Natural Rubber

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Natural rubber
Version 1.0.0.05
[German version]
Table of contents
General:
Product information
Packaging
Transport
Container transport
Cargo securing
Risk factors and loss prevention:
Temperature Odor
Humidity/Moisture Contamination
Ventilation Mechanical influences
Biotic activity Toxicity/Hazards to health
Gases Shrinkage/Shortage / Theft
Self-heating/Spontaneous combustion Insect infestation/Diseases
Product information
Product name
German Naturkautschuk
English Natural rubber (NR)
French Caoutchouc naturel
Spanish Caucho natural
CN/HS number * 4001 ff.
(* EU Combined Nomenclature/Harmonized System)
Product description
Rubber is a collective term for macromolecular substances of natural or synthetic origin (natural
rubber or synthetic rubber).
Natural rubber (abbreviated to NR) primarily comprises polyisoprene and is harvested from the
milky white latex of a number of species of plants which flourish in the tropics, above all from the
Spurge family (Euphorbiaceae). The rubber tree (Hevea brasiliensis) has achieved considerable
commercial importance. The tree is native to the Amazon region and is now cultivated in virtually all
tropical regions of South America, Africa and Asia. 90% of the world's production of natural rubber
is harvested from the rubber tree.
A diagonal incision is made in the bark, allowing the latex to exude. The latex has approximately
the following composition:
Constituents Percentage
Water 55...70
Rubber 30...40
Resins 1.5...2
Protein 1.5...3
Ash 0.5...1
Sugar 1...2
The latex, which is rich in rubber, can be preserved by adding ammonia and for special purposes it
can be transported to the countries in which it is processed as latex concentrate in liquid form. This
is done in barrels or in tank containers. It is far more common to filter the harvested latex, dilute it
with water and then to cause it to coagulate using substances such as acetic acid or formic acid or
by means of electrophoresis. This separates the raw natural rubber from the water, forming a solid
mass (coagulum) that is then further processed. Coagulation can also take place in the form of
auto-coagulation on the tapping panel (tree lace) and the collection cups (shell scrap and cup
lumps). Such coagulum has a greater degree of contamination, and is hence used in the natural
rubber grades which have less stringent requirements with respect to contamination.
A distinction is drawn between the following forms of natural rubber:
Crepes
Pale crepe rubber is among the highest quality crepes. Coagulation of this high-quality natural
rubber is achieved with sodium hydrogen sulfite (NaHSO
3
). The clean coagulum is washed and
milled. This produces sheets between 1.2 and 1.5 mm thick and 24 cm wide. The washing
process removes from the coagulum considerable amounts of the serum constituents which
can cause rotting. The sheets are dried in drying rooms for 2.5 to 4 days at 37C or air-dried
for 5 to 10 days on drying floors.
Excessive temperatures lead to discolored patches in the sheets as a result of oxidation. The
sheets are packed as bales and marketed as "thin pale crepe".
The 10-mm crepe from Sri Lanka is marketed as "thick pale crepe".
Sheets
Two different types of sheets are distinguished:
ADS (air dried sheets)
Air dried sheets are less common. They have an appearance similar to RSS (ribbed smoked
sheets), but are more transparent, as they are manufactured in smoke-free rooms.
RSS (ribbed smoked sheets) (see Figure 1)
The fresh latex is diluted to a rubber content of 15 - 16% and coagulated in coagulation
tanks using formic acid or acetic acid. Lumps of coagulum are formed after the acid has
acted for 3-4 hours. After milling and washing, sheets between 2.5 and 3.5 mm thick, 24 cm
wide and 90 or 135 cm in length are produced. The final mill is an embossed mill, which
gives the sheets their ribbed structure. Since these rubber sheets are not washed as
intensively as crepes, they contain a higher proportion of serum constituents which
encourage mold and rotting. For this reason, the sheets undergo an additional preservation
process in which they are smoked in smokehouses. The sheets are hung in the
smokehouses and dried for a week at temperatures up to 60C. The smoke resulting from
burning Hevea (rubber tree) wood and other organic materials such as coconut husks
preserves the sheets. The specific smell of these sheets is caused by the materials used to
produce the smoke. The sheets are pressed into bales and wrapped in protective sheets.
The surface is protected from oxidation by application of a bale coating solution and talcum.
Figure 1: Manufacture of ribbed smoked sheets
Technically specified natural rubber (TSR) - Standard rubber
TSRs are divided into a number of grades which are laid down in technical specifications
drafted by ISO and are manufactured using new processing techniques. Depending on the
TSR quality, different forms of coagulum are used: latex coagulated naturally in the collecting
cups (cup lumps), rubber sheets or latex coagulated by adding acid.
Different methods are used to produce TSRs, e.g. the Heveacrumb or Dynat processes.
In the Heveacrumb process, rubber coagulum is passed through creping rolls set at friction
speed and the shear forces involved tear the coagulum into small pieces. This process is
described as crumbling.
The Dynat process primarily uses cup lumps. After natural coagulation or acid coagulation, the
rubber is granulated by means of a rotary knife cutter. After granulation, the crumb is washed
and dried at elevated temperature up to 140C. Then the crumbs are compressed into blocks
of about 33 1/3 kg, wrapped in synthetic plastic sheeting (high-quality polyethylene bags) and
packaged in wooden or steel chests. [69]
The advantages of Technically Specified Rubbers over the conventional sheet and crepe
grades of rubbers are as follows:
Since it is available in a limited number of well defined grades, correct choice of grades
according to requirements by the consumers is rather easy.
Since it is possible to assess the actual content of foreign and volatile matter, mistakes can
be avoided in deciding the actual worth of the material.
Since it is marketed as compact, polyethylene wrapped bales, degradation of the rubber
on storage, handling and transportation can be reduced.
Since sizes have been standardized and the bales are compact, considerable savings can
be made in transport through mechanized handling and containerization.
Preserved latex concentrates
Ammonia is added to the latex to keep it liquid, and this is concentrated either by creaming or
centrifuging. The resulting concentrate can be transported as a liquid. Depending on the
quantity of ammonia added, a distinction is made between high-ammonia latex (HA) with 0.60
- 0.80 % ammonia and low-ammonia latex (LA) with 0.20 - 0.29 % ammonia.
Latex can be processed to make other raw rubber products:
Skim rubber
Skim rubber is produced from skim latex. Skim latex is produced as a byproduct during the
preparation of latex concentrate. It has a dry rubber content of only 3 to 7%. However, it also
has a very low dirt content. Coagulation of skim latex can be either spontaneous or by acid
treatment. It is important that the ammonia content is kept as low as possible. Further
processing is the same as for smoked sheet. [69]
Rubber powder
In order to reduce transportation costs, the latex can be converted to a fine rubber powder
instead of transporting it in the form of latex concentrates. This is done by atomizing the latex
and drying it with hot air. This form of rubber can be kept for long periods and is particularly
resilient.
Quality/Duration of storage
Crepes
In addition to the high quality thick and thin pale crepes, there are further categories which are
made from high-grade rubber scrap (field coagulum), e.g.:
Estae brown crepe
Thin brown crepe (remills)
Thick blanket crepe (ambers)
Flat bark crepe
Smoked blanket crepe
Sheets
Ribbed smoked sheets are graded on the basis of visual assessments (RSS IX, RSS 1, RSS 2,
RSS 3, RSS 4 and RSS 5). The grades have been described in the Green Book, published by
the International Rubber Quality and Packing Conference.
Prior to grading, the sheets are separated and inspected. Oxidized spots or streaks, weak,
heated, under-cured, oversmoked, opaque and burnt sheets are not permissible.
RSS IX is the top grade. The rubber must be provided by the producer in an excellent drying
quality. The rubber must be dry, clean, strong, sound and evenly smoked and free from
blemishes, specks, rust, blisters, sand, dirty packing and any other foreign matter. The
packaging must be clean. Small pinhead bubbles if scattered, will not be objected to.
The remaining grades RSS 1 through RSS 5 represent a sequential lifting of these
requirements.
Under-cured rubber displays patches which have not been dried sufficiently during smoking or
drying.
The International Standards Organisation (ISO) first published the draft Technical
Specifications for Natural Rubber during 1964. Based on these specifications, Malaysia
introduced their Standard Malaysian Rubber (SMR) scheme in 1965 and since then all the
natural-rubber-producing countries have started producing and marketing NR as Technically
Specified Rubbers. This resulted in the introduction of further national standards in addition to
SMR:
Standard Malaysian Rubber SMR
Standard Indonesian Rubber SIR
Standard Sri Lanka Rubber SSR
Standard Vietnam Rubber SVR
Indian Standard Natural Rubber ISNR
Standard Thai Rubber STR
These quality standards lay down the maximum permissible content of dirt, ash, nitrogen and
volatile substances. The following table shows some SMR values: [69]
Parameters
Dirt content
(max. %)
Ash content
(max. %)
Nitrogen content
(max. %)
Volatile
matter
(max.
%)
Color
coding
SMR 5 (see
Figure 2)
0.05 0.60 0.60 0.80
pale
green
SMR 10 0.08 0.75 0.60 0.80 brown
SMR 20 0.16 1.00 0.60 0.80 red
Figure 2
SMR 10, SMR 20 and SMR 50 are general-purpose grades, with SMR 10 being a high grade,
SMR 20 a medium grade and SMR 50 a lower grade.
If finer distinctions between different categories of rubber are required, it is recommended that
the purchaser and seller agree on the quality of the rubber on the basis of a sample.
Aging of natural rubber
Rubber aging processes, particularly as a result of atmospheric conditions, may start as early as
the transportation phase, and negatively impact the quality of the rubber: The effects of oxygen,
heat and light are the primary causes of aging symptoms, with oxidation processes leading to the
formation of hydroxides. These in turn react either by splitting molecules or establishing new cross-
linkages. The result is softening or hardening: oxidized rubber.
Hardening of natural rubber during transport and storage can be prevented by adding chemical
substances (hydroylamine hydrochloride) to achieve a constant viscosity. [69]
Recommended storage duration for natural rubber [72]
Initial storage 5 years
Extended storage 2 years
Recommended storage temperature for natural rubber [73]
Optimum storage temperature 15 - 30C
Storage of latex concentrates [71]
Max. duration of storage 6 - 12 months
Storage and transport temperature 5 - 35C
Intended use
There are a huge variety of applications for natural rubber across the world. The unique
combination of properties found in natural rubber cannot be fully duplicated synthetically. However,
each individual property can be improved on by (synthetic rubber).
Processing of natural rubber to form rubber products
Natural rubber is mixed with various additives designed to give the end product the required
properties, shaped and then vulcanized (see Figure 3).
Figure 3: Diagram showing the processing of rubber [70]
Mastication is a preliminary stage to processing the raw rubber. This process involves the use of
special mechanical equipment and additives (e.g. aromatic mercaptans - sulfur-containing
compounds) at low temperatures to shred the rubber molecules into smaller units. This improves
the plasticity and reduces the viscosity.
After mastication, the rubber is mixed together with fillers, plasticizers and rubber chemicals to
form a homogeneous mass in mills or closed kneaders.
The subsequent end product is preformed by compression molding, injection molding or
calendering. Compression molding machines, for example, are used to produce car tires, soles and
heels for shoes, and bungs. Thin, seamless rubber products, for example, are produced by dipping.
In the final processing step, the molded rubber mixture is vulcanized. The most important
vulcanization medium is sulfur, which is added to the rubber mixture before this is heated.
The tire-manufacturing industry is the world's largest consumer of natural rubber. Tires for cars,
bicycles and aircraft as well as many other kinds of rubber products such as seals, hoses, drive
belts, floor coverings, conveyor belts, molded articles, foam rubber, impregnation substances, and
medical equipment are all made from natural rubber.
Figures
(Click on the individual Figures to enlarge them.)
Figure 4 Figure 5
Countries of origin
Europe
Africa
Ivory Coast, Ghana, Cameroon, Liberia, Nigeria, other West African coastal
countries
Asia
China, India, Indonesia, Cambodia, Malaysia, Philippines, Sri Lanka,Thailand,
Vietnam
America Brazil
Australia
This Table shows only a selection of the most important countries of origin and should not be
thought of as exhaustive.
South-East Asia produces some 80% of the world's natural rubber. The remainder is split between
South-West Asia, Africa and Latin America.
Back to beginning
Packaging
Crepes
Pale crepe rubber is either packed in a double-layered bag (plastic sheeting inside, paper
outside) or the bales are wrapped in plastic sheeting and packed in wooden crates. Thicker
crepes can also be packed in sacking. The entire surface of the bale should be covered with
sufficient talcum to prevent the fibers from adhering to the rubber.

Sheets
Rubber sheets are folded to form bales (e.g. 60 cm x 60 cm and 100 - 113 kg per bale),
compressed and wrapped in protective sheets. A protective coating and talcum are applied to
the surface to protect against oxidation and to prevent the sheets from sticking to each other.
These form a background for stenciling the shipping marks. Bales are transported in crates or
loose in containers (see Figure 6). Skim rubber should not be used as protective sheets.
Figure 6
Sheets can also be simply folded and packed in plastic bags in the form of 35 kg bales. 36
bales together form a load unit of 1260 kg per pallet. These are unitized using shrink-wrap
sheeting or a shroud of plastic film. Metal crates can also be used.

TSRs are wrapped individually in plastic sheeting (polyethylene) and stacked on pallets. These
are unitized using shrink-wrap sheeting or a shroud of plastic film and are also attached to the
pallet with plastic strapping (see Figure 7). A labeling strip must be attached to each load unit.
Figure 7
Alternatively, TSRs can be packed in wooden or steel crates and secured to pallets (see Figure
3). The crates are unitized by being attached to the pallet with steel straps.
Figure 8
TSRs are generally packaged as 33 1/3 kg bales. Generally, 36 bales are loaded on a pallet.

Latex concentrate
Latex concentrates are packed in tanks, barrels and small containers. The capacity of a barrel
is generally 205 kg. [69]
When wooden packaging containers or cargo securing materials are used, it may, under certain
circumstances, be necessary to comply with the quarantine regulations of the country of destination
(Import regulations for packaging containers made from solid wood - IPPC standard) and a
phytosanitary certificate may have to be enclosed with the shipping documents. Information may be
obtained from the phytosanitary authorities of the countries concerned.
Marking of packages
Keep dry Use no hooks Keep away
from heat
(solar radiation)
Back to beginning
Transport
Symbols
General cargo

Liquid cargo
(latex concentrates)
Fire hazard
(flammable solids)
Class 4.1 IMDG Code
(applies to rubber scrap
and residue)
Means of transport
Ship, truck, railroad
Container transport
Standard containers should be used subject to compliance with limits for water content of goods and
packaging. Ideal conditions would be provided by insulated containers or open-sided containers in
well ventilated lower holds (protection from solar radiation and temperature variations).
Tank containers for rubber in liquid form.
Cargo handling
The cargo should not be handled if it is raining or snowing.
Stowage factor
Pale crepe rubber in bales, unpacked 1.55 m
3
/t
Pale crepe rubber in wooden crates 1.10 m
3
/t
Pale crepe rubber in two-layer sacks 1.50 m
3
/t
Ribbed smoked sheet rubber in bales 1.25 m
3
/t
Standard Indonesian rubber block on flat pallet 1.31 m
3
/t
Stowage space requirements
For maritime transport, natural rubber should preferably be stowed below deck. The
holds/containers must be dry, clean and dust-free. Do not stow near heat sources.
Segregation
Fiber rope, thin fiber nets or markings are used for segregation purposes.
Cargo securing
Because of its considerable impact- and pressure-sensitivity, packages of this cargo must be
secured in such a way that they are prevented from damaging each other. Spaces between
packages or pallets must be filled, to prevent slippage or tipping. By selecting the correct packaging
size or cargo unit (area module or area module multiple), holds can be tightly loaded (without
spaces).
Back to beginning
Risk factors and loss prevention
RF Temperature
Natural rubber requires particular temperature, humidity/moisture and possibly ventilation
conditions (SC VI) (storage climate conditions).
Term Temperature range Source
Favorable travel temperature range 5 - 25C [1]
Optimum travel temperature 20C [1]
Temperatures greater than 30C and exposure to sunlight, even for periods of a few hours, result
in activation of the rot-causing bacteria, especially in conjunction with moisture and proteins. In
addition, oxidation and the associated molecular breakdown are encouraged, and the rubber
develops soft patches, stickiness and becomes deformed (oxidized rubber).
If the destination is in a colder climate, the bales jam as a result of the drop in temperature and this
makes the job of unloading the container or means of transport more difficult. Figures 9 and 10
illustrate the typical temperature conditions during a voyage from Singapore to Europe. In this
case, the highest temperatures are recorded in the Gulf of Aden and in the Red Sea. Since the
travel temperature of 30C should not be exceeded (critical travel temperature), the containers
should be stowed below deck where possible. The optimum travel temperature for rubber is 20C.
A temperature of 25C should be maintained virtually constantly over a long period. This value was
recorded as the upper travel temperature limit in Figures 6 and 7.
Figure 9
Figure 10
Rubber starts to melt at approx. 180C.
The lower limit is 5 - 6C, as there is a risk of hardening as a result of crystallization. This can
cause difficulties unloading the container or means of transport because the jammed bales tear.
Latex concentrates also should be protected against extreme temperatures during transport and
storage. If barrel loads are exposed to direct sunlight in tropical and subtropical climates, the high
temperatures can result in a drop in quality.
At temperatures below 4C, the latex concentrates tend to coagulate, which is an irreversible
process. This results in difficulties when unloading, damage and additional costs. [74]
Back to beginning
RF Humidity/Moisture
Term Humidity/water content Source
Relative humidity 70...75 % [1]
Water content 1.08 % [1]
Maximum equilibrium moisture content 75% [1]
The water content of rubber is 1.08 %, and with its low water content, rubber thus belongs to water
content class 1 (WCC 1)(water content classes).
Moisture due to rain, seawater or condensation water must be strictly avoided, as it can lead to rot,
mold, mildew stains and discoloration. Rubber which has become wet and absorbed too much
moisture is termed bleached rubber.
Natural rubber is not hygroscopic. The poor thermal conductivity of rubber may lead to
condensation on the surface from capillary water, which in turn leads to mold and rot.
Since mold and mildew stains can occur in the middle of the cargo block, it is not possible to detect
damage when the consignment is accepted. This can only be detected when the container or means
of transport is unloaded.
Moisture damage is accompanied by unpleasant or penetrating odors.
In any instance of damage, the question must always be raised as to whether the rubber was damp
from the start, i.e. is it a case of precarriage damage, which is the responsibility of the producer, or
did the damage occur during transportation as a result of rain, condensation water or seawater (in
the case of containers which are not watertight being loaded on deck). The microbiological product
analysis as described by Professor Stantschew (see Moisture damage with natural rubber - German
only) can be used to identify the time at which the moisture arose. Three aspects are taken into
account:
Observation of the stages of mold growth
Temperature requirements of the mold
Oxygen requirements of the microorganisms
Back to beginning
RF Ventilation
If the rubber is dry for shipment or container dry, there is no need for ventilation.
Back to beginning
RF Biotic activity
Natural rubber displays 3rd order biotic activity.
It belongs to the class of goods in which respiration processes are suspended, but in which
biochemical, microbial and other decomposition processes still proceed.
Back to beginning
RF Gases
Chemical decomposition and the evolution of gas during processing lead to cavities on or in the
rubber sheets (blisters and bubbles). The inner surfaces of the blisters are often sticky, whereas
those of the bubbles are dry and not sticky.
Back to beginning
RF Self-heating/Spontaneous combustion
Smoking must be prohibited when loading the containers and in the warehouses, as natural rubber
is readily combustible due to its high hydrocarbon content. When natural rubber combusts, it
generates considerable heat (temperatures up to 1,200C) and smoke. A large quantity of gaseous
products and unburned solid particles in the form of thick, black smoke are released, which make
access to the seat of the fire more difficult. Burning rubber produces sputtering, burning drops of
resin, which can cause the fire to spread.
Natural rubber scrap and residue is assigned to Class 4.1 of the IMDG Code (Flammable solids).
If there is a risk of fire, the firefighting personnel should wear automatic breathing apparatus and
protective clothing.
Foam, CO
2
, dry chemicals or sprayed water can be used to extinguish the fire. [72]
Back to beginning
RF Odor
Bales of rubber emit a strong odor of rubber which can become a penetrating odor in the event of
damage.
Active
behavior
Unpleasant smell, so do not stow in the vicinity of foodstuffs, semiluxury
items and animal feedstuffs. Sour and foul odors: These are due to rotting
rubber.
Passive
behavior
Non-odor-sensitive.
Back to beginning
RF Contamination
Active
behavior
None.
Passive
behavior
Rubber is very sensitive to contamination. The thermoplastic properties of
rubber mean that foreign bodies are absorbed either by penetration or
sticking. Splinters become embedded in the rubber bales. This also applies to
rubber packed in thin plywood crates. These can splinter even under low
loads, and are hence also known as "dirty packing".
Depending on the degree to which the contamination has penetrated, it can
be removed by peeling.
The warehouses and containers must be kept absolutely clean, as any
contamination such as grass, pipe splinters, paper, textile scraps, graphite,
coal, ore dust, cement, copper crumbs from cathode copper plates, sulfur,
copper sulfate, and manganese residue will break down the rubber. This
would cause holes to be formed during the production of rubber gloves, for
instance.
Back to beginning
RF Mechanical influences
Rubber should be stowed in such a way as to avoid the risk of crushing.
The fragile wooden crates can splinter even under normal load conditions. Holes in the rubber
caused by wood splinters can adversely affect the value.
Strong rubber: Rubber which is resistant to deformation, i.e. resistant to tension and compression.
Weak rubber: Ribbed smoked sheets which tear easily or part when sudden tension is applied.
Back to beginning
RF Toxicity/Hazards to health
This risk factor has no major influence on transportation of this product.
Back to beginning
RF Shrinkage/Shortage/Theft
It is recommended that loading and unloading should be supervised.
Back to beginning
RF Insect infestation/Diseases
When wooden packaging containers or cargo securing materials are used, it may, under certain
circumstances, be necessary to comply with the quarantine regulations of the country of destination
(Import regulations for packaging containers made from solid wood - IPPC standard) and a
phytosanitary certificate may have to be enclosed with the shipping documents. Information may be
obtained from the phytosanitary authorities of the countries concerned.
Back to beginning
Gesamtverband der Deutschen Versicherungswirtschaft e. V. (GDV),
Berlin 2002-2012, www.tis-gdv.de

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