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Chapters covered from the textbook (Elements of CRE, 4th Ed., Fogler, 2006) 1.Chapters 1 4 (Mid Term Exam) 2.Chapter 6 3.Chapter 5 (Sections 5.1 5.3) 4.Chapter 8 5.Chapter 10
Learning sources
Textbook CD-ROM
Summary notes Web modules Interactive Computer modules (ICMs) Solved problems
Living example problems, Professional Reference Shelf, Software toolbox (Polymath, COMSOL).
Todays lecture
Chapter 1: Introduction
Definitions General Mole Balance Equation Batch CSTR PFR PBR
Chemical Identity
A chemical species is said to have reacted when it has lost its chemical identity.
Chemical Identity
A chemical species is said to have reacted when it has lost its chemical identity. The identity of a chemical species is determined by the kind, number, and configuration of that species atoms.
Chemical Identity
A chemical species is said to have reacted when it has lost its chemical identity.
1. Decomposition
Chemical Identity
A chemical species is said to have reacted when it has lost its chemical identity.
1. Decomposition
2. Combination
Chemical Identity
A chemical species is said to have reacted when it has lost its chemical identity.
1. Decomposition
2. Combination
3. Isomerization
Reaction Rate
The reaction rate is the rate at which a species looses its chemical identity per unit volume.
Reaction Rate
The reaction rate is the rate at which a species looses its chemical identity per unit volume. The rate of a reaction (mol/dm3/s) can be expressed as either the rate of Disappearance: -rA or as the rate of Formation (Generation): rA
Reaction Rate
Consider the isomerization
rA = the rate of formation of species A per unit volume -rA = the rate of a disappearance of species A per unit volume rB = the rate of formation of species B per unit volume
A B
Reaction Rate
EXAMPLE: AB
If Species B is being formed at a rate of 0.2 moles per decimeter cubed per second, ie, rB = 0.2 mole/dm3/s
Reaction Rate
EXAMPLE: AB
rB = 0.2 mole/dm3/s Then A is disappearing at the same rate: -rA= 0.2 mole/dm3/s
Reaction Rate
EXAMPLE: AB
rB = 0.2 mole/dm3/s
Then A is disappearing at the same rate: -rA= 0.2 mole/dm3/s The rate of formation (generation of A) is rA= -0.2 mole/dm3/s
Reaction Rate
For a catalytic reaction, we refer to rA, which is the rate of disappearance of species A on a per mass of catalyst basis. (mol/gcat/s) NOTE: dCA/dt is not the rate of reaction
Reaction Rate
Consider species j: rj is the rate of formation of species j per unit volume [e.g. mol/dm3/s]
Reaction Rate
rj is the rate of formation of species j per unit volume [e.g. mol/dm3*s] rj is a function of concentration, temperature, pressure, and the type of catalyst (if any)
Reaction Rate
rj is the rate of formation of species j per unit volume [e.g. mol/dm3/s] rj is a function of concentration, temperature, pressure, and the type of catalyst (if any) rj is independent of the type of reaction system (batch reactor, plug flow reactor, etc.)
Reaction Rate
rj is the rate of formation of species j per unit volume [e.g. mol/dm3/s] rj is a function of concentration, temperature, pressure, and the type of catalyst (if any) rj is independent of the type of reaction system (batch, plug flow, etc.) rj is an algebraic equation, not a differential equation
V=
dF A FA 0 rA
FA
V=
dF A FA 0 rA
FA
This is the volume necessary to reduce the entering molar flow rate (mol/s) from FA0 to the
exit molar flow rate of FA.
r dW =
A
dNA dt
r dW =
A
dNA dt
r dW =
A
dNA dt
r dW =
A
dNA dt
W=
dFA FA 0 r A
FA
KEEPING UP
Separations
Filtration
Distillation
Adsorption
Reaction Engineering
Mole Balance
Rate Laws
Stoichiometry
Heat Effects
Isothermal Design
Stoichiometry Rate Laws Mole Balance
Mole Balance
Rate Laws
Rate Laws
Mole Balance