UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

General Certificate of Education Ordinary Level

CHEMISTRY
5070/01
Paper 1 Multiple Choice
May/June 2004
1 hour
Additional Materials: Multiple Choice Answer Sheet
Soft clean eraser
Soft pencil (type B or HB is recommended)
READ THESE INSTRUCTIONS FIRST
Write in soft pencil.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Write your name, Centre number and candidate number on the answer sheet in the spaces provided
unless this has been done for you.
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C, and D.
Choose the one you consider correct and record your choice in soft pencil on the separate answer sheet.
Read the instructions on the Answer Sheet very carefully.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is to be found on page 16.
This document consists of 16 printed pages.
IB04 06_5070_01/FP
UCLES 2004
[Turn over
2
UCLES 2004 5070/01/M/J/04
1 Aqueous hydrogen peroxide undergoes catalytic decomposition as shown in the equation below.
2H
2
O
2
(aq) 2H
2
O(l) + O
2
(g)
The diagram shows part of the apparatus used to measure the rate of decomposition.
X
catalyst
aqueous
hydrogen
peroxide
Which piece of apparatus is connected at position X?
A burette
B gas syringe
C measuring cylinder
D pipette
2 A mixture of two substances is spotted on to a piece of chromatography paper.
The paper was inserted into a beaker containing a liquid.
liquid
beaker
spot of mixture
chromatography paper
For separation of the substances to occur the mixture must
A be placed so that the spot is just below the level of the liquid.
B be soluble in the liquid.
C contain substances of the same R
f
values.
D contain substances that are coloured.
3
UCLES 2004 5070/01/M/J/04 [Turn over
3 In a sample of air at 25
o
C, the molecules of oxygen, nitrogen and carbon dioxide all move with
different average speeds.
Which of the following lists the molecules in order of decreasing average speed?
fastest slowest
A carbon dioxide oxygen nitrogen
B nitrogen oxygen carbon dioxide
C oxygen carbon dioxide nitrogen
D oxygen nitrogen carbon dioxide
4 Which of the following is the best method of obtaining pure water from ink?
A chromatography
B distillation
C filtration
D freezing
5 The relative molecular mass, M
r
, of copper(II) sulphate, CuSO
4
, is 160.
The relative molecular mass, M
r
, of water is 18.
What is the percentage by mass of water in copper(II) sulphate crystals, CuSO
4
.5H
2
O?
A
160
100 x 18
B
8 1 160
100 x 18 x 5
+
C
18 160
100 x 18
+
D
18) x (5 160
100 x 18 x 5
+
4
UCLES 2004 5070/01/M/J/04
6 A solution of fertiliser was tested as shown.
fertiliser
solution
dirty green
precipitate
forms
add excess aqueous
sodium hydroxide
solution
warm the
mixture
moist red litmus
paper turns blue
Which ions must be present in the fertiliser?
A NH
4
+
and NO
3

B NH
4
+
and Fe
2+
C Fe
2+
and SO
4
2
D Fe
3+
and NO
3

7 An element X has two isotopes,

238
X and
235
X.
How does
238
X differ from
235
X?
A It has 3 more protons and 3 more electrons.
B It has 3 more protons, but no more electrons.
C It has 3 more neutrons and 3 more electrons.
D It has 3 more neutrons, but no more electrons.
5
UCLES 2004 5070/01/M/J/04 [Turn over
8 The formulae of the ions of four elements are shown below.
O
2

Li
+
Mg
2+
Which statement about these ions is correct?
They all have
A the same number of electrons in their outer shells.
B the same electronic structure as a noble gas.
C the same number of protons in their nuclei.
D more electrons than protons.
9 Which diagram represents the structure of sand, SiO
2
?
10 What happens when sodium chloride melts?
A Covalent bonds in a giant lattice are broken.
B Electrons are released from atoms.
C Electrostatic forces of attraction between ions are overcome.
D Molecules are separated into ions.
key
A B
C
D
Silicon atom
Oxygen atom
6
UCLES 2004 5070/01/M/J/04
11 In the circuit below, the lamp lights up.
lamp
substance X
electrodes
What could X be?
A a solution of ethanol in water
B a solution of sodium chloride in water
C liquid ethanol
D solid sodium chloride
12 The formula of china clay (aluminium silicate) was shown in an old book as Al
2
O
3
.2SiO
2
.2H
2
O.
This formula is shown in a modern book as Al
2
(OH)
x
Si
2
O
y.
What are the values of x and y in the modern formula?
x y
A 2 4
B 2 5
C 4 3
D 4 5
13 What is the concentration of iodine, I
2
, molecules in a solution containing 2.54 g of iodine in
250 cm
3
of solution?
A 0.01 mol / dm
3
B 0.02 mol / dm
3
C 0.04 mol / dm
3
D 0.08 mol / dm
3
14 The formula of an oxide of uranium is UO
2
.
What is the formula of the corresponding chloride?
A UCl
2
B UCl
4
C U
2
Cl D U
4
Cl
7
UCLES 2004 5070/01/M/J/04 [Turn over
15 The equation for the burning of hydrogen in oxygen is shown below.
2H
2
(g) + O
2
(g) 2H
2
O(g)
Which information does this equation give about the reaction?
A 36 g of steam can be obtained from 16 g of oxygen.
B 2 g of hydrogen combine with 1 g of oxygen.
C 2 mol of steam can be obtained from 1 mol of oxygen.
D 2 atoms of hydrogen combine with 2 atoms of oxygen.
16 A current was passed through concentrated aqueous potassium chloride, KCl, as shown.
concentrated aqueous
potassium chloride
+
_
Which entry in the table is correct?
ions moving towards
the cathode (-ve) the anode (+ve)
A K
+
only Cl

and OH

B K
+
only Cl

only
C K
+
and H
+
Cl

only
D K
+
and H
+
Cl

and OH

8
UCLES 2004 5070/01/M/J/04
17 When the experiment shown was set up, the bulb lit, but there were no decomposition products at
the electrodes.
lamp
X
electrodes
+ve
_
ve
What is X?
A aqueous sodium chloride
B bromine
C molten sodium chloride
D mercury
18 Which of the following changes is endothermic?
A H(g) + Cl(g) HCl(g)
B H
2
O(g) 2H(g) + O(g)
C H
2
O(l) H
2
O(s)
D 2H
2
(g) + O
2
(g) 2H
2
O(l)
9
UCLES 2004 5070/01/M/J/04 [Turn over
19 The diagram shows apparatus for measuring the volume of hydrogen given off when an excess of
dilute hydrochloric acid is added to powdered metal. The volume of gas is measured at room
temperature and pressure.
tap
dilute
hydrochloric
acid
metallic
powder
water
graduated
tube
The experiment is carried out three times, using the same mass of powder each time but with
different powders:
pure magnesium
pure zinc
a mixture of magnesium and zinc
Which powder gives the greatest volume of hydrogen and which the least volume?
greatest volume of H
2
least volume of H
2
A magnesium zinc
B magnesium the mixture
C zinc magnesium
D zinc the mixture
20 Which change will increase the speed of the reaction between 1 mol of each of the gases, X and
Y?
A a decrease in surface area of the catalyst
B a decrease in temperature
C a decrease in the volume of the reaction flask
D an increase in the volume of the reaction flask
10
UCLES 2004 5070/01/M/J/04
21 Dilute hydrochloric acid was reacted with magnesium ribbon and the volume of hydrogen gas
evolved was measured for the first 80 s.
0 10 20 30 40 50 60 70 80
0
10
20
30
40
time from start of reaction/ s
total
volume of
hydrogen
produced/ cm
3

What was the average rate of production of hydrogen?
A 0.4 cm
3
/ s B 2.5 cm
3
/ s C 4 cm
3
/ s D 40 cm
3
/ s
22 Small portions of aqueous potassium iodide and of acidified, aqueous potassium manganate(VII)
were added to four solutions. The colour changes seen are shown in the table.
solution number potassium iodide potassium manganate(VII)
1 colourless to red purple to colourless
2 colourless to red no change
3 no change purple to colourless
4 no change no change
Which solutions contained an oxidising agent?
A 1 only B 1 and 2 only C 1 and 3 only D 2 and 4 only
11
UCLES 2004 5070/01/M/J/04 [Turn over
23 The table gives information about three indicators.
colour change
indicator
low pH high pH
pH at which colour
change takes place
methyl orange red yellow 4.0
bromothymol blue yellow blue 6.5
phenolphthalein colourless pink 9.0
If equal volumes of these three indicators were mixed, which colour would be observed at pH 5?
A blue
B green
C orange
D yellow
24 A solution of hydrochloric acid has a concentration of 2 mol / dm
3
.
Different volumes of the acid are added to different volumes of aqueous sodium hydroxide.
NaOH + HCl NaCl + H
2
O
The maximum temperature of each mixture is measured. The graph shows the results.
temperature /
o
C
0
50
10
40
20
30
30
20
40
10
50
0
HCl / cm
3
NaOH / cm
3
What is the concentration of the aqueous sodium hydroxide?
A 0.67 mol / dm
3
B 1.3 mol / dm
3
C 1.5 mol / dm
3
D 3.0 mol / dm
3
12
UCLES 2004 5070/01/M/J/04
25 Which method of preparation of a pure salt solution requires the use of a pipette and burette?
A BaCl
2
(aq) + H
2
SO
4
(aq) BaSO
4
(s) + 2HCl (aq)
B CuO(s) + 2HCl (aq) CuCl
2
(aq) + H
2
O(l)
C KOH(aq) + HCl (aq) KCl (aq) + H
2
O(l)
D MgCO
3
(s) + H
2
SO
4
(aq) MgSO
4
(aq) + H
2
O(l) + CO
2
(g)
26 Which statement about the manufacture of ammonia by the Haber Process is correct?
A The reactants and product are elements.
B The reactants and product are gases.
C The reactants and product are compounds.
D The reactants are both obtained from the air.
27 Which of the following occurs in the Contact process?
A Sulphur dioxide is dissolved in water.
B Sulphur trioxide is dissolved in water.
C Sulphur dioxide is dissolved in dilute sulphuric acid.
D Sulphur trioxide is dissolved in concentrated sulphuric acid.
28 The diagrams show the arrangements of the electrons of four elements.
element 4 element 3 element 2 element 1
Which two elements are metals?
A 1 and 2
B 1 and 3
C 2 and 4
D 3 and 4
13
UCLES 2004 5070/01/M/J/04 [Turn over
29 Sodium, aluminium and sulphur are in the same period of the Periodic Table.
What trend in types of oxide occurs across this period?
left right
A acidic amphoteric basic
B amphoteric basic acidic
C basic acidic amphoteric
D basic amphoteric acidic
30 Use the Periodic Table to decide which element has all four of the properties shown.
high melting point
variable oxidation states
good electrical conductivity
forms coloured compounds
A caesium, Cs
B cobalt, Co
C iodine, I
D strontium, Sr
31 Iron rusts when exposed to oxygen in the presence of water.
Which of these methods will not slow down the rate of rusting of an iron roof?
A attaching strips of copper to it
B coating it with plastic
C galvanising it with zinc
D painting it
32 Why does aluminium have an apparent lack of reactivity?
A Aluminium has a coating of aluminium oxide, preventing further reaction.
B Aluminium has a giant molecular structure that is too hard to break.
C Aluminium is low in the reactivity series.
D The activation energy for the reaction of aluminium with other elements is too high.
14
UCLES 2004 5070/01/M/J/04
33 Which oxide can be reduced to the metal by hydrogen?
A calcium oxide
B copper(II) oxide
C magnesium oxide
D sodium oxide
34 The data gives the concentration, in parts of pollutant per billion parts of air, of polluting gases in
four different industrialised cities.
In which city are limestone buildings under greatest threat from pollution?
city
sulphur
dioxide
nitrogen
dioxide
ozone
A 17 46 23
B 32 33 30
C 38 40 11
D 45 14 21
35 The water in a lake contains the following dissolved substances.
mineral salts
nitrates
oxygen
phosphates
sewage
How many of these substances can cause eutrophication?
A 1 B 2 C 3 D 4
36 The equation represents the conversion of starch to a simple sugar.
(C
6
H
10
O
5
)
n
+ n H
2
O n C
6
H
12
O
6
starch simple sugar
This reaction is an example of
A condensation.
B hydrogenation.
C hydrolysis.
D polymerisation.
15
UCLES 2004 5070/01/M/J/04
37 Methane, CH
4
, the first member of the alkane homologous series, has a boiling point of 161
o
C.
Which molecular formula and boiling point could be correct for another alkane?
molecular formula boiling point /
o
C
A C
2
H
4
88
B C
2
H
6
185
C C
3
H
6
69
D C
3
H
8
42
38 A student carries out three tests on a gas X.
test results
damp red litmus paper stays red
aqueous bromine stays brown
lighted splint gas burns
Which gas could be X?
A ammonia
B ethene
C methane
D oxygen
39 An organic compound, Y, reacts with sodium hydroxide to give a compound with formula
C
3
H
5
O
2
Na.
What is compound Y?
A ethanol
B propane
C propanoic acid
D propanol
40 Which compound has an addition reaction with chlorine?
A C
2
H
4
B C
2
H
6
C C
2
H
5
OH D CH
3
CO
2
H
16
University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES) which is itself a department of
the University of Cambridge.
5070/01/M/J/04
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