Final JEE Mains/JEE-2014: Read The Following Instructions Very Carefully Before You Proceed

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VMC/JEE-2014 1 Final JEE Mains/ACEG

Aggarwal Corporate Heights, 3rd Floor, Plot No. A - 7, Netaji Subhash Place,
Pitampura, Delhi - 110034 Phone: 011-45221191-93
Final JEE Mains/JEE-2014
29/03/2014 M.M. : 360
03:00 PM- 06:00 PM
TEST CODE : ACEG
TIME : 3.00 Hrs
Read the following Instructions very carefully before you proceed.
1. The question paper consists of 3 parts (Part I : Chemistry, Part II : Physics, Part III : Mathematics).
Each Part contains 30 Straight Objective Questions.
2. For each question you will be given 4 Marks if you have darkened only the bubble corresponding to the
correct answer. 1 Mark will be deducted for indicating incorrect response for any question.
No deduction from the total score will be made if no response is indicated.
3. There is only One Correct Response for each question. Filling up More than One response in each
question will be treated as Wrong Response and marks for Wrong response will be deducted.
4. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on the Answer Sheet. Use of
pencil is strictly prohibited. However for rough work, use pencil on question paper itself.
5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager,
mobile phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
6. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
7. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group properly in the space given in the ANSWER SHEET.
8. Do not fold or make any stray marks on the Answer Sheet.
9. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in
the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
10. No one will be permitted to leave the test room before the end of the test, i.e. 06.00 PM
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PART - I (CHEMISTRY) 120 MARKS
STRAIGHT OBJECTIVE TYPE
This Part contains 30 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
1. One liter of gas A at two atmospheric pressure and two liters of gas B at three atmospheric pressure are
mixed in a four liter flask to form an ideal gas mixture. What will be the final pressure of the gaseous
mixture if the gases initially and finally were at the same temperature?
(A) 1.0 atm (B) 1.5 atm (C) 2.0 atm (D) 2.5 atm
2. 3 mol of a mixture of FeSO
4
and Fe
2
(SO
4
)
3
required 100 mL of 2 M KMnO
4
solution in acidic medium.
Hence, mole fraction of FeSO
4
in the mixture is:
(A)
1
3
(B)
2
3
(C)
2
5
(D)
3
5
3. Which of the following are not correct statements?
I. Carbohydrates are the polyhydroxy alcohols and phenols
II. All amino acids have different isoelectric point
III. Sucrose reduces Tollens reagent
IV. Starch is known as invert sugar also
(A) II only (B) I and III (C) III and IV (D) I, III and IV
SPACE FOR ROUGH WORK
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4. A mixture of nitrogen and hydrogen in the ratio of 1 : 3 reach equilibrium with ammonia when 50% of the
mixture has reacted. If the total pressure is p, the partial pressure of ammonia in the equilibrium mixture
was.
(A)
p
2
(B)
p
3
(C)
p
4
(D)
p
6
5. Which of the following compounds reacts most rapidly with the cold AgNO
3
solution?
(A) CH
3
CH = CHCl (B) CH
3
CH
2
CH
2
Cl
(C) CH
2
= CHCH
2
Cl (D) CH
3
CH
2
CH(Cl)
2
6. In Cannizzaro reaction given below :
OH
2 2
2PhCHO PhCH OH PhCO
+
the slowest step is :
(A) The abstraction of proton from the carboxylic group
(B) The deprotonation of PhCH
2
OH
(C) The attack of OH
at the carbonyl group

(D) The transfer of hydride to the carbonyl group
7. Acetone (CH
3
COCH
3
) is the major product in:
I.
H O
3
2 2
CH C CH
O
= = II.
H SO / HgSO / H O
2 4 4 2
3
CH C CH
III.
3
BH THF
.
3
H O / OH
2 2
CH C CH
(A) I (B) II (C) III (D) None of these

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8. How much amount of CaCl
2
(i = 2.47) is dissolved in 2.5L of water so that its osmotic pressure become
0.75 atm at 27 C ?
(A) 0.3 mol (B) 0.03 mol (C) 3 mol (D) 0.003 mol
9. The term anomers of glucose refers to :
(A) isomers of glucose that differ in configuration at carbon one (C 1)
(B) isomers of glucose that differ in configuration at carbons one and four (C 1 and C 4)
(C) a mixture of (D)-glucose and (L)-glucose
(D) enantiomers of glucose
10. Which of the following is incorrect statement?
(A) Principal quantum number can not be negative
(B) Azimuthal quantum number can not be negative
(C) Magnetic quantum number can not be negative
(D) Spin quantum number can be negative
11. The product P in the reaction:
(A) (B) (C) (D)
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12. The transition metals exhibit higher enthalpies of atomization due to :
(A) tendency of exhibiting variable oxidation states
(B) the presence of incompletely filled d-subshell
(C) their atoms existing in the solid state with unpaired electrons
(D) strong interatomic interaction arising because of having large number of impaired electrons in their
atoms
13. Which of the following ionic substances is most effective in coagulating aluminium hydroxide sol?
(A) Soldium chloride (B) Calcium chloride
(C) Ferric sulphate (D) Potassium phosphate
14. The boiling points of F
2
, Cl
2
, Br
2
and I
2
increase as we go down the group. This is best attributed to
difference in :
(A) Covalent bond strengths (B) dipole forces
(C) London dispersion forces (D) colligative forces
15. A gas is heated in such a way so that its pressure and volume both becomes double. Again by lowering
temperature, one fourth of initial number of moles of air has been taken in, to maintain the double volume
and pressure. By what fraction, the temperature must have been raised finally ?
(A)
1
5
times (B)
4
5
times (C)
16
5
times (D)
8
5
times
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16. In a cube structure of diamond which is made from X and Y, where X atoms are at the corners of the cube
and Y at the face centres of the cube. The molecular formula of the compound is :
(A) X
2
Y (B) X
3
Y (C) XY
2
(D) XY
3
17. The standard oxidation potentials of Zn, Cu, Ag and Ni electrodes are +0.76, 0.34, 0.80 and +0.25 V
respectively. Which of the following reactions will provide maximum voltage ?
(A)
2
Cu 2Ag (aq) Cu (aq) 2Ag
+ +
+ +
(B)
2
Zn 2Ag (aq) Zn (aq) 2Ag
+ +
+ +
(C)
2 2
Zn Cu (aq) Zn (aq) Cu
+ +
+ +
(D)
2
2
Zn 2H (aq) Zn (aq) H
+ +
+ +
18. Molecules of a gas have Z degree of freedom, where degree of freedom represents the number of
independent methods to express the energy of molecules. Determine the value of .
(A)
Z
1
2
= + (B)
2
1
Z
= + (C)
n
2
1
Z
| |
= +
|
\
(D)
2
1
Z
| |
=
|
\
19. What will be the value of A for a 0.001 Maq. solution of
3
NH ?
Given
5
b
K 1.6 10
= ,
1 2 1
238ohm cm mol .

A =
(A)
1 2 1
31.58ohm cm mol

(B)
1 2 1
42.78ohm cm mol

(C)
1 2 1
29.99ohm cm mol

(D)
1 2 1
18.47ohm cm mol

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20. The isotherm obtained for CO is as follows :
The compressibility factor for the gas at point A will be :
(A)
b
1
V
(B)
b
1
V
+ (C)
b
1
RT
+ (D)
a
1
RTV
+
21. Ionisation energy of He
+
is
18 1
19.6 10 J atom

. The energy of the stationary state, ) n 1 = of
2
Li
+
is :
(A)
15 1
2.2 10 J atom

(B)
17 1
8.82 10 J atom

(C)
16 1
4.41 10 J atom

(D)
17 1
4.41 10 J atom

22. If a reaction is non-spontaneous at its freezing point and becomes feasible at its boiling point, then :
(A) H A is ve , S A is +ve (B) H A and S A both are +ve
(C) H A and S A both are ve (D) H A is +ve, S A is ve
23. A substance undergoes first order decomposition. The decomposition follows two parallel first order
reactions as
The percentage distribution of B and Care :
(A) 50% B and 50 % C (B) 76.83%B and 23.17%C
(C) 90%B and 10%C (D) 60%B and 40%C
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24. Which of the following statements is/are not correct?
(A) La(OH)
3
is less basic than Lu(OH)
3
(B) In lanthanide series, ionic radius decrease from La
3+
ion
(C) La is actually an element of transition series rather than lanthanides
(D) Atomic radius of Zr and Hf are sane because of lanthanide contraction
25. The ONO angle is maximum in :
(A)
3
NO
(B)
2
NO
(C)
2
NO (D)
2
NO
+
26. Name the type of structure of silicate in which one oxygen atom is shared between two j
4
4
SiO

units.
(A) Linear chain silicate (B) Pyrosilicate
(C) Sheet silicate (D) Three-dimensional
27. Al and Ga have nearly the same covalent radii because of :
(A) Greatest shielding effect of s-electrons of Ga atoms
(B) Poor shielding effect of s-electrons of Ga atoms
(C) Poor shielding effect of d-electrons of Ga atoms
(D) Greatest shielding effect of d-electrons of Ga atoms
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28. The IUPAC name of the compound,
2
2
CH CH COOH is :
| |
OH NH

(A) 2-Amino-3-hydroxypropanoic acid (B) 1-Hydroxy-2-aminopropan-3-ioc acid
(C) 1-Amino-2-hydroxypropanoic acid (D) 3-Hydroxy-2-aminopropanoic acid.
29. Aqueous solution of borax acts as a buffer because :
(A) It contains weak acid and its salt, with strong base
(B) It contains tribasic acid and strong base
(C) It contains number of natural water molecules
(D) None of these
30. In which reaction does the oxidation state of the group 14 element change?
(A) j j
4
4 2
Si 4 OH SiO 2H

+ + (B) j j j
4 4 4 6
2
GeCl 2 Et N Cl Et N GeCl +
(C) , )
4 3 2
4
SiCl 4NH Si NH 4HCl + + (D)
4 2 2 2
SiH O SiO 2H O + +
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PART - II (PHYSICS) 120 MARKS
31. In the figure the springs S
1
S
2
S
3
and have spring constants
K
1
= 50 N/m, K
2
= 30 N/m, K
3
= 30 N/m and K
4
= 60 N/m
respectively. The mass of the block is 10 gm.
Find the period of small oscillations of the block.
(A)
20
sec
(B)
30
sec
(C)
40
sec
(D)
50
sec
32. For an EM wave traveling along positive x-axis, the electric field vector at a point is 720
j . Then magnetic
field vector at the same point is :
(A)
6
2 4 10

. k (B)
6
2 4 10

. k (C)
5
2 16 10

. k (D)
5
2 16 10

. k
33. In a region, steady and uniform electric and magnetic fields are present. These two fields are parallel to
each other. A charged particle is released from rest in this region. The path of the particle will be :
(A) helix (B) straight line (C) ellipse (D) circle
34. A string is stretched between fixed points separated by 75.0 cm. It is observed to have resonant frequencies
of 420 Hz and 315 Hz. There are no other resonant frequencies between these two. Then, the lowest
resonant frequency for this string is :
(A) 105 Hz (B) 1.05 Hz (C) 1050 Hz (D) 10.5 Hz
m
S
1
S
2
S
3
S
4
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35. The circuit has two oppositely connected ideal diodes in
parallel. What is the current flow in the circuit?
(A) 1.71 A (B) 2.00 A
(C) 2.31 A (D) 1.33 A
36. If the binding energy per nucleon in
7 4
3 2
and Li He nuclei are 5.60 MeV and 7.06 Mev respectively, then in
the reaction
7 4
3 2
2 + p Li He energy of proton must be.
(A) 28.24 MeV (B) 17.28 MeV (C) 1.46 MeV (D) 39.2 MeV
37. The diagram shows the energy levels for an electron in a certain
atom. Which transition shown represents the emission of a photon
with the most energy?
(A) I (B) II
(C) III (D) IV
38. Suppose the gravitational force varies inversely as the nth power of distance. Then the time period of a
planet in circular orbit of radius R around the sun will be proportional to :
(A)
1
2
n
R
+ | |
|
\
(B)
1
2
n
R
| |
|
\
(C) R
n
(D)
2
2
n
R
| |
|
\
12V
4
3
2
D
2
D
1
n = 4
n = 3
n = 2
n = 1
I II III IV
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39. A radiation of energy E falls normally on a perfectly reflecting surface. The momentum transferred to the
surface is :
(A) E/c (B) 2E/c (C) Ec (D) E/c
2
40. The total current supplied to the circuit by the battery is :
(A) 1 A (B) 2 A
(C) 4 A (D) 6 A
41. The length of a magnet is large compared to its width and breadth. The time period of its oscillation in a
vibration magnetometer is 2 s. The magnet is cut along its length into three equal parts and three parts are
then placed on each other with their like poles together. The time period of this combination will be :
(A) 2 s (B) 2/3 s (C) 2 3 s (D) 2 3 / s
42. In an LCR series a.c. circuit, the voltage across each of the components, L, C and R is 50 V. the voltage
across the LC combination will be :
(A) 50 V (B) 50 2 V (C) 100 V (D) 0 V (zero)
43. A coil having n turns and resistance R is connected with a galvanometer of resistance 4 R .
This combination is moved in time t seconds from a magnetic flux W
1
Weber to W
2
Weber. The induced
current in the circuit is :
(A)
2 1
5
W W
Rnt
(B)
, )
2 1
5
n W W
Rt
(C)
, )
2 1
W W
Rnt
(D)
, )
2 1
n W W
Rt
2
6V
6
3
1 5 .
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44. A block of mass 15 kg is resting on a rough inclined lane as shown in the figure. The minimum horizontal
force F of 50N is required to prevent down word slipping the coefficient of friction between the surfaces of
contact is.
(A) 1/2
(B) 2/3
(C) 3/4
(D) 1/4
45. A particle is projected form the ground with an initial speed of V at an angle with horizontal.
The average velocity of the particle between its point of projection and the highest point of trajectory is:
(A)
2
1 2
2
+
V
cos (B)
2
1 2
2

V
cos
(C)
2
1 3
2
+
V
cos (D) v cos
46. The number of images formed by the lens as
shown in the figure is :
(A) 1 (B) 2
(C) 3 (D) 4
47. If the ratio of change in current in emitter and corresponding change in collector current is 1.013, then the
value of is :
(A) 0.987 (B) 75.92 (C) 1.006 (D) 79.68
M
45
F
1
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48. The 3 physical quantities are related as
3 2
=
a b
x
c
, if the age error in a, b, and c are 2 1 and 4 %, % %,
respectively, then age error in x is :
(A) 8 % (B) 12 % (C) 14 % (D) 10 %
49. Two identical long, solid cylinders are used to conduct heat from temperature T
1
to temperature T
2
.
Originally the cylinders are connected in series and the rate of heat transfer is H. If the cylinders are
connected in parallel, then the rate of heat transfer would be :
(A) H/4 (B) 2H (C) 4H (D) 8H
50. A disc of mass M and radius R is performing pure rolling motion in the
x-y plane as shown in the figure. The magnitude of angular momentum
of the disc about O is :
(A)
2
2
MR
(B)
2
MR
(C)
2
3
2
MR (D)
2
2MR
51. 743 J of heat energy is added to raise the temperature of 5 mol of an ideal gas by 2k at constant pressure.
How much heat energy is required to raise the temperature of the same mass of the gas by 2 K at constant
volume?
(A) 826 J (B) 743 J (C) 660 J (D) 620 J
52. Three capacitors connected in series have an effective resistance of 2 F . If one of the capacitors is
removed, the equivalent capacitance becomes 3 F . The capacitance of the capacitor that is removed is:
(A) 6 F (B) 1 F (C) 3 2 / F (D) 2 3 / F
O
R
R
e
x
y
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53. The angle of declination at any point on the surface of the earth
(A) is equal to 11 5 . and same everywhere on the earth
(B) is equal to 8 and same everywhere on the earth
(C) has different values at different points on the surface of the earth
(D) is the angle between the axis of the magnetic dipole of the earth and the axis of rotation of the
earth
54. A shell at rest at the origin explodes into three fragments of mass 1 kg, 2 kg and m kilograms. The 1 kg and
2 kg pieces fly off with speeds of 12 m/s along the x-axis and 8m/s along the y-axis, respectively. If the
m kilogram piece files off with a speed of 40 m/s, the total mass of the shell would be :
(A) 0.5 kg (B) 5 kg (C) 3.5 kg (D) 4.5 kg
55. A point charge q is placed at the centre of one of the face of cuboid as
shown in figure. Find the electric flux crossing through the upper surface.
(A)
0
6
q
(B)
0
24
q
(C)
0
12
q
(D) Zero
56. If length of a potentiometer wire is 300 cm and in its primary circuit a standard cell of emf 2 V and a
rheostat having resistance setting at 4 is connected, the resistance per unit length of potentiometer wire
is 2/ . m If a battery of emf 1V and internal resistance 0 5 . is connected in secondary, then null point will
be obtained at:
(A) 250 cm (B) 200 cm (C) 150 cm (D) 100 cm
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57. A block of mass m is gently placed over a massive plank moving horizontally over a smooth surface with
velocity 6 m/s. The coefficient of friction between the block and plank is 0.2. The distance travelled by the
block till it slides on the plank is (take g = 10 m/s
2
)
(A) 4 m (B) 6 m (C) 9 m (D) 12 m
58. The refractive index of a 60 prism is , ) 7 3 / . The minimum angle of incidence of a ray of light that can
be transmitted through the prism is:
(A) 30 (B) 40 (C) 50 (D) 60
59. A current I flows through a thin wire shaped as regular polygon of n sides which can be inscribed in a
circle of radius R. The magnetic field induction at the centre of polygon due to one side of the polygon is:
(A)
0
| |
|
\
I
tan
R n

(B)
0
4
I
tan
R n

(C)
0
2
| |
|
\
I
tan
R n

(D)
0
2
| |
|
\
I
cos
R n

60. With reference to the following figure, which of

the following is possible?
(A) A = 0, B = 0, X = 1
(B) A = 0, B = 1, X = 0
(C) A = 1, B = 0, X = 0
(D) A = 1, B = 1, X = 0
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PART - III (MATHEMATICS) 120 MARKS
61. The sum of the series
2 3 4 5 6 7
2 1 2 1 2 1 2
1
3
3 3 3 3 3 3
............. + + + + + + + + upto infinite terms is equal to :
(A)
15
8
(B)
8
15
(C)
27
8
(D)
21
8
62. If f is a positive function such , ) , ) f x T f x + = where 0 T x R > , e then :
, ) , ) , )
, ) , )
, )
2 2
2 2
4 4
n
f x T f x T .............. nf x nT
lim n
f x T f x T .......... n f x n T
| |
+ + + + + +
|
|
| + + + + + +
\
is :
(A) 2 (B)
2
3
(C)
3
2
(D) None of these
63. The arithmetic mean of a set of observations is X . If each observation is divided by o and then is
increased by 10, then the mean of the new series is :
(A)
X
(B)
10 X
+
(C)
10 X
+
(D) 10 X +
64. Let f and g be twice differentiable function on R and , ) , ) 5 8 5 2 f " , g" = = ,
then
, ) , ) , ) , )
, ) , ) , ) , )
5
5 5 5
5 5 5 x
f x f x f '
im
g x g x g'
| |
|
|

\
is equal to :
(A) 0 (B) 1 (C) 2 (D) 4
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65. If 2sin x . cos y = 1, then
2
2
at
4 4
d y
dx
| |
,
|
\
is :
(A) 4 (B) 2 (C) 6 (D) 0
66. If x
1
and x
2
are roots of the quadratic equation
2
2 3 4 0 x x + = , then the quadratic equation whose roots
are, )
2
1
2 3 x

+ and , )
2
2
2 3 x

+ , is equal to :
(A)
2
64 25 1 0 x x + + = (B)
2
64 25 1 0 x x + =
(C)
2
64 25 1 0 x x + = (D)
2
64 25 1 0 x x =
67. In parallelogram PQRS (taken in order), P is , ) 1 1 , , Q is (8, 0) and R is (7, 5). Then point S has
co-ordinates :
(A) , ) 1, 4 (B) , ) 2 2 , (C)
7
2
2
| |
,
|
\
(D) , ) 2 4 ,
68. Consider the function , )
{ ;
{ ;
1 0 1
2 1 2
x x x
f x
x x
+ ; s <

=
`
; s s

)
where {.} denotes the fractional part function. Which
of the following statement is Incorrect ?
(A) , )
1 x
lim f x
exists
(B) , ) , ) 0 2 f f =
(C) , ) f x is continuous in [0, 2]
(D) , ) f x takes all intermediate values between , ) , ) 0 to 2 f f
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69. If
1
3 3 4
2 3 4 then
0 1 1
A A
(
(
= ;
(
(

is equal to :
(A) A (B) A
2
(C) A
3
(D) A
4
70. If
2 1
2
x
atan
a
x a
a
lim
x e
| |
|
\
| |
=
|
\
, then a is equal to :
(A) (B) (C)
2
(D)
2
71. The roots of the equation

2
6 2 x x x = + | | are given by :
(A) 2 2 4 , , (B) 0, 1, 4 (C) 2 1 4 , , (D) 0, 2, 4
72. Number of 7 digit telephone numbers that can be created if the first three digits must be 426,427or 428 and
right most digit is divisible by 3, is k thousand then k is equal to :
(A) 12 (B) 9 (C) 6 (D) 3
73. Let

, )
3 2 4 2 = + + ; = +

a i j k b i k and

4 2 3 c i j k = + +
. Sum of distinct values of for which the

equation

, )
xa yb zc xi y j zk + + = + +
has non trivial solution is :

(A) 1 (B) 4 (C) 7 (D) 8
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74. If the maximum number of distinct elements in a symmetric matrix of order n is 45, then the value of n is :
(A) 9 (B) 10 (C) 15 (D) None of these
75. A line passes through origin and is perpendicular to two parallel lines 2 6 0 x y + + = and 4 2 9 0 x y + = ,
then the ratio in which the origin divides this line segment is :
(A) 1 : 2 (B) 1 : 1 (C) 5 : 4 (D) 3 : 4
76. Let R be the set of real numbers. Consider the following subsets of R R.
, ) { ; , ) { ;
1 and 0 2 is an integer S x y y x x T x y x y = , : = + < < , = , : .
Which one of the following is true?
(A) Neither S nor T is an equivalence relation on R
(B) Both S and T are equivalence relations on R
(C) S is an equivalence relation on R but T is not
(D) T is an equivalence relation on R but S is not
77. Let , )
1
1
0
1 0
tan x
f x x
x

; =

=
`

; =
)
Then which of the following statement is Correct ?
(A) f has a non removable discontinuity of finite type at x = 0
(B) f has a non-removable discontinuity of oscillatory type at x = 0
(C) f has a non-removable discontinuity of infinite type at x = 0
(D) f is continuous on, ) , ) 0 0 , ,
Vidyamandir Classes
78. If point A lies on line
1 2 3
2 3 4
x y z
= = and point B lies on line
2 4 6
3 7 6
x y z
= = then AB can
be parallel to :
(A)

2 i j k + +
(B)

i j k + +
(C)

3 i j k + +
(D)

4 i j k + +
79. The range of the function , )

1 1
f x cos x tan x

= + is :
(A)
3
4 4
(
,
(

(B)
3
2 2
(
,
(

(C)
5
3 4
(
,
(

(D)
5
4 4
(
,
(

80. The integral
, )
2
1
ln x
dx
ln x +
}
is equal to :
(A)
, )
3
1
1
c
ln x
+
+
(B)
, )
2
1
1
c
ln x
+
+
(C)
, )
2
1
x
c
ln x
+
+
(D)
, ) 1
x
c
ln x
+
+
81. If and a b c , are vectors such that and b c are perpendicular, but and a b are not. Let m be a real
number. If x . a m x b c = , = then :
(A)
, )
, )
mb a c
x
c . b
+
= (B)
, )
, )
mb a c
x
a . b

=
(C)
, )
, )
mb a . c
x
a . b
+
= (D)
, )
, )
mb a c
x
a . b
+
=
Vidyamandir Classes
82. The shelf life, in days for bottles of a certain prescribed medicine is a random variable having the density
function , ) , )
3
20 000
0
100
0 elsewhere
x
f x x
,
; >

= +
`

;
)
, the probability that a bottle of this medicine will have a shelf
life of at least 10 days is :
(A)
1
121
(B)
21
121
(C)
1
11
(D)
100
121
83. If A is a skew-symmetric matrix and n is odd positive integer, then A
n
is :
(A) A symmetric matrix (B) A skew-symmetric matrix
(C) A diagonal matrix (D) None of these
84. The smallest natural number c for which the equation e
x
= cx
2
has exactly three distinct solutions, is :
(A) 1 (B) 2 (C) 3 (D) 4
85. The approximate percentage of the interval j 5 15 , for which the inequality
7
4
4
x
x
>
+
is satisfied, is :
(A) 55% (B) 65% (C) 60% (D) 45%
86. If x
1
, x
2
,.., x
18
are observations such that
, )
18
1
8 9
j
j
x
=
=
and
, )
18
2
1
8 45
j
j
x
=
=
, then the standard

deviation of these observations is :
(A)
18
34
(B) 5 (C) 5 (D)
3
2
Vidyamandir Classes
87. The value of , )
2
0
1
1
x
x
x
lim ln t dt
x
+
}
is equal to :
(A) 0 (B) 1 (C) 1 (D) 2
For Questions 88 - 89
Consider the function , )
1
2
2
1
x
f x sin x R
x
| |
= e
|
|
+
\
.
88. Number of points where , ) f x is not differentiable, is :
(A) 0 (B) 1 (C) 2 (D) 3
89. The value of , ) 0 f ' is :
(A) 2 (B) 2 (C) 1 (D) Non existent
90. The integral , )
1
0
f x dx
}
is equal to :
(A)
1
2
2 2
ln
(B) 2
2
ln
(C)
1
2
4 2
ln
(D) None of these

s
Vidyamandir Classes
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Vidyamandir Classes

VMC/JEE-2014 1 Final JEE Mains/ACEG

at the carbonyl group

(A) I (B) II (C) III (D) None of these

60. With reference to the following figure, which of

71. The roots of the equation

. Sum of distinct values of for which the

has non trivial solution is :

79. The range of the function , )

, then the standard

(D) None of these

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