P

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TARGET : JEE (ADVANCED) 2014
TEST SYLLABUS
Date : 27.04.2014 TEST : CUMULATIVE TEST-3 (CT-3)
Syllabus :
Physical : Mole & Equivalent Concept, Ionic equilibrium & Electrochemistry,
Gaseous State, Sol id State, Surf ace Chemi stry, Thermodynamics &
Thermochemistry.
Inorganic : Inorganic Nomenclature, Periodic table, Chemical Bonding,
Coordination compound, s-block, p-block & Metallurgy.
Organic : Organic Nomenclature, Isomerism, Stereoisomerism, GOC, POC,
tautorism, acids & bases
Course : VIJETA (JPAD)
& VIJAY (JRAD)
Date : 23-04-2014
DPP No. : 05
INORGANIC CHEMISTRY
This DPP & PT-2 is to be discussed (25-04-2014)
DPP No. # 05 (JEE-ADVANCED)
Total Marks : 169 Max. Time : 118 min.
Single correct Objective ('1' negative marking) Q.1 to Q.15 (3 marks, 2 min.) [45, 30]
One or more correct objective (no negative marking) Q.16 to Q.20 (4 marks, 2 min.) [20, 10]
Single digit integer type ('1' negative marking) Q.21 to Q.25 (4 marks, 3 min.) [20, 15]
Double digit integer type (no negative marking) Q.26 to Q.29 (4 marks, 3 min.) [16, 12]
Assertion and Reason ('1' negative marking) Q.30 to Q.32 (3 marks, 3 min.) [09, 09]
Comprehension ('1' negative marking) Q.33 to Q.41 (3 marks, 2 min.) [27, 18]
Match the Following (no negative marking) Q.42 to Q.45 (8 marks, 6 min.) [32, 24]
1. Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (C).Gas (C) on
reaction with magnesium give compound (D) which on hydrolysis gives again gas (B). Identify (B),(C) and (D).
(A) NH
3
, N
2
, Mg
3
N
2
(B) N
2
,NH
3
, MgNH (C) N
2
,N
2
O
5
, Mg(NO
3
)
2
(D) NH
3
, NO
2
, Mg(NO
2
)
2
2. A + H
2
O !" ! B + HCl
B + H
2
O !" ! C + HCl
Compound (A), (B) and (C) will be respectively :
(A) PCl
5
, POCl
3
, H
3
PO
3
(B) PCl
5
, POCl
3
, H
3
PO
4
(C) SOCl
2
, POCl
3
, H
3
PO
3
(D) PCl
3
, POCl
3
, H
3
PO
4
3. By which of the following methods, H
2
O
2
cant be synthesised ?
(A) Addition of ice cold H
2
SO
4
on BaO
2
(B) Addition of ice cold H
2
SO
4
on PbO
2
(C) Aerial oxidation of 2-ethyl anthraquinol (D) Electrolysis of (NH
4
)
2
SO
4
at a high current density
4. Choose the correct sequence for the geometry of the given molecules Borazone, Borazole, B
3
O
6
3
, Fe
2
Cl
6
, trimer of
FCN.
[P stands for planar and NP stands for non-planar]
(A) NP, NP, NP, P, P (B) P, P, NP, NP, P (C) NP, NP, NP, P, NP (D) NP, P, P, NP, P
5. One gas bleaches the colour of flowers by reduction, while the other by oxidation, the two gases respectively may
be :
(A) CO and Cl
2
(B) H
2
S and Br
2
(C) NH
3
and SO
3
(D) SO
2
and Cl
2
6. SbF
5
reacts with XeF
4
to form an adduct. The shapes of cation and anion in the adduct are respectively :
(A) square planar, trigonal bipyramidal (B) T-shaped, octahedral
(C) square pyramidal, octahedral (D) square planar, octahedral
7. Consider the following transformations :
(I) XeF
6
+ NaF !" ! [XeF
7
]

; (II) 2PCl
5
(s) !" ! ; (III) [Al(H
2
O)
6
]
3+
+ H
2
O !" !

[Al(H
2
O)
5
OH]
2+
+ H
3
O
+
Possible transformations are :
(A) I, II, III (B) I, III (C) I, II (D) II, III
8. Which of the following statements are correct about the reaction between the copper metal and dilute HNO
3
?
(I) The principal reducing product is NO gas.
(II) Cu metal is oxidised to Cu
2+
(aq.) ion which is blue in colour.
(III) NO is paramagnetic and has one unpaired electron in antibonding molecular orbital.
(IV) NO reacts with O
2
to produce NO
2
which is linear in shape.
(A) I, II, III (B) I, II (C) II, IV (D) All the above
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9. Cl
2
(g) + Ba(OH)
2
!" !
#
X(aq.) + BaCl
2
+ H
2
O
X + H
2
SO
4
!" !

Y + BaSO
4
Y
K 365 $ #
#
!" ! Z(green) + H
2
O + O
2
Y and Z are respectively :
(A) HClO
4
, ClO
2
(B) HClO
3
, ClO
2
(C) HClO
3
, Cl
2
O
6
(D) HClO
4
, Cl
2
O
7
10. Match column-I with column-II
Column-I Column-II
(P) Nitriding (I) Process of heating steel to redness and then cooling it very slowly.
(Q) Annealing (II) Process of heating steel in presence of NH
3
and producing hard coating
of iron Nitride on the surface of steel.
(R) Tempering (III) Process of heating steel to redness and then cooling it suddenly by plunging
it into water or oil.
(S) Quenching (IV) Process of heating quenched steel to a temperature well below redness
and then cooling it slowly.
P Q R S P Q R S
(A) II I III IV (B) II I IV III
(C) I II IV III (D) I II III IV
11. Consider the following metallurgical processes :
(I) Heating impure metal with CO and distilling the resulting volatile carbonyl (b.p. 43C) and finally decomposition
at 150200C to get the pure metal
(II) Heating the sulphide ore in air until a part is converted to oxide and then further heating in the absence of air to
let the oxide react with unchanged metal sulphide
(III) Electrolysis of the molten electrolyte containing approximately equal amounts of the metal chloride and NaCl to
obtained the metal
The processes used for obtaining magnesium, nickel and copper are respectively.
(A) (I), (II) and (III) (B) (II), (III) and (I) (C) (III), (I) and (II) (D) (II), (I) and (III)
12. Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false.
(i) In Gold Schmidt's thermite process aluminium acts as a reducing agent.
(ii) Mg is extracted by electrolysis of aq. solution of MgCl
2
.
(iii) Extraction of Pb is possible by smelting of its oxide.
(iv) Red Bauxite is purified by Serpecks process.
(A) T T T F (B) T F F T (C) F T T T (D) T F T F
13. In which of following silicate, the number of corner shared per tetrahedron is ' 2 '.
(A) Four membered cylic silicate (B) Pyrosilicate
(C) Orthosilicate (D) 2-D silicate
14. Consider the compounds given below
(A) BiCl
3
(B) SbCl
3
(C) VCl
5
(D) UO
3
15. #G vs T plot in the Ellinghams diagram slopes downward for the reaction
(A) Mg + O
2
" MgO (B) 2Ag + O
2
" Ag
2
O (C) C + O
2
" CO (D) CO + O
2
" CO
2
16. Aqueous solution of borax acid is treated with salicylic acid. Which of the following statements is/are incorrect for
the product formed in the above reaction ?
(A) no product will be formed because both are acids.
(B) product is 4-coordinated complex and optically resolvable.
(C) product is 4-coordinated complex and optically non-resolvable.
(D) there are two newly formed five membered rings.
17. Which of the following statement(s) is/are correct ?
(A) Chlorine dioxide (ClO
2
) is powerful oxidising agent but bleaching action is poorer than Cl
2
.
(B) ClO
2
in alkaline solution undergoes disproportionation.
(C) ClO
2
is diamagnetic in nature.
(D) ClO
2
is a yellow gas but deep red liquid.
18. The extraction of metals from oxide ores may involve :
(A) reduction with carbon (B) reduction with aluminium
(C) electrolyte reduction (D) reduction with CO
19. Froth floatation :
(A) is a physical method of separating mineral from the gangue.
(B) is a method to concentrate the ore depending on the difference in wettability of gangue and the ore.
(C) is used for the sulphide ores.
(D) is a method in which impurities sink to the bottom.
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20. Na
2
S
2
O
3
is oxidised to Na
2
SO
4
by :
(A) Cl
2
(B) Br
2
(C) I
2
(D) KMnO
4
21. Among the following, the number of compounds, that can act as dehydrating agent is ______.
Conc. H
2
SO
4
, anhyd. CaCl
2
, Conc. HNO
3
, CaO , CuSO
4
.5H
2
O , P
2
O
5
22. The number of equivalent Cl O bonds in Cl
2
O
7
is _________.
23. The oxidation state of TI in T!I
3
is_______.
24. Among the following, the number of compounds that would require electrolysis process to get their respective
metal is from their metal compound is _______.
NaCl , Cr
2
O
3
, MgCl
2
, Al
2
O
3
, CaCl
2
, Fe
2
O
3
25. The number of bicarbonates that do not exist in solid form among the following is ____.
LiHCO
3
, NaHCO
3
, Ca(HCO
3
)
2
, KHCO
3
, NH
4
HCO
3
, Ba(HCO
3
)
2
, Mg(HCO
3
)
2
26. H F is a weak acid but on addition of AsF
5
, it becomes a very strong acid. The number of 90 angles in the anionic
part of the product is_________.
27. The sum of oxidation states of all S atoms in pentathionate ion is
28. How many type of the following acids may undergo disproportionation reaction on heating
H
2
C
2
O
4
, H
3
PO
2
, H
3
PO
3
, HClO , HNO
2
, H
2
SO
3
, H
2
SO
4
, HClO
3
29. If Phosphorous acid, Tetrathionic acid and Pyrophosphoric acid have number of acidic hydrogen per molecule
respectively as x, y and z, then find the value of x + y z.
30. Statement-1 : Aluminium and zinc metal evolve H
2
gas from NaOH solution.
Statement-2 : Several non-metals such as P,S,Cl, etc. yield a hydride instead of H
2
gas from NaOH.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
31. Statement-1 : Lead, tin and bismuth are purified by liquation method.
Statement-2 : Lead, tin and bismuth have low m.p. as compared to impurities.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
32. Statement-1 : 2PbO
2
+ H
2
SO
4
!" 2PbSO
4
+ 2H
2
O + O
2
In this reaction H
2
SO
4
acts as reducing agent.
Statement-2 : If PbO
2
is considered as lead peroxide then the above reaction is an example of disproportionation.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
Paragraph for Question Nos. 33 to 34
A white solid having garlic smell (A)
cold
O H
2
! ! " ! (B)
heating
on
! !" ! gas (C) having rotten fish smell + acid (D)
33. A is :
(A) P (White) (B) P (Red) (C) P
2
O
3
(D) (COOH)
2
34. With increase in temperature following heating, acid (D) produces the following products in which correct sequence?
(A) Pyro acid, meta acid, anhydride (B) Meta acid, Pyro acid, anhydride
(C) Meta acid, anhydride, pyro acid (D) Pyro acid, anhydride, meta acid
Paragraph for Question Nos. 35 to 36
In SF
6
, sulphur is octahedrally hybridized (sp
3
d
2
). Hence , it is still having some vacant 3d-orbitals to accommodate
the nucleophilic attack through the sp
3
d
3
(pentagonal bipyramid) hybridization. But the size of sulphur is too small
to tolerate the seven co-ordination number.
35. Which of the following product is formed when BeCl
2
hydrolysed in alkaline medium ?
(A) Be(OH)
2
(B) % &
2
4
) OH ( Be (C) % &
n 2
) OH ( Be (D) None of these
36. The product of hydrolysis of SF
4
and TeF
6
are ______ and ______ respectively.
(A) H
2
SO
3
and H
2
TeO
4
(B) H
2
SO
4
and H
2
TeO
4
(C) H
2
SO
3
and Te(OH)
6
(D) H
2
SO
4
and Te(OH)
6
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Paragraph for Question Nos. 37 to 38
The Ellingham diagram for zinc, magnesium and carbon converting into corresponding oxides is shown below.
37. At what temperature, zinc and carbon have equal affinity for oxygen ?
(A) 1000C (B) 1500C (C) 500C (D) 1200C
38. At this temperature #G of the reaction is : ZnO + C !" ! Zn + CO
(A) ve (B) +ve (C) zero (D) nothing can be predicted
Paragraph for Question Nos. 39 to 41
The mineral colemanite is fused with sodium carbonate, compound (Z) is obtained along with white ppt. When (Z)
reacts with dil. H
2
SO
4
gives a compound (A) which on strong heating gives an oxide (C). (C) on reduction with Mg
produced (D) and non metal (X). Treatment of chlorine on a mixture of (C) and carbon at high temperature gives a
halide (E) which is fuming liquid (b. pt. 13C) along with a gas (F). (E) is a Lewis acid.
39. (Z) may be :
(A) H
3
BO
3
(B) BaCO
3
(C) borax (D) Na
3
BO
3
40. (A) and (C) may be :
(A) B
2
H
6
, B (B) B
2
H
6
, B
2
O
3
(C) H
3
BO
3
, B (D) H
3
BO
3
, B
2
O
3
41. (E) and (F) may be :
(A) BCl
3
, CoCl
2
(B) Cl
2
O, CCl
4
(C) BOCl, CO (D) None of these
42. Match the following :
Column I Column II
(A) Borax !" !
#
(p) BN
(B) B
2
H
6
+ H
2
O !" ! (q) B
2
H
6
(C) B
2
H
6
+ NH
3
(excess) !" !
#
(r) H
3
BO
3
(D) BCl
3
+ LiAlH
4
!" ! (s) NaBO
2
+ B
2
O
3
43. Match the following :
Column (A) Column (B)
Reaction Product's character
(A) NaNO
3

C 500
!" !
#
(p) Diamagnetic.
(B) KOH + O
3
!" ! (q) Paramagnetic.
(C) Na + O
2
(excess) !" ! (Major) (r) Bond order 1
(D) K (dissolved in liquid NH
3
)
! ! ! ! ! " !
solution Blue
(s) Bond order 1.5
44. Match the compound with effect on heating.
Column I Column II
(A) NH
4
ClO
4
(p) Leaves no residue on heating
(B) (NH
4
)
2
CO
3
(q) Reaction occurring is a redox reaction.
(C) (NH
4
)
2
Cr
2
O
7
(r) Produces N
2
on heating.
(D) Mg (NH
4
)PO
4
(s) Produces NH
3
on heating.
45. Column I Column II
(A) Chalcopyrites (p) Selfreduction
(B) Galena (q) Sulphur containing ore
(C) Argentite (r) Carbon reduction
(D) Malachite (s) Leaching followed by displacement method.