John Howland Architect Chemical Hazards at Ratna Ling

April 4, 2014
Board of Supervisors
Efren Carrillo, 5
th
District Supervisor
575 Administration Dr., Rm. 100A
Santa Rosa, CA 95403

Subject: File No. PLP08-0021, Ratna Ling Retreat Center
35755 Hauser Road, Cazadero Road
APN: 109-230-024 and -018

I would like to address the issue of Hazardous Materials at Ratna Ling Retreat. This is both a
public health and safety and environmental issue.

Ratna Lings Master Use Permit Application (3/26/13) trivializes the hazardous substances and
materials in the printing operation by stating that the printing and manufacturing process only use
non-toxic ink. (Exhibit A). The Subsequent Mitigated Negative Declaration states that the only
hazardous waste are rags used in the clean-up of the presses and small amounts of waste water,
and therefore hazards are not significant. (Section 8.a., pg. 24 SMND 2/28/14)

The SMND that you will be voting on Tuesday April 8, 2014 uses these assertions to conclude
that this project will not have a significant impact to health, safety, and the environment.

In reality Dharma Press at Ratna Ling Retreat uses highly toxic and highly flammable chemicals
in large quantities, and if their proposal for expansion and unlimited book production is approved,
even larger quantities of hazardous materials will be brought to our community with little or no
oversight. (Exhibit B) By not disclosing this information in their Master Use Permit Application,
the operators of Ratna Ling and Dharma Press put not only the environment at risk, but also their
volunteer workers, our own volunteer Fire Department, and our Emergency Medical Services
personnel.

I have attached to this letter:
1. the list of chemicals that was provided in the 2004 MND when Dharma Press agreed to
print only 100,000 books per year at Ratna Ling (Exhibit B)

2. the chemicals reported to Emergency Services in 2009 when Dharma Press claimed on
its website to be publishing 400,000 books at Ratna Ling. (Exhibit C)

3. The Material Safety Data Sheets (MSDS) which the operators of Dharma Press did not
attach to either of the Mitigated Negative Declarations, nor to the Hazardous Materials
Inventory Statement they filed at county Emergency Services. Most fire departments
require the MSDS to be filed along with the quantities of substances used. (Exhibit D)

The owners of Ratna Ling failed to report the complete list of hazardous chemicals they utilized
in both of their Mitigated Negative Declarations for Ratna Ling Retreat (2004 and 2014), which
negates the following sections of their Subsequent Mitigated Negative Declaration (2014) and
clearly alters that designation from not significant to significant:
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John John John John Howland Howland Howland Howland
Architect Architect Architect Architect

Architecture Architecture Architecture Architecture
Interiors Interiors Interiors Interiors
Planning Planning Planning Planning

i) 7.a. Green House Gas Emissions
ii) 8 Hazard and Hazardous Material
(1) 8.a-Create a Significant Hazard to the Public, Transport, or Disposal
(2) 8.b-Create a Significant Hazard to the Public
(3) 8.g- Impair Implementation of an Emergency Response Evacuation Plan
(4) 8.h-Expose People or Structures to a Significant Risk of Loss, Injury, or Death
Involving Wildfires

List of Hazardous Material in the
Mitigated Negative Declaration issued
in 2004
Total annual usage

Common Name Quantity unit Chemical
V120 120 gal
Ecolowash 5 gal
HD1 25 gal
HD2 25 gal
Type Wash 5 gal
SF Soy base Ink 4000 lbs.
Isopropyl alcohol 5 gal

List of Hazardous Materials Reported to Emergency Services, 2009
Stored on site

Common Name Quantity unit Chemical
annual
waste
Unleaded Gas 350 gal 1

Diesel Fuel 2400 gal 1
Chlorine 12 gal sodium hypochloric
Polymer 12 gal aluminum phosphate
Propane 20,000 gal LP
Battery Acid Sulfuric Acid/
Briol, Wash 140 gal Acetic Acid
Diamond Etch 25 gal
Butyl Oxitol
Diethlyne Glycol
Diamond sub 20 gal Glycol EtherPB
Pressroom chemicals 50 gal ???
Cool Band 5000 lb Paraffin
Uni-flex 40 gal
petroleum, hydrated
naphthenic
Purmelt 170 gal Polyurethane
Blanket wash 165 gal Acetic Acid 990 gal
Fountain solution 220 gal
Butyl Oxitol
550 gal

Diethlyne Glycol

The following issues related to public health and safety are not addressed in the Subsequent
Mitigated Negative Declaration (2014) filed by the operators of Ratna Ling and Dharma Press:
1. Who is going to monitor and verify that this printing operation is maintaining
the proper work place health and safety training and apparatus (i.e. wash
stations, ventilators)? Certainly not Cal OSHA, or the unions. This is a
volunteer operation. OSHA does not regulate volunteers.
2. Who is checking with the local fire department to ensure that they have the
proper training, equipment, and knowledge to handle a fire involving the
chemicals listed, some of which cannot be doused with water?
3. What procedure is in place in case of a toxic spill? Who will report it, respond
to it, and how long will that cleanup take?
4. If a toxic spill occurs, it could penetrate the aquifer.
5. Many of these chemicals require special handling by users and transporters
(workers, drivers, etc.). These also should be listed in the traffic study.

6. If Dharma Press had a disaster (i.e. chemical explosion) how would the
volunteers get medical help? How long would it take? What is the mortality
rate for victims that are one hour away from a full hospital? How long would
it take to evacuate 1 or 10 or 90 people?

Without having this 2014 Subsequent Mitigated Negative Declaration peer reviewed, how can
anyone be sure that any of the information it contains is accurate? We now know that the
hazardous materials report it contains is certainly inaccurate. How can PRMD monitor Ratna
Ling to insure the publics safety?
We now also know that the 2004 Mitigated Negative Declaration was grossly inaccurate and that
PRMD failed to monitor its repeated and constant violation by the owners of Ratna Ling and
Dharma Press.

Yours truly,

John Howland
Architect
22050 Timber Cove Rd.
Jenner, CA 95450

Attachments:
Exhibit A, Ratna Ling Updated Master Use Permit Application, page 3
Exhibit B, 2004 MND Total Raw Material Usage
Exhibit C, 2009 Emergency Service Hazardous Material Inventory Statement
Exhibit D, Material Safety Data Sheets

Copy;
Tennis Wick, Sonoma County Planning Director

, r
,,
----- ---- ----
Resort use permit issued in 2000, and simply modify existing uses that the County has
already deemed to be salutary and appropriate.
Ratna Ling is aBuddhist retreat center and all retreats that are authorized by the
Master Use Permit either focus on Buddhist practices or are designed to expose non-
Buddhists to Buddhist practices. Every retreat participant is reminded verbally, and in
writing, to maintain the sacred environment at Ratna Ling. All retreats include daily
meditation sessions and KumNye Yoga. Kum Nye Yoga is agentle Tibetan Yoga
practice that focuses on healing and bringing energies together to work smoothly and
harmoniously. Inkeeping with Buddhist requirements, all meals arevegetarian. Every
guest cottage contains information about Buddhist practices and every retreat participant
has access to the center's library containing an array of books and other resources on the
Buddhist traditions and practices.
It is sincerely hoped that the Master Use Permit will constitute acomprehensive
planning document that enables both Ratna Ling and the County to administer this
special property with greater clarity and efficiency in the years ahead.
ENVIRONMENTAL STEWARDSHIP
The Center is leader in environmental stewardship at the project site. Gene
Gretchen, is an internationally recognized leader in environmentally conscious practices
and he is the Co-director and Facilities Manager of the Center.
3
Mr. Gretchen has
implemented and maintains many environmentally sensitive practices on the project site.
The Center only uses non-toxic, vegetable-based ink at its printing presses. Ratna Ling's
landscaping is drought tolerant. The Center captures rain water off the roofs of some of
its buildings. Almost all faucets and fixtures on the project site are low flow. The Center
maintains an on-site organic garden that supplies most of the produce used in the
communal kitchen. Ratna Ling's volunteers, guests, and work study participants move
about the site by foot, bike or electric golf carts, resulting in insignificant Green House
Gas Emissions. The Center uses sustainable green products wherever possible, such as
the cork floors in its main conference center building. Retreat participants are also
reminded to bemindful of the environment and Ratna Ling's commitment to the best
possible environmental practices.
COMMUNITY CONTRIBUTIONS
The Center remains committed to working harmoniously with its neighbors and
County officials as it continues its unique and indisputably worthy mission. While
remaining true to the spiritual purposes of its projects, which have drawn positive world-
wide attention to Sonoma County, the Center has more than distinguished itself by its
numerous contributions to the economic welfare of the County as awhole, and by many
acts of generosity to the immediate Seaview Ridge community.
3A copy of Mr. Gretchen's CV is attached to this update.
3
Updated Project Description 3.26.13
EXHIBIT A
RATNA LING UPDATED MASTER USE PERMIT APPLICATION
j
Modified Use Permit Application (UPE 004-0032)
35755 Hauser Bridge Road
APN 109-230-024
Supplemental Analysis of Proposed Use (April 15,2004)
Exhibit A
Table 3: Emissions (no emissions ofa fugitive nature)
0/ v6 1 : . -
Material Description of/emission
Anmial Annual VOC's
U7a.ge
(pounds)
VI20 A washup/c1eaning solvent
~
813.6
ons
~1 2J11.
Ecolowash Washup solvent; contains petroleum naptha 5gallons 3.75
StepA
HDl Fountain solution; contains non-hazardous 25gallons 30.75
nitrates
HD2 Fountain solution; contains 2butoxyl ethanol, 25gallons 63.25
!
diaethalyne glycol monohexal ether
i
Typewash Contains toluene'hexane andisoproponol 5gallons 33.45
SF SoyPlus Non-hazardous per29CFR 1910.1200 4,000 39.99
Inks pounds
Isopropyl
alcohol 5gallons 32.85
Total 1017.64
. \ YJ ~~ \ b( 9 1 \ \
Note: OnJ anuary 5, 2004, aTNMCIDM representatiJ : met with Alex Saschin, Air Quality
Engineer with Northern Sonoma County Air Pollution Control District. Hereviewed the
information provided inTable 3and stated that thetotal of approximately 1,000VOC's
produced by theprinting operation annually is far below thethreshold level of 80,000 VOC's
annually that theDistrict begins toregard with concern.
Table 4: Wastewater Discharge fromthePrinting Operation
Volume Content . Frequency
7gallons 7gallons water, 21 oz. eaHDI &IID2 weekly
Note: OnJ anuary 5, 2004, alNMCIDM representative met with J ohn Short, Senior Engineer at
the California Regional Water Quality Control Board. He confirmed that the existing water
systemand discharge plans at Timber Hill hadreceived ageneral wastewater discharge permit.
With respect to theproposed printing operations, hereviewed the wastewater discharge for the
proposed ancillary printing facility, consisting of7 gallons weekly, andasked TNMC to develop
aproposal for dealing with this amount of discharge, such as aholding tank that would be
pumped out periodically. DM is currently researching alternatives to meet this concern.
Modified UsePermit Application (upE 004-0032)
35755Hauser Bridge Road
APN 109-230-024
Supplemental Analysis of Proposed Use(April 15. 2004)
Exhibit A
Table 1: Total maximum raw material usage:
Raw material Annual Usage Units
Anthem press plates 2,500 Plates
Presstek filter #1 50 Filters
Printing paper 12 Carloads (1carload =756,000 sheets)
Printing Ink
4,000 Pounds
V120 washup solvent 120 Gallons
Ecolowash Step A washup 5 Gallons
HD1fountain solution 25 Gallons
HD2 fountain solution 25 Gallons
Type wash 5 Gallons
Isopropyl alcohol 5 Gallons
Rags 4,500 16inx 7in shoptowels
Cover stock 10,000 Sheets
Gold foil 30 rolls (=30,000 feet)
Fabric 40,000 Yards
Table 2: Information on Current Equipment
: Equipment ID Inlet/Out Emission Energy Mode of
! Number Temp. points and Consumption Operation
i
where (KW/hr)
,
: vented
Presstek 0302-8025 16kwh/hour Intermittent
Dimension 800
CTP System
,
I
IHeidelberg Sordz 526-096 12hours/day
iPress continuous
IStahl Folder 32.950 240V, 40.amp 12hours/day
I
continuous
: BaumCutter Not known 60Hz, 460 or Intermittent
230
IEhlermann 630 1.5Kw, 2.0ps, 12hours/day
I Collator 50Hz continuous
Franklin Serial 230V, 4(11555)
Stamping Press 30343/08 Watts Intermittent
I
!
_ ._ .
-.. . '.- -..- .. ... _ - ,
- -
..
UNIFIED PROGRAM CONSOLIDATED FORM
FACILITY INFORMATION
BUSINESS ACTIVITIES
7078473510
~.2
DYES 181 NO 14.
15
Page1of_
L FACILITY IDENTIFICATION
2.
FACILITY 10 #
(Agency Use On!>')
3.
BUSINESS NAME (Same as Facility Name or DBA -Doing Business As}
Ratna Ling Center
II. ACTIVITIES DECLARATION
NOTE: Hyou check YES to any part of this list,
pleasesubmit theBusiness Owner/Operator Identification page(OES Form Z' 30)
. Does your facilitY... If Yes, olease complete these Pill es of theUPCF ...
A. HAZARDOUS MATERIALS
Have on site (for any purpose) hazardous materials at or above S5gallons for
liquids, 500 pounds for solids, or 200 cubic feet for compressed gases
(include liquids in ASTs and USTs); or the applicable Federal threshold
quantity for an extremely hazardous substance specified in 40 CFR Pan 355,
Appendix A or-B; or handle radiological materials in quantities for which an
emere:encv "Dlanisrequired pursuant to 10CFR Parts 30, 40or 70?
181YES 0 NO ~.
So UNDERGROUND STORAGE TANKS rUSTs)
L Own or operate underground storage tanks?
2. Intend to upgrade existing or install new USTs?
DYES ~ NO 5.
oYES 181 NO 6.
3. Need to report closing aUST? 0 YES 1:81NO 7.
C. ABOVE GROUND PEfROLEUM STORAGE TANKS (ASTs) ~'
Own OfOperateASTs above these thresholds: i f ? )1/- -~
-any tank capacity isgreater than 660 gallons, or 1 f t . - ~ / J. r / ) 8.
=-the total capacity for the facility isgreater than 1,320 gallons? '/ ~ -
D. HAZARDOUS WASTE
1. Generate hazardous waste? ~ -8-N& 9.
2. Recycle more than 100kg/month of excluded or exempted recyclable
materials (perH&SC 25143.2)?
Treat hazardous waste onsite?
oYES I'8t NO 10.
oYES 181 NO II.
3.
4.
Treatment subject to financial assurance requirements (for Permit by
Rule and Conditional Authorization)?
Consolidate hazardous wastegenerated at aremote site?
DYES 1:81 NO 13.
DYES 1:81 NO 12
5.
6.
Need to report the closureiremoval of a tank that was classified as
hazardous waste and cleaned onsite?
E. LOCAL REQUIREMENTS
HAZARDOUS l/MTERIALS INVENTORY
-CHEl\ iIlCAL I ESCRlPTION (OES 2731)
UST FACll..ITY (FormerlySWRCBFonnA)
UST TANK (one agcpcrunk){ForrncrIyFarmB)
UST FACILITY
UST TANK (o.e,,", tonk)
USTINSTALL TION-CERTIFrCATEOF
COMPLIANCE (aDO J "IIl" pel"1anIl) (Formerty Form C)
UST TANK (clo ri:portian-a!lcpaJ lcpcrtanl:)
NO FORM RE( UIRED TO CUPAs
EPA 10 NUMB ~R -provide at the top of this
page
RECYCLABLE MATERIALS REPORT (Oil<
per n:c)'cler)
ONSUE HAZA/RDoUS WASTE
TREATMENT FACILITY (F~I1DCJ lyDTSC
Forms 1772) .
ONSITE" ~ ID'1">rIUSWASTE
TREATMENT UNIT {cnepl\ IleJ ><lunrt)(Fonn<rly
OTSC F<ll1llll1772J :.s,C.O....J L)
CERTIFlCATI N OF FINANCIAL
ASSURANCE onner1yDTSC Form 1232)
REMOTEW~ TE ICONSOLIDATION
SITE ANNUAl NOTIFfCATION (Formerly
DTSC Form 1196)
HAZARDOUS IwASTE TANK CLOSURE
CERTlFlCA TI N (FormerlyDTSCForm1249)
(You may also berequired ICI provide additional information by your CUPA or local agency.)
oct .lJ l U8 U8:08p Construcnon omce (U (ti4 (;:Sol U p.;:S
-
UNlFIED PROGRAM CONSOLIDATED FORM
,
FACILITY INFORMATION
BUSINESS OWNER/OPERATOR IDENTIFICATION
Palte of
;
I. IDENTIFICATION
101.
I I I I I I I I I
I \ I
11. IBEGINNING DATE
100.
IENDl
GDATE
FACILITY 10 #
(Agency Use Only) 10/0812009 10/0 12012
.
3. IBUSINESS PHON E
101.
BUSINESS NAME (Samoa, FACILITY NAME orDBA-[)Qill8Bu,in As)
Ratna Ling Center
707 847-3777
103.
BUSINESS SITE ADDRESS
35755 Hauser Bridge Rd
105.
CITY
1~.
ICA
ZlPCODE
Cazadero
95421
1015.
SIC CODE (4 digit #)
107.
DUN &BRADSTREET
~/'\
2731
,
lOll
COUNTY
Sonoma
BUSINESS OPERATOR NAME
109.
BUSINESS OPERATOR PHONE
IlO.
Ratna Ling CenterlDharrna Publishing
707 847-3777
n, BUSINESS OWNER
OWNERNAME.
lit
OWNER!'l:llf'NE
J 1~
Head Lama Tibetan Nyingma Meditation Center
707 847-3777
OWNER MAILIliIG ADDRESS
113.
.
..
35755 Hauser.Bridge Rd
,
CITY
114.
.lSTATE
lJ S.
IZlPC<
DE
116.
"
Cazadero
,
.-. CA 9542
,-
ill. ENVIRONMENTAL CONTACT
CONTACT NAME
117.
CONTACT PHONE
us,
Arnaud Maitlandl 707 S47-3777ext 2C 1
CONTACT MAILING ADDRESS
119.
35755 Hauser. Bridge Rd
CITY
120.
ISTATE
121.
IZIPC(
DE
I"" .
Cazadero CA 9542
-PRIMARY- N. EMERGENCY CONTACfS -SE( ONDARY-
NAVfE
123.
NAME
128..
Ralph McFall' Doug Nwnberg
TITLE
124.
TITLE
129.
Print Manager Project Manager
BUSINESS PHONE
125.
BUSINESS PHONE
J 30.
707847-3777 ext 219 707847-3777 ext 111
24-HOUR PHONE
126.
24-HOUR PHONE
D!.
, 707 847-3777 707 322-6330
PAGER # 127.
PAGER #
132.
ADDmONAL LOCALLY COLLECTED INFORMATION: 13l.
Property Owner:
Phone No.: 707 ~ 7-3777-
Billing Address: 35755 Hauser Bridge Rd, Cazadero, CA ~5421
Certification: Based on my inquiry of those individuals responsible for obtaining the infonoation, I certify UDder penally of law that I have personally examined and
amfamiliar with: the information submitted and believe the information is true, accurate, and complete.
SIGNATURE OF OWNER/OPERA TOR OR DESfGNATED REPRESENTATIVE DATE 134. ! NAME OF PREPARER
135
10/0812009 DougNumbers
. NAME OF SJ GNffi (print) 136.
TITLE OF SIGNER
137.
Doug Nurnbera Project Manager
.See Instructions on next PlISe.
. .. .. .
Date: 1 0- . - 1 B /Zt;{J i
Business Name:
tS;J U1C as f.l<ilit)" N/lillC ur UII.\ )
Non-Waste Hazardous Materials Inventory Statement
For use by Unidocs Member Agencies or where approved by your Local Jurisdiction
~i.
....._ .._ - , Type of Report on This Page: 1 Page _ _ of_ _ II
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MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 01/08/04 Page 1 of 8

NFPA 704 (Section 16)
EMERGENCY OVERVIEW
DANGER!
EXTREMELY FLAMMABLE - EYE AND MUCOUS MEMBRANE IRRITANT
- EFFECTS CENTRAL NERVOUS SYSTEM - HARMFUL OR FATAL IF
SWALLOWED - ASPIRATION HAZARD
High fire hazard. Keep away from heat, spark, open flame, and other ignition
sources.
If ingested, do NOT induce vomiting, as this may cause chemical pneumonia (fluid in the lungs). Contact
may cause eye, skin and mucous membrane irritation. Harmful if absorbed through the skin. Avoid
prolonged breathing of vapors or mists. Inhalation may cause irritation, anesthetic effects (dizziness,
nausea, headache, intoxication), and respiratory system effects.
Long-term exposure may cause effects to specific organs, such as to the liver, kidneys, blood, nervous
system, and skin. Contains benzene, which can cause blood disease, including anemia and leukemia.

1. CHEMICAL PRODUCT and COMPANY INFORMATION (rev. Jan-04)
Amerada Hess Corporation
1 Hess Plaza
Woodbridge, NJ 07095-0961
EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800)424-9300
COMPANY CONTACT (business hours): Corporate Safety (732)750-6000
MSDS Internet Website www.hess.com/about/environ.html
SYNONYMS: Hess Conventional (Oxygenated and Non-oxygenated) Gasoline; Reformulated Gasoline
(RFG); Reformulated Gasoline Blendstock for Oxygenate Blending (RBOB); Unleaded
Motor or Automotive Gasoline
See Section 16 for abbreviations and acronyms.
2. COMPOSITION and INFORMATION ON INGREDIENTS * (rev. Jan-04)

INGREDIENT NAME (CAS No.) CONCENTRATION PERCENT BY WEIGHT
Gasoline (86290-81-5)

100
Benzene (71-43-2)

0.1 - 4.9 (0.1 - 1.3 reformulated gasoline)
n-Butane (106-97-8)

< 10
Ethyl Alcohol (Ethanol) (64-17-5)

0 - 10
Ethyl benzene (100-41-4)

< 3
n-Hexane (110-54-3)

0.5 to 4
Methyl-tertiary butyl ether (MTBE) (1634-04-4)

0 to 15.0
Tertiary-amyl methyl ether (TAME) (994-05-8)

0 to 17.2
Toluene (108-88-3)

1 - 25
1,2,4- Trimethylbenzene (95-63-6)

< 6
Xylene, mixed isomers (1330-20-7)

1 - 15

A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and
aromatic hydrocarbons. May contain antioxidant and multifunctional additives. Non-oxygenated
Conventional Gasoline and RBOB do not have oxygenates (Ethanol or MTBE and/or TAME).
Oxygenated Conventional and Reformulated Gasoline will have oxygenates for octane enhancement or
as legally required.

EXHIBIT D


3. HAZARDS IDENTIFICATION (rev. Dec-97)

EYES
Moderate irritant. Contact with liquid or vapor may cause irritation.
SKIN
Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with
prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of
skin are exposed repeatedly.
INGESTION
The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into
the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs),
severe lung damage, respiratory failure and even death.
Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and
central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors,
convulsions, loss of consciousness, coma, respiratory arrest, and death may occur.
INHALATION
Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous
system (brain) effects may include headache, dizziness, loss of balance and coordination,
unconsciousness, coma, respiratory failure, and death.
WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result
in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels,
which may cause unconsciousness, suffocation, and death.
CHRONIC EFFECTS and CARCINOGENICITY
Contains benzene, a regulated human carcinogen. Benzene has the potential to cause anemia and other
blood diseases, including leukemia, after repeated and prolonged exposure. Exposure to light
hydrocarbons in the same boiling range as this product has been associated in animal studies with
systemic toxicity. See also Section 11 - Toxicological Information.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Irritation from skin exposure may aggravate existing open wounds, skin disorders, and dermatitis (rash).
Chronic respiratory disease, liver or kidney dysfunction, or pre-existing central nervous system disorders
may be aggravated by exposure.
4. FIRST AID MEASURES (rev. Dec-97)
EYES
In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold
eyelids open to ensure adequate flushing. Seek medical attention.
SKIN
Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or waterless
hand cleanser. Obtain medical attention if irritation or redness develops.
INGESTION
DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous
vomiting occurs, lean victim forward to reduce the risk of aspiration. Small amounts of material which
enter the mouth should be rinsed out until the taste is dissipated.
INHALATION
Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial
respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek
medical attention immediately.



5. FIRE FIGHTING MEASURES (rev. Dec-97)
FLAMMABLE PROPERTIES:
FLASH POINT: -45
o
F (-43
o
C)
AUTOIGNITION TEMPERATURE: highly variable; > 530
o
F (>280
o
C)
OSHA/NFPA FLAMMABILITY CLASS: 1A (flammable liquid)
LOWER EXPLOSIVE LIMIT (%): 1.4%
UPPER EXPLOSIVE LIMIT (%): 7.6%
FIRE AND EXPLOSION HAZARDS
Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition.
Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to
an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier
than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may
cause fire or explosion hazard.
EXTINGUISHING MEDIA
SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting
foam, or Halon.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but
may be used to cool fire-exposed containers.
During certain times of the year and/or in certain geographical locations, gasoline may contain MTBE
and/or TAME. Firefighting foam suitable for polar solvents is recommended for fuel with greater than
10% oxygenate concentration - refer to NFPA 11 Low Expansion Foam - 1994 Edition.
FIRE FIGHTING INSTRUCTIONS
Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire
extinguishers and other fire fighting equipment.
Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of
combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing
apparatus with full facepiece and full protective clothing.
Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and
excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may
be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing
the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to
extinguish the fire, often including the need for properly applied fire fighting foam.
See Section 16 for the NFPA 704 Hazard Rating.
6. ACCIDENTAL RELEASE MEASURES (rev. Dec-97)
ACTIVATE FACILITY SPILL CONTINGENCY or EMERGENCY PLAN.
Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay
upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill
areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary
to determine the extent of subsurface impact.
Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking,
absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless
system is designed and permitted to handle such material. The use of fire fighting foam may be useful in
certain situations to reduce vapors. The proper use of water spray may effectively disperse product


vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require
protection.
Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste
container for reclamation or disposal - caution, flammable vapors may accumulate in closed containers.
Response and clean-up crews must be properly trained and must utilize proper protective equipment
(see Section 8).
7. HANDLING and STORAGE (rev. Dec-97)
HANDLING PRECAUTIONS
******USE ONLY AS A MOTOR FUEL******
******DO NOT SIPHON BY MOUTH******
Handle as a flammable liquid. Keep away from heat, sparks, and open flame! Electrical equipment
should be approved for classified area. Bond and ground containers during product transfer to reduce the
possibility of static-initiated fire or explosion.
Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that
can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low
flash point products (such as this product) - see API Publication 2003, "Protection Against Ignitions
Arising Out Of Static, Lightning and Stray Currents.
STORAGE PRECAUTIONS
Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented
containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain
explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition.
Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and
Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously
containing this product should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In
Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks".
WORK/HYGIENIC PRACTICES
Emergency eye wash capability should be available in the near proximity to operations presenting a
potential splash exposure. Use good personal hygiene practices. Avoid repeated and/or prolonged skin
exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a
cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this product
from exposed skin areas. Waterless hand cleaners are effective. Promptly remove contaminated
clothing and launder before reuse. Use care when laundering to prevent the formation of flammable
vapors which could ignite via washer or dryer. Consider the need to discard contaminated leather shoes
and gloves.
8. EXPOSURE CONTROLS and PERSONAL PROTECTION (rev. Jan-04)
EXPOSURE LIMITS
Component (CAS No.) Exposure Limits
Source TWA
(ppm)
STEL
(ppm)
Note
Gasoline (86290-81-5) ACGIH 300 500 A3
Benzene (71-43-2) OSHA
ACGIH
USCG
1
0.5
1
5
2.5
5
Carcinogen
A1, skin

n-Butane (106-97-8) ACGIH 800 -- 2003 NOIC: 1000 ppm (TWA) Aliphatic
Hydrocarbon Gases Alkane (C1-C4)
Ethyl Alcohol (ethanol) (64-17-5) OSHA
ACGIH
1000
1000
--
--

A4
Ethyl benzene (100-41-4) OSHA
ACGIH
100
100
--
125

A3


Component (CAS No.) Exposure Limits
Source TWA
(ppm)
STEL
(ppm)
Note
n-Hexane (110-54-3) OSHA
ACGIH
500
50
--
--

skin
Methyl-tertiary butyl ether [MTBE] (1634-04-4) ACGIH 50 A3
Tertiary-amyl methyl ether [TAME] (994-05-8) None established
Toluene (108-88-3) OSHA
ACGIH
200
50

--
Ceiling: 300 ppm; Peak: 500 ppm (10 min.)
A4 (skin)
1,2,4- Trimethylbenzene (95-63-6) ACGIH 25 --
Xylene, mixed isomers (1330-20-7) OSHA
ACGIH
100
100
--
150

A4

ENGINEERING CONTROLS
Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and
flammability limits, particularly in confined spaces.
EYE/FACE PROTECTION
Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.
SKIN PROTECTION
Gloves constructed of nitrile or neoprene are recommended. Chemical protective clothing such as that
made of of E.I. DuPont Tychem , products or equivalent is recommended based on degree of exposure.
Note: The resistance of specific material may vary from product to product as well as with degree of
exposure. Consult manufacturer specifications for further information.
RESPIRATORY PROTECTION
A NIOSH-approved air-purifying respirator with organic vapor cartridges or canister may be permissible
under certain circumstances where airborne concentrations are or may be expected to exceed exposure
limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29
CFR 1910.134, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on
respiratory protection selection and limitations.
Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure
levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying
respirator may not provide adequate protection.
9. PHYSICAL and CHEMICAL PROPERTIES (rev. Jan-04)
APPEARANCE
A translucent, straw-colored or light yellow liquid
ODOR
A strong, characteristic aromatic hydrocarbon odor. Oxygenated gasoline with MTBE and/or TAME may
have a sweet, ether-like odor and is detectable at a lower concentration than non-oxygenated gasoline.
ODOR THRESHOLD
Odor Detection Odor Recognition
Non-oxygenated gasoline: 0.5 - 0.6 ppm 0.8 - 1.1 ppm
Gasoline with 15% MTBE: 0.2 - 0.3 ppm 0.4 - 0.7 ppm
Gasoline with 15% TAME: 0.1 ppm 0.2 ppm
BASIC PHYSICAL PROPERTIES
BOILING RANGE: 85 to 437
o
F (39 to 200
o
C)
VAPOR PRESSURE: 6.4 - 15 RVP @ 100
o
F (38
o
C) (275-475 mm Hg @ 68
o
F (20
o
C)
VAPOR DENSITY (air = 1): AP 3 to 4
SPECIFIC GRAVITY (H
2
O = 1): 0.70 0.78
EVAPORATION RATE: 10-11 (n-butyl acetate = 1)
PERCENT VOLATILES: 100 %


SOLUBILITY (H
2
O): Non-oxygenated gasoline - negligible (< 0.1% @ 77
o
F). Gasoline with 15%
MTBE - slight (0.1 - 3% @ 77
o
F); ethanol is readily soluble in water
10. STABILITY and REACTIVITY (rev. Dec-94)
STABILITY: Stable. Hazardous polymerization will not occur.
CONDITIONS TO AVOID
Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources
INCOMPATIBLE MATERIALS
Keep away from strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and
sulfuric acids will form nitrocresols that can decompose violently.
11. TOXICOLOGICAL PROPERTIES (rev. Dec-97)
ACUTE TOXICITY
Acute Dermal LD50 (rabbits): > 5 ml/kg Acute Oral LD50 (rat): 18.75 ml/kg
Primary dermal irritation (rabbits): slightly irritating Draize eye irritation (rabbits): non-irritating
Guinea pig sensitization: negative
CHRONIC EFFECTS AND CARCINOGENICITY
Carcinogenicity: OSHA: NO IARC: YES - 2B NTP: NO ACGIH: YES (A3)
IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation
exposure to completely vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors
in female mice. The U.S. EPA has determined that the male kidney tumors are species-specific and are
irrelevant for human health risk assessment. The significance of the tumors seen in female mice is not
known. Exposure to light hydrocarbons in the same boiling range as this product has been associated in
animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The
significance of these animal models to predict similar human response to gasoline is uncertain.
This product contains benzene. Human health studies indicate that prolonged and/or repeated
overexposure to benzene may cause damage to the blood-forming system (particularly bone marrow),
and serious blood disorders such as aplastic anemia and leukemia. Benzene is listed as a human
carcinogen by the NTP, IARC, OSHA and ACGIH.
This product may contain methyl tertiary butyl ether (MTBE ): animal and human health effects studies
indicate that MTBE may cause eye, skin, and respiratory tract irritation, central nervous system
depression and neurotoxicity. MTBE is classified as an animal carcinogen (A3) by the ACGIH.
12. ECOLOGICAL INFORMATION (rev. Jan-04)
Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under
Federal and State regulations. If released, oxygenates such as ethers and alcohols will be expected to
exhibit fairly high mobility in soil, and therefore may leach into groundwater. The API (www.api.org)
provides a number of useful references addressing petroleum and oxygenate contamination of
groundwater.
13. DISPOSAL CONSIDERATIONS (rev. Dec-97)
Consult federal, state and local waste regulations to determine appropriate disposal options.



14. TRANSPORTATION INFORMATION (rev. Jan-04)

DOT PROPER SHIPPING NAME: Gasoline
DOT HAZARD CLASS and PACKING GROUP: 3, PG II
DOT IDENTIFICATION NUMBER: UN 1203
DOT SHIPPING LABEL:

FLAMMABLE LIQUID
PLACARD:

15. REGULATORY INFORMATION (rev. Jan-04)
U.S. FEDERAL, STATE, and LOCAL REGULATORY INFORMATION
This product and its constituents listed herein are on the EPA TSCA Inventory. Any spill or uncontrolled
release of this product, including any substantial threat of release, may be subject to federal, state and/or
local reporting requirements. This product and/or its constituents may also be subject to other federal,
state, or local regulations; consult those regulations applicable to your facility/operation.
CLEAN WATER ACT (OIL SPILLS)
Any spill or release of this product to "navigable waters" (essentially any surface water, including certain
wetlands) or adjoining shorelines sufficient to cause a visible sheen or deposit of a sludge or emulsion
must be reported immediately to the National Response Center (1-800-424-8802) or, if not practical, the
U.S. Coast Guard with follow-up to the National Response Center, as required by U.S. Federal Law. Also
contact appropriate state and local regulatory agencies as required.
CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIRONMENT)
The CERCLA definition of hazardous substances contains a petroleum exclusion clause which exempts
crude oil, refined, and unrefined petroleum products and any indigenous components of such. However,
other federal reporting requirements (e.g., SARA Section 304 as well as the Clean Water Act if the spill
occurs on navigable waters) may still apply.
SARA SECTION 311/312 - HAZARD CLASSES
ACUTE HEALTH CHRONIC HEALTH FIRE SUDDEN RELEASE OF PRESSURE REACTIVE
X X X -- --
SARA SECTION 313 - SUPPLIER NOTIFICATION
This product contains the following toxic chemicals subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:
INGREDIENT NAME (CAS NUMBER) CONCENTRATION WT. PERCENT
Benzene (71-43-2)
0.1 to 4.9 (0.1 to 1.3 for reformulated gasoline)
Ethyl benzene (100-41-4)
< 3
n-Hexane (110-54-3)
0.5 to 4
Methyl-tertiary butyl ether (MTBE) (1634-04-4)
0 to 15.0
Toluene (108-88-3)
1 to 15
1,2,4- Trimethylbenzene (95-63-6)
< 6
Xylene, mixed isomers (1330-20-7)
1 to 15
US EPA guidance documents (www.epa.gov/tri) for reporting Persistent Bioaccumulating Toxics (PBTs)
indicate this product may contain the following deminimis levels of toxic chemicals subject to Section 313
reporting:
INGREDIENT NAME (CAS NUMBER) CONCENTRATION - Parts per million (ppm) by weight
Polycyclic aromatic compounds (PACs)
Benzo (g,h,i) perylene (191-24-2)
Lead (7439-92-1)
17
2.55
0.079


CANADIAN REGULATORY INFORMATION (WHMIS)
Class B, Division 2 (Flammable Liquid)
Class D, Division 2A (Very toxic by other means) and Class D, Division 2B (Toxic by other means)
16. OTHER INFORMATION (rev. Jan-04)

NFPA HAZARD RATING HEALTH: 1 Slight
FIRE: 3 Serious
REACTIVITY: 0 Minimal
HMIS HAZARD RATING HEALTH: 1 * Slight
FIRE: 3 Serious
REACTIVITY: 0 Minimal
* CHRONIC
SUPERSEDES MSDS DATED: 12/30/97
ABBREVIATIONS:
AP = Approximately < = Less than > = Greater than
N/A = Not Applicable N/D = Not Determined ppm = parts per million
ACRONYMS:
ACGIH American Conference of Governmental
Industrial Hygienists
AIHA American Industrial Hygiene Association
ANSI American National Standards Institute
(212)642-4900
API American Petroleum Institute
(202)682-8000
CERCLA Comprehensive Emergency Response,
Compensation, and Liability Act
DOT U.S. Department of Transportation
[General Info: (800)467-4922]
EPA U.S. Environmental Protection Agency
HMIS Hazardous Materials Information System
IARC International Agency For Research On
Cancer
MSHA Mine Safety and Health Administration
NFPA National Fire Protection Association
(617)770-3000
NIOSH National Institute of Occupational Safety
and Health
NOIC Notice of Intended Change (proposed
change to ACGIH TLV)
NTP National Toxicology Program
OPA Oil Pollution Act of 1990
OSHA U.S. Occupational Safety & Health
Administration
PEL Permissible Exposure Limit (OSHA)
RCRA Resource Conservation and Recovery Act
REL Recommended Exposure Limit (NIOSH)
SARA Superfund Amendments and
Reauthorization Act of 1986 Title III
SCBA Self-Contained Breathing Apparatus
SPCC Spill Prevention, Control, and
Countermeasures
STEL Short-Term Exposure Limit (generally 15
minutes)
TLV Threshold Limit Value (ACGIH)
TSCA Toxic Substances Control Act
TWA Time Weighted Average (8 hr.)
WEEL Workplace Environmental Exposure
Level (AIHA)
WHMIS Workplace Hazardous Materials
Information System (Canada)

DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best
of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties,
expressed or implied, except those that may be contained in our written contract of sale or acknowledgment.
Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety
procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or
third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore,
vendee assumes the risk in their use of the material.
Material Safety Data Sheet
1. Product and company identification
Product name DIESEL FUEL NO. 2
MSDS # 11155
Product use Fuel.
Synonyms Ultra Low Sulfur No. 2 Amoco Premier Diesel Fuel, Ultra Low Sulfur No. 2 Amoco Premier Diesel
Fuel Winterized, Ultra Low Sulfur No. 2 BP Supreme Diesel, Low Sulfur No. 2 BP Diesel Fuel,
Ultra Low Sulfur No. 2 BP Diesel Fuel, Ultra Low Sulfur No. 2 BP Diesel Fuel Winterized
Code 11155
Supplier BP Products North America Inc.
150 West Warrenville Road
Naperville, Illinois 60563-8460
USA
EMERGENCY HEALTH
INFORMATION:
1 (800) 447-8735
Outside the US: +1 703-527-3887 (CHEMTREC)
EMERGENCY SPILL
INFORMATION:
1 (800) 424-9300 CHEMTREC (USA)
OTHER PRODUCT
INFORMATION
1 (866) 4 BP - MSDS
(866-427-6737 Toll Free - North America)
email: bpcares@bp.com
2. Hazards identification
Physical state
Color Colorless. to Various Colors. (May be dyed Red., Light Green. ,Yellow. )
Emergency overview WARNING !
COMBUSTIBLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
HARMFUL IF SWALLOWED.
ASPIRATION HAZARD.
HARMFUL OR FATAL IF LIQUID IS ASPIRATED INTO LUNGS.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS, AND NAUSEA, AND MAY
LEAD TO UNCONSCIOUSNESS.
Combustible liquid. Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and
cause damage. Keep away from heat, sparks and flame. Avoid exposure - obtain special
instructions before use. Do not breathe vapor or mist. Do not ingest. If ingested, do not induce
vomiting. Avoid contact with eyes, skin and clothing. Contains material which may cause cancer,
based on animal data. Risk of cancer depends on duration and level of exposure. Use only with
adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash
thoroughly after handling.
Dermal contact. Eye contact. Inhalation. Ingestion. Routes of entry
Potential health effects
Eyes Slightly irritating to the eyes.
Skin Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis.
Inhalation May cause respiratory tract irritation. Inhalation causes headaches, dizziness, drowsiness and
nausea and may lead to unconsciousness. See toxicological information (section 11).
Liquid.
Date of issue 07/20/2010.
Page: 1/8 DIESEL FUEL NO. 2
ENGLISH.
(ENGLISH)
Product name Product code
Version 2 Format Language US-COMP
11155
(US-COMP)
Ingestion Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. See
toxicological information (section 11).
See toxicological information (section 11)
3. Composition/information on ingredients
Ingredient name CAS # %
Petroleum distillates (Diesel Fuel No. 2) 68476-34-6 95 - 100
.
Contains one or more of the following biodiesels: Varies 0 - 5
soybean oil, me ester 67784-80-9 .
Fatty acids, sunflower-oil, Me esters 68919-54-0 .
Fatty acids methyl esters 67762-38-3 .
Fatty acids, vegetable-oil, Methyl esters 68990-52-3 .
rape oil, me ester 73891-99-3 .
Fatty acids, canola-oil, Me esters 129828-16-6 .
fatty acids, tallow, me esters 61788-61-2 .
Contains:
Naphthalene 91-20-3 1 - 3
May also contain small quantities of proprietary performance additives.
4. First aid measures
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention.
Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash
clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation
develops.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting.
Never give anything by mouth to an unconscious person. Get medical attention immediately.
5. Fire-fighting measures
Auto-ignition temperature 257C (494F)
Explosion limits Lower: 0.6%
Upper: 7.5%
Flammability of the
product
Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Unusual fire/explosion
hazards
Combustible liquid.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
No action shall be taken involving any personal risk or without suitable training. Move containers
from fire area if this can be done without risk. Use water spray to keep fire-exposed containers
cool.
Protective clothing (fire)
Fire-fighting procedures
Hazardous combustion
products
Combustion products may include the following:
carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)
Combustible liquid and vapor. Vapor may cause flash fire. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to
sewer may create fire or explosion hazard.
Fire/explosion hazards
Flash point Closed cup: >38C (>100.4F) [Pensky-Martens.]
Extinguishing media
Suitable In case of fire, use water fog, foam, dry chemicals, or carbon dioxide.
Do not use water jet. Not suitable
ENGLISH.
(ENGLISH)
11155
(US-COMP)
Special remarks on fire
hazards
Do not use water jet.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.
6. Accidental release measures
Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Approach
release from upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see section 13). Use spark-proof
tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see
section 1 for emergency contact information and section 13 for waste disposal.
Environmental
precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).
Large spill
Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Absorb
with an inert material and place in an appropriate waste disposal container. Use spark-proof tools
and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Small spill
Methods for cleaning up
Personal protection in
case of a large spill
Chemical splash goggles. Chemical-resistant protective suit. Boots. Chemical-resistant gloves.
Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the product.
Suggested protective clothing might not be adequate. Consult a specialist before handling this
product. CAUTION: The protection provided by air-purifying respirators is limited. Use a positive
pressure air-supplied respirator if there is any potential for an uncontrolled release, if exposure
levels are not known, or if concentrations exceed the protection limits of air-purifying respirator.
7. Handling and storage
Handling Do not ingest. Never siphon by mouth. If ingested, do not induce vomiting. Put on appropriate
personal protective equipment (see section 8). Workers should wash hands and face before
eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Store
and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate
static electricity during transfer by grounding and bonding containers and equipment before
transferring material.
Storage Store in accordance with local regulations. Store in a segregated and approved area. Store away
from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
section 10). Eliminate all ignition sources. Separate from oxidizing materials. Keep container
tightly closed and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8. Exposure controls/personal protection
Occupational exposure limits
Petroleum distillates ACGIH TLV (United States). Absorbed through skin.
TWA: 100 mg/m, (measured as total hydrocarbons) 8 hour(s). Issued/Revised:
1/2002 Form: Total hydrocarbons
Naphthalene ACGIH TLV (United States).
STEL: 79 mg/m 15 minute(s). Issued/Revised: 5/1996
STEL: 15 ppm 15 minute(s). Issued/Revised: 5/1996
TWA: 52 mg/m 8 hour(s). Issued/Revised: 5/1996
TWA: 10 ppm 8 hour(s). Issued/Revised: 5/1996
OSHA PEL (United States).
TWA: 50 mg/m 8 hour(s). Issued/Revised: 6/1993
Ingredient name Occupational exposure limits
ENGLISH.
(ENGLISH)
11155
(US-COMP)
TWA: 10 ppm 8 hour(s). Issued/Revised: 6/1993
Some states may enforce more stringent exposure limits.
While specific OELs for certain components may be shown in this section, other components may be present in any mist, vapor or
dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only.
Control Measures Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants below any recommended
or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash contaminated clothing before
reusing.
Personal protection
Eyes Avoid contact with eyes. Safety glasses with side shields.
Skin and body Avoid contact with skin and clothing. Wear suitable protective clothing.
Respiratory Use only with adequate ventilation. Do not breathe vapor or mist. If ventilation is inadequate, use
a NIOSH-certified respirator with an organic vapor cartridge and P95 particulate filter.
CAUTION: The protection provided by air-purifying respirators is limited. Use a positive pressure
air-supplied respirator if there is any potential for an uncontrolled release, if exposure levels are not
known, or if concentrations exceed the protection limits of air-purifying respirator.
Hands Wear gloves that cannot be penetrated by chemicals or oil.
The correct choice of protective gloves depends upon the chemicals being handled, the conditions
of work and use, and the condition of the gloves (even the best chemically resistant glove will
break down after repeated chemical exposures). Most gloves provide only a short time of
protection before they must be discarded and replaced. Because specific work environments and
material handling practices vary, safety procedures should be developed for each intended
application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and
with a full assessment of the working conditions.
Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions.
Physical and chemical properties 9.
Physical state Liquid.
Color Colorless. to Various Colors. (May be dyed Red., Light Green. ,Yellow. )
Odor Petroleum
820 to 875 kg/m
3
(0.82 to 0.875 g/cm
3
) Density
Specific gravity <1 [Water = 1]
Explosion limits Lower: 0.6%
Upper: 7.5%
Auto-ignition temperature 257C (494F)
Viscosity Kinematic: 1.7 to 4.1 mm
2
/s (1.7 to 4.1 cSt) at 40C
Flash point Closed cup: >38C (>100.4F) [Pensky-Martens.]
Solubility negligible <0.1%
10. Stability and reactivity
Stable under recommended storage and handling conditions (see section 7).
Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.
halogenated compounds.
Keep away from heat, sparks and flame. Avoid all possible sources of ignition (spark or flame).
Stability and reactivity
Conditions to avoid
Incompatibility with
various substances
Possibility of hazardous
reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
ENGLISH.
(ENGLISH)
11155
(US-COMP)
carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) Hazardous decomposition
products
Under normal conditions of storage and use, hazardous polymerization will not occur. Hazardous polymerization
11. Toxicological information
Acute toxicity
Classification
Naphthalene 2B Possible -
fuel, diesel no. 2 3 - -
Product/ingredient name NTP IARC OSHA
Aspiration of this product into the lungs can cause chemical pneumonia and can be fatal.
Aspiration into the lungs can occur while vomiting after ingestion of this product. Do not siphon by
mouth.
Middle distillate: From skin-painting studies of petroleum distillates of similar composition and
distillate range, it has been shown that these types of materials often possess weak carcinogenic
activity in laboratory animals. In these tests, the material is painted on the shaved backs of mice
twice a week for their lifetime. The material is not washed off between applications. Therefore,
there may be a potential risk of skin cancer from prolonged or repeated skin contact with this
product in the absence of good personal hygiene. This particular product has not been tested for
carcinogenic activity, but we have chosen to be cautious in light of the findings with other distillate
streams.
Occasional skin contact with this product is not expected to have serious effects, but good
personal hygiene should be practiced and repeated skin contact avoided. This product can also be
expected to produce skin irritation upon prolonged or repeated skin contact. Personal hygiene
measures taken to prevent skin irritation are expected to be adequate to prevent risk of skin
cancer.
Diesel exhaust particulates have been classified by the National Toxicological Program (NTP) to be
a reasonably anticipated human carcinogen. Exposure should be minimized to reduce potential
risk.
Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to
relatively high dose levels, but developmental toxicity was not observed in NTP (National
Toxicology Program) sponsored studies in rats and rabbits. Ingestion or inhalation of naphthalene
can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in
glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of
naphthalene may cause headache and nausea. Airborne exposure can result in eye irritation.
Naphthalene exposure has been associated with cataracts in animals and humans.
Other Toxicity Data
Potential chronic health effects
Carcinogenicity Contains material which may cause cancer, based on animal data. Risk of cancer depends on
duration and level of exposure.
Other information
IARC :
2B - Possible carcinogen to human.
3 - Not classifiable as a human carcinogen.
NTP :
Possible - Reasonably anticipated to be human carcinogens.
Ecological information 12.
Ecotoxicity
Mobility Spillages may penetrate the soil causing ground water contamination.
This product is not expected to bioaccumulate through food chains in the environment. Bioaccumulative potential
No testing has been performed by the manufacturer.
ENGLISH.
(ENGLISH)
11155
(US-COMP)
Other ecological
information
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer
could also be impaired.
13. Disposal considerations
Waste information The generation of waste should be avoided or minimized wherever possible. Empty containers or
liners may retain some product residues. This material and its container must be disposed of in a
safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Disposal of this product, solutions and any by-products should at all times comply with
the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
NOTE: The generator of waste has the responsibility for proper waste identification (based on characteristic(s) or listing),
transportation and disposal
14.
International transport regulations
Transport information
DOT
Classification
IMDG
Classification
Regulatory
information
UN
number
Proper shipping name Class Packing group Additional information
TDG
Classification
IATA/ICAO
Classification
UN 1202
NA 1993
UN 1202 Gas oil
Gas oil
Diesel fuel 3
3
3 III
III
III -
-
Remarks
Marine pollutant
UN 1202 Gas oil 3 III Remarks
Environmentally hazardous
substance mark.
15. Regulatory information
All components are listed or exempted.
U.S. Federal Regulations
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Naphthalene
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: DIESEL FUEL
NO. 2: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard
TSCA 12(b) one-time export: Naphthalene
State regulations
Naphthalene 91-20-3 1.0035 - 3.0111
Naphthalene 91-20-3 1.0035 - 3.0111
SARA 313
Form R - Reporting
requirements
Supplier notification
Concentration CAS number Product name
CERCLA: Hazardous substances.: o-Xylene: 1000 lbs. (454 kg); Naphthalene: 100 lbs. (45.4 kg);
benzo[def]chrysene: 1 lb. (0.454 kg); Ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg);
Cumene: 5000 lbs. (2270 kg); Phenol: 1000 lbs. (454 kg); Benzene: 10 lbs. (4.54 kg); Alkylaryl
sulfonic acid: 1000 lbs. (454 kg); Toluene: 1000 lbs. (454 kg); Methanol: 5000 lbs. (2270 kg); 2-
Butoxyethanol;
CERCLA Sections
102a/103 Hazardous
Substances (40 CFR
Part 302.4):
United States inventory
(TSCA 8b)
ENGLISH.
(ENGLISH)
11155
(US-COMP)
Massachusetts
Substances
The following components are listed: NAPHTHALENE
New Jersey Hazardous
Substances
The following components are listed: DIESEL FUEL; # 2 HEATING OIL; NAPHTHALENE; MOTH
FLAKES
Pennsylvania RTK
Hazardous Substances
The following components are listed: NAPHTHALENE
WARNING: This product contains a chemical known to the State of California to cause cancer.
Naphthalene; Ethylbenzene; benzo[def]chrysene
WARNING: This product contains a chemical known to the State of California to cause birth
defects or other reproductive harm.
Toluene
WARNING: This product contains a chemical known to the State of California to cause cancer and
birth defects or other reproductive harm.
Benzene
California Prop. 65
At least one component is not listed.
Not determined.
Not determined.
Prop 65 chemicals will result under certain conditions from the use of this material. For example,
burning fuels produces combustion products including diesel exhaust, a Prop 65 carcinogen, and
carbon monoxide, a Prop 65 reproductive toxin.
Canada inventory
Europe inventory
China inventory (IECSC)
Japan inventory (ENCS)
Korea inventory (KECI)
Philippines inventory
(PICCS)
Australia inventory (AICS)
Inventories
16. Other information
Label requirements WARNING !
COMBUSTIBLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
HARMFUL IF SWALLOWED.
ASPIRATION HAZARD.
HARMFUL OR FATAL IF LIQUID IS ASPIRATED INTO LUNGS.
INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS, AND NAUSEA, AND MAY
LEAD TO UNCONSCIOUSNESS.
National Fire
Protection
Association (U.S.A.) Health
0
2
1
Fire hazard
Instability
Specific hazard
History
Date of previous issue
Prepared by Product Stewardship
Notice to reader
HMIS Rating :
Physical
Hazard
Flammability
Health * 1
2
0
X Personal
protection
07/20/2010.
07/20/2010.
Date of issue
ENGLISH.
(ENGLISH)
11155
(US-COMP)
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information
contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product
other than for the stated application or applications without seeking advice from us.
It is the users obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP
Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from
any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for
supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the
product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of
any hazards described in this sheet and of any precautions that should be taken.
ENGLISH.
(ENGLISH)
11155
(US-COMP)
Propane
001045
Synthetic/Analytical chemistry.
8/19/2013.
Product name
AIRGAS INC., on behalf of its subsidiaries
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Product use
MSDS #
Date of
Preparation/Revision
In case of emergency
Section 1. Chemical product and company identification
Propane
:
:
:
:
Supplier
1-866-734-3438
Synonym : n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl
hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant.
:
:
Inhalation
Emergency overview
Section 2. Hazards identification
Routes of entry
Potential acute health effects
Acts as a simple asphyxiant.
Contact with rapidly expanding gas may cause burns or frostbite.
Ingestion is not a normal route of exposure for gases
Contact with rapidly expanding gas may cause burns or frostbite.
Eyes
Skin
Inhalation
Ingestion
Physical state Gas. [COLORLESS LIQUEFIED COMPRESSED GAS; ODORLESS BUT MAY HAVE
SKUNK ODOR ADDED.]
See toxicological information (Section 11)
WARNING!
FLAMMABLE GAS.
MAY CAUSE FLASH FIRE.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CONTENTS UNDER PRESSURE.
Keep away from heat, sparks and flame. Do not puncture or incinerate container. May
cause target organ damage, based on animal data. Use only with adequate ventilation.
Keep container closed.
:
:
:
:
:
:
:
Medical conditions
aggravated by over-
exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
:
Contact with rapidly expanding gases can cause frostbite.
Target organs : May cause damage to the following organs: the nervous system, heart, central nervous
system (CNS).
Potential chronic health effects
Chronic effects : May cause target organ damage, based on animal data.
Target organs : May cause damage to the following organs: the nervous system, heart, central nervous
system (CNS).
Page: 1/7
Build 1.1
Propane
Propane 74-98-6 100 ACGIH TLV (United States, 3/2012).
TWA: 1000 ppm 8 hour(s).
NIOSH REL (United States, 1/2013).
TWA: 1800 mg/m 10 hour(s).
OSHA PEL (United States, 6/2010).
OSHA PEL 1989 (United States, 3/1989).
Section 3. Composition, Information on Ingredients
Name % Volume Exposure limits CAS number
As this product is a gas, refer to the inhalation section.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. To avoid the risk of static discharges
and gas ignition, soak contaminated clothing thoroughly with water before removing it.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical
attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present,
the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
450C (842F)
Flammable.
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Closed cup: -104C (-155.2F). Open cup: -104C (-155.2F).
Lower: 2.1% Upper: 9.5%
In case of fire, use water spray (fog), foam or dry chemical.
Extremely flammable in the presence of the following materials or conditions: open
flames, sparks and static discharge and oxidizing materials.
Section 5. Fire-fighting measures
Flammability of the product
Auto-ignition temperature
Flash point
Flammable limits
Products of combustion
Fire hazards in the presence
of various substances
Fire-fighting media and
instructions
In case of fire, allow gas to burn if flow cannot be shut off immediately. Apply water from
a safe distance to cool container and protect surrounding area. If involved in fire, shut
off flow immediately if it can be done without risk.
Contains gas under pressure. Flammable gas. In a fire or if heated, a pressure
increase will occur and the container may burst, with the risk of a subsequent explosion.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
:
:
:
:
:
:
Page: 2/7
Build 1.1
Propane
Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (section 8). Shut off gas supply if this can be done safely.
Isolate area until gas has dispersed.
Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Environmental precautions
Section 6. Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Personal precautions :
Methods for cleaning up :
Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed
until ready for use. Avoid all possible sources of ignition (spark or flame). Segregate
from oxidizing materials. Cylinders should be stored upright, with valve protection cap in
place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures
should not exceed 52 C (125 F).
Use only with adequate ventilation. Use explosion-proof electrical (ventilating, lighting
and material handling) equipment. High pressure gas. Do not puncture or incinerate
container. Use equipment rated for cylinder pressure. Close valve after each use and
when empty. Keep container closed. Keep away from heat, sparks and flame. To avoid
fire, eliminate ignition sources. Protect cylinders from physical damage; do not drag, roll,
slide, or drop. Use a suitable hand truck for cylinder movement.
Section 7. Handling and storage
Handling
Storage
:
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
propane ACGIH TLV (United States, 3/2012).
NIOSH REL (United States, 1/2013).
OSHA PEL (United States, 6/2010).
OSHA PEL 1989 (United States, 3/1989).
Section 8. Exposure controls/personal protection
Engineering controls
Product name
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Personal protection
Eyes
Skin
Respiratory
:
:
:
:
Personal protection in case
of a large spill
: Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the
product.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Hands :
The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93
Page: 3/7
Build 1.1
Propane
Consult local authorities for acceptable exposure limits.
-42C (-43.6F)
-189.7C (-309.5F)
1.6 (Air = 1)
109 (psig)
96.6C (205.9F)
44.11 g/mole
Boiling/condensation point
Melting/freezing point
Section 9. Physical and chemical properties
Molecular weight
Critical temperature
Vapor pressure
Vapor density
C3-H8 Molecular formula
:
:
:
:
:
:
:
Specific Volume (ft
3
/lb) : 8.6206
Gas Density (lb/ft
3
) : 0.116
The product is stable.
Extremely reactive or incompatible with the following materials: oxidizing materials.
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 10. Stability and reactivity
Stability and reactivity
Incompatibility with various
substances
Hazardous decomposition
products
Hazardous polymerization
:
:
:
:
Section 11. Toxicological information
Specific effects
Carcinogenic effects No known significant effects or critical hazards.
Mutagenic effects No known significant effects or critical hazards.
Reproduction toxicity No known significant effects or critical hazards.
No specific information is available in our database regarding the other toxic effects of
this material to humans.
May cause damage to the following organs: the nervous system, heart, central nervous
system (CNS).
Chronic effects on humans
Other toxic effects on
humans
:
:
Toxicity data
:
:
:
IDLH : 2100 ppm
propane LC50 Inhalation
Gas.
Rat >800000 ppm 15 minutes
Product/ingredient name Result Species Dose Exposure
Section 12. Ecological information
Environmental fate : Not available.
Environmental hazards : This product shows a low bioaccumulation potential.
Toxicity to the environment : Not available.
Aquatic ecotoxicity
Not available.
Products of degradation: carbon oxides (CO, CO2) and water. : Products of degradation
Page: 4/7
Build 1.1
Propane
Section 13. Disposal considerations
Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local
regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.
Section 14. Transport information
2.1 Limited
quantity
Yes.
Packaging
instruction
Passenger
aircraft
Quantity
limitation:
Forbidden.
Cargo aircraft
Quantity
limitation:
150 kg
Special
provisions
19, T50
DOT Classification
TDG Classification 2.1
PROPANE
UN1978 PROPANE
Regulatory
information
UN number Proper shipping
name
Class Packing group Label Additional
information
UN1978
Explosive
Limit and
Limited
Quantity
Index
0.125
ERAP Index
3000
Passenger
Carrying Ship
Index
65
Passenger
Carrying
Road or Rail
Index
Forbidden
Special
provisions
29, 42
Mexico
Classification
UN1978 PROPANE 2.1 -
Not applicable (gas).
Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.
Page: 5/7
Build 1.1
Propane
Section 15. Regulatory information
U.S. Federal regulations
Connecticut Carcinogen Reporting: This material is not listed.
Connecticut Hazardous Material Survey: This material is not listed.
Florida substances: This material is not listed.
Illinois Chemical Safety Act: This material is not listed.
Illinois Toxic Substances Disclosure to Employee Act: This material is not listed.
Louisiana Reporting: This material is not listed.
Louisiana Spill: This material is not listed.
Massachusetts Spill: This material is not listed.
Massachusetts Substances: This material is listed.
Michigan Critical Material: This material is not listed.
Minnesota Hazardous Substances: This material is not listed.
New Jersey Hazardous Substances: This material is listed.
New Jersey Spill: This material is not listed.
New Jersey Toxic Catastrophe Prevention Act: This material is not listed.
New York Acutely Hazardous Substances: This material is not listed.
New York Toxic Chemical Release Reporting: This material is not listed.
Pennsylvania RTK Hazardous Substances: This material is listed.
Rhode Island Hazardous Substances: This material is not listed.
TSCA 8(a) IUR: Not determined
United States inventory (TSCA 8b): This material is listed or exempted.
Clean Air Act (CAA) 112 regulated flammable substances: propane
State regulations
CEPA Toxic substances: This material is not listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.
WHMIS (Canada) Class A: Compressed gas.
Class B-1: Flammable gas.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: propane
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
propane: Fire hazard, Sudden release of pressure
:
:
:
Canada
United States
Propane
Clean Air Act (CAA) 112 accidental release prevention - Flammable Substances:
Section 16. Other information
FLAMMABLE GAS.
MAY CAUSE FLASH FIRE.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CONTENTS UNDER PRESSURE.
Label requirements :
Label requirements : Class A: Compressed gas.
Class B-1: Flammable gas.
United States
Canada
Page: 6/7
Build 1.1
Propane
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
0
4
2
National Fire Protection
Association (U.S.A.)
Health
Special
Instability
Flammability
:
Hazardous Material
Information System (U.S.A.)
1
4
2
*
Health
Flammability
Physical hazards
:
Page: 7/7
Build 1.1
p. 1
1
1
0
He a lt h
Fire
Re a c t iv it y
Pe rs o na l
Pro t e c t io n
1
1
0
H
Diethylene glycol MSDS
Section 1: Chemical Product and Company Identification
Product Name: Diethylene glycol
Catalog Codes: SLD3151
CAS#: 111-46-6
RTECS: ID5950000
TSCA: TSCA 8(b) inventory: Diethylene glycol
CI#: Not applicable.
Synonym: Carbitol
Chemical Name: 2,2'-Oxydiethanol
Chemical Formula: C4H10O3
Contact Information:
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396
US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Diethylene glycol 111-46-6 100
Toxicological Data on Ingredients: Diethylene glycol: ORAL (LD50): Acute: 12565 mg/kg [Hamster.]. DERMAL (LD50):
Acute: 11890 mg/kg [Hamster.].
Section 3: Hazards Identification
Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion,
of inhalation.
Potential Chronic Health Effects:
Hazardous in case of skin contact (irritant, permeator), of ingestion. Slightly hazardous in case of eye contact (irritant).
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to blood, kidneys, the nervous system, liver. Repeated or
prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
p. 2
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before
reusing.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: 227.78C (442F)
Flash Points: CLOSED CUP: 138C (280.4F). OPEN CUP: 143C (289.4F) (Cleveland).
Flammable Limits: LOWER: 2% UPPER: 12.3%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks,
of heat.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: When heated to decomposition, it emits acrid smoke and irritating fumes.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
Section 7: Handling and Storage
Precautions:
p. 3
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Wear suitable
protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing
agents.
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid. (Clear viscous liquid.)
Odor: Odorless.
Taste: Sweet.
Molecular Weight: 106.12 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 245.8C (474.4F)
Melting Point: -8C (17.6F)
Critical Temperature: Not available.
Specific Gravity: 1.12 (Water = 1)
Vapor Pressure: 0.01 mm of Hg (@ 20C)
Vapor Density: 3.66 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether.
Solubility: Easily soluble in cold water, hot water, methanol, diethyl ether.
Section 10: Stability and Reactivity Data
p. 4
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Slightly reactive to reactive with oxidizing agents.
Corrosivity: Not considered to be corrosive for metals and glass.
Special Remarks on Reactivity: Hygroscopic; keep container tightly closed.
Special Remarks on Corrosivity: Not available.
Polymerization: No.
Section 11: Toxicological Information
Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
Acute oral toxicity (LD50): 12565 mg/kg [Hamster.]. Acute dermal toxicity (LD50): 11890 mg/kg [Hamster.].
Chronic Effects on Humans: The substance is toxic to blood, kidneys, the nervous system, liver.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Experimentally tumorigen by inhalation. Exposure can cause nausea,
headache and vomiting.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Section 14: Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
Section 15: Other Regulatory Information
p. 5
Federal and State Regulations:
Pennsylvania RTK: Diethylene glycol TSCA 8(b) inventory: Diethylene glycol
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC): R36/38- Irritating to eyes and skin.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 1
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
Section 16: Other Information
References:
-SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -Hawley, G.G.. The
Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.
Other Special Considerations: Not available.
Created: 10/11/2005 11:48 AM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 1
2
2
0
He a lt h
Fire
Re a c t iv it y
Pe rs o na l
Pro t e c t io n
2
2
0
H
2-Butoxyethanol MSDS
Section 1: Chemical Product and Company Identification
Product Name: 2-Butoxyethanol
Catalog Codes: SLB1600
CAS#: 111-76-2
RTECS: KJ8575000
TSCA: TSCA 8(b) inventory: 2-Butoxyethanol
CI#: Not available.
Synonym: Butyl Cellosolve; Ethylene glycol monobutyl
ether
Chemical Name: 2-Butoxyethanol
Chemical Formula: C6H14O2
Contact Information:
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396
US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
{2-}Butoxyethanol 111-76-2 100
Toxicological Data on Ingredients: 2-Butoxyethanol: ORAL (LD50): Acute: 1230 mg/kg [Mouse]. 470 mg/kg [Rat]. DERMAL
(LD50): Acute: 220 mg/kg [Rabbit]. VAPOR (LC50): Acute: 700 ppm 7 hours [Mouse].
Section 3: Hazards Identification
Potential Acute Health Effects:
Hazardous in case of skin contact (permeator), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of
skin contact (irritant). Severe over-exposure can result in death.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to blood, kidneys,
liver, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.
Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many
human organs.
Section 4: First Aid Measures
p. 2
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Combustible.
Auto-Ignition Temperature: 244C (471.2F)
Flash Points: CLOSED CUP: 61C (141.8F). (Setaflash) OPEN CUP: 69.4C (156.9F) (TAG).
Flammable Limits: LOWER: 1.1% UPPER: 12.7%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
p. 3
Combustible material. Poisonous liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.
Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers,
basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, alkalis.
Storage:
Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible
sources of ignition (spark or flame).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 20 (ppm) from ACGIH (TLV) [United States] SKIN TWA: 24 (mg/m3) from NIOSH TWA: 5 (ppm) from NIOSH TWA:
240 (mg/m3) from OSHA (PEL) [United States] TWA: 50 (ppm) from OSHA (PEL) [United States]Consult local authorities for
acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid.
Odor: Ethereal. Pleasant. (Slight.)
Taste: Not available.
Molecular Weight: 118.18 g/mole
Color: Colorless.
pH (1% soln/water): Not available.
Boiling Point: 171.5C (340.7F)
Melting Point: -70C (-94F)
Critical Temperature: 367.78C (694F)
Specific Gravity: 0.9012 (Water = 1)
Vapor Pressure: 0.1 kPa (@ 20C)
Vapor Density: 4.07 (Air = 1)
p. 4
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 0.8
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility:
Soluble in diethyl ether. Partially soluble in cold water.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact. Inhalation.
Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 470 mg/kg [Rat]. Acute dermal toxicity (LD50): 220 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 450 4
hours [Rat].
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: blood, kidneys,
liver, central nervous system (CNS).
Other Toxic Effects on Humans:
Hazardous in case of skin contact (permeator), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects (maternal and paternal fertility, fetoxicity) based on animal data. May cause birth
defects (teratogenic) based on animal data. May cause cancer (tumorigenic) based on animal data.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. Penetrates intact skin easily and can cause systemic effects
and central nervous system depression (see inhalation). Eyes: Causes eye irritation. Inhalation: May cause irritation of
the respiratory tract. May affect behavior (analgesia), behavior/central nervous system (headache, drowsiness, dizzness,
stuttering, coma, weakness, ataxia, slurred speech, loss of coordination and judgement, personality changes, analgesia,
blurred vision, tremor, excitement, somnolence), sense organs, the gastrointestinal tract (nausea, vomiting), metabolism
(metabolic acidosis), respiration (dyspnea), urinary system (kidneys - hematuria, albuminuria, polyuria, oliguria, renal failure),
liver (liver damage). Exposure to high vapor concentration may also cause corneal or lens opacity of the eyes. Ingestion:
Causes gastrointestinal tract irritation with nausea, vomiting, diarrhea. May affect behavior/central nervous system (see
inhalation), respiration (dyspnea), metabolism, cardiovascular system. Chronic Potential Health Effects: Inhalation and
p. 5
Ingestion: Prolonged or repeated inhalation or ingestion may affect the liver, blood (changes in red blood cell count, pigmented
or nucleated red blood cells, microcytosis with or without anemia, erythropenia, reticulocytosis, granulocytosis, leukocytosis),
urinary system (kidneys -hematuria), metabolism (weight loss), endocrine system (spleen, thymus, pancreas). Prolonged or
repeated inhalation of high concentrations may also cause lung hemmorrhage, congestion, bronchopneumonia.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: CLASS 6.1: Poisonous material.
Identification: : Toxic Liquid, organic, n.os.(Ethylene Glycol Monobutyl Ether) UNNA: 2810 PG: III
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:
Illinois toxic substances disclosure to employee act: 2-Butoxyethanol Rhode Island RTK hazardous substances: 2-
Butoxyethanol Pennsylvania RTK: 2-Butoxyethanol Florida: 2-Butoxyethanol Minnesota: 2-Butoxyethanol Massachusetts RTK:
2-Butoxyethanol Massachusetts spill list: 2-Butoxyethanol New Jersey: 2-Butoxyethanol California Director's list of Hazardous
Substances: 2-Butoxyethanol TSCA 8(b) inventory: 2-Butoxyethanol TSCA 8(d) H and S data reporting: 2-Butoxyethanol:
Effective Date: 4/13/89; Sunset Date: 6/30/98
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS B-3: Combustible liquid with a flash point between 37.8C (100F) and 93.3C (200F). CLASS D-1A: Material causing
immediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 2
Reactivity: 0
p. 6
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 2
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/09/2005 04:27 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
Aluminum phosphate, 99%
ACC# 95615
Section 1 - Chemical Product and Company Identification
MSDS Name: Aluminum phosphate, 99%
Catalog Numbers: AC299820000
Synonyms: Aluminophosphoric acid; Aluminum acid phosphate; Aluminum
monophosphate; Aluminum phosphate.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7784-30-7 Aluminum phosphate 99.0 232-056-9

Hazard Symbols: C
Risk Phrases: 34
Section 3 - Hazards Identification

EMERGENCY OVERVIEW
Appearance: white solid. Danger! Causes eye and skin burns. May cause severe
respiratory tract irritation with possible burns. May cause severe digestive tract
irritation with possible burns.
Target Organs: Eyes, skin, mucous membranes.

Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns.
Ingestion: May cause severe and permanent damage to the digestive tract. May
cause severe gastrointestinal tract irritation with nausea, vomiting and possible
burns.
Inhalation: May cause irritation of the respiratory tract with burning pain in the
nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Causes chemical burns to the respiratory tract.
Chronic: No information found.
Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT
allow victim to rub or keep eyes closed. Extensive irrigation with water is required
(at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an unconscious person.
Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
If breathing has ceased apply artificial respiration using oxygen and a suitable
mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Antidote: None reported.
Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media: Use dry chemical to fight fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then
place in suitable container. Wash area with soap and water. Clean up spills
immediately, observing precautions in the Protective Equipment section. Provide
ventilation.
Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate
ventilation. Use only in a chemical fume hood. Discard contaminated shoes.
Storage: Keep container closed when not in use. Store in a tightly closed container.
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Aluminum phosphate none listed none listed none listed

OSHA Vacated PELs: Aluminum phosphate: No OSHA Vacated PELs are listed for
this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or
European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Always use a NIOSH or European Standard EN 149
approved respirator when necessary.
Section 9 - Physical and Chemical Properties

Physical State: Solid
Appearance: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:> 1500 deg C
Decomposition Temperature:Not available.
Solubility: insoluble
Specific Gravity/Density:Not available.
Molecular Formula:AlO4P
Molecular Weight:121.95
Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Dust generation.
Incompatibilities with Other Materials: Metals.
Hazardous Decomposition Products: Phosphine, oxides of phosphorus, aluminum
oxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information

RTECS#:
CAS# 7784-30-7: TB6450000
LD50/LC50:
CAS# 7784-30-7:
Oral, mouse: LD50 = >5 gm/kg;
Skin, rabbit: LD50 = >4640 mg/kg;<BR.

Carcinogenicity:
CAS# 7784-30-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: No data available.
Section 12 - Ecological Information

No information available.
Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is
classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must
consult state and local hazardous waste regulations to ensure complete and accurate
classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information

US DOT IATA RID/ADR IMO
Canada
TDG
Shipping
Name:
No
information
available.

No
information
available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7784-30-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2
Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the
CWA. None of the chemicals in this product are listed as Priority Pollutants under the
CWA. None of the chemicals in this product are listed as Toxic Pollutants under the
CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7784-30-7 can be found on the following state right to know lists: New Jersey.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.

Safety Phrases:
S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)
CAS# 7784-30-7: No information available.
Canada - DSL/NDSL
CAS# 7784-30-7 is listed on Canada's DSL List.
Canada - WHMIS
This product does not have a WHMIS classification.
Canadian Ingredient Disclosure List
Exposure Limits
CAS# 7784-30-7: OEL-AUSTRALIA:TWA 2 mg(Al)/m3 OEL-BELGIUM:TWA 2 mg(
Al)/m3 OEL-DENMARK:TWA 2 mg(Al)/m3 OEL-FRANCE:TWA 2 mg(Al)/m3 OEL-T
HE NETHERLANDS:TWA 2 mg(Al)/m3 OEL-RUSSIA:TWA 2 mg(Al)/m3 OEL-SWEDEN
:TWA 2 mg(Al)/m3 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 OEL-UNITED KINGDOM:
TWA 2 mg(Al)/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH
TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
Section 16 - Additional Information

MSDS Creation Date: 3/01/1999
Revision #2 Date: 1/29/2003

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential
or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Material Safety Data Sheet Date of preparation: 8/20/91
For Printing Inks and related Materials Updated: 6/02
MSDS Number: 148

I. PRODUCT IDENTIFICATION
Manufacturer: Gans Ink and Supply Co, Inc.
Address: 1441 Boyd Street
Los Angeles, CA 90033

Emergency phone: (323) 264-2200
HMIS HAZARD IDENTIFICATION
Health 1

Flammability 0

Reactivity 0

Product Class: Lithographic Printing Ink Manufacturers code: Various
Trade Name: Stallion Black A103091. SF SoyPlus Inks except Reflex blue &
SoyPlus blends containing Reflex blue (see MSDS 148.1)

II. HAZARDOUS INGREDIENTS
Material CAS # % Exposure Limits Units

Non-hazardous
(Per 29 CFR 1910.1200)

III. PHYSICAL DATA
Boiling Range, F: N/A Vapor Density (Air = 1): N/A
Relative Density (H
2
O = 1): 1-1.19 Vapor Pressure (mm Hg @ 70F): 0
Material Density Lbs./Gal: 8.4-9.95 Solubility in Water: Insoluble
%Volatiles by Weight: less than 1% % Solids by Weight: greater than 99%
VOC Lbs/Gal: less than 0.09 (VOC) Appearance/Odor: colored oily paste

IV. FIRE AND EXPLOSION DATA
Flash Point: N/A Auto-ignition Temperature: N/A
Flammable Limits in Air Lower Limit: N/A Upper Limit: N/A
Extinguishing Media: Use water fog, foam, CO2, or dry chemical extinguishing media.

Special Fire Fighting Procedures: Water may be ineffective, but can be used to cool
containers exposed to heat or flame.

Unusual Fire & Explosion Hazard: Dense smoke may be generated while burning;
carbon dioxide, carbon monoxide, and other oxides may be generated as products of
combustion.

V. HEALTH HAZARD INFORMATION
1
Effects of Overexposure
Inhalation: This product has a low vapor pressure and is not expected to present an
inhalation hazard at ambient conditions. Caution should be taken to prevent
aerosolization or misting of this product. The threshold limit value (TLV) for this
product as oil mist is 5 mg/M
3
. Exposures below 5 mg/M
3
appear to be without
significant health risk. Acute overexposure may result in irritation of the throat and
lungs. Chronic exposure to high-concentrations of aerosols or mists to laboratory
animals has resulted in non-specific symptoms related to the nervous system,
gastrointestinal tract, and lungs.
Skin Contact: Avoid skin contact. This product in non-irritation to the skin upon direct
contact. Prolonged or repeated contact may result in contact dermatitis which is
characterized by dryness, chapping, and reddening. This condition may make the skin
more susceptible to other irritants, sensitizers, and disease. Pre-existing skin conditions
may make the skin more susceptible and facilitate uptake by this route.
Eye Contact: Avoid eye contact. This product may be slightly irritating to the eyes
upon direct contact. This product has a low vapor pressure and is not expected to present
a hazard to the eyes at ambient conditions. Exposure to high concentrations of vapors
may be irritations to the eyes.
Ingestion: Do not ingest. Ingestion of small quantities is usually nonfatal unless
aspiration occurs. Severe oral intoxication will lead to intense burning of the throat and
may result in drowsiness, dullness, numbness, and headache followed by dizziness,
weakness, and nausea. Loss of consciousness and convulsions followed by death may
result. See Notes to Physician section below.
Emergency & First Aid Procedures
Eyes: Immediately flush eyes with large amounts of water and continue flushing for 15
minutes until irritation subsides. If irritation persists, seek medical attention.

Skin: Remove contaminated clothing. Wash contaminated area thoroughly with soap
and water. If redness or irritation occurs, seek medical attention.

Inhalation: This material has a low vapor pressure and is not expected to present an
inhalation exposure at ambient conditions. If mist or exposure is generated when the
material is heated or handle, remove victim from exposure. If breathing has stopped or is
irregular, administer artificial respiration and supply oxygen if it is available. If victim is
unconscious, remove to fresh air and seek medical attention.
Ingestion: Do not induce vomiting. Seek immediate medical attention.

Notes to Physician: Aspiration may lead to chemical pneumonitis which is characterized
by pulmonary edema and hemorrhage, and may be fatal. Signs of lung involvement
include increased respiration rate, increased heart rate, and a bluish discoloration of the
skin. Coughing, choking, and gagging are often noted at the time if aspiration.
Gastrointestinal discomfort may develop, followed by vomiting, with risk of aspiration.

VI. REACTIVITY INFORMATION
2
Stability (Thermal, Light, etc.): Stable

Conditions to avoid: Excessive heat and
contact with strong oxidizers.
Hazardous Polymerization: Will no
occur.
Conditions to avoid:
Hazardous Decomposition Products: : CO
2
, CO, and other oxides may be generated as
products of combustion.

VII. ENVIRONMENTAL PRECAUTIONS
Steps to be taken in event of spill or release: Scrape up with trowel or scoop and place
in a suitable container. Clean up with a suitable solvent.

Waste Disposal Method: If recycling as ink is not possible, material may be incinerated
or landfilled at a licensed facility in accordance with local, state, and federal regulations.

VIII. SPECIAL PROTECTION INFORMATION
Ventilation Requirements: If vapor or mist is generated when the material is heated or
handled, adequate ventilation in accordance with good engineering practice must be
provided to maintain concentrations below the specific exposure or flammable limits.
Personal Protective Equipment
Respirator: Respiratory protection is not required under conditions of normal use. If
vapor or mist in generated when the material is heated or handled, use an organic vapor
respirator with a dust and mist filter. All respirators must be NIOSH certified. Do not
use compressed oxygen in hydrocarbon atmospheres.
Skin: No skin protection is required for single, short duration exposures. For prolonged
exposures, use impervious synthetic rubber clothing (boots, gloves, etc.) over parts of the
body subject to exposure.

Eye: Eye protection is not required under conditions of normal use. If material is
handled such that it could be splashed into eyes, wear plastic face or splash-proof safety
goggles.

IX. Special Precautions
Handling and Storage: Store in containers in a cool, well-ventilated area. Consumption
of food and beverages should be avoided in work areas where hydrocarbons are present.
Always wash hands and face with soap and water before eating, drinking, and smoking.

Other Precautions: For industrial use only. Do not ingest. Avoid prolonged contact
with skin, contact with eyes, and breathing of mist or vapor.

X. SHIPPING DATA
Flammability Classification
3

OSHA: Class III B

DOT: Not Regulated

XI. ADDITIONAL NOTES
SARA Title III Section 313:
This material may contain chemicals subject to the reporting requirements of the
Superfund Amendments and Reauthorization ACT (SARA). Please refer to Gans
supplier notification letter dated 3/1/89.

The data on this MSDS are based on the information furnished by our raw material suppliers; consequently,
Gans Ink and Supply Co, Inc. cannot guarantee its accuracy, nor assume liability of any kind.
4
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

SUBSTANCE: CHLORINE

TRADE NAMES/SYNONYMS:
MTG MSDS 22; CHLORINE MOLECULAR; DIATOMIC CHLORINE; DICHLORINE; MOLECULAR
CHLORINE; UN 1017; Cl2; MAT04600; RTECS FO2100000

CHEMICAL FAMILY: halogens, gas

CREATION DATE: Jan 24 1989
REVISION DATE: Dec 16 2002

SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENT: CHLORINE
CAS NUMBER: 7782-50-5
PERCENTAGE: 100.0

SECTION 3 HAZARDS IDENTIFICATION
NFPA RATINGS (SCALE 0-4): HEALTH=4 FIRE=0 REACTIVITY=0

EMERGENCY OVERVIEW:
COLOR: yellow or green
PHYSICAL FORM: gas
ODOR: distinct odor, irritating odor
MAJOR HEALTH HAZARDS: harmful if inhaled, respiratory tract burns, skin burns, eye burns
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat. May ignite combustibles.

POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: burns, chest pain, difficulty breathing, headache, dizziness, hyperactivity,
emotional disturbances, bluish skin color, lung damage, death
LONG TERM EXPOSURE: burns, skin disorders, lack of sense of smell, lung damage
SKIN CONTACT:
SHORT TERM EXPOSURE: burns
LONG TERM EXPOSURE: burns
EYE CONTACT:
MATHESON TRI-GAS, INC. EMERGENCY CONTACT:
959 ROUTE 46 EAST CHEMTREC 1-800-424-9300
PARSIPPANY, NEW JERSEY 07054-0624 INFORMATION CONTACT:
973-257-1100
SHORT TERM EXPOSURE: burns
LONG TERM EXPOSURE: burns
INGESTION:
SHORT TERM EXPOSURE: ingestion of harmful amounts is unlikely
LONG TERM EXPOSURE: ingestion of harmful amounts is unlikely

SECTION 4 FIRST AID MEASURES
INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not
breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate
medical attention.

SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing and
shoes before reuse. Destroy contaminated shoes.

EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate
medical attention.

INGESTION: Contact local poison control center or physician immediately. Never make an unconscious
person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting
occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get
medical attention immediately.

NOTE TO PHYSICIAN: For inhalation, consider oxygen. Avoid gastric lavage or emesis.

SECTION 5 FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Oxidizer. May ignite or explode on contact
with combustible materials.

EXTINGUISHING MEDIA: water

Do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Large fires: Flood with fine
water spray.

FIRE FIGHTING: Move container from fire area if it can be done without risk. Cool containers with water
spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: If
this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area
and deny entry. Let the fire burn. For small fires, contain and let burn. Use extinguishing agents appropriate
for surrounding fire. Cool containers with water spray until well after the fire is out. Apply water from a
protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay
upwind and keep out of low areas. Evacuation radius: 800 meters (1/2 mile).

SECTION 6 ACCIDENTAL RELEASE MEASURES
AIR RELEASE:
Reduce vapors with water spray. Collect runoff for disposal as potential hazardous waste.

SOIL RELEASE:
Dig holding area such as lagoon, pond or pit for containment. Dike for later disposal. Trap spilled material at
bottom in deep water pockets, excavated holding areas or within sand bag barriers. Absorb with sand or other
non-combustible material. Add an alkaline material (lime, crushed limestone, sodium bicarbonate, or soda
ash).

WATER RELEASE:
Add an alkaline material (lime, crushed limestone, sodium bicarbonate, or soda ash). Absorb with activated
carbon. Collect spilled material using mechanical equipment.

OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Avoid contact with combustible materials. Keep unnecessary
people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Notify Local
Emergency Planning Committee and State Emergency Response Commission for release greater than or
equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA
Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).

SECTION 7 HANDLING AND STORAGE
STORAGE: Store and handle in accordance with all current regulations and standards. Protect from
physical damage. Keep separated from incompatible substances. Store outside or in a detached building.
Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the
TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to
participate in local emergency response planning (U.S. EPA 40 CFR 355.30).

SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE LIMITS:
CHLORINE:
1 ppm (3 mg/m3) OSHA ceiling
0.5 ppm (1.5 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
1 ppm (3 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993)
0.5 ppm ACGIH TWA
1 ppm ACGIH STEL
0.5 ppm (1.45 mg/m3) NIOSH recommended ceiling 15 minute(s)

VENTILATION: Provide local exhaust or process enclosure ventilation system. Ensure compliance with
applicable exposure limits.

EYE PROTECTION: Wear splash resistant safety goggles with a faceshield. Provide an emergency eye
wash fountain and quick drench shower in the immediate work area.

CLOTHING: Wear appropriate chemical resistant clothing.

GLOVES: Wear appropriate chemical resistant gloves.

RESPIRATOR: The following respirators and maximum use concentrations are drawn from NIOSH and/or
OSHA.
5 ppm
Any chemical cartridge respirator with cartridge(s) providing protection against this substance.
Any supplied-air respirator.
10 ppm
Any supplied-air respirator operated in a continuous-flow mode.
Any powered, air-purifying respirator with cartridge(s) providing protection against this substance.
Any chemical cartridge respirator with a full facepiece and cartridge(s) providing protection against this
substance.
Any air-purifying respirator with a full facepiece and a canister providing protection against this substance.
Any self-contained breathing apparatus with a full facepiece.
Any supplied-air respirator with a full facepiece.
Escape -
Any air-purifying respirator with a full facepiece and a canister providing protection against this substance.
Any appropriate escape-type, self-contained breathing apparatus.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure
mode in combination with a separate escape supply.
Any self-contained breathing apparatus with a full facepiece.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: gas
COLOR: yellow or green
ODOR: distinct odor, irritating odor
MOLECULAR WEIGHT: 70.906
MOLECULAR FORMULA: Cl2
BOILING POINT: -31 F (-35 C)
FREEZING POINT: -150 F (-101 C)
VAPOR PRESSURE: 5168 mmHg @ 21 C
VAPOR DENSITY (air=1): 2.49
SPECIFIC GRAVITY: Not applicable
DENSITY: 3.214 g/L @ 0 C
WATER SOLUBILITY: 1.46% @ 0 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: 0.01 ppm
EVAPORATION RATE: Not applicable
VISCOSITY: 0.01327 cP @ 20 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: alkali

SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: Stable at normal temperatures and pressure.

CONDITIONS TO AVOID: Avoid contact with combustible materials. Minimize contact with material.
Avoid inhalation of material or combustion by-products. Keep out of water supplies and sewers.

INCOMPATIBILITIES: combustible materials, bases, metals, halogens, metal salts, reducing agents,
amines, metal carbide, metal oxides, oxidizing materials, halo carbons, acids

HAZARDOUS DECOMPOSITION:
Thermal decomposition products: chlorine

POLYMERIZATION: Will not polymerize.

SECTION 11 TOXICOLOGICAL INFORMATION
CHLORINE:
TOXICITY DATA:
293 ppm/1 hour(s) inhalation-rat LC50
CARCINOGEN STATUS: ACGIH: A4 -Not Classifiable as a Human Carcinogen
LOCAL EFFECTS:
Corrosive: inhalation, skin, eye
ACUTE TOXICITY LEVEL:
Toxic: inhalation
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: heart problems
TUMORIGENIC DATA: Available.
MUTAGENIC DATA: Available.
REPRODUCTIVE EFFECTS DATA: Available.

SECTION 12 ECOLOGICAL INFORMATION
ECOTOXICITY DATA:
FISH TOXICITY: 390 ug/L 96 hour(s) LC50 (Mortality) Orangethroat darter (Etheostoma spectabile)

INVERTEBRATE TOXICITY: 637.5 ug/L 1 hour(s) LC50 (Mortality) Pacific oyster (Crassostrea gigas)

ALGAL TOXICITY: 50-1000 ug/L 23 hour(s) (Population) Algae,phytoplankton,algal mat (Algae)

PHYTOTOXICITY: 20 ug/L 96 day(s) (Growth) Water-milfoil (Myriophyllum spicatum)

SECTION 13 DISPOSAL CONSIDERATIONS
Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Dispose in
accordance with all applicable regulations.

SECTION 14 TRANSPORT INFORMATION
U.S. DOT 49 CFR 172.101:
PROPER SHIPPING NAME: Chlorine
ID NUMBER: UN1017
HAZARD CLASS OR DIVISION: 2.3
LABELING REQUIREMENTS: 2.3; 8
ADDITIONAL SHIPPING DESCRIPTION: Toxic-Inhalation Hazard Zone B

CANADIAN TRANSPORTATION OF DANGEROUS GOODS:
SHIPPING NAME: Chlorine
ID NUMBER: UN1017
CLASSIFICATION: 2.3, 8

SECTION 15 REGULATORY INFORMATION
U.S. REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4):
CHLORINE: 10 LBS RQ

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30):
CHLORINE: 100 LBS TPQ

SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40):
CHLORINE: 10 LBS RQ

SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: Yes
CHRONIC: No
FIRE: No
REACTIVE: No
SUDDEN RELEASE: Yes

SARA TITLE III SECTION 313 (40 CFR 372.65):
CHLORINE

OSHA PROCESS SAFETY (29CFR1910.119):
CHLORINE: 1500 LBS TQ

STATE REGULATIONS:
California Proposition 65: Not regulated.

CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: ACD1E

NATIONAL INVENTORY STATUS:
U.S. INVENTORY (TSCA): Listed on inventory.

TSCA 12(b) EXPORT NOTIFICATION: Not listed.

CANADA INVENTORY (DSL/NDSL): Not determined.

SECTION 16 OTHER INFORMATION
MSDS SUMMARY OF CHANGES
SECTION 15 REGULATORY INFORMATION

Copyright 1984-2002 MDL Information Systems, Inc. All rights reserved.

MATHESON TRI-GAS, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES,
GUARANTEES OR REPRESENTATIONS REGARDING THE PRODUCT OR THE
INFORMATION HEREIN, INCLUDING BUT NOT LIMITED TO ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR USE. MATHESON TRI-GAS, INC. SHALL NOT BE
LIABLE FOR ANY PERSONAL INJURY, PROPERTY OR OTHER DAMAGES OF ANY
NATURE, WHETHER COMPENSATORY, CONSEQUENTIAL, EXEMPLARY, OR
OTHERWISE, RESULTING FROM ANY PUBLICATION, USE OR RELIANCE UPON THE
INFORMATION HEREIN.
Varn International, Inc., a Flint Group Company
14909 N. Beck Road
Plymouth, MI 48180
For Product Questions call: (800) 336-VARN(8276)
For Health and Safety Questions call: (800) 336-VARN(8276)
After Hours Emergency Health/Safety Questions: (800) 391-0698 Prosar (US/Canada)
24 Hour Emergency Spill Contact call: (800) 424-9300 Chemtrec (US/Canada)
I. PRODUCT AND COMPANY IDENTIFICATION
Product Name: ECOLO WASH 100
Product Code: 650-B011025
MSDS Code: MSD-B011025
Revision Number: 2
Revision Date: 2012-04-03 11:17:02
II. COMPOSITION/INFORMATION ON INGREDIENTS
CAS# Chemical Name %
111-76-2 Ethylene glycol mono-n-butyl ether 5 - 10
Please see Section VIII for product and component exposure guidelines.
Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard
Communication Standard).
III. HAZARDS IDENTIFICATION
HMIS Rating Health: 2 Flammability: 2 Reactivity: 0

This product falls under the following WHMIS class:
D1A
D2B
B3
Routes of Entry: Inhalation, Ingestion, Skin contact, Eye contact
Target Organs: Kidneys, Liver, Skin, Blood, Eyes
Medical Conditions
Aggravated:
Kidney disease, Liver disease, Skin disease including eczema and sensitization,
Eye disease
Immediate (Acute) Health Effects by Route of Exposure
Inhalation: Can cause minor respiratory irritation. Harmful! Can cause systemic damage.
Skin Contact: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
permanent damage. Harmful if absorbed through the skin.
Eye Contact: Can cause moderate/severe irritation, tearing and reddening, but not likely to
permanently injure eye tissue. Temporary vision impairment (cloudy or blurred
vision) is possible.
Ingestion: May be mildly irritating to the mouth, throat and stomach. Harmful if swallowed.
May cause systemic poisoning.
Long-Term (Chronic) Health Effects
Reproductive and
Developmental:
No data available to indicate product or any components present at greater than
0.1% may cause birth defects.
Mutagenicity: No data available to indicate product or any components present at greater than
0.1% is mutagenic or genotoxic.
ECOLO WASH 100
Page 1 of 5
Inhalation: Upon prolonged and/or repeated exposure, can cause minor respiratory
irritation, dizziness, weakness, fatigue, nausea, and headache.
Skin Contact: Upon prolonged or repeated contact, can cause moderate skin irritation,
defatting, and dermatitis. Not likely to cause permanent damage. Upon
prolonged or repeated exposure, harmful if absorbed through the skin. May
cause severe irritation and systemic damage.
Ingredients of this product appear on the following OSHA identified carcinogen lists at >= 0.1% by
weight (yes/no):
OSHA No NTP No IARC 1 & 2A No NIOSH No
IARC 2B No
IV. FIRST-AID MEASURES
Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen.
Eyes: Immediately flush eyes with plenty of water for at least 20 minutes retracting
eyelids often. Tilt the head to prevent chemical from transferring to the
uncontaminated eye. Get immediate medical attention and monitor the eye as
advised by your physician.
Skin Contact: Wash with soap and water. Remove contaminated clothing and launder. Get
medical attention if irritation develops or persists.
Ingestion: No hazard in normal industrial use. Do not induce vomiting. Seek medical
attention if symptoms develop. Provide medical care provider with this MSDS.
V. FIRE FIGHTING MEASURES
Flammability
Summary:
Combustible NFPA IIIA (NFPA description only; not to be used for shipping
purposes)
Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry chemical, or water spray when
fighting fires. Water or foam may cause frothing if liquid is burning but it still may
be a useful extinguishing agent if carefully applied to the fire. Do not direct a
water stream directly into the hot burning liquid.
Fire and/or Explosion
Hazards:
Material may be ignited if preheated to temperatures above the flash point in the
presence of a source of ignition.
Fire Fighting
Methods and
Protection:
Do not enter fire area without proper protection including self-contained
breathing apparatus and full protective equipment. Fight fire from a safe
distance and a protected location due to the potential of hazardous vapors and
decomposition products.
Hazardous
Combustion
Products:
Carbon dioxide, Carbon monoxide
Flash Point: >60 C (140 F) - < 93 C (200 F)
Firepoint: Firepoint not determined.
VI. ACCIDENTAL RELEASE MEASURES
Personal Precautions
and Equipment:
Exposure to the spilled material may be irritating or harmful. Follow personal
protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances
created by the spill including; the material spilled, the quantity of the spill, the
area in which the spill occurred. Also consider the expertise of employees in the
area responding to the spill.
VII. HANDLING AND STORAGE
Product Use: Press Wash
ECOLO WASH 100
Page 2 of 5
Handling
Precautions:
Harmful or irritating material. Avoid contacting and avoid breathing the material.
Use only in a well ventilated area. As with all chemicals, good industrial hygiene
practices should be followed when handling this material.
Rags soaked with solvent or oil present a fire hazard and should always be
stored in a UL listed or FM approved covered container.
Use with adequate ventilation
Wash thoroughly after handling.
Storage Conditions: Store in a cool dry place. Isolate from incompatible materials. Keep container
closed when not in use. Keep away from heat, sparks, and flame.
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering
Measures:
General room ventilation might be required to maintain operator comfort under
normal conditions of use.
Respiratory
Protection:
No respiratory protection required under normal conditions of use.
Eye Protection: Wear safety glasses with side shields when handling this product. Wear
additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Have an eye wash station available.
Skin Protection: Wear protective gloves. Inspect gloves at regular intervals and replace as
necessary. Clean protective equipment regularly. Wash hands and other
exposed areas with mild soap and water before eating, drinking, and when
leaving work.
Gloves: Wear impervious material. Butyl rubber or Nitrile
Exposure Guidelines:
CAS# Chemical Name OSHA Exposure Limits ACGIH TLV -
TWA
ACGIH
STEL
IDLH
111-76-2 Ethylene glycol mono-
n-butyl ether
50 ppm TWA; 240 mg/m3 TWA
prevent or reduce skin
absorption
20 ppm TWA No STEL 700 ppm
IDLH
If this product is provided in a dry powder state it should be considered a nuisance dust (PEL 10 mg/m3).
If the processing of this product produces a mist it should be considered to be an oil mist with a PEL of 5 mg/m3.
IX. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear Amber
Odor: Mild
Solubility in Water: Emulsifies
Vapor Pressure (mmHg @ 20 deg. C): 1.8
Volatile Organic Compounds (VOC) % by wt: 17.28
Volatile Organic Compounds (VOC) % by vol: 17.00
VOC lb/gal 1.25
Specific Gravity: 0.87
Bulk Density (lbs/Gal): 7.25
Bulk Density (kg/L): 0.87
X. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions to Avoid: Temperatures above flash point in combination with sparks, open flames, or
other sources of ignition.
ECOLO WASH 100
Page 3 of 5
Materials to
Avoid/Chemical
Incompatibility:
Strong oxidizing agents.
XI. TOXICOLOGICAL INFORMATION
Component Toxicology Data (NIOSH):
CAS# Chemical Name LD50/LC50
111-76-2 Ethylene glycol mono-n-butyl ether Inhalation LC50 Rat 2.21 mg/L 4 h; Inhalation LC50 Rat 450 ppm 4 h;
Oral LD50 Rat 470 mg/kg; Dermal LD50 Rat 2270 mg/kg; Dermal
LD50 Rabbit 220 mg/kg
XII. ECOLOGICAL INFORMATION
Ecotoxicity There is no data available on the preparation itself. Do not allow to
enter drains or watercourses.
Marine Pollutants Not on list
Severe Marine Pollutants Not on list
XIII. DISPOSAL CONSIDERATIONS
Waste Description
for Spent Product:
Spent or discarded material is not expected to be a hazardous waste.
Disposal Methods: Dispose in accordance with Federal, State, Provincial and Local regulations.
Material may be compatible with industrial waste incineration or inclusion in a
fuel blending program. This characterization is subject to approval by your waste
management contractor. This material should be recycled if possible.
XIV. REGULATORY INFORMATION
TSCA Status All ingredients of this product are listed or are excluded from listing on the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

Chemical Name CAS # Regulation Percentage
Not on list CERCLA
2-Butoxyethanol 111-76-2 NPRI (Cdn) 10.00
Methanol 67-56-1 PROP 65 0.06
Glycol Ethers N-230 111-76-2 SARA 313 10.00
Not on list SARA EHS

The following items require export notification for TSCA
Chemical Name TSCA 12b list section
Not on list
This product has been classified in accordance with the hazard criteria of the Canadian Controlled
Products Regulations and the MSDS contains information required by the Controlled Products
Regulations.
XV. TRANSPORTATION INFORMATION
49CFR/TDG - Non-bulk: GROUND SHIPMENTS NOT REGULATED IN PACKAGINGS OF 119 GAL
(450 L) OR LESS.
49CFR/TDG - Bulk: NA1993, COMBUSTIBLE LIQUID, N.O.S. (GLYCOL ETHER), PGIII, ERG128
IATA - Non-bulk: NOT REGULATED
IMDG - Non-bulk: NOT REGULATED
XVI. ADDITIONAL INFORMATION
ECOLO WASH 100
Page 4 of 5
References:
Disclaimer: Varn International, Inc. a Flint Group Company has prepared this Material Safety Data
Sheet (MSDS) in compliance with 29 CFR 1910.1200, understands that its customers may use this
MSDS to comply with that section, and believes that the data set forth herein are accurate as of the date
hereof; however, this MSDS shall not constitute a warranty with respect thereto.
TZACHARIA
ECOLO WASH 100
Page 5 of 5
SAFETY DATA SHEET according to EC directive 2001/58/EC
DIGISTAR PES HD ONE BLACK
Version 1 Print Date 26/04/2006
1/5
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
Product name : DIGISTAR PES HD ONE BLACK
Product code : M408710L001000
Company : Kiian Srl
Via A. De Gasperi 1
22070 Luisago
Telephone : +390319090111
Telefax : +390319090153
In order to get more information and in case of emergencies please address to Kiian.
: Tel. +39-031-9090111
Fax +39-031-9090153
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature : Digital screen printing ink
3. HAZARDS IDENTIFICATION
Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 1999/45/EC.
The product does not need to be labelled in accordance with EC directives or respective national laws.
4. FIRST AID MEASURES
General advice : When symptoms persist or in all cases of doubt seek medical advice.
Never give anything by mouth to an unconscious person.
After Inhalation : Remove to fresh air.
Keep patient warm and at rest.
If breathing is irregular or stopped, administer artificial respiration.
If unconscious place in recovery position and seek medical advice.
After Skin contact : Take off all contaminated clothing immediately.
Wash skin thoroughly with soap and water or use recognized skin
cleanser.
Do NOT use solvents or thinners.
Put shower on working place
2/5
After Eye contact : Irrigate copiously with clean, fresh water for at least 10 minutes,
holding the eyelids apart.
Remove contact lenses.
Seek medical advice.
Put eye-washer on working place
After Ingestion : If accidentally swallowed obtain immediate medical attention.
Keep at rest.
Do not induce vomiting.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Keep containers and surroundings cool with water spray.
Extinguishing media which
must not be used for safety
reasons
: Do NOT use water jet.
Specific hazards during fire
fighting
: As the product contains combustible organic components, fire will
produce dense black smoke containing hazardous products of
combustion (see section 10).
Exposure to decomposition products may be a hazard to health.
Cool closed containers exposed to fire with water spray.
Collect contaminated fire extinguishing water separately. This must
not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use personal protective equipment.
Ventilate the area.
Refer to protective measures listed in sections 7 and 8.
Material can create slippery conditions.
Environmental precautions : Try to prevent the material from entering drains or water courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods for cleaning up : Clean with detergents. Avoid solvents.
Contain and collect spillage with non-combustible absorbent material,
(e.g. sand, earth, diatomaceus earth, vermiculite) and place in
container for disposal according to local / national regulations (see
section 13).
Additional advice : Refer to section 15 for specific national regulation.
3/5
7. HANDLING AND STORAGE
Handling
Safe handling advice : Avoid exceeding of the given occupational exposure limits (see
section 8).
Use only in area provided with appropriate exhaust ventilation.
Avoid contact with skin, eyes and clothing.
Smoking, eating and drinking should be prohibited in the application
area.
Avoid inhalation of vapour or mist.
For personal protection see section 8.
Thoroughly mix before using
After using, store in a well-sealed container
Storage
Requirements for storage
areas and containers
: Observe label precautions.
Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Store in accordance with the particular national regulations.
Store between 5 an 35C in a dry, well ventilated place away from
source of heat, ignition and direct sunlight.
No smoking.
Electrical installations / working materials must comply with the
technological safety standards.
Advice on common storage : Keep away from oxidising agents and strongly acid or alkaline
materials.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
Respiratory protection : Provide adequate ventilation.
Hand protection : For prolonged or repeated contact use protective gloves.
Barrier creams may help to protect the exposed areas of skin, they
should however not be applied once exposure has occurred.
Skin should be washed after contact.
Wash your hands and put on barrier creams
Eye protection : Chemical resistant goggles must be worn.
Skin and body protection : Skin should be washed after contact.
Personnel should wear protective clothing
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid
Flash point : > 100 C
4/5
Density : 1,05 g/cm3
Viscosity : <= 60 s
Transversale section: 6 mm
Method: 2431 '84 (ISO 6)
Solids by weight : 35 %
10. STABILITY AND REACTIVITY
Conditions to avoid : Our products were manufactured in compliance with safety standards
to avoid decomposition and degrading under the defined conditions.
Taking the product type into account, it is advisable to leave the
product in its original packaging thus avoiding transferring it.
Hazardous reactions : Keep away from oxidising agents, strongly alkaline and strongly acid
materials in order to avoid exothermic reactions.
11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity : Inhalation of airborne droplets may cause irritation of the respiratory
tract.
Skin irritation : Repeated or prolonged contact with the preparation may cause
removal of natural fat from the skin resulting in desiccation of the
skin.
The product may be absorbed through the skin.
Note : The concentration of each substance should be borne in mind in
assessing the toxicological effects deriving from the preparation.
12. ECOLOGICAL INFORMATION
Further information : There is no data available for this product.
13. DISPOSAL CONSIDERATIONS
Product : The product should not be allowed to enter drains, water courses or
the soil.
Disposal together with normal waste is not allowed. Special disposal
required according to local regulations.
14. TRANSPORT INFORMATION
ADR : Not classified as dangerous in the meaning of transport regulations.
IMDG : Not classified as dangerous in the meaning of transport regulations.
IATA : Not classified as dangerous in the meaning of transport regulations.

5/5
15. REGULATORY INFORMATION
Hazardous components which must be listed on the label:
National legislation
Germany
Risk classification according
to BetrSichV (Germany)
: Exempt
Water contaminating class
(Germany)
: highly water endangering
Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 1999/45/EC.
The product does not need to be labelled in accordance with EC directives or respective national laws.
16. OTHER INFORMATION
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text.
Version: 1.1 Revision date 21.02.2006
SDS updated to the last adjustment of EEC directive 67/548/CE, 1999/45/CE.

Revision Number: 003.0 Issue date: 03/29/2011

IDH number: 974202 Product name: PURMELT QR 2580 BULK
Page 1 of 5

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: PURMELT QR 2580 BULK IDH number: 974202
Product type: 1-component-polyurethane adhesive

Region: United States
Company address: Contact information:
Henkel Corporation
10 Finderne Avenue, Suite B
Bridgewater, New J ersey 08807
Customer Service: 1-888-480-6889
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
HMIS:
Physical state: solid HEALTH: *2
Color: white FLAMMABILITY: 1
Odor: Characteristic PHYSICAL HAZARD: 0
Personal Protection: See MSDS Section 8
WARNING: CAUSES EYE IRRITATION.
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION.
MAY CAUSE LUNG DAMAGE.
MOLTEN ADHESIVE MAY CAUSE SEVERE BURNS.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Methylene bisphenyl isocyanate (MDI) vapors or mist at concentrations above the TLV can
irritate the mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose,
sore throat, coughing, chest discomfort, shortness of breath and reduced lung function
(breathing obstruction). This product may cause sensitization by inhalation and skin contact.
Repeated exposure may lead to respiratory sensitization reactions, producing an asthma-like
condition.
Skin contact: Repeated or prolonged skin contact may result in allergic sensitization. May cause skin
irritation. Molten adhesive may cause severe burns.
Eye contact: Liquid or vapor can cause moderate to severe irritation.
Ingestion: Harmful if swallowed. Not expected under normal conditions of use.

Existing conditions aggravated by
exposure:
Pre-existing skin or lung allergies may increase the chance of developing exaggerated allergic
symptoms from exposure to this product.

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous components CAS NUMBER %
Methylenebis(phenylisocyanate) 101-68-8 1 - 5

Page 2 of 5

4. FIRST AID MEASURES

Inhalation: If inhaled, immediately remove the affected person to fresh air. If not
breathing, give artificial respiration.

Skin contact: Cool melted product on skin with plenty of water. Do not remove solidified
product. Immediately wash skin thoroughly with soap and water. Get
immediate medical attention.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Continue to flush eyes while awaiting medical attention

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Seek
medical advice.

Notes to physician: Persons with asthmatic-type conditions, chronic bronchitis, other chronic
respiratory diseases or recurrent skin eczema or sensitization should be
excluded from working with isocyanates.

5. FIRE FIGHTING MEASURES

Flash point: >200 C (>392F) Cleveland open cup

Autoignition temperature: Not determined

Flammable/Explosive limits - lower: not applicable

Flammable/Explosive limits - upper: not applicable

Extinguishing media: water, carbon dioxide, foam, powder

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: None

Hazardous combustion products: Hydrogen cyanide. Oxides of carbon, oxides of nitrogen, irritating organic
vapors.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Keep unnecessary personnel away. Wear protective clothing, gloves and
safety glasses. Spilled material will solidify. Scrape up spilled material and
place in a closed container for disposal.

7. HANDLING AND STORAGE

Handling: Do not place wet or damp solid into melt tank. Avoid skin and eye contact.
Avoid breathing vapors or mists of this product. Wash thoroughly after
handling.

Storage: Store in tightly closed containers to prevent moisture contamination. Reacts
slowly with water to liberate carbon dioxide gas. Do not store above 100 F
(37.7 C).

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

Page 3 of 5

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
Methylenebis(phenylisocyanate) 0.005 ppm TWA
0.02 ppm (0.2
mg/m3) Ceiling
None None

Engineering controls: Work should be done in an adequately ventilated area (i.e., ventilation
sufficient to maintain concentrations below one half of the PEL and other
relevant standards). Local exhaust ventilation is recommended when general
ventilation is not sufficient to control airborne contamination below
occupational exposure limits.

Respiratory protection: No personal respiratory protective equipment normally required. Do not inhale
vapors and fumes. Concentrations greater than the TLV can occur when MDI
is sprayed, heated or used in a poorly ventilated area. A positive pressure,
supplied-air respirator or a self-contained breathing apparatus is
recommended when: airborne concentrations of isocyanate are known to
exceed 0.005 ppm; operations are performed in a confined space or area with
limited ventilation; material is heated or sprayed. Observe OSHA regulations
for respiratory use (29 CFR 1910.134).

Eye/face protection: Safety glasses with sideshields or chemical safety goggles should be worn if
there is a risk of splashing. Full face protection should be used if the potential
for splashing or spraying of product exists.

Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin
contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: solid
Color: white
Odor: Characteristic
Odor threshold: Not available
pH: Not applicable
Vapor pressure: Not available
Boiling point/range: Not available
Melting point/ range: 65 C (149F) (Softening Point)
Specific gravity: 1.2
Vapor density: Not determined
Flash point: >200 C (>392F) Cleveland open cup
Flammable/Explosive limits - lower: not applicable
Flammable/Explosive limits - upper: not applicable
Autoignition temperature: Not determined
Evaporation rate: Not applicable
Solubility in water: Not soluble. Reacts slowly with water to liberate carbon dioxide gas.
Partition coefficient (n-octanol/water): Not applicable
VOC content: 0 g/l
Viscosity: 4,000 - 6,000 mPa.s

Page 4 of 5

10. STABILITY AND REACTIVITY

Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors.
Hydrogen cyanide. Oxides of carbon. Oxides of nitrogen.

Incompatible materials: Reacts with alcohols and amines. Reacts with water.

Conditions to avoid: Container can be pressurised by carbon dioxide due to reaction with humid air
and/or water.

11. TOXICOLOGICAL INFORMATION

Hazardous components NTP Carcinogen IARC Carcinogen
OSHA Carcinogen
(Specificall y Regulated)
Methylenebis(phenylisocyanate) No No No

Hazardous components Health Effects/Target Organs
Methylenebis(phenylisocyanate) Irritant, Respiratory, Allergen

12. ECOLOGICAL INFORMATION

Ecological information: Not available

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product onl y.

Recommended method of disposal: This product is not a RCRA hazardous waste when discarded. Processing,
use, or contamination of this product may change the hazard classification and
waste management options. Dispose of according to Federal, State and local
governmental regulations.

Hazardous waste number: Not hazardous.

14. TRANSPORT INFORMATION

U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)
Packing group: None

Water Transportation (IMO/IMDG)
Packing group: None
Exceptions: None

Page 5 of 5

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12(b) Export Notification: None above reporting de minimus

CERCLA/SARA Section 302 EHS: None above reporting de minimus
CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Methylenebis(phenylisocyanate) (CAS#101-68-8).

California Proposition 65: No California Proposition 65 listed chemicals are known to be present.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
WHMIS hazard class: D.2.A, D.2.B

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: Updated composition in Section 3.

Prepared by: J . Boryszewski, Regulatory Affairs

DISCLAIMER: The data contained herein are furnished for information onl y and are believed to be reliable. However,
Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel
Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any
production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the
protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel
Corporation's products. In light of the foregoing, Henkel Corporation specificall y disclaims all warranties, express or
implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel
Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any
kind, including lost profits.

REVSON DATE: 08/01/07
SAFETY DATA SHEET
V120 Wash
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
PRODUCT NAME V120 Wash
APPLICATION A Lithographic Blanket and Roller Wash
Day nternational Chemical
Products Division,
SUPPLIER
Varn House, Northbank
ndustrial Park, rlam, Greater
Manchester,
M44 5BL, England
Tel. + 44 (0)161 775 5412
Fax. + 44 (0)161 775 5415
2 COMPOSITION/INFORMATION ON INGREDIENTS
EC No. Name CIassification CAS-No. Content
202-436-9 1,2,4-TRMETHYLBENZENE R10 Xn;R20 Xi;R36/37/38
N;R51/53
95-63-6 10-30%
AMNE ETHOXYLATE (ENECS - OECD
Polymer)
Xn;R22. Xi;R38,R41. N;R50/53. 61791-26-2 < 1
202-704-5 CUMENE R10 Xn;R65 Xi;R37 N;R51/53 98-82-8 1-5%
203-604-4 MESTYLENE R10 Xi;R37 N;R51/53 108-67-8 1-5%
265-150-3 NAPHTHA (PETROLEUM),
HYDROTREATED HEAVY (2)
Xn;R65. R10,R66. 64742-48-9 30-50%
265-150-3 NAPHTHA (PETROLEUM),
Xn;R65. Xi;R38. N;R51/53. R10. 64742-48-9 1-5%
265-198-5 SOLVENT NAPHTHA (PETROLEUM),
HEAVY AROMATC (1)
Xn;R65. N;R51/53. R66,R67. 64742-94-5 < 1
265-199-0 SOLVENT NAPHTHA (PETROLEUM),
LGHT AROMATC
Xn;R65. N;R51/53. R10,R66,R67. 64742-95-6 10-30%
215-535-7 XYLENE R10 Xn;R20/21 Xi;R38 1330-20-7 < 1
The Full Text for all R-Phrases are Displayed in Section 16
COMPOSITION COMMENTS
A petroleum distillate blend.
3 HAZARDS IDENTIFICATION
Flammable. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and
dizziness. Harmful: may cause lung damage if swallowed. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
CLASSIFICATION Xn;R65. N;R51/53. R10, R66, R67.
4 FIRST-AID MEASURES
INHALATION
Move the exposed person to fresh air at once. For breathing difficulties oxygen may be necessary. f breathing
stops, provide artificial respiration. Keep the affected person warm and at rest. Get prompt medical attention.
INGESTION
Do not induce vomiting. f vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the
lungs. Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical
attention immediately!
5 1 /
V120 Wash
SKIN CONTACT
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin
immediately with soap and water. Get medical attention if irritation persists after washing.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water
while lifting the eye lids. Continue to rinse for at least 15 minutes. Contact physician if irritation persists.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Fire can be extinguished using: Carbon dioxide (CO2). Foam. Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Avoid breathing fire vapours. Cool containers exposed to flames with water until well after the fire is out. Keep
run-off water out of sewers and water sources. Dike for water control.
6 ACCIDENTAL RELEASE MEASURES
SPILL CLEAN UP METHODS
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry
sand or earth and place into containers. Do not let washing down water contaminate ponds or waterways. Wear
necessary protective equipment.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Maintain good standards of hygiene and work practices. Avoid spilling, skin and eye contact. Keep away from
heat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if air
contamination is above accepted level.
STORAGE PRECAUTIONS
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in
a dry and cool place. Keep in original container. Protect against physical damage and/or friction. May attack
some plastics, rubber and coatings.
STORAGE CLASS
Flammable liquid storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Std ST - ppm LT - ppm LT - mg/m3 ST - mg/m3 Name
25 ppm 125 mg/m3 WEL 1,2,4-TRMETHYLBENZENE
25 ppm(Sk) 125
mg/m3(Sk)
WEL 50 ppm(Sk) 250
mg/m3(Sk)
CUMENE
20 ppm 100 mg/m3 WEL MESTYLENE
170 ppm 1000 mg/m3 WEL NAPHTHA (PETROLEUM),
135 ppm 800 mg/m3 WEL NAPHTHA (PETROLEUM),
80 ppm 450 mg/m3 WEL SOLVENT NAPHTHA (PETROLEUM),
HEAVY AROMATC (1)
40 ppm 200 mg/m3 WEL SOLVENT NAPHTHA (PETROLEUM),
LGHT AROMATC
50 ppm(Sk) 220
mg/m3(Sk)
WEL 100 ppm(Sk) 441
mg/m3(Sk)
XYLENE
INGREDIENT COMMENTS
WEL = Workplace Exposure Limits
PROTECTIVE EQUIPMENT
5 2 /
V120 Wash
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
Respiratory protection must be used if air contamination exceeds acceptable level.
HAND PROTECTION
Nitrile.
EYE PROTECTION
Use approved safety goggles or face shield.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.
HYGIENE MEASURES
DO NOT SMOKE N WORK AREA! Wash at the end of each work shift and before eating, smoking and using
the toilet. Wash promptly with soap & water if skin becomes contaminated. Promptly remove any clothing that
becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or
smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Liquid
COLOUR Yellow
ODOUR Hydrocarbon
SOLUBILITY Forms an emulsion with water.
BOILING POINT (C) > 150 @ 760 mm Hg RELATIVE DENSITY 0.82 g/ml @ 20C
VAPOUR PRESSURE 0.18 kPa @ 20C FLASH POINT (C) 45 CC (Closed cup).
AUTO IGNITION
TEMPERATURE (C)
> 200 FLAMMABILITY LIMIT -
LOWER(%)
0.6
FLAMMABILITY LIMIT -
UPPER(%)
7.0
10 STABILITY AND REACTIVITY
STABILITY
Avoid: Heat, sparks, flames. Stable under normal temperature conditions.
CONDITIONS TO AVOID
Avoid contact with strong oxidisers. Avoid heat, flames and other sources of ignition.
HAZARDOUS DECOMPOSITION PRODUCTS
Not known.
11 TOXICOLOGICAL INFORMATION
HEALTH WARNINGS
NHALATON. rritating to respiratory system. SKN CONTACT. Acts as a defatting agent on skin. May cause
cracking of skin, and eczema. EYE CONTACT. Direct contact with the eye may cause irritation. NGESTON.
May cause discomfort. Aspiration into the lungs during ingestion or subsequent vomiting will cause severe lung
damage.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Volatile Organic Content (%) is equal to 95 - 100
5 3 /
V120 Wash
MOBILITY
Solubility in water: Forms an emulsion with water
BIOACCUMULATION
No data available.
DEGRADABILITY
No data available.
ACUTE FISH TOXICITY
No data available.
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
WASTE CLASS
Regulation 2000/532/EC - Chapter Heading: Waste from MFSU of fine chemicals and chemical products not
otherwise specified - 070704. Description: Other organic solvents, washing liquids and mother liquors.
14 TRANSPORT INFORMATION
PROPER SHIPPING NAME Petroleum Distillates N.O.S. (Refined Hydrocarbons)
1268 UN NO. ROAD UK ROAD PACK GR.
Class 3: Flammable
liquids.
ADR CLASS 3 ADR LABEL NO.
3 RID CLASS NO. 1268 UN NO. SEA
3 IMDG CLASS IMDG PACK GR.
F-E , S-E EMS MARINE POLLUTANT
15 REGULATORY INFORMATION
LABELLING
Harmful Dangerous for the
environment
CONTAINS NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (2)
SOLVENT NAPHTHA (PETROLEUM), LGHT AROMATC
RISK PHRASES
R10 Flammable.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
5 4 /
V120 Wash
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
SAFETY PHRASES
S37 Wear suitable gloves.
S51 Use only in well-ventilated areas.
S57 Use appropriate containment to avoid environmental contamination.
S61 Avoid release to the environment. Refer to special instructions/safety
data sheets.
S62 f swallowed, do not induce vomiting: seek medical advice immediately
and show this container or label.
EU DIRECTIVES
Dangerous Substances Directive (67/548/EEC). Dangerous Preparations Directive (1999/45/EC). Safety Data
Sheets Directive (91/155/EEC) (As amended).
STATUTORY INSTRUMENTS
Chemicals (Hazard nformation and Packaging) Regulations. Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and Preparations Dangerous for Supply.
GUIDANCE NOTES
Workplace Exposure Limits EH40. ntroduction to Local Exhaust Ventilation HS(G)37. CHP for everyone
HSG(108).
16 OTHER INFORMATION
ISSUED BY
Day nternational Chemical Products Division
REVISION DATE 08/01/07
REV. NO./REPL. SDS
GENERATED
21/10/02
SDS NO. 4
RISK PHRASES IN FULL
Flammable. R10
Harmful by inhalation. R20
Harmful by inhalation and in contact with skin. R20/21
Harmful if swallowed. R22
rritating to eyes, respiratory system and skin. R36/37/38
rritating to respiratory system. R37
rritating to skin. R38
Risk of serious damage to eyes. R41
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R50/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R51/53
Harmful: may cause lung damage if swallowed. R65
Repeated exposure may cause skin dryness or cracking. R66
Vapours may cause drowsiness and dizziness. R67
DSCLAMER
The information in this material Safety Data Sheet is based on the present state of our knowledge and on the current EC and
National Regulations. The information relates to the specific product designated and may not be valid if it is used in
combination with other materials or process. Nothing herein is to be contrued as warranty, expessed or implied. t is always the
responsibility of the user to take the necessary steps in order to fulfil the demands laid down in the rules and legislation. The
product is for ndustrial use only.
5 5 /
Project Summary
E A P
United States
Environmental Protection
Agency
Waste Reduction Evaluation of
Soy-Based Ink at a Sheet-Fed
Offset Printer
Beth Simpson, Pamela Tazik, Gary Miller, and Paul Randall
Risk Reduction
Engineering Laboratory
Cincinnati, OH 45268
Research and Development
This Waste Reduction and Innova-
tive Technology Evaluation project fo-
cused on the use of soy-based inks as
a substitute for petroleum-based inks
in sheet-fed offset printing. The goal of
the study was to evaluate the waste
reduction and economic effects of us-
ing soy-based inks in place of the pe-
troleum-based inks traditionally used
in sheet-fed offset printing. The main
potential environmental benefits
claimed for soy-based inks are that they
are a renewable resource and emit less
amounts of volatile hydrocarbons dur-
ing the printing process. No published
studies verify the claim of reduced air
emissions or quantify other environ-
mental aspects of using soy-based inks
such as the amount of liquid wastes
generated and cleaners required. Other
reported benefits of soy-based inks are
that they are biodegradable in landfills
and are more conducive to cleanup with
degradable and less toxic cleaners than
are petroleum-based inks.
This Project Summary was developed
by EPAs Risk Reduction Engineering
Laboratory, Cincinnati, OH, to announce
key findings of the program demon-
stration that is fully documented in a
separate report (see ordering informa-
tion at back).
Introduction
The impetus for developing soy-based
inks initially came from the oil shortages
of the 1970s that threatened the supply
of petroleum-based chemicals. Now, in-
creased emphasis on improving worker
safety and reducing environmental emis-
sions is motivating the printing industry to
seek cleaner technologies. In the 1980s,
soy-based inks were first used in offset
web presses for printing newspapers,
mainly for presumed environmental ben-
efits. In the late 1980s, soy-ink formula-
tions were marketed for sheet-fed offset
presses.
Sheet-fed soy inks are defined as those
that have a minimum of 20% soy oil by
volume. The soy oil replaces petroleum
oils in the ink vehicle and varnish compo-
nents. Use of the soy oil affects color,
drying, and other operating characteristics
of the inks. Soy-based inks used in sheet-
fed presses still contain at least 10% pe-
troleum oils. Research is continuing to
increase the proportion of soy and other
vegetable-based oils in these ink formula-
tions while maintaining satisfactory print-
ing characteristics.
The Office of Printing Services (OPS)
at the University of Illinois is the operating
partner in this study. They are considered
a medium size, in-plant printer and gross
about $4.5 million annually. They agreed
to enter into this cooperative project be-
cause of their commitment to active re-
search participation and out of a desire to
be a model environmentally aware print
shop. They were one of the first sheet-fed
offset presses in the United States to use
soy-based inks.
Approach
Data for this study was collected during
a full-scale print run on a Miller TP104
Plus
*
six-color press in July 1992 at the
OPS. The print job evaluated was a 4400
sheet, six-color, work-and-turn. Only four
EPA/600/SR-94/144 September 1994
2
of the six colors were included in the study
because the type of ink used for two col-
ors was not changed between the runs.
All inks included in the study were manu-
factured by the same company, Handschy,
Inc. of Bellwood, IL.* In-plant measure-
ments consisted of weighing the contain-
ers of inks, blanket cleaners, and roller
cleaners used during makeready and print-
ing at each press unit before and after
each print run. Cleanup rags were weighed
before and after each print run. Wastes in
the wash-up trays were weighed at each
press unit at the end of each run. Samples
of each type and color of ink and each
cleaner used were analyzed at the same
temperature as the press for total solids
and volatile content at the Hazardous
Waste Research and Information Centers
(HWRIC) Hazardous Materials Laboratory.
The operators at OPS use the same
cleaners for both petroleum-based and
soy-based inks. They had previously tried
aqueous and less volatile organic clean-
ers and had not found any satisfactory
substitutes. Problems identified with some
of the cleaners they tested were that they
required more labor, dried much slower,
and sometimes left a film on the presses
that had to be removed in an additional
step.
Results
Ink Use
During the two print runs studied,
makeready for the petroleum-based ink
run was considerably more involved than
that for the soy-based run. This was
caused by excess moisture in the original
batch of paper and not by differences in
the inks. This difference in the two runs
affected ink and blanket cleaner usage
and waste paper generated. The excess
moisture in the paper caused it to curl and
wrinkle during feeding into the press. This
problem was not a result of the type of ink
being used for that run but because the
paper had been stored in high humidity
conditions before the first run. Because of
this, about 25% more pages were printed
using petroleum-based inks, which makes
a comparison of inks and cleaners used
and waste generated between the two
runs difficult. These differences were com-
pensated for to the extent possible in
evaluating results of in-plant measure-
ments.
The study results showed that the pe-
troleum-based ink run required larger
quantities of three of the four colors of ink
than did the soy-based ink print run (Table
1). The amount shown in the g/100 sheets
printed column compensate for the differ-
ence in the number of sheets printed dur-
ing makeready. The % difference column
compares the amount of petroleum-based
ink used with the amount of soy-based ink
used. For these specific print jobs, in to-
tal, approximately 17% more petroleum-
based inks were used on a per sheet
printed basis.
Cleaner Use
The amount of blanket cleaners used is
shown in Table 2. Almost 46% more blan-
ket cleaners were used during the petro-
leum ink run (3,455.4g compared with
2,368.0g). Some of this difference can be
attributed to the larger amount of blanket
cleaners used during the longer makeready
that occurred during this run. The amount
of blanket cleaner used during makeready
was not recorded separately from that used
during press cleaning at the end of the
print run. The amount of additional clean-
ers used for that purpose during the print-
ing run could not be directly measured; it
would not necessarily be directly propor-
tional to the amount of paper printed.
Therefore, an equivalent comparison can
not be made between the amount of blan-
ket cleaners used for each print run.
At the end of each printing run, roller
cleaners were used to clean up the
presses. Their use was not affected by
differences in makeready, but there was a
difference in the way the presses were
cleaned at the end of the two runs. At the
end of the petroleum ink run, the ink in
two of the stations was not changed. Also,
since the same colors were used in the
next run, each ink station was not cleaned
as thoroughly as it was at the end of the
second run with soy inks. The amounts of
each roller cleaner used for each color
and type of ink are shown in Table 3.
Overall, about 30% more roller cleaners
were used for the soy inks. This was ex-
pected since the stations were cleaned
more thoroughly at the end of the soy-
based ink run. Both inks appeared to re-
quire approximately the same amount of
cleaners and effort to remove from the
presses. On average in typical practice,
* Mention of trade names or commercial products does
not constitute endorsement or recommendation for
use.
Ink Color Ink Type Ink Used Ink Used %
(g) (g)/100 Difference
Sheets
Black Petroleum 241.8 3.8 19
Soy 162.7 3.2
Blue Petroleum 124.8 2.0 25
Soy 79.5 1.6
Red Petroleum 109.7 1.7 0
Soy 87.1 1.7
Yellow Petroleum
Soy 85.8 1.4 27
53.6 1.1
Table 1. Quantity Inks Used
Table 2. Quantity (g) of Blanket Cleaners Used
Ink Type Cleaner Name Cleaner Used (g)
Petroleum V120 1768.7
Clean Quick 1686.7
Soy V120 1141.2
Clean Quick 1226.8
3
of these materials were spilled during the
two runs. To clean the various rollers and
blankets, several rags were saturated with
each cleaner and were used to wipe down
the press. As a result, the rags contained
some highly volatile inks and cleaners. An
undeterminable portion of these cleaners
and inks ended up in the washup trays.
Rather than determining the rapidly chang-
ing amount of liquids on the rags immedi-
ately at the end of the print run, the rags
were dried and the amount of dried solids
on the rags was weighed. About 60%
more solids were on the rags used to
clean the presses after the petroleum ink
run. Since more inks and cleaners were
used in that run, apparently much of these
materials ended up on the cleanup rags.
The amount of liquids in the washup
trays from this study was measured di-
rectly at the end of the print runs. Almost
10% more liquids were generated in the
washup trays after the petroleum ink run.
This liquid was a mixture of inks and vari-
ous cleaners. The amount of each ink and
each cleaner that ended up in these trays
and the rags (less the amount evaporated
and on printed product) could not be di-
rectly measured.
The amount of each cleaner used to
saturate the rags was not metered out
precisely by the press operators so that
differences between the two runs in the
amounts used were mostly the result of
operator variability when they poured
cleaners on the rags and not the results
of the type of ink being cleaned. We ob-
served no reason for there to be a consis-
tent difference in the amount of liquid
wastes generated by the two types of inks
studied. Differences resulted from opera-
tor variability, extended makeready during
the petroleum ink run, and more thorough
cleaning conducted at the end of the soy
ink run. It can not be concluded that one
ink generated more liquid wastes than the
other.
Table 3. Quantity of Roller Cleaners Used at Each Color Station
Ink Color Ink Type RBP #1(g) RBP #2(g) MIX(g)
Black Petroleum 40.1 31.0 12.4
Soy 78.8 43.5 27.9
Blue Petroleum 44.8 34.5 33.8
Soy 75.7 56.2 52.1
Red Petroleum 29.5 75.8 19.5
Soy 97.9 19.7 24.9
Yellow Petroleum 35.1 96.6 61.5
Soy 40.3 84.9 71.5
the amount of cleaner used for the two
inks would be expected to be about the
same.
At the end of the petroleum-based ink
run, 663.8 g of ink and cleaner mixed
waste was in the washup trays. By com-
parison, there was 604.5 g at the end of
the soy-based ink run. This approximately
10% difference can be attributed to the
extended makeready at the beginning of
the petroleum-based ink run. On average
in typical practice, the amount of cleaner
usage for the two inks would be expected
to be the same.
Volatile Components
All inks had less than 6% volatile com-
ponents, and there were significantly less
volatile components in the soy-based inks
than in the petroleum-based inks. The pe-
troleum-based inks had an average of
about 4.6% volatile components compared
with an average of about 0.8% for the
soy-based inks. Thus, on average, the
soy-based inks only had about 17% of the
amount of volatiles as the petroleum-based
inks. The cleaners contained more than
97% volatile components except for one
roller cleaner that contained about 88%.
Based on these laboratory results and
on the amount of inks and cleaners used
(Tables 1 and 2), the amounts of solids
and volatiles in the inks and cleaners were
calculated (Table 4). The amounts of
volatiles were used to estimate the total
mass of air emissions. Over 90% of the
liquid wastes originated from the inks. As
for the volatiles, over 99% originated from
the cleaners in both cases.
Because of the difficulty of directly mea-
suring the amount of emissions from the
many sources on the press, the printed
papers, and the waste containers, a worst
case assumption was made that air emis-
sions were equal to the volatile content of
the materials used. Thus, for the petro-
leum-based ink run, 3,930.15 g were cal-
culated to be evaporated compared with
3,004.30 g for the soy-based ink run. This
was about 31% more emissions. As de-
scribed above, even after adjusting for
differences in makeready, about 17% more
petroleum-based ink was used. In addi-
tion, the petroleum-based inks had a higher
volatile content (4.6% compared with
0.77%). Just in terms of ink used, there
were 0.39 g/sheets of volatile emissions
from the petroleum inks compared to 0.23
g/100 sheets for the soy inks. This is
about 70% more emissions to the air for
an equivalent amount of printing with pe-
troleum inks.
As shown in Table 4, the mass of
volatiles estimated to be emitted from the
inks is less than 1.0% of the total mass
estimated to be emitted from the inks and
cleaners. Since most of the air emissions
were from the cleaners, less than 1% over-
all reduction in air emissions resulted from
using the soy-based inks. The longer the
print run the greater the reduction in vola-
tile emissions from using soy inks.
Liquid Components
The two main liquid wastes from the
printing press were from washup trays
and inks and cleaners on used rags. None
Parameter Petroleum Print Run Soy Print Run
Ink Solids 537.17 371.36
Cleaner Solids 64.78 48.64
Total Solids 601.95 420.00
Ink Volatiles 24.93 11.54
Cleaner Volatiles 3905.22 2992.76
Total Volatiles 3930.15 3004.30
Table 4. Solid and Volatile Contents of Inks and Cleaners Used (g)
4
Solid Waste
During makeready for the petroleum-
based ink run, 1375 waste sheets were
generated. The reverse side of 100 waste
sheets were reused during makeready for
the soy-based ink print run. This is the
amount of solid waste generated directly
during these print runs. No other contain-
ers of solid wastes were observed. Addi-
tional solid waste that may be generated
in printing include trimmings and excess
number of pages printed to compensate
for losses that may occur during folding,
binding and any other final preparation
steps. Because the soy inks generally
spread further (by an average of about
17%), less used ink containers may be
generated with those inks. The amount of
the other solid wastes would be unaf-
fected by the type of ink used. In this
case, the difference in makeready waste
resulted from moisture in the paper at the
beginning of the print run and not from
difficulty with using the inks.
Press alignment and ink metering was
automated for the press used in this study.
Based on observations of manually oper-
ated presses at this and other facilities,
automation or efficient press set-up, rather
than the choice of ink, results in less solid
waste being generated during printing.
Once operators are familiar with the use
of either the petroleum or soy inks, then
the amount of solid waste generated dur-
ing makeready will not be noticeably dif-
ferent. In both cases, more waste paper
might be generated on some jobs be-
cause of difficulties in obtaining accept-
able colors or other print quality factors. In
this regard, neither ink appears to have a
clear advantage over the other.
Costs
The main cost factor considered was
that of raw materials. No equipment ex-
penditures were required by OPS to switch
from using petroleum to soy inks. There
was a difference in the amount of labor
involved in the two print runs but that was
due to the problems with paper at the
beginning of the first run and the fact that
cleanup was more rigorous at the end of
the second run. Neither of these differ-
ences was due to the type of ink being
used. The operating conditions of the
press, such as temperature and speed,
were the same for each ink so there was
no difference in overall rate of production
or utilities used because of the type of ink
used. Insurance, monitoring requirements,
reporting and recordkeeping, and permit
requirements are the same for each type
of ink. Any differences in future costs for
remediation or property damage would be
minimal. Employee health costs would
slightly favor the use of soy-based inks
because of reduced employee exposure
to breathing released chemicals. All the
quantified cost factors are for the Miller
TP 104 press only and not for the entire
facility at OPS.
The purchase prices of raw materials
(inks, cleaners, and paper) for this print
job are approximately the same for both
types of ink. Generally soy inks cost about
10% more. The average purchase price
for both the soy inks and petroleum inks
is about $8.00/lb (or $0.018g). Actual costs,
depending on the color, range from about
$4.00 to $12.00/lb. Costs do vary, how-
ever, when the amount of materials used
for petroleum inks is compared with the
amount of materials for soy inks. On an
equivalent basis of ink used during print-
ing and typical makeready, the overall cost
savings in ink used for the soy-based ink
print run was estimated to be $1.17. This
cost difference is not a major factor in ink
selection. Higher costs are involved in
printing including labor, materials such as
paper, equipment amortization, and utili-
ties. The portion of total printing costs
allocated to inks is usually very small.
When adjusted to the amount of accept-
able product printed, the difference be-
tween cleaner costs for the petroleum and
soy-based ink runs for this print job was
only 5 cents. This difference would be
greater if the cleaning after the petroleum-
based ink run had been more thorough.
Because the same cleaners were used
for both inks and on average there would
be no difference between the two inks in
the amount of cleaner needed, costs for
cleaning would not be expected to differ.
Discussion
Overall, about 17% less soy ink com-
pared with petroleum ink was used for the
print job studied. Because less amounts
of volatile hydrocarbons are emitted from
the soy-based inks, air emissions were
less. Since the inks and cleaners continu-
ously evaporate during use and the waste
inks and cleaners end up mixed together
in washup trays and on the cleanup rags,
it was difficult to determine the proportion
that evaporated during the actual printing
process. Ultimately, most if not all of the
volatiles in the inks and cleaners will ei-
ther evaporate, be discharged to the wa-
ter (such as from a commercial laundry)
or be containerized and sent to a landfill.
Some of these emissions will occur at the
print shop, some perhaps after shipment
of the printed product, and some at waste
management facilities. The proportion of
volatilization that will occur in any one
place will vary depending on how the waste
materials are managed. For comparison
purposes, it was assumed in this study
that all the air emissions occurred at the
print shop.
An important factor that influences the
amount of waste generated per unit of
production is the length of the print run.
Some uses of ink (and resulting wastes
generated) in the printing process are fairly
consistent among print jobs. For instance,
the amount of ink required to coat the
rollers and plates for each revolution is
relatively consistent. A certain amount of
waste is expected for every print job, but
a higher proportion of waste is produced
per raw material input on shorter print
jobs, such as the one monitored here.
With longer print jobs, a greater percent-
age of the ink used would be applied to
acceptable product.
To most printers, there are little or no
perceived differences in the cost of using
soy-based inks because the raw material
cost is slightly higher or equivalent to pe-
troleum-based inks. The cost difference is
more than offset by the fact that the soy
inks spread almost 20% further and do
not release as much volatile organic chemi-
cals. Less tangible benefits of using soy
inks (company image as being environ-
mentally friendly, improved employee re-
lations due to a perceived healthier working
environment, and customer preference for
products) are major factors considered by
printers. If customer response to product
quality is negative, printers will not adopt
a new ink. At OPS, their experience has
been that customers find the quality of the
product to be acceptable, and many pre-
fer to have their job printed with soy-based
inks.
A company also must consider the will-
ingness of its workers to switch to and
use soy inks and the time it takes for
operators to become skilled in using these
inks. Understandably there may be some
excess waste generated during such a
change. At OPS, there was some initial
resistance to the new inks. Formulations
of soy inks in sheet-fed offset presses
were new. In the past few years, these
formulations have improved and the press
operators at OPS have gained the experi-
ence necessary to produce high quality
images. Presently, the employees prefer
to use soy-based inks on this particular
press. A major reason for this is that the
soy inks are very similar to petroleum-
based inks to work with and clean from
presses. If an alternative cleaner was used
that took the operators longer or required
more effort for the soy inks then there
would be considerable resistance and cost.
5
In addition to using soy-based inks, there
are other strategies printers can use to
reduce wastes from the sheet-fed offset
printing. Since most emissions were from
use of the cleaners, these emissions could
be reduced if aqueous or less volatile
cleaners were used. The press operators
at OPS have not found any of the alterna-
tive products they tried to be acceptable.
It should be kept in mind that the use of
less volatile cleaners may increase liquid
wastes.
Another strategy to reduce waste would
be to reduce the use of cleaners and inks.
This can be done in two ways; both may
involve additional capital for equipment.
One way is to recover or reuse waste inks
and cleaners. Installing a solvent still to
recover chemicals from the washup tray
wastes and possibly reusing those chemi-
cals in formulating cleaners might be fea-
sible. Some large printers have reportedly
adopted this approach.
A second way to reduce cleaner and
ink usage would be to purchase auto-
matic blanket washers and ink roller train
systems. Literature from one manufacturer
of this equipment claims that as little as
220 to 275 mL of cleaning solvent can be
used during a print run when the auto-
mated systems are in use. Although this
would not eliminate the need for hand
cleaning, it could greatly reduce the
amount of cleaner used and, thus, the
emissions from the cleaners. It could also
reduce employee exposure to potentially
harmful substances. An automatic blanket
washer could reduce cleaner use by up to
90%. It should be noted that on some
presses where these systems have been
installed the operators actually increased
use of the cleaners because, even during
a print run, the blankets can be cleaned
without stopping the press. Automatic ink
handling systems allow this type of press
to be operated with about 80% less ink in
the fountain.
The automatic blanket washer and ink
handling systems also reduce makeready
and cleanup times, saving the press crew
time and exposure to volatile compounds.
At OPS, it was estimated that such a
system would have a payback of about 3
yr. Most cost savings would be expected
in the cost of cleaners and in reduced
cleanup time.
Overall, soy inks have some environ-
mental and other advantages for sheet-
fed offset printers. The main environmental
advantage with soy inks is that they re-
lease less than 20% of the mass of vola-
tile organic chemicals compared to
petroleum inks. The soy inks also spread
about 15% further, which offsets the small
difference in cost that currently exists. Re-
portedly, recycling of soy ink printed pa-
per also has some advantages. In this
study all other factors including makeready
time, appearance of printed product, and
cleanup effort were essentially equivalent
between the two types of inks.
The full report was submitted in fulfill-
ment of Contract No. CR-815829 by the
Hazardous Waste Research and Informa-
tion Center, University of Illinois at Urbana-
Champaign under the sponsorship of the
U.S. Environmental Protection Agency.
6
Beth Simpson. Pamela Tazik and Gary Miller are with the Hazardous Waste
Research and Information Center, Champaign, IL 61820.
Paul Randall is the EPA Project Officer (see below).
The complete report, entitled "Waste Reduction Evaluation of Soy-Based Inks
at a Sheet-Fed Offset Printer," (Order No. PB95-100046/AS; Cost: $17.50,
subject to change) will be available only from:
National Technical Information Service
5285 Port Royal Road
Springfield, VA 22161
Telephone: 703-487-4650
The EPA Project Officer can be contacted at:
Risk Reduction Engineering Laboratory
U.S. Environmental Protection Agency
BULK RATE
POSTAGE & FEES PAID
EPA
PERMIT No. G-35
United States
Environmental Protection Agency
Center for Environmental Research Information
Official Business
Penalty for Private Use
$300
EPA/600/SR-94/144

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