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CAMBRIDGE INTERNATIONAL EXAMINATIONS GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/22 Paper 2 (AS Structured Questions), maximum raw mark 60
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the details of the discussions that took place at an Examiners meeting before marking began, which would have considered the acceptability of alternative answers. Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2013 series for most IGCSE, GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
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Page 2 Mark Scheme GCE AS/A LEVEL May/June 2013 a base is a proton acceptor or a lone pair donor a weak base is not fully ionised e.g. NH3 + H2O NH4+ + OH or B + H+ BH+ or equivalent is necessary (b) (i) stated pressure stated temperature named catalyst greater than 1 atm up to 5 atm 400 to 500 oC V2O5/vanadium(V) oxide Syllabus 9701 Paper 22
(a)
(1) (1)
[3]
(ii) SO3 is dissolved in concentrated H2SO4 and then diluted with water not 'SO3 dissolved in water' as the only statement (c) (i) with concentrated sulfuric acid ClCH2CH=CHCl with ammonia H2NCH2CH(OH)CH2NH2 (ii) nucleophilic substitution
(1)
[4]
[Total: 11]
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Page 3 Mark Scheme GCE AS/A LEVEL May/June 2013 Syllabus 9701 Paper 22 (1) (1) (1) (1) (1) (1) (1)
(a) (i) n(H2SO4) = (ii) (iii) (iv) (v) (vi) (vii) (viii)
25.0 1.00 = 0.025 mol 1000 16.2 2.00 n(NaOH) = = 0.0324 mol 1000 0.0324 = 0.0162 mol n(H2SO4) reacting with NaOH = 2 n(H2SO4) reacting with NH3 = 0.025 - 0.0162 = 0.0088 mol n(NH3) reacting with H2SO4 = 2 x 0.0088 = 0.0176 mol n(NaNO3) reacting = n(NH3) produced = 0.0176 mol mass of NaNO3 that reacted = 0.0176 x 85 = 1.496 g 1.496 100 = 91.2195122 = 91.2 % of NaNO3 = 1.64 give one mark for the correct expression give one mark for answer given as 91.2 i.e to 3 sig. fig. allow ecf where appropriate
(b)
(1)
[1]
[Total: 10]
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Page 4 3 (a) (i) (ii) (iii) (iv) (v) (vi) (b) (i) element oxide Na Na2O yellow or orange Mg MgO Al Al2O3 Si SiO2 P P2O5/P4O10 or P2O3/P4O6 white or yellow S SO2 Mark Scheme GCE AS/A LEVEL May/June 2013 Syllabus 9701 Paper 22 penalise (-1) the use of names of elements or formulae of compounds Ca O or N or C C or N or S or F or Cl or Br Si or Ge or B Al or Si or P or S or H Al (1) (1) (1) (1)
(1) (1)
[6]
flame
white
white
white
blue
(1) (1)
chloride pH
NaCl 7
AlCl3 or Al2Cl6
SiCl4
PCl3 or PCl5
SCl2 or S2Cl2
1 to 4
(1) (1)
[4]
(1) (ii) intermolecular forces/van der Waals forces are stronger or greater in ICl ICl has most electrons or has the largest permanent dipole (iii) ICl greatest difference in electronegativity is between I and Cl
[5]
[Total: 15]
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Page 5 4 (a) Mark Scheme GCE AS/A LEVEL May/June 2013 Syllabus 9701 Paper 22
CH3CHBrCHBrCH2OH
PCl5
CH3CH=CHCH2Cl
H2 and Ni catalyst
CH3CH2CH2CH2OH
NaBH4
NO REACTION
CH3CH=CHCO2H
(5 1)
[5]
(1) (c)
[1]
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Page 6 (d) (i) reagent 2,4-dinitrophenylhydrazine Tollens' reagent Fehlings reagent correct reagent observation (ii) reduction or nucleophilic addiction Mark Scheme GCE AS/A LEVEL May/June 2013 observation red/orange ppt. silver mirror or grey ppt. or black ppt. brick red ppt. (1) (1) (1) [3] Syllabus 9701 Paper 22
(e)
C : H : O =
(1)
[2]
[Total: 13]
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Page 7 5 (a) (b) C4H8O2 Mark Scheme GCE AS/A LEVEL May/June 2013 Syllabus 9701 Paper 22 (1) [1]
HCO2CH2CH2CH3 W CH3CO2CH2CH3 Y
give one mark for each correct answer (c) (i) CHO or aldehyde absent (ii) >CO or carbonyl absent (iii) CO2H or carboxylic acid present (d) (i) CH3CO2H or ethanoic acid (ii) Y above (e) none no chiral carbon atoms present
HCO2CH(CH3)2 X CH3CH2CO2CH3 Z
(4 1) [4]
[3]
[2] [1]
[Total: 11]