Name :

NRIC :

962 /

TRI!$ TERM $O%ER 6 2& '

ST

(!)!T!N *E$!(!R!N NE#ERI TEREN##!N+ CHEMISTRY One hour and thirty minutes

M!R"IN# SCHEME

TRIAL 1ST TERM LOWER 6 2013

"

ST*M

This answer paper consists of , printed pages SECTION !

-uestion No.

!ns/er

E012anation

Isotopes have the same proton numbers. Since protons are in the nucleus therefore the nuclear charges are the same. The relative molecular mass value unknown organic compound is 140. Parent ion peak is at m = 140 e
10

!"0 = #1" $ 10% & #1 $ "0% = 140

'

'alence electronic configuration of (d( 4s" indicates that vanadium can have o$idation states of &1 to &). The o$idation states of ' in '*4"+ is &,- in '*(+ is &)- in '*"& is &) and in '*"& is &4.

C onvergence limit is from n = 1 to n = .- f4 can be used to calculate the 4II and III5 energ/ difference between n = ( and n = " and f) to calculate the energ/ difference between n = 4 and n = " b/ using the e0uation 12 = h f. The difference in the energ/ between the two gives the energ/ difference between n = ( and n = 4. ) 3agnesium has " valence or delocali4ed electrons. 5umber o valence electrons = 10.0 $ " $ ,.0" $ 10"( "4 = ).0" $ 10"( Sulphur has a simple molecular structure where the intermolecular forces are van der 6aals forces. I(+ has ) orbitals with ( lone pairs of electrons and " bonding electron+ pairs- is linear according to 'S2P7 #valence+shell electron+pair repulsion theor/%. S*4"+ should be tetrahedral- 89( should be trigonal planar and P!( should be p/ramidal #with one lone pair of electrons%. 5umber of atoms in a unit cell = = = : corners $ 1 : 1 & 1 " & # 1 centre $ 1%

TRIAL 1ST TERM LOWER 6 2013

TRIAL 1ST TERM LOWER 6 2013 -uestion No. !ns/er

(
E012anation

ST*M

C T1 is of lower temperature- hence more molecules have lower energ/. 4II and III5 The activation energ/ for T1 and T" are the same as activation energ/ does not depend on temperature. The number of molecules for T 1 and T" are the same. & ! ;n increase in pressure will increase the boiling point of water. Ice will onl/ sublime at a pressure lower than ,11 Pa. ;t ,11 Pa and "<: =water e$ists in the gaseous phase. 7ate = k>;?m>8?n 2$p " =@ 4r = k#"a%m#b%n 2$p 1 r k#a%m#b%n =@ m = " 2$p ( =@ r = k#a%m#"b%n 2$p 1 r k#a%m#b%n =@ n = 0 =@ 7ate = k>;?" 2 8 =c = = >S*(?"A >S*"?">*"?

#4.,B"%"AAAAA #0.)0B"%"#0.010B"% = 1.C $ 104 ' ) ; Dewis base is an electron+pair donor. 5!( has a lone pair that is donated to the empt/ orbital in 89(. Det the solubilit/ be = / 3g#*!%" 3g"& & "*!+ / "/ & 0.1 / #"/ & 0.1%" = ".0 $ 10+11 8ut / E 0.1F therefore "/ & 0.1 G 0.1 0.01/ = ".0 $ 10+11 / = ".0 $ 10+< 6 ! The mi$ture shows negative deviation. Thus- intermolecular forces between the molecules in the mi$ture are stronger than those between molecules in the pure li0uids. ! l( and propanone molecules are held together b/ h/drogen bonds which are stronger than the van der 6aals

TRIAL 1ST TERM LOWER 6 2013

TRIAL 1ST TERM LOWER 6 2013 -uestion No. !ns/er

4
E012anation

ST*M

forces between ! l( molecules or propanone.

SECTION ) 4 Stru9tured -uestions 5

-+ESTION NO 64a54i5 S+##ESTE8 !NS%ERS ;H 145& 8H 1,* & H 1451,*& IH 1451,*" & 2H 145"1,*4 & Iinitrogen tetrao$ide 7elative atomic mass of 9e = )(.<4#).:"% & )).<(#<1.:0% & ),.<4#".10% & )C.<(#0.":% 100 = )).:4 >4 sfg? TOT!$ S+##ESTE8 M!R"S " correct 1 3 4 correct " 3 1 1

64:54i5 64:54ii5 64:54ii5

1 1 6 M!R"S

74a5

#(s (p (d % 13 #"s "p 1s% 13

74:5

13 each orbital Total 43

7495

n = (- 1

n = "- 1 n = 1- 1
TOT!$ 9 M!R"S

TRIAL 1ST TERM LOWER 6 2013

TRIAL 1ST TERM LOWER 6 2013

ST*M

SECTION C 4Essay -uestion5

TRIAL 1ST TERM LOWER 6 2013

-+ESTION NO TRIAL 1ST TERM LOWER 6 2013

S+##ESTE8 !NS%ERS

S+##ESTE8 M!R"S

,4a5

ST*M "

,4:5

;mmonia ;mmonium +In ammonium- all the h/drogen atoms are arranged tetrahedrall/. +!ence the bond angle is e$actl/ 10<.)J. + In the ammonia molecule- the greater repulsion between the lone pair of electrons compared to the repulsion between the bonded pair of electrons + causes the bond angle to be slightl/ smaller than 10<.)J . #10C0% omparing 2$periment 1 and " #where the concentration of 5*" is kept constant%r1Br" = #;1B;"%n (."0 $ 10+( :.00 $ 10+( = 1.0 ".) 0.40 = 0.40n

1 1 1 1

,4954i5

1 1

n=1 The reaction is first order with respect to fluorine. omparing 2$periment 1 and ( #where the concentration of 9" kept constant%(."0 $ 10+( = 1.) - 0.(0 = 0.(0n 1.0C $ 10+" ).0 n=1 The reaction is first order with respect to nitrogen dio$ide. ,4954ii5 7ate = k>9"? >5*"? ,4954iii5 The rate e0uation indicates that the rate determining step involves the reaction between one fluorine molecule and one nitrogen dio$ide molecule. Step I H 9" & 5*" K 5*"9 & 9 #slow% Step IIH 9 & 5*" K 5*"9 #fast% TOT!$ 94a54i5 =c remains unchanged. The amount of 5* increases. The e0uilibrium shifts to the right > this will help to reduce the amount of o$/gen in the s/stem?. =c remains unchanged. The amount of 5* does not change. The e0uilibrium is not affected b/ pressure > because the total number of moles of reactant product gases is the same.?

1 1

20 1&1#slow% 20 1&1#fast% 6 M!R"S 1 1

94a54ii5

1 1

TRIAL 94a54iii5 1ST TERM=c LOWER decreases. 6 2013 9or an endothermic reaction-

>the value e0uilibrium constant decreases when temperature is decreased.?

TRIAL 1ST TERM LOWER 6 2013

ST*M

EN8 O; M!R"IN# SCHEME

TRIAL 1ST TERM LOWER 6 2013