Beruflich Dokumente
Kultur Dokumente
Reshuffling Test 1
Paper 1
PHYSICS, CHEMISTRY & MATHEMATICS
QP CODE: 120627.1
ANSWERS
Reshuffling Test 1
ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
A
B
D
D
C
C
D
B
B
C
D
C
A
C
A
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
Physics
P110305
P110605
P110308
P110415
P110404
P110507
P110604
P110605
P110413
P110708
P110718
P110804
P110905
P110905
P110905
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Chemistry
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Mathematics
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
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4.
Sol.
3t 6t 2
V =
= 0
2
5.
Sol.
6.
Sol.
7.
Sol.
8.
Sol.
9.
Sol.
10.
Sol.
11.
Sol.
12.
Sol.
(0.2 + xo) 10 = 4
xo = 0.2 m below 0.
13.
Sol.
14.
Sol.
g
r
g
=
2
r +h
15.
Sol.
16.
Sol.
17.
Sol.
18.
Sol.
19.
Sol.
20.
Sol.
21.
Sol.
22.
Sol.
23.
Sol.
24.
Sol.
25.
4 2 2
2
=
m/s
3
27
(2 + 2 2)
Sol.
V=
26.
=
= 1M ;
= 50 cm
2
2
Sol.
27.
Sol.
28.
Sol.
Sin
VP
1
4
=
=
VQ
2
Sin
2
(g +a) 1 = g
b
a
=
b g + a
29.
Sol.
30.
Sol.
1.
Sol.
1.
C
Fe = [Ar]184s23d6
Fe+ = [Ar]184s13d6 (Contains 5 unpaired electrons)
Fe3+ = [Ar]184s03d5 (Contains 5 unpaired electrons)
C110108
2.
Sol.
2.
C
Li and Mg display diagonal relationship.
C110705
3.
Sol.
3.
C
The central atoms of SF4, CF4, XeF4 and SeF4 undergo sp3d, sp3, sp3d2 and sp3d
hybridization respectively.
C110306
4.
Sol.
B
Meq of metal ion = Meq of MnO4 solution
SECTION 2 (Chemistry)
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[
4.
W
1000 = N V
E
26
1000 = 400 1 5 = 2000
or,
52 / n
or, n = 4
Change in oxidation number of 4 units.
C111102
5.
Sol.
5.
3RT
3R 800
=
= 150R
M
16
2RT
2 R 300
=
= 150R
Most probable speed of He =
M
4
C111206
6.
Sol.
6.
C
Plaster of paris(CaSO4).H2O sets on standing to a hardmass.
C110908
7.
Sol.
7.
D
H2O2 easily decomposes to H2O and O2 even in presence of dust particles.
C111006
8.
Sol.
8.
A ( g)
2B ( g)
a
0
ax
2x
For 1:1 molar ratio, a x = 2x x = a/3
2.303
a
2.303
3
t=
log
=
log = 1635.3 sec = 27.25 min
k
aa/3
k
2
C110606
9.
Sol.
D
X ( s)
2Y ( g ) + 3Z ( g)
2
KC = [Y] [Z]3
[2Z]3 [Y]2 = [Y]2[Z]3
[ Y '] =
2
or, [Y] =
[Y]
[Y]
2 2
9.
C110401
10.
Sol.
B
At second equivalence point the only species present at appreciable concentration is
HPO24 .
pH =
K a2
10.
C110502
11.
+p
2
K a3
12 + 8
= 10
2
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[
Sol.
11.
It is a neutralization reaction.
C111906
12.
Sol.
12.
C
X is HBO2 which is obtained by removing one water molecule from H3BO3.
C111505
13.
Sol.
13.
D
The compound in (D) after hydrolysis does not polymerise beyond two molecules.
C111607
14.
Sol.
14.
B
II and III are stabilized by resonance and II is aromatic. IV (1o) is more stable than 1(2o).
C111303
15.
C
Cl
Sol.
CH3CH2CHCH3
Cl2
CH3
CH3
CH3
15.
C111404
16.
Sol.
16.
B
Orientation of product takes place according to the activating group(OH).
C111804
17.
Sol.
C
The initially formed 3o carbocation undergoes rearrangement to another 3o carbocation
for more no. of hyperconjugative structures. Then ring expansion followed by methyl shift
takes place.
C111705
17.
18.
Sol.
18.
D
It is most soluble in NH4OH due to complex formation, followed by KNO3. AgNO3 and
NaCl exert common ion effect. Therefore, it is more soluble in low conc. NaCl than that
in higher conc. AgNO3.
C110501
19.
Sol.
Rate =
19.
20.
Sol.
20.
21.
d [I2 ]
1 d [I2 ]
3 dt
0.693
t1/2
k
0.693 / 10 1
KC = 1 =
=
= 0.1
k2
0.693 / 1 10
C110606
k=
C
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Sol.
21.
22.
Sol.
22.
D
In(III), negative charge is present on oxygen and in (I) it is present on carbon. So (III) is
more stable than (I). (II) is most unstable due to more number charged species.
C111301
23.
Sol.
Na2CO3
No gas is produced
23.
Li2CO3
CO2 is evolved
C110804
24.
Sol.
24.
A
Due to p - p back bond formation in BF3.
C110306
25.
Sol.
25.
D
Due to weak C I bond in comparison to other C X bonds.
C111606
26.
Sol.
26.
C
At equilibrium, Ssys. + Ssurr. = 0
C111906
27.
Sol.
27.
C
Due to presence of bulky methyl group, NO2 does not exhibit R effect in (C).
C111301
28.
Sol.
28.
D
X = CH3CH2CH2CH3, Y = Trans-2-butene
C111713
29.
Sol.
29.
C111801
30.
Sol.
30.
D
(D) gives four geometrical isomers as it is not symmetrical like the other compounds.
C111403
, and Cl.
SECTION 3 (Mathematics)
1.
Sol.
D
M111301
The given series is geometric with an initial term of 1 and a common ratio of cos2 , so
its sum is
1
1
5 = cos2n =
=
2
1 cos sin2
n=0
1
Therefore sin2 = , and
5
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cos 2 = 1 2 sin2 = 1
2.
Sol.
2 3
=
5 5
D
M110909
Let B = ( a, b ) and A = ( a, b ) . Then
4a2 + 7a 1 = b
and 4a2 7a 1 = b
50
=5 2
So AB = 2 a2 + b2 = 2
4
3.
M110204
Sol.
4.
Sol.
A
M110302
9z1z2 + 4z1z2 + z2 z3 = ( z3 z3 ) z1z2 + ( z1z1 ) z2 z3 = 12
3
3
5
= 1 < 0log10
< 10 and
. Since < 4,
2
2
2
5
5
7
7
log10
> 0 > 1 = sin
< 1 = sin
Also, log10
2
2
2
2
Since both functions are continuous we have at least one real roots in each of the
3 3 5
5 7
, ,
and ,
intervals 1,
2 2
2 2 2
Sol.
12
=2
32
M111004
x
Here
= cos t + sin t
4
y
= cos t sin t
and
7
Squaring and adding equation (1) and (2)
x2 y2
+
= 2 (sin2 t + cos2 t)
16 7
x2 y2
+
= 1 , which is an ellipse
32 14
eccentricity e =
(1)
(2)
b2
14 3
= 1
= .
2
32 4
a
6.
Sol.
C
M111205
Total number of ways = 6 6 ....... to n times = 6n .
Total number of ways to show only even numbers = 3 3 .........n times 3n
The required number of ways = 6n 3n .
7.
Sol.
A
M110903
Any point on the parabola is (x , x2+ 7x + 2)
Its distance from the line y = 3x 3 is given by
P=
3x x 2 + 7x + 2 3
9 +1
x 2 + 4x + 5
10
x 2 + 4x + 5
10
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[
D
M110410
( 1 x4) (1 + 9C1 x+ 9C2 x2 + 9C3 x3 9C9x9)
Coefficient of x7 = 9C7 9C3 = 48
9.
Sol.
B
M111203
Total number of ways of posting the letters
= 36 3C1 26 + 3C2 = 540.
10.
Sol.
D
M110304
| iz + ( 3 4i)| | iz| + |3 4i|
= |z| +5 < 4 + 5 = 9.
11.
M110410
10
Sol.
x +1
x 1
1/3
1/2
x x +1 x x
3
To simplify, for first term put x = p and for second term put x = q2, then it will
become (x1/3 x-1/2)10
Tr+1 = 10Cr(x1/3)10-r ( x 1/2)r
For term independent of x;
10 r r
10 r r
=0
x 3 x 2 = x0
3
2
5r = 20 r = 4 T5 = 10C4
12.
Sol.
C
M110101
Given , are roots of equation x 2 2x + 3 = 0
2 2 + 3 = 0
and 2 2 + 3 = 0
.(1)
.(2)
2 = 2 3, 3 = 2 2 3
P = 2 2 3 3 2 + 5 2 = 2 + 2 2 = 3 2 = 1, by Eq. (1)
Similarly, we can have Q = 2
Sum of roots = 3 and product of roots = 2
So, the required equation is x 2 3x + 2 = 0
13.
Sol.
D
M110505
Let d be the common difference of the A.P., then
3 = a10 = 2 + 9d d = 1/9
a4 = 2+3d = 7/3
1 1
1
, ,...
Then
h1 h2
h10
1
1
1
1
=
= + 9D D =
3 h10 2
54
1
1
7
18
= + 6D =
h7 =
h7 h1
18
7
Hence, a4 . h7 = (7/3) (18/7) = 6.
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[
10
14.
Sol.
M111301
4a2
a2 cos2 2
+
sec 2 + cos ec 2 cos2 + sin2
2
2
= a (sin 2 + cos2 2) = a2
And p12 p22 = a 4 sin2 2 cos2 2 = (1/ 4 ) a 4 sin2 4
p12 + p22 =
p12 + p22
p p
4
1 + 2 =
=
= 4 cos ec 2 4
2 2
2
p1 p2
sin 4
p2 p1
2
15.
Sol.
B
M111403
The given expression is equal to
(
= ( 2 sin 20
1
cos 60o + cos 40o
2
1
1 1
3
=
4
o
sin30o
16.
M110305
Sol.
z1 + z2 = z1 + z2
z1 + z2 = z1 z 2
z1 + z1 = z2 z2
z1 + z1
= 1 = ei
z2 + z2
17.
Sol.
18.
Sol.
M110413
n
a
C
n r +1
1+ r = 1+ n r = 1+
ar 1
r
Cr 1
n +1
=
r
B
M111301
The expression is equal to 3 cos4 + sin4 2 cos6 + sin6
2
3
= 3 ( cos2 + sin2 ) 2 cos2 sin2 2 ( cos2 + sin2 ) 3 sin2 cos2 ( sin2 + cos2 )
A
M110733
x2 y2 + 2y 1 = 0
Equations of lines are y = x + 1, y = x + 1
angle bisectors are y = 1 and x = 0
1
area of triangle = 2 2 = 2 sq. units
2
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11
20.
Sol:
21.
Sol.
Not Available
2
1 n
1 n(n + 1)(2n + 1) (n + 1)2
n + 1
2 = r 2
=
n r =1
n
6
4
2
2
2n + 1 n + 1 (n + 1)(4n + 2 3n 3) n 1
=
=
= (n + 1)
4
12
12
6
Hence, B is correct answer
D
M111301
According to given condition
Sin + sin = a and cos + cos = c
+
cos
= a and 2 cos
Or , 2 sin
2
2
a
+
=
Now
Or , tan
c
2
+
cos
= c
2
2
+
2 tan
2 = 2ac
sin( + ) =
a2 + c 2
+
1 + tan2
2
22.
M111502
Sol.
23.
Sol.
D
M110808
Let the line y = x intersect the
circle and the line y = 6 at M and K,
respectively, and let the line y = x
intersect the circle and the line
y = 6 at N and L, respectively.
Quadrilateral PMON has four right
angles and MP = PN, so PMON is a
square. In addition, MK = KJ=6 and
KO = 6 2 . Hence
r = MO = MK + KO = 6 + 6 2
y
P
N
M
K
24.
Sol.
C
M110501
We have b = a + r, c = a + 2r, and d = a + 3r, where r is positive real number. Also
Hence
a 1
=
d 4
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[
12
25.
Sol.
M110701
1
and y intercept
2
1
(0, 9), so its equation is y = x + 9
2
Since the coordinates of A satisfy both this
equation and y = x, if follows that
Line AC has slope
A ' = ( 6,6 ) .
Similarly, line BC has equation
y = 2x + 12,
y
B
(0,12)
A
y=x
C (2 , 8)
(0,9)
A'
B'
(6 4)
+ (6 4) = 2 2
2
A
M110504
18log x = k, 21log y = k, 28log z = k
x18 = y 21 = z28
3,3 logy x, 3logz y, 7logx z are in
18 log x = k
21 log y = k
28 log z = k
k
k
k
3, 3 18 , 3 21 , 7 28
k
k
k
21
28
18
21 28 18
3,
,
,
6 7
4
7
1
3, , 4, 4 are in A.P
2
2
27.
Sol.
28.
Sol.
A
M110826
The given circle is (x 1)2 + (y 1)2 = 1.
3
In the figure MC = 1
2
locus of the point M is
3
(x 1)2 + (y 1)2 = .
4
A
M
1
B
1
C(1,1)
M110503
a
a1 = , a2 = a, a3 = ar
r
If a1, a2 , a3 ( a1 > 0 ) are in G.P.
a
+ 5ar 14a
r
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[
13
9
+ 5r 14
r
5r 2 14r + 9 0
5r 2 5r 9r + 9 0
9
The internal is 1,
5
29.
M110109
Sol.
x + 18x + 30 = 2 x 2 + 18x + 30 + 15
Let x 2 + 18x + 30 = y
2
y = 2 y + 15
y = 6 (rejected),y=10
Or x 2 + 18x + 20 = 0
product of real roots=20
30.
Sol.
D
M110414
4n
2 15n 1
(1 + 15 )
15n 1
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[
14
QP CODE: 120627.2
ANSWERS
Reshuffling Test 1
ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
C
D
B
B
C
D
C
A
C
A
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
A
B
D
D
C
Physics
P110507
P110604
P110605
P110413
P110708
P110718
P110804
P110905
P110905
P110905
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
P110305
P110605
P110308
P110415
P110404
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Chemistry
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Mathematics
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[
15
QP CODE: 120627.3
ANSWERS
Reshuffling Test 1
ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
D
C
A
C
A
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
A
B
D
D
C
C
D
B
B
C
Physics
P110718
P110804
P110905
P110905
P110905
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
P110305
P110605
P110308
P110415
P110404
P110507
P110604
P110605
P110413
P110708
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Chemistry
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Mathematics
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[
16
QP CODE: 120627.4
ANSWERS
Reshuffling Test 1
ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
D
A
C
A
B
D
C
A
B
A
B
C
B
A
A
A
B
D
D
C
C
D
B
B
C
D
C
A
C
A
Physics
P111101
P111101
P111026
P111213
P111207
P111213
P111005
P110613
P111005
P111303
P111306
P111307
P111103
P111103
P110723
P110305
P110605
P110308
P110415
P110404
P110507
P110604
P110605
P110413
P110708
P110718
P110804
P110905
P110905
P110905
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Chemistry
B
C111804
C
C111705
D
C110501
C
C110601
C
C110606
C
C111706
D
C111301
B
C110804
A
C110306
D
C111606
C
C111906
C
C111301
D
C111713
C
C111801
D
C111403
C
C110108
C
C110705
C
C110306
B
C111102
C
C111206
C
C110908
D
C111006
C
C110606
D
C110401
B
C110502
C
C111906
C
C111505
D
C111607
B
C111303
C
C111404
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Mathematics
B
M110305
B
M110413
B
M111301
A
M110733
B
Not Available
D
M111301
A
M111502
D
M110808
C
M110501
B
M110701
A
M110504
A
M110826
B
M110503
B
M110109
D
M110414
D
M111301
D
M110909
D
M110204
A
M110302
B
M111004
C
M111205
A
M110903
D
M110410
B
M111203
D
M110304
C
M110410
C
M110101
D
M110505
C
M111301
B
M111403
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[
17
Paper-2
PHYSICS, CHEMISTRY & MATHEMATICS
CODE: 120628.1
ANSWERS
Reshuffling Test 1
ANSWER KEY
1
2
3
4
5
C
D
C
D
D
8
9
10
11
12
13
B
B
B
C
A
A
14
15
16
17
18
19
20
ABC
AC
AB
CD
ACD
AD
1
2
3
4
3
1
4
8
Physics
Part A
P110309
P110310
P110806
P111012
P110610
P111302,
P111305
P111026,
P111209
P110815
P110815
P110815
P110815
P111105
P111105
P111105,
P111222
P111207
P111105
P111010
P111002
P110912
P110917
Part C
P110606
P110705
P110807
P111309
1
2
3
4
5
Chemistry
Part A
B
C110101
D
C110307
C
C110504
D
C111804
C
C111507
1
2
3
4
5
Mathematics
Part A
C
M111502
B
M110406
B
M111210
A
M111201
A
M110101
C111401
M110504
C110402
M110902
8
9
10
11
12
13
C
D
C
B
B
A
C111302
C110603
C110603
C110603
C111902
C111903
8
9
10
11
12
13
B
D
A
B
C
D
M111214
M110101
M10101
M110107
M110902
M110910
14
C111905
14
M110902
ABCD C110908
ABCD C111804
AB
C111509
ABCD C111204
BC
C111102
BCD
C110503
Part C
8
C110402
9
C111301
5
C110809
6
C110107
15
16
17
18
19
20
ABCD
ABC
AC
BD
AD
BC
1
2
3
4
2
2
1
3
M1105010
M110415
M110406
M111103
M110719
M110810
Part C
M111422
M110304
M111426
M110510
15
16
17
18
19
20
1
2
3
4
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[
18
3.
Sol.
Net force is equal to mass multiplied by acceleration and net torque about cm should be
zero.
4.
Sol.
5
Sol.
4
4
6.
Sol.
7.
Sol.
8.
Sol.
9.
Sol.
COTME Kf = mg
(i)
1
m 2 = mg
2
3
2
3g
w=
and
10.
Sol.
COTME Kf = mg
11.
Sol.
Vcm =
IAR
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[
(f)
19
12.
Sol.
2A
=
(F / m)
2Am
F
2Am
F
13.
Sol.
14.
Sol.
A
T = Time taken to reach from (A) to (0) Time taken to reach from ( A) to
2
2A
2(A / 2)
=
F/m
F/m
15.
Sol.
16.
Sol.
17.
Sol.
18.
Sol.
4Po r2
Po r2
19.
Sol.
20.
Sol.
PART C
1.
Sol.
2
2
V2
v 2
I = 2
2 2
v2 = 6
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[
20
2.
Sol.
R
I1 = Icm + m
2
R
and I2 = Icm + m
2
3.
Sol.
4.
Sol.
R/2
cm R/2
Chemistry
PART A
1.
Sol.
1.
2.
Sol.
B
Kinetic energy = e stopping potential
K.E 6.4 1019
=
=4V
Stopping potential =
e
1.6 10 19
C110101
2.
D
The bond order of O22+ is highest among the given species.
it contains the strongest covalent bond
C110307
3.
Sol.
C
pK a = - log(2 104) = 3.7
pH = pK a + log
3.
C110504
4.
Sol.
D
The activating order of the group attached to benzene ring is:
NHCOCH3 > CH2CONH2 > CONHCH3 > COCH2NH2
( + Re ffect )
(Hyperconjugation )
4.
C111804
5.
Sol.
5.
C
X = B3N3H3Cl3
C111507
6.
Sol.
6.
D
In both compounds the CH3 groups are at different positions.
C111401
7.
B
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21
Sol.
G0 = - RT nK
or, H0 TS0 = - RT nK
H0 1 S0
+
R
T
R
y = mx + c
or, nK =
A
nK
Intercept =
1/T
S0
= 4 S0 = 4 2 = 8 Cal K1 mol1.
R
7.
C110402
8.
Sol.
8.
C
Acidic strength: Penolic OH > 1o OH > 2o OH >3o OH
C111302
9.
Sol.
9.
D
H = HP HR = 20 40 = - 20 kJ
C110603
10.
Sol.
10.
C
Energy of product + Ea(b) of uncatalysed reaction = 140
Ea(b) = 140 - 20 = 120 kJ
C110603
11.
Sol.
B
Let activation energy of the forward reaction for the catalysed reaction be E'a .
E'a = Ea x
Where x = amount of energy lowered down by the catalysed reaction.
k(catalysed reaction) = k(uncatalysed reaction)
11.
Ea
E'
E x
= a = a
500 300
300
Since Ea = 100 kJ, x will be 40 kJ
C110603
12.
Sol.
B
W = WA B + WB C + WC A
or,
VC
+ [-P(VA - VC)]
VB
VB
+ P(VC VA)
VC
V
= 2.303 PBVB log B + P(2V V)
VC
= 2.303 nRT log
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[
22
V
+ PV
2V
1
= 2.303 3 PV log + PV
2
= 2.303 3 PV -0.3010 + PV
= - 2PV + PV = -PV
C111902
= 2.303 3PV log
12.
13.
Sol.
A
C A is isobaric path
PV
5
5 P V
q = nCPT = 1 R [ TA TC ] = R A A C C
2
2 R
R
5 PV 2PV
5
= R
= PV
2
R
2
A B is isochoric path
P V
3
3 P V
q = nCVT = 1 R [ TB TA ] = R B B A A
2
2 R
R
3 3PV PV 3
R
= 2 2PV = 3PV
2
R
C111903
=
13.
14.
Sol.
B
Moles of gas at A = Moles of gas at B
PA VA PB VB
=
RT1
RT2
14.
PV 3PV
=
T2 = 3 T1
T1
T2
When moles at A and C are compared, T2 will be equal to 2 T1.
C111905
15.
Sol.
ABCD
Cold
2 Ca ( OH)2 + 2 Cl2
CaCl2 + Ca ( OCl )2 + 2H2O
or,
Hot
6 Ca ( OH)2 + 6 Cl2
5 CaCl2 + Ca ( ClO3 )2 + 6H2O
30 C
Ca ( OH)2 + Cl2
CaOCl2 + H2O
o
15.
C110908
16.
ABCD
CH3 O
Sol.
CH3O
AlCl
3
CH3 C C Cl
CH3 C C
CH3
CH3
CH3
CH3 C + CO
CH3
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[
23
C(CH3)3
takes place
C111804
17.
Sol.
17.
AB
Graphite is black whereas BN is white. Graphite is a poor conductor but BN does not
conduct at all.
C111509
18.
ABCD
Sol.
18.
19.
Sol.
19.
BC
H3PO3 is a dibasic acid and H3PO2 is a monobasic acid.
C111102
20.
Sol.
BCD
These ions undergo hydrolysis in water
NH+4 + H2O
NH4 OH + H+
20.
R
T y = mx
V b
CN + H2O
HCN + OH
Fe+ + H2O
C110503
FeOH+ + H+
Part C
1.
Sol.
C ( s ) + CO2 ( g)
2CO ( g)
P
0
Px
2x
P x + 2x = P + x = 6
P
P + = 6 P = 4 and x = 2
2
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24
K P
(p )
= CO
pCO2
( 4)
=
2
16
= 8 atm
2
1.
C110402
2.
Sol.
2.
9
The carbocation has 6 and the double bond has 3 hyperconjugation structures.
C111301
3.
Sol.
3.
5
X = NaHCO3, Y = HCOONa
C110809
4.
Sol.
6
n = 4, = 0, 1 4s and 4p subshells
m = 0, +1 4s, 4px and 4py
s = 4s2 , 4p2x and 4p2y = 6 electrons
4.
C110107
Mathematics
PART A
1.
Sol.
M111502
b2 + c 2 a2 c 2 + a2 b2 a2 + b2 c 2 a2 + b2 + c 2
Expression=
+
+
=
2abc
2abc
2abc
2abc
=
2.
Sol.
( a + b + c )2 2 ( ab + bc + ca ) = 112 2.38 =
2abc
2.40
9
16
M110406
z + z0i
Center is 0
and Diameter is z0
2
3.
Sol.
B
M111210
The first and last digits must be both odd or both even for their average to be an integer.
There are 5 . 5 = 25 odd odd combinations for the first and last digits. There are 4 .5
=20 even even combinations that do not use zero as the first digit. Hence the total is
45.
4.
Sol.
M111201
a
, We may assume that a > 0 and b < 0 so that a b . We
b
must also have a c b . If c = 0 , there are 3 ways to choose a and 3 ways to choose
The slope of the line is
b.
However, the lines x y = 0, 2x 2y = 0 and 3x 3y = 0 are the same. Thus the
number of lines in this case is 3 2 2 = 7 . If c 0, there are 3 ways to choose a, 3 ways
to choose b and 4 ways to choose c. Thus the number of lines in this case is 3 2 4 = 36 .
The total is 7 + 36 = 43 .
5.
A M110101
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[
25
Sol.
c
, we get
a3
b 2c 2 2 b2 c
x 2 x+c =0
a3
a
2
bc
bc
a 2 x b 2 x + c = 0
a
a
bc
2 x = ,
a
( + ) x = ,
1
1
x=
.
,
( + ) ( + )
6.
Sol.
A
M110504
Let the common ratio be r. Then
a + log4 3
a + log2 3
a + log8 3
=
a + log4 3
log4 3 log8 3
=
log2 3 log4 3
1
1
log2 3 log2 3
3
= 2
1
log2 3 log2 3
2
1
=
3
r=
7.
M110902
Sol.
1992
1992
n =1
n =1
A nBn =
8.
Sol.
1
1
and
. Hence
n
n +1
1992
n n + 1 = 1 1993 = 1993
B
M111214
We have
The perfect square divisors of that product are the numbers of the form 22a 3 2b 5 2c 7 2d
with 0 a 15, 0 b 6, 0 c 2 , and 0 d 1. Thus there are
D
M110101
+ + = 0 + + = q
= r
+ q + r = 0
3
3 = q r
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26
5 = 3 q 2r
5 = q ( q r ) 2r
= + q2 + q 2r
5 = q2 ( + + ) + 3qr r ( 2 + 2 + 2 )
= 5qr
10.
Sol.
M10101
1
=
=
3
q
q r + r
11.
Sol.
B
M110107
3 + = 0, 3 + 3 2 = c, 3 = d
1 3
c
8d
+ = =
d
3c
12.
13.
M110902
M110910
14.
B
M110902
SOLUTION_12 14
1 2m
1 + 2m
h=
,k =
2l
2m
1
k 2
m=
l=
2k 2
2h ( k 1)
3
1
x = 8a y 2 3y + 2 y =
( x + 2a )
2
8a
3
1
3
curve in symmetric about line y =
2
15.
Sol.
ABCD
M1105010
b is the H.M. of a and c and their G.M. =
ac
ac > b
G.M > H.M
n
And A.M. of a and cn > G.M. of an and cn
an + c n
> anc n
2
)n
a n + c n > 2 ac > 2b n
Put n = 100, 3, 5, 2
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[
27
16.
Sol.
ABC
M110415
Putting x = in the equation,
.... (1)
0 = a0 + a1 +a22 +a3 + . . .
2
Putting x = in the equation,
.... (2)
0 = a0 + a12 +a2 + a3 + . . .
Putting x = 1 in the equation,
...
.... (3)
3n = a0 + a1 +a2 + a3 +
adding (1), (2) and (3),
.... (a)
3n = 3(a0 +a3 +a6 + . . . .)
a0 + a3 +a6 + . . . . = 3n-1 (option C)
subtracting (2) from (1),
0 = ( - 2) (a1 a2 + a4 a5 + . . . )
. . . (4)
Since - 2 0 , a1 +a4 + a7 +. . . = a2 + a5 +a8 + . . .
. . . .(5)
Also from (3) (a), a1 + a2 +a4 +a5 + . . . . = 3n 3n-1 = 2.3n-1
From (4) and (5) , a1 +a4 + a7 +. . . = a2 + a5 + a8 + . . . = 3n-1 = a0 + a3 + a6 + . .
17.
Sol.
AC
M110406
Clearly the inscried triangle is equilateral.
2
2
i
i
z z0
z z0
2
=e 3, 3
=e 3
z1 z0
z1 z0
z2 = -1 +i(2 +
3 ) and z3 = -1 + i(2 -
z2
3)
z0(2i)
z3
18.
Sol.
BD
z1(2 +2i)
M111103
x2 y2
+
=1
a2 b2
x2 y2
which is of the from 2 + 2 = 1 with a2 = 22 , b2 = 12
a
b
2
2
2
Here 1 = 2 1 e
Equation of the ellipse is
( b = a (1 e ))
Foci of the ellipse are ( 3, 0 ) and ( 3, 0 )
e=
3
2
3
1
4
b2 = a2 1 3b2 = a2 b2 = a2
3
3
Equation of hyperbola is
x 2 3y 2
2 =1
a2
a
3, 0
3
= 1 a2 = 3 .
2
a
Hence, the equation of hyperbola is x 2 3y 2 = 3
2
A focus of hyperbola is ( ae, 0 ) = 3
, 0 = ( 2, 0 )
3
19.
AD
M110719
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[
28
Sol.
20.
Sol.
BC
M110810
Let L1 : y = mx
Putting y = mx in the equation of circle , we get
x2 + m2 x2 x + 3mx = 0
x[ (1+ m2)x 1 + 3m] = 0
1 3m
x = 0,
1 + m2
So points of intersection of L1 and the circle are
m (1 3m )
P1(0, 0), P2 1 3m ,
2
1 + m2
1 + m
Also points of intersection of L2 and the circle are Q1(1, 0) and Q2(2, 1).
By the given condition;
P1P2 = Q1Q22
(1 + m2) (3m 1)2 = 2(1 + m2)2
(3m 1)2 = 2(1+ m2)
7m2 6m 1 = 0
1
(7m + 1) (m 1) = 0 m = 1,
7
1
So L1 : y = x, y = x
7
i.e. x y = 0, 7y + x = 0.
Part C
1.
Sol.
2 M111422
4 [1 + cot2 (a + x)] + a2 4a = 0
4cot2 (a + x) + (a 2)2 = 0
a 2 = 0 and cot2 (a + x) = 0
a = 2.
2.
Sol.
M110304
z1 2z2
(z
= 2 z1z2
)( z
2
2
1 = 0
z1 = 2
3.
Sol.
M111426
1
3 cos
x 2 6 x + 10 is defined if x2 6x + 10 1
if x2 6x + 9 0
if |x 3|2 0
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29
if x 3 = 0
if x = 3
4.
Sol.
Given expression is
=
M110510
1
(a + b + c)
2
1
2a
1
=
2
b+ca 2
1
3
b +c a 2
Now, as (a + b + c) =
b + c a + 1 2
2a
(b + c a)
1
3
9 = 3
2
2
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[
30
CODE: 120628.2
ANSWERS
Reshuffling Test 1
ANSWER KEY
1
2
3
C
D
D
6
7
8
9
10
11
12
B
C
D
B
C
B
A
13
14
15
16
17
18
19
20
A
AB
CD
ACD
AD
ABC
AC
1
2
3
4
1
4
8
3
Physics
Part A
P110806
P111012
P110610
P111302,
P111305
P111026,
P111209
P110815
P110309
P110310
P110815
P110815
P110815
P111105
P111105,
P111222
P111105
P111010
P111002
P110912
P110917
P111207
P111105
Part C
P110705
P110807
P111309
P110606
1
2
3
Chemistry
Part A
C
C110504
D
C111804
C
C111507
1
2
3
Mathematics
Part A
B
M111210
A
M111201
A
M110101
C111401
M110504
C110402
M110902
6
7
8
9
10
11
12
C
B
D
C
B
D
A
C111302
C110101
C110307
C110603
C110603
C110603
C111903
6
7
8
9
10
11
12
B
C
B
A
B
D
D
M111214
M111502
M110406
M10101
M110107
M110101
M110910
13
C111905
13
M110902
B
C111902
AB
C111509
ABCD C111204
BC
C111102
BCD
C110503
ABCD C110908
ABCD C111804
Part C
9
C111301
5
C110809
6
C110107
8
C110402
14
15
16
17
18
19
20
C
AC
BD
AD
BC
ABCD
ABC
1
2
3
4
2
1
3
2
M110902
M110406
M111103
M110719
M110810
M1105010
M110415
Part C
M110304
M111426
M110510
M111422
14
15
16
17
18
19
20
1
2
3
4
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[
31
CODE: 120628.3
ANSWERS
Reshuffling Test 1
ANSWER KEY
4
5
6
7
8
9
10
11
B
C
D
C
D
C
B
B
12
13
14
15
16
17
18
19
20
A
A
ACD
AD
ABC
AC
AB
CD
1
2
3
4
4
8
3
1
Physics
Part A
P110610
P111302,
P111305
P111026,
P111209
P110815
P110309
P110310
P110806
P111012
P110815
P110815
P110815
P111105,
P111222
P111105
P111105
P110912
P110917
P111207
P111105
P111010
P111002
Part C
P110807
P111309
P110606
P110705
Chemistry
Part A
C
C111507
Mathematics
Part A
A
M110101
C111401
M110504
C110402
M110902
4
5
6
7
8
9
10
11
C
B
D
C
D
B
D
C
C111302
C110101
C110307
C110504
C111804
C110603
C110603
C110603
4
5
6
7
8
9
10
11
B
C
B
B
A
B
D
A
M111214
M111502
M110406
M111210
M111201
M110107
M110101
M10101
12
C111905
12
M110902
B
C111902
A
C111903
BC
C111102
BCD
C110503
ABCD C110908
ABCD C111804
AB
C111509
ABCD C111204
Part C
5
C110809
6
C110107
8
C110402
9
C111301
13
14
15
16
17
18
19
20
C
D
AD
BC
ABCD
ABC
AC
BD
1
2
3
4
1
3
2
2
M110902
M110910
M110719
M110810
M1105010
M110415
M110406
M111103
Part C
M111426
M110510
M111422
M110304
13
14
15
16
17
18
19
20
1
2
3
4
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[
32
CODE: 120628.4
ANSWERS
Reshuffling Test 1
ANSWER KEY
2
3
4
5
6
7
B
C
D
C
D
D
10
11
12
13
14
15
16
17
18
19
20
A
A
C
B
B
AD
ABC
AC
AB
CD
ACD
1
2
3
4
8
3
1
4
Physics
Part A
P111026,
P111209
P110815
P110309
P110310
P110806
P111012
P110610
P111302,
P111305
P111105,
P111222
P111105
P111105
P110815
P110815
P110815
P110917
P111207
P111105
P111010
P111002
P110912
Part C
P111309
P110606
P110705
P110807
Chemistry
Part A
Mathematics
Part A
C110402
M110902
2
3
4
5
6
7
C
B
D
C
D
C
C111302
C110101
C110307
C110504
C111804
C111507
2
3
4
5
6
7
B
C
B
B
A
A
M111214
M111502
M110406
M111210
M111201
M110101
C111401
M110504
C111905
M110902
B
C111902
A
C111903
B
C110603
D
C110603
C
C110603
BCD
C110503
ABCD C110908
ABCD C111804
AB
C111509
ABCD C111204
BC
C111102
Part C
6
C110107
8
C110402
9
C111301
5
C110809
10
11
12
13
14
15
16
17
18
19
20
C
D
B
D
A
BC
ABCD
ABC
AC
BD
AD
1
2
3
4
3
2
2
1
M110902
M110910
M110107
M110101
M10101
M110810
M1105010
M110415
M110406
M111103
M110719
Part C
M110510
M111422
M110304
M111426
10
11
12
13
14
15
16
17
18
19
20
1
2
3
4
FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[