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CONFIDENTIAL

R12.0
Material Characterization for
CAE Simulation
Technical Research Division
Rheology Laboratory
2
> General
CAE and physical properties measurement P. 3
Laboratory equipments P. 4
Sample preparation P. 5
> Measurement of thermoplastic
Viscosity P. 7
Density (P-v-T) P. 9
Crystallization P. 11
Thermal properties (Cp, k) P. 12
Mechanical properties (E, ) P. 14
> Measurement of thermoset
Reactivity (cross-linking, curing kinetics) P. 16
Chemorheology of reactive material P. 17

Content
3
Constitutive equation
= f (, deformation, )
Conversion rate, R
Heat capacity, C
p
Thermal conductivity, k

Density, (P-v-T);
v
P, T
=f ()
Physical properties considered in CAE
t

: u V V = |
.
|

\
|
V +
c
c
T k T
t
T
Cp
g p
Dt
D
+ V V =
u
0 = + V + R j X

( ) 0 = V +
c
c
u

t
Thermodynamic
state
END FLOW PROPERTY to POST DEFORMATION
Thermoset: E(t, T, C)
Thermoplastic: E(t, T); Poisson ratio,
Mass
balance
Energy
balance
Momentum
balance
Cross-
linking
kinetics
4
Laboratory equipments
MCR 502
Rotation and
oscillation
test for
viscoelastic
property
CR-6000
Viscosity
Rheograph RG25
k, viscosity,
counter pressure
equipped
DSC 8500
Heating rate: 750 /min
Cooling rate: 600 /min
Min temp -180 (LN2)
pvT100
P-v-T
5
Sample preparation - Storage and treatment
Freezer
Vacuum oven
Halogen moisture analyzer
Mettler Toledo, HG63
Moisture level 0.01%
Analytical balance
Mettler Toledo, AE100+
Sensitivity 0.1 mg
6
Measurement of thermoplastics
7
Viscosity measurement
Rotational rheometer
Drag flow
Capillary rheometer
Pressure driven flow
Non-Newtonian
8
Viscosity data
Curve fitting:
turn scattered data points into usable
material function for CAE analysis
9
Density (P-v-T)
10
5 C/min 200 C/min
P-v-T of Semicrystalline Polymer
> Effect on different cooling rate
11
Crystallization coupled w/ P-v-T
12
Thermal properties - Thermal Conductivity (k)
13
Thermal properties - Heat capacity (Cp)
Differential Scanning Calorimeter
Perkin-Elmer, DSC 8500
Heating rate: 750 /min
Cooling rate: 600 /min
Min temp -180 (LN2)
14
Mechanical properties (E, )
> Youngs modulus will be tested at different temperature
and different level of cross-linking.

15
Measurement of thermoset
16
Reactivity (cross-linking, curing kinetics)
Conversion vs. Heating rate
17
Chemorheology of reactive material
Shear rate = 1/s
> Viscosity-Conversion Relationship
Thank you for your attention!

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