Department of Chemistry Dr. Hari Singh Gour Vishwavidyalaya, Sagar (M.P.

Pure Chemistry

Semester-I Course Name Course Code Inorganic Chemistry CHE-C-111 Organic Chemistry CHE-C-112 Physical Chemistry CHE-C-113 Laboratory E ercise CHE-C-11!

Credits 2 1 1 2

CH!"C ### Paper $% General $norgani& Chemistry"$

L 02 T P C 02

'( Hrs () Hrs*wee+

1.

,tomi& Stru&ture: Idea of de Broglie matter wave, Heisenberg n!ertaint" #rin!i#le, atomi! orbitals, $!%r&dinger wave e' ation, signifi!an!e of and

2, ( ant m n mbers, radial and ang lar wave f n!tions and #robabilit"
distrib tion ! rves, s%a#es of s, #, d orbitals, effe!tive n !lear !%arge. 2. Periodi& Properties: Trends in #eriodi! table and a##li!ations in #redi!ting and e)#laining t%e #%"si!al and !%emi!al be%aviors. *tomi! and ioni! radii, ioni+ation energ", ele!tron affinit" and ele!tro negativit". ,. Chemi&al -onding : -alen!e bond t%eor" and its limitations, dire!tional !%ara!teristi!s of !ovalent bond, vario s t"#es of %"bridi+ation and of sim#le inorgani! mole! les and ions, -alen!e s%ell and H23. 73 t%eor", %omon !lear and ele!tron s%a#es #air

re# lsion .-$/P01 t%eor" and its a##li!ations to 2H ,, H,34, $56, Cl5,, ICl2%eteron !lear .C3 and 231 diatomi! mole! les,m lti!enter bonding in ele!tron defi!ient mole! les, bond strengt% and bond energ", #er!entage ioni! !%ara!ter, from di#ole moment and ele!tronegativit" differen!e. 8ea9 intera!tions, H"drogen bonding, van der 8aal for!es. 6. $oni& Solids : Con!e#t and #ro#erties of ioni! bond and str !t re of ioni! !oordination n mber, limitation of radi s #olari+ing bond : #ower free defe!ts, semi!ond !tors, latti!e energ" and Born : Haber 7etalli! !om#o nds, radi s ratio effe!t and ratio r le, latti!e

!"!le, $olvation energ" and sol bilit" of ioni! solids, and Polari+abilit" of ions, 5a;an<s r le. ele!tron, valen!e bond t%eor".

=.

Chemistry of .o/el gases: C%emi!al #ro#erties of t%e 2obel gases, !%emistr" of >enon, str !t re and bonding in )enon !om#o nds.

CH!"C ##) Paper " $$ General 0rgani& Chemistry"$

L 01 T P C 01 #1 Hrs (# Hrs*wee+

#.

Stru&ture and -onding: H"bridi+ation, bond lengt% and bond angles, bond energ", lo!ali+ed and delo!ali+ed !%emi!al bond, in!l sion !om#o nds, !lat%rates, !%arge transfer !om#le)es, resonan!e, %"#er-!on; gation, aromati!it", ind !tive and field effe!ts, %"drogen bonding.

).

Me&hanism of 0rgani& rea&tions: C rved arrow notations, drawing ele!tron movement wit% arrows, %alf%eaded and do ble-%eaded arrows, %omol"ti! and %eterol"ti! bond brea9ing. T"#es of reagents : ele!tro#%ili! and n !leo#%ili!. T"#es of organi! rea!tions, rea!tive intermediates : !arbo!ations, !arbanians, free radi!als, !arbenes, ar"nes and nitrenes .wit% e)am#les1

'.

Stereo&hemistry : Con!e#t of isomerism, t"#es of isomerism, o#ti!al isomerism. /lements of s"mmetr", !%iralit", enantiomers, !%iral and two stereogeni! !enters, meso a!%iral mole! les re!emi+ation. wit% diastereomers, t%reo and er"t%ro diastereomers,

!om#o nds, resol tion, inversion, retention and

0elative and absol te !onfig ration and se' en!e r les. 0 $ s"stem of nomen!lat re. CH!"C ##' Paper 2$$$% General Physi&al Chemistry"$
L 01 T P C 01 #1 Hrs (# Hrs*wee+

#. Mathemati&al Con&ept %

Logarit%mi! relations, ! rve s9et!%ing, linear gra#%s and !al! lation of slo#es, differentiation of f n!tions li9e >n , e), sin ), log )? ma)ima and minima, #artial differentiation and re!i#ro!a!it" relations. Integration of some sef l@relevant f n!tions? #erm tations and !ombinations, fa!torials. Probabilit". 2. Computers: introd !tion to !om# ters, different !om#onents of a !om# ter, %ardware and software, In# t : 3 t# t devi!es, binar" n mbers and binar" arit%meti!. Introd !tion to !om# ter lang ages, Programming, o#erating s"stem. '. Gaseous states % -ander 8aals e' ation of state, t%e isot%erms of van der 8aal e' ation, relations%i# between !riti!al !onstants and van der 8aal !onstants. T%e law of !orres#onding states, red !ed e' ation of state. 3. Mole&ular velo&ities% 0oot mean s' are velo!it", average and most #robable velo!ities. ( alitative dis! ssion of t%e 7a)well<s distrib tion of velo!ities, !ollision n mber, mean free #at% and 1. 4i5uid State % Intermole! lar for!es, str !t re of li' ids .a ' alitative $tr !t ral differen!es between solids, li' ids and Classifi!ation, str !t re of nemati! and !%olestri! and seven segment !ell. gases. li' ids. T%ermogra#%" #%ases. des!ri#tion1. li' efa!tion of gases based on Ao le : T%omson effe!t. mole! lar diameter, !ollision

Li' id !r"stals, differen!e between li' id !r"stals, solid and

CH!"C ##3 General Chemistry"$ 4a/oratory Course

L 0 T P 02 C 02 '( Hrs () Hrs*wee+

Beneral Instr !tions: Calibration of fra!tional weig%ts, balan!e and 9nowledge of vol metri! meas rement a##arat s and meas rement nits. Inorgani! C%emistr": Pre#aration of standard sol tions and t%eir verifi!ation .ma)im m two e)am#les1. $emi mi!ro anal"sis : *nion and !ation anal"sis, $e#aration and identifi!ation of !ations from Bro # I, II, III, I-, and -I on t%e basis of sol bilit" of t%eir C%lorides, H"dro)ides, $ l#%ides, Carbonates, P%os#%ates et!. salts. 3rgani! C%emistr": Cete!tion of elements : 2itrogen, $ l#% r and %alogens. $tandardi+ation of t%ermometers and determination of melting #oints Cetermination of boiling #oints. 7i)ed melting #oint determination. P rifi!ation of organi! !om#o nds: s blimation, !r"stalli+ation and distillation. P%"si!al C%emistr" C%emi!al 9ineti!s : %"drol"sis of met%"l a!etate@ et%"l a!etate !atal"+ed b" H4 ions /ffe!t of strengt% of a!ids on %"drol"sis of ester Pre#aration of arseni s s l#%ides sol. * !om#arative a!!o nt of mono, di and tri-valent ions d ring !oag lation $ rfa!e tension determination Per!entage !om#osition of binar" mi)t res b" s rfa!e tension.