0.14938
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481

997.04
977.63
965.78
933.68
910.32
886.79
858.05
840.20
825.06
809.58
797.44
791.50

0.00000
-0.23810
-0.46854
-0.86828
-0.99969
-1.05407
-1.03540
-0.94484
-0.81285
-0.58153
-0.31633
-0.15048

-1

ms
1388.0
1310.1
1263.8
1225.1
1184.4
1151.5
1134.4
1117.8
303.15 K
1509.5
1579.5
1608.0
1539.2
1465.1
1395.3
1317.9
1271.9
1233.5
1192.8
1160.0
1142.8
1126.2
300.65 K
1503.4
1578.2
1610.6
1545.5
1471.8
1402.5
1325.5
1280.0
1241.8
1201.3
1168.4
1151.2
1134.6
298.15 K
1496.9
1576.8
1613.3
1551.8
1478.5
1409.7
1333.2
1288.1
1250.1
1209.9
1176.8
1159.7

-1

S
-1

TPa
589.6
684.3
751.1
814.1
887.8
953.7
990.0
1026.9

TPa
-66.3
-50.6
-41.9
-35.6
-25.9
-14.8
-6.3
0.0

441.5
411.6
402.6
455.7
516.4
584.8
677.9
743.5
805.2
877.7
942.4
978.1
1014.4

0.0
-58.7
-91.3
-100.0
-85.2
-68.7
-52.5
-43.4
-36.8
-26.6
-15.2
-6.5
0.0

444.1
411.5
400.6
451.5
511.2
578.3
669.6
733.6
794.0
864.8
928.1
963.2
998.6

0.0
-60.6
-94.3
-103.1
-87.9
-71.0
-54.1
-44.8
-37.8
-27.3
-15.5
-6.7
0.0

449.8
414.0
401.2
450.3
509.4
575.8
665.9
728.9
788.4
858.0
920.7
955.2

0.0
-63.0
-98.1
-107.3
-91.4
-74.0
-56.4
-46.7
-39.2
-28.4
-15.9
-6.9

A 5 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.2. Continuacin

x1

VE

1.0000

kgm
785.89

cm mol
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

997.65
978.43
966.92
935.52
912.29
888.85
860.19
842.36
827.23
811.73
799.60
793.64
788.02

0.00000
-0.23592
-0.46899
-0.87745
-1.00862
-1.06258
-1.04265
-0.95108
-0.81782
-0.58440
-0.31827
-0.15169
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

998.20
979.19
968.06
937.33
914.27
890.93
862.31
844.53
829.39
813.89
801.75
795.79
790.15

0.00000
-0.23390
-0.47053
-0.88690
-1.01880
-1.07235
-1.05015
-0.95833
-0.82328
-0.58826
-0.32065
-0.15348
0.00000

0.0000
0.0503
0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

998.68
979.87
969.14
939.14
916.24
892.97
864.42
846.67
831.54
816.06
803.89
797.92
792.30

0.00000
-0.23155
-0.47205
-0.89688
-1.02900
-1.08142
-1.05720
-0.96431
-0.82748
-0.59144
-0.32092
-0.15292
0.00000

0.0000
0.0503

999.10
980.38

0.00000
-0.22674

A 6 | A. GAYOL

-3

-1

-1

ms
1143.1
295.65 K
1489.9
1575.2
1615.9
1558.2
1485.2
1416.8
1341.0
1296.3
1258.4
1218.5
1185.4
1168.3
1151.6
293.15 K
1482.5
1573.4
1618.6
1564.8
1492.2
1424.2
1348.8
1304.8
1267.0
1227.3
1194.1
1177.1
1160.3
290.65 K
1474.7
1571.6
1621.4
1571.4
1499.1
1431.6
1356.7
1315.3
1275.5
1236.8
1202.9
1185.8
1169.1
288.15 K
1466.4
1569.8

-1

S
-1

TPa
990.2

TPa
0.0

454.5
415.4
400.5
447.5
506.0
571.4
660.0
721.7
780.2
848.3
910.0
944.0
978.4

0.0
-65.5
-101.9
-111.4
-94.9
-77.0
-58.6
-48.6
-40.6
-29.4
-16.4
-7.2
0.0

459.5
416.7
399.7
444.7
502.4
566.9
654.1
714.2
771.8
838.4
899.3
932.6
966.5

0.0
-68.3
-106.2
-115.9
-98.8
-80.2
-61.1
-50.9
-42.1
-30.6
-16.9
-7.6
0.0

464.9
418.3
399.0
442.0
499.1
562.5
648.3
704.9
763.8
828.1
888.9
921.7
954.9

0.0
-71.2
-110.7
-120.6
-102.8
-83.7
-63.7
-55.4
-43.7
-32.5
-17.3
-7.7
0.0

470.7
419.8

0.0
-74.7

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.2. Continuacin
x1

VE

-3

0.0916
0.1994
0.2795
0.3701
0.5043
0.6028
0.6991
0.8078
0.9007
0.9481
1.0000

kgm
970.16
940.86
918.10
894.99
866.46
848.80
833.63
818.20
805.97
800.00
794.44

u
-1

cm mol
-0.47316
-0.90559
-1.03710
-1.09049
-1.06229
-0.97061
-0.82887
-0.59409
-0.31813
-0.14926
0.00000

-1

ms
1624.2
1578.0
1506.0
1439.2
1364.7
1324.7
1284.0
1246.0
1211.5
1194.4
1178.2

-1

-1

TPa
398.3
439.2
495.6
558.0
642.4
696.8
755.7
818.2
878.7
910.9
942.9

TPa
-115.6
-125.6
-107.0
-87.5
-66.4
-58.5
-45.1
-33.9
-17.3
-7.5
0.0

Tabla A.3. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria x1 etanol (1) x2 n-hexano (2) en el intervalo de temperaturas
(318.15- 288.15) K.

x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

0.0000
0.0992
0.2014
0.3030
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

1.36045
1.35918
1.35810
1.35721
1.35632
1.35546
1.35450
1.35344
1.35248
1.35146
1.35070

1.36650
1.36526
1.36413
1.36313
1.36218
1.36120
1.36001
1.35872
1.35746
1.35614
1.35502

1.37227
1.37095
1.36981
1.36874
1.36774
1.36654
1.36522
1.36367
1.36229
1.36074
1.35926

1.37757
1.37659
1.37555
1.37441
1.37330
1.37195
1.37037
1.36863
1.36706
1.36535
1.36332

0.00000
-0.00030
-0.00039
-0.00029
-0.00021
-0.00011
-0.00009
-0.00011
-0.00018
-0.00023
0.00000

308.15

298.15

288.15

0.00000 0.00000 0.00000

-0.00010 -0.00003 0.00043
-0.00006 0.00016 0.00085
0.00011 0.00041 0.00116
0.00030 0.00071 0.00147
0.00044 0.00078 0.00151
0.00041 0.00077 0.00137
0.00034 0.00061 0.00114
0.00013 0.00041 0.00087
-0.00004 0.00016 0.00059
0.00000 0.00000 0.00000

Tabla A.4. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de mezcla
para x1 etanol (1) x2 n-hexano (2) en el intervalo de temperaturas (318.15- 288.15) K.
x1

kgm
0.0000
0.0992
0.2014
0.2966
0.4025
0.5004

VE

-3

636.28
640.60
646.91
654.07
663.02
673.26

cm mol
0.000
0.363
0.493
0.519
0.574
0.525

u
-1

-1

ms
318.15 K
979.3
978.6
976.3
979.5
980.1
984.9

TPa

-1

1638.6
1630.0
1621.7
1593.6
1570.2
1531.3

S
TPa

-1

0.0
42.4
86.7
107.5
138.7
150.1

A 7 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.4. Continuacin

x1

VE

-3

0.6012
0.7077
0.7988
0.8986
1.0000

kgm
685.65
701.05
717.31
739.44
768.48

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

638.55
642.95
649.29
656.45
665.40
675.63
687.98
703.34
719.57
741.63
770.63

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

640.90
645.37
651.74
658.87
667.84
678.07
690.40
705.72
721.91
743.92
772.85

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

643.23
647.77
654.16
661.30
670.27
680.48
692.79
708.08
724.21
746.17
775.05

0.0000
0.0992

645.55
650.14

A 8 | A. GAYOL

cm mol
0.466
0.423
0.337
0.200
0.000

u
-1

-1

ms
992.6
1004.0
1018.2
1040.6
1075.9
315.65 K
0.000
990.4
0.346
990.0
0.467
987.7
0.496
990.0
0.552
991.0
0.505
995.6
0.451
1003.0
0.413
1014.1
0.330
1027.9
0.199
1049.6
0.000
1084.3
313.15 K
0.000
1001.7
0.329
1001.1
0.446
998.8
0.480
1001.7
0.531
1002.0
0.487
1006.2
0.435
1013.5
0.403
1024.0
0.323
1037.4
0.195
1058.6
0.000
1092.7
310.65 K
0.000
1013.2
0.312
1012.3
0.426
1010.0
0.458
1013.4
0.511
1012.9
0.470
1016.9
0.423
1023.8
0.393
1034.0
0.318
1046.9
0.194
1067.5
0.000
1101.0
308.15 K
0.000
1024.6
0.299
1023.5

-1

S
-1

TPa
1480.3
1415.1
1344.7
1249.0
1124.1

TPa
151.0
140.6
117.0
72.7
0.0

1596.6
1587.0
1578.8
1554.3
1530.2
1493.2
1444.7
1382.6
1315.4
1224.0
1103.6

0.0
39.3
81.5
103.9
132.0
143.3
144.5
134.9
112.5
70.4
0.0

1555.0
1546.0
1538.0
1512.6
1491.5
1456.5
1410.1
1351.3
1287.2
1199.6
1083.7

0.0
37.8
77.9
97.4
126.2
137.3
138.4
129.8
108.6
68.1
0.0

1514.4
1506.5
1498.6
1472.4
1454.2
1421.2
1377.1
1320.9
1260.0
1176.0
1064.4

0.0
36.7
74.8
91.5
120.9
132.0
133.3
125.0
105.0
66.0
0.0

1475.7
1468.4

0.0
35.4

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.4. Continuacin
x1

VE

-3

0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

kgm
656.57
663.73
672.67
682.86
695.17
710.41
726.52
748.42
777.24

cm mol
0.405
0.435
0.493
0.454
0.408
0.383
0.311
0.191
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

647.83
652.48
658.93
666.08
675.04
685.22
697.50
712.73
728.78
750.64
779.40

0.000
0.286
0.388
0.419
0.474
0.439
0.396
0.373
0.306
0.188
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

650.15
654.85
661.32
668.48
677.42
687.58
699.85
715.06
731.07
752.88
781.59

0.000
0.275
0.372
0.402
0.461
0.427
0.387
0.365
0.301
0.187
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

652.42
657.16
663.66
670.84
679.76
689.90
702.15
717.33
733.32
755.07
783.73

0.000
0.264
0.355
0.384
0.445
0.414
0.376
0.357
0.295
0.184
0.000

u
-1

-1

ms
1021.2
1025.1
1023.8
1027.7
1034.3
1044.0
1056.5
1076.6
1109.4
305.65 K
1035.7
1034.6
1032.4
1035.5
1034.8
1038.4
1044.6
1054.0
1066.0
1085.6
1117.8
303.15 K
1047.1
1046.0
1043.7
1046.6
1045.8
1049.1
1055.1
1064.0
1075.6
1094.6
1126.2
300.65 K
1058.4
1057.5
1054.9
1057.3
1056.7
1059.8
1065.5
1074.0
1085.2
1103.6
1134.6

-1

S
-1

TPa
1460.4
1433.7
1418.2
1386.7
1344.7
1291.6
1233.2
1152.8
1045.4

TPa
71.4
85.7
115.7
126.3
127.8
120.5
101.3
63.8
0.0

1439.0
1431.8
1423.8
1400.1
1383.4
1353.5
1313.8
1263.0
1207.5
1130.4
1026.9

0.0
33.7
67.8
83.3
110.3
120.7
122.5
115.7
97.6
61.7
0.0

1402.9
1395.6
1388.2
1365.7
1349.8
1321.5
1283.7
1235.2
1182.3
1108.5
1008.7

0.0
31.8
64.8
79.7
105.6
115.9
117.8
111.3
94.2
59.9
0.0

1368.3
1360.7
1354.0
1333.4
1317.5
1290.5
1254.6
1208.6
1158.0
1087.3
991.1

0.0
29.8
61.7
77.0
101.1
110.9
113.1
107.2
90.9
58.0
0.0

A 9 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.4. Continuacin

x1

VE

kgm

-3

cm mol

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

654.70
659.48
666.01
673.19
682.11
692.23
704.46
719.61
735.57
757.28
785.89

0.000
0.254
0.341
0.368
0.430
0.403
0.367
0.350
0.291
0.183
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

656.96
661.78
668.32
675.52
684.40
694.53
706.74
721.87
737.78
759.46
788.03

0.000
0.245
0.328
0.352
0.419
0.392
0.358
0.344
0.288
0.181
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

659.21
664.08
670.63
677.83
686.71
696.83
709.01
724.12
740.02
761.64
790.16

0.000
0.234
0.315
0.340
0.407
0.381
0.351
0.337
0.282
0.180
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012

661.45
666.36
672.93
680.13
689.01
699.13
711.27

0.000
0.226
0.303
0.328
0.396
0.370
0.344

A 10 | A. GAYOL

u
-1

-1

ms
298.15 K
1069.8
1069.1
1066.2
1068.1
1067.7
1070.5
1075.9
1084.0
1094.8
1112.8
1143.1
295.65 K
1081.4
1080.7
1077.5
1079.0
1078.8
1081.4
1086.5
1094.1
1104.5
1121.9
1151.6
293.15 K
1093.1
1092.2
1089.0
1090.2
1090.0
1092.3
1097.1
1104.4
1114.5
1131.2
1160.3
290.65 K
1106.0
1103.8
1100.5
1101.2
1101.2
1103.2
1107.7

TPa

-1

S
TPa

-1

1334.5
1326.7
1320.9
1302.1
1286.0
1260.5
1226.2
1182.6
1134.2
1066.5
973.8

0.0
28.0
59.1
74.5
96.7
106.5
108.6
103.4
87.8
56.1
0.0

1301.7
1293.9
1288.8
1271.4
1255.6
1231.3
1198.7
1157.2
1111.1
1046.1
956.8

0.0
26.5
56.6
72.0
92.7
102.2
104.4
99.6
84.9
54.4
0.0

1269.7
1262.3
1257.4
1241.2
1225.7
1202.8
1171.8
1132.2
1087.9
1026.0
940.0

0.0
25.4
54.1
69.3
88.8
98.2
100.3
95.8
81.5
52.6
0.0

1235.9
1231.7
1227.0
1212.5
1196.9
1175.2
1145.8

0.0
26.8
54.1
69.3
86.8
95.6
97.8

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.4. Continuacin
x1

VE

-3

0.7077
0.7988
0.8986
1.0000

kgm
726.36
742.22
763.81
792.31

cm mol
0.333
0.281
0.180
0.000

0.0000
0.0992
0.2014
0.2966
0.4025
0.5004
0.6012
0.7077
0.7988
0.8986
1.0000

663.64
668.63
675.17
682.36
691.24
701.40
713.46
728.54
744.36
765.91
794.44

0.000
0.210
0.293
0.319
0.387
0.356
0.342
0.331
0.283
0.183
0.000

u
-1

-1

ms
1114.7
1124.3
1140.6
1169.1
288.15 K
1118.3
1115.3
1111.9
1112.2
1112.4
1114.4
1118.4
1124.9
1134.0
1149.9
1178.2

-1

-1

TPa
1107.9
1065.9
1006.4
923.4

TPa
93.2
79.7
51.3
0.0

1205.0
1202.3
1197.9
1184.7
1169.2
1147.9
1120.5
1084.7
1044.7
987.4
906.8

0.0
26.9
53.0
68.1
84.2
92.2
94.8
90.7
78.0
50.4
0.0

Tabla A.5. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria x1 etanol (1) x2 n-heptano (2) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.0000
0.0831
0.1688
0.2504
0.3543
0.4544
0.5585
0.6611
0.7610
0.8862
1.0000

1.37410
1.37273
1.37101
1.36957
1.36773
1.36563
1.36312
1.36050
1.35771
1.35391
1.35070

1.37952
1.37815
1.37639
1.37498
1.37313
1.37102
1.36850
1.36585
1.36298
1.35875
1.35502

1.38491
1.38355
1.38197
1.38043
1.37849
1.37639
1.37375
1.37093
1.36782
1.36342
1.35926

1.39027
1.38861
1.38704
1.38566
1.38359
1.38127
1.37851
1.37557
1.37249
1.36808
1.36332

0.00000
0.00057
0.00086
0.00133
0.00192
0.00216
0.00209
0.00187
0.00142
0.00055
0.00000

0.00000
0.00067
0.00101
0.00159
0.00229
0.00263
0.00266
0.00253
0.00211
0.00094
0.00000

0.00000
0.00077
0.00139
0.00194
0.00267
0.00314
0.00317
0.00298
0.00243
0.00124
0.00000

0.00000
0.00058
0.00132
0.00214
0.00287
0.00325
0.00329
0.00312
0.00273
0.00169
0.00000

A 11 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.6. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de mezcla
para x1 etanol (1) x2 n-heptano (2) en el intervalo (318.15-288.15) K.
x1

VE

kgm

-3

cm mol

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

662.43
665.24
669.46
677.28
692.42
705.78
716.95
737.16
746.02
753.99
768.48

0.000
0.395
0.513
0.600
0.599
0.505
0.466
0.336
0.252
0.178
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

664.55
667.42
671.66
679.52
694.68
708.02
719.17
739.34
748.19
756.15
770.63

0.000
0.379
0.494
0.576
0.578
0.489
0.454
0.331
0.249
0.177
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

666.72
669.69
673.94
681.83
696.99
710.34
721.46
741.61
750.45
758.38
772.85

0.000
0.357
0.470
0.550
0.558
0.471
0.442
0.323
0.244
0.174
0.000

0.0000
0.1040

668.89
671.92

0.000
0.343

A 12 | A. GAYOL

u
-1

-1

ms
318.15 K
1043.0
1036.2
1032.0
1027.7
1028.7
1032.3
1036.7
1048.9
1056.3
1062.7
1075.9
315.65 K
1053.8
1046.6
1042.9
1038.3
1038.9
1042.2
1046.5
1058.0
1065.0
1071.4
1084.3
313.15 K
1064.3
1057.0
1052.8
1048.9
1048.8
1052.0
1056.1
1067.1
1073.8
1080.0
1092.7
310.65 K
1075.0
1067.4

TPa

-1

S
TPa

-1

1387.8
1399.9
1402.6
1398.0
1364.9
1329.6
1297.7
1233.1
1201.4
1174.3
1124.1

0.0
39.6
67.8
100.9
120.6
118.5
109.5
76.3
55.4
37.0
0.0

1355.1
1367.9
1369.0
1365.0
1333.7
1300.3
1269.6
1208.4
1178.4
1152.1
1103.7

0.0
38.9
64.4
96.3
115.4
113.7
104.8
73.6
53.8
35.9
0.0

1324.3
1336.5
1338.7
1333.2
1304.3
1271.9
1242.8
1184.3
1155.7
1130.4
1083.7

0.0
37.3
62.8
91.7
111.0
108.9
100.6
70.8
52.1
34.8
0.0

1293.6
1306.1

0.0
36.4

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.6. Continuacin.
x1

VE

-3

0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

kgm
676.22
684.12
699.28
712.63
723.76
743.86
752.67
760.62
775.05

cm mol
0.448
0.528
0.540
0.456
0.428
0.316
0.241
0.171
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

671.03
674.13
678.48
686.40
701.56
714.90
726.02
746.08
754.88
762.82
777.24

0.000
0.328
0.424
0.504
0.521
0.442
0.417
0.311
0.238
0.169
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

673.16
676.33
680.70
688.64
703.81
717.13
728.25
748.29
757.06
764.99
779.40

0.000
0.312
0.404
0.483
0.502
0.430
0.406
0.305
0.234
0.167
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

675.32
678.54
682.96
690.90
706.06
719.40
730.49
750.52
759.27
767.20
781.59

0.000
0.300
0.385
0.463
0.488
0.416
0.397
0.299
0.231
0.164
0.000

u
-1

-1

ms
1063.8
1059.4
1059.0
1061.9
1065.7
1076.1
1082.4
1088.7
1101.0
308.15 K
1085.6
1077.9
1074.5
1070.1
1069.4
1071.8
1075.3
1085.2
1091.2
1097.3
1109.4
305.65 K
1096.3
1088.5
1084.9
1080.6
1079.7
1081.6
1085.0
1094.3
1100.0
1106.0
1117.8
303.15 K
1107.0
1099.1
1095.4
1091.3
1090.0
1091.6
1094.6
1103.4
1108.8
1114.8
1126.2

-1

S
-1

TPa
1306.7
1302.4
1275.1
1244.4
1216.7
1160.9
1134.0
1109.2
1064.4

TPa
59.2
87.6
106.2
104.4
96.6
68.2
50.7
33.4
0.0

1264.4
1276.7
1276.7
1272.3
1246.5
1217.8
1191.1
1138.1
1112.6
1088.7
1045.4

0.0
35.1
56.2
83.1
101.3
100.2
92.5
65.7
49.1
32.4
0.0

1236.1
1247.9
1248.2
1243.5
1218.8
1191.9
1166.5
1115.9
1091.7
1068.5
1026.9

0.0
33.6
54.2
79.4
96.6
96.1
88.8
63.2
47.5
31.3
0.0

1208.4
1220.0
1220.3
1215.4
1192.1
1166.6
1142.5
1094.4
1071.2
1048.8
1008.8

0.0
32.4
52.1
75.6
92.4
92.0
85.2
61.0
46.0
30.0
0.0

A 13 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.6. Continuacin.

x1

VE

kgm

-3

cm mol

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

677.44
680.72
685.16
693.12
708.28
721.62
732.71
752.70
761.44
769.36
783.73

0.000
0.287
0.367
0.445
0.473
0.404
0.386
0.294
0.228
0.162
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

679.57
682.90
687.38
695.36
710.51
723.85
734.92
754.90
763.62
771.54
785.89

0.000
0.275
0.349
0.427
0.459
0.392
0.378
0.289
0.225
0.160
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

681.68
685.06
689.56
697.56
712.73
726.05
737.11
757.07
765.77
773.70
788.03

0.000
0.263
0.335
0.410
0.445
0.381
0.370
0.285
0.223
0.157
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569

683.78
687.22
691.75
699.77
714.92
728.25
739.30

0.000
0.252
0.319
0.393
0.432
0.371
0.361

A 14 | A. GAYOL

u
-1

-1

ms
300.65 K
1117.6
1109.6
1105.9
1101.8
1100.3
1101.5
1104.2
1112.4
1117.7
1123.5
1134.6
298.15 K
1128.4
1120.3
1116.6
1112.6
1110.6
1111.4
1113.8
1121.5
1126.6
1132.2
1143.1
295.65 K
1139.2
1131.1
1127.1
1123.3
1121.0
1121.4
1123.6
1130.7
1135.6
1141.1
1151.6
293.15 K
1150.2
1142.1
1138.1
1134.2
1131.5
1131.6
1133.5

TPa

-1

S
TPa

-1

1181.7
1193.1
1193.3
1188.4
1166.2
1142.2
1119.3
1073.6
1051.2
1029.7
991.2

0.0
31.2
49.9
72.1
88.2
88.1
81.8
58.9
44.3
29.0
0.0

1155.7
1166.7
1166.8
1161.8
1141.0
1118.5
1096.8
1053.2
1031.7
1011.0
973.8

0.0
30.0
47.7
68.7
84.3
84.7
78.8
56.9
42.9
28.2
0.0

1130.4
1140.9
1141.5
1136.2
1116.5
1095.2
1074.6
1033.2
1012.5
992.6
956.9

0.0
28.5
46.0
65.4
80.6
81.1
75.5
54.9
41.3
27.1
0.0

1105.5
1115.5
1116.0
1110.8
1092.6
1072.3
1052.7

0.0
27.2
43.7
62.2
77.1
77.7
72.5

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.6. Continuacin.
x1

VE

-3

0.8763
0.9172
0.9501
1.0000

kgm
759.23
767.92
775.85
790.16

cm mol
0.280
0.220
0.155
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

685.89
689.37
693.92
701.94
717.11
730.44
741.48
761.38
770.07
777.99
792.31

0.000
0.243
0.306
0.382
0.421
0.363
0.355
0.278
0.219
0.155
0.000

0.0000
0.1040
0.2010
0.3438
0.5444
0.6702
0.7569
0.8763
0.9172
0.9501
1.0000

687.95
691.46
696.04
704.08
719.24
732.56
743.60
763.49
772.15
780.06
794.44

0.000
0.235
0.295
0.368
0.413
0.357
0.352
0.277
0.221
0.158
0.000

u
-1

-1

ms
1140.0
1144.8
1150.0
1160.3
290.65 K
1161.3
1153.3
1149.3
1145.1
1142.0
1141.9
1143.4
1149.3
1153.8
1158.7
1169.1
288.15 K
1172.3
1164.4
1160.2
1156.2
1152.7
1152.1
1153.3
1158.7
1162.6
1167.2
1178.2

-1

-1

TPa
1013.5
993.7
974.6
940.0

TPa
53.0
40.0
26.3
0.0

1081.2
1090.5
1091.0
1086.4
1069.2
1049.9
1031.5
994.3
975.4
957.4
923.4

0.0
25.8
41.5
59.5
73.9
74.5
69.8
51.3
38.9
26.1
0.0

1057.7
1066.7
1067.3
1062.5
1046.4
1028.5
1011.1
975.5
958.2
941.0
906.8

0.0
24.7
40.0
56.6
70.9
71.9
67.6
50.1
38.9
26.7
0.0

Tabla A.7. Influencia de la composicin sobre los ndices de refraccin, las variaciones del ndice
de refraccin de la mezcla binaria x1 etanol (1) x2 n-octano (2) en el intervalo de temperaturas
(318.15- 288.15 K)
x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.0000
0.0845
0.1956
0.3047
0.4132
0.5109
0.6219
0.7121
0.8100
0.9039
1.0000

1.38455
1.38302
1.38156
1.37913
1.37672
1.37405
1.37104
1.36758
1.36270
1.35745
1.35070

1.38974
1.38889
1.38727
1.38480
1.38213
1.37932
1.37629
1.37267
1.36766
1.36224
1.35502

1.39509
1.39397
1.39240
1.38973
1.38711
1.38454
1.38115
1.37758
1.37246
1.36691
1.35926

1.40033
1.39910
1.39750
1.39476
1.39193
1.38931
1.38610
1.38212
1.37691
1.37153
1.36332

0.00000
0.00133
0.00363
0.00489
0.00616
0.00679
0.00754
0.00713
0.00557
0.00350
0.00000

0.00000
0.00208
0.00432
0.00564
0.00674
0.00732
0.00814
0.00765
0.00604
0.00388
0.00000

0.00000
0.00191
0.00432
0.00556
0.00682
0.00776
0.00834
0.00800
0.00639
0.00421
0.00000

0.00000
0.00190
0.00441
0.00571
0.00689
0.00789
0.00879
0.00814
0.00656
0.00465
0.00000

A 15 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.8. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de mezcla
para x1 etanol (1) x2 n-octano (2) en el intervalo de temperaturas (318.15- 288.15) K.
x1

VE

kgm

-3

cm mol

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

682.48
684.15
687.66
690.81
695.48
701.21
708.40
717.56
730.47
745.57
768.48

0.000
0.376
0.534
0.607
0.632
0.635
0.599
0.535
0.409
0.241
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

684.46
686.20
689.75
692.93
.697.62
703.36
710.55
719.73
732.64
747.74
770.63

0.000
0.359
0.510
0.581
0.607
0.611
0.579
0.518
0.397
0.235
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

686.53
688.36
691.93
695.13
699.82
705.60
712.80
721.99
734.88
749.98
772.85

0.000
0.338
0.489
0.556
0.586
0.588
0.558
0.500
0.386
0.228
0.000

0.0000
0.1008
0.2161
0.2997

688.57
690.49
694.09
697.31

0.000
0.321
0.464
0.530

A 16 | A. GAYOL

u
-1

-1

ms
318.15 K
1085.4
1075.2
1071.9
1066.9
1065.2
1061.4
1059.4
1059.7
1060.5
1064.3
1075.9
315.65 K
1095.8
1085.6
1082.2
1077.3
1075.4
1071.6
1069.5
1069.0
1070.1
1073.5
1084.3
313.15 K
1106.2
1095.9
1092.4
1087.6
1085.6
1081.7
1079.4
1078.4
1079.6
1082.5
1092.7
310.65 K
1116.5
1105.9
1102.6
1098.0

TPa

-1

S
TPa

-1

1243.7
1264.4
1265.6
1271.7
1267.3
1266.0
1257.7
1241.1
1217.3
1184.0
1124.1

0.0
32.7
47.7
63.8
71.3
82.0
85.7
81.2
70.2
47.9
0.0

1216.6
1236.5
1237.9
1243.4
1239.6
1238.1
1230.5
1215.9
1192.0
1160.5
1103.7

0.0
31.3
45.7
60.6
68.1
77.9
81.6
78.4
66.6
45.5
0.0

1190.3
1209.6
1211.1
1216.2
1212.6
1211.2
1204.0
1191.1
1167.6
1137.8
1083.7

0.0
30.1
43.8
57.9
64.8
74.1
77.7
75.5
63.4
43.5
0.0

1164.9
1184.1
1185.0
1189.5

0.0
29.3
41.8
54.7

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.8. Continuacin.
x1

VE

-3

0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

kgm
702.02
707.80
715.01
724.23
737.11
752.21
775.05

cm mol
0.561
0.566
0.539
0.482
0.374
0.221
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

690.61
692.59
696.24
699.47
704.20
709.99
717.22
726.44
739.32
754.41
777.24

0.000
0.304
0.441
0.508
0.538
0.545
0.518
0.466
0.364
0.215
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

692.62
694.69
698.36
701.60
706.34
712.14
719.41
728.63
741.50
756.59
779.40

0.000
0.286
0.421
0.487
0.517
0.526
0.498
0.451
0.354
0.210
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

694.67
696.80
700.51
703.77
708.51
714.33
721.61
730.84
743.69
758.79
781.59

0.000
0.270
0.399
0.464
0.497
0.507
0.482
0.436
0.346
0.205
0.000

0.0000
0.1008

696.68
698.89

0.000
0.253

u
-1

-1

ms
1095.7
1091.8
1089.4
1087.6
1089.0
1091.6
1101.0
308.15 K
1126.9
1116.2
1113.0
1108.4
1106.0
1102.0
1099.4
1097.0
1098.5
1100.7
1109.4
305.65 K
1137.2
1126.6
1123.2
1118.8
1116.1
1112.2
1109.5
1106.4
1108.0
1109.7
1117.8
303.15 K
1147.5
1137.0
1133.5
1129.3
1126.3
1122.4
1119.5
1115.8
1117.4
1118.8
1126.2
300.65 K
1157.8
1147.4

-1

S
-1

TPa
1186.5
1185.2
1178.5
1167.3
1143.9
1115.7
1064.4

TPa
61.7
70.5
73.9
72.8
60.3
41.3
0.0

1140.2
1158.8
1159.4
1163.8
1160.9
1159.8
1153.6
1143.9
1120.9
1094.2
1045.4

0.0
28.2
39.6
52.0
58.6
67.0
70.3
70.2
57.3
39.3
0.0

1116.4
1134.2
1135.0
1138.8
1136.5
1135.2
1129.2
1121.1
1098.6
1073.3
1026.9

0.0
26.9
37.9
49.2
55.9
63.6
66.5
67.5
54.5
37.4
0.0

1093.2
1110.1
1111.0
1114.2
1112.6
1111.3
1105.8
1099.1
1076.9
1052.9
1008.8

0.0
25.4
36.0
46.3
53.1
60.2
63.2
65.1
51.9
35.7
0.0

1070.8
1086.8

0.0
24.0

A 17 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.8. Continuacin.

x1

VE

-3

0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

kgm
702.62
705.88
710.64
716.47
723.77
733.00
745.86
760.95
783.73

cm mol
0.380
0.446
0.478
0.489
0.465
0.422
0.336
0.199
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

698.70
700.98
704.73
708.01
712.78
718.62
725.94
735.17
748.02
763.12
785.89

0.000
0.239
0.363
0.427
0.460
0.474
0.449
0.410
0.328
0.194
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

700.72
703.04
706.82
710.12
714.89
720.75
728.08
737.33
750.16
765.27
788.03

0.000
0.229
0.348
0.411
0.446
0.458
0.436
0.398
0.322
0.190
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000

702.73
705.11
708.92
712.22
717.01
722.88
730.23
739.47
752.31
767.41

0.000
0.214
0.331
0.395
0.430
0.443
0.420
0.386
0.313
0.185

A 18 | A. GAYOL

u
-1

-1

ms
1143.9
1139.7
1136.4
1132.5
1129.5
1125.2
1126.9
1127.9
1134.6
298.15 K
1168.2
1157.9
1154.3
1150.2
1146.6
1142.7
1139.4
1134.7
1136.4
1137.0
1143.1
295.65 K
1178.7
1168.6
1164.9
1160.7
1157.0
1153.1
1149.5
1144.1
1146.1
1146.1
1151.6
293.15 K
1189.3
1179.4
1175.5
1171.5
1167.7
1163.6
1159.9
1153.8
1155.8
1155.4

-1

S
-1

TPa
1087.7
1090.7
1089.6
1088.2
1083.0
1077.6
1055.8
1033.1
991.2

TPa
34.1
43.8
50.7
57.2
60.0
62.6
49.3
34.0
0.0

1048.8
1064.0
1064.9
1067.7
1067.1
1065.6
1061.1
1056.5
1035.1
1013.6
973.8

0.0
22.7
32.3
41.4
48.3
54.3
57.3
60.3
46.9
32.3
0.0

1027.2
1041.6
1042.7
1045.2
1044.9
1043.5
1039.5
1036.1
1014.9
994.7
956.9

0.0
21.5
30.7
39.1
45.8
51.5
54.5
58.2
44.5
30.8
0.0

1006.1
1019.5
1020.8
1023.0
1022.9
1021.8
1017.9
1015.8
995.0
976.2

0.0
20.1
29.1
36.8
43.2
48.7
51.5
56.0
42.3
29.5

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.8. Continuacin.
x1

VE

-3

1.0000

kgm
790.16

cm mol
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

704.74
707.16
711.00
714.31
719.11
725.00
732.35
741.60
754.43
769.54
792.31

0.000
0.206
0.318
0.381
0.417
0.430
0.410
0.379
0.309
0.183
0.000

0.0000
0.1008
0.2161
0.2997
0.3993
0.4995
0.5998
0.7010
0.8080
0.9000
1.0000

706.75
709.17
713.02
716.35
721.16
727.05
734.42
743.69
756.51
771.62
794.44

0.000
0.205
0.317
0.377
0.412
0.426
0.405
0.374
0.308
0.185
0.000

u
-1

-1

ms
1160.3
290.65 K
1200.0
1190.4
1186.2
1182.3
1178.3
1174.1
1170.2
1163.4
1165.6
1164.3
1169.1
288.15 K
1211.0
1201.6
1197.1
1193.5
1189.0
1184.8
1180.5
1172.9
1175.6
1173.1
1178.2

-1

-1

TPa
940.0

TPa
0.0

985.4
997.9
999.6
1001.4
1001.6
1000.6
997.2
996.2
975.6
958.6
923.4

0.0
18.8
27.6
34.6
41.0
46.2
49.0
54.3
40.3
29.0
0.0

964.9
976.6
978.7
979.9
980.8
979.8
977.0
977.4
956.5
941.8
906.8

0.0
17.6
26.4
32.5
39.1
43.9
47.0
53.3
38.5
29.2
0.0

Tabla A.9. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria x1 etanol (1) x2 n-nonano (2) en el intervalo de temperaturas
(318.15- 288.15) K.

x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

1.39368
1.39053
1.38941
1.38702
1.38409
1.38128
1.37867
1.37342
1.36786
1.36019
1.35070

1.39718
1.39648
1.39505
1.39203
1.38970
1.38613
1.38390
1.37846
1.37293
1.36539
1.35502

1.40298
1.40253
1.39983
1.39682
1.39422
1.39119
1.38803
1.38311
1.37744
1.36931
1.35926

1.40749
1.40598
1.40466
1.40167
1.39904
1.39597
1.39272
1.38784
1.38207
1.37389
1.36332

0.00000
0.00088
0.00346
0.00591
0.00721
0.00860
0.00962
0.00904
0.00795
0.00490
0.00000

0.00000
0.00325
0.00545
0.00718
0.00900
0.00955
0.01088
0.01002
0.00888
0.00587
0.00000

0.00000
0.00364
0.00472
0.00663
0.00833
0.00957
0.01010
0.00993
0.00881
0.00538
0.00000

0.00000
0.00263
0.00512
0.00710
0.00882
0.01006
0.01054
0.01046
0.00929
0.00585
0.00000

A 19 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.10. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de mezcla
para x1 etanol (1) x2 n-nonano (2) en el intervalo de temperaturas (323.15-288.15) K.
x1

VE

kgm

-3

cm mol

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

698.31
698.32
700.63
703.51
706.93
710.83
715.52
722.32
731.70
745.55
768.48

0.000
0.561
0.545
0.657
0.675
0.722
0.656
0.667
0.573
0.404
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

700.21
700.26
702.61
705.54
708.99
712.89
717.61
724.43
733.82
747.68
770.63

0.000
0.551
0.527
0.634
0.651
0.699
0.634
0.648
0.560
0.397
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

702.20
702.31
704.69
707.65
711.12
715.05
719.78
726.62
736.01
749.90
772.85

0.000
0.534
0.508
0.611
0.627
0.676
0.614
0.630
0.547
0.389
0.000

0.0000
0.0937
0.1799

704.16
704.32
706.75

0.000
0.521
0.486

A 20 | A. GAYOL

u
-1

-1

ms
318.15 K
1123.9
1118.6
1109.2
1102.1
1097.0
1091.1
1087.3
1080.2
1074.7
1070.1
1075.9
315.65 K
1133.9
1128.5
1119.2
1112.2
1107.1
1101.1
1097.2
1089.9
1084.1
1079.2
1084.3
313.15 K
1143.8
1138.6
1129.2
1122.3
1117.0
1111.0
1107.0
1099.5
1093.3
1088.1
1092.7
310.65 K
1153.6
1148.4
1139.2

TPa

-1

S
TPa

-1

1133.7
1144.4
1160.1
1170.2
1175.4
1181.8
1182.1
1186.5
1183.3
1171.3
1124.1

0.0
9.9
25.0
34.1
38.5
44.0
43.7
47.3
43.1
30.2
0.0

1110.8
1121.3
1136.3
1145.8
1150.7
1157.0
1157.5
1162.1
1159.5
1148.4
1103.6

0.0
11.2
26.8
37.1
42.7
49.6
50.8
56.1
54.3
44.0
0.0

1088.6
1098.3
1112.9
1121.9
1127.0
1133.0
1133.7
1138.4
1136.7
1126.4
1083.7

0.0
10.2
25.2
34.8
40.3
46.8
47.9
53.2
51.9
42.2
0.0

1067.2
1076.6
1090.2

0.0
9.7
23.6

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.10. Continuacin.
x1

VE

-3

0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

kgm
709.76
713.25
717.19
721.94
728.79
738.19
752.09
775.05

cm mol
0.582
0.600
0.651
0.590
0.612
0.533
0.382
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

706.13
706.33
708.80
711.83
715.34
719.30
724.07
730.96
740.37
754.26
777.24

0.000
0.511
0.470
0.564
0.580
0.632
0.572
0.593
0.520
0.375
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

708.07
708.32
710.83
713.89
717.42
721.39
726.18
733.08
742.51
756.42
779.40

0.000
0.498
0.449
0.542
0.558
0.612
0.553
0.578
0.508
0.368
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932

710.05
710.33
712.88
715.96
719.53
723.51
728.32
735.23
744.67
758.59

0.000
0.490
0.435
0.525
0.538
0.594
0.536
0.564
0.498
0.362

u
-1

-1

ms
1132.4
1127.1
1120.8
1116.9
1109.0
1102.6
1096.9
1101.0
308.15 K
1163.6
1158.4
1149.4
1142.4
1137.2
1130.8
1126.6
1118.6
1112.0
1105.9
1109.4
305.65 K
1173.6
1168.4
1159.5
1152.4
1147.2
1140.7
1136.5
1128.2
1121.3
1114.8
1117.8
303.15 K
1183.6
1178.5
1169.5
1162.5
1157.2
1150.7
1146.3
1137.8
1130.6
1123.8

-1

S
-1

TPa
1098.8
1103.6
1109.9
1110.5
1115.7
1114.3
1105.1
1064.4

TPa
32.5
37.6
44.1
44.9
50.4
49.4
40.4
0.0

1046.0
1055.0
1068.0
1076.5
1081.0
1087.2
1088.0
1093.3
1092.2
1084.1
1045.4

0.0
9.1
22.2
30.7
35.3
41.5
42.4
47.8
46.8
38.7
0.0

1025.4
1034.1
1046.4
1054.8
1059.2
1065.3
1066.2
1071.7
1071.2
1063.8
1026.9

0.0
8.6
20.8
28.9
33.2
39.1
39.9
45.3
44.6
37.0
0.0

1005.2
1013.6
1025.5
1033.5
1037.8
1043.8
1044.9
1050.7
1050.5
1043.8

0.0
8.0
19.6
27.2
31.2
36.8
37.6
43.1
42.5
35.5

A 21 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.10. Continuacin.

x1

VE

-3

1.0000

kgm
781.59

cm mol
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

712.00
712.30
714.89
717.99
721.59
725.57
730.41
737.33
746.79
760.72
783.73

0.000
0.483
0.421
0.509
0.520
0.578
0.520
0.551
0.487
0.356
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

713.96
714.29
716.91
720.04
723.66
727.66
732.50
739.43
748.91
762.86
785.89

0.000
0.476
0.408
0.495
0.504
0.562
0.507
0.540
0.478
0.351
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

715.90
716.24
718.91
722.06
725.70
729.72
734.57
741.52
751.01
764.97
788.03

0.000
0.472
0.396
0.481
0.489
0.548
0.493
0.528
0.470
0.347
0.000

0.0000
0.0937
0.1799
0.2924

717.84
718.22
720.91
724.09

0.000
0.461
0.383
0.465

A 22 | A. GAYOL

u
-1

-1

ms
1126.2
300.65 K
1193.6
1188.5
1179.7
1172.7
1167.3
1160.6
1156.1
1147.4
1140.0
1132.7
1134.6
298.15 K
1203.7
1198.7
1189.8
1182.8
1177.4
1170.6
1166.1
1157.0
1149.3
1141.7
1143.1
295.65 K
1214.0
1208.8
1200.1
1193.0
1187.6
1180.7
1176.0
1166.8
1158.8
1150.8
1151.6
293.15 K
1224.3
1219.2
1210.5
1203.4

-1

S
-1

TPa
1008.7

TPa
0.0

985.8
993.8
1005.2
1012.8
1017.0
1023.2
1024.3
1030.2
1030.4
1024.5
991.1

0.0
7.5
18.4
25.4
29.1
34.7
35.4
40.8
40.4
34.0
0.0

966.7
974.4
985.3
992.7
996.9
1002.8
1004.0
1010.2
1010.8
1005.7
973.8

0.0
7.0
17.4
23.9
27.4
32.7
33.3
38.7
38.5
32.6
0.0

947.8
955.5
965.8
973.0
977.0
983.1
984.3
990.6
991.5
987.1
956.8

0.0
6.8
16.4
22.6
25.7
30.9
31.4
36.7
36.7
31.2
0.0

929.3
936.6
946.6
953.6

0.0
6.3
15.3
21.1

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.10. Continuacin.
x1

VE

-3

0.3909
0.4886
0.5730
0.6916
0.7858
0.8932
1.0000

kgm
727.73
731.77
736.65
743.60
753.10
766.94
790.16

cm mol
0.475
0.534
0.479
0.517
0.462
0.355
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

719.79
720.18
722.90
726.10
729.77
733.82
738.71
745.68
755.19
768.91
792.31

0.000
0.457
0.375
0.454
0.463
0.522
0.469
0.508
0.457
0.365
0.000

0.0000
0.0937
0.1799
0.2924
0.3909
0.4886
0.5730
0.6816
0.7858
0.8932
1.0000

721.68
722.15
724.85
728.11
731.76
735.87
740.71
747.76
757.23
771.23
794.44

0.000
0.439
0.365
0.434
0.451
0.502
0.460
0.494
0.452
0.339
0.000

u
-1

-1

ms
1197.9
1190.9
1186.2
1176.6
1168.4
1160.1
1160.3
290.65 K
1234.9
1229.6
1221.0
1213.8
1208.2
1201.1
1196.3
1186.6
1178.1
1169.4
1169.1
288.15 K
1245.4
1240.3
1231.5
1224.4
1218.6
1211.6
1206.4
1196.8
1187.7
1178.7
1178.2

-1

TPa
957.6
963.6
964.8
971.4
972.6
968.9
940.0

TPa
24.1
29.0
29.3
34.8
34.9
30.1
0.0

-1

911.0
918.4
927.9
934.8
938.7
944.6
945.9
952.5
954.1
951.1
923.4

0.0
6.2
14.7
20.2
22.8
27.5
27.8
33.1
33.4
29.0
0.0

893.4
900.2
909.7
916.1
920.3
925.7
927.6
933.7
936.2
933.3
906.8

0.0
5.5
13.9
18.8
21.6
25.8
26.5
31.2
32.3
28.0
0.0

Tabla A.11. Influencia de la composicin sobre los ndices de refraccin, las variaciones de
ndices de refraccin de la mezcla binaria x1 n-hexano (1) x2 n-heptano (2) en el intervalo
de temperaturas (318.15- 288.15) K.
x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

0.0000
0.0761
0.1651
0.2081

1.37952
1.37516
1.37307
1.37218

1.37952
1.37914
1.37818
1.37769

1.38491
1.38477
1.38386
1.38343

1.39027 0.00000
1.38962 -0.00291
1.38877 -0.00331
1.38823 -0.00339

308.15

298.15

288.15

0.00000
0.00061
0.00081
0.00088

0.00000
0.00083
0.00106
0.00118

0.00000
0.00030
0.00056
0.00056

A 23 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.11. Continuacin

x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.2537
0.2973
0.3485
0.3951
0.4487
0.5008
0.5450
0.6021
0.6419
0.7227
0.7675
0.8756
1.0000

1.37126
1.37065
1.37009
1.36966
1.36892
1.36817
1.36765
1.36686
1.36622
1.36509
1.36442
1.36251
1.36052

1.37719
1.37669
1.37609
1.37553
1.37483
1.37414
1.37354
1.37275
1.37217
1.37101
1.37032
1.36858
1.36652

1.38293
1.38241
1.38177
1.38119
1.38050
1.37982
1.37924
1.37845
1.37789
1.37668
1.37599
1.37425
1.37211

1.38775
1.38718
1.38659
1.38602
1.38539
1.38474
1.38418
1.38346
1.38294
1.38187
1.38124
1.37970
1.37777

-0.00344
-0.00322
-0.00281
-0.00235
-0.00208
-0.00183
-0.00151
-0.00122
-0.00110
-0.00070
-0.00052
-0.00037
0.00000

0.00097
0.00104
0.00110
0.00115
0.00114
0.00113
0.00111
0.00106
0.00099
0.00088
0.00078
0.00044
0.00000

0.00127
0.00131
0.00132
0.00134
0.00133
0.00132
0.00131
0.00125
0.00120
0.00102
0.00090
0.00055
0.00000

0.00065
0.00063
0.00068
0.00069
0.00073
0.00073
0.00072
0.00072
0.00069
0.00063
0.00056
0.00037
0.00000

Tabla A.12. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad

del sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de
mezcla para x1 n-hexano (1) x2 n-heptano (2) en el intervalo (323.15-288.15) K.
x1

VE

-3

cm mol

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

662.43
660.49
658.41
656.32
653.90
651.49
649.02
646.47
643.06
640.00
636.28

0.000
-0.188
-0.399
-0.551
-0.626
-0.692
-0.682
-0.623
-0.480
-0.293
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415

664.55
662.60
660.53
658.45
656.05
653.67
651.20
648.66
645.29

0.000
-0.181
-0.387
-0.540
-0.614
-0.682
-0.671
-0.611
-0.473

kgm

A 24 | A. GAYOL

u
-1

-1

ms
318.15 K
1043.0
1039.6
1035.0
1030.3
1025.2
1019.6
1013.9
1008.6
1001.0
994.3
979.3
315.65 K
1053.8
1050.4
1045.7
1041.0
1036.0
1030.4
1024.8
1019.4
1012.0

TPa

-1

S
TPa

-1

1387.7
1400.8
1417.8
1435.4
1455.1
1476.4
1498.7
1520.6
1552.1
1580.5
1638.8

0.0
-16.3
-30.5
-41.1
-48.7
-53.7
-54.3
-53.5
-46.9
-37.9
0.0

1355.1
1368.0
1384.6
1401.5
1420.1
1440.8
1462.3
1483.6
1513.2

0.0
-15.4
-28.8
-39.0
-46.7
-51.2
-51.7
-50.8
-45.1

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.13. Continuacin.
x1

VE

-3

0.9188
1.0000

kgm
642.24
638.55

cm mol
-0.286
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

666.72
664.79
662.74
660.66
658.26
655.90
653.47
650.94
647.58
644.56
640.90

0.000
-0.179
-0.384
-0.531
-0.603
-0.670
-0.661
-0.602
-0.464
-0.281
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

668.89
666.96
664.91
662.87
660.47
658.14
655.71
653.21
649.86
646.86
643.23

0.000
-0.176
-0.375
-0.523
-0.591
-0.661
-0.651
-0.593
-0.455
-0.278
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

671.03
669.13
667.08
665.05
662.67
660.35
657.94
655.45
652.13
649.15
645.55

0.000
-0.175
-0.370
-0.517
-0.582
-0.650
-0.639
-0.583
-0.447
-0.272
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670

673.16
671.27
669.23
667.21
664.84
662.54

0.000
-0.173
-0.364
-0.509
-0.573
-0.640

u
-1

-1

ms
1005.2
990.4
313.15 K
1064.3
1060.9
1056.4
1051.6
1046.7
1041.1
1035.6
1030.1
1023.0
1016.1
1001.7
310.65 K
1075.0
1071.5
1066.9
1062.3
1057.2
1051.9
1046.4
1041.0
1033.7
1027.2
1013.2
308.15 K
1085.6
1082.2
1077.6
1073.0
1068.0
1062.7
1057.3
1051.9
1044.7
1038.4
1024.6
305.65 K
1096.3
1092.8
1088.4
1083.7
1078.8
1073.5

-1

TPa
1541.1
1596.6

TPa
-35.9
0.0

-1

1324.1
1336.4
1352.2
1368.7
1386.6
1406.7
1426.9
1447.8
1475.7
1502.7
1555.0

0.0
-14.7
-27.7
-37.1
-44.3
-48.3
-49.2
-47.7
-42.7
-33.6
0.0

1293.7
1305.9
1321.2
1336.9
1354.6
1373.2
1392.7
1412.8
1440.2
1465.0
1514.4

0.0
-13.6
-25.8
-34.8
-41.2
-45.6
-46.3
-44.8
-39.2
-31.5
0.0

1264.5
1276.1
1290.8
1305.9
1323.0
1340.9
1359.6
1378.9
1404.9
1428.5
1475.6

0.0
-13.1
-24.6
-33.2
-39.1
-43.3
-43.9
-42.3
-37.2
-29.9
0.0

1236.0
1247.5
1261.5
1276.2
1292.4
1309.8

0.0
-12.2
-23.5
-31.6
-37.5
-41.4

A 25 | A. GAYOL

A.

Tablas de Propiedad.
Tabla A.12. Continuacin.
x1

VE

-3

0.6584
0.7425
0.8415
0.9188
1.0000

kgm
660.14
657.67
654.37
651.40
647.83

cm mol
-0.631
-0.574
-0.441
-0.267
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

675.32
673.43
671.41
669.42
667.05
664.76
662.38
659.92
656.63
653.69
650.15

0.000
-0.169
-0.357
-0.503
-0.564
-0.630
-0.622
-0.566
-0.431
-0.261
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

677.44
675.57
673.55
671.57
669.20
666.94
664.58
662.13
658.85
655.94
652.42

0.000
-0.167
-0.352
-0.496
-0.552
-0.622
-0.614
-0.558
-0.424
-0.258
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

679.57
677.71
675.70
673.74
671.37
669.14
666.79
664.36
661.09
658.20
654.70

0.000
-0.166
-0.347
-0.490
-0.543
-0.615
-0.607
-0.552
-0.418
-0.254
0.000

0.0000
0.1170

681.68
679.84

0.000
-0.165

A 26 | A. GAYOL

u
-1

-1

ms
1068.2
1062.8
1055.8
1049.4
1035.7
303.15 K
1107.0
1103.4
1099.0
1094.5
1089.7
1084.4
1079.1
1073.8
1066.8
1060.6
1047.1
300.65 K
1117.6
1114.0
1109.8
1105.2
1100.4
1095.2
1090.0
1084.7
1077.8
1071.7
1058.4
298.15 K
1128.4
1124.7
1120.5
1116.0
1111.3
1106.1
1101.0
1095.7
1088.9
1082.9
1069.8
295.65 K
1139.2
1135.6

-1

TPa
1327.7
1346.2
1370.9
1393.9
1439.0

TPa
-42.0
-40.5
-35.9
-28.7
0.0

-1

1208.4
1219.6
1233.1
1247.0
1262.5
1279.3
1296.5
1314.3
1338.3
1359.9
1402.8

0.0
-11.5
-22.2
-30.1
-35.9
-39.3
-39.9
-38.5
-33.7
-27.1
0.0

1181.8
1192.8
1205.5
1219.0
1234.0
1250.1
1266.5
1283.7
1306.6
1327.3
1368.3

0.0
-10.9
-21.3
-28.7
-34.1
-37.4
-38.1
-36.6
-32.2
-25.8
0.0

1155.7
1166.4
1178.7
1191.6
1206.0
1221.5
1237.3
1253.7
1275.7
1295.6
1334.6

0.0
-10.2
-20.2
-27.3
-32.4
-35.6
-36.2
-34.8
-30.5
-24.5
0.0

1130.4
1140.7

0.0
-9.8

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.12. Continuacin.
x1

VE

-3

0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

kgm
677.82
675.89
673.52
671.32
668.98
666.57
663.31
660.43
656.96

cm mol
-0.340
-0.485
-0.535
-0.607
-0.599
-0.547
-0.411
-0.249
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

683.78
681.96
679.96
678.04
675.67
673.49
671.18
668.77
665.51
662.66
659.21

0.000
-0.164
-0.338
-0.482
-0.528
-0.601
-0.595
-0.540
-0.405
-0.247
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

685.89
684.07
682.07
680.18
677.81
675.66
673.36
670.95
667.72
664.89
661.45

0.000
-0.161
-0.331
-0.477
-0.518
-0.596
-0.588
-0.531
-0.400
-0.245
0.000

0.0000
0.1170
0.2414
0.3535
0.4625
0.5670
0.6584
0.7425
0.8415
0.9188
1.0000

687.95
686.13
684.15
682.26
679.93
677.77
675.47
673.09
669.88
667.04
663.64

0.000
-0.156
-0.327
-0.468
-0.514
-0.587
-0.579
-0.526
-0.395
-0.238
0.000

u
-1

-1

ms
1131.4
1126.9
1122.3
1117.1
1112.0
1106.9
1100.1
1094.1
1081.4
293.15 K
1150.2
1146.5
1142.4
1138.0
1133.4
1128.2
1123.3
1118.1
1111.4
1105.5
1093.1
290.65 K
1161.3
1157.6
1153.5
1149.1
1144.6
1139.4
1134.5
1129.3
1122.8
1116.8
1106.0
288.15 K
1172.3
1168.5
1164.5
1160.2
1155.6
1150.6
1145.7
1140.6
1134.2
1127.9
1118.3

-1

TPa
1152.6
1165.0
1178.8
1193.8
1208.8
1224.5
1245.8
1264.9
1301.6

TPa
-19.1
-25.9
-30.7
-33.7
-34.4
-33.0
-28.7
-22.9
0.0

-1

1105.4
1115.5
1126.8
1138.8
1152.1
1166.5
1180.9
1196.2
1216.4
1234.8
1269.6

0.0
-9.2
-18.2
-24.7
-29.2
-32.0
-32.6
-31.1
-27.1
-21.4
0.0

1081.1
1090.9
1102.0
1113.4
1126.2
1139.9
1153.8
1168.6
1188.0
1205.9
1235.9

0.0
-8.3
-16.5
-22.4
-26.5
-28.9
-29.2
-27.4
-23.4
-17.5
0.0

1057.7
1067.4
1077.8
1088.9
1101.3
1114.4
1127.8
1142.0
1160.5
1178.4
1204.9

0.0
-7.5
-15.4
-20.8
-24.5
-26.8
-26.8
-25.0
-21.0
-14.6
0.0

A 27 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.13 Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria x1 n-hexano (1) x2 n-octano (2) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.0000
0.0850
0.1632
0.2007
0.2625
0.2916
0.3446
0.3812
0.4472
0.4906
0.5476
0.6010
0.6465
0.6955
0.7540
0.8751
1.0000

1.38489
1.38428
1.38341
1.38273
1.38160
1.38107
1.37998
1.37917
1.37768
1.37657
1.37515
1.37374
1.37253
1.37106
1.36939
1.36575
1.36052

1.39058
1.38897
1.38770
1.38703
1.38596
1.38535
1.38423
1.38345
1.38187
1.38079
1.37938
1.37802
1.37688
1.37562
1.37391
1.37051
1.36652

1.39551
1.39455
1.39338
1.39277
1.39165
1.39117
1.39016
1.38944
1.38794
1.38691
1.38548
1.38414
1.38301
1.38172
1.38015
1.37681
1.37211

1.40040
1.39872
1.39731
1.39671
1.39562
1.39515
1.39416
1.39337
1.39189
1.39086
1.38953
1.38825
1.38710
1.38576
1.38415
1.38092
1.37777

0.00000
0.00146
0.00250
0.00273
0.00311
0.00329
0.00349
0.00357
0.00369
0.00364
0.00360
0.00350
0.00340
0.00312
0.00288
0.00219
0.00000

0.00000
0.00043
0.00105
0.00128
0.00170
0.00179
0.00194
0.00204
0.00205
0.00201
0.00198
0.00190
0.00186
0.00177
0.00147
0.00099
0.00000

0.00000
0.00103
0.00169
0.00196
0.00228
0.00248
0.00271
0.00285
0.00290
0.00288
0.00278
0.00269
0.00263
0.00248
0.00228
0.00178
0.00000

0.00000
0.00024
0.00060
0.00085
0.00116
0.00135
0.00156
0.00160
0.00161
0.00156
0.00152
0.00145
0.00133
0.00110
0.00081
0.00032
0.00000

Tabla A.14. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de mezcla
para x1 n-hexano (1) x2 n-octano (2) en el intervalo de temperaturas (323.15-288.15) K.
x1

VE

-3

cm mol

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

682.48
679.21
676.25
672.64
664.74
660.24
655.51
650.10
643.58
636.28

0.000
0.010
-0.017
-0.115
-0.125
-0.141
-0.135
-0.121
-0.080
0.000

0.0000

684.46

0.000

kgm

A 28 | A. GAYOL

u
-1

-1

ms
318.15 K
1085.4
1081.7
1071.8
1066.1
1028.9
1038.1
1027.7
1015.9
1001.5
979.3
315.65 K
1095.8

TPa

-1

S
TPa

-1

1243.7
1258.4
1287.3
1308.0
1420.9
1405.5
1444.4
1490.6
1549.3
1638.8

0.0
-18.9
-20.9
-39.4
0.5
-54.6
-54.8
-51.0
-40.2
0.0

1216.7

0.0

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.14. Continuacin.
x1

VE

-3

0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

kgm
681.21
678.28
674.69
666.84
662.35
657.65
652.28
645.80
638.55

cm mol
0.011
-0.017
-0.114
-0.122
-0.136
-0.130
-0.118
-0.079
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751.
1.0000

686.53
683.29
680.37
676.80
669.01
664.55
659.88
654.54
648.10
640.90

0.000
0.012
-0.014
-0.107
-0.118
-0.130
-0.125
-0.113
-0.074
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

688.57
685.36
682.47
678.89
671.17
666.72
662.08
656.78
650.38
643.23

0.000
0.012
-0.016
-0.103
-0.118
-0.125
-0.121
-0.109
-0.072
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

690.61
687.41
684.53
681.00
673.30
668.88
664.28
659.00
652.64
645.55

0.000
0.014
-0.012
-0.103
-0.110
-0.118
-0.116
-0.102
-0.068
0.000

0.0000

692.62

0.000

u
-1

-1

ms
1091.9
1082.2
1076.6
1039.7
1048.8
1038.4
1026.6
1012.5
990.4
313.15 K
1106.2
1102.1
1092.4
1086.9
1050.4
1059.1
1048.9
1037.4
1023.4
1001.7
310.65 K
1116.5
1112.3
1102.8
1097.2
1061.2
1069.7
1059.6
1048.0
1034.4
1013.2
308.15 K
1126.9
1122.5
1113.0
1107.7
1072.1
1080.4
1070.3
1058.9
1045.4
1024.6
305.65 K
1137.2

-1

S
-1

TPa
1231.2
1258.9
1278.8
1387.3
1372.7
1410.1
1454.6
1510.5
1596.6

TPa
-17.8
-19.8
-37.7
0.7
-52.1
-52.2
-48.6
-38.6
0.0

1190.3
1204.9
1231.7
1250.7
1354.7
1341.5
1377.4
1419.5
1473.3
1555.0

0.0
-16.4
-18.2
-35.4
1.3
-48.6
-48.8
-45.8
-36.2
0.0

1165.0
1179.4
1204.9
1223.5
1323.1
1310.8
1345.4
1386.3
1437.0
1514.4

0.0
-15.3
-17.1
-33.2
1.8
-45.5
-45.5
-42.2
-33.7
0.0

1140.2
1154.5
1179.3
1196.8
1292.2
1280.8
1314.1
1353.2
1402.1
1475.6

0.0
-14.3
-15.7
-31.5
2.0
-43.1
-42.9
-39.9
-31.5
0.0

1116.4

0.0

A 29 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.14. Continuacin.

x1

VE

-3

0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

kgm
689.45
686.59
682.36
675.43
671.02
666.45
661.19
654.89
647.83

cm mol
0.012
-0.013
0.062
-0.110
-0.115
-0.114
-0.099
-0.069
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

694.67
691.52
688.68
684.64
677.57
673.18
668.65
663.42
657.17
650.15

0.000
0.012
-0.012
0.024
-0.105
-0.108
-0.109
-0.094
-0.066
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

696.68
693.55
690.72
686.77
679.68
675.31
670.82
665.60
659.41
652.42

0.000
0.011
-0.012
0.012
-0.102
-0.105
-0.107
-0.090
-0.067
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

698.70
695.60
692.78
688.93
681.79
677.44
673.00
667.81
661.64
654.70

0.000
0.009
-0.011
-0.006
-0.099
-0.099
-0.107
-0.088
-0.066
0.000

0.0000
0.0850

700.72
697.63

0.000
0.011

A 30 | A. GAYOL

u
-1

-1

ms
1132.8
1123.4
1118.1
1083.0
1091.0
1081.0
1069.7
1056.3
1035.7
303.15 K
1147.5
1143.1
1133.7
1128.6
1094.0
1101.7
1091.8
1080.7
1067.4
1047.1
300.65 K
1157.8
1153.4
1144.2
1139.1
1105.1
1112.4
1102.6
1091.5
1078.5
1058.4
298.15 K
1168.2
1163.7
1154.7
1149.6
1116.4
1123.1
1113.5
1102.6
1089.5
1069.8
295.65 K
1178.7
1174.2

-1

S
-1

TPa
1130.4
1154.1
1172.3
1262.3
1252.0
1283.9
1321.6
1368.4
1439.0

TPa
-13.5
-14.9
-28.8
1.5
-41.1
-41.1
-38.0
-30.3
0.0

1093.2
1106.7
1129.7
1146.6
1233.2
1223.9
1254.6
1290.7
1335.5
1402.8

0.0
-12.8
-14.0
-27.9
1.5
-38.8
-38.8
-36.0
-28.6
0.0

1070.8
1083.9
1105.9
1122.2
1204.8
1196.7
1226.2
1261.0
1303.9
1368.3

0.0
-12.2
-13.5
-26.6
1.0
-37.0
-37.0
-34.1
-27.2
0.0

1048.8
1061.6
1082.7
1098.4
1176.9
1170.3
1198.4
1231.7
1273.2
1334.6

0.0
-11.5
-12.7
-25.4
0.3
-35.0
-35.1
-32.6
-25.7
0.0

1027.2
1039.7

0.0
-10.8

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.14. Continuacin.
x1

VE

-3

0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

kgm
694.82
691.15
683.90
679.57
675.15
669.98
663.88
656.96

cm mol
-0.008
-0.039
-0.095
-0.094
-0.104
-0.082
-0.066
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

702.73
699.67
696.86
693.31
686.01
681.68
677.30
672.15
666.09
659.21

0.000
0.008
-0.008
-0.060
-0.093
-0.089
-0.101
-0.079
-0.066
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

704.74
701.69
698.90
695.46
688.09
683.79
679.44
674.31
668.30
661.45

0.000
0.009
-0.006
-0.076
-0.087
-0.084
-0.097
-0.075
-0.065
0.000

0.0000
0.0850
0.1632
0.2625
0.4472
0.5476
0.6465
0.7540
0.8751
1.0000

706.75
703.64
700.87
697.53
690.13
685.85
681.52
676.43
670.44
663.64

0.000
0.027
0.008
-0.080
-0.077
-0.075
-0.089
-0.070
-0.060
0.000

u
-1

-1

ms
1165.3
1160.2
1128.3
1133.9
1124.4
1113.6
1100.7
1081.4
293.15 K
1189.3
1184.9
1176.3
1171.1
1144.2
1145.0
1135.5
1124.7
1112.1
1093.1
290.65 K
1200.0
1195.6
1187.9
1182.0
1160.0
1156.1
1146.7
1136.0
1123.4
1106.0
288.15 K
1211.0
1206.2
1199.4
1193.0
1176.2
1167.2
1157.8
1147.4
1134.6
1118.3

-1

S
-1

TPa
1059.9
1074.8
1148.5
1144.4
1171.6
1203.6
1243.3
1301.6

TPa
-12.1
-24.4
-1.4
-33.1
-33.1
-30.5
-24.1
0.0

1006.1
1017.9
1037.1
1051.8
1113.4
1119.0
1145.1
1176.0
1213.9
1269.6

0.0
-10.5
-12.0
-23.5
-10.6
-31.3
-31.4
-28.7
-22.7
0.0

985.4
996.9
1013.9
1029.1
1080.1
1094.2
1119.3
1149.2
1185.7
1235.9

0.0
-9.8
-12.3
-22.0
-17.4
-28.4
-28.1
-25.1
-19.0
0.0

964.8
976.8
991.9
1007.3
1047.3
1070.2
1094.6
1122.9
1158.6
1204.9

0.0
-8.4
-12.1
-20.6
-24.9
-26.1
-25.4
-22.9
-16.3
0.0

A 31 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.15. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria x1 n-hexano (1) x2 n-nonano (2) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

nD

nD

T/K

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.0000
0.0752
0.1569
0.2094
0.2410
0.3016
0.3520
0.3806
0.4375
0.4773
0.5374
0.5872
0.6444
0.6855
0.7620
0.8785
1.0000

1.39304
1.39180
1.39007
1.38905
1.38829
1.38678
1.38551
1.38470
1.38303
1.38182
1.37986
1.37819
1.37614
1.37464
1.37167
1.36658
1.36052

1.39839
1.39641
1.39452
1.39338
1.39263
1.39141
1.39020
1.38945
1.38783
1.38669
1.38479
1.38316
1.38101
1.37951
1.37648
1.37179
1.36652

1.40321
1.40167
1.39997
1.39882
1.39829
1.39695
1.39558
1.39491
1.39343
1.39226
1.39051
1.38888
1.38690
1.38541
1.38243
1.37761
1.37211

1.40783
1.40571
1.40368
1.40260
1.40193
1.40063
1.39945
1.39879
1.39747
1.39638
1.39472
1.39309
1.39093
1.38943
1.38646
1.38220
1.37777

0.00000
0.00121
0.00213
0.00282
0.00309
0.00355
0.00392
0.00404
0.00422
0.00430
0.00429
0.00424
0.00405
0.00389
0.00341
0.00211
0.00000

0.00000
0.00042
0.00113
0.00166
0.00192
0.00263
0.00303
0.00319
0.00338
0.00351
0.00353
0.00348
0.00316
0.00297
0.00238
0.00140
0.00000

0.00000
0.00080
0.00164
0.00212
0.00257
0.00312
0.00332
0.00354
0.00383
0.00389
0.00401
0.00393
0.00373
0.00352
0.00292
0.00172
0.00000

0.00000
0.00014
0.00057
0.00106
0.00134
0.00186
0.00220
0.00240
0.00279
0.00290
0.00304
0.00291
0.00247
0.00221
0.00154
0.00078
0.00000

Tabla A.16. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de mezcla
para x1 n-hexano (1) x2 n-nonano (2) en el intervalo de temperaturas (323.15-288.15) K.
x1

VE

-3

cm mol

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

698.31
694.95
691.23
687.14
681.42
676.64
670.69
663.81
655.60
646.70
636.28

0.000
-0.038
-0.102
-0.149
-0.209
-0.226
-0.235
-0.225
-0.193
-0.137
0.000

0.0000

700.21

0.000

kgm

A 32 | A. GAYOL

u
-1

-1

ms
318.15 K
1123.9
1117.2
1108.5
1098.9
1085.8
1074.7
1061.4
1046.0
1027.7
1008.2
979.3
315.65 K
1133.9

TPa

-1

S
TPa

-1

1133.7
1153.0
1177.4
1205.2
1244.8
1279.5
1323.5
1376.8
1444.1
1521.2
1638.8

0.0
-18.7
-35.5
-50.3
-66.7
-75.2
-81.6
-82.3
-74.5
-56.2
0.0

1110.8

0.0

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.16. Continuacin.
x1

VE

-3

0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

kgm
696.85
693.16
689.10
683.40
678.65
672.73
665.90
657.73
648.90
638.55

cm mol
-0.032
-0.098
-0.144
-0.198
-0.216
-0.222
-0.215
-0.183
-0.131
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

702.20
698.83
695.18
691.14
685.48
680.75
674.85
668.07
659.96
651.17
640.90

0.000
-0.024
-0.092
-0.137
-0.192
-0.207
-0.210
-0.206
-0.177
-0.123
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

704.16
700.81
697.18
693.17
687.53
682.84
676.96
670.23
662.17
653.44
643.23

0.000
-0.024
-0.090
-0.133
-0.184
-0.201
-0.202
-0.199
-0.171
-0.121
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620

706.13
702.77
699.18
695.18
689.57
684.91
679.05
672.38
664.35

0.000
-0.014
-0.084
-0.126
-0.174
-0.190
-0.189
-0.190
-0.161

u
-1

-1

ms
1127.2
1118.5
1109.1
1095.9
1085.1
1071.9
1056.6
1038.5
1019.2
990.4
313.15 K
1143.8
1137.1
1128.5
1119.1
1106.3
1095.3
1082.2
1067.0
1049.3
1030.0
1001.7
310.65 K
1153.6
1147.0
1138.5
1129.2
1116.4
1105.6
1092.6
1077.5
1059.9
1041.0
1013.2
308.15 K
1163.6
1157.1
1148.6
1139.3
1126.7
1115.9
1103.1
1088.1
1070.6

-1

S
-1

TPa
1129.4
1153.1
1179.8
1218.3
1251.5
1293.9
1345.1
1409.7
1483.5
1596.6

TPa
-17.9
-33.9
-48.1
-63.5
-71.8
-77.9
-78.7
-71.2
-54.0
0.0

1088.5
1106.8
1129.6
1155.4
1192.0
1224.4
1265.2
1314.8
1376.3
1447.5
1555.0

0.0
-16.9
-32.2
-45.6
-60.8
-68.2
-74.0
-74.3
-67.7
-50.8
0.0

1067.1
1084.5
1106.6
1131.5
1167.0
1198.1
1237.3
1285.0
1344.2
1412.3
1514.4

0.0
-16.2
-30.7
-43.4
-57.5
-64.7
-70.2
-70.3
-63.7
-47.7
0.0

1084.2
1108.2
1142.5
1172.5
1210.2
1256.2
1313.2
1378.3
1475.6

0.0
-15.4
-29.2
-41.3
-54.7
-61.5
-66.6
-66.6
-60.1

A 33 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.16. Continuacin.

x1

VE

-3

0.8785
1.0000

kgm
655.67
645.55

cm mol
-0.111
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

708.07
704.73
701.15
697.18
691.58
686.96
681.13
674.50
666.52
657.89
647.83

0.000
-0.014
-0.080
-0.122
-0.165
-0.184
-0.179
-0.183
-0.155
-0.108
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

710.05
706.71
703.16
699.21
693.62
689.04
683.23
676.64
668.73
660.14
650.15

0.000
-0.009
-0.076
-0.116
-0.153
-0.176
-0.168
-0.172
-0.149
-0.102
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

712.00
708.66
705.14
701.20
695.65
691.10
685.30
678.76
670.90
662.34
652.42

0.000
-0.003
-0.071
-0.109
-0.147
-0.170
-0.158
-0.167
-0.145
-0.096
0.000

0.0000
0.0752
0.1569
0.2410
0.3520

713.96
710.62
707.12
703.22
697.68

0.000
0.001
-0.067
-0.106
-0.138

A 34 | A. GAYOL

u
-1

-1

ms
1051.9
1024.6
305.65 K
1173.6
1167.0
1158.6
1149.4
1136.9
1126.3
1113.5
1098.7
1081.4
1062.9
1035.7
303.15 K
1183.6
1177.1
1168.6
1159.6
1147.2
1136.6
1124.0
1109.3
1092.2
1073.9
1047.1
300.65 K
1193.6
1187.1
1178.8
1169.7
1157.4
1147.0
1134.5
1119.9
1103.0
1084.9
1058.4
298.15 K
1203.7
1197.2
1188.9
1180.0
1167.8

-1

S
-1

TPa
1142.5
1172.5

TPa
-45.1
0.0

1025.4
1041.9
1062.6
1085.7
1118.8
1147.5
1184.2
1228.2
1282.9
1345.5
1439.0

0.0
-14.6
-27.7
-39.3
-52.2
-58.8
-63.5
-63.8
-57.7
-43.3
0.0

1005.3
1021.2
1041.3
1063.6
1095.5
1123.3
1158.4
1201.1
1253.5
1313.4
1402.8

0.0
-14.0
-26.4
-37.5
-49.7
-55.9
-60.5
-60.4
-54.7
-41.1
0.0

985.8
1001.4
1020.7
1042.3
1073.0
1099.9
1133.8
1174.7
1225.2
1282.8
1368.3

0.0
-13.2
-25.2
-35.7
-47.4
-53.3
-57.6
-57.6
-52.0
-39.0
0.0

966.7
981.8
1000.5
1021.3
1051.1

0.0
-12.6
-23.9
-34.0
-45.1

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.16. Continuacin.
x1

VE

-3

0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

kgm
693.17
687.39
680.90
673.07
664.56
654.70

cm mol
-0.165
-0.151
-0.161
-0.140
-0.092
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

715.90
712.55
709.10
705.21
699.69
695.21
689.45
683.01
675.22
666.76
656.96

0.000
0.009
-0.064
-0.101
-0.132
-0.160
-0.141
-0.155
-0.135
-0.089
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

717.84
714.51
711.08
707.21
701.70
697.26
691.51
685.11
677.38
668.95
659.21

0.000
0.008
-0.063
-0.100
-0.125
-0.156
-0.134
-0.148
-0.132
-0.085
0.000

0.0000
0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

719.79
716.45
713.05
709.20
703.71
699.30
693.57
687.20
679.51
671.13
661.45

0.000
0.016
-0.058
-0.094
-0.117
-0.150
-0.126
-0.141
-0.124
-0.081
0.000

0.0000

721.68

0.000

u
-1

-1

ms
1157.4
1145.1
1130.6
1113.8
1095.9
1069.8
295.65 K
1214.0
1207.4
1199.2
1190.3
1178.2
1168.0
1155.7
1141.3
1124.7
1107.0
1081.4
293.15 K
1224.3
1217.8
1209.6
1200.8
1188.8
1178.6
1166.5
1152.3
1135.8
1118.3
1093.1
290.65 K
1234.9
1228.2
1220.1
1211.4
1199.5
1189.4
1177.3
1163.3
1146.7
1129.6
1106.0
288.15 K
1245.4

-1

S
-1

TPa
1076.9
1109.4
1148.9
1197.6
1253.0
1334.6

TPa
-50.7
-55.0
-54.8
-49.5
-36.9
0.0

947.8
962.7
980.7
1000.9
1029.5
1054.4
1086.0
1123.9
1170.8
1223.9
1301.6

0.0
-11.7
-22.6
-32.2
-42.8
-48.2
-52.0
-51.8
-46.6
-34.8
0.0

929.4
943.7
961.2
980.6
1008.4
1032.4
1062.8
1099.3
1144.4
1195.4
1269.6

0.0
-11.2
-21.5
-30.8
-40.8
-45.9
-49.4
-49.3
-44.2
-32.8
0.0

911.0
925.3
942.1
960.9
987.7
1010.8
1040.2
1075.4
1119.1
1167.8
1235.9

0.0
-10.2
-19.9
-28.4
-37.7
-42.4
-45.4
-45.0
-39.5
-28.6
0.0

893.4

0.0

A 35 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.16. Continuacin.

x1

VE

-3

kgm
718.35
714.96
711.13
705.68
701.27
695.58
689.25
681.60
673.26
663.64

0.0752
0.1569
0.2410
0.3520
0.4375
0.5374
0.6444
0.7620
0.8785
1.0000

cm mol
0.017
-0.054
-0.089
-0.112
-0.140
-0.119
-0.134
-0.120
-0.077
0.000

-1

-1

ms
1238.6
1230.6
1222.1
1210.1
1200.1
1188.1
1174.2
1157.7
1140.8
1118.3

-1

-1

TPa
907.3
923.6
941.6
967.7
990.1
1018.4
1052.3
1094.6
1141.3
1204.9

TPa
-9.5
-18.6
-26.9
-35.4
-39.6
-42.4
-41.8
-36.2
-25.8
0.0

Tabla A.17. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1)+ x2 n-hexano (2) (1- x1- x2) n-heptano (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

T/K
0.0000
0.0000
0.0727
0.0728
0.0734
0.0759
0.0805
0.0815
0.0827
0.0901
0.0966
0.1983
0.2122
0.2151
0.2155
0.2233
0.2234
0.2318
0.2385
0.3651
0.3672
0.3781
0.3886
0.3945

1.0000
0.0000
0.4526
0.7973
0.5097
0.6328
0.1206
0.7188
0.2716
0.2359
0.3409
0.7348
0.6517
0.4927
0.5755
0.4010
0.3101
0.2119
0.1102
0.5748
0.5088
0.4322
0.3507
0.2682

A 36 | A. GAYOL

nD

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

1.36052
1.37410
1.37905
1.36585
1.37556
1.37257
1.38848
1.36899
1.38889
1.38516
1.38188
1.36240
1.36580
1.37273
1.36893
1.37582
1.37944
1.38238
1.38562
1.36074
1.36432
1.36783
1.37106
1.37483

1.36652
1.37952
1.38995
1.37678
1.38654
1.38321
1.39853
1.37975
1.39899
1.39513
1.39230
1.37344
1.37662
1.38306
1.37978
1.38615
1.38938
1.39234
1.39544
1.37180
1.37494
1.37795
1.38109
1.38440

1.37211
1.38512
1.38995
1.37678
1.38654
1.38321
1.39853
1.37975
1.39899
1.39513
1.39230
1.37344
1.37662
1.38306
1.37978
1.38615
1.38938
1.39234
1.39544
1.37180
1.37494
1.37795
1.38109
1.38440

1.37777
1.39027
1.39432
1.38269
1.39154
1.38860
1.40384
1.38528
1.40359
1.40410
1.39368
1.38030
1.38311
1.38884
1.38605
1.39200
1.39472
1.39815
1.40097
1.37744
1.38071
1.38374
1.38723
1.39111

0.00000 0.00000 0.00000

0.00000 0.00000 0.00000
0.00353 0.00403 0.00412
0.00176 0.00178 0.00160
0.00196 0.00269 0.00250
0.00317 0.00347 0.00309
0.00229 0.00345 0.00279
0.00268 0.00251 0.00252
0.00780 -0.00167 0.00801
0.00321 0.00398 0.00337
0.00369 0.00449 0.00407
0.00169 0.00163 0.00182
0.00293 0.00308 0.00304
0.00472 0.00463 0.00471
0.00368 0.00422 0.00400
0.00512 0.00589 0.00532
0.00573 0.00634 0.00575
0.00578 0.00688 0.00605
0.00594 0.00692 0.00630
0.00195 0.00218 0.00254
0.00344 0.00361 0.00374
0.00488 0.00514 0.00486
0.00586 0.00616 0.00594
0.00715 0.00747 0.00696

0.00000
0.00000
0.00348
0.00210
0.00243
0.00326
0.00348
0.00274
0.00782
0.00759
0.00057
0.00338
0.00433
0.00547
0.00515
0.00626
0.00628
0.00717
0.00726
0.00311
0.00451
0.00575
0.00728
0.00896

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.17. Continuacin.

x1

x2

nD

T/K
0.4048
0.4976
0.5100
0.5159
0.5398
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8501
0.8668
0.9144
1.0000

0.1848
0.4480
0.3785
0.3120
0.0805
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.1091
0.0524
0.0476
0.0000

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

1.37735
1.35941
1.36276
1.36642
1.37645
1.36189
1.36511
1.36851
1.37138
1.35674
1.36402
1.36703
1.35611
1.35956
1.36279
1.35546
1.35845
1.35481
1.35031

1.38749
1.37031
1.37374
1.37658
1.38503
1.37210
1.37550
1.37853
1.38122
1.37098
1.37370
1.37682
1.36608
1.36919
1.37229
1.36488
1.36353
1.35944
1.35477

1.38749
1.37031
1.37374
1.37658
1.38503
1.37210
1.37550
1.37853
1.38122
1.37098
1.37370
1.37682
1.36608
1.36919
1.37229
1.36488
1.36807
1.36403
1.35922

1.39403
1.37538
1.37917
1.38158
1.39158
1.37770
1.38070
1.38375
1.38664
1.37634
1.37921
1.38222
1.37127
1.37429
1.37746
1.37054
1.37302
1.36863
1.36345

0.00735
0.00217
0.00375
0.00546
0.00885
0.00430
0.00580
0.00744
0.00855
0.00012
0.00608
0.00764
0.00219
0.00423
0.00604
0.00226
0.00410
0.00236
0.0000

0.00833
0.00254
0.00431
0.00591
0.00959
0.00454
0.00626
0.00802
0.00934
0.00488
0.00636
0.00822
0.00282
0.00469
0.00665
0.00277
0.00472
0.00250
0.0000

0.00793
0.00293
0.00476
0.00580
0.00815
0.00482
0.00664
0.00809
0.00918
0.00488
0.00645
0.00828
0.00276
0.00460
0.00642
0.00247
0.00464
0.00253
0.0000

0.00986
0.00312
0.00539
0.00608
0.01025
0.00576
0.00726
0.00882
0.01019
0.00570
0.00750
0.00930
0.00346
0.00527
0.00724
0.00373
0.00526
0.00282
0.0000

Tabla A.18. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 etanol (1)+ x2 n-hexano (2) (1- x1-x2 ) n-heptano (3) en el intervalo de
temperaturas (323.15-288.15) K.

x1

x2

VE

-3

kgm
0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155

636.2
662.4
649.1
662.6
657.4
667.6
653.6

cm mol

u
-1

318.15 K
0.0000
0.0000
0.4558
0.4310
0.5353
0.6689
0.5357

-1

-1

ms

TPa

1067.5
979.3
983.8
1012.3
999.5
1026.4
987.9

1638.60
1387.80
1591.46
1472.71
1522.31
1421.58
1567.54

S
TPa

-1

0.00
0.00
73.01
67.76
75.21
70.30
86.18

A 37 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.18. Continuacin.

x1

0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230

A 38 | A. GAYOL

x2

0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371

VE

kgm

-3

cm mol

664.6
675.3
674.6
683.7
672.2
679.8
689.4
692.9
695.6
698.4
701.2
709.1
708.6
714.6
716.9
719.1
727.4
747.6
753.6
756.9
754.2
754.5
755.5
768.4

638.5
664.5
651.5
664.9
659.7
669.8
655.9
667.0
677.0
676.9
686.1
674.5
682.1
691.7
695.2
697.8

u
-1

-1

-1

ms

TPa

0.3775
-0.4554
0.3906
-0.4924
0.6244
0.6041
0.3838
0.4951
0.6043
0.6069
0.3859
0.1722
0.5318
0.3760
0.4393
0.4641
0.3151
0.1953
0.1810
-0.0794
0.1814
0.1567
0.1317
0.0000

984.0
1004.3
1012.9
1024.3
1009.0
1002.7
1022.4
1011.0
1017.5
1023.7
1008.8
1024.7
1030.3
1021.1
1026.0
1032.0
1035.1
1052.5
1060.6
1063.9
1060.0
1064.4
1063.5
1067.5

1553.75
1468.08
1444.71
1393.95
1460.95
1462.96
1387.42
1411.80
1388.56
1366.09
1401.21
1342.95
1329.32
1341.89
1325.04
1305.48
1282.95
1207.30
1179.49
1167.08
1179.98
1169.74
1170.14
1124.10

315.65 K
0.0000
0.0000
0.4330
0.4120
0.5147
0.6553
0.5123
0.3466
-0.4923
0.3666
-0.5349
0.6030
0.5825
0.3667
0.4792
0.5874

990.4
1053.8
995.1
1023.1
1010.5
1037.2
999.0
995.1
1015.2
1023.6
1035.1
1019.7
1013.4
1033.0
1021.3
1027.7

1596.60
1355.10
1550.08
1436.73
1484.41
1387.58
1527.48
1513.84
1431.52
1409.67
1360.13
1425.62
1427.50
1354.81
1378.89
1356.69

S
TPa

-1

134.76
93.05
105.24
85.35
110.07
133.44
117.52
133.18
130.67
127.56
134.66
110.69
114.52
115.36
114.50
110.21
89.34
52.50
39.78
24.59
39.67
28.60
31.92
0.00

0.00
0.00
68.69
64.61
71.67
67.10
81.72
127.84
87.83
100.21
80.38
105.15
127.30
111.98
127.44
125.17

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

700.7
703.5
711.4
710.9
716.8
719.1
721.4
729.6
749.8
755.8
759.1
756.4
756.7
757.7
770.6

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157

640.9
666.2
653.9
667.2
662.1
672.0
658.4
669.5
680.2
679.3
688.6
676.9
684.5
694.0
697.6
700.2
703.0
705.9
713.7
713.2
719.2
721.4
723.7
731.9
752.1
758.0
761.3
758.6

cm mol

u
-1

0.5918
0.3737
0.1617
0.5197
0.3688
0.4303
0.4540
0.3093
0.1936
0.1794
-0.0797
0.1782
0.1567
0.1307
0.0000
313.15 K
0.0000
0.0000
0.4401
0.3811
0.5364
0.5296
0.5292
0.2996
-0.6579
0.1736
-0.9310
0.4623
0.4555
0.0151
0.2930
0.3282
0.2406
0.2860
-0.0783
0.1909
0.2811
0.2570
0.1862
0.2102
0.1376
0.0731
-0.1411
0.0977

-1

-1

S
TPa

-1

ms

TPa

1033.8
1019.0
1034.5
1040.2
1030.8
1035.7
1041.6
1044.5
1061.4
1069.4
1072.6
1068.8
1073.2
1072.2
1084.3

1335.27
1368.95
1313.28
1300.09
1312.81
1296.36
1277.60
1256.11
1183.64
1156.93
1144.91
1157.16
1147.42
1147.87
1103.60

122.39
128.93
106.23
109.85
111.12
110.05
105.99
85.96
50.65
38.43
23.71
38.06
27.51
30.77
0.00

1001.7
1064.3
1006.2
1033.9
1021.4
1047.9
1010.0
1006.1
1026.1
1034.3
1045.9
1030.5
1023.8
1043.4
1031.5
1037.9
1043.9
1029.0
1044.4
1050.1
1040.5
1045.2
1051.1
1053.8
1070.3
1078.0
1081.2
1077.4

1555.00
1324.30
1510.42
1401.93
1447.49
1354.95
1488.82
1475.35
1396.03
1375.84
1327.57
1391.19
1393.60
1323.59
1347.32
1325.75
1305.33
1337.91
1284.31
1271.48
1284.25
1268.72
1250.56
1230.17
1160.69
1135.12
1123.40
1135.48

0.00
0.00
65.56
61.44
68.21
63.80
78.00
121.66
82.75
95.27
75.39
100.10
121.92
106.72
122.24
119.73
117.11
123.78
101.69
104.92
106.77
105.94
101.81
82.85
48.88
37.16
22.88
36.96

A 39 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.9541
0.9558
1.0000

0.0197
0.0099
0.0000

758.9
759.9
772.8

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

643.2
668.8
656.3
669.5
664.5
674.3
660.8
671.9
682.7
681.6
690.7
679.2
686.9
696.3
699.9
702.5
705.3
708.2
716.1
715.5
721.5
723.7
725.9
734.2
754.3
760.2
763.6
760.9
761.1
762.2
775.0

0.0000
0.0000
0.1978
0.2083

1.0000
0.0000
0.7289
0.2874

645.5
671.0
658.7
671.8

A 40 | A. GAYOL

cm mol

u
-1

0.0874
0.0399
0.0000
310.65 K
0.0000
0.0000
0.3908
0.3689
0.4687
0.6334
0.4674
0.2851
-0.5690
0.3214
-0.5581
0.5587
0.5436
0.3349
0.4470
0.5537
0.5567
0.3492
0.1374
0.4924
0.3508
0.4125
0.4340
0.2972
0.1874
0.1734
-0.0816
0.1734
0.1522
0.1254
0.0000
308.15 K
0.0000
0.0000
0.3721
0.3505

-1

-1

S
TPa

-1

ms

TPa

1081.8
1080.9
1092.7

1125.79
1126.22
1083.70

26.50
29.61
0.00

1013.2
1075.0
1017.3
1044.7
1032.3
1058.6
1021.1
1017.2
1036.9
1045.0
1056.5
1041.1
1034.3
1053.8
1041.6
1047.9
1053.9
1038.9
1054.2
1059.
1050.0
1054.7
1060.6
1063.0
1079.0
1086.6
1089.8
1086.0
1090.4
1089.4
1101.0

1514.40
1293.60
1472.05
1368.32
1412.03
1323.32
1451.36
1438.31
1362.21
1343.26
1297.00
1358.25
1360.81
1293.27
1316.76
1296.10
1276.49
1308.11
1256.53
1244.06
1256.90
1242.11
1224.50
1205.14
1138.61
1113.90
1102.59
1114.29
1104.81
1105.34
1064.40

0.00
0.00
62.85
59.00
65.58
61.20
74.70
116.20
78.77
91.11
72.01
96.03
117.03
101.93
117.47
115.03
112.45
119.21
97.77
100.66
102.99
102.25
98.08
80.02
47.39
35.91
22.14
35.76
25.54
28.64
0.00

1024.6
1085.6
1028.5
1055.5

1475.70
1264.40
1435.12
1335.91

0.00
0.00
60.02
56.39

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

666.8
676.5
663.1
674.4
685.2
683.9
689.8
681.5
689.2
698.5
702.2
704.8
707.6
710.5
718.4
717.7
723.8
726.0
728.2
736.5
756.5
762.4
765.8
763.1
763.3
764.4
777.2

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072.
0.1371

647.8
673.1
661.1
674.1
669.1
678.6
665.5
676.8
687.7
686.2
692.0
683.8
691.5
700.8
704.5
707.1

cm mol

u
-1

0.4488
0.6255
0.4495
0.2563
-0.6098
0.3019
-0.0460
0.5388
0.5253
0.3231
0.4343
0.5397
0.5403
0.3398
0.1272
0.4802
0.3445
0.4048
0.4248
0.2922
0.1866
0.1711
-0.0817
0.1705
0.1508
0.1239
0.0000
305.65 K
0.0000
0.0000
0.3514
0.3334
0.4303
0.6183
0.4301
0.2266
-0.6514
0.2839
-0.0442
0.5205
0.5088
0.3104
0.4197
0.5254

-1

-1

S
TPa

-1

ms

TPa

1043.3
1069.4
1032.1
1028.2
1047.8
1055.7
1067.4
1051.8
1044.9
1064.2
1051.9
1058.1
1064.0
1048.9
1064.1
1069.8
1059.7
1064.3
1070.2
1072.4
1087.8
1095.3
1098.5
1094.7
1099.2
1098.1
1109.4

1377.64
1292.65
1415.50
1402.36
1329.13
1311.69
1272.38
1326.14
1328.90
1263.88
1286.95
1267.12
1248.22
1279.11
1229.26
1217.31
1230.21
1215.90
1198.96
1180.59
1116.87
1093.09
1082.13
1093.35
1084.10
1084.83
1045.40

62.59
58.30
71.55
110.55
74.32
86.83
73.50
91.64
112.00
97.17
112.60
110.20
107.59
114.67
93.65
96.41
99.22
98.37
94.28
77.14
45.83
34.70
21.39
34.44
24.49
27.67
0.00

1035.7
1096.3
1039.6
1066.4
1054.2
1080.1
1043.2
1039.2
1058.7
1066.5
1078.6
1062.5
1055.3
1074.7
1062.1
1068.3

1439.00
1236.10
1399.51
1304.38
1344.56
1262.94
1380.79
1367.97
1297.24
1281.13
1242.19
1295.28
1298.29
1235.39
1258.23
1239.19

0.00
0.00
56.90
53.54
59.59
55.45
68.04
105.16
69.96
82.59
68.60
87.48
107.25
92.52
107.93
105.61

A 41 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

709.8
712.8
720.6
720.0
726.1
728.2
730.4
738.7
758.7
764.6
768.0
765.3
765.5
766.5
779.4

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095

650.1
675.3
663.4
676.4
671.5
680.8
667.8
679.3
690.3
688.5
694.2
686.1
693.9
703.0
706.8
709.4
712.1
715.2
722.9
722.3
728.3
730.5
732.7
741.0
760.9
766.8

A 42 | A. GAYOL

cm mol

u
-1

0.5256
0.3285
0.1173
0.4691
0.3374
0.3980
0.4153
0.2878
0.1849
0.1687
-0.0827
0.1683
0.1493
0.1224
0.0000
303.15 K
0.0000
0.0000
0.3368
0.3183
0.4139
0.6121
0.4141
0.1951
-0.6953
0.2696
-0.0508
0.5044
0.4934
0.3003
0.4076
0.5136
0.5116
0.3200
0.1083
0.4577
0.3301
0.3913
0.4073
0.2837
0.1831
0.1657

-1

-1

S
TPa

-1

ms

TPa

1074.1
1058.9
1073.9
1079.7
1069.4
1073.9
1079.7
1081.7
1096.6
1104.0
1107.1
1103.4
1107.9
1106.8
1117.8

1220.99
1250.94
1203.08
1191.35
1204.26
1190.67
1174.22
1156.89
1095.85
1072.94
1062.21
1073.19
1064.16
1064.92
1026.90

103.05
110.07
89.88
92.27
95.42
94.74
90.63
74.42
44.40
33.62
20.63
33.37
23.65
26.78
0.00

1047.1
1107.0
1050.8
1077.3
1065.2
1090.9
1054.3
1050.3
1069.6
1077.3
1089.4
1073.3
1065.9
1085.2
1072.3
1078.5
1084.2
1068.9
1083.8
1089.6
1079.1
1083.5
1089.3
1091.1
1105.5
1112.8

1402.90
1208.40
1364.97
1273.85
1312.47
1234.05
1346.98
1334.31
1266.26
1251.42
1213.62
1265.05
1268.42
1207.78
1230.25
1211.93
1194.47
1223.63
1177.41
1166.13
1178.93
1165.90
1150.10
1133.64
1075.19
1053.00

0.00
0.00
54.30
51.15
57.04
52.88
64.91
100.01
66.01
78.72
64.82
83.45
102.79
88.32
103.58
101.29
98.82
105.93
86.22
88.47
91.87
91.21
87.24
71.80
43.02
32.44

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.9530
0.9535
0.9541
0.9558
1.0000

0.0239
0.0157
0.0197
0.0099
0.0000

770.2
767.5
767.7
768.8
781.5

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

652.4
677.4
665.8
678.6
673.7
683.0
670.1
681.7
692.8
690.7
696.4
688.4
696.1
705.2
709.1
711.6
714.4
717.4
725.2
724.5
730.6
732.7
734.9
743.2
763.1
769.0
772.4
769.7
769.9
770.9
783.7

0.0000
0.0000
0.1978
0.2083
0.2164

1.0000
0.0000
0.7289
0.2874
0.4640

654.7
679.5
668.1
680.9
676.0

cm mol

u
-1

-0.0835
0.1662
0.1479
0.1206
0.0000
300.65 K
0.0000
0.0000
0.3200
0.3033
0.3965
0.6009
0.3966
0.1643
-0.7420
0.2577
-0.0612
0.4884
0.4775
0.2927
0.3949
0.5011
0.4980
0.3098
0.0990
0.4471
0.3234
0.3833
0.3989
0.2785
0.1811
0.1626
-0.0847
0.1633
0.1460
0.1180
0.0000
298.15 K
0.0000
0.0000
0.3038
0.2899
0.3806

-1

-1

S
TPa

-1

ms

TPa

1115.8
1112.1
1116.6
1115.4
1126.2

1042.77
1053.43
1044.56
1045.43
1008.70

20.04
32.38
22.85
25.99
0.00

1058.4
1117.6
1062.0
1088.1
1076.2
1101.7
1065.4
1061.4
1080.4
1088.0
1100.3
1084.0
1076.5
1095.7
1082.5
1088.6
1094.3
1079.0
1093.7
1099.4
1088.7
1093.1
1098.8
1100.4
1114.3
1121.4
1124.5
1120.8
1125.3
1124.1
1134.6

1368.30
1181.70
1331.76
1244.46
1281.39
1206.10
1314.56
1302.11
1236.42
1222.99
1185.91
1236.09
1239.54
1181.14
1203.37
1185.64
1168.84
1197.19
1152.80
1141.79
1154.61
1142.11
1126.82
1111.22
1055.23
1033.93
1023.84
1034.27
1025.62
1026.43
991.10

0.00
0.00
51.74
48.83
54.35
50.30
61.96
95.21
62.18
75.17
61.02
79.73
98.37
84.25
99.48
97.11
94.69
101.83
82.85
84.82
88.55
87.92
83.97
69.30
41.67
31.50
19.32
31.37
22.09
25.06
0.00

1069.8
1128.4
1073.2
1099.0
1087.3

1334.50
1155.70
1299.52
1215.93
1251.20

0.00
0.00
49.47
46.73
51.90

A 43 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

685.2
672.4
684.1
695.4
692.9
698.6
690.7
698.4
707.4
711.4
713.9
716.6
719.7
727.5
726.7
732.9
735.0
737.2
745.4
765.3
771.2
774.5
771.8
772.1
773.1
785.8

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760

656.9
681.6
670.4
683.1
678.3
687.4
674.7
683.4
698.0
695.0
700.7
690.0
700.7
709.4

A 44 | A. GAYOL

cm mol

u
-1

0.5881
0.3822
0.1291
-0.7999
0.2533
-0.0648
0.4727
0.4633
0.2901
0.3839
0.4889
0.4854
0.3021
0.0895
0.4371
0.3164
0.3771
0.3909
0.2754
0.1801
0.1610
-0.0845
0.1614
0.1448
0.1161
0.0000
295.65 K
0.0000
0.0000
0.2906
0.2767
0.3658
0.5716
0.3697
0.5868
-0.8544
0.2658
-0.0639
0.9248
0.4509
0.2980

-1

-1

S
TPa

-1

ms

TPa

1112.6
1076.5
1072.5
1091.4
1098.7
1111.2
1094.8
1087.1
1106.2
1092.8
1098.9
1104.4
1089.0
1103.6
1109.4
1098.5
1102.7
1108.5
1109.7
1123.2
1130.2
1133.2
1129.5
1134.0
1132.8
1143.1

1178.95
1283.06
1270.69
1207.17
1195.30
1159.12
1207.95
1211.51
1155.27
1177.05
1159.99
1143.93
1171.57
1128.57
1117.96
1130.72
1118.83
1104.00
1089.34
1035.62
1015.07
1005.36
1015.43
1007.07
1007.92
973.80

47.90
59.25
90.59
58.35
71.80
57.57
76.25
94.28
80.46
95.46
93.12
90.81
98.09
79.43
81.26
85.25
84.73
80.77
66.96
40.36
30.45
18.74
30.36
21.39
24.32
0.00

1081.4
1139.2
1084.4
1110.0
1098.4
1123.5
1087.7
1072.4
1102.4
1109.6
1122.3
1094.7
1097.7
1116.7

1301.70
1130.40
1268.39
1188.15
1221.95
1152.38
1252.56
1272.13
1178.80
1168.51
1132.94
1209.31
1184.37
1130.21

0.00
0.00
47.47
44.68
49.64
45.44
56.76
118.12
54.74
68.70
54.17
101.66
90.49
76.96

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.18 Continuacin.

x1

x2

VE

-3

kgm
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

710.7
713.2
718.8
719.0
729.7
726.0
732.2
731.4
739.3
741.8
767.5
773.3
776.7
774.0
774.2
775.3
788.0

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097

659.2
683.7
669.7
685.3
680.6
689.6
677.0
685.9
697.3
694.3
702.8
692.2
703.0
711.2
715.9
718.3
721.0
721.3
731.9
731.1
737.3
739.4
741.5
746.9

cm mol

u
-1

0.7460
0.8476
0.4743
0.6318
0.0829
0.7622
0.6143
0.9795
0.3846
0.8284
0.1782
0.1596
-0.0847
0.1602
0.1441
0.1151
0.0000
293.15 K
0.0000
0.0000
0.8007
0.2615
0.3514
0.5534
0.3557
0.5453
-0.4046
0.7172
-0.0519
0.9052
0.4395
0.3491
0.3625
0.4677
0.4625
0.6204
0.0753
0.4193
0.3058
0.3658
0.3772
0.5426

-1

-1

S
TPa

-1

ms

TPa

1092.7
1098.8
1114.6
1088.9
1113.6
1109.3
1098.4
1092.9
1118.1
1100.2
1132.
1139.0
1142.0
1138.3
1142.8
1141.2
1151.6

1178.36
1161.28
1119.62
1172.86
1105.06
1119.19
1131.95
1144.68
1081.80
1113.70
1016.36
996.64
987.16
997.01
988.85
989.82
956.80

118.55
115.56
87.08
120.77
76.27
102.32
106.65
130.25
77.78
110.46
39.05
29.51
18.11
29.44
20.71
23.66
0.00

1093.1
1150.2
1084.4
1121.2
1109.6
1134.6
1099.1
1083.7
1102.4
1109.6
1133.4
1105.7
1108.5
1127.5
1113.5
1119.6
1125.0
1099.1
1123.7
1129.5
1118.2
1122.2
1127.9
1119.2

1269.70
1105.50
1269.60
1160.62
1193.36
1126.38
1222.64
1241.31
1179.89
1169.59
1107.57
1181.52
1157.66
1106.01
1126.50
1110.51
1095.73
1147.54
1081.86
1071.99
1084.64
1073.88
1059.87
1068.82

0.00
0.00
77.15
42.40
47.49
43.17
54.24
112.85
80.14
93.08
51.22
97.48
86.71
73.99
88.11
85.62
83.47
116.48
73.12
74.66
79.18
78.85
74.81
84.45

A 45 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.18. Continuacin.

x1

x2

VE

-3

kgm
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

769.6
775.5
778.8
776.1
776.4
780.3
790.1

0.0000
0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

1.0000
0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

661.4
685.8
677.9
687.5
682.8
691.8
682.2
691.2
697.6
698.6
704.7
697.4
708.1
712.5
718.1
720.5
723.2
723.5
736.9
733.3
739.5
741.6
743.7
752.0
771.8
774.8
781.0
775.4
778.5
779.5
792.3

0.0000

1.0000

663.6

A 46 | A. GAYOL

cm mol

u
-1

0.1759
0.1563
-0.0860
0.1574
0.1426
-0.1145
0.0000
290.65 K
0.0000
0.0000
-0.2322
0.2518
0.3402
0.5417
-0.1473
0.0677
-0.1145
0.3803
-0.0172
0.4320
0.0369
0.4638
0.3565
0.4595
0.4527
0.6114
-0.2426
0.4126
0.3027
0.3613
0.3726
0.2659
0.1760
0.3866
-0.0839
0.3862
0.1425
0.1131
0.0000
288.15 K
0.0000

-1

-1

S
TPa

-1

ms

TPa

1141.3
1148.0
1150.9
1147.3
1151.8
1159.2
1160.3

997.44
978.42
969.17
978.68
970.82
953.69
940.00

37.84
28.56
17.46
28.41
19.98
4.76
0.00

1106.0
1161.3
1118.6
1132.2
1120.9
1145.6
1121.6
1106.3
1135.6
1131.6
1154.7
1127.7
1129.9
1138.2
1123.8
1130.0
1135.4
1109.4
1143.8
1139.8
1128.1
1132.0
1137.7
1138.4
1150.5
1148.0
1159.9
1147.4
1160.9
1159.3
1169.1

1235.90
1081.20
1178.96
1134.61
1165.51
1101.33
1165.15
1182.17
1111.50
1117.73
1064.16
1127.42
1106.15
1083.23
1102.54
1086.75
1072.48
1122.82
1037.20
1049.58
1062.46
1052.15
1038.75
1026.01
979.03
979.19
951.72
979.45
953.07
954.43
923.40

0.00
0.00
16.21
41.81
46.68
41.55
25.12
80.01
36.40
64.54
29.97
67.15
58.45
72.23
85.72
82.66
80.30
113.04
48.49
71.64
76.97
76.49
72.50
60.51
37.04
46.41
17.20
46.28
19.38
22.53
0.00

1118.3

1205.00

0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.18. Continuacin.

x1

x2

0.0000
0.1978
0.2083
0.2164
0.2275
0.2306
0.3543
0.3644
0.3707
0.3794
0.3800
0.5051
0.5194
0.6111
0.6230
0.6286
0.6920
0.7098
0.7119
0.7759
0.7821
0.7858
0.8407
0.9295
0.9499
0.9530
0.9535
0.9541
0.9558
1.0000

0.0000
0.7289
0.2874
0.4640
0.0935
0.6155
0.4969
0.3322
0.1971
0.0832
0.2523
0.2987
0.0760
0.2072
0.1371
0.0657
0.2442
0.1261
0.0588
0.1728
0.1155
0.0586
0.1097
0.0483
0.0095
0.0239
0.0157
0.0197
0.0099
0.0000

VE

kgm

-3

cm mol

-1

687.9
677.9
690.3
685.7
694.6
682.2
689.5
697.6
701.2
704.7
700.2
708.1
715.2
720.9
723.3
726.0
729.3
736.9
736.1
742.3
744.4
746.5
754.8
774.6
780.4
783..8
781.1
781.3
782.3
794.4

0.0000
-0.1571
-0.1456
-0.0807
0.1887
-0.1061
0.2566
-0.2100
-0.0984
-0.0500
-0.0899
-0.1796
-0.0488
-0.2486
-0.1052
-0.0815
-0.3336
-0.4934
-0.0950
-0.2311
-0.1305
-0.0855
-0.1662
-0.0748
-0.0240
-0.2699
-0.0204
-0.0342
-0.0558
0.0000

-1

-1

ms

TPa

1172.3
1118.6
1143.0
1132.0
1156.7
1121.6
1117.6
1135.6
1142.5
1154.7
1138.4
1129.9
1148.9
1134.0
1139.9
1145.
1129.6
1143.8
1150.1
1138.0
1141.7
1147.3
1148.0
1159.3
1165.7
1168.6
1165.1
1169.8
1168.1
1178.2

1057.70
1178.96
1108.63
1137.99
1076.02
1165.15
1161.03
1111.50
1092.34
1064.16
1101.90
1106.15
1059.18
1078.66
1063.79
1049.65
1074.44
1037.20
1026.97
1040.18
1030.58
1017.50
1005.21
960.57
942.85
934.15
943.06
935.25
936.76
906.80

TPa

-1

0.00
43.74
40.03
44.60
38.87
51.58
83.60
59.85
61.55
51.47
64.38
80.67
68.66
82.65
79.91
77.12
85.20
68.03
68.05
74.11
73.88
69.76
58.22
36.01
27.08
16.74
26.93
18.62
21.85
0.00

Tabla A.19. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1)+ x2 n-hexano (2) (1- x1-x2) n-octano (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

T/K
0.0000
0.0000
0.0747

1.0000
0.0000
0.5303

nD

nD

318.15

308.15

298.15

288.15

1.36052
1.38489
1.37137

1.36652
1.39058
1.37672

1.37211 1.37777
1.39551 1.40040
1.38212 1.38779

318.15

308.15

298.15

288.15

0.00000
0.00000
0.00199

0.00000
0.00000
0.00158

0.00000
0.00000
0.00173

0.00000
0.00000
0.00216

A 47 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.19. Continuacin.

x1

x2

T/K

nD

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

0.00038
0.00163
0.00543
0.00144
0.00170
0.00080
0.00003
0.00080
0.00393
0.00128
0.00399
0.00477
0.00324
0.00428
0.00234
0.00236
0.00219
0.00618
0.00390
0.00550
0.00483
0.00584
0.00274
0.00398
0.00507
0.00671
0.00000
0.00276
0.00405
0.00506
0.00073
0.00292
0.00405
0.00149
0.00297
0.00122
0.00138
0.00000

0.00018
0.00144
0.00508
0.00115
0.00128
0.00068

0.00058
0.00171
0.00490
0.00149
0.00168
0.00125

0.00078
0.00178
0.00520
0.00186
0.00199
0.00145

0.00007
0.00125
0.00269
0.00141
0.00354
0.00428
0.00275
0.00416
0.00192
0.00272
0.00409
0.00500
0.00407
0.00577
0.00492
0.00607
0.00311
0.00408
0.00512
0.00638
0.00071
0.00307
0.00436
0.00533
0.00141
0.00034
0.00420
0.00179
0.00312
0.00154
0.00163
0.00000

0.00143 0.00072
0.00072 0.00054
0.00342 0.00346
0.00180 0.00190
0.00361 0.00410
0.00405 0.00486
0.00252 0.00360
0.00440 0.00450
0.00197 0.00239
0.00293 0.00311
0.00423 0.00456
0.00490 0.00537
0.00454 0.00287
0.00569 0.00577
0.00533 0.00540
0.00583 0.00610
0.00378 0.00379
0.00477 0.00461
0.00557 0.00570
0.00696 0.00730
0.00196 -0.00018
0.00366 0.00405
0.00495 0.00518
0.00699 0.00645
0.00217 0.00054
0.00348 0.00387
0.00483 0.00510
0.00209 0.00247
0.00351 0.00366
0.00185 0.00204
0.00116 0.00057
0.00000 0.00000

0.0811
0.0835
0.0845
0.0875
0.0898
0.0935

0.0388
0.6090
0.5639
0.6916
0.1164
0.7681

1.38152
1.36879
1.37365
1.36645
1.38065
1.36373

1.38692
1.37438
1.37906
1.37195
1.38584
1.36943

1.39224
1.37994
1.38415
1.37764
1.39121
1.37539

1.39730
1.38531
1.38971
1.38337
1.39644
1.38101

0.1014
0.1099
0.1476
0.2034
0.2153
0.2198
0.2207
0.2306
0.2728
0.3658
0.3752
0.3797
0.3814
0.3859
0.5142
0.5230
0.6166
0.6239
0.6315
0.6489
0.6588
0.7113
0.7148
0.7260
0.7783
0.7877
0.7987
0.8470
0.8570
0.9069
0.9486
1.0000

0.8477
0.8448
0.0690
0.7280
0.3887
0.2970
0.5573
0.1027
0.1103
0.4997
0.3455
0.2619
0.4134
0.1811
0.2357
0.1566
0.2732
0.2062
0.1412
0.0578
0.2874
0.1895
0.1287
0.0638
0.1759
0.1177
0.0586
0.1086
0.0542
0.0520
0.0254
0.0000

1.36069
1.36130
1.38203
1.36139
1.37196
1.37482
1.36691
1.37869
1.37511
1.36242
1.36568
1.37155
1.36552
1.37263
1.36619
1.36883
1.35965
1.36227
1.36468
1.36775
1.35510
1.35843
1.36108
1.36329
1.35441
1.35770
1.35989
1.35444
1.35690
1.35348
1.35285
1.35031

1.36662
1.36757
1.38632
1.36719
1.37705
1.37984
1.37202
1.38401
1.38007
1.36818
1.37292
1.37568
1.37104
1.37817
1.37141
1.37415
1.36503
1.36735
1.36969
1.37233
1.36078
1.36362
1.36624
1.36837
1.35988
1.35988
1.36477
1.35942
1.36170
1.35839
1.35763
1.35477

1.37342
1.37247
1.39195
1.37289
1.38221
1.38463
1.37698
1.38914
1.38500
1.37347
1.37804
1.38050
1.37653
1.38296
1.37666
1.37869
1.37052
1.37281
1.37486
1.37757
1.36683
1.36892
1.37151
1.37466
1.36531
1.36765
1.36998
1.36432
1.36665
1.36323
1.36165
1.35922

1.37819
1.37776
1.39684
1.37831
1.38775
1.39041
1.38323
1.39405
1.39021
1.37868
1.38328
1.38581
1.37982
1.38781
1.38146
1.38363
1.37522
1.37729
1.37957
1.38241
1.36937
1.37388
1.37625
1.37858
1.36820
1.37250
1.37466
1.36911
1.37117
1.36775
1.36534
1.36345

A 48 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.20. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 Etanol (1)+ x2 n-hexano (2) (1- x1-x2 ) n-octano (3) en el intervalo de
temperaturas (323.15-288.15) K.

x1

x2

VE

-3

kgm
0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

636.2
682.4
670.1
679.1
683.5
690.9
668.1
677.1
681.8
671.5
691.0
694.4
694.3
698.9
703.0
708.3
711.5
716.4
720.9
725.2
730.4
734.1
744.1
768.4

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566

638.5
684.4
672.3
681.1
685.7
693.1
670.4
679.4
684.1
673.8
693.2
696.6

cm mol

u
-1

318.15 K
0.0000
0.0000
0.5851
0.5375
-0.4044
0.4582
-0.6113
0.5809
0.5810
0.9258
0.5613
0.5634
0.6845
0.6434
0.4185
0.5907
0.5669
0.5674
0.5940
0.5593
0.5403
1.1756
0.5266
0.0000
315.65 K
0.0000
0.0000
0.5631
0.5153
-0.3845
0.4351
-0.6350
0.5574
0.5586
0.9027
0.5378
0.5346

-1

-1

S
TPa

-1

ms

TPa

1067.5
1085.4
1067.1
1073.4
1031.4
936.9
1033.1
1022.4
1012.9
1001.5
1038.4
1030.9
1036.5
1026.9
1015.2
1046.8
1035.6
1025.4
1047.4
1036.4
1048.4
1039.1
1052.9
1067.0

1638.60
1243.70
1284.75
1277.81
1402.65
1648.59
1373.91
1412.80
1451.47
1492.17
1335.27
1361.57
1323.84
1356.89
1397.40
1273.64
1310.42
1342.60
1256.90
1291.35
1239.10
1267.75
1212.26
1124.10

0.00
0.00
28.07
-56.88
31.21
393.94
72.20
77.54
90.13
94.90
92.26
86.27
99.89
106.38
119.56
91.58
101.36
109.13
85.56
95.37
76.48
82.44
56.50
0.00

990.4
1095.8
1077.
1084.0
1042.1
1065.9
1043.1
1033.0
1023.6
1012.1
1048.7
1041.1

1596.60
1216.60
1255.60
1249.33
1369.47
1269.64
1341.87
1379.36
1416.44
1455.44
1305.13
1330.87

0.00
0.00
26.03
-55.28
29.50
41.94
68.66
73.88
85.84
90.30
88.10
82.78

A 49 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A20. Continuacin.

x1

x2

VE

-3

kgm
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

696.6
701.1
705.3
710.5
713.7
718.6
723.1
727.4
732.7
.736.3
746.3
770.6

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

640.9
686.5
674.6
683.2
687.9
695.4
672.8
681.7
686.4
676.1
695.5
698.9
699.0
703.4
707.6
712.9
716.0
720.9
725.4
729.6
734.9
738.6
748.5
772.8

0.0000
0.0000

1.0000
0.0000

643.2
688.5

A 50 | A. GAYOL

cm mol

u
-1

0.6710
0.6226
0.4011
0.5708
0.5465
0.5489
0.5776
0.5447
0.5244
1.1522
0.5123
0.0000
313.15 K
0.0000
0.0000
0.5411
0.4922
-0.3648
0.4152
-0.6543
0.5363
0.5363
0.8790
0.5169
0.5172
0.6503
0.6013
0.3825
0.5535
0.5303
0.5290
0.5612
0.5283
0.5081
1.1285
0.4985
0.0000
310.65 K
0.0000
0.0000

-1

-1

S
TPa

-1

ms

TPa

1046.5
1036.8
1025.4
1056.5
1045.5
1035.2
1056.8
1046.0
1057.7
1048.4
1061.8
1084.3

1294.52
1326.74
1365.14
1246.48
1281.75
1313.06
1230.98
1263.76
1213.82
1241.66
1188.39
1103.60

95.60
102.28
114.40
87.68
96.99
104.82
82.35
91.44
73.46
79.47
54.51
0.00

1001.7
1106.2
1088.2
1094.6
1052.9
1075.8
1054.1
1043.5
1034.0
1023.1
1058.9
1051.3
1056.5
1046.7
1035.6
1066.2
1055.2
1045.1
1066.1
1055.6
1066.9
1057.6
1070.7
1092.7

1555.00
1190.30
1227.60
1221.46
1337.04
1242.46
1311.16
1347.07
1383.09
1419.85
1275.76
1300.79
1266.08
1297.46
1333.92
1220.15
1254.28
1284.15
1205.69
1237.05
1189.46
1216.34
1165.35
1083.70

0.00
0.00
24.43
-53.72
27.94
41.00
65.82
70.77
82.68
86.32
84.08
79.33
91.58
98.46
109.71
83.98
93.22
100.55
79.14
87.79
70.74
76.70
52.77
0.00

1013.2
1116.5

1514.40
1164.90

0.00
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.20. Continuacin.

x1

x2

VE

-3

kgm
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

676.9
685.3
690.1
697.6
675.1
684.0
688.6
678.5
697.8
701.2
701.3
705.7
709.8
715.2
718.3
723.2
727.7
731.9
737.2
740.8
750.7
775.0

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587

645.5
690.6
679.2
687.4
692.2
699.8
677.5
686.3
690.9
680.8
700.1
703.4
703.6
708.0
712.1
717.4
720.6
725.4
729.9
734.1

cm mol

u
-1

0.5176
0.4704
-0.3461
0.3950
-0.6732
0.5142
0.5149
0.8583
0.4962
0.4952
0.6290
0.5821
0.3630
0.5356
0.5111
0.5108
0.5452
0.5126
0.4927
1.1063
0.4836
0.0000
308.15 K
0.0000
0.0000
0.4990
0.4514
-0.3279
0.3783
-0.6896
0.4946
0.4980
0.8408
0.4803
0.4807
0.6120
0.5640
0.3484
0.5193
0.4957
0.4941
0.5307
0.4984

-1

-1

S
TPa

-1

ms

TPa

1098.6
1105.0
1063.2
1085.8
1064.6
1054.0
1044.5
1033.8
1069.1
1061.5
1066.5
1056.6
1045.8
1075.8
1064.9
1054.9
1075.5
1065.2
1076.1
1066.7
1079.5
1101.0

1200.60
1194.99
1306.85
1215.72
1281.27
1315.73
1350.89
1385.71
1247.57
1271.69
1238.49
1269.03
1303.70
1194.66
1227.56
1256.44
1181.11
1211.10
1165.65
1191.95
1142.92
1064.40

22.99
-51.62
27.75
39.67
62.99
67.79
79.83
82.94
80.48
76.07
87.69
94.76
105.29
80.42
89.50
96.79
75.98
84.22
67.92
74.19
50.99
0.00

1024.6
1126.9
1109.0
1115.6
1074.0
1096.1
1075.3
1064.6
1055.2
1043.7
1079.5
1071.8
1076.6
1066.8
1056.0
1085.5
1074.8
1064.8
1084.8
1074.7

1475.70
1140.20
1174.45
1168.94
1276.44
1189.33
1251.66
1285.39
1319.17
1354.91
1219.88
1243.35
1211.60
1241.06
1274.48
1169.77
1201.21
1229.25
1157.53
1186.01

0.00
0.00
21.66
-50.07
26.25
37.97
59.59
64.84
76.43
81.75
76.71
72.80
83.88
90.82
101.08
76.99
85.57
92.90
73.37
80.99

A 51 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.20. Continuacin.

x1

x2

VE

-3

kgm
0.8470
0.8570
0.9070
1.0000

0.1087
0.0542
0.0520
0.0000

739.5
743.0
753.0
777.2

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

647.8
692.6
681.4
689.4
694.3
702.0
679.8
688.6
693.1
683.0
702.3
705.7
705.9
710.2
714.3
719.7
722.8
727.6
732.1
736.3
741.7
745.2
755.2
779.4

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455

650.1
694.6
683.6
691.5
696.5
704.1
682.1
690.9

A 52 | A. GAYOL

cm mol

u
-1

0.4803
1.0846
0.4727
0.0000
305.65 K
0.0000
0.0000
0.4806
0.4328
-0.3120
0.3631
-0.7055
0.4753
0.4787
0.8220
0.4615
0.4643
0.5922
0.5460
0.3311
0.5029
0.4824
0.4785
0.5165
0.4854
0.4663
1.0646
0.4606
0.0000
303.15 K
0.0000
0.0000
0.4661
0.4163
-0.2946
0.3488
-0.7186
0.4576

-1

-1

S
TPa

-1

ms

TPa

1085.4
1076.1
1088.4
1109.4

1142.36
1167.78
1121.05
1045.40

65.21
71.42
49.39
0.00

1035.7
1137.2
1119.5
1126.1
1084.6
1106.2
1085.8
1075.3
1065.9
1054.5
1089.7
1082.0
1086.6
1076.8
1066.2
1095.2
1084.4
1074.6
1094.1
1084.3
1094.5
1085.2
1097.3
1117.8

1439.00
1116.40
1149.12
1143.83
1247.58
1164.05
1223.74
1255.88
1288.47
1322.89
1193.33
1216.09
1185.71
1214.23
1246.14
1145.84
1176.32
1203.20
1134.42
1161.71
1120.00
1144.78
1099.70
1026.90

0.00
0.00
20.23
-48.70
25.06
36.47
56.83
61.61
72.84
78.03
73.21
69.66
80.26
87.14
96.79
73.84
82.36
89.32
70.58
77.83
62.81
69.13
47.70
0.00

1047.1
1147.5
1129.9
1136.6
1095.1
1116.5
1096.2
1085.9

1402.90
1093.20
1124.44
1119.47
1219.58
1139.13
1196.59
1227.42

0.00
0.00
18.92
-47.14
24.20
34.80
54.37
58.93

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.20. Continuacin.

x1

x2

VE

-3

kgm
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

695.4
685.3
704.6
707.9
708.2
712.5
716.5
722.0
725.0
729.8
734.4
738.5
743.9
747.5
757.4
781.5

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

652.4
696.6
685.8
693.5
698.6
706.3
684.4
693.1
697.6
687.6
706.8
710.1
710.4
714.8
718.7
724.2
727.3
732.0
736.6
740.7
746.1
749.7
759.5
783.7

cm mol

u
-1

0.4610
0.8066
0.4449
0.4477
0.5772
0.5299
0.3171
0.4903
0.4688
0.4647
0.5049
0.4720
0.4550
1.0457
0.4507
0.0000
300.65 K
0.0000
0.0000
0.4484
0.4004
-0.2788
0.3360
-0.7319
0.4410
0.4445
0.7904
0.4285
0.4357
0.5604
0.5142
0.3028
0.4771
0.4553
0.4502
0.4920
0.4594
0.4430
1.0268
0.4393
0.0000

-1

-1

S
TPa

-1

ms

TPa

1076.7
1065.3
1099.9
1092.3
1096.6
1086.8
1076.4
1104.9
1094.3
1084.4
1103.5
1093.7
1103.8
1094.5
1106.2
1126.2

1258.68
1291.67
1167.54
1189.49
1160.47
1188.02
1218.70
1122.28
1151.75
1177.66
1111.87
1138.20
1098.03
1122.11
1078.98
1008.70

69.68
74.63
70.02
66.72
76.89
83.67
93.00
70.67
79.07
85.87
68.00
75.10
60.45
66.82
46.31
0.00

1058.4
1157.8
1140.4
1147.0
1105.6
1126.7
1106.
1096.4
1087.4
1076.0
1110.2
1102.4
1106.5
1097.0
1086.5
1114.5
1104.1
1094.3
1112.9
1103.3
1113.0
1103.6
1115.0
1134.6

1368.30
1070.80
1100.59
1095.88
1192.73
1115.17
1170.51
1200.17
1229.88
1261.77
1142.52
1163.99
1136.21
1162.59
1192.19
1099.67
1127.91
1153.06
1089.91
1115.19
1076.79
1100.28
1058.89
991.10

0.00
0.00
17.61
-45.76
23.46
33.29
52.06
56.50
66.48
71.47
66.80
64.03
73.72
80.16
89.25
67.75
75.77
82.57
65.31
72.15
58.16
64.66
44.90
0.00

A 53 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.20. Continuacin.

x1

x2

VE

-3

kgm
0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

654.7
698.7
688.0
695.5
700.8
708.5
686.7
695.3
699.8
689.8
709.1
712.3
712.7
717.0
720.9
726.4
729.5
734.2
738.8
742.9
748.3
751.8
761.7
785.8

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413

656.9
700.7
690.2
697.6
702.9
710.6
689.0
697.5
702.0
692.0
711.3
714.5
714.9
719.2
723.1

A 54 | A. GAYOL

cm mol

u
-1

298.15 K
0.0000
0.0000
0.4326
0.3849
-0.2617
0.3229
-0.7444
0.4256
0.4283
0.7760
0.4148
0.4218
0.5455
0.4997
0.2881
0.4645
0.4433
0.4380
0.4808
0.4479
0.4325
1.0092
0.4297
0.0000
295.65 K
0.0000
0.0000
0.4209
0.3711
-0.2454
0.3108
-0.7519
0.4110
0.4165
0.7629
0.4018
0.4097
0.5337
0.4871
0.2774

-1

-1

S
TPa

-1

ms

TPa

1069.8
1168.2
1150.7
1157.7
1116.1
1137.0
1117.1
1107.0
1098.2
1086.8
1120.5
1112.7
1116.6
1107.1
1096.7
1124.2
1113.9
1104.2
1122.3
1112.9
1122.2
1112.9
1123.9
1143.1

1334.50
1048.80
1077.58
1072.71
1166.71
1091.68
1144.99
1173.42
1201.95
1232.67
1118.09
1138.90
1112.42
1137.82
1166.39
1077.63
1104.80
1128.98
1068.50
1092.76
1056.10
1078.79
1039.19
973.80

0.00
0.00
16.73
-44.46
23.01
31.81
49.84
54.05
63.65
68.55
63.76
61.31
70.62
76.90
85.79
65.05
72.82
79.39
62.84
69.40
56.08
62.46
43.55
0.00

1081.4
1178.7
1161.0
1168.4
1126.9
1147.2
1127.7
1117.6
1109.0
1097.8
1130.9
1123.1
1126.8
1117.3
1107.0

1301.70
1027.20
1055.42
1049.93
1140.84
1069.19
1120.01
1147.66
1174.74
1204.25
1094.29
1114.56
1089.13
1113.78
1141.22

0.00
0.00
16.26
-43.32
22.10
30.91
47.64
52.04
60.91
65.64
60.91
58.84
67.61
73.90
82.44

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.20. Continuacin.

x1

x2

VE

-3

kgm
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

728.7
731.7
736.3
741.0
745.1
750.5
754.0
763.9
788.0

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

659.2
702.7
692.4
699.6
705.0
712.7
691.2
699.8
704.2
694.3
713.5
716.7
721.4
725.3
699.4
733.9
738.5
712.6
747.2
730.9
756.2
743.2
752.7
790.1

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455

661.4
704.7
694.6
701.6
707.1
714.9
693.5
701.9

cm mol

u
-1

0.4539
0.4326
0.4266
0.4709
0.4377
0.4218
0.9930
0.4212
0.0000
293.15 K
0.0000
0.0000
0.4075
0.3597
-0.2302
0.3002
-0.7623
0.3972
0.4028
0.7497
0.3878
0.3976
0.5210
0.4731
0.2668
0.4430
0.4222
-0.2164
3.8989
-0.0628
-0.1163
0.4062
3.5063
0.0000
290.65 K
0.0000
0.0000
0.3943
0.3478
-0.2142
0.2888
-0.7710
0.3875

-1

-1

S
TPa

-1

ms

TPa

1134.0
1123.8
1114.1
1131.9
1122.6
1131.5
1122.2
1132.9
1151.6

1055.99
1082.16
1105.60
1047.57
1070.85
1035.85
1057.83
1019.85
956.80

62.39
69.93
76.45
60.50
66.79
54.09
60.43
42.22
0.00

1093.1
1189.3
1171.2
1179.4
1137.8
1157.8
1138.6
1128.5
1120.1
1108.9
1141.6
1133.6
1102.0
1137.1
1127.7
1106.8
1144.0
1133.8
1124.2
1141.5
1132.4
1140.9
1131.8
1160.3

1269.70
1006.10
1033.99
1027.52
1115.49
1046.56
1095.37
1122.09
1147.96
1176.46
1070.64
1090.65
1177.23
1066.31
1089.98
1145.50
1034.66
1059.93
1082.43
1026.90
1049.33
1015.85
1037.05
940.00

0.00
0.00
16.06
-42.33
21.17
29.41
45.33
49.72
58.09
62.83
57.82
56.39
175.64
47.09
52.62
170.57
41.87
50.89
113.66
41.83
85.58
37.09
77.19
0.00

1106.0
1200.0
1181.4
1190.5
1148.9
1168.5
1149.4
1139.4

1235.90
985.40
1013.29
1005.47
1090.67
1024.41
1071.55
1097.30

0.00
0.00
16.46
-40.70
21.25
28.28
44.09
48.61

A 55 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.20. Continuacin.

x1

x2

VE

-3

kgm
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

706.3
696.5
715.7
718.8
723.6
727.5
701.6
736.0
740.6
714.9
749.4
733.1
758.3
745.3
754.9
792.3

0.0000
0.0000
0.2154
0.2199
0.2306
0.2728
0.3659
0.3753
0.3798
0.3815
0.5142
0.5230
0.6167
0.6239
0.6315
0.7114
0.7148
0.7261
0.7877
0.7987
0.8470
0.8570
0.9070
1.0000

1.0000
0.0000
0.3887
0.2970
0.1027
0.1104
0.4997
0.3455
0.2619
0.4134
0.2358
0.1566
0.2732
0.2062
0.1413
0.1895
0.1288
0.0638
0.1177
0.0587
0.1087
0.0542
0.0520
0.0000

663.6
706.7
697.3
704.3
709.8
717.6
696.4
704.8
709.1
699.3
718.5
721.6
726.4
730.3
704.5
738.8
743.4
717.7
752.2
735.9
761.1
748.1
757.7
794.4

A 56 | A. GAYOL

cm mol

u
-1

0.3923
0.7354
0.3764
0.3870
0.5086
0.4642
0.2582
0.4321
0.4142
-0.2181
3.8579
-0.0643
-0.1164
0.3987
3.4701
0.0000
288.15 K
0.0000
0.0000
0.2609
0.2149
-0.3225
0.1622
-0.8952
0.2720
0.2760
0.6210
0.2625
0.2750
0.4055
0.3589
0.1560
0.3323
0.3154
-0.3104
3.7284
-0.1467
-0.2015
0.3086
3.3572
0.0000

-1

-1

S
TPa

-1

ms

TPa

1131.2
1119.9
1152.1
1144.1
1112.9
1147.3
1138.0
1117.2
1154.1
1143.9
1134.3
1151.3
1142.2
1150.3
1141.2
1169.1

1121.95
1149.54
1048.09
1067.39
1150.58
1044.31
1067.03
1120.60
1013.65
1038.28
1060.10
1006.72
1028.32
996.51
1017.15
923.40

56.64
61.65
55.87
54.81
168.95
45.94
51.43
164.23
40.31
49.51
109.53
40.67
82.47
36.40
74.95
0.00

1118.3
1112.0
1191.1
1202.1
1159.7
1178.9
1160.1
1150.0
1142.0
1130.8
1162.7
1154.3
1123.7
1157.4
1148.3
1127.6
1163.7
1153.6
1144.3
1160.7
1151.6
1159.4
1150.3
1178.2

1205.00
964.90
992.99
982.55
1066.25
1002.60
1047.63
1072.77
1096.30
1122.99
1025.05
1044.59
1124.07
1022.16
1043.89
1095.81
993.19
1017.00
1037.74
986.78
1007.79
977.28
997.38
906.80

0.00
0.00
16.83
-40.89
20.54
27.05
41.91
46.72
54.30
59.37
52.92
52.96
161.94
43.99
49.22
157.77
38.91
47.92
105.17
39.38
79.66
35.50
72.69
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.21. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1)+ x2 n-hexano (2) (1- x1-x2) n-nonano (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

T/K
0.0000
0.0000
0.0727
0.0728
0.0734
0.0759
0.0805
0.0815
0.0827
0.0901
0.0966
0.1983
0.2122
0.2151
0.2155
0.2233
0.2234
0.2318
0.2385
0.3651
0.3672
0.3781
0.3886
0.3945
0.4048
0.4976
0.5100
0.5159
0.5398
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8501
0.8668
0.9144
1.0000

1.0000
0.0000
0.4526
0.7973
0.5097
0.6328
0.1206
0.7188
0.2716
0.2359
0.3409
0.7348
0.6517
0.4927
0.5755
0.4010
0.3101
0.2119
0.1102
0.5748
0.5088
0.4322
0.3507
0.2682
0.1848
0.4480
0.3785
0.3120
0.0805
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.1091
0.0524
0.0476
0.0000

nD

nD

318.15

308.15

298.15

288.15

318.15

308.15

1.36052
1.39368
1.37905
1.36585
1.37556
1.37257
1.38848
1.36899
1.38889
1.38516
1.38188
1.36240
1.36580
1.37273
1.36893
1.37582
1.37944
1.38238
1.38562
1.36074
1.36432
1.36783
1.37106
1.37483
1.37735
1.35941
1.36276
1.36642
1.37645
1.36189
1.36511
1.36851
1.37138
1.35674
1.36402
1.36703
1.35611
1.35956
1.36279
1.35546
1.35845
1.35481
1.35031

1.36652
1.39718
1.38995
1.37678
1.38654
1.38321
1.39853
1.37975
1.39899
1.39513
1.39230
1.37344
1.37662
1.38306
1.37978
1.38615
1.38938
1.39234
1.39544
1.37180
1.37494
1.37795
1.38109
1.38440
1.38749
1.37031
1.37374
1.37658
1.38503
1.37210
1.37550
1.37853
1.38122
1.37098
1.37370
1.37682
1.36608
1.36919
1.37229
1.36488
1.36353
1.35944
1.35477

1.37211
1.40298
1.38995
1.37678
1.38654
1.38321
1.39853
1.37975
1.39899
1.39513
1.39230
1.37344
1.37662
1.38306
1.37978
1.38615
1.38938
1.39234
1.39544
1.37180
1.37494
1.37795
1.38109
1.38440
1.38749
1.37031
1.37374
1.37658
1.38503
1.37210
1.37550
1.37853
1.38122
1.37098
1.37370
1.37682
1.36608
1.36919
1.37229
1.36488
1.36807
1.36403
1.35922

1.37777
1.40749
1.39432
1.38269
1.39154
1.38860
1.40384
1.38528
1.40359
1.40410
1.39368
1.38030
1.38311
1.38884
1.38605
1.39200
1.39472
1.39815
1.40097
1.37744
1.38071
1.38374
1.38723
1.39111
1.39403
1.37538
1.37917
1.38158
1.39158
1.37770
1.38070
1.38375
1.38664
1.37634
1.37921
1.38222
1.37127
1.37429
1.37746
1.37054
1.37302
1.36863
1.36345

0.00000 0.00000
0.00000 0.00000
0.00353 0.00403
0.00176 0.00178
0.00196 0.00269
0.00317 0.00347
0.00229 0.00345
0.00268 0.00251
0.00780 -0.00167
0.00321 0.00398
0.00369 0.00449
0.00169 0.00163
0.00293 0.00308
0.00472 0.00463
0.00368 0.00422
0.00512 0.00589
0.00573 0.00634
0.00578 0.00688
0.00594 0.00692
0.00195 0.00218
0.00344 0.00361
0.00488 0.00514
0.00586 0.00616
0.00715 0.00747
0.00735 0.00833
0.00217 0.00254
0.00375 0.00431
0.00546 0.00591
0.00885 0.00959
0.00430 0.00454
0.00580 0.00626
0.00744 0.00802
0.00855 0.00934
0.00012 0.00488
0.00608 0.00636
0.00764 0.00822
0.00219 0.00282
0.00423 0.00469
0.00604 0.00665
0.00226 0.00277
0.00410 0.00472
0.00236 0.00250
0.00000 0.00000

298.15

288.15

0.00000
0.00000
0.00412
0.00160
0.00250
0.00309
0.00279
0.00252
0.00801
0.00337
0.00407
0.00182
0.00304
0.00471
0.00400
0.00532
0.00575
0.00605
0.00630
0.00254
0.00374
0.00486
0.00594
0.00696
0.00793
0.00293
0.00476
0.00580
0.00815
0.00482
0.00664
0.00809
0.00918
0.00488
0.00645
0.00828
0.00276
0.00460
0.00642
0.00247
0.00464
0.00253
0.00000

0.00000
0.00000
0.00348
0.00210
0.00243
0.00326
0.00348
0.00274
0.00782
0.00759
0.00057
0.00338
0.00433
0.00547
0.00515
0.00626
0.00628
0.00717
0.00726
0.00311
0.00451
0.00575
0.00728
0.00896
0.00986
0.00312
0.00539
0.00608
0.01025
0.00576
0.00726
0.00882
0.01019
0.00570
0.00750
0.00930
0.00346
0.00527
0.00724
0.00373
0.00526
0.00282
0.00000

A 57 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.22. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 Etanol (1)+ x2 n-hexano (2) (1- x1-x2 ) n-nonano (3) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

x2

VE

-3

kgm
0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

636.2
698.3
668.8
662.9
659.8
665.9
672.1
678.5
684.4
690.4
696.3
684.3
690.4
696.2
702.6
696.7
703.2
709.6
715.6
690.5
716.6
723.1
690.7
723.7
729.7
704.0
717.8
768.4

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101

638.5
700.2
671.0
665.1
662.1
668.2
674.3
680.6
686.5

A 58 | A. GAYOL

cm mol

u
-1

318.15 K
0.0000
0.0000
-1.1326
-1.1780
-0.8729
-0.7486
0.3875
0.4139
0.4314
0.4872
0.5471
-0.6064
-0.5337
-0.4904
-0.5550
-0.4070
-0.2474
-0.3364
-0.1764
4.2398
-0.4564
-0.2859
4.7434
-0.2567
-0.2342
3.4620
2.4565
0.0000
315.65 K
0.0000
0.0000
-1.126
-1.168
-0.875
-0.756
0.369
0.395
0.415

-1

-1

S
TPa

-1

ms

TPa

1067.5
1123.9
1044.5
1031.8
1006.2
1020.4
1034.6
1048.8
1063.6
1077.2
1089.9
1038.3
1052.4
1065.8
1081.4
1045.1
1037.8
1053.1
1066.4
1030.2
1048.4
1061.7
1009.0
1044.2
1058.7
1018.4
1028.8
1067.5

1638.60
1133.70
1370.45
1416.65
1496.75
1442.19
1390.01
1339.91
1291.56
1248.00
1208.92
1355.43
1307.66
1264.41
1216.78
1314.07
1320.19
1270.44
1228.82
1364.44
1269.33
1226.86
1422.02
1267.21
1222.59
1369.26
1315.98
1124.10

0.00
0.00
-82.08
-79.19
-6.03
-18.50
9.59
5.89
3.44
9.54
21.88
7.13
0.60
-0.92
-6.33
27.81
52.68
34.56
31.15
200.63
41.38
34.93
263.90
51.96
36.33
213.75
164.13
0.00

990.4
1133.9
1055.1
1042.5
1017.0
1030.7
1045.3
1059.4
1074.0

1596.60
1110.76
1338.79
1383.39
1460.16
1408.75
1357.17
1308.97
1262.75

0.00
0.00
-78.94
-76.01
-6.18
-17.10
8.55
4.98
2.92

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

692.5
698.3
686.5
692.5
698.4
704.7
698.9
705.4
711.8
717.7
692.7
718.8
725.2
693.0
725.9
731.9
706.3
720.1
770.6

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764

640.9
702.2
679.1
673.2
664.5
670.5
676.6
682.9
688.7
694.7
700.4
688.8
694.8
700.6
706.9
706.6
714.0
719.9
695.1
701.2
727.5
695.4
702.3
734.1

cm mol

U
-1

0.467
0.529
-0.611
-0.540
-0.496
-0.562
-0.412
-0.252
-0.339
-0.182
4.187
-0.457
-0.289
4.685
-0.256
-0.234
3.420
2.429
0.0000
313.15 K
0.0000
0.0000
-2.350
-2.342
-0.882
-0.758
0.352
0.381
0.398
0.450
0.509
-0.616
-0.545
-0.504
-0.568
-1.216
-1.079
-1.115
3.256
3.237
-1.216
3.720
3.710
-0.883

-1

-1

S
TPa

-1

ms

TPa

1087.6
1100.1
1048.9
1062.9
1076.1
1091.6
1055.3
1047.8
1063.1
1076.3
1040.5
1058.2
1071.3
1019.0
1053.4
1068.0
1028.2
1038.5
1084.3

1220.61
1183.10
1323.92
1278.13
1236.55
1190.71
1284.78
1290.97
1243.04
1202.74
1333.12
1242.35
1201.35
1389.62
1241.27
1197.78
1339.07
1287.54
1103.60

8.54
20.49
5.87
-0.26
-1.70
-6.94
26.14
50.15
32.64
29.07
192.01
39.43
33.04
253.81
50.42
34.80
205.64
157.51
0.00

1001.7
1143.8
1079.6
1065.6
1027.9
1041.4
1055.8
1069.8
1084.3
1097.8
1110.3
1059.3
1073.1
1086.3
1101.7
1078.3
1073.0
1086.1
1050.8
1065.4
1080.9
1028.9
1045.1
1077.4

1555.00
1088.53
1263.38
1308.00
1424.14
1375.22
1325.82
1279.32
1234.86
1194.35
1157.98
1293.69
1249.73
1209.56
1165.50
1217.12
1216.34
1177.52
1302.82
1256.29
1176.47
1358.40
1303.52
1173.39

0.00
0.00
-120.04
-115.44
-6.20
-16.28
8.47
4.79
2.72
8.06
19.16
5.36
-0.55
-2.19
-7.29
-14.45
1.66
-7.97
152.56
137.27
-1.98
213.13
189.42
6.36

A 59 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.7932
0.8067
0.8668
1.0000

0.1192
0.0585
0.0524
0.0000

708.7
713.8
728.2
772.8

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

643.2
704.1
681.2
675.4
666.8
672.8
678.8
685.1
690.9
696.8
702.6
691.0
697.0
702.8
709.1
708.8
716.3
722.1
697.3
703.4
729.7
697.7
704.6
736.3
711.0
716.1
730.5
775.0

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101

6455
706.1
683.4
677.6
669.1
675.0
681.1
687.3
693.1

A 60 | A. GAYOL

cm mol

U
-1

2.604
2.776
1.796
0.0000
310.65 K
0.0000
0.0000
-2.3262
-2.3200
-0.8803
-0.7599
0.3359
0.3642
0.3809
0.4285
0.4871
-0.6181
-0.5505
-0.5112
-0.5771
-1.2122
-1.0731
-1.1089
3.2172
3.1947
-1.2098
3.6748
3.6648
-0.8755
2.5740
2.7437
1.7768
0.0000
308.15 K
0.0000
0.0000
-2.3008
-2.2930
-0.8784
-0.7588
0.3215
0.3519
0.3646

-1

-1

S
TPa

-1

ms

TPa

1037.9
1052.5
1062.9
1092.7

1309.88
1264.57
1215.35
1083.70

169.58
152.62
106.54
0.00

1013.2
1153.6
1090.0
1076.3
1038.3
1052.0
1066.4
1080.4
1094.6
1108.1
1120.4
1069.6
1083.4
1096.4
1111.9
1088.4
1082.9
1095.7
1061.0
1075.6
1090.5
1038.8
1055.0
1086.6
1047.6
1062.3
1072.4
1101.0

1514.40
1067.13
1235.42
1278.11
1391.12
1342.90
1295.27
1250.45
1207.99
1168.62
1133.76
1264.68
1222.17
1183.58
1140.57
1190.85
1190.52
1153.29
1273.81
1228.74
1152.39
1328.09
1274.98
1150.03
1281.52
1237.48
1190.32
1064.40

0.00
0.00
-114.61
-110.30
-4.12
-15.13
8.33
4.54
2.74
7.31
17.95
5.25
-0.79
-2.46
-8.13
-14.41
1.26
-8.00
146.26
131.12
-2.29
205.18
181.91
6.14
163.24
146.35
102.10
0.00

1024.6
1163.6
1100.5
1086.8
1048.9
1062.8
1077.1
1090.9
1105.1

1475.70
1045.94
1208.21
1249.36
1358.24
1311.26
1265.58
1222.50
1181.41

0.00
0.00
-109.71
-105.46
-3.38
-14.63
7.98
4.32
2.29

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

699.0
704.6
693.3
699.2
704.9
711.2
711.0
718.5
724.3
699.6
705.7
731.9
700.0
706.9
738.5
713.3
718.3
732.7
777.2

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764

647.8
708.0
679.1
673.2
664.5
670.5
676.6
682.9
688.7
694.7
700.4
688.8
694.8
700.6
706.9
706.6
714.0
719.9
695.1
701.2
727.5
695.4
702.3
734.1

cm mol

U
-1

0.4149
0.4720
-0.6185
-0.5534
-0.5158
-0.5790
-1.2037
-1.0641
-1.1024
3.1810
3.1572
-1.2005
3.6300
3.6244
-0.8669
2.5453
2.7126
1.7594
0.0000
305.65 K
0.0000
0.0000
-0.9604
-0.9644
0.3754
0.4922
1.6113
1.6384
1.6621
1.7128
1.7733
0.4824
0.5492
0.5902
0.5222
-0.2484
-0.2142
-0.2540
4.1055
4.0809
-0.4275
4.4897
4.4668
-0.1748

-1

-1

S
TPa

-1

ms

TPa

1118.3
1130.6
1080.2
1093.8
1106.7
1122.0
1098.4
1092.7
1105.6
1071.3
1085.8
1100.1
1049.0
1065.0
1096.1
1057.3
1072.1
1081.8
1109.4

1143.83
1110.10
1236.13
1195.27
1158.12
1116.79
1165.56
1165.68
1129.38
1245.29
1201.91
1128.93
1298.10
1247.12
1126.85
1254.05
1211.08
1166.08
1045.40

6.92
16.89
4.64
-1.20
-2.89
-8.36
-14.18
1.09
-8.34
139.96
125.31
-2.60
197.05
174.71
5.53
157.31
140.40
98.07
0.00

1035.7
1173.6
1111.0
1097.5
1059.8
1073.6
1087.6
1101.4
1115.4
1128.6
1140.8
1090.7
1104.2
1116.9
1132.0
1108.5
1102.5
1115.4
1081.6
1095.9
1109.6
1059.2
1075.0
1105.4

1439.00
1025.38
1192.84
1233.16
1339.69
1293.89
1249.38
1207.15
1166.91
1130.08
1096.90
1220.40
1180.34
1144.08
1103.79
1151.62
1152.01
1116.32
1229.77
1187.32
1116.29
1281.79
1232.15
1114.73

0.00
0.00
-94.45
-89.65
10.09
-1.36
19.87
15.56
12.91
16.69
25.57
15.67
9.30
7.16
1.36
-3.58
11.18
1.33
145.92
131.10
7.11
201.90
179.78
15.21

A 61 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.7932
0.8067
0.8668
1.0000

0.1192
0.0585
0.0524
0.0000

708.7
713.8
728.2
779.4

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

650.1
710.0
676.2
670.0
673.7
679.6
685.5
691.7
697.4
703.2
708.8
697.7
703.6
709.3
715.4
715.4
716.7
722.9
728.6
7101
722.8
736.2
704.6
731.5
737.1
742.9
759.4
781.5

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119

652.4
712.0
689.8
684.0
675.9
681.8
687.7
693.8
699.5
705.3

A 62 | A. GAYOL

cm mol

u
-1

3.3058
3.4688
2.4283
0.0000
303.15 K
0.0000
0.0000
0.0885
0.1340
-0.8768
-0.7603
0.2957
0.3276
0.3371
0.3836
0.4423
-0.6200
-0.5589
-0.5243
-0.5859
-1.1922
-0.2655
-0.3504
-0.2082
3.0858
0.3832
-0.3019
4.4107
0.3404
0.3728
0.4330
-0.4524
0.0000
300.65 K
0.0000
0.0000
-2.2269
-2.2210
-0.8759
-0.7606
0.2823
0.3175
0.3265
0.3710

-1

-1

S
TPa

-1

ms

TPa

1067.1
1081.8
1091.2
1117.8

1239.15
1197.00
1153.11
1026.90

163.26
146.17
104.72
0.00

1047.1
1183.6
1096.1
1081.2
1070.8
1084.4
1098.3
1112.0
1125.9
1139.0
1151.2
1101.1
1114.6
1127.3
1142.2
1118.6
1097.8
1112.5
1125.2
1106.1
1091.7
1119.4
1069.4
1086.4
1100.8
1114.8
1126.1
1126.2

1402.90
1005.31
1230.68
1276.68
1294.44
1251.30
1209.28
1169.08
1131.13
1096.16
1064.51
1181.99
1144.02
1109.43
1071.32
1116.94
1157.62
1117.63
1083.94
1150.97
1160.72
1083.89
1240.82
1158.15
1119.41
1083.14
1038.37
1008.70

0.00
0.00
-26.49
-14.67
-3.68
-13.81
7.37
3.62
1.82
5.88
14.65
3.57
-2.03
-3.81
-8.78
-14.14
40.15
24.99
21.21
114.79
73.51
24.80
208.17
80.07
64.04
51.83
9.28
0.00

1058.4
1193.6
1132.0
1118.8
1081.6
1095.1
1109.0
1122.5
1136.2
1149.2

1368.30
985.83
1131.30
1167.77
1264.39
1222.86
1182.29
1143.86
1107.22
1073.49

0.00
0.00
-96.99
-93.40
-3.51
-13.33
6.88
3.50
1.62
5.41

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

710.9
699.9
705.7
711.4
717.5
717.6
725.0
730.7
706.3
712.3
738.4
706.9
713.6
745.0
720.1
725.0
739.3
783.7

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764

654.7
713.9
691.9
686.2
678.2
684.0
689.9
696.0
701.6
707.4
712.9
702.1
707.9
713.5
719.6
719.7
727.2
732.9
708.5
714.5
740.5
709.2
715.8
747.2

cm mol

U
-1

0.4296
-0.6194
-0.5609
-0.5286
-0.5884
-1.1855
-1.0407
-1.0816
3.0765
3.0525
-1.1762
3.5053
3.5052
-0.8412
2.4632
2.6266
1.7074
0.0000
298.15 K
.0.0000
0.0000
-2.2037
-2.1978
-0.8738
-0.7574
0.2718
0.3077
0.3141
0.3581
0.4171
-0.6190
-0.5618
-0.5311
-0.5899
-1.1787
-1.0325
-1.0743
3.0445
3.0188
-1.1673
3.4672
3.4685
-0.8328

-1

-1

S
TPa

-1

ms

TPa

1161.3
1111.5
1124.9
1137.5
1152.3
1128.7
1122.4
1134.9
1102.1
1116.2
1128.9
1079.7
1094.9
1124.1
1086.9
1101.5
1110.28
1134.6

1042.97
1156.44
1119.60
1086.37
1049.52
1093.72
1094.81
1062.37
1165.51
1126.71
1062.50
1213.36
1168.81
1062.17
1175.33
1136.67
1097.18
991.10

13.76
3.32
-2.41
-4.11
-9.10
-14.14
-0.17
-8.74
123.13
109.84
-3.52
174.33
155.17
4.76
139.74
124.20
86.73
0.00

1069.8
1203.7
1142.6
1129.5
1092.5
1106.0
1119.7
1133.0
1146.8
1159.6
1171.7
1122.0
1135.3
1147.7
1162.5
1138.9
1132.3
1144.8
1112.4
1126.5
1138.5
1089.9
1105.0
1133.5

1334.50
966.70
1106.98
1142.16
1235.13
1195.11
1156.09
1119.19
1083.71
1051.14
1021.66
1131.23
1095.94
1063.79
1028.17
1071.07
1072.52
1041.06
1140.47
1102.95
1041.64
1186.82
1144.03
1041.63

0.00
0.00
-93.05
-89.49
-3.23
-12.78
6.63
3.41
1.37
4.86
12.73
2.88
-2.52
-4.36
-9.36
-14.04
-0.41
-8.93
118.07
105.06
-3.61
167.48
149.07
4.51

A 63 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.7932
0.8067
0.8668
1.0000

0.1192
0.0585
0.0524
0.0000

722.4
727.3
741.5
785.8

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

656.9
715.9
676.2
670.0
673.7
679.6
685.5
691.7
697.4
703.2
708.8
697.7
703.6
709.3
715.4
715.4
716.7
722.9
728.6
710.1
722.8
736.2
704.6
731.5
737.1
742.9
759.4
788.0

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927

659.2
717.8
696.1
690.5
682.7
688.5
694.3

A 64 | A. GAYOL

cm mol

U
-1

2.4374
2.5996
1.6915
0.0000
295.65 K
0.0000
0.0000
1.4245
1.4556
0.3270
0.4382
1.5075
1.5407
1.5594
1.6075
1.6699
0.4361
0.4949
0.5321
0.4688
-0.2609
0.5653
0.4787
0.6117
3.9019
1.1412
0.4397
5.1417
1.0209
1.0480
1.1009
0.1563
0.0000
293.15 K
0.0000
0.0000
-2.1585
-2.1530
-0.8687
-0.7536
0.2511

-1

-1

S
TPa

-1

ms

TPa

1096.944
1111.383
1119.750
1143.100

1150.48
1113.21
1075.53
973.80

134.32
119.25
83.39
0.00

1081.4
1214.0
1153.4
1140.3
1103.6
1116.8
1130.5
1143.8
1157.3
1170.1
1182.1
1132.7
1145.8
1158.1
1172.7
1149.1
1142.3
1154.7
1122.7
1136.7
1148.2
1100.3
1115.2
1142.9
1106.9
1121.3
1129.2
1151.6

1301.70
947.79
1111.47
1147.71
1218.57
1179.70
1141.34
1105.08
1070.50
1038.55
1009.53
1117.04
1082.53
1051.06
1016.22
1058.46
1069.21
1037.44
1088.71
1089.84
1049.20
1121.73
1140.99
1046.50
1107.18
1070.57
1032.62
956.80

0.00
0.00
-61.00
-55.20
8.95
-0.64
17.23
13.36
10.94
13.68
20.59
12.87
7.11
4.79
-0.61
-4.38
17.85
8.13
85.91
110.61
24.30
121.71
164.39
29.24
110.07
94.79
58.46
0.00

1093.1
1224.3
1164.3
1151.4
1114.9
1127.8
1141.4

1269.70
929.39
1059.62
1092.34
1178.33
1141.78
1105.48

0.00
0.00
-85.93
-82.51
-3.22
-11.62
6.15

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

700.2
705.8
711.6
717.0
706.4
712.2
717.8
723.8
724.0
731.5
737.1
712.9
718.8
744.8
713.7
720.2
751.5
726.8
731.7
745.9
790.1

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721

661.4
719.7
698.2
692.6
684.9
690.7
696.4
702.3
707.9
713.6
719.0
708.6
714.3
719.9
725.8
726.1
733.6
739.2
715.1
720.9

cm mol

U
-1

0.2900
0.2938
0.3328
0.3911
-0.6172
-0.5627
-0.5369
-0.5913
-1.1635
-1.0168
-1.0583
2.9815
2.9549
-1.1488
3.3925
3.3958
-0.8156
2.3879
2.5476
1.6610
0.0000
290.65 K
0.0000
0.0000
-2.1343
-2.1285
-0.8646
-0.7500
0.2418
0.2835
0.2868
0.3255
0.3828
-0.6142
-0.5606
-0.5369
-0.5896
-1.1520
-1.0075
-1.0487
2.9519
2.9267

-1

-1

S
TPa

-1

ms

TPa

1154.7
1168.0
1180.8
1192.7
1143.3
1156.4
1168.8
1183.2
1159.5
1152.5
1164.9
1133.3
1147.1
1158.1
1110.8
1125.5
1152.6
1117.0
1131.4
1138.9
1160.3

1071.03
1038.35
1007.92
980.29
1082.86
1049.86
1019.78
986.88
1027.20
1029.12
999.70
1092.16
1057.17
1001.01
1135.36
1095.95
1001.65
1102.59
1067.71
1033.54
940.00

2.84
1.10
4.01
10.93
2.39
-2.99
-5.04
-9.65
-13.81
-1.05
-9.29
108.64
96.29
-3.88
154.35
137.43
3.95
124.24
109.85
77.11
0.00

1106.0
1234.9
1175.3
1162.6
1126.1
1139.0
1152.5
1165.5
1178.8
1191.4
1203.3
1154.1
1167.2
1179.5
1193.7
1169.9
1162.7
1175.0
1143.9
1157.5

1235.90
911.03
1036.87
1068.08
1151.16
1115.98
1080.88
1048.02
1016.39
987.17
960.41
1059.48
1027.44
998.44
966.85
1006.07
1008.18
979.69
1068.72
1035.18

0.00
0.00
-80.71
-77.47
-1.03
-9.38
7.12
3.96
1.87
4.46
10.65
3.36
-2.33
-4.59
-9.20
-12.68
-0.46
-8.74
104.56
92.61

A 65 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.22. Continuacin.

x1

x2

VE

-3

kgm
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

746.9
715.9
722.4
753.6
729.0
733.8
748.0
792.3

0.0000
0.0000
0.0758
0.0815
0.1983
0.2122
0.2151
0.2233
0.2234
0.2318
0.2385
0.3781
0.3886
0.3945
0.4048
0.5159
0.6205
0.6286
0.6456
0.6562
0.7017
0.7253
0.7428
0.7820
0.7932
0.8067
0.8668
1.0000

1.0000
0.0000
0.6329
0.7188
0.7348
0.6517
0.4927
0.4010
0.3101
0.2119
0.1102
0.4322
0.3507
0.2682
0.1848
0.3120
0.2768
0.2143
0.1390
0.0721
0.2000
0.1291
0.0625
0.1764
0.1192
0.0585
0.0524
0.0000

663.6
721.6
700.9
0.695.3
687.8
693.5
699.2
705.1
710.7
716.3
721.7
711.4
717.1
722.6
728.5
728.5
736.4
742.0
717.9
7237
749.7
718.8
725.3
756.3
731.9
736.7
750.8
794.4

A 66 | A. GAYOL

cm mol

U
-1

-1.1385
3.3588
3.3624
-0.8053
2.3666
2.5258
1.6491
0.0000
288.15 K
.0.0000
0.0000
-2.2426
-2.2363
-0.9761
-0.8620
0.1102
0.1481
0.1443
0.1785
0.2351
-0.7187
-0.6669
-0.6489
-0.7020
-1.1815
-1.0823
-1.1241
2.8331
2.8042
-1.2036
3.2421
3.2469
-0.8624
2.2708
2.4293
1.5705
0.0000

-1

-1

S
TPa

-1

ms

TPa

1168.1
1121.5
1135.8
1162.3
1127.2
1141.4
1148.6
1169.1

981.12
1110.53
1072.82
982.27
1079.53
1045.84
1013.25
923.40

-3.56
148.58
132.30
4.27
119.97
105.81
74.46
0.00

1118.3
1245.4
1186.4
1173.8
1137.3
1150.0
1163.4
1176.3
1189.4
1201.9
1214.1
1164.7
1177.7
1190.0
1203.9
1180.2
1172.6
1184.9
1154.1
1167.6
1177.9
1131.7
1145.8
1171.7
1137.1
1151.2
1158.0
1178.2

1205.00
893.38
1013.51
1043.63
1124.12
1090.24
1056.57
1024.91
994.52
966.30
939.90
1036.14
1005.28
977.13
946.88
985.38
987.47
959.81
1045.74
1013.47
961.34
1086.16
1050.14
963.05
1056.55
1024.19
993.10
906.80

0.00
0.00
46.52
10.64
27.73
49.17
131.77
164.35
201.14
241.82
287.68
84.19
108.94
139.22
166.11
61.55
43.42
58.44
192.56
205.05
38.29
205.09
210.62
22.05
152.88
159.41
106.29
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.23. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1)+ x2 n-hexano (2) (1- x1-x2) agua (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

T/K
0.0000
0.0000
0.0158
0.0408
0.0459
0.0780
0.0860
0.0935
0.1175
0.6297
0.6388
0.9145
1.0000

1.0000
0.0000
0.0080
0.0364
0.4269
0.0177
0.0400
0.2969
0.1070
0.0812
0.0820
0.0251
0.0000

nD

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

1.36052
1.32976
1.33253
1.33631
1.35651
1.34046
1.34239
1.35490
1.34995
1.35400
1.35393
1.35195
1.35031

1.36652
1.33125
1.33351
1.33761
1.36211
1.34257
1.34414
1.36642
1.34857
1.35871
1.35882
1.35677
1.35477

1.37211
1.33259
1.33495
1.33899
1.36801
1.34425
1.34612
1.37232
1.34042
1.36277
1.36294
1.37087
1.35922

1.37777
1.33353
1.33586
1.34015
1.37365
1.34624
1.34783
1.37753
1.35296
1.36698
1.36880
1.36513
1.36345

0.00000
0.00000
0.00211
0.00451
0.01263
0.00847
0.00955
0.01403
0.01441
0.00878
0.00849
0.00262
0.00000

0.00000
0.00000
0.00155
0.00407
0.01469
0.00881
0.00941
0.02246
0.01074
0.00977
0.00964
0.00312
0.00000

0.00000
0.00000
0.00171
0.00396
0.01737
0.00896
0.00974
0.02556
0.00054
0.01023
0.01012
0.01294
0.00000

0.00000
0.00000
0.00164
0.00392
0.01994
0.00972
0.01008
0.02815
0.01129
0.01106
0.01257
0.00314
0.00000

Tabla A.24. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 etanol (1) - x2 n-hexano (2) (1- x1-x2) agua (3) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

x2

VE

-3

kgm
0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

636.2
990.2
978.2
637.1
639.7
647.5
668.3
683.2
705.3
710.5
719.8
768.4

0.0000

1.0000

638.6

cm mol

u
-1

318.15 K
0.0000
0.0000
-2.0391
1.8011
2.2720
1.9985
-0.2441
0.3738
0.1099
0.2608
0.1187
0.0000
315.65 K
0.0000

-1

-1

S
TPa

-1

ms

TPa

979.3
1536.5
1561.6
981.7
978.9
978.0
979.9
994.0
1012.4
1016.1
1025.1
1067.5

1638.60
427.70
419.18
1628.44
1631.18
1614.30
1557.94
1481.20
1383.22
1362.94
1321.97
1141.91

0.00
0.00
-81.67
126.55
140.93
179.19
159.49
163.51
132.04
124.85
103.82
0.00

990.4

1596.55

0.00

A 67 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.24. Continuacin.

x1

x2

VE

-3

kgm
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

991.2
979.1
639.4
642.0
650.0
671.3
685.6
707.7
712.8
722.1
770.6

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

640.9
992.2
980.2
641.8
644.4
652.4
674.5
688.0
710.1
715.2
724.5
772.8

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

643.2
993.2
981.2
644.2
646.8
654.9
677.8
690.5
7125
717.5
726.8
775.0

0.0000
0.0000

1.0000
0.0000

645.5
994.0

A 68 | A. GAYOL

cm mol

u
-1

0.0000
-2.0190
1.7768
2.2403
1.9543
-0.3515
0.3543
0.0977
0.2525
0.1114
0.0000
313.15 K
0.0000
0.0000
-2.0017
1.7559
2.2095
1.9185
-0.4744
0.3343
0.0850
0.2420
0.1044
0.0000
310.65 K
0.0000
0.0000
-1.9837
1.7353
2.1811
1.8824
-0.6140
0.3156
0.0730
0.2332
0.0969
0.0000
308.15 K
0.0000
0.0000

-1

-1

S
TPa

-1

ms

TPa

1533.2
1560.4
992.9
990.2
989.2
991.1
1004.5
1022.5
1025.8
1034.6
1084.3

429.16
419.45
1586.22
1588.48
1572.20
1516.47
1445.54
1351.48
1333.18
1293.66
1103.60

0.00
-79.66
122.98
137.87
175.72
156.43
165.78
137.80
132.80
113.14
0.00

1001.7
1529.3
1558.4
1003.9
1001.5
1000.2
1002.0
1015.1
1032.5
1035.5
1044.2
1092.7

1555.00
430.91
420.06
1545.72
1547.11
1531.84
1476.59
1410.46
1320.99
1303.81
1265.87
1083.70

0.00
0.00
-78.34
118.75
131.99
168.61
148.19
158.80
132.50
127.97
108.99
0.00

1013.2
1525.0
1556.1
1015.0
1012.7
1011.4
1012.9
1025.4
1042.5
1045.4
1053.7
1101.0

1514.40
432.93
420.86
1506.61
1507.35
1492.57
1437.92
1377.37
1291.40
1275.13
1239.17
1064.40

0.00
0.00
-77.15
115.06
126.84
161.75
140.34
153.02
127.33
123.07
105.19
0.00

1024.6
1520.3

1475.70
435.26

0.00
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.24. Continuacin.

x1

x2

VE

-3

kgm
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

982.1
646.5
649.2
657.3
682.0
692.9
714.8
719.9
729.1
777.2

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

647.8
994.9
983.0
648.9
651.6
659.7
685.7
695.2
717.2
722.2
731.4
779.4

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

650.1
995.7
983.9
651.2
653.9
662.1
689.2
697.6
719.5
724.5
733.7
781.5

0.0000
0.0000
0.0408
0.0982
0.1996

1.0000
0.0000
0.0364
0.8291
0.7597

652.4
996.4
984.6
653.5
656.3

cm mol

U
-1

-1.9650
1.7169
2.1547
1.8494
-0.9014
0.3009
0.0638
0.2252
0.0907
0.0000
305.65 K
0.0000
0.0000
-1.9467
1.6942
2.1251
1.8182
-1.0952
0.2837
0.0509
0.2164
0.0846
0.0000
303.15 K
0.0000
0.0000
-1.9288
1.6771
2.1007
1.7903
-1.2601
0.2696
0.0424
0.2101
0.0792
0.0000
300.65 K
0.0000
0.0000
-1.9104
1.6586
2.0744

-1

-1

S
TPa

-1

ms

TPa

1553.7
1026.3
1024.0
1022.6
1024.0
1035.8
1052.5
1055.2
1063.3
1109.4

421.76
1468.43
1468.85
1454.71
1398.07
1345.04
1262.83
1247.56
1212.94
1045.40

-76.20
110.77
121.54
155.00
130.12
147.07
122.47
118.61
101.27
0.00

1035.7
1515.1
1550.7
1037.4
1035.3
1033.8
1035.1
1046.4
1062.5
1065.1
1073.0
1117.8

1439.00
437.88
423.05
1431.95
1431.81
1418.30
1361.14
1313.43
1235.02
1220.59
1187.54
1026.90

0.00
0.00
-75.25
106.20
115.84
147.99
121.26
140.55
117.31
113.77
97.26
0.00

1047.1
1509.4
1547.4
1048.5
1046.4
1044.8
1046.2
1057.
1072.6
1074.8
1082.7
1126.2

1402.90
440.80
424.45
1396.76
1396.58
1383.56
1325.44
1282.83
1207.91
1194.81
1162.68
1008.70

0.00
0.00
-74.48
102.60
111.62
142.35
113.31
134.76
112.60
109.87
93.54
0.00

1058.4
1503.4
1543.7
1059.7
1057.7

1368.30
444.05
426.15
1362.49
1362.05

0.00
0.00
-73.81
98.48
106.72

A 69 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.24. Continuacin.

x1

x2

VE

-3

kgm
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

664.4
692.1
700.0
721.8
726.7
735.9
783.7

0.0000
0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

654.7
997.0
985.3
655.8
658.6
666.8
694.8
702.3
724.1
729.0
738.2
997.0
785.8

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

656.9
997.7
986.0
660.9
669.1
697.2
692.9
711.7
726.4
731.3
740.5
788.0

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723

659.2
998.2
986.6
660.4
663.2
671.4

A 70 | A. GAYOL

cm mol

u
-1

1.7654
-1.3538
0.2565
0.0321
0.2029
0.0748
0.0000
298.15 K
0.0000
0.0000
-1.8921
1.6402
2.0490
1.7435
-1.4081
0.2426
0.0237
0.1960
0.0690
0.0000
0.0000
295.65 K
0.0000
0.0000
-1.8734
1.1250
0.6318
-2.5873
-0.8021
-0.6448
0.0146
0.1897
0.0645
0.0000
293.15 K
0.0000
0.0000
-1.8548
1.6025
1.9989
1.7001

-1

-1

S
TPa

-1

ms

TPa

1056.0
1057.3
1067.6
1082.6
1084.6
1092.2
1134.6

1349.61
1292.21
1253.44
1181.83
1169.52
1138.94
991.10

136.21
106.63
129.13
107.99
105.57
90.11
0.00

1069.8
1496.8
1539.8
1071.0
1069.0
1067.3
1068.5
1078.2
1092.8
1094.6
1102.0
1496.8
1143.1

1334.50
447.62
428.02
1329.23
1328.58
1316.60
1260.54
1224.77
1156.36
1144.79
1115.38
447.62
973.80

0.00
0.00
-73.30
94.58
102.15
130.33
100.87
123.72
103.58
101.46
86.50
0.00
0.00

1081.4
1489.9
1535.5
1080.4
1078.6
1079.7
1084.0
1092.5
1102.9
1104.5
1111.7
1151.6

1301.70
451.53
430.11
1296.19
1284.55
1230.21
1228.21
1177.00
1131.59
1120.79
1092.58
956.80

0.00
0.00
-72.93
90.25
86.40
70.48
93.90
98.69
99.41
97.61
83.21
0.00

1093.1
1482.5
1531.0
1093.9
1092.0
1090.1

1269.70
455.80
432.37
1265.26
1264.39
1253.26

0.00
0.00
-72.76
87.25
93.78
119.39

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.24. Continuacin.

x1

x2

VE

-3

kgm
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

699.6
706.9
728.7
733.5
742.7
790.1

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

661.4
998.7
987.1
662.7
665.5
673.6
701.8
709.2
731.0
735.8
744.9
792.3

0.0000
0.0000
0.0408
0.0982
0.1996
0.2705
0.3499
0.5246
0.6660
0.7149
0.7612
1.0000

1.0000
0.0000
0.0364
0.8291
0.7597
0.6723
0.5952
0.4255
0.2872
0.2476
0.2038
0.0000

663.6
999.1
988.3
665.5
668.4
676.5
700.4
719.2
733.9
738.7
738.6
794.4

cm mol

U
-1

-1.4257
0.2149
0.0047
0.1825
0.0597
0.0000
290.65 K
0.0000
0.0000
-1.8353
1.5849
1.9746
1.6825
-1.4100
0.2055
-0.0004
0.1790
0.0579
0.0000
288.15 K
0.0000
0.0000
-1.8323
1.4537
1.8441
1.5597
-0.9160
-0.7328
-0.0773
0.0967
0.8730
0.0000

-1

-1

S
TPa

-1

ms

TPa

1091.1
1099.7
1113.3
1114.7
1121.6
1160.3

1200.68
1169.47
1107.14
1096.98
1070.16
940.00

91.11
113.42
95.17
93.60
79.98
0.00

1106.0
1474.6
1526.4
1105.5
1103.6
1101.7
1102.3
1110.6
1123.6
1124.8
1131.6
1169.1

1235.90
460.44
434.80
1234.64
1233.60
1222.96
1172.60
1143.10
1083.47
1074.17
1048.35
923.40

0.00
0.00
-72.72
85.81
91.66
115.92
88.59
109.83
91.99
90.80
77.48
0.00

1118.3
1466.4
1521.3
1116.9
1114.9
1113.3
1117.1
1124.2
1133.8
1135.3
1134.8
1178.2

1205.00
465.46
437.17
1204.42
1203.56
1192.45
1143.89
1100.12
1059.95
1050.08
1051.27
906.80

0.00
0.00
-73.17
82.58
88.30
110.48
83.88
88.51
88.20
86.07
99.19
0.00

A 71 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.25. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1) + x2 n-heptano (2) + (1-x1-x2) agua (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

nD

T/K
0.0000
0.0000
0.1278
0.1700
0.2517
0.2665
0.4643
0.4944
0.5827
0.6641
0.6679
0.6822
0.6963
0.7075
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8792
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.6862
0.0590
0.4805
0.4592
0.3665
0.3016
0.2980
0.2886
0.0418
0.2571
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0877
0.0744
0.0256
0.0086
0.0000

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

1.36052
1.32976
1.37240
1.36916
1.36833
1.35336
1.36490
1.36490
1.36255
1.36005
1.35991
1.36028
1.35448
1.35883
1.35764
1.35758
1.35667
1.35577
1.35565
1.35472
1.35356
1.35365
1.35210
1.35116
1.35031

1.36652
1.33125
1.37898
1.37583
1.37375
1.35888
1.37016
1.36964
1.36741
1.36520
1.36502
1.36511
1.35915
1.36392
1.36256
1.36237
1.36175
1.36052
1.36031
1.35958
1.35838
1.35826
1.35645
1.35593
1.35477

1.37211
1.33259
1.38383
1.38382
1.38103
1.36329
1.37635
1.37513
1.37278
1.37046
1.36669
1.37000
1.36352
1.36556
1.36644
1.36735
1.36662
1.36527
1.36492
1.35769
1.36301
1.36290
1.36102
1.36060
1.35922

1.37777
1.33353
1.38978
1.38790
1.38853
1.36808
1.38074
1.38015
1.37755
1.37527
1.37514
1.37479
1.36783
1.37413
1.37251
1.37186
1.37155
1.37019
1.36924
1.36866
1.36768
1.36713
1.36514
1.36491
1.36345

0.00000
0.00000
0.00427
0.00230
0.00282
0.01543
0.00419
0.00452
0.00448
0.00320
0.00314
0.00364
0.00852
0.00307
0.00288
0.00332
0.00246
0.00268
0.00286
0.00212
0.00182
0.00227
0.00179
0.00130
0.00000

0.00000 0.00000
0.00000 0.00000
0.00581 0.00558
0.00400 0.00698
0.00329 0.00558
0.01846 0.02055
0.00468 0.00609
0.00448 0.00518
0.00467 0.00537
0.00370 0.00430
0.00360 0.00061
0.00381 0.00404
0.00948 0.01021
0.00355 0.00058
0.00324 0.00256
0.00357 0.00401
0.00298 0.00331
0.00294 0.00321
0.00303 0.00316
0.00249 -0.00388
0.00219 0.00239
0.00245 0.00268
0.00175 0.00194
0.00170 0.00202
0.00000 0.00000

288.15
0.00000
0.00000
0.00675
0.00634
0.00839
0.02331
0.00596
0.00568
0.00572
0.00470
0.00465
0.00441
0.01112
0.00479
0.00431
0.00422
0.00393
0.00390
0.00323
0.00285
0.00285
0.00272
0.00190
0.00220
0.00000

Tabla A.26. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 etanol (1) + x2 n-heptano (2) + (1-x1-x2) agua (3) en el intervalo de
temperaturas (323.15-288.15) K.

x1

x2

VE

-3

0.0000
0.0000
0.1278

A 72 | A. GAYOL

1.0000
0.0000
0.8021

U
-1

kgm

cm mol

662.4
990.2
663.6

318.15 K
0.0000
0.0000
1.6270

-1

-1

ms

TPa

1043.0
1536.6
1036.5

1387.69
427.70
1402.54

S
TPa

-1

0.00
0.00
113.58

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.26. Continuacin.

x1

x2

VE

-3

kgm
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

663.7
696.5
706.6
714.1
715.3
715.9
727.2
730.0
731.0
738.7
741.2
742.9
753.2
764.6
773.3
768.4

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

664.6
991.2
665.8
665.9
698.8
708.9
716.3
717.5
718.1
729.4
732.2
733.2
740.9
743.4
745.1
755.4
766.7
775.5
770.6

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665

666.7
992.2
668.0
668.2
701.1
711.2

cm mol

u
-1

2.0631
0.0186
-0.0421
-0.0227
-0.1128
-0.0487
-0.1289
-0.0836
-0.1067
-0.1595
-0.0751
-0.0624
-0.0748
-0.0675
-0.3834
0.0000
315.65 K
0.0000
0.0000
1.6073
2.0416
-0.0015
-0.0562
-0.0348
-0.1234
-0.0596
-0.1383
-0.0910
-0.1120
-0.1646
-0.0789
-0.0657
-0.0771
-0.0681
-0.3834
0.0000
313.15 K
0.0000
0.0000
1.5833
2.0132
-0.0229
-0.0744

-1

-1

TPa

1036.3
1033.4
1037.1
1038.9
1039.9
1039.6
1046.8
1048.6
1048.9
1056.0
1056.4
1057.6
1067.1
1077.8
1094.9
1067.5

1402.92
1344.24
1315.48
1297.34
1292.82
1292.44
1254.86
1245.63
1243.14
1213.71
1208.91
1203.25
1165.75
1125.71
1078.59
1141.91

129.88
122.62
119.77
105.80
101.99
100.42
85.81
81.96
77.67
64.27
58.60
53.60
30.54
-0.98
-42.38
0.00

1053.8
1533.2
1047.3
1046.7
1043.8
1047.2
1048.9
1049.7
1049.3
1056.4
1058.
1058.1
1065.2
1065.5
1066.6
1076.0
1086.5
1103.5
1084.3

1355.05
429.16
1369.27
1370.55
1313.23
1286.23
1268.86
1264.87
1264.67
1228.47
1219.70
1217.43
1189.37
1184.73
1179.61
1143.34
1104.83
1058.74
1103.60

0.00
0.00
111.26
128.51
125.42
124.66
112.47
109.22
108.08
94.96
91.67
87.80
75.64
70.56
66.24
44.52
15.00
-25.36
0.00

1064.3
1529.3
1057.7
1057.4
1054.1
1057.3

1324.12
430.91
1337.91
1338.58
1283.58
1257.72

TPa

-1

ms

0.00
0.00
107.15
123.13
119.79
119.07

A 73 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.26. Continuacin.

x1

x2

VE

-3

kgm
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

718.6
719.8
720.4
731.7
734.5
735.5
743.2
745.7
747.3
757.7
769.0
777.7
772.8

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

668.9
993.2
670.2
670.4
703.5
713.5
720.9
722.1
722.7
734.0
736.8
737.8
745.5
747.9
749.6
759.9
771.2
780.0
775.0

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886

671.0
994.0
672.4
672.6
705.8
715.8
723.2
724.4
725.0

A 74 | A. GAYOL

cm mol

u
-1

-0.0485
-0.1375
-0.0737
-0.1477
-0.0996
-0.1210
-0.1715
-0.0859
-0.0707
-0.0811
-0.0700
-0.3828
0.0000
310.65 K
0.0000
0.0000
1.5633
1.9891
-0.0429
-0.0901
-0.0603
-0.1479
-0.0842
-0.1574
-0.1085
-0.1297
-0.1770
-0.0917
-0.0750
-0.0845
-0.0715
-0.3826
0.0000
308.15 K
0.0000
0.0000
1.5421
1.9618
-0.0633
-0.1061
-0.0706
-0.1599
-0.0965

-1

-1

S
TPa

-1

ms

TPa

1058.5
1059.4
1059.1
1065.8
1067.4
1067.7
1074.4
1074.6
1075.6
1084.8
1095.0
1111.6
1092.7

1241.93
1237.70
1237.37
1203.10
1194.72
1192.44
1165.55
1161.20
1156.54
1121.43
1084.48
1039.87
1083.70

108.11
104.58
103.33
91.19
88.05
84.21
72.59
67.75
63.85
42.68
14.29
-24.81
0.00

1075.0
1525.0
1068.4
1068.1
1064.3
1067.3
1068.3
1069.1
1068.8
1075.3
1076.9
1077.1
1083.5
1083.7
1084.6
1093.5
1103.4
1120.4
1101.0

1293.68
432.93
1306.89
1307.43
1254.86
1230.08
1215.40
1211.56
1211.23
1178.24
1170.21
1168.26
1142.51
1138.29
1134.04
1100.43
1064.87
1021.36
1064.40

0.00
0.00
102.87
118.07
114.49
113.73
103.52
100.34
99.09
87.26
84.24
80.76
69.66
64.90
61.35
41.08
13.64
-24.61
0.00

1085.6
1520.2
1079.1
1078.6
1074.6
1077.3
1078.0
1078.9
1078.6

1264.50
435.26
1276.98
1277.97
1226.90
1203.60
1189.80
1185.77
1185.58

0.00
0.00
98.64
113.67
109.23
108.91
99.27
95.87
94.75

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.26. Continuacin.

x1

x2

VE

-3

kgm
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

736.3
739.0
740.1
747.7
750.2
751.8
762.1
773.4
782.2
777.2

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

673.2
994.9
674.6
674.8
708.0
718.1
725.4
726.6
727.2
738.5
741.3
742.3
749.9
752.4
754.0
764.3
775.6
784.3
779.4

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904

675.3
995.7
676.8
677.0
710.3
720.4
727.7
775.6
729.5
740.8
743.5
744.5

cm mol

u
-1

-0.1662
-0.1149
-0.1362
-0.1827
-0.0962
-0.0786
-0.0872
-0.0726
-0.3817
0.0000
305.65 K
0.0000
0.0000
1.5220
1.9388
-0.0800
-0.1197
-0.0813
-0.1695
-0.1063
-0.1734
-0.1216
-0.1427
-0.1869
-0.1007
-0.0830
-0.0901
-0.0744
-0.3804
0.0000
303.15 K
0.0000
0.0000
1.5053
1.9161
-0.0956
-0.1329
-0.0896
-5.2350
-0.1158
-0.1814
-0.1268
-0.1488

-1

-1

S
TPa

-1

ms

TPa

1084.7
1086.3
1086.4
1092.8
1092.8
1093.6
1102.4
1112.0
1128.9
1109.4

1154.35
1146.60
1144.69
1119.78
1116.21
1111.99
1079.69
1045.53
1003.19
1045.40

83.81
80.85
77.44
66.59
62.46
58.89
39.37
12.93
-24.37
0.00

1096.3
1515.1
1089.9
1089.2
1084.8
1087.4
1087.9
1088.6
1088.3
1094.1
1095.6
1095.7
1101.9
1101.9
1102.8
1111.1
1120.6
1137.3
1117.8

1236.01
437.88
1247.84
1248.97
1200.04
1177.68
1164.76
1161.28
1160.98
1131.01
1123.77
1121.96
1098.05
1094.64
1090.49
1059.64
1026.70
985.63
1026.90

0.00
0.00
94.52
109.09
104.45
104.04
94.98
92.11
90.89
80.32
77.65
74.39
63.95
59.95
56.40
37.76
12.17
-24.08
0.00

1107.0
1509.4
1100.7
1100.0
1095.1
1097.4
1097.6
1130.1
1098.1
1103.6
1105.1
1105.1

1208.36
440.80
1219.51
1220.62
1173.75
1152.56
1140.57
1009.49
1136.80
1108.23
1101.28
1099.66

0.00
0.00
90.49
104.47
99.73
99.53
91.12
-39.37
87.03
77.02
74.45
71.41

A 75 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.26. Continuacin.

x1

x2

VE

-3

-1

kgm

cm mol

-0.1901
-0.1049
-0.0852
-0.0929
-0.0759
-0.3798
0.0000
300.65 K
0.0000
0.0000
1.4887
1.8942
-0.1103
-0.1467
-0.0983
-0.1868
-0.1247
-0.1884
-0.1327
-0.1547
-0.1938
-0.1094
-0.0883
-0.0.965
-0.0765
-0.3790
0.0000
298.15 K
0.0000
0.0000
1.4705
1.8739
-0.1255
-0.1591
-0.1068
-0.1950
-0.1337
-0.1946
-0.1383
-0.1603
-0.1977

0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

752.2
754.6
756.2
766.5
777.8
786.5
781.5

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

677.4
996.4
678.9
679.2
712.6
722.6
729.9
731.1
731.7
743.0
745.7
746.7
754.3
756.8
758.4
768.7
779.9
788.7
783.7

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514

6796
997.0
681.1
681.3
714.8
724.9
732.1
733.3
733.9
745.2
747.9
749.0
756.5

A 76 | A. GAYOL

u
-1

-1

S
TPa

-1

ms

TPa

1111.2
1111.0
1111.8
1120.0
1129.2
1145.8
1126.2

1076.70
1073.56
1069.75
1039.84
1008.26
968.32
1008.70

61.37
57.62
54.37
36.14
11.54
-23.77
0.00

1117.6
1503.4
1111.3
1110.7
1105.4
1107.4
1107.4
1108.2
1107.8
1113.1
1114.4
1114.5
1120.4
1120.1
1120.9
1128.9
1137.7
1154.3
1134.6

1181.83
444.05
1192.60
1193.35
1148.43
1128.29
1117.18
1113.69
1113.55
1086.20
1079.65
1078.11
1056.04
1053.06
1049.42
1020.74
990.48
951.55
991.10

0.00
0.00
86.87
99.94
95.12
95.05
87.29
84.35
83.33
73.74
71.37
68.46
58.77
55.17
52.05
34.55
10.94
-23.57
0.00

1128.4
1496.8
1122.0
1121.5
1115.8
1117.5
1117.2
1118.0
1117.6
1122.6
1123.9
1123.9
1129.6

1155.69
447.62
1166.16
1166.81
1123.63
1104.53
1094.24
1090.90
1090.78
1064.75
1058.35
1056.90
1035.85

0.00
0.00
83.37
95.80
90.75
90.80
83.64
80.83
79.84
70.79
68.38
65.61
56.40

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.26. Continuacin.

x1

x2

VE

-3

kgm
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

759.0
760.6
770.9
782.1
790.8
785.8

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

681.7
997.7
683.3
683.5
717.1
727.1
734.3
735.5
736.2
747.4
750.1
751.2
758.7
761.2
762.8
773.1
784.3
793.0
788.0

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220

683.8
998.2
685.4
685.7
719.3
729.3
736.5
737.7
738.4
749.6
752.3
753.3
760.9
763.3
764.9

cm mol

U
-1

-0.1130
-0.0908
-0.0981
-0.0779
-0.3779
0.0000
295.65 K
0.0000
0.0000
1.4526
1.8516
-0.1411
-0.1712
-0.1145
-0.2032
-0.1426
-0.2014
-0.1428
-0.1659
-0.2004
-0.1166
-0.0935
-0.1017
-0.0794
-0.3766
0.0000
293.15 K
0.0000
0.0000
1.4330
1.8291
-0.1556
-0.1844
-0.1229
-0.2115
-0.1513
-0.2077
-0.1491
-0.1716
-0.2053
-0.1211
-0.0969

-1

-1

S
TPa

-1

ms

TPa

1129.3
1129.9
1137.7
1146.3
1162.9
1143.1

1033.09
1029.70
1002.11
972.97
935.02
973.80

53.02
50.11
33.20
10.39
-23.33
0.00

1139.2
1489.9
1132.9
1132.4
1126.2
1127.7
1127.2
1127.9
1127.5
1132.2
1133.4
1133.4
1138.9
1138.5
1139.1
1146.7
1155.1
1171.5
1151.6

1130.37
451.53
1140.27
1140.88
1099.52
1081.39
1071.79
1068.62
1068.49
1043.66
1037.62
1036.23
1016.10
1013.54
1010.29
983.64
955.65
918.85
956.80

0.00
0.00
79.69
91.55
86.48
86.64
79.98
77.30
76.33
67.73
65.49
62.82
54.03
50.85
48.06
31.61
9.63
-23.13
0.00

1150.2
1482.5
1143.9
1143.4
1136.7
1138.1
1137.3
1138.0
1137.6
1142.0
1143.1
1143.0
1148.4
1147.9
1148.4

1105.44
455.80
1114.78
1115.42
1075.85
1058.53
1049.72
1046.66
1046.51
1022.83
1017.11
1015.90
996.42
994.04
991.14

0.00
0.00
76.04
87.42
82.37
82.51
76.45
73.86
72.91
64.71
62.62
60.18
51.52
48.53
46.06

A 77 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.26. Continuacin.

x1

x2

VE

-3

kgm
0.8906
0.9442
0.9591
1.0000

0.0744
0.0256
0.0086
0.0000

775.2
786.4
795.1
790.1

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

685.8
998.7
687.6
687.8
721.5
731.6
738.7
739.9
740.5
751.8
754.5
755.5
763.0
765.5
767.1
777.4
788.5
797.2
792.3

0.0000
0.0000
0.1278
0.1700
0.4944
0.5827
0.6641
0.6679
0.6822
0.7473
0.7668
0.7771
0.8070
0.8343
0.8468
0.8906
0.9442
0.9591
1.0000

1.0000
0.0000
0.8021
0.7541
0.4592
0.3665
0.3016
0.2980
0.2886
0.2163
0.1961
0.1904
0.1514
0.1320
0.1220
0.0744
0.0256
0.0086
0.0000

688.0
999.1
690.4
690.6
724.3
734.4
741.5
742.7
743.4
754.6
757.3
758.3
765.9
768.3
770.0
780.2
791.3
800.1
794.4

A 78 | A. GAYOL

cm mol

U
-1

-0.1048
-0.0809
-0.3763
0.0000
290.65 K
0.0000
0.0000
1.4193
1.8106
-0.1663
-0.1941
-0.1269
-0.2159
-0.1550
-0.2111
-0.1503
-0.1747
-0.2047
-0.1210
-0.0976
-0.1040
-0.0799
-0.3731
0.0000
288.15 K
0.0000
0.0000
1.2628
1.6700
-0.2682
-0.2848
-0.2051
-0.2944
-0.2349
-0.2767
-0.2255
-0.2423
-0.2751
-0.1828
-0.1670
-0.1580
-0.1296
-0.4268
0.0000

-1

-1

S
TPa

-1

ms

TPa

1155.9
1163.9
1180.3
1160.3

965.35
938.60
902.71
940.00

30.01
8.98
-23.05
0.00

1161.3
1474.6
1155.0
1154.6
1147.1
1148.4
1147.3
1148.0
1147.6
1151.8
1152.8
1152.8
1157.9
1157.4
1157.8
1165.1
1172.9
1189.1
1169.1

1081.08
460.44
1090.14
1090.40
1052.76
1036.40
1028.31
1025.32
1025.30
1002.54
997.25
995.90
977.39
975.18
972.39
947.64
921.81
887.06
923.40

0.00
0.00
72.74
83.24
78.45
78.73
73.24
70.70
69.90
61.90
60.08
57.54
49.36
46.56
44.18
28.71
8.32
-22.74
0.00

1172.3
1466.4
1166.2
1165.9
1157.8
1158.5
1157.2
1157.9
1157.3
1161.4
1162.2
1162.3
1167.1
1166.4
1167.1
1173.8
1181.3
1197.7
1178.2

1057.71
465.46
1064.85
1065.18
1029.89
1014.38
1007.07
1004.04
1004.38
982.53
977.43
976.03
958.40
956.59
953.33
930.21
905.49
871.10
906.80

0.00
0.00
67.96
78.08
74.28
74.69
69.90
67.30
66.90
59.17
57.38
54.86
47.10
44.73
41.87
27.62
8.13
-22.74
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.27. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1)+ x2 n-octano (2) (1- x1-x2) agua (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

T/K
0.0000
0.0000
0.0487
0.3265
0.6182
0.7054
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
1.0000
0.0000
0.0000
0.0487
0.3265
0.6182
0.7054
0.7328
0.7689
0.8049
0.8351
0.8588
1.0000

1.0000
0.0000
0.5391
0.0476
0.3294
0.2466
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0000
1.0000
0.0000
0.5391
0.0476
0.3294
0.2466
0.2110
0.1784
0.1517
0.1244
0.0984
0.0000

nD

nD

318.15

308.15

298.15 288.15

318.15

308.15

298.15

288.15

1.32985
1.38489
1.36962
1.38349
1.35195
1.35521
1.35661
1.35814
1.35961
1.36119
1.36278
1.36451
1.35031
1.32985
1.38489
1.36962
1.38349
1.35195
1.35521
1.35661
1.35814
1.35961
1.36119
1.36278
1.35031

1.33131
1.39058
1.37400
1.38786
1.35583
1.35898
1.36064
1.36218
1.36373
1.36533
1.36700
1.36875
1.35477
1.33131
1.39058
1.37400
1.38786
1.35583
1.35898
1.36064
1.36218
1.36373
1.36533
1.36700
1.35477

1.33250
1.39551
1.37917
1.39307
1.36027
1.36378
1.36548
1.36697
1.36849
1.37023
1.37224
1.37371
1.35922
1.33250
1.39551
1.37917
1.39307
1.36027
1.36378
1.36548
1.36697
1.36849
1.37023
1.37224
1.35922

0.00000
0.00000
0.00910
0.04434
-0.00868
-0.00265
0.00016
0.00274
0.00494
0.00741
0.00994
0.01234
0.00000
0.00000
0.00000
0.00910
0.04434
-0.00868
-0.00265
0.00016
0.00274
0.00494
0.00741
0.00994
0.00000

0.00000
0.00000
0.00960
0.04607
-0.00950
-0.00350
-0.00036
0.00226
0.00455
0.00706
0.00971
0.01214
0.00000
0.00000
0.00000
0.00960
0.04607
-0.00950
-0.00350
-0.00036
0.00226
0.00455
0.00706
0.00971
0.00000

0.00000
0.00000
0.01140
0.04884
-0.00950
-0.00311
0.00011
0.00268
0.00492
0.00758
0.01059
0.01273
0.00000
0.00000
0.00000
0.01140
0.04884
-0.00950
-0.00311
0.00011
0.00268
0.00492
0.00758
0.01059
0.00000

0.00000
0.00000
0.01022
0.05210
0.02102
-0.00268
0.00652
0.00055
0.00556
0.00861
0.01089
0.01364
0.00000
0.00000
0.00000
0.01022
0.05210
0.02102
-0.00268
0.00652
0.00055
0.00556
0.00861
0.01089
0.00000

1.33339
1.40040
1.38120
1.39850
1.39506
1.36844
1.37607
1.36901
1.37331
1.37544
1.37669
1.37877
1.36345
1.33339
1.40040
1.38120
1.39850
1.39506
1.36844
1.37607
1.36901
1.37331
1.37544
1.37669
1.36345

Tabla A.28. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 etanol (1)+ x2 n-octano (2) (1- x1-x2 ) agua (3) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

x2

VE

-3

kgm
0.0000
0.0000

1.0000
0.0000

682.5
990.2

cm mol
318.15 K
0.0000
0.0000

u
-1

-1

-1

ms

TPa

TPa

1085.4
1536.6

1243.74
427.70

-1

0.00
0.00

A 79 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.28. Continuacin.

x1

x2

VE

-3

-1

kgm

cm mol

0.9022
-0.2524
0.4370
0.5816
0.1560
0.4389
0.4341
0.3885
0.1988
-0.1651
0.0000
315.65 K
0.0000
0.0000
1.3456
0.0115
0.6628
0.7975
0.3649
0.6396
0.6262
0.5743
0.3772
-0.0009
0.0000
313.15 K
0.0000
0.0000
0.3660
-0.6766
0.1464
0.3082
-0.1001
0.1957
0.2041
0.1714
-0.0047
-0.3419
0.0000
310.615 K
0.0000
0.0000

0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

682.8
721.8
729.5
732.3
739.9
741.2
745.7
750.0
756.6
771.4
768.4

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

684.5
991.2
682.8
721.8
729.5
732.3
739.9
741.2
745.7
750.0
756.6
771.4
770.6

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

686.5
992.2
689.2
729.4
736.3
739.1
746.8
748.0
752.4
756.7
763.3
778.1
772.8

0.0000
0.0000

1.0000
0.0000

688.6
993.2

A 80 | A. GAYOL

u
-1

-1

S
TPa

-1

ms

TPa

1077.7
1078.1
1069.3
1067.6
1075.6
1070.2
1071.3
1072.5
1079.2
1085.4
1067.5

1260.95
1191.78
1198.81
1197.96
1168.01
1177.84
1168.46
1159.03
1134.77
1079.79
1141.90

30.47
53.81
75.59
75.52
41.65
52.18
47.08
36.00
14.51
-38.77
0.00

1095.8
1533.2
1087.9
1091.7
1078.8
1077.1
1085.0
1079.4
1080.3
1081.4
1088.0
1104.2
1084.3

1216.72
429.16
1237.42
1162.30
1177.69
1176.84
1147.99
1157.79
1149.09
1140.17
1116.45
1063.12
1103.60

0.00
0.00
35.39
56.76
88.08
88.51
56.41
67.33
63.12
53.01
32.30
-18.65
0.00

1106.2
1529.3
1098.2
1100.8
1088.3
1086.3
1094.1
1088.4
1089.2
1090.2
1096.7
1112.6
1092.7

1190.35
430.91
1202.93
1131.48
1146.55
1146.51
1118.60
1128.40
1120.13
1111.90
1089.12
1038.07
1083.70

0.00
0.00
26.45
46.91
77.09
78.19
47.07
57.88
53.87
44.44
24.51
-24.36
0.00

1116.5
1525.0

1165.02
432.93

0.00
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.28. Continuacin.

x1

x2

VE

-3

kgm
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

691.3
731.9
738.6
741.4
749..0
750.2
754.7
758.9
765.5
780.4
775.0

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

690.6
994.0
693.4
734.5
740.8
743.6
751.3
752.4
756.9
761.1
767.7
782.6
777.2

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

692.6
994.9
695.5
736.9
743.0
745.8
753.5
754.6
759.0
763.3
769.9
784.7
779.4

0.0000
0.0000

1.0000
0.0000

694.7
995.7

cm mol

u
-1

0.3483
-0.7281
0.1308
0.2950
-0.1119
0.1865
0.1953
0.1641
-0.0095
-0.3431
0.0000
308.15 K
0.0000
0.0000
0.3332
-0.7820
0.1172
0.2842
-0.1211
0.1792
0.1878
0.1595
-0.0119
-0.3427
0.0000
305.65 K
0.0000
0.0000
0.3169
-0.8276
0.1037
0.2724
-0.1306
0.1707
0.1812
0.1543
-0.0161
-0.3437
0.0000
303.15 K
0.0000
0.0000

-1

-1

S
TPa

-1

ms

TPa

1108.4
1109.8
1097.7
1095.6
1103.3
1097.6
1098.2
1099.0
1105.5
1121.0
1101.0

1177.40
1109.30
1123.58
1123.68
1096.71
1106.44
1098.71
1090.79
1068.83
1019.60
1064.40

25.47
44.91
73.49
74.62
44.47
55.12
51.44
42.30
23.04
-24.21
0.00

1126.9
1520.2
1118.7
1121.2
1107.2
1105.0
1112.6
1106.6
1107.2
1107.9
1114.2
1129.6
1109.4

1140.24
435.26
1152.24
1083.01
1100.93
1101.41
1075.28
1085.27
1077.72
1070.34
1049.18
1001.43
1045.40

0.00
0.00
24.34
38.41
69.87
71.27
42.00
52.81
49.12
40.51
21.90
-24.04
0.00

1137.2
1515.1
1129.0
1131.3
1116.7
1114.3
1121.8
1115.7
1116.1
1116.7
1122.9
1138.1
1117.8

1116.43
437.88
1127.80
1060.16
1079.13
1079.84
1054.51
1064.54
1057.54
1050.50
1030.03
983.81
1026.90

0.00
0.00
23.02
34.67
66.46
67.99
39.58
50.34
47.01
38.73
20.68
-23.89
0.00

1147.5
1509.4

1093.24
440.80

0.00
0.00

A 81 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.28. Continuacin.

x1

x2

VE

-3

kgm
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

697.6
739.4
745.3
748.0
755.7
756.8
761.3
765.5
772.1
786.9
781.5

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

696.7
996.4
699.7
741.6
747.5
750.1
757.9
759.0
763.4
767.6
774.3
789.1
783.7

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

698.7
997.0
701.8
743.6
749.6
752.3
760.1
761.1
765.6
769.8
776.4
791.2
785.8

0.0000

1.0000

700.7

A 82 | A. GAYOL

cm mol

u
-1

0.3042
-0.8652
0.0914
0.2616
-0.1389
0.1639
0.1748
0.1498
-0.0186
-0.3423
0.0000
300.65 K
0.0000
0.0000
0.2904
-0.8834
0.0796
0.2523
-0.1485
0.1563
0.1681
0.1445
-0.0219
-0.3423
0.0000
298.15 K
0.0000
0.0000
0.2803
-0.8663
0.0681
0.2430
-0.1572
0.1498
0.1639
0.1401
-0.0249
-0.3419
0.0000
295.65 K
0.0000

-1

-1

S
TPa

-1

ms

TPa

1139.4
1141.6
1126.3
1123.7
1131.1
1124.9
1125.2
1125.6
1131.7
1146.5
1126.2

1104.00
1037.76
1057.67
1058.76
1034.17
1044.17
1037.55
1031.03
1011.17
966.63
1008.70

21.76
31.01
63.08
64.90
37.28
47.95
44.83
37.07
19.50
-23.53
0.00

1157.8
1503.4
1149.8
1151.5
1135.8
1133.0
1140.4
1134.0
1134.2
1134.5
1140.4
1155.0
1134.6

1070.78
444.05
1080.95
1016.84
1037.05
1038.31
1014.51
1024.49
1018.25
1011.98
992.99
949.90
991.10

0.00
0.00
20.54
28.18
59.89
61.79
35.03
45.60
42.69
35.18
18.36
-23.37
0.00

1168.2
1496.8
1160.2
1161.7
1145.3
1142.5
1149.7
1143.2
1143.1
1143.4
1149.2
1163.5
1143.1

1048.76
447.62
1058.52
996.42
1016.85
1018.23
995.18
1005.24
999.50
993.49
975.05
933.49
973.80

0.00
0.00
19.53
25.55
56.86
58.80
32.87
43.44
40.86
33.63
17.23
-23.09
0.00

1178.7

1027.19

0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.28. Continuacin.

x1

x2

VE

-3

kgm
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

997.7
703.8
745.3
751.8
754.5
762.3
763.3
767.7
771.9
778.6
793.4
788.0

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

702.7
998.2
705.9
746.6
754.0
756.6
764.4
765.4
769.9
774.1
780.7
795.5
790.1

0.0000
0.0000
0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

1.0000
0.0000
0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

704.7
998.7
707.9
748.4
756.1
758.7
766.6
767.5
772.0
776.2
782.8
797.6
792.3

0.0000
0.0000

1.0000
0.0000

706.8
999.1

cm mol

u
-1

0.0000
0.2723
-0.8135
0.0586
0.2343
-0.1652
0.1444
0.1577
0.1376
-0.0267
-0.3412
0.0000
293.15 K
0.0000
0.0000
0.2632
-0.7227
0.0486
0.2257
-0.1724
0.1398
0.1536
0.1338
-0.0282
-0.3406
0.0000
290.65 K
0.0000
0.0000
0.2577
-0.6865
0.0411
0.2202
-0.1759
0.1375
0.1517
0.1338
-0.0263
-0.3382
0.0000
288.15 K
0.0000
0.0000

-1

-1

S
TPa

-1

ms

TPa

1489.9
1170.7
1171.8
1155.0
1152.1
1159.2
1152.4
1152.3
1152.4
1158.1
1172.1
1151.6

451.53
1036.60
977.07
997.02
998.56
976.19
986.42
980.85
975.41
957.53
917.31
956.80

0.00
18.58
23.60
53.80
55.84
30.65
41.33
38.75
32.10
16.14
-22.95
0.00

1189.3
1482.5
1181.4
1182.2
1164.8
1161.7
1168.8
1161.8
1161.6
1161.6
1167.2
1180.9
1160.3

1006.07
455.80
1014.89
958.30
977.40
979.19
957.50
967.84
962.61
957.41
940.21
901.27
940.00

0.00
0.00
17.43
21.97
50.73
52.94
28.51
39.26
36.85
30.46
15.07
-22.86
0.00

1200.0
1474.6
1192.1
1192.5
1174.6
1171.3
1178.4
1171.2
1170.9
1170.7
1176.2
1189.8
1169.1

985.39
460.44
993.96
939.54
958.48
960.53
939.34
949.68
944.82
940.01
923.32
885.60
923.40

0.00
0.00
16.65
20.02
48.06
50.47
26.64
37.32
35.13
29.16
14.17
-22.64
0.00

1211.0
1466.4

964.82
465.46

0.00
0.00

A 83 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.28. Continuacin.

x1

x2

0.1282
0.6182
0.7328
0.7689
0.8049
0.8351
0.8588
0.8870
0.9091
0.9602
1.0000

0.8716
0.3294
0.2110
0.1784
0.1517
0.1244
0.0984
0.0758
0.0530
0.0062
0.0000

VE

kgm

-3

cm mol

-1

710.6
750.8
758.9
761.5
769.4
770.3
774.8
779.0
785.6
800.5
794.4

0.1165
-0.7316
-0.0340
0.1495
-0.2409
0.0747
0.0912
0.0760
-0.0793
-0.3855
0.0000

-1

-1

ms

TPa

1202.7
1202.6
1184.2
1180.8
1187.7
1180.5
1180.0
1179.6
1185.1
1198.2
1178.2

972.84
920.86
939.50
941.74
921.37
931.51
926.95
922.45
906.33
870.08
906.80

TPa

-1

15.59
18.11
45.30
47.86
24.93
35.37
33.33
27.69
13.18
-22.25
0.00

Tabla A.29. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla ternaria x1 etanol (1)+ x2 n-nonano (2) (1- x1-x2) agua (3) en el
intervalo de temperaturas (318.15- 288.15) K.

x1

x2

T/K
0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0098
0.0000

A 84 | A. GAYOL

nD

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

1.39368
1.32976
1.35426
1.35474
1.35426
1.35375
1.35376
1.35255
1.35031

1.39718
1.33125
1.35874
1.35911
1.35869
1.35819
1.35816
1.35708
1.35477

1.40298
1.33259
1.36287
1.36412
1.36316
1.36241
1.36225
1.36146
1.35922

1.40749
1.33353
1.36711
1.36782
1.36778
1.36699
1.36658
1.36563
1.36345

0.00000
0.00000
0.00846
0.00749
0.00644
0.00617
0.00606
0.00293
0.00000

0.00000
0.00000
0.00921
0.00798
0.00690
0.00664
0.00646
0.00318
0.00000

0.00000
0.00000
0.00965
0.00913
0.00741
0.00690
0.00657
0.00327
0.00000

0.00000
0.00000
0.01046
0.00922
0.00832
0.00778
0.00717
0.00339
0.00000

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.30. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla ternaria x1 etanol (1)+ x2 n-nonano (2) (1- x1-x2 ) agua (3) en el intervalo de
temperaturas (318.15- 288.15) K.

x1

x2

VE

-3

kgm
0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

698.3
990.2
795.3
784.1
780.7
783.5
783.8
772.4
773.1
768.4

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

700.2
991.2
797.6
786.3
782.9
785.7
786.0
774.5
775.3
770.6

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

702.2
992.2
799.8
788.6
785.2
788.0
788.3
776.8
777.5
772.8

0.0000
0.0000
0.7523
0.7942

1.0000
0.0000
0.0087
0.0180

704.2
993.2
802.1
790.8

cm mol

u
-1

318.15 K
0.0000
0.0000
-0.6535
-0.4108
-0.3374
-0.4275
-0.4761
-0.1124
-0.2321
0.0000
315.65 K
0.0000
0.0000
-0.6588
-0.4179
-0.3415
-0.4312
-0.4796
-0.1140
-0.2337
0.0000
313.15 K
0.0000
0.0000
-0.6648
-0.4244
-0.3474
-0.4381
-0.4850
-0.1163
-0.2367
0.0000
310.65 K
0.0000
0.0000
-0.6710
-0.4300

-1

ms

TPa

-1

S
TPa

-1

1123.9
1536.6
1156.8
1133.3
1122.6
1126.8
1127.0
1093.9
1097.5
1067.5

1133.70
427.70
939.56
993.01
1016.20
1005.04
1004.30
1081.87
1073.77
1141.90

0.00
0.00
-31.59
-14.64
-13.01
-24.27
-30.79
-16.93
-28.95
0.00

1133.9
1533.2
1165.3
1142.2
1131.4
1135.5
1135.7
1102.4
1106.1
1084.3

1110.76
429.16
923.21
974.67
997.75
987.04
986.38
1062.30
1054.25
1103.60

0.00
0.00
-19.36
-2.50
0.23
-10.49
-16.60
-0.81
-12.59
0.00

1143.8
1529.3
1173.8
1150.9
1140.0
1144.1
1144.2
1110.9
1114.6
1092.7

1088.53
430.91
907.31
957.22
979.98
969.40
968.86
1043.19
1035.16
1083.70

0.00
0.00
-20.42
-3.98
-0.91
-11.52
-17.33
-1.19
-12.83
0.00

1153.6
1525.0
1182.3
1159.5

1067.13
432.93
891.78
940.46

0.00
0.00
-21.72
-5.40

A 85 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.30. Continuacin.

x1

x2

VE

-3

kgm
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

787.4
790.3
790.6
779.0
779.8
775.0

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

706.1
994.0
804.4
793.1
789.7
792.5
792.8
781.2
782.0
777.2

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

647.8
708.1
994.9
806.6
795.3
791.9
794.7
795.0
783.4
779.4

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

710.1
995.7
808.8
797.5
794.1
796.9
797.2
785.6
786.4
781.5

0.0000
0.0000

1.0000
0.0000

712.0
996.4

A 86 | A. GAYOL

cm mol

U
-1

-0.3533
-0.4428
-0.4907
-0.1203
-0.2403
0.0000
308.15 K
0.0000
0.0000
-0.6766
-0.4363
-0.3584
-0.4478
-0.4942
-0.1219
-0.2410
0.0000
305.65 K
0.0000
0.0000
0.0000
-0.6822
-0.4430
-0.3636
-0.4525
-0.4983
-0.1244
0.0000
303.15 K
0.0000
0.0000
-0.6877
-0.4478
-0.3682
-0.4567
-0.5026
-0.1267
-0.2449
0.0000
300.65 K
0.0000
0.0000

-1

ms

TPa

-1

S
TPa

-1

1148.5
1152.6
1152.9
1119.4
1123.1
1101.0

962.61
952.49
951.58
1024.31
1016.56
1064.40

-2.30
-12.45
-18.46
-2.03
-13.26
0.00

1163.6
1520.2
1190.8
1168.2
1157.2
1161.2
1161.3
1127.7
1131.5
1109.4

1045.94
435.26
876.67
923.94
945.65
935.71
935.20
1006.42
998.72
1045.40

0.00
0.00
-22.89
-6.87
-3.57
-13.55
-19.00
-2.18
-13.24
0.00

1035.7
1173.6
1515.1
1199.3
1177.0
1165.8
1169.7
1169.8
1136.3
1117.8

1439.00
1025.38
437.88
861.96
907.61
929.12
919.66
919.10
988.64
1026.90

0.00
0.00
0.00
-24.17
-8.67
-4.94
-14.45
-19.78
-2.76
0.00

1183.6
1509.4
1207.8
1184.1
1174.3
1178.3
1178.4
1144.8
1148.6
1126.2

1005.31
440.80
847.48
894.24
913.10
903.77
903.15
971.21
963.83
1008.70

0.00
0.00
-25.48
-7.77
-6.05
-15.44
-20.65
-3.24
-13.74
0.00

1193.6
1503.

985.83
444.05

0.00
0.00

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.30. Continuacin.

x1

x2

VE

-3

kgm
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

811.0
799.7
796.3
799.1
799.4
787.7
788.6
783.7

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

714.0
997.0
813.2
801.9
798.5
801.3
801.6
789.9
790.7
785.8

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

715.9
997.7
815.4
804.1
800.6
803.5
803.8
792.1
792.9
788.0

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

717.8
998.2
817.6
806.2
802.8
805.7
806.0
794.2
795.1
790.1

0.0000

1.0000

719.8

cm mol

u
-1

-0.6935
-0.4550
-0.3736
-0.4619
-0.5075
-0.1295
-0.2478
0.0000
298.15 K
0.0000
0.0000
-0.6994
-0.4618
-0.3790
-0.4661
-0.5111
-0.1317
-0.2501
0.0000
295.65 K
0.0000
0.0000
-0.7038
-0.4662
-0.3834
-0.4706
-0.5147
-0.1335
-0.2518
0.0000
293.15 K
0.0000
0.0000
-0.7099
-0.4702
-0.3894
-0.4756
-0.5193
-0.1369
-0.2546
0.0000
290.65 K
0.0000

-1

ms

TPa

-1

S
TPa

-1

1216.2
1190.3
1182.9
1186.8
1187.0
1153.3
1157.1
1134.6

833.54
882.54
897.46
888.38
887.75
954.36
947.10
991.10

-26.80
-5.77
-7.36
-16.51
-21.58
-3.76
-14.02
0.00

1203.7
1496.8
1224.7
1200.9
1191.5
1195.3
1195.6
1161.8
1165.7
1143.1

966.70
447.62
819.78
864.53
882.04
873.31
872.66
937.82
930.61
973.80

0.00
0.00
-28.19
-10.32
-8.69
-17.51
-22.42
-4.19
-14.28
0.00

1214.0
1489.9
1233.2
1207.8
1200.2
1204.0
1204.3
1170.4
1174.3
1151.6

947.79
451.53
806.40
852.45
866.98
858.48
857.77
921.52
914.45
956.80

0.00
0.00
-29.57
-9.30
-10.03
-18.62
-23.42
-4.75
-14.58
0.00

1224.3
1482.5
1241.9
1217.8
1209.1
1212.8
1213.2
1179.2
1183.2
1160.3

929.39
455.80
792.96
836.23
851.95
843.74
842.98
905.34
898.43
940.00

0.00
0.00
-31.20
-12.63
-11.53
-19.84
-24.53
-5.36
-14.92
0.00

1234.9

911.03

0.00

A 87 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.30. Continuacin.

x1

x2

VE

-3

-1

kgm

cm mol

0.0000
-0.7144
-0.4387
-0.3930
-0.4777
-0.5215
-0.1378
-0.2542
0.0000
288.15 K
0.0000
0.0000
-0.7558
-0.4891
-0.4405
-0.5226
-0.5653
-0.1835
-0.3003
0.0000

0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

998.7
819.8
807.9
805.0
807.8
808.1
796.4
797.2
792.3

0.0000
0.0000
0.7523
0.7942
0.8254
0.8312
0.8403
0.9317
0.9354
1.0000

1.0000
0.0000
0.0087
0.0180
0.0170
0.0113
0.0103
0.0080
0.0098
0.0000

721.7
999.1
822.5
810.7
807.8
810.6
810.9
7991
800.0
794.4

u
-1

ms

TPa

-1

TPa

-1

1474.6
1250.7
1223.9
1217.9
1221.6
1222.1
1188.1
1192.0
1169.1

460.44
779.76
826.31
837.39
829.42
828.46
889.47
882.70
923.40

0.00
-32.89
-9.92
-12.82
-20.91
-25.62
-5.93
-15.22
0.00

1245.4
1466.4
1259.1
1232.7
1226.4
1230.3
1230.7
1196.6
1200.6
1178.2

893.38
465.46
766.76
811.63
822.95
815.00
814.15
873.80
867.09
906.80

0.00
0.00
-34.45
-12.05
-14.06
-22.12
-26.55
-6.28
-15.40
0.00

Tabla A.31. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria %1 Tween 20 (1) %2 agua (2) en el intervalo de temperaturas
(318.15- 288.15) K.

%1

x1

T/K
0.000
4.015
8.652
17.659
30.204
40.356
49.932
67.212
78.462
89.526
100.000

0.000
0.005
0.014
0.026
0.052
0.074
0.107
0.204
0.302
0.510
1.000

A 88 | A. GAYOL

nD

nD

318.15

308.15

298.15

288.15

318.15

308.15

298.15

288.15

1.32976
1.33482
1.34053
1.35269
1.37009
1.38777
1.39769
1.43295
1.43779
1.45208
1.46180

1.33125
1.33618
1.34215
1.35487
1.37383
1.38600
1.40293
1.43601
1.44111
1.45550
1.46535

1.33259
1.33753
1.34369
1.35676
1.37603
1.38839
1.40603
1.43997
1.44440
1.45902
1.46895

1.33353
1.33861
1.34491
1.35829
1.37788
1.39053
1.40860
1.44406
1.44739
1.46265
1.47253

0.00000
0.00439
0.00926
0.01956
0.03370
0.04792
0.05358
0.07673
0.06734
0.05485
0.00000

0.00000
0.00425
0.00936
0.02019
0.03584
0.04450
0.05711
0.07789
0.06854
0.05572
0.00000

0.00000
0.00425
0.00954
0.02069
0.03659
0.04538
0.05862
0.08005
0.06979
0.05675
0.00000

0.00000
0.00437
0.00979
0.02121
0.03737
0.04638
0.05996
0.08267
0.07103
0.05809
0.00000

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.32. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla binaria %1 Tween 20 (1) %2 agua (2) en el intervalo de temperaturas (318.15-288.15) K.
%1

x1

VE

-3

kgm
0.000
4.015
17.659
8.652
30.204
40.356
49.932
67.212
78.462
89.526
100.000

0.000
0.005
0.026
0.014
0.052
0.074
0.107
0.204
0.302
0.510
1.000

990.2
996.3
1012.4
1.001.5
1.027.0
1038.7
1050.8
1069.2
1078.1
1082.8
1083.7

0.000
4.015
17.659
8.652
30.204
40.356
49.932
67.212
78.462
89.526
100.000

0.000
0.005
0.026
0.014
0.052
0.074
0.107
0.204
0.302
0.510
1.000

994.0
998.9
1015.6
1004.5
1031.6
1044.8
1057.3
1075.4
1086.6
1091.2
1091.5

0.000
4.015
17.659
8.652
30.204
40.356
49.932
67.212
78.462
89.526
100.000

0.000
0.005
0.026
0.014
0.052
0.074
0.107
0.204
0.302
0.510
1.000

997.0
1002.1
1019.8
1008.0
1036.7
1050.7
1063.9
1083.6
1094.9
1099.5
1099.6

0.000
4.015
17.659
8.652
30.204
40.356
49.932

0.000
0.005
0.026
0.014
0.052
0.074
0.107

999.1
1004.5
1023.2
1010.7
1041.1
1056.0
1070.3

u
-1

cm mol
318.15 K
0.0000
0.0056
0.0198
0.0102
0.0321
0.0413
0.0504
0.0602
0.0591
0.0448
0.0000
308.15 K
0.0000
0.0043
0.0191
0.0093
0.0327
0.0433
0.0527
0.0619
0.0626
0.0473
0.0000
298.15 K
0.0000
0.0046
0.0202
0.0098
0.0345
0.0458
0.0557
0.0660
0.0662
0.0500
0.0000
288.15 K
0.0000
0.0048
0.0214
0.0104
0.0366
0.0486
0.0594

-1

-1

S
TPa

-1

ms

TPa

1536.62
1543.10
1562.89
1549.60
1582.59
1595.22
1603.62
1598.28
1572.32
1534.64
1487.81

427.70
421.52
404.36
415.80
388.75
378.32
370.05
366.11
375.19
392.11
416.85

0.00
-5.74
-21.42
-10.96
-35.67
-45.00
-52.23
-54.29
-44.00
-25.88
0.00

1520.30
1528.46
1558.50
1538.46
1588.11
1608.50
1624.35
1624.94
1605.29
1567.64
1520.35

435.26
428.51
405.34
420.60
384.34
369.92
358.44
352.14
357.10
372.90
396.32

0.00
-5.18
-23.04
-11.29
-39.16
-49.63
-57.38
-56.95
-47.61
-27.51
0.00

1496.89
1508.31
1548.64
1521.19
1586.57
1619.42
1643.90
1659.17
1637.87
1600.71
1553.90

447.62
438.60
408.84
428.68
383.20
362.91
347.80
335.21
340.45
354.96
376.61

0.00
-6.17
-26.23
-12.79
-42.97
-56.05
-64.37
-64.68
-51.46
-29.09
0.00

1466.40
1480.50
1532.71
1497.34
1584.94
1627.40
1661.58

465.46
454.17
415.99
441.26
382.34
357.53
338.39

0.00
-6.97
-30.45
-14.88
-50.59
-64.46
-73.28

A 89 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.32. Continuacin.

%1

x1

VE

-3

67.212
78.462
89.526
100.000

0.204
0.302
0.510
1.000

kgm
1091.4
1103.1
1107.7
1107.7

cm mol
0.0705
0.0705
0.0530
0.0000

u
-1

-1

ms
1685.28
1670.94
1635.07
1588.51

-1

TPa
322.59
324.68
337.67
357.74

-1

TPa
-70.47
-56.26
-31.35
0.00

Tabla A.33. Influencia de la composicin sobre los ndices de refraccin, las variaciones de ndices
de refraccin de la mezcla binaria %1 Triton X-102 (1) %2 agua (2) en el intervalo de
temperaturas (318.15- 288.15) K.
%1
T/K
0.000
4.442
10.234
19.451
31.577
39.676
50.442
59.454
69.120
80.711
90.303
100.000

x1
0.000
0.001
0.003
0.006
0.012
0.016
0.025
0.035
0.053
0.095
0.191
1.000

318.15
1.32976
1.33743
1.34543
1.35879
1.37781
1.38929
1.40762
1.42153
1.43858
1.45488
1.46797
1.47978

nD
308.15 298.15
1.33125 1.33259
1.33872 1.34007
1.34678 1.34830
1.36071 1.36247
1.37985 1.38191
1.39191 1.39435
1.41056 1.41335
1.42537 1.42838
1.44190 1.44514
1.45845 1.46205
1.47163 1.47536
1.48357 1.48738

288.15
1.33353
1.34114
1.34958
1.36403
1.38379
1.39658
1.41607
1.43141
1.44811
1.46558
1.47909
1.49122

318.15
0.00000
0.00626
0.01225
0.02197
0.03511
0.04175
0.05202
0.05717
0.06172
0,05595
0.03985
0.00000

nD
308.15 298.15
0.00000 0.00000
0.00604 0.00602
0.01206 0.01218
0.02229 0.02260
0.03547 0.03597
0.04260 0.04341
0.05307 0.05409
0.05899 0.06009
0.06282 0.06395
0.05697 0.05809
0.04051 0.04128
0.00000 0.00000

288.15
0.00000
0.00613
0.01246
0.02308
0.03666
0.04436
0.05538
0.06151
0.06507
0.05934
0.04217
0.00000

Tabla A.34. Influencia de la composicin sobre la densidad, el volumen de exceso, la velocidad del
sonido, la compresibilidad isoentrpica, la variacin de la compresibilidad isoentrpica de la
mezcla binaria %1 Triton X-102 (1) %2 agua (2) en el intervalo de temperaturas (318.15- 288.15)
K.
%1

x1

VE

-3

kgm
0.000
4.442
10.234
19.451
31.577
39.676
60.420
69.120
80.711
90.303

0.000
0.001
0.003
0.006
0.012
0.016
0.036
0.053
0.095
0.191

A 90 | A. GAYOL

990.2
994.6
999.4
1007.6
1018.5
1026.0
1044.8
1050.2
1055.5
1056.0

u
-1

cm mol
318.15 K
0.0000
54.1855
115.7764
183.3834
220.1893
211.2045
78.3276
14.1510
-64.6292
-68.7833

-1

ms-

TPa

1536.62
1541.04
1546.03
1555.01
1567.52
1575.38
1583.04
1576.28
1549.26
1513.61

427.70
423.33
418.62
410.42
399.56
392.71
381.93
383.21
394.70
413.32

S
TPa

-1

0.00
-4.97
-10.47
-19.94
-32.45
-40.41
-54.01
-53.93
-44.03
-26.71

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.34. Continuacin.

%1

x1

VE

-3

100.000

1.000

kgm
1053.2

0.000
4.442
10.234
19.451
31.577
39.676
60.420
69.120
80.711
90.303
100.000

0.000
0.001
0.003
0.006
0.012
0.016
0.036
0.053
0.095
0.191
1.000

994.0
998.7
1003.8
1012.6
1024.2
1032.1
1053.3
1058.2
1063.6
1064.0
1060.9

0.000
4.442
10.234
19.451
31.577
39.676
60.420
69.120
80.711
90.303
100.000

0.000
0.001
0.003
0.006
0.012
0.016
0.036
0.053
0.095
0.191
1.000

997.0
1002.1
1007.5
1016.9
1029.4
1037.9
1060.6
1066.1
1071.8
1072.1
1068.7

0.000
4.442
10.234
19.451
31.577
39.676
60.420
69.120
80.711
90.303
100.000

0.000
0.001
0.003
0.006
0.012
0.016
0.036
0.053
0.095
0.191
1.000

999.1
1004.5
1010.3
1020.5
1034.1
1043.3
1067.9
1074.1
1080.0
1080.2
1076.7

u
-1

cm mol
0.0000
308.15 K
0.0000
56.8708
121.4063
192.0079
229.6503
220.6059
62.8573
8.19573
-72.1300
-73.9967
0.0000
298.15 K
0.0000
60.3259
128.7517
203.4934
242.8357
232.6769
64.8802
4.04516
-78.5867
-77.9916
0.0000
288.15 K
0.0000
64.7017
138.0822
218.2626
260.3440
248.8713
70.5003
0.0110
-83.0316
-80.9451
0.0000

-1

S
-1

ms1466.72

TPa
441.36

TPa
0.00

1520.30
1527.81
1536.30
1551.76
1573.89
1587.87
1611.47
1607.04
1582.33
1546.76
1500.74

435.26
428.93
422.08
410.12
394.12
384.27
365.59
365.91
375.48
392.81
418.50

0.00
-5.58
-11.46
-21.88
-35.84
-44.34
-59.54
-57.76
-46.25
-27.31
0.00

1496.89
1507.97
1520.33
1543.14
1576.32
1597.18
1638.41
1637.66
1616.47
1581.60
1536.06

447.62
438.82
429.42
412.95
390.92
377.67
351.20
349.74
357.05
372.88
396.55

0.00
-6.53
-12.97
-24.73
-40.57
-49.68
-65.55
-62.58
-49.35
-28.62
0.00

1466.40
1480.83
1497.26
1528.40
1574.10
1604.01
1665.22
1669.69
1653.12
1617.02
1572.88

465.46
453.95
441.50
419.47
390.27
372.54
337.70
333.94
338.82
354.04
375.41

0.00
-7.51
-14.74
-28.47
-46.75
-57.20
-73.34
-69.27
-53.96
-30.10
0.00

A 91 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.35. Influencia de la composicin sobre los ndices de refraccin de la mezcla binaria %1
Na2SO4 (1) %2 agua (2) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K
0.000
1.943
4.948
5.404
10.936
13.863
17.352
22.617

nD
318.15
1.32976
1.33318
1.33765
1.33772
1.34574
1.33318
1.34968
1.37267

308.15
1.33125
1.33460
1.33857
1.33922
1.34733
1.33922
1.35114
1.37491

298.15
1.33259
1.33590
1.33988
1.34057
1.34694
1.34057
1.35275
1.33988

288.15
1.33353
1.33695
1.34105
1.34181
1.34873
1.34181
1.35427
1.34105

Tabla A.36. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla binaria %1 Na2SO4 (1) %2 agua (2) en el intervalo de
temperaturas (318.15-288.15) K.
%1

u
-3

-1

gcm

ms

TPa

-1

318.15 K
0.000
1.943
4.948
5.404
10.936
13.863
17.352
22.617

990.2
1007.1
1033.6
1037.7
1088.7
1116.8
1151.4
1151.2

0.000
1.943
4.948
5.404
10.936
13.863
17.352
22.617

994.0
1011.2
1037.9
1042.0
1093.5
1121.8
1156.6
1156.72

1536.62
1555.96
1586.19
1589.47
1646.98
1678.12
1718.53
1718.66

427.70
410.10
384.53
381.44
338.62
317.96
294.07
294.08

1520.30
1541.05
1572.47
1576.44
1637.47
1670.35
1713.74
1713.79

435.26
416.41
389.65
386.15
341.06
319.49
294.38
294.34

1496.89
1519.07
1552.80
1557.16
1622.15
1657.91

447.62
427.16
398.18
394.36
346.17
322.99

308.15 K

298.15 K
0.000
1.943
4.948
5.404
10.936
13.863

A 92 | A. GAYOL

997.0
1014.4
1041.5
1045.7
1097.8
1126.4

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.36. Continuacin.

%1

u
-3

17.352
22.617

gcm
1161.5
1161.6

0.000
1.943
4.948
5.404
10.936
13.863
17.352
22.617

999.1
1016.9
1044.5
1048.7
1101.6
1130.5
1166.0
1166.1

-1

-1

ms
1704.43
1704.64

TPa
296.36
296.26

1466.40
1489.53
1526.05
1530.96
1600.63
1639.17
1689.78
1689.78

465.46
443.21
411.10
406.80
354.32
329.21
300.35
300.33

288.15 K

Tabla A.37. Influencia de la composicin sobre los ndices de refraccin de la mezcla binaria %1
Na2S2O3 (1) %2 agua (2) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K

318.15

308.15

nD
298.15

288.15

0.000
4.637
9.773
15.250
19.264
25.337
29.775
31.747

1.32976
1.33775
1.35007
1.36103
1.37197
1.38553
1.39493
1.39944

1.33125
1.33929
1.35113
1.36209
1.37442
1.38796
1.39574
1.40038

1.33259
1.34073
1.35264
1.36343
1.37621
1.38974
1.39716
1.40190

1.33353
1.34193
1.35405
1.36500
1.37793
1.39165
1.39911
1.40381

Tabla A.38. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla binaria %1 Na2S2O3 (1) %2 agua (2) en el intervalo de
temperaturas (318.15-288.15) K.
%1

u
-3

-1

kgm

-1

ms

TPa

1536.62
1577.18
1622.21
1675.20
1720.47
1785.74
1839.15
1865.91
1875.58

427.70
391.20
355.21
319.02
292.22
259.17
235.93
225.31
221.54

318.15 K
0.000
4.637
9.773
15.250
19.264
25.337
29.775
31.747
32.590

990.2
10276
1069.7
1116.9
1156.1
1209.9
1253.0
1274.8
1283.1

A 93 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.38. Continuacin.

%1

u
-3

-1

kgm

-1

ms

TPa

1520.30
1562.97
1610.99
1667.62
1715.94
1786.20
1843.38
1872.26
1883.07

435.26
396.69
358.59
320.44
292.37
257.79
233.72
222.70
218.72

1496.89
1542.63
1594.31
1655.02
1707.35
1783.36
1845.25
1876.53
1888.28

447.62
405.79
364.69
323.96
294.02
257.43
232.16
220.65
216.50

1466.404
1515.45
1571.66
1636.80
1694.35
1776.79
1844.55
1878.28
1891.26

465.46
419.30
374.01
329.94
297.32
258.20
231.29
219.25
214.84

308.15 K
0.000
4.637
9.773
15.250
19.264
25.337
29.775
31.747
32.590

994.0
1031.9
1074.5
1122.1
1161.5
1215..8
1259.1
1281.0
1289.3

0.000
4.637
9.773
15.250
19.264
25.337
29.775
31.747
32.590

997.0
1035.5
1078.7
1126.9
1166.7
1221.4
1265.0
1287.0
1295.4

298.15 K

288.15 K
0.000
4.637
9.773
15.250
19.264
25.337
29.775
31.747
32.590

999.1
1038.4
1082.4
1131.2
1171.5
1226.7
1270.7
1292.8
1301.3

Tabla A.39. Influencia de la composicin sobre los ndices de refraccin de la mezcla binaria %1
K2HPO4 (1) %2 agua (2) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K

318.15

308.15

298.15

288.15

0.000
5.668
10.942
21.225
30.916
41.184
50.435
57.731

1.32976
1.33699
1.34319
1.36237
1.37821
1.39394
1.41028
1.42227

1.33125
1.33841
1.34454
1.36349
1.37911
1.39598
1.41145
1.42378

1.33259
1.33971
1.34596
1.36513
1.38060
1.39762
1.41296
1.42518

1.33353
1.34084
1.34723
1.36667
1.38215
1.39918
1.41458
1.42659

A 94 | A. GAYOL

nD

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.40. Influencia de la composicin sobre la densidad, la velocidad del sonido, la
compresibilidad isoentrpica de la mezcla binaria %1 K2HPO4 (1) %2 agua (2) en el intervalo de
temperaturas (318.15-288.15) K.
%1

u
-3

-1

kgm

-1

ms

TPa

1583.49
1628.72
1728.33
1847.40
2005.92
2165.97
1593.68
1583.49

383.87
347.16
283.05
227.87
176.51
139.40
375.37
383.87

1569.87
1617.06
1722.20
1847.53
2013.02
2178.26
1579.85
1569.87

388.96
350.69
283.83
226.87
174.56
137.31
380.40
388.96

1549.73
1599.80
1711.78
1844.80
2018.24
2189.68
1560.61
1549.73

397.75
356.96
286.14
226.61
172.98
135.38
388.46
397.75

1522.55
1576.36
1696.28
1838.52
2021.67
2199.92
1533.89
1522.55

410.94
366.48
290.31
227.28
171.73
133.63
400.95
410.94

318.15 K
0.000
5.668
10.942
21.225
30.916
41.184
50.435
57.731

1038.9
1085.8
1182.7
1285.8
1407.9
1529.0
1048.9
1038.9

0.000
5.668
10.942
21.225
30.916
41.184
50.435
57.731

1043.2
1090.4
1187.8
1291.3
1413.6
1534.5
1053.2
1043.2

0.000
5.668
10.942
21.225
30.916
41.184
50.435
57.731

1046.8
1094.5
1192.6
1296.6
1419.2
1540.5
1056.9
1046.8

308.15 K

298.15 K

288.15 K
0.000
5.668
10.942
21.225
30.916
41.184
50.435
57.731

1049.7
1098.1
1197.1
1301.6
1424.7
1546.2
1060.0
1049.7

A 95 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.41. Influencia de la composicin sobre los ndices de refraccin de la mezcla binaria %1
K3PO4 (1) %2 agua (2) en el intervalo de temperaturas (318.15- 288.15) K.
%1

nD

T/K

318.15

308.15

298.15

288.15

0.000
5.090
11.034
20.408
30.371
33.130

1.32976
1.33800
1.34895
1.36663
1.38537
1.39072

1.33125
1.34039
1.35088
1.36744
1.38636
1.39166

1.33259
1.34183
1.35245
1.36881
1.38786
1.39339

1.33353
1.34301
1.35381
1.37038
1.38953
1.39515

Tabla A.42. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla binaria %1 K3PO4 (1) %2 agua (2) en el intervalo de
temperaturas (318.15-288.15) K.
%1

u
-3

-1

gcm

-1

ms

TPa

1536.62
1581.44
1637.19
1745.73
1895.71
1945.30

427.70
385.62
340.94
275.11
212.51
196.49

1520.30
1567.03
1626.03
1741.12
1898.50
1950.07

435.26
391.13
344.12
275.33
210.95
194.68

1496.89
1547.11
1610.18
1732.67
1898.53
1952.52

447.62
399.87
349.57
276.86
210.05
193.37

1466.40
1519.92
1587.86
1719.53
1895.54
1951.87

465.46
413.15
358.26
280.01
209.85
192.70

318.15 K
0.000
5.090
11.034
20.408
30.371
33.130

990.20
1036.8
1094.2
1192.7
1309.4
1344.9

0.000
5.090
11.034
20.408
30.371
33.130

994.0
1041.1
1099.0
1198.0
1315.2
1350.7

308.15 K

298.15 K
0.000
5.090
11.034
20.408
30.371
33.130

997.0
1044.8
1103.3
1203.1
1320.8
1356.5

0.000
5.090
11.034
20.408
30.371
33.130

999.1
1047.7
1107.0
1207.8
1326.2
1362.0

288.15 K

A 96 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.43. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
Na2SO4 (1) %2 Tween 20 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K

%2
0.000
100.00
0.000
3.435
8.435
13.435
23.435
38.435
83.435
0.000
0.011
10.011
20.011
30.011
0.000
1.500
5.500
9.500
0.000
1.412
3.412
0.000

0.000
0.000
1.565
1.565
1.565
1.565
1.565
1.565
1.565
4.989
4.989
4.989
4.989
4.989
6.500
6.500
6.500
6.500
8.588
8.588
8.588
10.799

nD
318.15

308.15

298.15

288.15

1.32976
1.46180
1.33221
1.33723
1.34313
1.35007
1.36297
1.38362
1.44393
1.33697
1.33753
1.35206
1.36321
1.37101
1.33974
1.34299
1.34701
1.35092
1.34214
1.34334
1.34450
1.34513

1.33125
1.46535
1.33369
1.33858
1.34501
1.35144
1.36556
1.38610
1.44705
1.33845
1.33913
1.35360
1.36472
1.37351
1.34110
1.34465
1.34835
1.35244
1.34359
1.34565
1.34620
1.34696

1.33259
1.46895
1.33494
1.34001
1.34656
1.35310
1.36779
1.38849
1.45068
1.33985
1.34054
1.35413
1.36655
1.37563
1.34245
1.34619
1.35045
1.35398
1.34511
1.34729
1.34781
1.34853

1.33353
1.47253
1.33594
1.34108
1.34783
1.35452
1.36965
1.39062
1.45425
1.34105
1.34176
1.35566
1.36831
1.37770
1.34369
1.34752
1.35191
1.35551
1.34645
1.34871
1.34920
1.34993

Tabla A.44. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla ternaria %1 Na2SO4 (1) %2 Tween 20 (2) - %3 agua
(3) en el intervalo de temperaturas (318.15-288.15) K.
%1

%2

u
-3

-1

kgm

-1

ms

TPa

1536.62
1487.81
1553.28
1557.03
1565.07
1572.50
1586.58
1603.11
1555.53
1587.00
1588.23

427.70
416.85
412.83
409.46
402.45
396.32
384.90
370.97
382.13
383.72
382.48

318.15
0.000
0.000
1.565
1.565
1.565
1.565
1.565
1.565
1.565
4.989
4.989

0.000
100.00
0.000
3.435
8.435
13.435
23.435
38.435
83.435
0.000
0.011

990.2
1083.7
1004.0
1007.3
1014.4
1020.3
1032.1
1048.9
1081.5
1034.7
1036.4

A 97 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.44. Continuacin.

%1

%2

u
-3

4.989
4.989
4.989
6.500
6.500
6.500
6.500
8.588
8.588
8.588
10.799

10.011
20.011
30.011
0.000
1.500
5.500
9.500
0.000
1.412
3.412
0.000

kgm
1044.9
1058.7
1062.5
1049.1
1051.4
1055.0
1059.2
1066.2
1069.2
1071.4
1087.5

0.000
0.000
1.565
1.565
1.565
1.565
1.565
1.565
1.565
4.989
4.989
4.989
4.989
4.989
6.500
6.500
6.500
6.500
8.588
8.588
8.588
10.799

0.000
100.00
0.000
3.435
8.435
13.435
23.435
38.435
83.435
0.000
0.011
10.011
20.011
30.011
0.000
1.500
5.500
9.500
0.000
1.412
3.412
0.000

994.0
1091.5
1007.8
1011.3
1018.7
1025.1
1037.4
1055.3
1089.6
1039.1
1039.7
1049.7
1063.3
1067.4
1053.5
1055.8
1059.7
1064.1
1071.3
1074.3
1076.0
1092.2

0.000
0.000
1.565
1.565
1.565
1.565
1.565
1.565

0.000
100.00
0.000
3.435
8.435
13.435
23.435
38.435

997.0
1099.6
1011.1
1014.8
1022.5
1029.2
1042.2
1061.1

-1

-1

ms
1600.74
1610.28
1613.87
1602.43
1604.79
1608.64
1612.64
1623.05
1625.10
1626.91
1644.84

TPa
373.47
364.26
361.32
371.21
369.29
366.28
363.02
356.01
354.14
352.62
339.87

1520.30
1520.35
1537.21
1544.01
1555.20
1566.59
1587.91
1615.83
1588.14
1573.26
1573.86
1598.34
1612.37
1620.02
1589.70
1593.19
1600.22
1607.45
1610.25
1615.05
1617.97
1634.91

435.26
396.32
419.88
414.74
405.83
397.47
382.29
362.94
363.85
388.80
388.28
372.88
361.75
356.96
375.57
373.12
368.51
363.70
359.97
356.86
354.99
342.54

1496.89
1553.90
1515.31
1524.41
1539.82
1555.05
1585.04
1626.29

447.62
376.61
424.03
412.45
401.78
381.91
356.30
346.56

308.15

298.15

A 98 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.44. Continuacin.

%1

%2

u
-3

1.565
4.989
4.989
4.989
4.989
4.989
6.500
6.500
6.500
6.500
8.588
8.588
8.588
10.799

83.435
0.000
0.011
10.011
20.011
30.011
0.000
1.500
5.500
9.500
0.000
1.412
3.412
0.000

kgm
1097.9
1042.8
1043.4
1054.4
1068.2
1072.8
1057.4
1059.8
1063.9
1068.5
1075.4
1078.5
1080.3
1096.5

0.000
0.000
1.565
1.565
1.565
1.565
1.565
1.565
1.565
4.989
4.989
4.989
4.989
4.989
6.500
6.500
6.500
6.500
8.588
8.588
8.588
10.799

0.000
100.00
0.000
3.435
8.435
13.435
23.435
38.435
83.435
0.000
0.011
10.011
20.011
30.011
0.000
1.500
5.500
9.500
0.000
1.412
3.412
0.000

999.1
1107.7
1013.4
1017.4
1025.5
1032.6
1046.4
1066.5
1106.1
1045.7
1046.4
1058.4
1072.4
1077.7
1060.6
1063.1
1067.5
1072.4
1078.9
1082.1
1084.0
1100.2

-1

-1

ms
1621.12
1553.62
1554.34
1590.22
1609.55
1623.38
1571.19
1576.08
1586.92
1597.15
1593.50
1599.77
1603.60
1619.56

TPa
397.29
396.68
375.04
361.34
353.70
383.07
379.84
373.23
366.86
366.19
362.29
359.95
347.69
430.72

1466.404
1588.51
1485.99
1497.87
1517.24
1537.11
1576.85
1633.50
1655.46
1527.03
1528.04
1576.58
1601.73
1622.23
1545.77
1552.31
1566.90
1581.29
1569.87
1577.91
1583.38
1597.91

465.46
357.74
446.84
438.06
423.57
409.85
384.34
351.37
329.86
410.07
409.28
380.10
363.44
352.59
394.57
390.33
381.53
372.91
376.08
371.15
367.93
355.95

288.15

A 99 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.45. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
Na2S2O3 (1) %2 Tween 20 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K

%2
0.000
100.00
0.0000
23.062
38.062
48.981
10.062
13.062
0.000
0.134
5.134
10.134
20.134
30.134
0.000
3.000
13.000
23.000
28.000
0.000
0.116
5.116
10.116
0.000
1.000
3.000

0.000
0.000
1.937
1.937
1.937
1.937
1.937
1.937
4.865
4.865
4.865
4.865
4.865
4.865
7.000
7.000
7.000
7.000
7.000
9.883
9.883
9.883
9.883
12.000
12.000
12.000

nD
318.15

308.15

298.15

288.15

1.32976
1.46180
1.33259
1.36231
1.38153
1.39960
1.34716
1.35115
1.34983
1.34000
1.34659
1.35366
1.36698
1.38130
1.34123
1.34863
1.36210
1.37556
1.39100
1.34958
1.35059
1.35658
1.36367
1.35188
1.35507
1.35874

1.33125
1.46535
1.33399
1.36515
1.38453
1.40437
1.34877
1.35363
1.34124
1.34139
1.34833
1.35581
1.36968
1.38286
1.34356
1.34978
1.36380
1.37703
1.39246
1.35139
1.35158
1.3589
1.36497
1.35389
1.35706
1.36071

1.33259
1.46895
1.33524
1.36731
1.38671
1.40715
1.34987
1.35616
1.34266
1.34268
1.34994
1.35748
1.37193
1.38507
1.34361
1.35106
1.36574
1.37920
1.39538
1.35293
1.35268
1.36054
1.36663
1.35547
1.35875
1.36193

1.33353
1.47253
1.33622
1.36903
1.38868
1.40976
1.35121
1.35877
1.34390
1.34389
1.35127
1.35894
1.37373
1.38710
1.34487
1.35245
1.36745
1.38119
1.39829
1.35431
1.35404
1.36200
1.36830
1.35688
1.36033
1.36354

Tabla A.46. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla ternaria %1 Na2S2O3 (1) %2 Tween 20 (2) - %3 agua
(3) en el intervalo de temperaturas (318.15- 288.15) K.
%1

%2

u
-3

-1

kgm

-1

ms

TPa

1536.62
1487.81
1553.77
1587.76
1605.29

427.70
416.85
411.92
383.70
369.04

318.15
0.000
0.000
1.937
1.937
1.937

0.0000
100.00
0.0000
23.062
38.062

A 100 | A. GAYOL

990.2
1083.7
1005.5
1033.8
1051.5

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.46. Continuacin.

%1

%2

u
-3

1.937
1.937
1.937
4.865
4.865
4.865
4.865
4.865
4.865
7.000
7.000
7.000
7.000
7.000
9.883
9.883
9.883
9.883
12.000
12.000
12.000

48.981
10.062
13.062
0.000
0.134
5.134
10.134
20.134
30.134
0.000
3.000
13.000
23.000
28.000
0.000
0.116
5.116
10.116
0.000
1.000
3.000

kgm
1064.1
1017.5
1021.6
1028.5
1029.0
1034.4
1040.9
1054.6
1066.5
1046.6
1049.4
1061.8
1074.5
1084.0
1069.4
1069.7
1077.3
1080.2
1087.9
1089.0
1091.4

0.000
0.000
1.937
1.937
1.937
1.937
1.937
1.937
4.865
4.865
4.865
4.865
4.865
4.865
7.000
7.000
7.000
7.000
7.000
9.883
9.883
9.883
9.883

0.000
100.00
0.0000
23.062
38.062
48.981
10.062
13.062
0.000
0.134
5.134
10.134
20.134
30.134
0.000
3.000
13.000
23.000
28.000
0.000
0.116
5.116
10.116

994.0
1091.5
1009.6
1039.1
1058.3
1072.0
1022.1
1026.4
1032.8
1033.3
1039.3
1045.8
1060.1
1072.7
1051.1
1054.1
1067.0
1080.3
1089.8
1074.1
1074.5
1082.3
1085.5

-1

-1

ms
1611.83
1568.85
1573.09
1577.80
1578.67
1585.88
1592.67
1606.81
1617.14
1597.63
1601.25
1614.03
1624.33
1634.45
1622.58
1623.04
1630.27
1633.29
1642.66
1644.02
1646.75

TPa
361.71
399.26
395.55
390.53
389.92
384.36
378.72
367.23
358.53
374.32
371.63
361.52
352.73
345.31
355.17
354.85
349.25
347.03
340.63
339.73
337.87

1520.30
1520.35
1537.84
1589.08
1619.05
1633.44
1559.87
1566.88
1563.76
1564.61
1575.05
1586.09
1608.42
1627.15
1584.46
1590.72
1611.88
1630.35
1642.84
1610.87
1611.69
1623.35
1630.17

435.26
396.32
418.80
381.08
360.45
349.60
402.06
396.83
395.93
395.32
387.84
380.09
364.60
352.10
378.93
374.90
360.70
348.22
339.96
358.77
358.28
350.59
346.65

308.15

A 101 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.46. Continuacin.

%1

%2

u
-3

12.000
12.000
12.000

0.000
1.000
3.000

kgm
1092.8
1094.0
1096.4

0.000
0.000
1.937
1.937
1.937
1.937
1.937
1.937
4.865
4.865
4.865
4.865
4.865
4.865
7.000
7.000
7.000
7.000
7.000
9.883
9.883
9.883
9.883
12.000
12.000
12.000

0.000
100.00
0.0000
23.062
38.062
48.981
10.062
13.062
0.000
0.134
5.134
10.134
20.134
30.134
0.000
3.000
13.000
23.000
28.000
0.000
0.116
5.116
10.116
0.000
1.000
3.000

997.0
1099.6
1012.9
1044.0
1064.3
1078.7
1026.1
1030.5
1036.5
1037.0
1043.3
1050.1
1062.1
1078.3
1055.0
1058.2
1071.8
1085.8
1095.4
1078.3
1078.7
1086.9
1090.4
1097.3
1098.5
1101.1

-1

-1

ms
1632.60
1634.57
1639.10

TPa
343.29
342.10
339.46

1496.89
1553.90
1515.78
1586.45
1630.41
1653.60
1545.49
1555.38
1543.67
1545.04
1559.12
1574.59
1605.89
1633.38
1565.69
1574.60
1604.36
1632.59
1646.67
1594.05
1594.72
1611.51
1623.08
1617.38
1620.19
1626.64

447.62
376.61
429.68
380.57
353.45
339.02
408.01
401.10
404.87
403.96
394.29
384.07
365.06
347.58
386.63
381.13
362.47
345.53
336.65
364.95
364.51
354.27
348.12
348.36
346.77
343.22

1466.40
1588.51
1486.72
1578.66
1638.42
1671.69
1524.60
1537.18
1516.58
1517.96
1536.92
1556.57
1598.08

465.46
357.74
445.57
382.77
348.20
329.72
417.97
409.29
418.29
417.32
404.48
391.65
366.06

298.15

288.15
0.000
0.000
1.937
1.937
1.937
1.937
1.937
1.937
4.865
4.865
4.865
4.865
4.865

0.000
100.00
0.0000
23.062
38.062
48.981
10.062
13.062
0.000
0.134
5.134
10.134
20.134

A 102 | A. GAYOL

999.1
1107.7
1015.3
1048.2
1069.8
1085.3
1029.3
1034.0
1039.4
1039.9
1046.6
1053.8
1069.6

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.46. Continuacin.
%1

%2

4.865
7.000
7.000
7.000
7.000
7.000
9.883
9.883
9.883
9.883
12.000
12.000
12.000

kgm
1083.5
1058.3
1061.7
1076.0
1090.8
1100.6
1082.0
1082.4
1090.9
1094.7
1101.2
1102.5
1105.2

30.134
0.000
3.000
13.000
23.000
28.000
0.000
0.116
5.116
10.116
0.000
1.000
3.000

u
-3

-1

-1

ms
1636.39
1540.35
1551.96
1591.58
1630.26
1646.37
1571.09
1571.47
1593.82
1610.28
1596.00
1599.91
1608.31

TPa
344.67
398.23
391.05
366.87
344.93
335.19
374.42
374.10
360.83
352.26
356.48
354.32
349.77

Tabla A.47. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
K2HPO4 (1) %2 Tween 20 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K
0.000
0.000
1.526
1.526
1.526
1.526
1.526
1.526
1.526
1.526
3.205
3.205
3.205
3.205
3.205
5.192
5.192
5.192
5.192
5.192
7.195
7.195
7.195

%2
0.000
100.00
0.000
3.475
7.970
11.976
18.054
23.198
29.933
38.586
0.000
7.357
11.303
17.515
22.157
0.000
1.581
7.038
15.117
4.822
0.000
3.279
6.252

nD
318.15

308.15

298.15

288.15

1.32976
1.46180
1.33174
1.33633
1.34273
1.34813
1.35595
1.36336
1.37235
1.38492
1.33549
1.34482
1.34964
1.35859
1.36509
1.33802
1.33982
1.34745
1.36068
1.34417
1.34116
1.34616
1.34867

1.33125
1.46535
1.33323
1.33781
1.34414
1.34960
1.35717
1.36472
1.37403
1.38629
1.33691
1.34634
1.35146
1.36009
1.36659
1.33944
1.34115
1.34857
1.36249
1.34617
1.34244
1.34739
1.35008

1.33259
1.46895
1.33439
1.33899
1.34570
1.35107
1.35896
1.36669
1.37613
1.38834
1.33824
1.34785
1.35318
1.36194
1.36862
1.34076
1.34235
1.35016
1.36446
1.34778
1.34381
1.34826
1.35164

1.33353
1.47253
1.33535
1.34002
1.34696
1.35253
1.36057
1.36844
1.37794
1.39046
1.33934
1.34916
1.35471
1.36362
1.37042
1.34194
1.34359
1.35152
1.36619
1.34902
1.34505
1.34945
1.35308

A 103 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.48. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
K2HPO4 (1) %2 Tween 20 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1

%2

u
-3

-1

kgm

ms

TPa

-1

318.15
0.000
0.000
1.526
1.526
1.526
1.526
1.526
1.526
1.526
1.526
3.205
3.205
3.205
3.205
3.205
5.192
5.192
5.192
5.192
7.195
7.195
7.195

0.000
100.00
0.000
3.475
7.970
11.976
18.054
23.198
29.933
38.586
0.000
7.357
11.303
17.515
22.157
0.000
1.581
15.117
4.822
0.000
3.279
6.252

990.2
1083.7
1003.3
1007.4
1012.9
1017.1
1024.5
1030.5
1038.5
1049.8
1017.0
1024.5
1032.2
1037.6
1045.3
1027.0
1036.0
1041.9
1040.8
1050.6
1057.2
1058.6

0.000
0.000
1.526
1.526
1.526
1.526
1.526
1.526
1.526
1.526
3.205
3.205
3.205
3.205
3.205
5.192
5.192
5.192
5.192

0.000
100.00
0.000
3.475
7.970
11.976
18.054
23.198
29.933
38.586
0.000
7.357
11.303
17.515
22.157
0.000
1.581
15.117
4.822

994.0
1091.5
1007.2
1011.6
1017.3
1021.7
1029.4
1035.7
1044.2
1056.1
1021.1
1029.0
1036.9
1042.7
1050.7
1038.9
1040.4
1046.5
1045.3

1536.62
1487.81
1550.41
1555.54
1562.36
1567.39
1576.27
1583.25
1591.73
1602.39
1563.56
1573.51
1581.36
1587.81
1595.58
1580.00
1582.37
1588.94
1587.55
1596.13
1601.87
1604.20

427.70
416.85
414.63
410.20
404.44
400.18
392.85
387.12
380.04
370.96
402.18
394.20
387.39
382.26
375.76
390.02
385.46
380.15
381.21
373.59
368.63
367.05

1520.30
1520.35
1534.11
1541.86
1551.66
1559.35
1573.08
1584.25
1597.67
1615.59
1548.28
1563.69
1574.06
1585.44
1596.98
1565.71
1569.03
1579.65
1576.48

435.26
396.32
421.83
415.80
408.27
402.50
392.54
384.66
375.16
362.75
408.52
397.42
389.22
381.53
373.18
392.63
390.42
382.94
384.91

308.15

A 104 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.49. Continuacin.
%1

%2

u
-3

7.195
7.195
7.195

0.000
3.279
6.252

kgm
1055.0
1061.7
1063.3

0.000
0.000
1.526
1.526
1.526
1.526
1.526
1.526
1.526
1.526
3.205
3.205
3.205
3.205
3.205
5.192
5.192
5.192
5.192
7.195
7.195
7.195

0.000
100.00
0.000
3.475
7.970
11.976
18.054
23.198
29.933
38.586
0.000
7.357
11.303
17.515
22.157
0.000
1.581
15.117
4.822
0.000
3.279
6.252

997.0
1099.6
1010.4
1015.0
1021.0
1025.7
1033.8
1040.4
1049.4
1062.0
1024.5
1032.9
1041.0
1047.2
1055.5
1042.5
1044.0
1050.5
1049.2
1058.7
1065.7
1067.5

0.000
0.000
1.526
1.526
1.526
1.526
1.526
1.526
1.526
1.526
3.205
3.205
3.205
3.205
3.205
5.192

0.000
100.00
0.000
3.475
7.970
11.976
18.054
23.198
29.933
38.586
0.000
7.357
11.303
17.515
22.157
0.000

999.1
1107.7
1012.7
1017.6
1023.9
1028.9
1037.4
1044.5
1054.1
1067.4
1027.0
1035.9
1044.4
1051.1
1059.7
1045.3

-1

ms
1582.90
1591.25
1595.17

TPa
378.29
371.95
369.57

-1

1496.89
1553.90
1511.37
1521.58
1534.94
1546.38
1564.82
1580.31
1600.01
1625.76
1526.55
1547.97
1561.60
1578.52
1594.37
1545.37
1550.12
1564.85
1559.93
1563.87
1575.20
1581.25

447.62
376.61
433.25
425.53
415.70
407.70
395.03
384.84
372.21
356.25
418.85
404.03
393.90
383.23
372.69
401.64
398.60
388.73
391.67
386.18
378.15
374.65

1466.40
1588.51
1481.62
1494.66
1511.39
1526.26
1550.84
1571.44
1598.66
1633.15
1498.34
1525.31
1542.49
1566.46
1586.09
1518.13

465.46
357.74
449.79
439.88
427.55
417.22
400.76
387.67
371.19
351.25
433.69
414.88
402.41
387.72
375.08
415.05

298.15

288.15

A 105 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.48. Continuacin.

%1

%2

5.192
5.192
5.192
7.195
7.195
7.195

1.581
15.117
4.822
0.000
3.279
6.252

u
-3

kgm
1047.0
1053.8
1052.3
1061.8
1069.1
1071.0

-1

-1

ms
1523.94
1544.11
1537.27
1538.04
1552.63
1561.77

TPa
411.25
397.99
402.11
398.11
388.01
382.79

Tabla A. 49. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
K3PO4 (1) %2 Tween 20 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K
0.000
0.000
2.002
2.002
2.002
2.002
2.002
4.303
4.400
4.410
4.423
4.428
4.435
4.440
4.521
7.338
7.350
7.373
7.386
7.419
7.451
7.482
10.259
10.268
10.318

A 106 | A. GAYOL

%2
0.000
100.00
0.100
7.507
15.161
22.596
30.790
26.999
14.330
6.570
0.000
6.371
21.676
6.387
2.752
4.179
8.329
12.786
2.310
0.000
5.996
6.459
3.585
0.000
2.170

nD
318.15

308.15

298.15

288.15

1.32976
1.46180
1.33369
1.34346
1.35424
1.36440
1.37563
1.37439
1.35575
1.34662
1.33793
1.34607
1.36779
1.34697
1.34274
1.34871
1.35469
1.35815
1.34619
1.34257
1.35159
1.35192
1.35288
1.34832
1.35054

1.33125
1.46535
1.33510
1.34511
1.35550
1.36579
1.37667
1.37608
1.35703
1.34789
1.33933
1.34728
1.36856
1.34799
1.34221
1.34987
1.35594
1.36235
1.34738
1.34387
1.35277
1.35321
1.35403
1.34961
1.35171

1.33259
1.46895
1.33634
1.34656
1.35729
1.36776
1.37855
1.37825
1.35870
1.34917
1.34070
1.34876
1.37051
1.34929
1.34575
1.35130
1.35762
1.36422
1.34879
1.34533
1.35395
1.35483
1.35563
1.35095
1.35311

1.33353
1.47253
1.33736
1.34785
1.35887
1.36957
1.38045
1.38026
1.36031
1.35051
1.34188
1.35007
1.37227
1.35063
1.34725
1.35274
1.35915
1.36593
1.35016
1.34659
1.35532
1.35631
1.35708
1.35237
1.35547

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.50. Influencia de la sobre la densidad, la velocidad del sonido, la compresibilidad
isoentrpica de la mezcla ternaria %1 K3PO4 (1) %2 Tween 20 (2) - %3 agua (3) en el intervalo de
temperaturas (318.15- 288.15) K.
%1

%2

u
-3

kgm

-1

TPa

1536.62
1487.81
1555.69
1574.74
1588.26
1598.93
1608.23
1628.30
1609.85
1592.82
1575.67
1590.90
1623.69
1592.28
1584.94
1612.00
1623.70
1631.11
1608.04
1602.43
1617.36
1619.14
1638.49
1633.15
1635.87

427.70
416.85
409.36
396.14
385.89
377.22
369.68
355.16
368.28
379.41
390.75
380.74
358.73
379.60
384.40
361.98
354.54
350.08
364.31
367.81
358.55
357.27
341.37
345.83
342.68

1520.30
1520.35
1539.95
1564.24
1582.98
1600.46
1615.57
1634.32
1606.04
1583.16
1560.84
1581.33
1625.85
1583.03

435.26
396.32
416.08
399.75
386.67
374.60
364.33
350.69
368.30
382.38
396.58
383.70
355.98
382.38

ms

-1

318.15
0.000
0.000
2.002
2.002
2.002
2.002
2.002
4.303
4.400
4.410
4.423
4.428
4.435
4.440
4.521
7.338
7.350
7.373
7.386
7.419
7.451
7.482
10.259
10.268
10.318

0.000
100.00
0.100
7.507
15.161
22.596
30.790
26.999
14.330
6.570
0.000
6.371
21.676
6.387
2.752
4.179
8.329
12.786
2.310
0.000
5.996
6.459
3.585
0.000
2.170

990.2
1083.7
1009.3
1017.9
1027.3
1036.9
1045.8
1061.9
1047.7
1038.8
1030.8
1037.
1057.3
1039.0
1035.5
1063.1
1069.8
1073.6
1061.5
1058.8
1066.1
1067.6
1091.1
1084.1
1090.4

0.000
0.000
2.002
2.002
2.002
2.002
2.002
4.303
4.400
4.410
4.423
4.428
4.435
4.440

0.000
100.00
0.100
7.507
15.161
22.596
30.790
26.999
14.330
6.570
0.000
6.371
21.676
6.387

994.0
1091.5
1013.4
1022.3
1032.0
1042.1
1051.6
1067.5
1052.6
1043.4
1035.0
1042.2
1062.7
1043.5

308.15

A 107 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.50. Continuacin.

%1

%2

u
-3

4.521
7.338
7.350
7.373
7.386
7.419
7.451
7.482
10.259
10.268
10.318

2.752
4.179
8.329
12.786
2.310
0.000
5.996
6.459
3.585
0.000
2.170

kgm
1039.9
1067.7
1074.7
1078.7
1066.1
1063.3
1070.9
1072.4
1096.0
1087.7
1095.2

0.000
0.000
2.002
2.002
2.002
2.002
2.002
4.303
4.400
4.410
4.423
4.428
4.435
4.440
4.521
7.338
7.350
7.373
7.386
7.419
7.451
7.482
10.259
10.268
10.318

0.000
100.00
0.100
7.507
15.161
22.596
30.790
26.999
14.330
6.570
0.000
6.371
21.676
6.387
2.752
4.179
8.329
12.786
2.310
0.000
5.996
6.459
3.585
0.000
2.170

997.0
1099.6
1016.7
1026.0
1036.2
1046.9
1056.8
1072.7
1057.0
1047.3
1038.6
1046.1
1067.5
1047.4
1043.7
1071.8
1079.0
1083.2
1070.1
1067.1
1075.1
1076.6
1100.3
1092.8
1099.5

0.000
0.000
2.002
2.002
2.002
2.002
2.002

0.000
100.00
0.100
7.507
15.161
22.596
30.790

999.1
1107.7
1019.2
1028.9
1039.6
1051.0
1061.6

-1

ms
1572.90
1602.11
1617.16
1627.96
1596.66
1589.46
1608.89
1611.17
1630.14
1622.18
1626.25

TPa
388.66
364.87
355.80
349.79
367.94
372.26
360.73
359.21
343.35
349.37
345.23

-1

1496.89
1553.90
1517.75
1548.90
1573.15
1597.86
1619.37
1636.84
1597.67
1568.13
1540.34
1565.92
1624.00
1567.88
1555.01
1587.07
1606.07
1620.40
1579.80
1571.22
1595.14
1598.31
1616.71
1605.58
1611.47

447.62
376.61
426.95
406.24
389.95
374.12
360.81
347.93
370.64
388.29
405.80
389.83
355.18
388.35
396.22
370.40
359.28
351.58
374.42
379.56
365.55
363.58
347.70
354.97
350.22

1466.40
1588.51
1488.53
1526.33
1557.98
1591.04
1619.18

465.46
357.74
442.81
417.15
396.26
375.85
359.29

298.15

288.15

A 108 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.50. Continuacin.
%1

%2

4.303
4.400
4.410
4.423
4.428
4.435
4.440
4.521
7.338
7.350
7.373
7.386
7.419
7.451
7.482
10.259
10.268
10.318

kgm
1077.3
1060.7
1050.5
1041.4
1049.3
1071.8
1050.7
1046.7
1075.3
1082.7
1087.2
1073.4
1070.4
1078.7
1082.9
1104.1
1097.2
1103.2

26.999
14.330
6.570
0.000
6.371
21.676
6.387
2.752
4.179
8.329
12.786
2.310
0.000
5.996
6.459
3.585
0.000
2.170

u
-3

-1

-1

ms
1635.20
1583.53
1546.58
1512.75
1544.03
1617.92
1545.98
1531.23
1565.99
1589.54
1607.36
1556.82
1545.55
1575.64
1579.55
1597.64
1582.93
1591.14

TPa
347.13
375.96
397.96
419.60
399.75
356.42
398.21
407.45
379.21
365.52
356.00
384.35
391.09
373.41
370.12
354.82
363.74
358.01

Tabla A.51. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
Na2SO4 (1) %2 Triton X-102 (2) - %3 agua (3) en el intervalo de temperaturas (318.15-288.15) K.
%1
T/K
0.000
0.000
2.508
2.518
2.552
2.522
2.471
2.500
2.553
2.592
5.068
5.003
5.014
4.947
5.002
9.172
9.120
9.005
9.058
2.494
5.108
9.034

%2
0.000
100.00
4.404
10.388
14.763
17.513
23.230
25.893
32.171
29.458
5.508
7.787
8.209
13.626
16.758
0.535
0.938
1.157
2.085
0.000
0.000
0.000

nD
318.15

308.15

298.15

288.15

1.32976
1.47978
1.34062
1.34732
1.35351
1.35893
1.36805
1.38499
1.38313
1.37792
1.34595
1.34985
1.35061
1.35084
1.34386
1.34352
1.34420
1.34485
1.34500
1.33365
1.33790
1.34272

1.33125
1.48357
1.34254
1.34944
1.35898
1.36221
1.37023
1.38685
1.38735
1.38046
1.34656
1.35207
1.35288
1.34569
1.34341
1.34538
1.34612
1.34678
1.34720
1.33523
1.34064
1.34456

1.33259
1.48738
1.34406
1.35089
1.36095
1.36444
1.37235
1.38862
1.38974
1.38281
1.34895
1.35395
1.35477
1.34786
1.34533
1.34662
1.34694
1.34733
1.34816
1.33657
1.34167
1.34606

1.33353
1.49122
1.34536
1.35224
1.36173
1.36597
1.37465
1.38975
1.39199
1.38497
1.35045
1.35554
1.35630
1.34978
1.34704
1.34800
1.34825
1.34857
1.34911
1.33775
1.34275
1.34741

A 109 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.52. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla ternaria %1 Na2SO4 (1) %2 Triton X-102 (2) - %3 agua
(3) en el intervalo de temperaturas (318.15-288.15) K.
%1

%2

kgm

0.000
0.000
2.508
2.518
2.552
2.522
2.471
2.500
2.553
2.592
5.068
5.003
5.014
4.947
5.002
9.172
9.120
9.005
9.058
2.494
5.108
9.034

0.000
100.00
4.404
10.388
14.763
17.513
23.230
25.893
32.171
29.458
5.508
7.787
8.209
13.626
16.758
0.535
0.938
1.157
2.085
0.000
0.000
0.000

0.000
0.000
2.508
2.518
2.552
2.522
2.471
2.500
2.553
2.592
5.068
5.003
5.014
4.947
5.002
9.172

0.000
100.00
4.404
10.388
14.763
17.513
23.230
25.893
32.171
29.458
5.508
7.787
8.209
13.626
16.758
0.535

A 110 | A. GAYOL

u
-3

318.15
990.2
1053.2
1016.2
1021.9
1026.1
1025.4
1032.9
1036.3
1041.7
1039.6
1040.1
1041.7
1042.1
1046.6
1050.1
1072.5
1072.3
1071.5
1072.5
1012.0
1035.3
1070.3
308.15 K
994.0
1060.9
1020.5
1026.6
1031.0
1030.4
1038.3
1042.1
1047.4
1045.5
1044.8
1046.4
1046.9
1057.4
1055.4
1077.2

-1

ms

TPa

-1

1536.62
1466.72
1565.46
1571.02
1574.69
1573.94
1580.84
1583.95
1587.92
1586.71
1590.94
1592.02
1592.43
1595.48
1598.84
1628.62
1628.27
1627.52
1629.03
1561.77
1587.30
1627.02

427.70
441.36
401.54
396.46
393.02
393.65
387.39
384.58
380.70
382.03
379.82
378.76
378.41
375.34
372.52
351.50
351.74
352.30
351.34
405.09
383.36
352.73

1520.30
1500.74
1554.01
1564.03
1570.68
1570.85
1582.99
1589.28
1597.23
1593.72
1581.85
1584.94
1585.44
1592.35
1598.22
1617.84

435.26
418.50
405.75
398.18
393.14
393.27
384.31
379.91
374.12
376.57
382.50
380.40
380.01
372.97
370.93
354.65

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.52. Continuacin.
%1

%2

u
-3

9.120
9.005
9.058
2.494
5.108
9.034

0.938
1.157
2.085
0.000
0.000
0.000

kgm
1077.1
1076.1
1077.4
1016.1
1039.6
1075.6

0.000
0.000
2.508
2.518
2.552
2.522
2.471
2.500
2.553
2.592
5.068
5.003
5.014
4.947
5.002
9.172
9.120
9.005
9.058
2.494
5.108
9.034

0.000
100.00
4.404
10.388
14.763
17.513
23.230
25.893
32.171
29.458
5.508
7.787
8.209
13.626
16.758
0.535
0.938
1.157
2.085
0.000
0.000
0.000

997.0
1068.7
1024.1
1030.7
1035.
1034.9
1043.3
1047.3
1053.2
1050.9
1048.8
1050.7
1051.1
1056.3
1060.3
1081.4
1081.3
1080.4
1081.7
1019.5
1043.3
1079.7

-1

-1

ms
1617.87
1617.48
1620.25
1546.83
1573.79
1615.80

TPa
354.68
355.19
353.55
411.30
388.35
356.10

1496.89
1536.06
1535.79
1551.53
1561.63
1562.82
1580.94
1590.70
1603.24
1597.10
1567.24
1572.55
1573.13
1583.65
1593.95
1601.23
1601.64
1601.42
1604.73
1525.36
1554.25
1598.97

447.62
396.55
413.95
403.01
396.02
395.61
383.48
377.34
369.37
373.05
388.15
384.86
384.41
377.46
371.20
360.64
360.49
360.91
358.99
421.56
396.76
362.25

1466.40
1572.88
1510.69
1532.43
1546.33
1548.47
1574.06
1588.12
1605.12
1596.47
1545.63
1553.71
1554.43
1571.35

465.46
375.41
426.62
411.76
402.44
401.50
385.22
376.86
366.73
371.61
397.66
392.89
392.37
381.93

298.15

288.15
0.000
0.000
2.508
2.518
2.552
2.522
2.471
2.500
2.553
2.592
5.068
5.003
5.014
4.947

0.000
100.00
4.404
10.388
14.763
17.513
23.230
25.893
32.171
29.458
5.508
7.787
8.209
13.626

999.1
1076.
1027.0
1034.1
1039.1
1038.7
1047.7
1052.0
1058.3
1055.8
1052.6
1054.3
1054.7
1060.4

A 111 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.52. Continuacin.

%1

%2

5.002
9.172
9.120
9.005
9.058
2.494
5.108
9.034

-1

kgm
1064.6
1085.0
1085.0
1084.3
1085.4
1022.0
1046.3
1083.2

16.758
0.535
0.938
1.157
2.085
0.000
0.000
0.000

u
-3

-1

ms
1584.49
1578.30
1579.38
1579.25
1582.82
1496.73
1527.64
1575.79

TPa
374.11
369.97
369.47
369.77
367.73
436.75
409.54
371.76

Tabla A.53. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
Na2S2O3 (1) %2 Triton X-102 (2)- %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K
0.000
0.000
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
4.931
4.953
5.043
5.077
5.077
5.077
5.077
5.077
5.077
7.539
7.539
7.539
7.539
7.539
7.539
7.539
9.966

A 112 | A. GAYOL

%2
0.000
100.00
0.000
5.566
10.012
14.991
20.038
23.940
26.236
30.007
40.301
45.913
15.144
20.041
0.000
4.961
5.566
10.071
13.248
15.144
24.984
0.000
1.792
8.272
12.264
13.248
15.090
20.057
0.000

nD
318.15

308.15

298.15

288.15

1.32976
1.47978
1.34202
1.35047
1.34939
1.35203
1.36107
1.37156
1.38811
1.39735
1.36334
1.40633
1.36302
1.36446
1.34202
1.35866
1.35047
1.35491
1.35064
1.36302
1.35364
1.34514
1.35657
1.35426
1.35827
1.35064
1.35096
1.35271
1.34514

1.33125
1.48357
1.34362
1.35471
1.35194
1.35463
1.36137
1.37381
1.39124
1.40175
1.36596
1.41041
1.36594
1.36592
1.34362
1.36080
1.35471
1.35763
1.35297
1.36594
1.35571
1.34663
1.35875
1.35666
1.35893
1.35297
1.35371
1.35486
1.34663

1.33259
1.48738
1.34503
1.35780
1.35362
1.35629
1.35629
1.37673
1.39393
1.40507
1.36807
1.41568
1.36799
1.37473
1.34503
1.36252
1.35780
1.35973
1.35494
1.36799
1.36358
1.34802
1.36019
1.35829
1.35933
1.35494
1.35577
1.35698
1.34802

1.33353
1.49122
1.34620
1.35967
1.35769
1.35769
1.35769
1.37883
1.39639
1.40849
1.36972
1.41767
1.36968
1.37439
1.34620
1.36366
1.35967
1.36126
1.35625
1.36968
1.36693
1.34931
1.36165
1.35991
1.36090
1.35625
1.35751
1.35923
1.34931

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.53. Continuacin.
%1
T/K
9.966
9.966
12.442
12.442
12.442
12.442

%2
3.230
4.961
0.000
1.7917
3.2298
4.9610

nD
318.15
1.35700
1.35866
1.34202
1.35660
1.35700
1.35870

308.15
1.35935
1.36080
1.34362
1.35880
1.35940
1.36080

298.15
1.36099
1.36252
1.34503
1.36020
1.36100
1.36250

288.15
1.36250
1.36366
1.34620
1.36170
1.36250
1.36370

Tabla A.54. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla ternaria %1 Na2S2O3 (1) %2 Triton X-102 (2) - %3
agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1

%2

u
-3

-1

kgm

-1

ms

TPa

1536.62
1466.72
1558.22
1562.75
1563.06
1566.41
1566.72
1571.38
1571.66
1575.36
1576.24
1580.11
1581.07
1584.99
1590.28
1592.68
1580.89
1584.71
1587.04
1591.22
1598.42
1601.14
1608.34
1608.93
1611.73
1619.28
1604.75
1624.03

427.70
441.36
407.63
403.32
403.24
399.90
399.66
395.38
395.11
391.81
390.99
387.91
387.16
383.20
377.99
374.55
388.23
384.25
382.00
378.19
371.51
371.25
364.63
363.31
361.40
356.72
368.07
353.89

318.15
0.000
0.000
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
5.077
5.077
5.077
5.077
5.077
7.539
7.539
7.539
7.539
7.539
7.577
9.966

0.000
100.00
0.000
4.499
4.922
9.437
10.012
14.804
14.991
19.703
20.038
23.940
25.891
30.424
39.462
45.913
0.000
5.566
10.071
15.144
24.984
0.000
9.705
13.248
15.090
20.057
3.994
0.000

990.2
1053.2
1010.3
1015.2
1015.0
1019.1
1019.3
1024.2
1024.6
1028.4
1029.4
1032.5
1033.2
1038.7
1046.1
1052.5
1030.6
1036.3
1039.3
1044.3
1053.5
1050.6
1060.2
1063.2
1065.1
1069.1
1054.9
1071.3

A 113 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.54. Continuacin.

%1

%2

u
-3

9.966
9.966
10.017
12.442
12.442
12.442
12.442

8.272
12.264
4.437
0.000
1.792
3.230
4.961

kgm
1079.3
1082.8
1075.7
1091.4
1094.6
1095.8
1097.6

0.000
0.000
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
5.077
5.077
5.077
5.077
5.077
7.539
7.539
7.539
7.539
7.539
7.577
9.966
9.966
9.966
10.017
12.442
12.442
12.442
12.442

0.000
100.00
0.000
4.499
4.922
9.437
10.012
14.804
14.991
19.703
20.038
23.940
25.891
30.424
39.462
45.913
0.000
5.566
10.071
15.144
24.984
0.000
9.705
13.248
15.090
20.057
3.994
0.000
8.272
12.264
4.437
0.000
1.792
3.230
4.961

994.0
1060.9
1014.4
1019.5
1019.4
1023.8
1024.0
1029.2
1029.5
1033.6
1034.7
1037.9
1039.2
1044.6
1052.4
1059.3
1035.0
1040.9
1044.2
1049.5
1059.2
1055.2
1065.3
1068.6
1071.0
1075.3
1059.7
1076.1
1084.8
1088.9
1080.8
1096.3
1099.7
1101.0
1103.0

-1

-1

ms
1636.78
1643.08
1627.44
1646.06
1645.95
1649.55
1654.71

TPa
345.84
342.09
350.97
338.16
337.21
335.38
332.74

1520.30
1500.74
1543.08
1550.86
1551.51
1558.28
1558.74
1567.30
1567.77
1574.88
1576.41
1582.66
1585.01
1592.28
1604.68
1612.88
1566.95
1575.13
1580.97
1588.80
1602.95
1588.57
1603.51
1608.91
1611.53
1618.38
1595.15
1612.65
1628.27
1635.22
1619.92
1636.25
1641.48
1644.38
1648.46

435.26
418.50
414.00
407.79
407.51
402.24
401.92
395.52
395.16
390.07
388.91
384.62
383.01
377.56
368.99
362.87
393.48
387.20
383.13
377.46
367.42
375.53
365.06
361.48
359.51
355.04
370.84
357.32
347.68
343.43
352.57
340.69
337.47
335.87
333.61

308.15

A 114 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.54. Continuacin.
%1

%2

u
-3

-1

kgm

-1

ms

TPa

1496.89
1536.06
1521.33
1532.30
1533.63
1545.07
1544.97
1557.99
1558.64
1569.68
1571.99
1581.06
1585.02
1596.23
1616.57
1631.39
1546.91
1559.83
1569.73
1581.74
1603.54
1570.35
1593.73
1604.89
1607.42
1616.00
1580.79
1595.76
1614.30
1624.07
1606.14
1621.06
1627.50
1630.90
1635.60

447.62
396.55
424.52
416.22
415.56
407.53
407.52
398.56
398.10
390.88
389.30
383.52
381.09
373.74
361.48
352.41
402.31
393.29
387.01
379.14
365.31
382.85
367.94
361.64
359.67
354.35
376.09
363.49
352.13
346.49
357.12
345.69
341.83
339.98
337.41

1466.40
1572.88
1492.48
1507.05
1508.57
1524.54
1524.16
1542.32
1543.11

465.46
375.41
439.99
429.07
428.26
417.23
417.38
405.23
404.68

298.15
0.000
0.000
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
2.523
5.077
5.077
5.077
5.077
5.077
7.539
7.539
7.539
7.539
7.539
7.577
9.966
9.966
9.966
10.017
12.442
12.442
12.442
12.442

0.000
100.00
0.000
4.499
4.922
9.437
10.012
14.804
14.991
19.703
20.038
23.940
25.891
30.424
39.462
45.913
0.000
5.566
10.071
15.144
24.984
0.000
9.705
13.248
15.090
20.057
3.994
0.000
8.272
12.264
4.437
0.000
1.792
3.230
4.961

997.0
1068.7
1017.7
1023.2
1023.1
1027.8
1028.0
1033.6
1033.9
1038.3
1039.4
1043.0
1044.4
1050.1
1058.5
1066.2
1038.7
1045.0
1048.6
1054.2
1064.5
1059.2
1070.0
1073.5
1076.0
1080.6
1064.0
1080.3
1089.7
1094.2
1085.4
1100.8
1104.4
1105.8
1107.8

0.000
0.000
2.523
2.523
2.523
2.523
2.523
2.523
2.523

0.000
100.00
0.000
4.499
4.922
9.437
10.012
14.804
14.991

999.1
1076.7
1020.3
1026.1
1026.0
1031.2
1031.3
1037.3
1037.7

288.15

A 115 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.54. Continuacin.

%1

%2

2.523
2.523
2.523
2.523
2.523
2.523
2.523
5.077
5.077
5.077
5.077
5.077
7.539
7.539
7.539
7.539
7.539
7.577
9.966
9.966
9.966
10.017
12.442
12.442
12.442
12.442

-1

kgm
1042.4
1043.6
1047.5
1049.1
1055.0
1064.3
1073.1
1041.7
1048.4
1052.3
1058.3
1069.4
1062.5
1074.1
1077.9
1080.5
1085.4
1067.6
1084.0
1094.1
1098.9
1089.5
1104.8
1108.6
1110.2
1112.4

19.703
20.038
23.940
25.891
30.424
39.462
45.913
0.000
5.566
10.071
15.144
24.984
0.000
9.705
13.248
15.090
20.057
3.994
0.000
8.272
12.264
4.437
0.000
1.792
3.230
4.961

u
-3

-1

ms
1558.79
1562.06
1574.62
1580.55
1596.41
1625.48
1647.76
1519.70
1537.80
1552.10
1569.13
1599.71
1545.18
1578.33
1596.30
1601.16
1612.38
1559.70
1572.86
1594.63
1606.98
1586.55
1600.18
1607.62
1611.39
1616.51

TPa
394.80
392.68
385.00
381.56
371.89
355.60
343.20
415.65
403.33
394.44
383.75
365.40
394.18
373.73
364.06
360.98
354.38
385.01
372.88
359.41
352.37
364.61
353.48
349.00
346.89
344.01

Tabla A.55. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
K2HPO4 (1) %2 Triton X-102 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K
0.000
0.000
2.510
2.510
2.510
2.510
2.510
2.510
2.510
2.510
5.040
5.040
5.040

A 116 | A. GAYOL

%2
0.000
100.00
0.000
7.029
10.669
15.113
20.162
25.734
29.995
35.171
0.000
5.737
12.916

nD
318.15

308.15

298.15

288.15

1.32976
1.47978
1.33405
1.34467
1.35001
1.35708
1.36457
1.37352
1.37931
1.38811
1.34207
1.35552
1.36161

1.33125
1.48357
1.33569
1.34673
1.35249
1.35974
1.36692
1.37682
1.38222
1.39039
1.34089
1.35354
1.36112

1.33259
1.48738
1.33705
1.34823
1.35397
1.36158
1.36897
1.37984
1.38463
1.39296
1.33960
1.35001
1.35979

1.33353
1.49122
1.33812
1.34945
1.35528
1.36316
1.37062
1.38143
1.38677
1.39530
1.33818
1.34783
1.35698

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.55. Continuacin.
%1
T/K
5.040
5.040
5.040
7.500
7.500
7.500
7.500
10.027
10.027
10.027
10.027
12.555
12.555
12.555

%2
15.053
19.990
26.176
0.000
8.401
11.892
15.259
0.000
1.569
3.062
0.999
0.503
0.000
0.448

nD
318.15
1.36165
1.34935
1.35050
1.34210
1.34359
1.34419
1.34725
1.34587
1.34619
1.34709
1.34602
1.34910
1.34890
1.34952

308.15
1.35772
1.34746
1.34811
1.34307
1.34576
1.34619
1.34862
1.34704
1.34774
1.34840
1.34767
1.35085
1.35039
1.35105

298.15
1.35122
1.34522
1.34676
1.34453
1.34800
1.34818
1.34966
1.34806
1.34939
1.35032
1.34938
1.35238
1.35174
1.35261

288.15
1.34788
1.34298
1.34481
1.34588
1.34929
1.34978
1.35165
1.34935
1.35061
1.35156
1.35065
1.35362
1.35319
1.35388

Tabla A.56. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla ternaria %1 K2HPO4 (1) %2 Triton X-102 (2) - %3
agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1

%2

u
-3

-1

kgm

ms

TPa

-1

318.15
0.000
0.000
2.510
2.510
2.510
2.510
2.510
2.510
2.510
2.510
5.002
5.002
5.002
5.002
5.002
5.002
7.487
7.487
7.487
7.487

0.000
100.00
0.000
7.029
10.669
15.113
20.162
25.734
29.995
35.171
0.000
8.546
16.688
21.124
25.089
3.987
0.000
11.892
8.401
15.259

990.2
1053.2
1011.1
1017.3
1020.8
1025.5
1029.6
1034.4
1037.9
1043.2
1033.5
1040.6
1047.5
1054.2
1056.8
1035.7
1053.4
1065.7
1062.2
1074.8

1536.62
1466.72
1558.45
1563.26
1566.42
1570.71
1574.67
1579.93
1582.64
1586.11
1579.20
1584.45
1589.80
1595.08
1598.29
1580.49
1597.55
1610.59
1607.66
1620.26

427.70
441.36
407.18
402.21
399.24
395.24
391.68
387.25
384.64
381.02
387.98
382.77
377.68
372.81
370.41
386.50
371.95
361.71
364.24
354.38

A 117 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.56. Continuacin.

%1

%2

u
-3

-1

kgm
1075.9
1077.5
1078.9
1076.5
1098.8
1098.5
1101.1
1099.0

10.027
10.027
10.027
10.027
12.555
12.555
12.555
12.555

0.000
1.569
3.062
0.999
0.503
0.000
0.221
0.448

0.000
0.000
2.510
2.510
2.510
2.510
2.510
2.510
2.510
2.510
5.002
5.002
5.002
5.002
5.002
5.002
7.487
7.487
7.487
7.487
10.027
10.027
10.027
10.027
12.555
12.555
12.555
12.555

0.000
100.00
0.000
7.029
10.669
15.113
20.162
25.734
29.995
35.171
0.000
8.546
16.688
21.124
25.089
3.987
0.000
11.892
8.401
15.259
0.000
1.569
3.062
0.999
0.503
0.000
0.221
0.448

994.0
1060.9
1015.1
1021.8
1025.4
1030.3
1034.8
1040.1
1043.7
1049.3
1037.7
1045.3
1052.7
1059.4
1062.4
1040.2
1057.7
1071.0
1067.2
1079.8
1080.4
1082.2
1083.7
1081.1
1103.6
1103.2
1105.8
1103.6

0.000
0.000
2.510
2.510
2.510
2.510
2.510

0.000
100.00
0.000
7.029
10.669
15.113
20.162

997.4
1068.7
1018.5
1025.5
1029.4
1034.7
1039.5

-1

ms
1619.23
1620.52
1624.09
1619.67
1641.55
1642.81
1643.62
1642.16

TPa
354.49
353.38
351.38
354.10
337.71
337.28
336.17
337.42

1520.30
1500.74
1543.45
1552.93
1558.72
1566.33
1574.02
1583.49
1589.31
1596.87
1564.97
1576.62
1588.11
1593.87
1600.45
1569.15
1584.49
1602.20
1597.77
1610.29
1606.99
1609.55
1612.44
1608.14
1630.92
1631.76
1632.96
1631.10

435.26
418.50
413.50
405.81
401.37
395.58
390.03
383.43
379.29
373.71
393.46
384.84
376.62
371.55
367.47
390.44
376.55
363.72
367.02
357.12
358.39
356.66
354.90
357.65
340.66
340.41
339.12
340.57

1496.89
1536.06
1521.74
1536.47
1545.32
1556.70
1568.70

447.62
396.55
423.99
413.03
406.77
398.82
390.92

308.15

298.15

A 118 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.56. Continuacin.
%1

%2

u
-3

2.510
2.510
2.510
5.002
5.002
5.002
5.002
5.002
5.002
7.487
7.487
7.487
7.487
10.027
10.027
10.027
10.027
12.555
12.555
12.555
12.555

25.734
29.995
35.171
0.000
8.546
16.688
21.124
25.089
3.987
0.000
11.892
8.401
15.259
0.000
1.569
3.062
0.999
0.503
0.000
0.221
0.448

kgm
1045.1
1049.1
1054.9
1041.2
1049.4
1057.4
1064.1
1067.5
1044.0
1061.5
1075.5
1071.7
1084.3
1084.4
1086.4
1088.0
1085.2
1107.8
1107.4
1110.1
1107.9

0.000
0.000
2.510
2.510
2.510
2.510
2.510
2.510
2.510
2.510
5.002
5.002
5.002
5.002
5.002
5.002
7.487
7.487
7.487
7.487
10.027
10.027

0.000
100.00
0.000
7.029
10.669
15.113
20.162
25.734
29.995
35.171
0.000
8.546
16.688
21.124
25.089
3.987
0.000
11.892
8.401
15.259
0.000
1.569

999.1
1076.7
1020.9
1028.5
1032.7
1038.3
1043.5
1049.6
1053.9
1060.1
1044.1
1052.9
1061.5
1068.2
1072.1
1047.1
1064.7
1079.5
1075.6
1088.1
1087.8
1090.0

-1

-1

ms
1582.96
1592.35
1604.55
1544.79
1563.39
1581.73
1588.56
1600.35
1551.96
1565.60
1587.81
1582.28
1594.52
1589.31
1592.94
1595.41
1591.10
1614.85
1615.45
1616.95
1615.02

TPa
381.83
375.92
368.18
402.43
389.84
377.99
372.40
365.75
397.67
384.31
368.77
372.67
362.73
365.06
362.75
361.09
363.97
346.14
346.00
344.53
346.05

1466.40
1572.88
1492.96
1512.87
1524.95
1540.73
1557.66
1577.68
1591.44
1608.69
1517.30
1543.67
1570.03
1577.96
1595.71
1527.88
1539.87
1567.06
1560.67
1573.08
1565.37
1570.38

465.46
375.41
439.42
424.78
416.39
405.70
394.95
382.75
374.62
364.49
416.02
398.54
382.16
375.97
366.29
409.09
396.10
377.21
381.68
371.37
375.13
372.02

288.15

A 119 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.56. Continuacin.

%1

%2

10.027
10.027
12.555
12.555
12.555
12.555

-1

kgm
1091.7
1088.7
1111.6
1111.1
1113.8
1111.6

3.062
0.999
0.503
0.000
0.221
0.448

u
-3

-1

ms
1572.35
1567.93
1592.63
1593.00
1594.71
1592.80

TPa
370.50
373.60
354.67
354.64
353.03
354.57

Tabla A.57. Influencia de la composicin sobre los ndices de refraccin de la mezcla ternaria %1
K3PO4 (1) %2 Triton X-102 (2) - %3 agua (3) en el intervalo de temperaturas (318.15- 288.15) K.
%1
T/K
0.000
0.000
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104

A 120 | A. GAYOL

%2
0.000
100.00
0.000
2.697
4.864
7.833
10.037
12.579
14.410
16.834
20.124
22.606
27.645
30.584
34.247
36.844
40.793
5.194
10.088
10.119
12.758
17.584
18.535
24.892
29.939
33.127
0.000
7.355
15.055
15.405
20.360
25.360
27.311
30.660

nD
318.15

308.15

298.15

288.15

1.32976
1.47978
1.33332
1.33847
1.34014
1.34581
1.34831
1.35275
1.35633
1.35881
1.36415
1.37059
1.37689
1.38049
1.38682
1.39302
1.34523
1.34669
1.35396
1.34593
1.35820
1.34416
1.34437
1.34539
1.34825
1.34917
1.33867
1.35010
1.34436
1.34498
1.34483
1.34758
1.34703
1.34825

1.33125
1.48357
1.33490
1.34042
1.34214
1.34825
1.35039
1.35557
1.35892
1.36073
1.36786
1.37361
1.37979
1.38328
1.39059
1.39641
1.34694
1.34888
1.35551
1.34752
1.36112
1.34616
1.34600
1.34767
1.35058
1.35155
1.34046
1.35301
1.34687
1.34679
1.34742
1.35020
1.34900
1.35067

1.33259
1.48738
1.33621
1.34179
1.34357
1.34985
1.35389
1.35760
1.36150
1.36241
1.36985
1.37499
1.38305
1.38579
1.39356
1.39942
1.34933
1.35076
1.35762
1.35026
1.36278
1.34869
1.34854
1.35014
1.35235
1.35370
1.34197
1.35364
1.35144
1.34904
1.35027
1.35234
1.35118
1.35254

1.33353
1.49122
1.33726
1.34294
1.34475
1.35113
1.35461
1.35897
1.36231
1.36394
1.37155
1.37606
1.38532
1.38772
1.39604
1.40227
1.35130
1.35185
1.35961
1.35343
1.36442
1.35083
1.35031
1.35153
1.35416
1.35550
1.34311
1.35524
1.35368
1.35136
1.35186
1.35416
1.35305
1.35430

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.58. Continuacin.
%1
T/K
5.104
5.104
5.504
5.504
5.504
5.504
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
10.249
10.249
10.249
10.249

%2
35.587
40.438
0.000
2.669
4.871
22.915
2.579
5.190
10.178
12.750
15.304
17.057
19.608
25.580
28.363
30.964
0.000
7.489
22.786
0.000
0.888
2.218
2.931

nD
318.15
1.35316
1.35449
1.33981
1.35244
1.34415
1.34744
1.34433
1.34579
1.34578
1.34748
1.34823
1.34852
1.34964
1.35298
1.35453
1.35591
1.34337
1.34602
1.35119
1.34573
1.34862
1.34861
1.34889

308.15
1.35701
1.35818
1.34111
1.35522
1.34884
1.34903
1.34620
1.34729
1.34853
1.34963
1.35032
1.35081
1.35197
1.35474
1.35652
1.35859
1.34526
1.34727
1.35302
1.34719
1.35051
1.35053
1.35065

298.15
1.36182
1.36222
1.34229
1.35696
1.35053
1.35116
1.34773
1.34909
1.34947
1.35133
1.35195
1.35270
1.35263
1.35660
1.35844
1.36096
1.34683
1.34896
1.35468
1.34847
1.35145
1.35207
1.35218

288.15
1.36575
1.36498
1.34344
1.35839
1.35217
1.35333
1.34911
1.35071
1.35109
1.35305
1.35359
1.35436
1.35415
1.35830
1.36015
1.36291
1.34808
1.35039
1.35615
1.34980
1.35289
1.35347
1.35373

Tabla A.59. Influencia de la composicin sobre la densidad, la velocidad del sonido, la

compresibilidad isoentrpica de la mezcla ternaria %1 K3PO4 (1) %2 Triton X-102 (2) - %3 agua
(3) en el intervalo de temperaturas (318.15- 288.15) K.
%1

%2

u
-3

-1

kgm

ms

TPa

-1

318.15
0.000
0.000
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526

0.000
100.00
0.000
2.697
4.864
7.833
10.037
12.579
14.410
16.834
20.124
22.606

990.2
1053.2
1009.3
1016.4
1017.0
1020.6
1022.0
1024.4
1025.
1028.6
1032.1
1032.9

1536.62
1466.72
1556.04
1562.65
1562.97
1566.40
1567.68
1569.48
1570.46
1573.51
1576.72
1577.57

427.70
441.36
409.17
402.89
402.47
399.31
398.11
396.29
395.47
392.64
389.73
389.01

A 121 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.58. Continuacin.

%1

%2

u
-3

2.526
2.526
2.526
2.526
2.526
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
10.249
10.249
10.249
10.249

26.671
34.247
35.380
36.844
40.793
2.669
5.194
10.088
12.758
17.584
18.535
22.915
24.892
27.311
29.939
30.660
0.000
4.871
7.355
10.119
15.055
15.405
20.360
25.360
35.587
0.000
2.579
2.794
5.190
7.489
10.178
12.750
15.304
17.057
19.608
22.786
25.580
28.363
30.964
0.000
0.888
2.218
2.931

kgm
1037.4
1044.4
1044.9
1045.9
1048.8
1110.2
1040.5
1044.9
1047.7
1052.7
1052.9
1061.9
1065.0
1070.7
1076.3
1060.5
1037.0
1042.6
1043.4
1046.1
1051.1
1051.2
1055.9
1061.9
1086.5
1061.5
1065.3
1065.2
1066.1
1067.1
1070.7
1076.5
1083.0
1088.8
1091.5
1099.0
1108.0
1109.6
1120.5
1079.3
1086.0
1089.3
1059.1

0.000

0.000

994.0

-1

-1

ms
1581.66
1587.04
1587.31
1588.05
1589.24
1654.80
1584.40
1587.80
1590.06
1594.54
1594.09
1605.69
1608.80
1603.97
1599.34
1610.24
1581.06
1585.84
1586.71
1588.55
1592.40
1592.80
1595.78
1602.84
1615.93
1603.90
1607.64
1460.79
1608.55
1612.14
1616.28
1622.61
1628.01
1632.73
1636.76
1644.14
1658.09
1662.24
1673.33
1622.28
1629.61
1632.96
1635.70

TPa
385.29
380.14
379.81
379.09
377.50
328.90
382.83
379.59
377.51
373.61
373.73
365.22
362.78
363.01
363.21
363.67
385.77
381.37
380.64
378.80
375.16
374.94
371.90
366.54
352.47
366.26
363.20
439.91
362.51
360.56
357.50
352.79
348.37
344.51
341.98
336.51
328.28
326.15
318.71
352.04
346.44
344.27
352.90

1520.30

435.26

308.15

A 122 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.58. Continuacin.
%1

%2

0.000
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104
7.580
7.580
7.580
7.580
7.580
7.580
7.580

100.00
0.000
2.697
4.864
7.833
10.037
12.579
14.410
16.834
20.124
22.606
26.671
34.247
35.380
36.844
40.793
2.669
5.194
10.088
12.758
17.584
18.535
22.915
24.892
27.311
29.939
30.660
0.000
4.871
7.355
10.119
15.055
15.405
20.360
25.360
35.587
0.000
2.579
2.794
5.190
7.489
10.178
12.750

u
-3

kgm
1060.9
1013.3
1020.6
1021.4
1025.1
1026.7
1029.2
1030.1
1033.7
1037.3
1038.3
1043.1
1050.4
1051.1
1052.2
1055.2
1115.4
1045.1
1049.8
1052.7
1058.0
1058.3
1067.4
1070.7
1077.2
1083.8
1067.4
1041.2
1047.2
1048.2
1051.0
1056.3
1056.4
1061.5
1068.1
1096.5
1065.8
1069.9
1069.9
1071.0
1072.5
1076.4
1082.3

-1

ms
1500.74
1540.43
1549.49
1551.28
1556.98
1559.72
1563.25
1565.73
1570.60
1576.12
1578.81
1585.97
1597.07
1598.35
1600.13
1604.92
1645.24
1574.19
1581.18
1585.62
1593.38
1593.62
1602.55
1604.31
1609.87
1611.47
1614.66
1566.99
1575.52
1578.16
1582.06
1589.34
1590.08
1597.83
1604.75
1619.99
1591.03
1596.47
1596.80
1599.10
1601.59
1606.71
1613.07

-1

TPa
418.50
415.85
408.06
406.83
402.37
400.36
397.60
395.97
392.16
388.06
386.36
381.14
373.21
375.97
371.18
367.90
331.19
386.11
381.00
377.81
372.28
372.06
364.78
362.86
358.18
355.29
359.33
391.11
384.69
383.04
380.14
374.77
374.38
368.99
363.53
347.51
370.64
366.69
366.55
365.13
363.46
359.87
355.07

A 123 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.58. Continuacin.

%1

%2

7.580
7.580
7.580
7.580
7.580
7.580
7.580
10.249
10.249
10.249
10.249

15.304
17.057
19.608
22.786
25.580
28.363
30.964
0.000
0.888
2.218
2.931

u
-3

-1

kgm
1089.3
1094.
1097.5
1104.3
1116.2
1116.1
1126.4
1083.9
1091.7
1094.7
1064.1

-1

ms
1618.65
1622.62
1627.32
1635.44
1649.44
1653.14
1663.76
1610.23
1618.81
1622.30
1625.83

TPa
350.37
347.15
344.05
338.54
329.28
327.83
320.70
355.80
349.53
347.09
355.51

1496.89
1536.06
1518.21
1529.84
1533.18
1541.52
1546.03
1551.53
1555.65
1562.72
1571.02
1575.77
1586.34
1604.00
1606.39
1609.35
1618.17
1630.54
1558.34
1569.51
1576.30
1587.70
1588.95
1594.17
1594.31
1612.17
1621.03
1617.47
1546.85
1559.53
1564.23
1570.47
1581.57

447.62
396.55
426.72
417.17
415.00
408.93
405.90
401.99
399.45
394.41
388.81
386.04
379.10
368.04
366.71
364.97
359.82
335.81
392.51
385.11
380.67
373.26
372.54
367.03
365.83
355.54
349.47
355.82
399.96
391.13
388.36
384.19
376.81

298.15
0.000
0.000
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.019
5.104
5.104
5.104
5.104
5.104

0.000
100.00
0.000
2.697
4.864
7.833
10.037
12.579
14.410
16.834
20.124
22.606
26.671
34.247
35.380
36.844
40.793
2.669
5.194
10.088
12.758
17.584
18.535
22.915
24.892
27.311
29.939
30.660
0.000
4.871
7.355
10.119
15.055

A 124 | A. GAYOL

997.0
1068.7
1016.6
1024.2
1025.1
1029.0
1030.7
1033.3
1034.4
1038.2
1042.0
1043.2
1048.2
1056.0
1056.7
1057.8
1061.3
1120.0
1049.1
1054.1
1057.2
1062.7
1063.1
1072.0
1075.4
1082.1
1088.9
1074.2
1044.9
1051.2
1052.3
1055.3
1060.9

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla A.58. Continuacin.
%1

%2

u
-3

5.104
5.104
5.104
5.104
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
10.249
10.249
10.249
10.249

15.405
20.360
25.360
35.587
0.000
2.579
2.794
5.190
7.489
10.178
12.750
15.304
17.057
19.608
22.786
25.580
28.363
30.964
0.000
0.888
2.218
2.931

kgm
1061.0
1066.5
1073.1
1102.6
1069.7
1074.1
1074.0
1075.3
1077.0
1080.8
1086.4
1093.9
1098.5
1102.2
1108.8
1121.0
1122.3
1132.3
1088.1
1096.1
1099.0
1072.4

0.000
0.000
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
2.526
5.019
5.019
5.019
5.019
5.019

0.000
100.00
0.000
2.697
4.864
7.833
10.037
12.579
14.410
16.834
20.124
22.606
26.671
34.247
35.380
36.844
40.793
2.669
5.194
10.088
12.758
17.584

999.1
1076.7
1019.1
1026.9
1027.9
1032.2
1034.0
1036.8
1038.0
1042.0
1046.1
1047.5
1042.7
1061.1
1062.0
1063.3
1067.1
1124.0
1052.4
1057.7
1061.1
1067.0

-1

-1

ms
1582.67
1597.00
1603.47
1628.56
1572.61
1580.47
1580.82
1583.90
1585.87
1591.90
1598.90
1603.39
1606.98
1612.37
1620.87
1635.39
1643.39
1652.52
1592.78
1602.51
1606.22
1610.30

TPa
376.24
367.64
362.42
341.94
377.98
372.71
372.56
370.67
369.19
365.10
360.04
355.57
352.50
348.96
343.25
333.52
329.90
323.40
362.26
355.26
352.66
359.58

1466.40
1572.88
1488.93
1503.05
1507.95
1518.89
1525.39
1533.20
1539.16
1548.77
1560.44
1567.65
1582.40
1607.38
1610.93
1615.18
1628.63
1610.10
1535.85
1551.65
1561.28
1577.01

465.46
375.41
442.61
431.02
427.80
419.93
415.63
410.28
406.63
400.07
392.55
388.45
382.97
364.73
362.83
360.47
353.29
343.17
402.82
392.65
386.61
376.84

288.15

A 125 | A. GAYOL

A.

Tablas de Propiedad.

Tabla A.58. Continuacin.

%1

%2

5.019
5.019
5.019
5.019
5.019
5.019
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104
5.104
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
7.580
10.249
10.249
10.249
10.249

18.535
22.915
24.892
27.311
29.939
30.660
0.000
4.871
7.355
10.119
15.055
15.405
20.360
25.360
35.587
0.000
2.579
2.794
5.190
7.489
10.178
12.750
15.304
17.057
19.608
22.786
25.580
28.363
30.964
0.000
0.888
2.218
2.931

A 126 | A. GAYOL

u
-3

kgm
1067.4
1076.2
1079.7
1086.3
1093.1
1079.6
1047.8
1054.5
1055.8
1059.0
1064.9
1065.1
1070.9
1077.6
1109.1
1073.0
1077.6
1077.5
1079.0
1077.0
1084.7
1090.2
1097.7
1102.3
1106.2
1112.9
1125.3
1127.0
1137.0
1091.6
1099.7
1102.8
1077.1

-1

ms
1579.31
1581.49
1575.63
1626.89
1635.77
1631.97
1519.58
1536.92
1543.84
1552.71
1568.39
1569.92
1595.50
1610.48
1644.47
1547.45
1558.10
1558.54
1562.79
1585.87
1571.21
1578.52
1582.56
1585.76
1591.67
1600.28
1615.61
1633.61
1645.01
1569.36
1580.46
1584.28
1588.58

-1

TPa
375.58
371.48
373.04
347.78
341.88
347.78
413.29
401.46
397.37
391.66
381.72
380.92
366.81
357.78
333.41
389.18
382.25
382.05
379.44
369.19
373.42
368.09
363.72
360.75
356.81
350.86
340.43
332.46
325.00
371.94
364.02
361.25
367.89

Anexo B
Curva Binodal

B. Curva Binodal.
B.

CURVA BINODAL.................................................................................................................... 3

B 2 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

B. CURVA BINODAL
Tabla B.1. Curva binodal de la mezcla ternaria x1 Etanol (1) x2 n-alcano (2) - x3 agua (3) a T =
318.15 K.
n-hexano

n-heptano

n-octano

n-nonano

x1

x2

x1

x2

x1

x2

x1

x2

0.0374
0.1317
0.1621
0.2065
0.2802
0.3062
0.4240
0.4290
0.4774
0.4834
0.5038
0.5161
0.0374
0.1317
0.1621
0.2065
0.2802

0.9593
0.0077
0.8292
0.0014
0.0014
0.6751
0.0473
0.4105
0.0761
0.0856
0.2384
0.1060
0.9593
0.0077
0.8292
0.0014
0.0014

0.0306
0.0640
0.1119
0.1773
0.2378
0.3183
0.3541
0.3768
0.4170
0.5038

0.0007
0.9227
0.0003
0.8038
0.0023
0.6437
0.0112
0.5490
0.0702
0.2578

0.0028
0.0311
0.0479
0.0947
0.1080
0.1377
0.1514
0.1771
0.1802
0.1830
0.1871
0.1881
0.1946
0.2802
0.2913
0.3247
0.3377
0.4339
0.4923
0.5691
0.6538
0.6538
0.6552
0.6856
0.7130
0.8805

0.9961
0.9680
0.9518
0.9038
0.0013
0.8620
0.8478
0.8220
0.8190
0.8145
0.8119
0.8116
0.8041
0.0011
0.7063
0.6741
0.6616
0.0014
0.5037
0.0612
0.2877
0.2877
0.3223
0.1013
0.1809
0.1068

0.0447
0.0653
0.0798
0.1078
0.1119
0.2047
0.2681
0.3177
0.3231
0.3275
0.3694
0.5297
0.6262
0.6500
0.6808
0.7237
0.7674
0.7853

0.9545
0.0114
0.9200
0.8920
0.8879
0.7945
0.7316
0.0015
0.6764
0.6724
0.0044
0.4701
0.0044
0.3378
0.0015
0.0082
0.2147
0.0657

B 3 | A. GAYOL

B. Curva Binodal.
Tabla B.2 Curva binodal de la mezcla ternaria %1 sal (1) %2 Tween 20 (2) - %3 agua (3) a T =
298.15 K

Na2SO4

Na2S2O3

K2HPO4

K3PO4

% w1

%w2

% w1

%w2

% w1

%w2

% w1

%w2

2.3157
2.5400
3.2310
3.6970
4.1244
4.8960
5.3104
6.0375
6.5969
6.8217
7.0941
7.4822
7.8432
8.1068
8.3052
8.4470
8.6106

42.4670
39.1766
35.6167
33.0171
30.0145
25.6293
22.1111
19.7265
16.8942
15.4986
13.3730
10.6661
8.5280
6.7185
5.3632
3.9825
3.2280

2.4451
3.4513
4.5046
5.7474
7.1402
7.6837
8.3508
9.0022
9.2843
9.7192
10.2174
10.5234
10.9018
11.2629
11.5079
11.7015
11.9870
12.1563
12.4104
12.6118

57.2262
51.1228
43.5241
36.8636
31.4453
29.3657
26.2649
22.5331
21.0568
18.9734
16.7035
14.9201
12.7771
10.9040
9.2649
7.8858
6.5301
5.5783
4.1600
2.4931

2.3803
2.8768
3.4699
4.0082
4.1732
4.5832
4.7211
5.1900
5.2893
5.5302
5.9695
6.3792
6.7596
7.5713
7.6638
7.6885
8.1121
8.3163
8.4288
8.6917
8.9322
9.2852
9.8641
9.9980
10.0145
10.1231
10.1999
10.5370
10.5805
10.5972

45.6353
43.2751
41.7917
38.7319
37.9152
34.8982
33.7302
32.5687
31.6388
30.0353
27.8388
27.2539
26.2994
23.0458
19.5487
21.3402
18.3827
17.0487
15.7607
15.1015
13.7618
11.9068
8.6633
7.6576
6.6031
5.1225
5.7515
4.2356
3.6092
2.8767

2.5007
4.0215
5.2400
5.6084
6.0742
6.5607
6.8288
7.2407
7.5538
7.7343
7.9848
8.2221
8.4279
8.6186
8.7770
8.8776
9.0266
9.1178
9.3279
9.3947

45.6208
37.5809
30.1472
27.2043
25.2333
21.8858
20.4563
18.4019
16.4652
14.7356
13.3228
12.0940
10.3204
9.4388
8.3958
7.3574
6.3314
5.3285
4.2094
2.6206

B 4 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla B.3. Curva binodal de la mezcla ternaria %1 sal (1) %2 Triton X-102 (2) - %3 agua (3) a T =
298.15 K.

Na2SO4

Na2S2O3

K2HPO4

K3PO4

% w1

%w2

% w1

%w2

% w1

%w2

% w1

%w2

0.34
0.55
2.80
3.02
3.74
4.04
4.73
5.18
5.37
5.55
5.94
6.25
6.61
6.94
7.33
7.21
7.57
7.96
8.14
8.25
8.45
10.33
10.88
11.58

45.12
43.43
32.25
29.65
27.02
25.28
22.72
19.49
18.50
16.77
14.23
12.81
10.66
8.84
7.15
8.13
6.58
4.58
3.98
3.28
2.33
0.75
0.32
0.13

1.23
2.67
6.14
6.69
7.54
8.02
8.71
9.23
9.96
10.34
10.67
10.96
11.37
11.53
14.02
15.34
16.65

54.47
47.72
31.54
29.07
24.05
21.53
17.69
15.70
12.61
10.80
9.06
7.54
6.19
4.80
1.49
0.56
0.18

2.51
2.79
2.80
3.22
3.61
4.27
4.96
5.44
6.18
6.63
6.74
6.87
7.12
7.52
7.87
8.20
8.51
8.90
9.20
9.45
9.68
9.76
9.98
10.30
10.52
12.17
13.10
14.85

45.00
42.04
40.06
37.86
36.04
33.33
30.13
26.49
23.93
22.07
19.75
20.58
18.43
16.88
15.12
13.43
11.87
10.55
9.23
8.18
7.27
5.97
5.22
4.00
2.98
1.41
0.65
0.11

2.46
3.34
3.76
3.82
4.06
4.40
4.67
5.00
5.29
5.54
5.88
6.27
6.32
6.64
7.12
7.30
7.92
8.09
8.43
8.64
8.92
9.12
9.34
9.58
9.76
9.95
13.27
13.82
15.98

42.64
38.04
36.04
36.51
34.44
32.92
31.06
29.85
27.08
26.21
24.16
21.52
19.80
18.41
17.05
15.56
14.30
13.03
11.79
10.16
9.00
7.65
6.53
5.37
4.36
3.46
0.38
0.22
0.01

B 5 | A. GAYOL

Anexo C
Rectas de Reparto

C.

C.
C.1

Rectas de Reparto.

RECTAS DE REPARTO ............................................................................................................. 3

Bibliografa ........................................................................................................................ 5

C 2 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

C. RECTAS DE REPARTO
Tabla C.1. Rectas de reparto de la mezcla ternaria %1 Na2SO4 (1) %2 Tween 20 (2) - %3 agua (3) a
T = 298.15 K
Tween 20 fase rica

Na2SO4 fase rica

w1I

w1II

w2I

w2II

36.09
48.80
54.27

3.56
0.20
0.05

3.23
0.91
0.30

9.20
12.18
13.13

Rectas de
reparto

33.06
49.88
55.71

-5.44
-4.31
-4.22

Tabla C.2 Rectas de reparto de la mezcla ternaria %1 Na2S2O3 (1) %2 Tween 20 (2) - %3 agua (3) a
T = 298.15 K

Tween 20 fase rica

Na2S2O3 fase rica

w1I

w1II

w2I

w2II

40.70
53.58
59.92

2.19
0.07
0.00

5.50
2.88
1.65

14.53
19.08
20.96

Rectas de
reparto

41.51
55.92
62.95

-3.86
-3.30
-3.10

Tabla C.3. Rectas de reparto de la mezcla ternaria %1 K2HPO4 (1) %2 Tween 20 (2) - %3 agua (3) a
T = 298.15 K

Tween 20 fase rica

K2HPO4 fase rica

w1I

w1II

w2I

w2II

51.60
39.71
50.31

0.02
0.51
0.29

1.08
3.44
1.29

17.13
14.16
14.78

Rectas de
reparto

54.01
40.64
51.80

-3.21
-3.65
-3.70

C 3 | A. GAYOL

C.

Rectas de Reparto.

Tabla C.4. Rectas de reparto de la mezcla ternaria %1 K3PO4 (1) %2 Tween 20 (2) - %3 agua (3) a T
= 298.15 K

Tween 20 fase rica

K3PO4 fase rica

w1I

w1II

w2I

w2II

43.93
47.40
40.32

0.01
0.00
2.61

2.78
1.69
3.63

15.01
17.03
19.92

Rectas de
reparto

45.59
49.82
43.49

-3.59
-3.09
-2.47

Tabla C.5. Rectas de reparto de la mezcla ternaria %1 Na2SO4 (1) %2 Triton X-102 (2) - %3 agua (3)
a T = 298.15 K1

Triton X-102 fase rica

Na2SO4 fase rica

w1I

w1II

w2I

w2II

43.43
32.25
45.12

0.55
2.80
0.34

0.32
0.75
0.13

10.58
10.13
11.58

Rectas de
reparto

44.33
32.34
46.38

-4.17
-4.30
-4.00

Tabla C.6. Rectas de reparto de la mezcla ternaria %1 Na2S2O3 (1) %2 Triton X-102 (2) - %3 agua
(3) a T = 298.15 K1
Triton X-102 fase rica

Na2S2O3 fase rica

w1I

w1II

w2I

w2II

47.72
31.54
54.47

2.67
6.14
1.23

0.56
1.49
0.18

15.34
14.02
16.65

Rectas de
reparto

48.84
31.07
56.44

-3.72
-3.81
-3.52

Ulloa, G., Coutens, C., Snchez, M., Sineiro, J., Rodrguez, A., Deive, F.J., Nez, M.J. (2012b) Sodium salt effect on
aqueous solutions containing Tween 20 and Triton X-102. J. Chem. Thermodyn., 47, 62-67.

C 4 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla C.7.Rectas de reparto de la mezcla ternaria %1 K2HPO4 (1) %2 Triton X-102 (2) - %3 agua (3)
a T = 298.15 K2
Triton X-102 fase rica

K2HPO4 fase rica

w1I

w1II

w2I

w2II

40.06
42.04
45.00

2.80
2.80
2.51

1.41
0.65
0.11

12.17
13.10
14.85

Rectas de
reparto

39.77
42.66
46.56

-4.13
-4.02
-3.64

Tabla C.8. Rectas de reparto de la mezcla ternaria %1 K3PO4 (1) %2 Triton X-102 (2) - %3 agua
(3) a T = 298.15 K2
Triton X-102 fase rica

K3PO4 fase rica

w1I

w1II

w2I

w2II

31.06
37.00
42.88

4.67
3.68
2.37

0.22
0.02
0.38

15.98
13.82
13.27

Rectas de
reparto

32.85
38.34
43.87

-2.73
-3.65
-3.90

C.1 Bibliografa
lvarez, M.S., Moscoso, F., Rodriguez, A., Sanromn, M.A., Deive, F.J. (2012b)
Triton X surfactants to form aqueous biphasic systems: Experiment and
correlation., J. Chem. Thermodyn. 54, 385-392.
Ulloa, G., Coutens, C., Snchez, M., Sineiro, J., Rodrguez, A., Deive, F.J., Nez,
M.J. (2012b) Sodium salt effect on aqueous solutions containing Tween 20 and
Triton X-102. J. Chem.l Thermodyn. 47, 62-67.

lvarez, M.S., Moscoso, F., Rodriguez, A., Sanromn, M.A., Deive, F.J. (2012b) Triton X surfactants to form
aqueous biphasic systems: Experiment and correlation. The Journal of Chemical Thermodynamics 54, 385-392.

C 5 | A. GAYOL

Anexo D
Magnitudes
Derivadas

D.

Magnitudes Derivadas.

D.

MAGNITUDES DERIVADAS ........................................................................................ 3

D 2 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

D. MAGNITUDES DERIVADAS

Tabla D.1. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 288.15 K
288.15 K

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

Lf

b10

()
0.608
0.701
0.657
0.627
0.604
0.436

-6

B10

(m )

(nm)

(m mol )

(m )

(m mol )

(m mol )(ms )

51.509
118.677
134.563
150.468
166.460
15.438

0.172
0.227
0.237
0.246
0.255
0.115

12.877
29.669
33.641
37.617
41.615
3.859

12.877
29.669
33.641
0.459
0.490
0.100

15.288
39.094
38.935
39.296
39.387
1.505

0.612
1.348
1.536
1.723
1.912
0.205

Y10

-1

Va10
3

-1

R10
3

-1

RA

MA

-1

Z10

-3

2 -1

(kgm s )
3.32
3.06
3.17
3.25
3.32
4.28

1.00
0.85
0.87
0.88
0.89
1.16

0
0
0
0
0
0

936.002
742.149
806.484
855.874
898.780
1465.084

D 3 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.2. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 290.65 K.
6

290.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.616
0.713
0.667
0.637
0.612
0.435

(m )
51.569
118.896
134.813
150.746
166.752
15.448

D 4 | A. GAYOL

-6

B10

(nm)
0.172
0.228
0.237
0.246
0.255
0.115

(m mol )
12.892
29.724
33.703
37.686
41.688
3.862

Y10
-1

(m )
12.892
29.724
33.703
0.459
0.491
0.101

Va10
3

-1

(m mol )
15.658
40.225
40.057
40.522
40.660
1.412

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
926.307
731.564
796.524
845.688
888.869
1472.743

-1

(m mol )(ms )
0.613
1.347
1.536
1.722
1.912
0.205

-3

MA

2 -1

3.30
3.03
3.15
3.23
3.29
4.30

1.00
0.85
0.87
0.88
0.89
1.16

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.3. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 293.15 K.
6

293.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.625
0.726
0.678
0.646
0.621
0.435

(m )
51.631
119.116
135.071
151.025
167.056
15.458

-6

B10

(nm)
0.172
0.228
0.237
0.246
0.255
0.115

(m mol )
12.908
29.779
33.768
37.756
41.764
3.864

Y10
-1

(m )
12.908
29.779
33.768
0.460
0.492
0.101

Va10
3

-1

(m mol )
16.021
41.416
41.197
41.725
41.954
1.325

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
916.856
720.582
786.484
835.757
878.852
1479.863

-1

(m mol )(ms )
0.613
1.347
1.535
1.722
1.911
0.206

-3

MA

2 -1

3.28
3.00
3.12
3.20
3.27
4.32

1.00
0.85
0.87
0.88
0.89
1.16

D 5 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.4. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 295.65 K.
6

295.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.633
0.739
0.688
0.656
0.630
0.435

(m )
51.691
119.348
135.326
151.305
167.360
15.468

D 6 | A. GAYOL

-6

B10

(nm)
0.172
0.228
0.238
0.247
0.255
0.115

(m mol )
12.923
29.837
33.832
37.826
41.840
3.867

Y10
-1

(m )
12.923
29.837
33.832
0.460
0.492
0.101

Va10
3

-1

(m mol )
16.382
42.517
42.334
42.925
43.221
1.242

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
907.534
710.437
776.570
825.939
869.103
1486.431

-1

(m mol )(ms )
0.613
1.346
1.535
1.722
1.911
0.206

-3

MA

2 -1

3.26
2.97
3.09
3.17
3.24
4.34

1.00
0.85
0.87
0.88
0.89
1.16

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.5. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 298.15 K.
6

298.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.642
0.751
0.699
0.666
0.639
0.435

(m )
51.752
119.580
135.585
151.587
167.663
15.479

-6

B10

(nm)
0.172
0.228
0.238
0.247
0.255
0.115

(m mol )
12.938
29.895
33.896
37.897
41.916
3.870

Y10
-1

(m )
12.938
29.895
33.896
0.461
0.493
0.101

Va10
3

-1

(m mol )
16.739
43.618
43.461
44.122
44.495
1.164

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
898.363
700.398
766.827
816.221
859.394
1492.459

-1

(m mol )(ms )
0.613
1.346
1.535
1.722
1.911
0.207

-3

MA

2 -1

3.24
2.94
3.07
3.15
3.22
4.36

1.00
0.85
0.87
0.88
0.89
1.16

D 7 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.6. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 300.65 K.
6

300.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.650
0.764
0.710
0.676
0.649
0.435

(m )
51.814
119.817
135.846
151.869
167.972
15.490

D 8 | A. GAYOL

-6

B10

(nm)
0.173
0.228
0.238
0.247
0.255
0.115

(m mol )
12.954
29.954
33.961
37.967
41.993
3.872

Y10
-1

(m )
12.954
29.954
33.961
0.461
0.493
0.101

Va10
3

-1

(m mol )
17.097
44.712
44.596
45.315
45.755
1.091

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
889.235
690.521
757.107
806.616
849.843
1497.948

-1

(m mol )(ms )
0.613
1.346
1.535
1.722
1.911
0.207

-3

MA

2 -1

3.22
2.92
3.04
3.13
3.20
4.38

1.00
0.85
0.87
0.88
0.89
1.15

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.7. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 303.15 K.
6

303.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.659
0.777
0.721
0.686
0.658
0.436

(m )
51.875
120.051
136.105
152.148
168.279
15.500

-6

B10

(nm)
0.173
0.228
0.238
0.247
0.255
0.115

(m mol )
12.969
30.013
34.026
38.037
42.070
3.875

Y10
-1

(m )
12.969
30.013
34.026
0.462
0.494
0.101

Va10
3

-1

(m mol )
17.453
45.804
45.719
46.505
47.009
1.023

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
880.253
680.772
747.579
797.134
840.415
1502.912

-1

(m mol )(ms )
0.613
1.346
1.535
1.722
1.911
0.207

-3

MA

2 -1

3.20
2.89
3.02
3.10
3.17
4.40

1.00
0.85
0.87
0.88
0.89
1.15

D 9 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.8. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 305.65 K.
6

305.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.668
0.791
0.733
0.697
0.668
0.436

(m )
51.938
120.290
136.371
152.436
168.593
15.512

D 10 | A. GAYOL

-6

B10

(nm)
0.173
0.228
0.238
0.247
0.256
0.115

(m mol )
12.984
30.073
34.093
38.109
42.148
3.878

Y10
-1

(m )
12.984
30.073
34.093
0.462
0.495
0.101

Va10
3

-1

(m mol )
17.815
46.916
46.861
47.704
48.273
0.960

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
871.188
670.958
737.985
787.647
830.991
1507.321

-1

(m mol )(ms )
0.613
1.346
1.535
1.721
1.911
0.208

-3

MA

2 -1

3.18
2.86
2.99
3.08
3.15
4.42

1.00
0.85
0.87
0.88
0.89
1.15

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.9. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 308.15 K.
6

308.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.677
0.804
0.745
0.707
0.677
0.437

(m )
51.998
120.524
136.629
152.713
168.896
15.523

-6

B10

(nm)
0.173
0.229
0.238
0.247
0.256
0.115

(m mol )
13.000
30.131
34.157
38.178
42.224
3.881

Y10
-1

(m )
13.000
30.131
34.157
0.463
0.495
0.101

Va10
3

-1

(m mol )
18.174
48.008
48.009
48.908
49.541
0.903

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
862.271
661.431
728.470
778.248
821.653
1511.220

-1

(m mol )(ms )
0.614
1.346
1.535
1.721
1.910
0.208

-3

MA

2 -1

3.16
2.84
2.97
3.05
3.12
4.43

1.00
0.85
0.87
0.88
0.89
1.15

D 11 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.10. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 310.65 K.
6

310.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.686
0.819
0.757
0.718
0.687
0.438

(m )
52.060
120.759
136.888
152.995
169.206
15.534

D 12 | A. GAYOL

-6

B10

(nm)
0.173
0.229
0.238
0.247
0.256
0.115

(m mol )
13.015
30.190
34.222
38.249
42.302
3.884

Y10
-1

(m )
13.015
30.190
34.222
0.464
0.496
0.101

Va10
3

-1

(m mol )
18.538
49.135
49.155
50.131
50.818
0.850

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
853.330
651.721
719.057
768.788
812.319
1514.595

-1

(m mol )(ms )
0.614
1.346
1.535
1.721
1.910
0.209

-3

MA

2 -1

3.14
2.81
2.94
3.03
3.10
4.45

1.00
0.85
0.87
0.88
0.89
1.15

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.11. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 313.15 K.
6

313.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.696
0.833
0.769
0.729
0.697
0.439

(m )
52.122
120.992
137.151
153.277
169.515
15.546

-6

B10

(nm)
0.173
0.229
0.239
0.248
0.256
0.115

(m mol )
13.030
30.248
34.288
38.319
42.379
3.887

Y10
-1

(m )
13.030
30.248
34.288
0.464
0.496
0.101

Va10
3

-1

(m mol )
18.900
50.281
50.320
51.351
52.078
0.802

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
844.493
641.990
709.590
759.439
803.176
1517.430

-1

(m mol )(ms )
0.614
1.345
1.534
1.721
1.910
0.209

-3

MA

2 -1

3.12
2.78
2.92
3.00
3.08
4.46

1.00
0.85
0.87
0.88
0.89
1.14

D 13 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.12. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 315.65 K.
6

315.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.702
0.844
0.778
0.727
0.695
0.432

(m )
52.214
121.283
137.467
153.776
170.041
15.599

D 14 | A. GAYOL

-6

B10

(nm)
0.173
0.229
0.239
0.248
0.256
0.116

(m mol )
13.053
30.321
34.367
38.444
42.510
3.900

Y10
-1

(m )
13.053
30.321
34.367
0.465
0.497
0.101

Va10
3

-1

(m mol )
19.268
51.419
51.474
52.591
53.360
0.759

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
835.594
632.420
700.303
750.031
793.968
1519.773

-1

(m mol )(ms )
0.614
1.345
1.534
1.721
1.910
0.210

-3

MA

2 -1

3.10
2.76
2.89
2.97
3.05
4.46

1.00
0.85
0.87
0.89
0.89
1.14

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.13. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 318.15 K.
6

318.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.714
0.855
0.787
0.739
0.705
0.433

(m )
52.241
121.560
137.769
154.042
170.333
15.611

-6

B10

(nm)
0.173
0.229
0.239
0.248
0.257
0.116

(m mol )
13.060
30.390
34.442
38.510
42.583
3.903

Y10
-1

(m )
13.060
30.390
34.442
0.466
0.498
0.101

Va10
3

-1

(m mol )
19.952
52.542
52.659
53.832
54.653
0.720

R10
3

-1

RA

MA

-1

(m mol )(ms )
0.613
1.345
1.534
1.720
1.910
0.210

Z10

-3

2 -1

3.06
2.73
2.86
2.95
3.03
4.47

1.00
0.85
0.87
0.88
0.89
1.14

0
0
0
0
0
0

(kgm s )
820.352
623.109
690.914
740.764
784.831
1521.578

D 15 | A. GAYOL

D.

Magnitudes Derivadas.

Tabla D.14. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 320.65 K.
6

320.65 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.710
0.867
0.797
0.750
0.716
0.434

(m )
52.456
121.858
138.092
154.332
170.657
15.622

D 16 | A. GAYOL

r
(nm)
0.173
0.229
0.239
0.248
0.257
0.116

-6

B10
3

Y10
-1

(m mol )
13.114
30.464
34.523
38.583
42.664
3.905

(m )
13.114
30.464
34.523
0.466
0.499
0.101

Va10
3

-1

(m mol )
19.695
53.701
53.882
55.100
55.940
0.687

R10
3

-1

RA

MA

-1

(m mol )(ms )
0.616
3.08
1.345
2.70
1.534
2.84
1.720
2.92
1.910
3.00
0.210
4.48

Z10

-3

2 -1

1.00
0.86
0.87
0.89
0.89
1.14

0
0
0
0
0
0

(kgm s )
824.355
613.596
681.316
731.340
775.726
1522.893

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla D.15. Magnitudes derivadas de los valores experimentales de Etanol, n-hexano, n-heptano, n-octano, n-nonano y agua a 323.15 K.
6

323.15 K

Lf

b10

Etanol
n-hexano
n-heptano
n-octano
n-nonano
Agua

()
0.722
0.878
0.806
0.762
0.726
0.436

(m )
52.482
122.146
138.380
154.599
170.947
15.633

-6

B10

(nm)
0.173
0.230
0.239
0.248
0.257
0.116

(m mol )
13.120
30.536
34.595
38.650
42.737
3.908

Y10
-1

(m )
13.120
30.536
34.595
0.467
0.499
0.101

Va10
3

-1

(m mol )
20.396
54.819
55.068
56.390
57.260
0.659

R10
3

-1

RA

Z10

0
0
0
0
0
0

(kgm s )
808.944
604.529
672.148
721.911
766.584
1523.686

-1

(m mol )(ms )
0.615
1.345
1.533
1.719
1.909
0.211

-3

MA

2 -1

3.04
2.67
2.81
2.89
2.98
4.49

1.00
0.85
0.87
0.88
0.89
1.14

D 17 | A. GAYOL

Anexo E
Parmetros de
ajuste de
ATPs con Tween 20

E. Parmetros de ajuste de ATPs con Tween 20.

E.

PARMETROS DE AJUSTE DE ATPS CON TWEEN 20.............................................................. 3

E.1

Tween 20 Na2S2O3 - agua. ......................................................................................... 3

E.2

Tween 20 K2HPO4 - agua. .......................................................................................... 7

E.3

Tween 20 K3PO4 - agua............................................................................................ 11

E.4

Bibliografa. ................................................................................................................ 14

E 2 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

E. PARMETROS DE AJUSTE DE ATPS CON TWEEN 20.

E.1 Tween 20 Na2S2O3 - agua.
Tabla E.1. Parmetros de ajuste de la ecuacin polinmica1 (5.3) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Tween 20 - Na2S2O3 agua

T (K)
288.15
298.15
308.15
318.15

A0
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

1.93 % Na2S2O3 nD
A1
A2
0.1680
0.1470
0.1479
0.1446
0.1458
0.1417
0.1559
0.1354
4.86 % Na2S2O3 nD
B
C
0.1550
0.1310
0.1899
0.1368
0.2268
0.1442
0.3326
0.1359
7.00 % Na2S2O3 nD
B
C
-3
0.1687
1.754510
-3
0.1652
1.704610
-3
0.1762
1.622510
-3
0.1716
1.636710
9.88 % Na2S2O3 nD
B
C
0.2095
0.1417
0.2052
0.1389
0.2052
0.1352
0.2043
0.1345
12.00 % Na2S2O3 nD
B
C
0.1990
0.2132
0.1947
0.2073
0.1919
0.2209
0.1876
0.2222

A3
0.0000
0.0000
0.0000
0.0000

-5
1.3110
-6
7.1510
-6
5.0810
-6
4.2210

D
0.0000
0.0000
0.0000
0.0000

-5
1.2210
-6
1.4910
-6
2.3510
-5
2.3610

D
0.0000
0.0000
0.0000
0.0000

-5
3.9010
-5
3.3310
-5
2.9310
-5
3.1410

D
0.0000
0.0000
0.0000
0.0000

-7
4.7210
-7
5.2910
-7
2.9210
-7
4.4710

D
0.0000
0.0000
0.0000
0.0000

-7
9.7210
-7
8.1610
-7
5.1610
-7
5.2410

Govindarajan, r., Divya, K., Perumalsamy, M., (2013), Phase Behavior and Density for Binary and Ternary
Solutions of PEG 4000 + Triammonium Citrate + Water Aqueous Two Phase Systems at Different
Temeperatures, J. Chem. Eng. Data 58, 315-321.

E 3 | A. GAYOL

E.

Parmetros de ajuste de ATPs con Tween 20.

Tabla E.2 Parmetros de ajuste de la ecuacin polinmica2 (5.5) y las desviaciones cuadrticas
medias () de la densidad del sistema Tween 20 - Na2S2O3 agua
T (K)
288.15
298.15
308.15
318.15

0
0.9906
1.0052
1.0020
0.9981

T (K)
288.15
298.15
308.15
318.15

0
1.0261
1.0052
1.0234
1.0158

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

1.93 % Na2S2O3
A1
A2
0.9870
-0.1700
0.2169
-0.2122
0.2101
-0.2186
0.2060
-0.2389
4.86 % Na2S2O3
A1
A2
0.4484
-1.8176
0.2169
-0.2122
0.4651
-2.2410
0.4090
-1.6855
7.00 % Na2S2O3
A1
A2
0.9831
1.7588
0.9782
1.6889
0.9868
1.5693
0.9632
1.4738
9.88 % Na2S2O3
A1
A2
0.8762
0.7467
0.8680
0.6642
0.8933
0.9198
0.9195
1.1848
12.00 % Na2S2O3
A1
A2
0.8609
0.8408
0.8555
0.7962
0.8513
0.7607
0.8480
0.7336

A3
-3.1777
0.1573
0.1687
0.1831

-2
5.2910
-4
1.3210
-4
1.2710
-4
1.2210

A3
3.1993
0.1573
4.3300
2.9490

-3
1.0910
-3
1.0410
-4
1.2710
-4
9.8710

A3
-0.4462
-1.4441
-3.1533
-4.5177

-3
1.3710
-3
1.2010
-3
1.1010
-3
1.0210

A3
-9.6851
-10.5205
-7.9328
-5.2506

-4
1.0810
-5
9.7410
-4
1.0810
-4
1.2010

A3
-6.6598
-7.0315
-7.3272
-7.5533

-6
8.8910
-6
7.4510
-6
6.7410
-6
6.2010

Saravanan, S., Reena, J.A., Rao, J.R., Murugesan, T., Nair, B.U.,(2006), Phase Equilibrium compositions,
Densities, and Viscosities of Aqueous Two-Phase Poly(ethylene glycol) + Poly(acrylic acid) System at Various
Temperatures, J. Chem. Eng. Data, 51 1246-1249.

E 4 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla E.3. Parmetros de ajuste de la ecuacin polinmica3 (5.6) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Tween 20 - Na2S2O3 agua.
T (K)
288.15
298.15
308.15
318.15

A0
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

1.93 % Na2S2O3 nD
A1
A2
0.1680
0.1470
0.1479
0.1446
0.1458
0.1417
0.1559
0.1354
4.86 % Na2S2O3 nD
B
C
0.1550
0.1310
0.1899
0.1368
0.2268
0.1442
0.3326
0.1359
7.00 % Na2S2O3 nD
B
C
-3
0.1687
1.754510
-3
0.1652
1.704610
-3
0.1762
1.622510
-3
0.1716
1.636710
9.88 % Na2S2O3 nD
B
C
0.2095
0.1417
0.2052
0.1389
0.2052
0.1352
0.2043
0.1345
12.00 % Na2S2O3 nD
B
C
0.1990
0.2132
0.1947
0.2073
0.1919
0.2209
0.1876
0.2222

A3
0.0000
0.0000
0.0000
0.0000

-5
1.3110
-6
7.1510
-6
5.0810
-6
4.2210

D
0.0000
0.0000
0.0000
0.0000

-5
1.2210
-6
1.4910
-6
2.3510
-5
2.3610

D
0.0000
0.0000
0.0000
0.0000

-5
3.9010
-5
3.3310
-5
2.9310
-5
3.1410

D
0.0000
0.0000
0.0000
0.0000

-7
4.7210
-7
5.2910
-7
2.9210
-7
4.4710

D
0.0000
0.0000
0.0000
0.0000

-7
9.7210
-7
8.1610
-7
5.1610
-7
5.2410

Kalaivani, S., Srikanth, C.K., Regupathi, I.,(2012), Densities and Viscosities of Binary and Ternary Mixutes and
Aqueous two-Phase System of Poly/ethylene glycol) 2000 + Diammonium hydrogen Citrate + Water at
Different Temperatures, J. Chem. Eng. Data., 57, 2528-2534.

E 5 | A. GAYOL

E.

Parmetros de ajuste de ATPs con Tween 20.

Tabla E.4 Parmetros de ajuste de las ecuaciones polinmicas3,4 (5.7) y (5.8) y las desviaciones
cuadrticas medias () de la densidad del sistema Tween 20 - Na2S2O3 agua
T (K)
288.15
298.15
308.15
318.15

A0
0.1676
0.1371
0.1300
0.1218

T (K)
288.15
298.15
308.15
318.15

A0
0.1470
0.1358
0.1330
0.1270

T (K)
288.15
298.15
308.15
318.15

A0
0.8169
0.8165
0.8034
0.7932

T (K)
288.15
298.15
308.15
318.15

A0
0.8079
0.7860
0.8593
0.7860

T (K)
288.15
298.15
308.15
318.15

A0
0.8506
0.8358
0.8237
0.8145

1.93 % Na2S2O3
A1
A2
3.1627
0.0000
0.8134
0.0000
0.8010
0.0000
0.8014
0.0000
4.86% Na2S2O3
A1
A2
0.8294
0.0000
0.8097
0.0000
0.7982
0.0000
0.7876
0.0000
7.00 % Na2S2O3
A1
A2
0.1500
0.0000
0.1425
0.0000
0.1363
0.0000
0.1311
0.0000
9.88 % Na2S2O3
A1
A2
0.1222
0.0000
0.1157
0.0000
0.1222
0.0000
0.1157
0.0000
12.00 % Na2S2O3
A1
A2
0.1380
0.0000
0.1264
0.0000
0.1202
0.0000
0.1153
0.0000

A3
0.0000
0.0000
0.0000
0.0000

-2
7.4610
-6
6.2610
-6
5.4610
-6
5.2310

A3
0.0000
0.0000
0.0000
0.0000

-7
8.8010
-6
3.6810
-7
8.0110
-6
1.0510

A3
0.0000
0.0000
0.0000
0.0000

-5
4.0410
-6
4.8710
-6
5.3210
-6
6.2410

A3
0.0000
0.0000
0.0000
0.0000

-6
4.2310
-6
4.2010
-6
4.2310
-6
4.3110

A3
0.0000
0.0000
0.0000
0.0000

-9
4.1110
-10
5.9110
-10
9.1210
-9
2.2810

Regupathi, I., Covindarajan, R., Amaresh, S.P., Murugesan. T.,(2009), Densities and Viscosities of Polyethylene
Glycol 6000 + Triammoniun Citrate + Water Systems, J. Chem, Eng. Data, 54, 3291-3295.

E 6 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

E.2 Tween 20 K2HPO4 - agua.

Tabla E.5 Parmetros de ajuste de la ecuacin polinmica1 (5.3) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Tween 20 - K2HPO4 agua
T (K)
288.15
298.15
308.15
318.15

A0
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

1.57 % K2HPO4 nD
A1
A2
0.1298
0.1368
0.1139
0.1375
0.1077
0.1393
0.0993
0.1431
3.20 % K2HPO4 nD
B
C
0.1728
0.1405
0.1676
0.1373
0.1683
0.1341
0.1672
0.1338
5.19 % K2HPO4 nD
B
C
0.1480
0.1618
0.1441
0.1582
0.1455
0.1534
0.1471
0.1512
7.19 % K2HPO4 nD
B
C
0.1611
0.1285
0.1576
0.1254
0.1598
0.1227
0.1632
0.1207

A3
0.0000
0.0000
0.0000
0.0000

-5
2.3810
-6
3.5210
-6
3.6110
-5
2.0010

D
0.0000
0.0000
0.0000
0.0000

-7
2.4210
-7
2.7310
-7
2.7110
-7
6.2710

D
0.0000
0.0000
0.0000
0.0000

-6
1.9910
-6
1.8410
-6
1.7110
-6
1.1810

D
0.0000
0.0000
0.0000
0.0000

-8
2.3610
-8
7.8510
-7
5.9210
-7
7.5010

E 7 | A. GAYOL

E.

Parmetros de ajuste de ATPs con Tween 20.

Tabla E.6 Parmetros de ajuste de la ecuacin polinmica2 (5.5) y las desviaciones cuadrticas
medias () de la densidad del sistema Tween 20 - K2HPO4 agua
T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

E 8 | A. GAYOL

1.57 % K2HPO4
A1
A2
1.4363
29.7911
1.4042
27.7438
1.3738
25.8067
1.3546
24.5858
3.20 % K2HPO4
A1
A2
1.1091
5.4100
1.0944
4.9506
1.0826
4.5806
1.1849
7.7769
5.19 % K2HPO4
A1
A2
0.9540
1.1139
0.9477
0.9915
0.9427
0.8955
0.9265
0.5845
7.19 % K2HPO4
A1
A2
0.9299
1.0250
0.9086
0.7294
0.9197
0.8829
0.9163
0.8360

A3
1773.1363
1642.7348
1519.3478
1441.5871

-3
2.4610
-3
2.1810
-3
1.9510
-3
1.7810

A3
109.5629
95.2074
83.6450
183.5269

-4
6.4310
-4
5.8410
-4
5.3310
-3
1.2510

A3
-14.0731
-16.4312
-18.2815
-24.2728

-5
4.9710
-5
4.5010
-5
4.0810
-4
1.3710

A3
-10.5600
-14.6721
-12.5366
-13.1890

-5
4.6810
-5
3.9510
-5
3.9110
-5
3.6210

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla E.7 Parmetros de ajuste de la ecuacin polinmica3 (5.6) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Tween 20 - K2HPO4 agua.
T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

1.57 % K2HPO4 nD
B
C
0.1298
0.1368
0.1139
0.1375
0.1077
0.1393
0.0993
0.1431
3.20 % K2HPO4 nD
B
C
0.1728
0.1405
0.1676
0.1373
0.1683
0.1341
0.1672
0.1338
5.19 % K2HPO4 nD
B
C
0.1480
0.1618
0.1441
0.1582
0.1455
0.1534
0.1471
0.1512
7.19 % K2HPO4 nD
B
C
0.1611
0.1285
0.1576
0.1254
0.1598
0.1227
0.1632
0.1207

D
0.0000
0.0000
0.0000
0.0000

-5
2.3810
-6
3.5210
-6
3.6110
-5
2.0010

D
0.0000
0.0000
0.0000
0.0000

-7
2.4210
-7
2.7310
-7
2.7110
-7
6.2710

D
0.0000
0.0000
0.0000
0.0000

-6
1.9910
-6
1.8410
-6
1.7110
-6
1.1810

D
0.0000
0.0000
0.0000
0.0000

-8
2.3610
-8
7.8510
-7
5.9210
-7
7.5010

E 9 | A. GAYOL

E.

Parmetros de ajuste de ATPs con Tween 20.

Tabla E.8 Parmetros de ajuste de las ecuaciones polinmicas3,4 (5.7) y (5.8) y las desviaciones
cuadrticas medias () de la densidad del sistema Tween 20 - K2HPO4 agua
T (K)
288.15
298.15
308.15
318.15

A0
0.8257
0.8421
0.8279
0.8284

T (K)
288.15
298.15
308.15
318.15

A0
0.8619
0.8430
0.8302
0.8988

T (K)
288.15
298.15
308.15
318.15

A0
0.9199
0.9039
0.8916
0.8147

T (K)
288.15
298.15
308.15
318.15

A0
0.8836
0.8925
0.8589
0.8512

E 10 | A. GAYOL

1.57 % K2HPO4
A1
A2
0.1403
0.0000
0.1322
0.0000
0.1250
0.0000
0.1195
0.0000
3.20 % K2HPO4
A1
A2
0.1461
0.0000
0.1391
0.0000
0.1329
0.0000
0.1126
0.0000
5.19 % K2HPO4
A1
A2
0.0521
0.0000
0.0491
0.0000
0.0466
0.0000
0.0741
0.0000
7.19 % K2HPO4
A1
A2
0.1479
0.0000
-0.0164
0.0000
0.1346
0.0000
0.1291
0.0000

A3
0.0000
0.0000
0.0000
0.0000

-6
1.4110
-6
1.3510
-6
2.6810
-7
9.1410

A3
0.0000
0.0000
0.0000
0.0000

-6
5.8810
-6
5.5710
-6
5.4410
-5
1.3710

A3
0.0000
0.0000
0.0000
0.0000

-5
1.2110
-5
1.1510
-5
1.0710
-5
6.1110

A3
0.0000
0.0000
0.0000
0.0000

-6
4.0010
-6
3.9010
-6
3.7510
-6
3.6510

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

E.3 Tween 20 K3PO4 - agua.

1

Tabla E.9: Parmetros de ajuste de la ecuacin polinmica (5.3) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Tween 20 - K3PO4 agua
T (K)
288.15
298.15
308.15
318.15

A0
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

2.00 % K3PO4 nD
A1
A2
0.1817
0.1406
0.1756
0.1376
0.1774
0.1352
0.1741
0.1366
4.43 % K3PO4 nD
B
C
0.1864
0.1397
0.1802
0.1370
0.1702
0.1364
0.1868
0.1340
7.19 % K3PO4 nD
B
C
0.1812
0.1509
0.1768
0.1475
0.1770
0.1440
0.1900
0.1242
10.26 % K3PO4 nD
B
C
0.1843
0.1323
0.1772
0.1279
0.1775
0.1211
0.1795
0.1251

A3
0.0000
0.0000
0.0000
0.0000

-6
1.4710
-6
1.4710
-6
1.6610
-6
1.5210

D
0.0000
0.0000
0.0000
0.0000

-6
6.0810
-6
5.2510
-6
2.6610
-6
4.2310

D
0.0000
0.0000
0.0000
0.0000

-7
1.0210
-8
5.0210
-8
4.9510
-6
3.6610

D
0.0000
0.0000
0.0000
0.0000

-8
4.0710
-7
2.9710
-7
2.1510
-7
1.9110

E 11 | A. GAYOL

E.

Parmetros de ajuste de ATPs con Tween 20.

2

Tabla E.10: Parmetros de ajuste de la ecuacin polinmica (5.5) y las desviaciones cuadrticas
medias () de la densidad del sistema Tween 20 - K3PO4 agua
T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

T (K)
288.15
298.15
308.15
318.15

0
0.9991
0.9970
0.9940
0.9902

E 12 | A. GAYOL

2.00 % K3PO4
A1
A2
1.3365
18.8232
1.3118
17.5902
1.2914
16.5712
1.2743
15.7152
4.43 % K3PO4
A1
A2
1.0640
3.4437
1.0549
3.2388
1.0443
2.9991
1.0372
2.8402
7.19 % K3PO4
A1
A2
0.9852
1.7942
0.9761
1.6671
0.9705
1.5904
0.9662
1.5305
10.26 % K3PO4
A1
A2
0.9206
1.2259
0.9143
1.1651
0.9093
1.1156
0.9073
1.0969

A3
844.1603
782.5103
731.5599
688.7595

-3
1.1410
-3
1.0210
-4
9.2410
-4
8.4610

A3
35.5900
30.9647
25.5533
21.9664

-3
1.1310
-4
5.8410
-4
9.2510
-4
8.4910

A3
0.1378
-1.6295
-2.6969
-3.5292

-4
2.0010
-4
1.7110
-4
1.5810
-4
1.4710

A3
-4.5446
-5.1369
-5.6196
-5.8026

-5
2.8710
-5
3.4210
-5
4.1810
-5
2.9910

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

3

Tabla E.11 Parmetros de ajuste de la ecuacin polinmica (5.6) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Tween 20 - K3PO4 agua.
T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

2.00 % K3PO4 nD
B
C
0.1817
0.1406
0.1756
0.1376
0.1774
0.1352
0.1741
0.1366
4.43 % K3PO4 nD
B
C
0.1864
0.1397
0.1802
0.1370
0.1702
0.1364
0.1868
0.1340
7.19 % K3PO4 nD
B
C
0.1812
0.1509
0.1768
0.1475
0.1770
0.1440
0.1900
0.1242
10.26 % K3PO4 nD
B
C
0.1843
0.1323
0.1772
0.1279
0.1775
0.1211
0.1795
0.1251

D
0.0000
0.0000
0.0000
0.0000

-6
1.4710
-6
1.4710
-6
1.6610
-6
1.5210

D
0.0000
0.0000
0.0000
0.0000

-6
6.0810
-6
5.2510
-6
2.6610
-6
4.2310

D
0.0000
0.0000
0.0000
0.0000

-7
1.0210
-8
5.0210
-8
4.9510
-6
3.6610

D
0.0000
0.0000
0.0000
0.0000

-8
4.0710
-7
2.9710
-7
2.1510
-7
1.9110

E 13 | A. GAYOL

E.

Parmetros de ajuste de ATPs con Tween 20.

3,4

Tabla E.12: Parmetros de ajuste de las ecuaciones polinmicas (5.7) y (5.8) y las desviaciones
cuadrticas medias () de la densidad del sistema Tween 20 - K3PO4 agua
T (K)
288.15
298.15
308.15
318.15

A0
0.9906
0.9743
0.9620
0.9520

T (K)
288.15
298.15
308.15
318.15

A0
0.9658
0.9582
0.9372
0.9283

T (K)
288.15
298.15
308.15
318.15

A0
1.0013
0.9799
0.9676
0.9584

T (K)
288.15
298.15
308.15
318.15

A0
0.9609
0.9389
0.9196
0.9207

2.00 % K3PO4
A1
A2
0.1394
0.0000
0.1318
0.0000
0.1254
0.0000
0.1199
0.0000
4.43 % K3PO4
A1
A2
0.1335
0.0000
0.1254
0.0000
0.1208
0.0000
0.1157
0.0000
7.19 % K3PO4
A1
A2
0.1366
0.0000
0.1294
0.0000
0.1242
0.0000
0.1198
0.0000
10.26 % K3PO4
A1
A2
0.2014
0.0000
0.2187
0.0000
0.2403
0.0000
0.2039
0.0000

A3
0.0000
0.0000
0.0000
0.0000

-7
8.3010
-7
7.1510
-7
6.1910
-7
5.4210

A3
0.0000
0.0000
0.0000
0.0000

-6
4.2710
-6
8.7110
-6
3.9610
-6
3.8510

A3
0.0000
0.0000
0.0000
0.0000

-5
1.2010
-6
2.1010
-6
2.0610
-6
2.0410

A3
0.0000
0.0000
0.0000
0.0000

-6
2.2910
-6
3.0810
-6
4.1510
-6
2.8310

E.4 Bibliografa.
Govindarajan, r., Divya, K., Perumalsamy, M.,(2013), Phase Behavior and
Density for Binary and Ternary Solutions of PEG 4000 + Triammonium Citrate +
Water Aqueous Two Phase Systems at Different Temeperatures, J. Chem. Eng.
Data 58, 315-321.
Kalaivani, S., Srikanth, C.K., Regupathi, I.,(2012), Densities and Viscosities of
Binary and Ternary Mixutes and Aqueous two-Phase System of Poly/ethylene
glycol) 2000 + Diammonium hydrogen Citrate + Water at Different
Temperatures, J. Chem. Eng. Data., 57, 2528-2534.
Regupathi, I., Covindarajan, R., Amaresh, S.P., Murugesan. T.,(2009), Densities
and Viscosities of Polyethylene Glycol 6000 + Triammoniun Citrate + Water
Systems, J. Chem, Eng. Data, 54, 3291-3295.

E 14 | A. GAYOL

Anexo F
Parmetros de
ajuste de ATPs con
Triton X-102

F.

Parmetros de ajuste de ATPs con Triton X-102.

F.

PARMETROS DE AJUSTE DE ATPS CON TRITON X-102. ....................................................... 3

F.1.

Triton X-102 Na2S2O3 - agua. ..................................................................................... 3

F.2.

Triton X-102 K2HPO4 - agua. ...................................................................................... 7

F.3.

Triton X-102 K3PO4 - agua. ...................................................................................... 11

F.4.

Bibliografa ................................................................................................................. 14

F 2 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

F. PARMETROS DE AJUSTE DE ATPS CON TRITON X-102.

F.1. Triton X-102 Na2S2O3 - agua.
Tabla F.1 Parmetros de ajuste de la ecuacin polinmica 1(5.3) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Triton X-102 - Na2S2O3 agua
T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

2.50% Na2S2O3 nD
B
C
0.1307
0.5186
0.1302
0.4743
0.1246
0.5006
0.1219
0.4729
5.00% Na2S2O3 nD
B
C
0.0778
0.3917
0.0749
0.3879
0.0467
0.4084
0.0491
0.3840
7.48% Na2S2O3 nD
B
C
0.0206
0.2946
0.0173
0.2902
0.0143
0.2912
0.0123
0.2872
10.03% Na2S2O3nD
B
C
0.3044
0.1660
0.3062
0.1618
0.2994
0.1612
0.2846
0.1602
12.55% Na2S2O3nD
B
C
0.3313
0.1344
0.3307
0.1313
0.3242
0.1311
0.3138
0.1285

D
0.0000
0.0000
0.0000
0.0000

-3
2.0810
-3
1.9710
-3
1.6610
-3
1.5110

D
0.0000
0.0000
0.0000
0.0000

-4
2.3510
-4
2.7810
-4
2.7010
-4
2.6010

D
0.0000
0.0000
0.0000
0.0000

-5
9.2110
-5
9.0010
-4
1.0010
-4
1.0810

D
0.0000
0.0000
0.0000
0.0000

-6
9.5710
-6
8.0510
-6
7.8910
-6
6.0410

D
0.0000
0.0000
0.0000
0.0000

-5
5.8110
-5
5.3710
-5
5.4910
-5
4.9310

Govindarajan, r., Divya, K., Perumalsamy, M., (2013), Phase Behavior and Density for Binary and Ternary
Solutions of PEG 4000 + Triammonium Citrate + Water Aqueous Two Phase Systems at Different
Temeperatures, J. Chem. Eng. Data., 58, 315-321.

F 3 | A. GAYOL

F. Parmetros de ajuste de ATPs con Triton X-102.

Tabla F.2 Parmetros de ajuste de la ecuacin polinmica2 (5.5) y las desviaciones cuadrticas
medias () de la densidad del sistema Triton X-102 - Na2S2O3 agua
T (K)
288.15
298.15
308.15
318.15

A
1.0120
1.0093
1.0061
1.0021

2.50% Na2S2O3
B
C
0.2500
-0.6491
0.2522
-0.6630
0.2420
-0.6462
0.2345
-0.6425

D
0.8724
0.8454
0.8197
0.8182

-4
3.0610
-4
2.5510
-4
2.4710
-4
2.4210

T (K)
288.15
298.15
308.15
318.15

A
1.0206
1.0181
1.0147
1.0106

5.00% Na2S2O3
B
C
0.6817
-4.3826
0.6624
-4.2968
0.6466
-4.2288
0.6353
-4.1880

D
9.7565
9.5738
9.4298
9.3443

-4
9.1910
-4
8.7910
-4
8.5010
-4
8.2610

T (K)
288.15
298.15
308.15
318.15

A
1.0314
1.0287
1.0252
1.0210

7.48% Na2S2O3
B
C
1.1686
-9.4908
1.1402
-9.3122
1.1176
-9.1740
1.1027
-9.1114

D
25.0631
24.6223
24.2754
24.0762

-3
2.0410
-3
1.9610
-3
1.9010
-3
1.8610

T (K)
288.15
298.15
308.15
318.15

A
1.0416
1.0387
1.0351
1.0308

10.03% Na2S2O3
B
C
1.9446
-23.6489
1.8999
-23.1827
1.8638
-22.8000
1.8367
-22.5553

D
94.6387
92.7987
91.1899
89.9877

-3
3.6010
-3
3.4710
-3
3.3710
-3
3.2910

T (K)
288.15
298.15
308.15
318.15

A
1.0114
1.0091
1.0059
1.0020

12.55% Na2S2O3
B
C
0.3328
-1.3096
0.3213
-1.2916
0.3117
-1.2780
0.3007
-1.2390

D
2.3101
2.2819
2.2605
2.1819

-4
2.9510
-4
2.8110
-4
2.7210
-4
2.6210

Saravanan, S., Reena, J.A., Rao, J.R., Murugesan, T., Nair, B.U.,(2006), Phase Equilibrium compositions,
Densities, and Viscosities of Aqueous Two-Phase Poly(ethylene glycol) + Poly(acrylic acid) System at Various
Temperatures, J. Chem. Eng. Data., 51 1246-1249.

F 4 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla F.3 Parmetros de ajuste de la ecuacin polinmica3 (5.6) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Triton X-102 - Na2S2O3 agua.
T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

2.50% Na2S2O3 nD
B
C
0.1307
0.5186
0.1302
0.4743
0.1246
0.5006
0.1219
0.4729
5.00% Na2S2O3 nD
B
C
0.0778
0.3917
0.0749
0.3879
0.0467
0.4084
0.0491
0.3840
7.48% Na2S2O3 nD
B
C
0.0206
0.2946
0.0173
0.2902
0.0143
0.2912
0.0123
0.2872
10.03% Na2S2O3nD
B
C
0.3044
0.1660
0.3062
0.1618
0.2994
0.1612
0.2846
0.1602
12.55% Na2S2O3nD
B
C
0.3313
0.1344
0.3307
0.1313
0.3242
0.1311
0.3138
0.1285

D
0.0000
0.0000
0.0000
0.0000

-3
2.0810
-3
1.9710
-3
1.6610
-3
1.5110

D
0.0000
0.0000
0.0000
0.0000

-4
2.3510
-4
2.7810
-4
2.7010
-4
2.6010

D
0.0000
0.0000
0.0000
0.0000

-5
9.2110
-5
9.0010
-4
1.0010
-4
1.0810

D
0.0000
0.0000
0.0000
0.0000

-6
9.5710
-6
8.0510
-6
7.8910
-6
6.0410

D
0.0000
0.0000
0.0000
0.0000

-5
5.8110
-5
5.3710
-5
5.4910
-5
4.9310

Kalaivani, S., Srikanth, C.K., Regupathi, I.,(2012), Densities and Viscosities of Binary and Ternary Mixutes and
Aqueous two-Phase System of Poly/ethylene glycol) 2000 + Diammonium hydrogen Citrate + Water at
Different Temperatures, J. Chem. Eng. Data., 57, 2528-2534.

F 5 | A. GAYOL

F. Parmetros de ajuste de ATPs con Triton X-102.

Tabla F.4 Parmetros de ajuste de las ecuaciones polinmicas 3,4 (5.7) y (5.8) y las desviaciones
cuadrticas medias () de la densidad del sistema Tween 20 - Na2S2O3 agua.
T (K)
288.15
298.15
308.15
318.15

A
0.8255
0.8317
0.8194
0.8088

2.50% Na2S2O3
B
C
0.1127
0.0000
0.1041
0.0000
0.0968
0.0000
0.0908
0.0000

D
0.0000
0.0000
0.0000
0.0000

-5
3.0510
-6
1.8910
-6
1.7610
-6
2.2610

T (K)
288.15
298.15
308.15
318.15

A
0.8592
0.8353
0.8214
0.8100

5.00% Na2S2O3
B
C
0.1099
0.0000
0.1025
0.0000
0.0960
0.0000
0.0907
0.0000

D
0.0000
0.0000
0.0000
0.0000

-7
5.1710
-7
5.4010
-7
5.6210
-7
5.9410

T (K)
288.15
298.15
308.15
318.15

A
0.8528
0.8353
0.8221
0.8138

7.48% Na2S2O3
B
C
0.1143
0.0000
0.1070
0.0000
0.1004
0.0000
0.0919
0.0000

D
0.0000
0.0000
0.0000
0.0000

-7
5.4310
-7
4.4610
-7
4.0910
-7
4.4510

T (K)
288.15
298.15
308.15
318.15

A
0.8477
0.8314
0.8190
0.8104

10.03% Na2S2O3
B
C
0.1213
0.0000
0.1126
0.0000
0.1044
0.0000
0.0932
0.0000

D
0.0000
0.0000
0.0000
0.0000

-8
1.2910
-9
7.0310
-9
8.3710
-8
5.8710

T (K)
288.15
298.15
308.15
318.15

A
0.9016
0.8826
0.8687
0.8581

12.55% Na2S2O3
B
C
0.1134
0.0000
0.1053
0.0000
0.0984
0.0000
0.0925
0.0000

D
0.0000
0.0000
0.0000
0.0000

-5
1.0810
-6
9.8010
-6
9.0410
-6
5.0210

Regupathi, I., Covindarajan, R., Amaresh, S.P., Murugesan. T.,(2009), Densities and Viscosities of Polyethylene
Glycol 6000 + Triammoniun Citrate + Water Systems, J. Chem, Eng. Data., 54, 3291-3295.

F 6 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

F.2. Triton X-102 K2HPO4 - agua.

Tabla F.5 Parmetros de ajuste de la ecuacin polinmica1 (5.3) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Triton X-102 - K2HPO4 agua
2.54% K2HPO4 nD
T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

0.1646
0.1768
0.1615
0.1733
0.1565
0.1796
0.1520
0.1681
5.08% K2HPO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

1.9210
-6
2.6610
-6
1.0410
-7
2.6810

0.0182
0.3472
0.0139
0.3380
0.0141
0.3104
0.0120
0.2994
7.48% K2HPO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

2.7810
-4
2.6710
-4
2.2010
-4
1.9110

0.0363
0.1657
0.0326
0.1619
0.0337
0.1559
0.0298
0.1588
10.03% K2HPO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

3.4910
-7
5.0110
-7
8.7710
-6
2.6310

0.0678
0.1601
0.0695
0.1567
0.0429
0.1581
0.0409
0.1591
12.55% K2HPO4 nD
B
C
0.1119
0.1568
0.1530
0.1527
0.1130
0.1526
0.0778
0.1527

0.0000
0.0000
0.0000
0.0000

2.1710
-7
2.1710
-8
2.4510
-8
7.7510

D
0.0000
0.0000
0.0000
0.0000

-8
5.2210
-8
4.9810
-8
3.4710
-7
1.0810

-6

-4

-7

-7

F 7 | A. GAYOL

F. Parmetros de ajuste de ATPs con Triton X-102.

Tabla F.6 Parmetros de ajuste de la ecuacin polinmica2 (5.5) y las desviaciones cuadrticas
medias () de la densidad del sistema Triton X-102 - K2HPO4 agua
T (K)
288.15
298.15
308.15
318.15

0
1.0103
1.0080
1.0133
1.0009

T (K)
288.15
298.15
308.15
318.15

0
1.0223
1.0201
1.0166
1.0126

T (K)
288.15
298.15
308.15
318.15

0
1.0319
1.0293
1.0259
1.0218

T (K)
288.15
298.15
308.15
318.15

0
1.0435
1.0408
1.0373
1.0331

T (K)
288.15
298.15
308.15
318.15

0
1.0551
1.0523
1.0487
1.0444

F 8 | A. GAYOL

2.54% K2HPO4
A1
A2
0.2996
-0.9367
0.2892
-0.9257
-1.8500
21.8598
0.2743
-0.9224
5.08% K2HPO4
A1
A2
0.6704
-3.9918
0.5771
-2.5884
0.6388
-3.8689
0.6223
-3.7538
7.48% K2HPO4
A1
A2
1.1580
-10.5388
1.1457
-10.6505
1.1247
-10.5562
1.1169
-10.6612
10.03% K2HPO4
A1
A2
8.6177
-496.8238
8.4762
-489.1972
8.3720
-483.6298
8.2917
-479.3609
12.55% K2HPO4
A1
A2
53.3924
-14449.2574
51.6824
-14273.3893
51.1342
-14136.5199
50.5298
-13900.8918

A3
1.3959
1.3815
-46.7184
1.3854

-4
2.4310
-4
2.3410
-2
7.7010
-4
2.2310

A3
8.4834
3.6139
8.2400
7.9521

-3
1.0410
-3
1.0310
-4
9.8510
-4
9.7010

A3
35.1682
36.0722
36.0676
36.8334

-3
2.1510
-3
2.0810
-3
2.0310
-3
1.9910

A3
8713.6686
8581.6048
8483.9559
8410.1391

-3
3.9410
-3
3.8210
-3
3.7310
-3
3.6710

A3
1244808.4671
1231103.8761
1220462.1042
1193804.325

-3
6.2710
-3
6.1010
-3
5.9610
-3
5.8710

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Tabla F.7 Parmetros de ajuste de la ecuacin polinmica3 (5.6) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Triton X-102 - K2HPO4 agua.
2.54% K2HPO4 nD
T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)
288.15
298.15
308.15
318.15

A
1.3335
1.3326
1.3312
1.3298

0.1646
0.1768
0.1615
0.1733
0.1565
0.1796
0.1520
0.1681
5.08% K2HPO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

1.9210
-6
2.6610
-6
1.0410
-7
2.6810

0.0182
0.3472
0.0139
0.3380
0.0141
0.3104
0.0120
0.2994
7.48% K2HPO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

2.7810
-4
2.6710
-4
2.2010
-4
1.9110

0.0363
0.1657
0.0326
0.1619
0.0337
0.1559
0.0298
0.1588
10.03% K2HPO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

3.4910
-7
5.0110
-7
8.7710
-6
2.6310

0.0678
0.1601
0.0695
0.1567
0.0429
0.1581
0.0409
0.1591
12.55% K2HPO4 nD
B
C
0.1119
0.1568
0.1530
0.1527
0.1130
0.1526
0.0778
0.1527

0.0000
0.0000
0.0000
0.0000

2.1710
-7
2.1710
-8
2.4510
-8
7.7510

D
0.0000
0.0000
0.0000
0.0000

-8
5.2210
-8
4.9810
-8
3.4710
-7
1.0810

-6

-4

-7

-7

F 9 | A. GAYOL

F. Parmetros de ajuste de ATPs con Triton X-102.

Tabla F.8 Parmetros de ajuste de las ecuaciones polinmicas3,4 (5.7) y (5.8) y las desviaciones
cuadrticas medias () de la densidad del sistema Tween 20 - K2HPO4 agua
T (K)
288.15
298.15
308.15
318.15

0
0.8697
0.8539
0.8412
0.8352

T (K)
288.15
298.15
308.15
318.15

0
0.8764
0.8933
0.8497
0.8410

T (K)
288.15
298.15
308.15
318.15

0
0.8678
0.8521
0.8401
0.8312

T (K)
288.15
298.15
308.15
318.15

0
0.8842
0.8707
0.8607
0.8534

T (K)
288.15
298.15
308.15
318.15

0
0.9006
0.8876
0.8780
0.8709

F 10 | A. GAYOL

2.54% K2HPO4
A1
A2
0.1111
0.0000
0.1033
0.0000
0.0974
0.0000
0.0905
0.0000
5.08% K2HPO4
A1
A2
0.1147
0.0000
0.0842
0.0000
0.1012
0.0000
0.0968
0.0000
7.48% K2HPO4
A1
A2
0.1468
0.0000
0.1412
0.0000
0.1365
0.0000
0.1316
0.0000
10.03% K2HPO4
A1
A2
0.1290
0.0000
0.1193
0.0000
0.1103
0.0000
0.1024
0.0000
12.55% K2HPO4
A1
A2
-0.0162
0.0000
-0.0291
0.0000
-0.0391
0.0000
-0.0354
0.0000

A3
0.0000
0.0000
0.0000
0.0000

-7
4.2410
-7
4.3310
-6
1.2310
-7
5.4310

A3
0.0000
0.0000
0.0000
0.0000

-6
2.5210
-5
6.3810
-6
2.7710
-6
4.1610

A3
0.0000
0.0000
0.0000
0.0000

-6
7.1310
-6
9.2310
-5
1.1010
-5
1.3210

A3
0.0000
0.0000
0.0000
0.0000

-7
1.3310
-7
1.3310
-7
1.2910
-7
1.3110

A3
0.0000
0.0000
0.0000
0.0000

-6
4.3910
-6
4.3110
-6
4.2010
-6
4.0710

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

F.3. Triton X-102 K3PO4 - agua.

1

Tabla F.9 Parmetros de ajuste de la ecuacin polinmica (5.3) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Triton X-102 - K3PO4 agua

2.53% K3PO4 nD
T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3313
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3473
1.3494
1.3516
1.3533

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

0.0000
0.0000
0.0000
0.0000

2.2910
-3
2.2410
-3
2.1810
-3
2.0210

2.470110
4.746310
-4
-4
2.222810
-2.244910
-4
-4
1.808610
-9.727310
-4
-3
1.500610
-1.656610
7.58% K3PO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

9.3510
-3
1.0910
-3
1.3210
-3
1.5810

0.0431
0.1836
0.0418
0.1777
0.0403
0.1768
0.0387
0.1728
10.26% K3PO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

1.1810
-5
1.0510
-6
5.3010
-6
6.2810

0.1208
0.1152
0.1007
0.0913

0.0000
0.0000
0.0000
0.0000

2.3110
-6
2.2510
-6
3.2810
-6
2.3610

0.1194
0.3862
0.1155
0.3909
0.1122
0.3812
0.1094
0.3588
5.01% K3PO4 nD
B
C
-4

-4

0.1670
0.1631
0.1654
0.1642

-3

-4

-5

-6

F 11 | A. GAYOL

F. Parmetros de ajuste de ATPs con Triton X-102.

2

Tabla F.10 Parmetros de ajuste de la ecuacin polinmica (5.5) y las desviaciones cuadrticas
medias () de la densidad del sistema Triton X-102 - K3PO4 agua.
T (K)
288.15
298.15
308.15
318.15

0
1.0124
1.0104
1.0072
1.0033

2.53% K3PO4
A1
A2
0.3089
-1.0178
0.2689
-0.7249
0.2596
-0.7138
0.2525
-0.7111

A3
1.4874
0.9385
0.9244
0.9237

-4
4.3110
-4
3.2010
-4
3.1010
-4
3.0210

T (K)
288.15
298.15
308.15
318.15

0
1.0261
1.0237
1.0203
1.0237

5.01% K3PO4
A1
A2
0.5473
-2.5452
0.5274
-2.4454
0.5106
-2.3647
0.5274
-2.4454

A3
4.6769
4.4707
4.3085
4.4707

-3
1.4710
-3
1.4510
-3
1.4610
-3
1.4310

T (K)
288.15
298.15
308.15
318.15

0
1.0453
1.0423
1.0388
1.0345

7.58% K3PO4
A1
A2
0.7517
-3.7139
0.7574
-3.8024
0.7556
-3.8282
0.7240
-3.6445

A3
7.3716
7.5384
7.5591
7.2176

-3
3.5410
-3
3.3910
-3
3.3410
-3
3.2510

T (K)
288.15
298.15
308.15
318.15

0
1.0392
1.0405
1.0411
1.0409

10.26% K3PO4
A1
A2
7.5557
-251.6060
8.1686
-279.3540
9.0686
-346.7075
9.8294
-391.2630

A3
577.8664
960.0286
2519.4049
3343.1913

-3
3.2110
-3
3.7710
-3
4.4210
-3
5.1410

F 12 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

3

Tabla F.11 Parmetros de ajuste de la ecuacin polinmica (5.6) y las desviaciones cuadrticas
medias () del ndice de refraccin del sistema Triton X-102 - K3PO4 agua.
2.53% K3PO4 nD
T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3313
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3473
1.3494
1.3516
1.3533

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

T (K)

288.15
298.15
308.15
318.15

1.3335
1.3326
1.3312
1.3298

0.0000
0.0000
0.0000
0.0000

2.2910
-3
2.2410
-3
2.1810
-3
2.0210

2.470110
4.746310
-4
-4
2.222810
-2.244910
-4
-4
1.808610
-9.727310
-4
-3
1.500610
-1.656610
7.58% K3PO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

9.3510
-3
1.0910
-3
1.3210
-3
1.5810

0.0431
0.1836
0.0418
0.1777
0.0403
0.1768
0.0387
0.1728
10.26% K3PO4 nD
B
C

0.0000
0.0000
0.0000
0.0000

1.1810
-5
1.0510
-6
5.3010
-6
6.2810

0.1208
0.1152
0.1007
0.0913

0.0000
0.0000
0.0000
0.0000

2.3110
-6
2.2510
-6
3.2810
-6
2.3610

0.1194
0.3862
0.1155
0.3909
0.1122
0.3812
0.1094
0.3588
5.01% K3PO4 nD
B
C
-4

-4

0.1670
0.1631
0.1654
0.1642

-3

-4

-5

-6

F 13 | A. GAYOL

F. Parmetros de ajuste de ATPs con Triton X-102.

3,4

Tabla F.12 Parmetros de ajuste de las ecuaciones polinmicas (5.7) y (5.8) y las desviaciones
cuadrticas medias () de la densidad del sistema Triton X-102 - K3PO4 agua
T (K)
288.15
298.15
308.15
318.15

0
0.7553
0.7406
0.7297
0.7221

T (K)
288.15
298.15
308.15
318.15

0
0.8904
0.8769
0.8648
0.8690

T (K)
288.15
298.15
308.15
318.15

0
0.9096
0.8997
0.8953
0.8771

T (K)
288.15
298.15
308.15
318.15

0
0.8514
0.9172
0.9811
1.0518

2.53% K3PO4
A1
A2
0.1261
0.0000
0.1215
0.0000
0.1145
0.0000
0.1084
0.0000
5.01% K3PO4
A1
A2
0.0112
0.0000
0.1412
0.0000
0.1349
0.0000
0.1231
0.0000
7.58% K3PO4
A1
A2
0.2071
0.0000
0.2012
0.0000
0.1939
0.0000
0.1893
0.0000
10.26% K3PO4
A1
A2
-0.5094
0.0000
-0.4902
0.0000
-0.3733
0.0000
-0.3415
0.0000

A3
0.0000
0.0000
0.0000
0.0000

-4
5.9310
-4
4.6010
-4
4.4610
-4
4.3510

A3
0.0000
0.0000
0.0000
0.0000

-4
3.6510
-4
3.5610
-4
3.8110
-4
3.0910

A3
0.0000
0.0000
0.0000
0.0000

-4
1.9510
-4
1.5610
-4
1.5410
-4
1.5410

A3
0.0000
0.0000
0.0000
0.0000

-4
4.2610
-4
4.4310
-4
3.5310
-4
3.3710

F.4. Bibliografa
Govindarajan, r., Divya, K., Perumalsamy, M., (2013), Phase Behavior and
Density for Binary and Ternary Solutions of PEG 4000 + Triammonium
Citrate + Water Aqueous Two Phase Systems at Different Temeperatures, J.
Chem. Eng. Data., 58, 315-321
Kalaivani, S., Srikanth, C.K., Regupathi, I.,(2012), Densities and Viscosities of
Binary and Ternary Mixutes and Aqueous two-Phase System of
Poly/ethylene glycol) 2000 + Diammonium hydrogen Citrate + Water at
Different Temperatures, J. Chem. Eng. Data., 57, 2528-2534.
Regupathi, I., Covindarajan, R., Amaresh, S.P., Murugesan. T.,(2009),
Densities and Viscosities of Polyethylene Glycol 6000 + Triammoniun Citrate
+ Water Systems, J. Chem, Eng. Data., 54, 3291-3295.
Saravanan, S., Reena, J.A., Rao, J.R., Murugesan, T., Nair, B.U.,(2006), Phase
Equilibrium compositions, Densities, and Viscosities of Aqueous Two-Phase
Poly(ethylene glycol) + Poly(acrylic acid) System at Various Temperatures, J.
Chem. Eng. Data., 51, 1246-1249.

F 14 | A. GAYOL

Anexo G
Grficas

G.

G.

Grficas.

GRFICAS .................................................................................................................. 3
G.1
G.1.1.

Sistemas estudiados ......................................................................................... 3

Grficas sistemas binarios orgnico orgnico ............................................. 5

G.1.1.1.
G.1.1.2.
G.1.1.3.
G.1.1.4.
G.1.1.5.
G.1.1.6.
G.1.1.7.
G.1.2.

Grficas sistemas binarios orgnico acuoso ............................................. 33

G.1.2.1.
G.1.3.

Etanol n-hexano n-heptano ............................................................ 53

Etanol n-hexano n-octano ............................................................... 56
Etanol n-hexano n-nonano.............................................................. 59

Grficas sistemas ternarios orgnico acuoso ............................................ 62

G.1.5.1.
G.1.5.2.
G.1.5.3.
G.1.5.4.
G.1.6.

Tween 20 agua ................................................................................... 37

Tritn X-102 agua ............................................................................... 41
Na2SO4 agua ....................................................................................... 45
Na2S2O3 agua ...................................................................................... 47
K2HPO4 agua ........................................................................................ 49
K3PO4 agua ......................................................................................... 51

Grficas sistemas ternarios orgnico orgnico ......................................... 53

G.1.4.1.
G.1.4.2.
G.1.4.3.
G.1.5.

Etanol agua......................................................................................... 33

Grficas sistemas binarios acuoso acuoso ................................................ 37

G.1.3.1.
G.1.3.2.
G.1.3.3.
G.1.3.4.
G.1.3.5.
G.1.3.6.
G.1.4.

Etanol n-hexano ................................................................................... 5

Etanol n-heptano ................................................................................. 9
Etanol n-octano .................................................................................. 13
Etanol n-nonano................................................................................. 17
n-hexano n-heptano........................................................................... 21
n-hexano n-octano ............................................................................. 25
n-hexano n-nonano ............................................................................ 29

Etanol n-hexano agua ..................................................................... 62

Etanol n-heptano agua ..................................................................... 65
Etanol n-octano agua ...................................................................... 68
Etanol n-nonano agua ..................................................................... 71

Grficas sistemas ternarios acuoso - acuoso ............................................... 74

G.1.6.1.
G.1.6.2.
G.1.6.3.
G.1.6.4.
G.1.6.5.
G.1.6.6.
G.1.6.7.
G.1.6.8.

G 2 | A. GAYOL

Tween 20 Na2SO4 agua.................................................................... 74

Tween 20 Na2S2O3 agua .................................................................. 82
Tween 20 K2HPO4 agua .................................................................... 92
Tween 20 K3PO4 agua .................................................................... 100
Triton X-102 Na2SO4 agua ............................................................. 108
Triton X-102 Na2S2O3 agua ............................................................ 114
Triton X-102 K2HPO4 agua .............................................................. 124
Triton X-102 K3PO4 agua ............................................................... 134

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G. GRFICAS
G.1 Sistemas estudiados
En la presente Tesis Doctoral se ha realizado el estudio las propiedades fsicas de los siguientes
sistemas:
Sistemas binarios orgnico orgnico:

Etanol n-hexano
Etanol n-heptano
Etanol n-octano
Etanol n-nonano
n-hexano n-heptano
n-hexano n-octano
n-hexano n-nonano

Sistemas binarios orgnico acuoso:

Etanol agua
Sistemas binarios acuoso acuoso:

Tween 20 agua
Tritn X-102 agua
Na2SO4 agua
Na2S2O3 agua
K2HPO4 agua
K3PO4 agua

Sistemas ternarios orgnico orgnico:

Etanol n-hexano n-heptano
Etanol n-hexano n-octano
Etanol n-hexano n-nonano
Sistemas ternarios orgnico acuoso:

Etanol n-hexano agua

Etanol n-heptano agua
Etanol n-octano agua
Etanol n-nonano agua

G 3 | A. GAYOL

G.

Grficas.

Sistemas ternarios acuoso acuoso:

Tween 20 Na2SO4 agua

Tween 20 Na2S2O3 agua
Tween 20 K2HPO4 agua
Tween 20 K3PO4 agua
Tritn X-102 Na2SO4 agua
Tritn X-102 Na2S2O3 agua
Tritn X-102 K2HPO4 agua
Tritn X-102 K3PO4 agua

G 4 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.

Grficas sistemas binarios orgnico orgnico

G.1.1.1.

Etanol n-hexano

Figura G-1. ndice de refraccin para el sistema binario Etanol (1) n-hexano (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-2. Densidad para el sistema binario Etanol (1) n-hexano (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

G 5 | A. GAYOL

G.

Grficas.

Figura G-3. Velocidad del sonido para el sistema binario Etanol (1) n-hexano (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-4. Desviacin del ndice de refraccin para el sistema binario Etanol (1) n-hexano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo
de Redlich-Kister.

G 6 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-5. Volumen de exceso para el sistema binario Etanol (1) n-hexano (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister

Figura G-6. Compresibilidad isoentrpica para el sistema binario Etanol (1) n-hexano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 7 | A. GAYOL

G.

Grficas.

Figura G-7. Desviacin de la compresibilidad isoentrpica el sistema binario Etanol (1) n-hexano (2)
a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al
modelo de Redlich-Kister

G 8 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.2.

Etanol n-heptano

Figura G-8. ndice de refraccin para el sistema binario Etanol (1) n-heptano (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-9. Densidad para el sistema binario Etanol (1) n-heptano (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

G 9 | A. GAYOL

G.

Grficas.

Figura G-10. Velocidad del sonido para el sistema binario Etanol (1) n-heptano (2) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-11. Desviacin del ndice de refraccin para el sistema binario Etanol (1) n-heptano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo
de Redlich-Kister

G 10 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-12. Volumen de exceso para el sistema binario Etanol (1) n-heptano (2) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de RedlichKister.

Figura G-13. Compresibilidad isoentrpica para el sistema binario Etanol (1) n-heptano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 11 | A. GAYOL

G.

Grficas.

Figura G-14. Desviacin de la compresibilidad isoentrpica el sistema binario Etanol (1) n-heptano
(2) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al
modelo de Redlich-Kister

G 12 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.3.

Etanol n-octano

Figura G-15. ndice de refraccin para el sistema binario Etanol (1) n-octano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-16. Densidad para el sistema binario Etanol (1) n-octano (2) a, T=288.15 K; , T = 298.15 K;
, T = 308.15 K; , T = 318.15 K

G 13 | A. GAYOL

G.

Grficas.

Figura G-17. Velocidad del sonido para el sistema binario Etanol (1) n-octano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-18. Desviacin del ndice de refraccin para el sistema binario Etanol (1) n-octano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de
Redlich-Kister.

G 14 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-19. Volumen de exceso para el sistema binario Etanol (1) n-octano (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

Figura G-20. Compresibilidad isoentrpica para el sistema binario Etanol (1) n-octano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 15 | A. GAYOL

G.

Grficas.

Figura G-21. Desviacin de la compresibilidad isoentrpica el sistema binario Etanol (1) n-octano (2)
a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al
modelo de Redlich-Kister.

G 16 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.4.

Etanol n-nonano

Figura G-22. ndice de refraccin para el sistema binario Etanol (1) n-nonano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-23. Densidad para el sistema binario Etanol (1) n-nonano (2) a, T=288.15 K; , T = 298.15 K; ,
T = 308.15 K; , T = 318.15 K

G 17 | A. GAYOL

G.

Grficas.

Figura G-24. Velocidad del sonido para el sistema binario Etanol (1) n-nonano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-25. Desviacin del ndice de refraccin para el sistema binario Etanol (1) n-nonano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de
Redlich-Kister.

G 18 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-26. Volumen de exceso para el sistema binario Etanol (1) n-nonano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

Figura G-27. Compresibilidad isoentrpica para el sistema binario Etanol (1) n-nonano (2) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K.

G 19 | A. GAYOL

G.

Grficas.

Figura G-28. Desviacin de la compresibilidad isoentrpica el sistema binario Etanol (1) n-nonano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de
Redlich-Kister.

G 20 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.5.

n-hexano n-heptano

Figura G-29. ndice de refraccin para el sistema binario n-hexano (1) n-heptano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-30. Densidad para el sistema binario n-hexano (1) n-heptano (2) a, T=288.15 K; , T = 298.15 K;
, T = 308.15 K; , T = 318.15 K

G 21 | A. GAYOL

G.

Grficas.

Figura G-31. Velocidad del sonido para el sistema binario n-hexano (1) n-heptano (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-32. Desviacin del ndice de refraccin para el sistema binario n-hexano (1) n-heptano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de
Redlich-Kister.

G 22 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-33. Volumen de exceso para el sistema binario n-hexano (1) n-heptano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

Figura G-34. Compresibilidad isoentrpica para el sistema binario n-hexano (1) n-heptano (2) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 23 | A. GAYOL

G.

Grficas.

Figura G-35. Desviacin de la compresibilidad isoentrpica el sistema binario n-hexano (1) n-heptano (2)a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de RedlichKister.

G 24 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.6.

n-hexano n-octano

Figura G-36. ndice de refraccin para el sistema binario n-hexano (1) n-octano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-37. Densidad para el sistema binario n-hexano (1) n-octano (2) a, T=288.15 K; , T = 298.15 K; , T
= 308.15 K; , T = 318.15 K

G 25 | A. GAYOL

G.

Grficas.

Figura G-38. Velocidad del sonido para el sistema binario n-hexano (1) n-octano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-39. Desviacin del ndice de refraccin para el sistema binario n-hexano (1) n-octano (2) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

G 26 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-40. Volumen de exceso para el sistema binario n-hexano (1) n-octano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

Figura G-41. Compresibilidad isoentrpica para el sistema binario n-hexano (1) n-octano (2) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 27 | A. GAYOL

G.

Grficas.

Figura G-42. Desviacin de la compresibilidad isoentrpica el sistema binario n-hexano (1) n-octano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de RedlichKister.

G 28 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.1.7.

n-hexano n-nonano

Figura G-43. ndice de refraccin para el sistema binario n-hexano (1) n-nonano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-44. Densidad para el sistema binario n-hexano (1) n-nonano (2) a, T=288.15 K; , T = 298.15 K; , T
= 308.15 K; , T = 318.15 K

G 29 | A. GAYOL

G.

Grficas.

Figura G-45. Velocidad del sonido para el sistema binario n-hexano (1) n-nonano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-46. Desviacin del ndice de refraccin para el sistema binario n-hexano (1) n-nonano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de RedlichKister.

G 30 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-47. Volumen de exceso para el sistema binario n-hexano (1) n-nonano (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

Figura G-48. Compresibilidad isoentrpica para el sistema binario n-hexano (1) n-nonano (2) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 31 | A. GAYOL

G.

Grficas.

Figura G-49. Desviacin de la compresibilidad isoentrpica el sistema binario n-hexano (1) n-nonano (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de RedlichKister.

G 32 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.2.

Grficas sistemas binarios orgnico acuoso

G.1.2.1.

Etanol agua

Figura G-50. ndice de refraccin para el sistema binario Etanol (1) agua (2) a, T=288.15 K; , T = 298.15 K;
, T = 308.15 K; , T = 318.15 K

Figura G-51. Densidad para el sistema binario Etanol (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 33 | A. GAYOL

G.

Grficas.

Figura G-52. Velocidad del sonido para el sistema binario Etanol (1) agua (2) a, T=288.15 K; , T = 298.15 K;
, T = 308.15 K; , T = 318.15 K

Figura G-53. Desviacin del ndice de refraccin para el sistema binario Etanol (1) agua (2) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

G 34 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-54. Volumen de exceso para el sistema binario Etanol (1) agua (2) a, T=288.15 K; , T = 298.15 K;
, T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de Redlich-Kister.

Figura G-55. Compresibilidad isoentrpica para el sistema binario Etanol (1) agua (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

G 35 | A. GAYOL

G.

Grficas.

Figura G-56. Desviacin de la compresibilidad isoentrpica el sistema binario Etanol (1) agua (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K. La lnea solida corresponde al modelo de
Redlich-Kister.

G 36 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.3.

Grficas sistemas binarios acuoso acuoso

G.1.3.1.

Tween 20 agua

Figura G-57. ndice de refraccin para el sistema binario Tween 20 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-58. Densidad para el sistema binario Tween 20 (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 37 | A. GAYOL

G.

Grficas.

Figura G-59. Velocidad del sonido para el sistema binario Tween 20 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-60. Desviacin del ndice de refraccin para el sistema binario Tween 20 (1) agua (2) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K.

G 38 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-61. Volumen de exceso para el sistema binario Tween 20 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K.

Figura G-62. Compresibilidad isoentrpica para el sistema binario Tween 20 (1) agua (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

G 39 | A. GAYOL

G.

Grficas.

Figura G-63. Desviacin de la compresibilidad isoentrpica el sistema binario Tween 20 (1) agua (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K.

G 40 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.3.2.

Tritn X-102 agua

Figura G-64. ndice de refraccin para el sistema binario Tritn X-102 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-65. Densidad para el sistema binario Tritn X-102 (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 41 | A. GAYOL

G.

Grficas.

Figura G-66. Velocidad del sonido para el sistema binario Tritn X-102 (1) agua (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-67. Desviacin del ndice de refraccin para el sistema binario Tritn X-102 (1) agua (2) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K.

G 42 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-68. Volumen de exceso para el sistema binario Tritn X-102 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K.

Figura G-69. Compresibilidad isoentrpica para el sistema binario Tritn X-102 (1) agua (2) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 43 | A. GAYOL

G.

Grficas.

Figura G-70. Desviacin de la compresibilidad isoentrpica el sistema binario Tritn X-102 (1) agua (2) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K.

G 44 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.3.3.

Na2SO4 agua

Figura G-71. ndice de refraccin para el sistema binario Na2SO4 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-72. Densidad para el sistema binario Na2SO4 (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 45 | A. GAYOL

G.

Grficas.

Figura G-73. Velocidad del sonido para el sistema binario Na2SO4 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-74. Compresibilidad isoentrpica para el sistema binario Na2SO4 (1) agua (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

G 46 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.3.4.

Na2S2O3 agua

Figura G-75. ndice de refraccin para el sistema binario Na2S2O3 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-76. Densidad para el sistema binario Na2S2O3 (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 47 | A. GAYOL

G.

Grficas.

Figura G-77. Velocidad del sonido para el sistema binario Na2S2O3 (1) agua (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

Figura G-78. Compresibilidad isoentrpica para el sistema binario Na2S2O3 (1) agua (2) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K

G 48 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.3.5.

K2HPO4 agua

Figura G-79. ndice de refraccin para el sistema binario K2HPO4 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-80. Densidad para el sistema binario K2HPO4 (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 49 | A. GAYOL

G.

Grficas.

Figura G-81. Velocidad del sonido para el sistema binario K2HPO4 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-82. Compresibilidad isoentrpica para el sistema binario K2HPO4 (1) agua (2) a, T=288.15 K; , T
= 298.15 K; , T = 308.15 K; , T = 318.15 K

G 50 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.3.6.

K3PO4 agua

Figura G-83. ndice de refraccin para el sistema binario K3PO4 (1) agua (2) a, T=288.15 K; , T = 298.15 K;
, T = 308.15 K; , T = 318.15 K

Figura G-84. Densidad para el sistema binario K3PO4 (1) agua (2) a, T=288.15 K; , T = 298.15 K; , T =
308.15 K; , T = 318.15 K

G 51 | A. GAYOL

G.

Grficas.

Figura G-85. Velocidad del sonido para el sistema binario K3PO4 (1) agua (2) a, T=288.15 K; , T = 298.15
K; , T = 308.15 K; , T = 318.15 K

Figura G-86. Compresibilidad isoentrpica para el sistema binario K3PO4 (1) agua (2) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K

G 52 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.4.

Grficas sistemas ternarios orgnico orgnico

G.1.4.1.

Etanol n-hexano n-heptano

Figura G-87. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) nhexano (2) n-heptano (3) a T = 298.15 K.

Figura G-88. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el sistema
ternario Etanol (1) n-hexano (2) n-heptano (3) a T = 298.15 K.

G 53 | A. GAYOL

G.

Grficas.

Figura G-89. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-hexano (2) nheptano (3) a T = 298.15 K

Figura G-90. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario Etanol
(1) n-hexano (2) n-heptano (3) a T = 298.15 K

G 54 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-91. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) n-hexano
(2) n-heptano (3) a T = 298.15 K

Figura G-92. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema

ternario Etanol (1) - n-hexano (2) n-heptano (3) a T = 298.15 K

G 55 | A. GAYOL

G.

Grficas.

G.1.4.2.

Etanol n-hexano n-octano

Figura G-93. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) n-hexano (2)
n-octano (3) a T = 298.15 K.

Figura G-94. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el sistema ternario
Etanol (1) n-hexano (2) n-octano (3) a T = 298.15 K.

G 56 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-95. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-hexano (2) n-octano (3) a T
= 298.15 K

Figura G-96. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario Etanol (1) nhexano (2) n-octano (3) a T = 298.15 K

G 57 | A. GAYOL

G.

Grficas.

Figura G-97. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) n-hexano (2) noctano (3) a T = 298.15 K

Figura G-98. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema ternario
Etanol (1) - n-hexano (2) n-octano (3) a T = 298.15 K

G 58 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.4.3.

Etanol n-hexano n-nonano

Figura G-99. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) nhexano (2) n-nonano (3) a T = 298.15 K.

Figura G-100. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el
sistema ternario Etanol (1) n-hexano (2) n-nonano (3) a T = 298.15 K.

G 59 | A. GAYOL

G.

Grficas.

Figura G-101. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-hexano (2) nnonano (3) a T = 298.15 K

Figura G-102. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario
Etanol (1) n-hexano (2) n-nonano (3) a T = 298.15 K

G 60 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-103. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) nhexano (2) n-nonano (3) a T = 298.15 K

Figura G-104. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema

ternario Etanol (1) - n-hexano (2) n-nonano (3) a T = 298.15 K

G 61 | A. GAYOL

G.

Grficas.

G.1.5.

Grficas sistemas ternarios orgnico acuoso

G.1.5.1.

Etanol n-hexano agua

Figura G-105. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) n-hexano (2)
agua (3) a T = 298.15 K.

Figura G-106. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el sistema
ternario Etanol (1) n-hexano (2) agua (3) a T = 298.15 K.

G 62 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-107. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-hexano (2) agua (3) a T =
298.15 K

Figura G-108. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario Etanol (1) nhexano (2) agua (3) a T = 298.15 K

G 63 | A. GAYOL

G.

Grficas.

Figura G-109. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) n-hexano (2)
agua (3) a T = 298.15 K

Figura G-110. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema ternario
Etanol (1) - n-hexano (2) agua (3) a T = 298.15 K

G 64 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.5.2.

Etanol n-heptano agua

Figura G-111. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) n-heptano (2)
agua (3) a T = 298.15 K.

Figura G-112. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el sistema
ternario Etanol (1) n-heptano (2) agua (3) a T = 298.15 K.

G 65 | A. GAYOL

G.

Grficas.

Figura G-113. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-heptano (2) agua (3) a T =
298.15 K

Figura G-114. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario Etanol (1) nheptano (2) agua (3) a T = 298.15 K

G 66 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-115. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) n-heptano (2)
agua (3) a T = 298.15 K

Figura G-116. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema ternario
Etanol (1) - n-heptano (2) agua (3) a T = 298.15 K

G 67 | A. GAYOL

G.

Grficas.

G.1.5.3.

Etanol n-octano agua

Figura G-117. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) n-octano (2)
agua (3) a T = 298.15 K.

Figura G-118. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el sistema
ternario Etanol (1) n-octano (2) agua (3) a T = 298.15 K.

G 68 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-119. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-heptano (2) agua (3) a T =
298.15 K

Figura G-120. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario Etanol (1) noctano (2) agua (3) a T = 298.15 K

G 69 | A. GAYOL

G.

Grficas.

Figura G-121. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) n-octano (2)
agua (3) a T = 298.15 K

Figura G-122. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema ternario
Etanol (1) - n-octano (2) agua (3) a T = 298.15 K

G 70 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

G.1.5.4.

Etanol n-nonano agua

Figura G-123. Isolneas de la variacin del ndice de refraccin para el sistema ternario Etanol (1) n-nonano (2)
agua (3) a T = 298.15 K.

Figura G-124. Isolneas de la contribucin ternaria de la variacin del ndice de refraccin para el sistema
ternario Etanol (1) n-nonano (2) agua (3) a T = 298.15 K.

G 71 | A. GAYOL

G.

Grficas.

Figura G-125. Isolneas del volumen de exceso para el sistema ternario Etanol (1) n-nonano (2) agua (3) a T =
298.15 K

Figura G-126. Isolneas de la contribucin ternaria del volumen de exceso para el sistema ternario Etanol (1) nnonano (2) agua (3) a T = 298.15 K

G 72 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-127. Isolneas de la compresibilidad isoentrpica para el sistema ternario Etanol (1) n-nonano (2)
agua (3) a T = 298.15 K

Figura G-128. Isolneas de la contribucin ternaria de la compresibilidad isoentrpica para el sistema ternario
Etanol (1) - n-nonano (2) agua (3) a T = 298.15 K

G 73 | A. GAYOL

G.

Grficas.

G.1.6.

Grficas sistemas ternarios acuoso - acuoso

G.1.6.1.

Tween 20 Na2SO4 agua

Figura G-129. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.56% Na2SO4

Figura G-130. Densidad para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K, 1.56% Na2SO4

G 74 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-131. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.56% Na2SO4

Figura G-132. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.56% Na2SO4

G 75 | A. GAYOL

G.

Grficas.

Figura G-133. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.98% Na2SO4

Figura G-134. Densidad para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K, 4.98% Na2SO4

G 76 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-135. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.98% Na2SO4

Figura G-136. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.98% Na2SO4

G 77 | A. GAYOL

G.

Grficas.

Figura G-137. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 6.50% Na2SO4

Figura G-138. Densidad para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K, 6.50% Na2SO4

G 78 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-139. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 6.50% Na2SO4

Figura G-140. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 6.50% Na2SO4

G 79 | A. GAYOL

G.

Grficas.

Figura G-141. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 8.58% Na2SO4

Figura G-142. Densidad para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a, T=288.15 K; , T =
298.15 K; , T = 308.15 K; , T = 318.15 K, 8.58% Na2SO4

G 80 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-143. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 8.58% Na2SO4

Figura G-144. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 8.58% Na2SO4

G 81 | A. GAYOL

G.

Grficas.

G.1.6.2.

Tween 20 Na2S2O3 agua

Figura G-145. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.93% Na2S2O3

Figura G-146. Densidad para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.93% Na2S2O3

G 82 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-147. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.93% Na2S2O3

Figura G-148. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.93% Na2S2O3

G 83 | A. GAYOL

G.

Grficas.

Figura G-149. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.86% Na2S2O3

Figura G-150. Densidad para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.86% Na2S2O3

G 84 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-151. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.86% Na2S2O3

Figura G-152. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.86% Na2S2O3

G 85 | A. GAYOL

G.

Grficas.

Figura G-153. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.00% Na2S2O3

Figura G-154. Densidad para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.00% Na2S2O3

G 86 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-155. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.00% Na2S2O3

Figura G-156. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.00% Na2S2O3

G 87 | A. GAYOL

G.

Grficas.

Figura G-157. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.88% Na2S2O3

Figura G-158. Densidad para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.88% Na2S2O3

G 88 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-159. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.88% Na2S2O3

Figura G-160. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.88% Na2S2O3

G 89 | A. GAYOL

G.

Grficas.

Figura G-161. ndice de refraccin para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.00% Na2S2O3

Figura G-162. Densidad para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.00% Na2S2O3

G 90 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-163. Velocidad del sonido para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.00% Na2S2O3

Figura G-164. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - Na2S2O3 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.00% Na2S2O3

G 91 | A. GAYOL

G.

Grficas.

G.1.6.3.

Tween 20 K2HPO4 agua

Figura G-165. ndice de refraccin para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.57% K2HPO4

Figura G-166. Densidad para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.57% K2HPO4

G 92 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-167. Velocidad del sonido para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.57% K2HPO4

Figura G-168. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 1.57% K2HPO4

G 93 | A. GAYOL

G.

Grficas.

Figura G-169. ndice de refraccin para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 3.20% K2HPO4

Figura G-170. Densidad para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 3.20% K2HPO4

G 94 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-171. Velocidad del sonido para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 3.20% K2HPO4

Figura G-172. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 3.20% K2HPO4

G 95 | A. GAYOL

G.

Grficas.

Figura G-173. ndice de refraccin para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.19% K2HPO4

Figura G-174. Densidad para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.19% K2HPO4

G 96 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-175. Velocidad del sonido para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.19% K2HPO4

Figura G-176. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.19% K2HPO4

G 97 | A. GAYOL

G.

Grficas.

Figura G-177. ndice de refraccin para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.19% K2HPO4

Figura G-178. Densidad para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a, T=288.15 K;
, T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.19% K2HPO4

G 98 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-179. Velocidad del sonido para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.19% K2HPO4

Figura G-180. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K2HPO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.19% K2HPO4

G 99 | A. GAYOL

G.

Grficas.

G.1.6.4.

Tween 20 K3PO4 agua

Figura G-181. ndice de refraccin para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

Figura G-182. Densidad para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

G 100 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-183. Velocidad del sonido para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

Figura G-184. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K3PO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

G 101 | A. GAYOL

G.

Grficas.

Figura G-185. ndice de refraccin para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

Figura G-186. Densidad para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

G 102 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-187. Velocidad del sonido para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

Figura G-188. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K3PO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

G 103 | A. GAYOL

G.

Grficas.

Figura G-189. ndice de refraccin para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

Figura G-190. Densidad para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K2HPO4

G 104 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-191. Velocidad del sonido para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

Figura G-192. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K3PO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

G 105 | A. GAYOL

G.

Grficas.

Figura G-193. ndice de refraccin para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

Figura G-194. Densidad para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a, T=288.15 K; ,
T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K2HPO4

G 106 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-195. Velocidad del sonido para el sistema ternario Tween 20 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

Figura G-196. Compresibilidad isoentrpica para el sistema ternario Tween 20 (1) - K3PO4 (2) agua
(3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

G 107 | A. GAYOL

G.

Grficas.

G.1.6.5.

Triton X-102 Na2SO4 agua

Figura G-197. ndice de refraccin para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.52% Na2SO4

Figura G-198. Densidad para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.52% Na2SO4

G 108 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-199. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.52% Na2SO4

Figura G-200. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2SO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.52% Na2SO4

G 109 | A. GAYOL

G.

Grficas.

Figura G-201. ndice de refraccin para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2SO4

Figura G-202. Densidad para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2SO4

G 110 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-203. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2SO4

Figura G-204. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2SO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2SO4

G 111 | A. GAYOL

G.

Grficas.

Figura G-205. ndice de refraccin para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.12% Na2SO4

Figura G-206. Densidad para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.12% Na2SO4

G 112 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-207. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2SO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.12% Na2SO4

Figura G-208. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2SO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 9.12% Na2SO4

G 113 | A. GAYOL

G.

Grficas.

G.1.6.6.

Triton X-102 Na2S2O3 agua

Figura G-209. ndice de refraccin para el sistema ternario Triton X-102 (1) Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.50% Na2S2O3

Figura G-210. Densidad para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.50% Na2S2O3

G 114 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-211. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.50% Na2S2O3

Figura G-212. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2S2O3 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.50% Na2S2O3

G 115 | A. GAYOL

G.

Grficas.

Figura G-213. ndice de refraccin para el sistema ternario Triton X-102 (1) Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2S2O3

Figura G-214. Densidad para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2S2O3

G 116 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-215. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2S2O3

Figura G-216. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2S2O3 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.00% Na2S2O3

G 117 | A. GAYOL

G.

Grficas.

Figura G-217. ndice de refraccin para el sistema ternario Triton X-102 (1) Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% Na2S2O3

Figura G-218. Densidad para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% Na2S2O3

G 118 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-219. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% Na2S2O3

Figura G-220. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2S2O3 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% Na2S2O3

G 119 | A. GAYOL

G.

Grficas.

Figura G-221. ndice de refraccin para el sistema ternario Triton X-102 (1) Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% Na2S2O3

Figura G-222. Densidad para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% Na2S2O3

G 120 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-223. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% Na2S2O3

Figura G-224. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2S2O3 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% Na2S2O3

G 121 | A. GAYOL

G.

Grficas.

Figura G-225. ndice de refraccin para el sistema ternario Triton X-102 (1) Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% Na2S2O3

Figura G-226. Densidad para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% Na2S2O3

G 122 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-227. Velocidad del sonido para el sistema ternario Triton X-102 (1) - Na2S2O3 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% Na2S2O3

Figura G-228. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - Na2S2O3 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% Na2S2O3

G 123 | A. GAYOL

G.

Grficas.

G.1.6.7.

Triton X-102 K2HPO4 agua

Figura G-229. ndice de refraccin para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.54% K2HPO4

Figura G-230. Densidad para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.54% K2HPO4

G 124 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-231. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.54% K2HPO4

Figura G-232. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K2HPO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.54% K2HPO4

G 125 | A. GAYOL

G.

Grficas.

Figura G-233. ndice de refraccin para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.08% K2HPO4

Figura G-234. Densidad para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.08% K2HPO4

G 126 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-235. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.08% K2HPO4

Figura G-236. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K2HPO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 5.08% K2HPO4

G 127 | A. GAYOL

G.

Grficas.

Figura G-237. ndice de refraccin para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% K2HPO4

Figura G-238. Densidad para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% K2HPO4

G 128 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-239. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% K2HPO4

Figura G-240. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K2HPO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.48% K2HPO4

G 129 | A. GAYOL

G.

Grficas.

Figura G-241. ndice de refraccin para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% K2HPO4

Figura G-242. Densidad para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% K2HPO4

G 130 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-243. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% K2HPO4

Figura G-244. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K2HPO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.03% K2HPO4

G 131 | A. GAYOL

G.

Grficas.

Figura G-245. ndice de refraccin para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% K2HPO4

Figura G-246. Densidad para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% K2HPO4

G 132 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-247. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K2HPO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% K2HPO4

Figura G-248. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K2HPO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 12.55% K2HPO4

G 133 | A. GAYOL

G.

Grficas.

G.1.6.8.

Triton X-102 K3PO4 agua

Figura G-249. ndice de refraccin para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

Figura G-250. Densidad para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

G 134 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-251. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

Figura G-252. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K3PO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 2.00% K3PO4

G 135 | A. GAYOL

G.

Grficas.

Figura G-253. ndice de refraccin para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

Figura G-254. Densidad para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

G 136 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-255. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

Figura G-256. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K3PO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 4.43% K3PO4

G 137 | A. GAYOL

G.

Grficas.

Figura G-257. ndice de refraccin para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

Figura G-258. Densidad para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

G 138 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-259. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

Figura G-260. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K3PO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 7.41% K3PO4

G 139 | A. GAYOL

G.

Grficas.

Figura G-261. ndice de refraccin para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

Figura G-262. Densidad para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a, T=288.15
K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

G 140 | A. GAYOL

CARACTERIZACIN FSICO QUMICA DE SISTEMAS ORGNICO-ACUOSO Y ACUOSO-ACUOSO.

Figura G-263. Velocidad del sonido para el sistema ternario Triton X-102 (1) - K3PO4 (2) agua (3) a,
T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

Figura G-264. Compresibilidad isoentrpica para el sistema ternario Triton X-102 (1) - K3PO4 (2)
agua (3) a, T=288.15 K; , T = 298.15 K; , T = 308.15 K; , T = 318.15 K, 10.26% K3PO4

G 141 | A. GAYOL