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FIITJEE - JEE (Mains)

BATCHES NWTRA35G01,NWTRA35A01-A04, NWTRA35C01-C02,


CAMP35, NWTW35A01-A02, NWTWA35A01-A07 & NWTWA35C01-C02

Reshuffling Test 1
Paper 1
PHYSICS, CHEMISTRY & MATHEMATICS

QP CODE: 120627.1
ANSWERS
Reshuffling Test 1

ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

A
B
D
D
C
C
D
B
B
C
D
C
A
C
A
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A

Physics
P110305
P110605
P110308
P110415
P110404
P110507
P110604
P110605
P110413
P110708
P110718
P110804
P110905
P110905
P110905
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Chemistry
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Mathematics
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414

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Hints & Solutions


SECTION 1 (Physics)
1.
Sol.
2.
Sol.
3.
Sol.

4.
Sol.

A (Concept Code: P110305)


60 20
Maximum acceleration =
= 4.
40 30
B (Concept Code: P110605)
1
tan = 45o
e
D (Concept Code: P110308)
1
(4 2)t + (1 2)t 2 = 0
2
1
T = 4,
=44+
(4)2
2
= 24 m
D (Concept Code: P110415)
dV 3 12t
=
dt 2

3t 6t 2
V =
= 0
2

5.
Sol.

C (Concept Code: P110404)


T = 8 2 3 10 = 2
f1 = T 1 = 1 ; f2 = 2 3 10 = 6

6.
Sol.

C (Concept Code: P110507)


W = 40 10 0.4 20

7.

D (Concept Code: P110604)


(6 8)2
K.E. =
= 288
2 4

Sol.
8.
Sol.

B (Concept Code: P110605)


1
Iu
W=
(2mu)2 (mu)2 = , I = 3mu
2m
2

9.
Sol.

B (Concept Code: P110413)


Force = Slope of curve

10.
Sol.

C (Concept Code: P110708)


VA = VC + VC VP = 2VC VP

11.
Sol.

D (Concept Code: P110718)


W 0.3 + 500 0.5 = T1 0.7
W + 500
and T1 = T2 =
2

12.

C (Concept Code: P110804)


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Sol.

(0.2 + xo) 10 = 4
xo = 0.2 m below 0.

13.
Sol.

A (Concept Code: P110905)


g r

14.

C (Concept Code: P110905)

Sol.

g
r
g
=

2
r +h

15.
Sol.

A (Concept Code: P110905)


F = ghA mg = 20N

16.
Sol.

D (Concept Code: P111101)


F r2

17.
Sol.

A (Concept Code: P111101)


V = (100 cm3) (4 105) (100)

18.
Sol.

C (Concept Code: P111026)


Surface energy Surface area.

19.

A (Concept Code: P111213)


(T T1 )(T3 T2 )
W = nR 2
10 kJ
T2

Sol.

20.
Sol.

B (Concept Code: P111207)


1
5 20 1 = 2 20 + m 80
2
m = 1 kg ice melts
So, mass of water = 5 + 1 = 6 kg.

21.
Sol.

D (Concept Code: P111213)


Use gas equation PV = nRT

22.
Sol.

C (Concept Code: P111005)


N mg = ma N = mg + ma N = mg + M3g = 4W

23.

A (Concept Code: P110613)


d ( mgh )
dm
dm 3 103
= gh
=
= 50 kg / sec , P =
dt
60
dt
dt
= 50 x 10 x 25
= 12500 W

Sol.

24.
Sol.

B (Concept Code: P111005)


When stones are there inside the boat. the volume of water displaced is equal to the
weight of the boat + stones. When stones are unloaded into the water the volume of
water displaced is equal to the volume of stones unloaded plus (weight of boat) /
(density of water). This time the displaced volume of water is smaller than in the first
case. Therefore the water level falls.

25.

A (Concept Code: P111303)


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4 2 2
2
=
m/s
3
27
(2 + 2 2)

Sol.

V=

26.

B (Concept Code: P111306)


2

=
= 1M ;
= 50 cm
2
2

Sol.
27.
Sol.

28.
Sol.

C (Concept Code: P111307)

Sin
VP
1
4

=
=
VQ

2
Sin
2

B (Concept Code: P111103)


(g +a) 1 = g
b

a
=
b g + a

29.
Sol.

A (Concept Code: P111103)


Phase diff. = ( 2)
a
1
Cos = 3 =
a 3

30.
Sol.

A (Concept Code: P110723)


Force produces zero torque about the centre which is the point of rotation because
= r F , It = 0 the L is constant.

1.
Sol.

1.

C
Fe = [Ar]184s23d6
Fe+ = [Ar]184s13d6 (Contains 5 unpaired electrons)
Fe3+ = [Ar]184s03d5 (Contains 5 unpaired electrons)
C110108

2.
Sol.
2.

C
Li and Mg display diagonal relationship.
C110705

3.
Sol.
3.

C
The central atoms of SF4, CF4, XeF4 and SeF4 undergo sp3d, sp3, sp3d2 and sp3d
hybridization respectively.
C110306

4.
Sol.

B
Meq of metal ion = Meq of MnO4 solution

SECTION 2 (Chemistry)

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[

4.

W
1000 = N V
E
26
1000 = 400 1 5 = 2000
or,
52 / n
or, n = 4
Change in oxidation number of 4 units.
C111102

5.

Sol.

R.M.S speed of CH4 =

5.

3RT
3R 800
=
= 150R
M
16
2RT
2 R 300
=
= 150R
Most probable speed of He =
M
4
C111206

6.
Sol.
6.

C
Plaster of paris(CaSO4).H2O sets on standing to a hardmass.
C110908

7.
Sol.
7.

D
H2O2 easily decomposes to H2O and O2 even in presence of dust particles.
C111006

8.
Sol.

8.

A ( g)
2B ( g)
a
0
ax
2x
For 1:1 molar ratio, a x = 2x x = a/3
2.303
a
2.303
3
t=
log
=
log = 1635.3 sec = 27.25 min
k
aa/3
k
2
C110606

9.
Sol.

D
X ( s)

2Y ( g ) + 3Z ( g)
2

KC = [Y] [Z]3
[2Z]3 [Y]2 = [Y]2[Z]3
[ Y '] =
2

or, [Y] =

[Y]

[Y]
2 2

9.

C110401

10.
Sol.

B
At second equivalence point the only species present at appreciable concentration is
HPO24 .

pH =

K a2

10.

C110502

11.

+p
2

K a3

12 + 8
= 10
2

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[

Sol.
11.

It is a neutralization reaction.
C111906

12.
Sol.
12.

C
X is HBO2 which is obtained by removing one water molecule from H3BO3.
C111505

13.
Sol.
13.

D
The compound in (D) after hydrolysis does not polymerise beyond two molecules.
C111607

14.
Sol.
14.

B
II and III are stabilized by resonance and II is aromatic. IV (1o) is more stable than 1(2o).
C111303

15.

C
Cl

Sol.

CH3CH2CHCH3

Cl2

CH3 CH2 CHCH2Cl + CH3 CHCHCH3

CH3

CH3

CH3

15.

C111404

16.
Sol.
16.

B
Orientation of product takes place according to the activating group(OH).
C111804

17.
Sol.

C
The initially formed 3o carbocation undergoes rearrangement to another 3o carbocation
for more no. of hyperconjugative structures. Then ring expansion followed by methyl shift
takes place.
C111705

17.
18.
Sol.

18.

D
It is most soluble in NH4OH due to complex formation, followed by KNO3. AgNO3 and
NaCl exert common ion effect. Therefore, it is more soluble in low conc. NaCl than that
in higher conc. AgNO3.
C110501

19.

Sol.

Rate =

19.

= 3 Rate = 3 1.2 103 = 3.6 103 mol L1s1.


dt
C110601

20.

Sol.

20.
21.

d [I2 ]

1 d [I2 ]
3 dt

0.693
t1/2
k
0.693 / 10 1
KC = 1 =
=
= 0.1
k2
0.693 / 1 10
C110606
k=

C
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Sol.
21.

It has maximum number of hyperconjugative structure.


C111706

22.
Sol.
22.

D
In(III), negative charge is present on oxygen and in (I) it is present on carbon. So (III) is
more stable than (I). (II) is most unstable due to more number charged species.
C111301

23.
Sol.

Na2CO3
No gas is produced

23.

Li2CO3
CO2 is evolved
C110804

24.
Sol.
24.

A
Due to p - p back bond formation in BF3.
C110306

25.
Sol.
25.

D
Due to weak C I bond in comparison to other C X bonds.
C111606

26.
Sol.
26.

C
At equilibrium, Ssys. + Ssurr. = 0
C111906

27.
Sol.
27.

C
Due to presence of bulky methyl group, NO2 does not exhibit R effect in (C).
C111301

28.
Sol.
28.

D
X = CH3CH2CH2CH3, Y = Trans-2-butene
C111713

29.

Sol.

It gains aromaticity by forming the cation ,

29.

C111801

30.
Sol.
30.

D
(D) gives four geometrical isomers as it is not symmetrical like the other compounds.
C111403

, and Cl.

SECTION 3 (Mathematics)
1.
Sol.

D
M111301
The given series is geometric with an initial term of 1 and a common ratio of cos2 , so
its sum is

1
1
5 = cos2n =
=
2
1 cos sin2
n=0
1
Therefore sin2 = , and
5
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cos 2 = 1 2 sin2 = 1
2.
Sol.

2 3
=
5 5

D
M110909
Let B = ( a, b ) and A = ( a, b ) . Then

4a2 + 7a 1 = b

and 4a2 7a 1 = b
50
=5 2
So AB = 2 a2 + b2 = 2
4
3.

M110204

Sol.

We have sin1 > 0 = log10 1 and sin

4.
Sol.

A
M110302
9z1z2 + 4z1z2 + z2 z3 = ( z3 z3 ) z1z2 + ( z1z1 ) z2 z3 = 12

3
3
5
= 1 < 0log10
< 10 and
. Since < 4,
2
2
2
5
5
7
7
log10
> 0 > 1 = sin
< 1 = sin
Also, log10
2
2
2
2
Since both functions are continuous we have at least one real roots in each of the
3 3 5
5 7
, ,
and ,
intervals 1,

2 2
2 2 2

Or, z1z2 z3 ( z1 + z2 + z3 ) = 12 or, z1 z2 z3 z1 + z2 + z3 = 12


Or, z1 + z2 + z3 = z1 + z2 + z3 =
5.

Sol.

12
=2
32

M111004
x
Here
= cos t + sin t
4
y
= cos t sin t
and
7
Squaring and adding equation (1) and (2)
x2 y2
+
= 2 (sin2 t + cos2 t)
16 7
x2 y2
+
= 1 , which is an ellipse

32 14

eccentricity e =

(1)
(2)

b2
14 3
= 1
= .
2
32 4
a

6.
Sol.

C
M111205
Total number of ways = 6 6 ....... to n times = 6n .
Total number of ways to show only even numbers = 3 3 .........n times 3n
The required number of ways = 6n 3n .

7.
Sol.

A
M110903
Any point on the parabola is (x , x2+ 7x + 2)
Its distance from the line y = 3x 3 is given by

P=

3x x 2 + 7x + 2 3
9 +1

x 2 + 4x + 5
10

x 2 + 4x + 5
10

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(as x2 +4x + 5 > 0 for all x R)


dP
= 0 x = -2
dx
The required point (-2, -8).
8.
Sol.

D
M110410
( 1 x4) (1 + 9C1 x+ 9C2 x2 + 9C3 x3 9C9x9)
Coefficient of x7 = 9C7 9C3 = 48

9.
Sol.

B
M111203
Total number of ways of posting the letters
= 36 3C1 26 + 3C2 = 540.

10.
Sol.

D
M110304
| iz + ( 3 4i)| | iz| + |3 4i|
= |z| +5 < 4 + 5 = 9.

11.

M110410
10

Sol.

x +1
x 1

In the expression 2/3

1/3
1/2
x x +1 x x
3
To simplify, for first term put x = p and for second term put x = q2, then it will
become (x1/3 x-1/2)10
Tr+1 = 10Cr(x1/3)10-r ( x 1/2)r
For term independent of x;
10 r r
10 r r
=0
x 3 x 2 = x0
3
2

5r = 20 r = 4 T5 = 10C4
12.
Sol.

C
M110101
Given , are roots of equation x 2 2x + 3 = 0

2 2 + 3 = 0
and 2 2 + 3 = 0

.(1)
.(2)

2 = 2 3, 3 = 2 2 3

P = 2 2 3 3 2 + 5 2 = 2 + 2 2 = 3 2 = 1, by Eq. (1)
Similarly, we can have Q = 2
Sum of roots = 3 and product of roots = 2
So, the required equation is x 2 3x + 2 = 0
13.
Sol.

D
M110505
Let d be the common difference of the A.P., then
3 = a10 = 2 + 9d d = 1/9
a4 = 2+3d = 7/3

Next, let D be the common difference of the A.P.

1 1
1
, ,...
Then
h1 h2
h10

1
1
1
1
=
= + 9D D =
3 h10 2
54
1
1
7
18
= + 6D =
h7 =
h7 h1
18
7
Hence, a4 . h7 = (7/3) (18/7) = 6.
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[

10

14.

Sol.

M111301

4a2
a2 cos2 2
+
sec 2 + cos ec 2 cos2 + sin2
2
2
= a (sin 2 + cos2 2) = a2
And p12 p22 = a 4 sin2 2 cos2 2 = (1/ 4 ) a 4 sin2 4
p12 + p22 =

p12 + p22
p p
4
1 + 2 =
=
= 4 cos ec 2 4
2 2
2
p1 p2
sin 4
p2 p1
2

15.
Sol.

B
M111403
The given expression is equal to

cos2 10o + cos2 50o cos 50o cos10o

(
= ( 2 sin 20

= cos10o cos 50o

+ cos10o cos 50o

1
cos 60o + cos 40o
2
1
1 1

= (1 cos 40o ) + + cos 40o


2
22

3
=
4
o

sin30o

16.

M110305

Sol.

z1 + z2 = z1 + z2

z1 + z2 = z1 z 2
z1 + z1 = z2 z2
z1 + z1
= 1 = ei
z2 + z2

17.

Sol.

18.
Sol.

M110413
n
a
C
n r +1
1+ r = 1+ n r = 1+
ar 1
r
Cr 1
n +1
=
r

B
M111301
The expression is equal to 3 cos4 + sin4 2 cos6 + sin6

2
3
= 3 ( cos2 + sin2 ) 2 cos2 sin2 2 ( cos2 + sin2 ) 3 sin2 cos2 ( sin2 + cos2 )

= 3 1 2 sin2 cos2 2 1 3 sin2 cos2 = 1


19.
Sol.

A
M110733
x2 y2 + 2y 1 = 0
Equations of lines are y = x + 1, y = x + 1
angle bisectors are y = 1 and x = 0
1
area of triangle = 2 2 = 2 sq. units
2
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11

20.

Sol:

21.
Sol.

Not Available
2
1 n
1 n(n + 1)(2n + 1) (n + 1)2
n + 1
2 = r 2
=

n r =1
n
6
4
2
2
2n + 1 n + 1 (n + 1)(4n + 2 3n 3) n 1

=
=
= (n + 1)

4
12
12
6
Hence, B is correct answer

D
M111301
According to given condition
Sin + sin = a and cos + cos = c
+

cos
= a and 2 cos
Or , 2 sin
2
2
a
+
=
Now
Or , tan

c
2

+

cos
= c
2
2

+
2 tan

2 = 2ac
sin( + ) =
a2 + c 2
+
1 + tan2

2
22.

M111502

Sol.

Note that cot A + cot B =

23.
Sol.

D
M110808
Let the line y = x intersect the
circle and the line y = 6 at M and K,
respectively, and let the line y = x
intersect the circle and the line
y = 6 at N and L, respectively.
Quadrilateral PMON has four right
angles and MP = PN, so PMON is a
square. In addition, MK = KJ=6 and
KO = 6 2 . Hence
r = MO = MK + KO = 6 + 6 2

cos A sinB + cosB sin A


sinC
=
sin A sinB
sin A sinB
cot C
sin A sinB
cos C
=
Hence
cot A + cot B sin C sinC
By the Laws of the Sines and Cosines,
2
2
2
9 ( a2 + b2 ) 9c 2 5
cot C
a b a + b c
=
=
=
cot A + cot B c c
2ab
9
18c 2

y
P

N
M
K

24.
Sol.

C
M110501
We have b = a + r, c = a + 2r, and d = a + 3r, where r is positive real number. Also

b2 = ad yields ( a + r ) = a ( a + 3r ) , or r 2 = ar . If follows that r = a and d = a + 3a = 4a .


2

Hence

a 1
=
d 4

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12

25.

Sol.

M110701

1
and y intercept
2
1
(0, 9), so its equation is y = x + 9
2
Since the coordinates of A satisfy both this
equation and y = x, if follows that
Line AC has slope

A ' = ( 6,6 ) .
Similarly, line BC has equation
y = 2x + 12,

y
B
(0,12)
A

y=x
C (2 , 8)

(0,9)

A'
B'

and B ' = ( 4, 4 ) . Thus


A 'B ' =
26.
Sol.

(6 4)

+ (6 4) = 2 2
2

A
M110504
18log x = k, 21log y = k, 28log z = k

x18 = y 21 = z28
3,3 logy x, 3logz y, 7logx z are in
18 log x = k
21 log y = k
28 log z = k
k
k
k
3, 3 18 , 3 21 , 7 28
k
k
k
21
28
18
21 28 18
3,
,
,
6 7
4
7
1
3, , 4, 4 are in A.P
2
2
27.
Sol.

28.

Sol.

A
M110826
The given circle is (x 1)2 + (y 1)2 = 1.
3
In the figure MC = 1
2
locus of the point M is
3
(x 1)2 + (y 1)2 = .
4

A
M
1
B
1

C(1,1)

M110503
a
a1 = , a2 = a, a3 = ar
r
If a1, a2 , a3 ( a1 > 0 ) are in G.P.

9a1 + 5a3 14a2


9

a
+ 5ar 14a
r

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13

9
+ 5r 14
r
5r 2 14r + 9 0
5r 2 5r 9r + 9 0
9
The internal is 1,
5

29.

M110109

Sol.

x + 18x + 30 = 2 x 2 + 18x + 30 + 15
Let x 2 + 18x + 30 = y
2

y = 2 y + 15
y = 6 (rejected),y=10

Or x 2 + 18x + 20 = 0
product of real roots=20
30.
Sol.

D
M110414
4n
2 15n 1

(1 + 15 )

15n 1

=n C2 152 +n C3 153 + ............... + n Cn 15n


= divisible by 225.

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[

14

QP CODE: 120627.2
ANSWERS
Reshuffling Test 1

ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

C
D
B
B
C
D
C
A
C
A
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
A
B
D
D
C

Physics
P110507
P110604
P110605
P110413
P110708
P110718
P110804
P110905
P110905
P110905
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
P110305
P110605
P110308
P110415
P110404

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Chemistry
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Mathematics
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[

15

QP CODE: 120627.3
ANSWERS
Reshuffling Test 1

ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

D
C
A
C
A
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
A
B
D
D
C
C
D
B
B
C

Physics
P110718
P110804
P110905
P110905
P110905
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
P110305
P110605
P110308
P110415
P110404
P110507
P110604
P110605
P110413
P110708

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Chemistry
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Mathematics
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304

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[

16

QP CODE: 120627.4
ANSWERS
Reshuffling Test 1

ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
A
B
D
D
C
C
D
B
B
C
D
C
A
C
A

Physics
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
P110305
P110605
P110308
P110415
P110404
P110507
P110604
P110605
P110413
P110708
P110718
P110804
P110905
P110905
P110905

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Chemistry
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Mathematics
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403

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[

17

Paper-2
PHYSICS, CHEMISTRY & MATHEMATICS

CODE: 120628.1
ANSWERS
Reshuffling Test 1

ANSWER KEY

1
2
3
4
5

C
D
C
D
D

8
9
10
11
12
13

B
B
B
C
A
A

14

15
16
17
18
19
20

ABC
AC
AB
CD
ACD
AD

1
2
3
4

3
1
4
8

Physics
Part A
P110309
P110310
P110806
P111012
P110610
P111302,
P111305
P111026,
P111209
P110815
P110815
P110815
P110815
P111105
P111105
P111105,
P111222
P111207
P111105
P111010
P111002
P110912
P110917
Part C
P110606
P110705
P110807
P111309

1
2
3
4
5

Chemistry
Part A
B
C110101
D
C110307
C
C110504
D
C111804
C
C111507

1
2
3
4
5

Mathematics
Part A
C
M111502
B
M110406
B
M111210
A
M111201
A
M110101

C111401

M110504

C110402

M110902

8
9
10
11
12
13

C
D
C
B
B
A

C111302
C110603
C110603
C110603
C111902
C111903

8
9
10
11
12
13

B
D
A
B
C
D

M111214
M110101
M10101
M110107
M110902
M110910

14

C111905

14

M110902

ABCD C110908
ABCD C111804
AB
C111509
ABCD C111204
BC
C111102
BCD
C110503
Part C
8
C110402
9
C111301
5
C110809
6
C110107

15
16
17
18
19
20

ABCD
ABC
AC
BD
AD
BC

1
2
3
4

2
2
1
3

M1105010
M110415
M110406
M111103
M110719
M110810
Part C
M111422
M110304
M111426
M110510

15
16
17
18
19
20
1
2
3
4

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[

18

Hints & Solutions


Physics
PART A
1.
Sol.
2.
Sol.

C (Concept code: P110309)


Displacement
Vavg =
Time taken
D (Concept code: P110310)
1
x2
y = x tan g 2
2 u cos2

3.

C (Concept code: P110806)

Sol.

Net force is equal to mass multiplied by acceleration and net torque about cm should be
zero.

4.
Sol.

D (Concept code: P111012)


F = (mg + kv)
v decreases as ball goes up
Constant downward force + decreasing downward force.

5
Sol.

D (Concept code: P110610)


VB = VBW + VW
4 2 = approach velocity
= rebound velocity
w.r.t wedge

4
4

6.
Sol.

B (Concept code: P111302, P111305)


y0 2f = 4f

7.
Sol.

A (Concept code: P111026, P111209)


Wgas + Watm + WS = 0

8.
Sol.

B (Concept code: P110815)


V dT (Hg glass) = r2 dh

9.

B (Concept code: P110815)

Sol.

COTME Kf = mg

(i)

1
m 2 = mg
2
3
2
3g
w=

and

10.

B (Concept code: P110815)

Sol.

COTME Kf = mg

11.

C (Concept code: P110815)

Sol.

Vcm =

IAR

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[

(f)

19

12.

A (Concept code: P111105)

Sol.

Time taken to move from mean to extreme (t) =


Time period = 4t = 4

2A
=
(F / m)

2Am
F

2Am
F

13.
Sol.

A (Concept code: P111105)


Acceleration = constant velocity time curve should be straight line.

14.

B (Concept code: P111105, P111222)

Sol.

A
T = Time taken to reach from (A) to (0) Time taken to reach from ( A) to

2
2A
2(A / 2)

=
F/m
F/m

15.
Sol.

ABC (Concept code: P111207)


e=a
m
And =
v

16.
Sol.

AC (Concept code: P111105)


The force experienced by pendulum will be same, while they will move in opposite
direction. (phase diff. = rad)

17.
Sol.

AB (Concept code: P111010)


The velocities at upper end and lower end of the lower pipe are not equal, so it will not
be fully filled.

18.
Sol.

CD (Concept code: P111002)


Free body diagram.
N

4Po r2

Po r2

19.
Sol.

ACD (Concept code: P110912)


For the angular momentum to remain conserved, the final velocity of the particle must
not be zero.

20.

AD (Concept code: P110917)


GM
V=
[3R2 r 2 ], inside the earth.
2R3

Sol.

PART C
1.
Sol.

3 (Concept code: P110606)


1

2
2

V2

v 2
I = 2

2 2

v2 = 6

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[

20

2.

1 (Concept code: P110705)

Sol.

R
I1 = Icm + m
2

R
and I2 = Icm + m
2
3.
Sol.

4.
Sol.

R/2

cm R/2

4 (Concept code: P110807)


F
FR
acm = and =
2
m
mR 2
3
8 (Concept code: P111309)
4 1 2 2
=
3
4

Chemistry
PART A
1.
Sol.

1.
2.
Sol.

B
Kinetic energy = e stopping potential
K.E 6.4 1019
=
=4V
Stopping potential =
e
1.6 10 19
C110101

2.

D
The bond order of O22+ is highest among the given species.
it contains the strongest covalent bond
C110307

3.
Sol.

C
pK a = - log(2 104) = 3.7

pH = pK a + log

[Salt ] , or 3.4 = 3.7 + log x , on solving x = 0.05.


0.1
[ Acid]

3.

C110504

4.
Sol.

D
The activating order of the group attached to benzene ring is:
NHCOCH3 > CH2CONH2 > CONHCH3 > COCH2NH2
( + Re ffect )

(Hyperconjugation )

Low charge density


carbonyl carbon

High charge density


carbonyl carbon

4.

C111804

5.
Sol.
5.

C
X = B3N3H3Cl3
C111507

6.
Sol.
6.

D
In both compounds the CH3 groups are at different positions.
C111401

7.

B
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21

Sol.

G0 = - RT nK
or, H0 TS0 = - RT nK

H0 1 S0
+
R
T
R
y = mx + c
or, nK =
A

nK

Intercept =

1/T

S0
= 4 S0 = 4 2 = 8 Cal K1 mol1.
R

7.

C110402

8.
Sol.
8.

C
Acidic strength: Penolic OH > 1o OH > 2o OH >3o OH
C111302

9.
Sol.
9.

D
H = HP HR = 20 40 = - 20 kJ
C110603

10.
Sol.
10.

C
Energy of product + Ea(b) of uncatalysed reaction = 140
Ea(b) = 140 - 20 = 120 kJ
C110603

11.
Sol.

B
Let activation energy of the forward reaction for the catalysed reaction be E'a .

E'a = Ea x
Where x = amount of energy lowered down by the catalysed reaction.
k(catalysed reaction) = k(uncatalysed reaction)

AeEa /R 500 = AeEa /R 300


'

11.

Ea
E'
E x
= a = a
500 300
300
Since Ea = 100 kJ, x will be 40 kJ
C110603

12.
Sol.

B
W = WA B + WB C + WC A

or,

= 0 + (-2.303 nRT log

VC
+ [-P(VA - VC)]
VB

VB
+ P(VC VA)
VC
V
= 2.303 PBVB log B + P(2V V)
VC
= 2.303 nRT log

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[

22

V
+ PV
2V
1
= 2.303 3 PV log + PV
2
= 2.303 3 PV -0.3010 + PV
= - 2PV + PV = -PV
C111902
= 2.303 3PV log

12.
13.
Sol.

A
C A is isobaric path
PV
5
5 P V
q = nCPT = 1 R [ TA TC ] = R A A C C
2
2 R
R
5 PV 2PV
5
= R
= PV

2
R
2

A B is isochoric path
P V
3
3 P V
q = nCVT = 1 R [ TB TA ] = R B B A A
2
2 R
R

3 3PV PV 3
R
= 2 2PV = 3PV
2
R

C111903
=

13.
14.
Sol.

B
Moles of gas at A = Moles of gas at B
PA VA PB VB
=
RT1
RT2

14.

PV 3PV
=
T2 = 3 T1
T1
T2
When moles at A and C are compared, T2 will be equal to 2 T1.
C111905

15.
Sol.

ABCD
Cold
2 Ca ( OH)2 + 2 Cl2
CaCl2 + Ca ( OCl )2 + 2H2O

or,

Hot
6 Ca ( OH)2 + 6 Cl2
5 CaCl2 + Ca ( ClO3 )2 + 6H2O

30 C
Ca ( OH)2 + Cl2
CaOCl2 + H2O
o

15.

C110908

16.

ABCD
CH3 O

Sol.

CH3O
AlCl

3
CH3 C C Cl
CH3 C C

CH3

CH3

CH3

CH3 C + CO
CH3

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[

23

C(CH3)3

Both the above electrophiles form products and polysubsitution of

takes place

at the para position. As (CH3)3C CO+ is a deactivating group, polysubstitution of


O = C - C(CH 3)3

does not take place.


16.

C111804

17.
Sol.
17.

AB
Graphite is black whereas BN is white. Graphite is a poor conductor but BN does not
conduct at all.
C111509

18.

ABCD

Sol.

For isochoric curve, P =

18.

For isobaric curve,


PV Pb = RT
or, PV = RT + Pb
R
or, V = T + b y = mx + C
P
Gas shows positive deviation. So attractive forces overcome by repulsive forces.
C111204

19.
Sol.
19.

BC
H3PO3 is a dibasic acid and H3PO2 is a monobasic acid.
C111102

20.
Sol.

BCD
These ions undergo hydrolysis in water
NH+4 + H2O
NH4 OH + H+

20.

R
T y = mx
V b

CN + H2O

HCN + OH

Fe+ + H2O
C110503

FeOH+ + H+

Part C
1.
Sol.

C ( s ) + CO2 ( g)
2CO ( g)
P
0
Px
2x
P x + 2x = P + x = 6
P
P + = 6 P = 4 and x = 2
2
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24

K P

(p )
= CO

pCO2

( 4)
=
2

16
= 8 atm
2

1.

C110402

2.
Sol.
2.

9
The carbocation has 6 and the double bond has 3 hyperconjugation structures.
C111301

3.
Sol.
3.

5
X = NaHCO3, Y = HCOONa
C110809

4.
Sol.

6
n = 4, = 0, 1 4s and 4p subshells
m = 0, +1 4s, 4px and 4py
s = 4s2 , 4p2x and 4p2y = 6 electrons

4.

C110107

Mathematics
PART A
1.

Sol.

M111502
b2 + c 2 a2 c 2 + a2 b2 a2 + b2 c 2 a2 + b2 + c 2
Expression=
+
+
=
2abc
2abc
2abc
2abc
=

2.

Sol.

( a + b + c )2 2 ( ab + bc + ca ) = 112 2.38 =
2abc

2.40

9
16

M110406
z + z0i
Center is 0
and Diameter is z0
2

3.
Sol.

B
M111210
The first and last digits must be both odd or both even for their average to be an integer.
There are 5 . 5 = 25 odd odd combinations for the first and last digits. There are 4 .5
=20 even even combinations that do not use zero as the first digit. Hence the total is
45.

4.

Sol.

M111201

a
, We may assume that a > 0 and b < 0 so that a b . We
b
must also have a c b . If c = 0 , there are 3 ways to choose a and 3 ways to choose
The slope of the line is

b.
However, the lines x y = 0, 2x 2y = 0 and 3x 3y = 0 are the same. Thus the
number of lines in this case is 3 2 2 = 7 . If c 0, there are 3 ways to choose a, 3 ways
to choose b and 4 ways to choose c. Thus the number of lines in this case is 3 2 4 = 36 .
The total is 7 + 36 = 43 .
5.

A M110101

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[

25

Sol.

Multiplying the given equation by

c
, we get
a3

b 2c 2 2 b2 c
x 2 x+c =0
a3
a
2
bc
bc
a 2 x b 2 x + c = 0
a
a
bc
2 x = ,
a
( + ) x = ,
1
1
x=
.
,
( + ) ( + )
6.
Sol.

A
M110504
Let the common ratio be r. Then

a + log4 3
a + log2 3
a + log8 3
=
a + log4 3
log4 3 log8 3
=
log2 3 log4 3
1
1
log2 3 log2 3
3
= 2
1
log2 3 log2 3
2
1
=
3

r=

7.

M110902

Sol.

The roots of n2 + n x 2 ( 2n + 1) x + 1 = 0 are

1992

1992

n =1

n =1

A nBn =

8.
Sol.

1
1
and
. Hence
n
n +1

1992

n n + 1 = 1 1993 = 1993

B
M111214
We have

1!.2!.3!......9! = (1)(1.2 )(1.2.3 ) = (1.2...9 )


= 19 2837 4655 6 4738 291 = 2303135573

The perfect square divisors of that product are the numbers of the form 22a 3 2b 5 2c 7 2d
with 0 a 15, 0 b 6, 0 c 2 , and 0 d 1. Thus there are

(16 )( 7 )( 3 )( 2) = 672 such number


9.
Sol.

D
M110101
+ + = 0 + + = q

= r

+ q + r = 0
3

3 = q r
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26

5 = 3 q 2r
5 = q ( q r ) 2r

= + q2 + q 2r

5 = q2 ( + + ) + 3qr r ( 2 + 2 + 2 )
= 5qr
10.

Sol.

M10101

1
=
=
3
q
q r + r

11.
Sol.

B
M110107
3 + = 0, 3 + 3 2 = c, 3 = d
1 3
c
8d
+ = =

d
3c

12.

13.

M110902
M110910

14.
B
M110902
SOLUTION_12 14
1 2m
1 + 2m
h=
,k =
2l
2m
1
k 2
m=
l=
2k 2
2h ( k 1)

(l,m) lies on y 2 = 4ax


m2 = 4al
2
k2
1
2k 2 = 4a 2h k 1
)

3
1

x = 8a y 2 3y + 2 y =
( x + 2a )
2
8a

3
1

vertex is 2a, length of latus rectum =


8a
2

3
curve in symmetric about line y =
2
15.
Sol.

ABCD
M1105010
b is the H.M. of a and c and their G.M. =

ac

ac > b
G.M > H.M
n
And A.M. of a and cn > G.M. of an and cn

an + c n
> anc n
2

)n

a n + c n > 2 ac > 2b n
Put n = 100, 3, 5, 2

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27

16.
Sol.

ABC
M110415
Putting x = in the equation,
.... (1)
0 = a0 + a1 +a22 +a3 + . . .
2
Putting x = in the equation,
.... (2)
0 = a0 + a12 +a2 + a3 + . . .
Putting x = 1 in the equation,
...
.... (3)
3n = a0 + a1 +a2 + a3 +
adding (1), (2) and (3),
.... (a)
3n = 3(a0 +a3 +a6 + . . . .)
a0 + a3 +a6 + . . . . = 3n-1 (option C)
subtracting (2) from (1),
0 = ( - 2) (a1 a2 + a4 a5 + . . . )
. . . (4)
Since - 2 0 , a1 +a4 + a7 +. . . = a2 + a5 +a8 + . . .
. . . .(5)
Also from (3) (a), a1 + a2 +a4 +a5 + . . . . = 3n 3n-1 = 2.3n-1
From (4) and (5) , a1 +a4 + a7 +. . . = a2 + a5 + a8 + . . . = 3n-1 = a0 + a3 + a6 + . .

17.
Sol.

AC
M110406
Clearly the inscried triangle is equilateral.
2
2
i
i
z z0
z z0
2
=e 3, 3
=e 3
z1 z0
z1 z0

z2 = -1 +i(2 +

3 ) and z3 = -1 + i(2 -

z2

3)

z0(2i)
z3

18.

Sol.

BD

z1(2 +2i)

M111103

x2 y2
+
=1
a2 b2
x2 y2
which is of the from 2 + 2 = 1 with a2 = 22 , b2 = 12
a
b
2
2
2
Here 1 = 2 1 e
Equation of the ellipse is

( b = a (1 e ))
Foci of the ellipse are ( 3, 0 ) and ( 3, 0 )

e=

3
2

Eccentricity of the hyperbola =

3
1
4
b2 = a2 1 3b2 = a2 b2 = a2
3
3

Equation of hyperbola is

x 2 3y 2
2 =1
a2
a

Also the hyperbola passes through a focus of the ellipse, i.e.

3, 0

3
= 1 a2 = 3 .
2
a
Hence, the equation of hyperbola is x 2 3y 2 = 3

2
A focus of hyperbola is ( ae, 0 ) = 3
, 0 = ( 2, 0 )
3

19.

AD

M110719

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28

Sol.

P lies on the line 2x + 3y + 1 = 0


........(1)
|PA PB| is maximum if P, A, B are collinear.
Equation of the line AB is
x + y = 2
........(2)
P is the point of intersection of (1) and (2) which is (7, 5)
Equation of perpendicular bisector of AB is
y = x
.......(3)
For minimum value of |PA PB| ,
1 1
P is the point of intersection of (1) and (3) which is ,
5 5

20.
Sol.

BC
M110810
Let L1 : y = mx
Putting y = mx in the equation of circle , we get
x2 + m2 x2 x + 3mx = 0
x[ (1+ m2)x 1 + 3m] = 0
1 3m
x = 0,
1 + m2
So points of intersection of L1 and the circle are

m (1 3m )
P1(0, 0), P2 1 3m ,

2
1 + m2
1 + m
Also points of intersection of L2 and the circle are Q1(1, 0) and Q2(2, 1).
By the given condition;
P1P2 = Q1Q22
(1 + m2) (3m 1)2 = 2(1 + m2)2
(3m 1)2 = 2(1+ m2)
7m2 6m 1 = 0
1
(7m + 1) (m 1) = 0 m = 1,
7
1
So L1 : y = x, y = x
7
i.e. x y = 0, 7y + x = 0.

Part C
1.
Sol.

2 M111422
4 [1 + cot2 (a + x)] + a2 4a = 0
4cot2 (a + x) + (a 2)2 = 0
a 2 = 0 and cot2 (a + x) = 0
a = 2.

2.

Sol.

M110304

z1 2z2

(z

= 2 z1z2

)( z

2
2

1 = 0

z1 = 2
3.

Sol.

M111426
1

3 cos
x 2 6 x + 10 is defined if x2 6x + 10 1
if x2 6x + 9 0
if |x 3|2 0
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29

if x 3 = 0
if x = 3
4.

Sol.

Given expression is
=

M110510

1
(a + b + c)
2

1
2a
1
=
2
b+ca 2
1

3
b +c a 2

Now, as (a + b + c) =

b + c a + 1 2
2a

(b + c a)

Applying A.M. H.M.


Minimum value of the expression =

1
3
9 = 3
2
2

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[

30

CODE: 120628.2
ANSWERS
Reshuffling Test 1

ANSWER KEY

1
2
3

C
D
D

6
7
8
9
10
11
12

B
C
D
B
C
B
A

13

14
15
16
17
18
19
20

A
AB
CD
ACD
AD
ABC
AC

1
2
3
4

1
4
8
3

Physics
Part A
P110806
P111012
P110610
P111302,
P111305
P111026,
P111209
P110815
P110309
P110310
P110815
P110815
P110815
P111105
P111105,
P111222
P111105
P111010
P111002
P110912
P110917
P111207
P111105
Part C
P110705
P110807
P111309
P110606

1
2
3

Chemistry
Part A
C
C110504
D
C111804
C
C111507

1
2
3

Mathematics
Part A
B
M111210
A
M111201
A
M110101

C111401

M110504

C110402

M110902

6
7
8
9
10
11
12

C
B
D
C
B
D
A

C111302
C110101
C110307
C110603
C110603
C110603
C111903

6
7
8
9
10
11
12

B
C
B
A
B
D
D

M111214
M111502
M110406
M10101
M110107
M110101
M110910

13

C111905

13

M110902

B
C111902
AB
C111509
ABCD C111204
BC
C111102
BCD
C110503
ABCD C110908
ABCD C111804
Part C
9
C111301
5
C110809
6
C110107
8
C110402

14
15
16
17
18
19
20

C
AC
BD
AD
BC
ABCD
ABC

1
2
3
4

2
1
3
2

M110902
M110406
M111103
M110719
M110810
M1105010
M110415
Part C
M110304
M111426
M110510
M111422

14
15
16
17
18
19
20
1
2
3
4

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[

31

CODE: 120628.3
ANSWERS
Reshuffling Test 1

ANSWER KEY

4
5
6
7
8
9
10
11

B
C
D
C
D
C
B
B

12

13
14
15
16
17
18
19
20

A
A
ACD
AD
ABC
AC
AB
CD

1
2
3
4

4
8
3
1

Physics
Part A
P110610
P111302,
P111305
P111026,
P111209
P110815
P110309
P110310
P110806
P111012
P110815
P110815
P110815
P111105,
P111222
P111105
P111105
P110912
P110917
P111207
P111105
P111010
P111002
Part C
P110807
P111309
P110606
P110705

Chemistry
Part A
C
C111507

Mathematics
Part A
A
M110101

C111401

M110504

C110402

M110902

4
5
6
7
8
9
10
11

C
B
D
C
D
B
D
C

C111302
C110101
C110307
C110504
C111804
C110603
C110603
C110603

4
5
6
7
8
9
10
11

B
C
B
B
A
B
D
A

M111214
M111502
M110406
M111210
M111201
M110107
M110101
M10101

12

C111905

12

M110902

B
C111902
A
C111903
BC
C111102
BCD
C110503
ABCD C110908
ABCD C111804
AB
C111509
ABCD C111204
Part C
5
C110809
6
C110107
8
C110402
9
C111301

13
14
15
16
17
18
19
20

C
D
AD
BC
ABCD
ABC
AC
BD

1
2
3
4

1
3
2
2

M110902
M110910
M110719
M110810
M1105010
M110415
M110406
M111103
Part C
M111426
M110510
M111422
M110304

13
14
15
16
17
18
19
20
1
2
3
4

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[

32

CODE: 120628.4
ANSWERS
Reshuffling Test 1

ANSWER KEY

2
3
4
5
6
7

B
C
D
C
D
D

10
11
12
13
14
15
16
17
18
19
20

A
A
C
B
B
AD
ABC
AC
AB
CD
ACD

1
2
3
4

8
3
1
4

Physics
Part A
P111026,
P111209
P110815
P110309
P110310
P110806
P111012
P110610
P111302,
P111305
P111105,
P111222
P111105
P111105
P110815
P110815
P110815
P110917
P111207
P111105
P111010
P111002
P110912
Part C
P111309
P110606
P110705
P110807

Chemistry
Part A

Mathematics
Part A

C110402

M110902

2
3
4
5
6
7

C
B
D
C
D
C

C111302
C110101
C110307
C110504
C111804
C111507

2
3
4
5
6
7

B
C
B
B
A
A

M111214
M111502
M110406
M111210
M111201
M110101

C111401

M110504

C111905

M110902

B
C111902
A
C111903
B
C110603
D
C110603
C
C110603
BCD
C110503
ABCD C110908
ABCD C111804
AB
C111509
ABCD C111204
BC
C111102
Part C
6
C110107
8
C110402
9
C111301
5
C110809

10
11
12
13
14
15
16
17
18
19
20

C
D
B
D
A
BC
ABCD
ABC
AC
BD
AD

1
2
3
4

3
2
2
1

M110902
M110910
M110107
M110101
M10101
M110810
M1105010
M110415
M110406
M111103
M110719
Part C
M110510
M111422
M110304
M111426

10
11
12
13
14
15
16
17
18
19
20
1
2
3
4

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[

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