Chapter 1

Fundamental Concepts in Chemistry

Q. 1. The soul of chemistry is its dealing with
a. Internal structural changes in matter
b. Composition of matter
c. Properties of matter
d. Composition and properties of matter
(d)
Q. 2. ll of the following statements are incorrect for 2! mol of hydrogen pero"ide e"cept
a. it has 2! mol of hydrogen atoms
b. it has #! mol of o"ygen atoms
c. it has $! mol of atoms
d. #! mol of hydrogen atoms
(c)
Q. #. If proton number of two atoms is same then it can be concluded that
a. they are isotopes
b. compounds of both with CI
2
will be similar in reacti%ity towards other compounds
c. both ha%e same colors
d. both ha%e same melting points
(b)
Q. &. chemist poured lemon 'uice on soil( the idea that he may ha%e in his mind is that
a. there may be a possibility of a chemical reaction
b. lemon 'uice is dangerous to health
c. lemon 'uice is dangerous to health
d. water should be preferred o%er lemon 'uice for drin)ing
(a)
Q. *. +r. ,han has disco%ered two isotopes of an element with atomic number 11-. The relati%e
abundance of isotopes
11-
.ue
#!!
and
11-
.ue
#!*
is /!0 and #!0 respecti%ely. The a%erage
atomic weight of .ue is
a. #!1.* a.m.u
b. #!2.* a.m.u
c. #!#.* a.m.u
d. #!&.* a.m.u
(a)
Q. 1. 2hich of the following is not related to a.m.u
a. gram
b. )ilogram
c. microgram
d. gram3lit
(d)
Q. /. The number of significant figures in !.!!2!! is
a. two
b. three
c. fi%e
d. one
(b)
Q. $. ll of the following statements are incorrect e"cept
a. precision and accuracy should go side by side in a scientific wor)
b. scientific wor) must be precise( accuracy is not essential
c. scientific wor) must be accurate( precision is not essential
d. 4calculations must be made before any e"periment
(a)
Q. -. 5mpirical formula and formula unit of an ionic compound
a. are always similar
b. are always different
c. may be similar or different
d. ionic compounds don6t6 ha%e any empirical formula
(c)
Q. 1!. Copper (II) o"ide is mi"ed with organic compound during combustion analysis. The purpose
is
a. to carry out complete combustion
b. to reduce the economy of the process
c. to reduce the time for completion of the reaction
d. all of the abo%e
(a)
Q. 11. 7ismar) brown is a dye. Its molar mass is 22$.# g3mol. 2hen the dye was analy8ed by a
scientist( it was found that it contains #!.1$0 nitrogen. 9ow many nitrogen atoms are there
in each 7ismar) brown molecule:
a. 1
b. *
c. &
d. #
(b)
Q.12. The mass of 2 mole of sodium hydro"ide will be
a. 2 g
b. 2! g
c. &! g
d. $! g
(d)
Q. 1#. ;< compound is always consists of the same elements combined in the same fi"ed ratio<.
The statement is
a. a hypothesis
b. a fact
c. a law
d. an obser%ation
(c)
Q. 1&. Compound ha%ing highest boiling point among the following is
a. 9=
(I)
b. 9CI
(I)
c. 97>
(I)
d. 9I
(I)
(d)
Q. 1*. Islamian genius in%estigated that the amount of heat re?uired to raise the temperature of 11
gram of water form #!
o
C to #1
o
C is
a. one calorie
b. little bit greater than on calorie
c. little bit less than one calorie
d. ne%er e?ual to one calorie
(c)
Q. 11. n atom is
a. smallest indi%isible particle in an element
b. smallest particle of an element which can undergo a chemical reaction
c. building bloc) of an element
d. always smaller than molecule
(b)
Q. 1/. 1! moles of 9
2
@ contains
a. 1!! moles of bonds
b. 1!! moles of electrons
c. #! atoms
d. 2* moles of hydrogen bonds
(b)
Q. 1$. The %olume of one )ilogram of water at &
o
C is e?ual to one litre. The temperature of water
is )ept at &
o
C because water
a. has no dissol%ed gasses at this temperature
b. has ma"imum density at this temperature
c. polarity of water molecule is least at this temperature
d. dipole moment has ma"imum %alue at this temperature
(b)
Q. 1-. compound contains two elements A and B percentage of A is 2!0 (t.wt C &!) and that
of B is $!0 (t.wt C$!). The empirical formula of the compound is
a. AB
2
b. A
2
B
c. A
#
B
d. AB
()
Q. 2!. piece of paper is burnt in air( the gas produced is passed through distilled water. The P9
of water solution will be
a. 1
b. /
c. 2.1
d. 1.$
(d)
Q. 21. 2hich of the following is a substance:
a. sea water
b. brass
c. tape water
d. graphite
(d)
Q. 22. =ree8ing point of a substance is a temperature at which a li?uid substance is con%erted to
solid( it is
a. always lower than its melting point
b. usually a little lower than its melting point
c. always higher than its melting point
d. e"actly the same as its melting point
(d)
Q. 2#. Dumber of co%alent bonds in 1! mol of carbon tetrachloride is
a. 2.& " 1!
2*
b. &!
c. & " 1!
2&
d. 1.& " 1!
21
(a)
Q. 2&. student subtracted !.!!!** from 1!.2#&*1/$ and reported the result as 1!.2#&!1. 7ut
his friend told him that the result was wrong. 2hat is the correct result:

a. 1!.2#&!1/
b. 1!.2#&!1/$
c. 1!.2#&
d. 1!.2#
(d)
Q. 2*. The following statement contained in a student6s laboratory report is a conclusion.
a. a gas is liberated
b. colour of the gas is greenish yellow
c. o"ide of the gas is strongly acidic
d. the gas is chlorine
(d)
Q. 21. If 1!g each of uranium and hydrogen are con%erted into energy according to e?uation 5 C
mc
2
a. energy obtained from uranium will be too much greater than that of hydrogen
b. energy obtained from hydrogen will be a little bit less than that of uranium
c. energy obtained from hydrogen and uranium will always be e"actly e?ual
d. diamond
(c)
Q. 2/. student analy8ed a sample of sea water and found that it contained 2.#g of DaCi( !.!!*g
of EgFo
&
( !.2#&g of CaCI
2
and 1!.12g of 9
2
@. Total mass of the sample is
a. 12.1*-
b. 12.1*
c. 12./!
d. 1*./
(d)
Q. 2$. *!.!! mG sample of a cough mi"ture prepared by a pharmacist was found to ha%e a
mass of &1.!g. what is the density (in g3mG) of this mi"ture. Ftated to the correct number of
significant figures:
a. !.-2
b. !.-2!
c. !.-2!!
d. 1.!$/
(b)
Q. 2-. @8one (@
#
) filters the cosmic rays of sunlight. 9ow many o"ygen atoms are there in !.2
mole of o8one (@
#
( molar mass &$.! g3mol):
a. 1.!2 " 1!
22
b. 1.!2 " 1!
2#
c. #.11 " 1!
2#
d. 1 " 1!
2#
(c)
Q. #!. @n heating( the hydrated salt CaF@
&
( "9
2
@ loses its water of crystalli8ation. In an
e"periment it was found that when !.2 mol of the hydrated salt was heated !.1! mol of
water was lost. 2hat is the molecular formula of the hydrated compound:
a. CaF@
&
b. CaF@
#
. H 9
2
@
c. CaF@
&
.9
2
@
d. CaF@
&
.29
2
@
(b)
Q. #1. Iirconium chloride reacts with magnesium to produce Iirconium. The process is called
,noll process.
IrCI& 4 2Eg Ir 4 2EgCI
2
9ow many moles Ir would be produced if !.2 mol of Eg metal is used in the reaction:
a. !.1
b. !.!1
c. !.2!
d. !.!*
(a)
Q. #2. Tobacco contains a poisonous al)aloid called Dicotine. The molecular formula of nicotine is
C
1!
9
1&
D
2
(molar mass C 112.2#g). The mass percentage of nitrogen in nicotine( is:
a. &.#20
b. $.2#0
c. 12.&0
d. 1/.#0
(d)
Q. ##. sample of an ionic compound contains 2.$2 g Da( &.#* g CI( and /.$# g @. The empirical
formula of this compound isJ
a. DaCI@
2
b. DaCI@
#
c. DaCI@
d. DaCI@
&
(d)
CHAPTER 2
GASES
Q. 1. Professor Qawwi told his students that air is a mi"ture becauseJ suddenly a student raised
his hand and said
a. it is colourless
b. o"ygen can be remo%ed from it
c. its composition is different at different altitudes
d. it has different properties from its constituents
(c)
Q. 2. Imagine +r. ,han is sitting in a room. The room is closed from all sides( no entry( no e"it of
any gas. If the room e"pands suddenly then
a. he will be frightened
b. his blood pressure will decrease
c. he will feel cool
d. he will feel warmth
(c)
Q. #. which of the following elements will ha%e strongest Kan +er 2aal force of attraction
between its molecules
a. hydrogen
b. o"ygen
c. chlorine
d. nitrogen
(c)
Q. &. The bea)er shown in the figure contains slurry of ice and water( the three thermometers
=ahrenheit( ,el%in and Centigrade placed in it. The thermometers are represented by ( 7
and C respecti%ely. The lowest reading will be on thermometer.
a.
b. 7
c. C
d. 7oth and C
(c)
Q. *. 2hich thermometer will ha%e its reading 2/# degrees greater than that of thermometer C:
a.
b. 7
c. C has greater reading than all other thermometer
d. 7 has 2/# degrees greater reading than
(b)
Q. 1. The temperature recorded by ,el%in scale is
a. !,
b. 2/#,
c. #/#,
d. bsolute scale is unable to record this temperature
(b)
Q. /. If three birds called @
2
( CI
2
and 9
2
were flying in the garden of Islamia College Peshawar
then(
I. =astest birds are @
2
and CI
2
II. Flowest bird is CI
2
III. 7ird called @
2
is in the middle.
a. I only
b. II and III only
c. I and III only
d. III only
(b)
Q. $. @ne liter of an un)nown gas weighs 1.2* grams at F.T.P( one possible formula for the gas
is
a. C@
2
b. C@
c. @
2
d. F@
2
(b)
Q. -. If pressure on a gas is increased from 2 atm to & atm than its %olume will decrease from
a. 1G to &G
b. $G to 2G
c. #G to 1G
d. &G to 2G
(d)
Q. 1!. n un)nown gas has a density of 2.&* g3G at 1.* atmospheric pressure and 2*
o
C. The gas
is
a. ,r
b. CI
2
c. F@
2
d. r
(d)
Q. 11. This is a )nown fact that the molar %olumes of different gases at F.T.P are
a. little bit greater than the molar %olumes of li?uids
b. little bit less than the molar %olumes of solids
c. about the same as the molar %olumes of li?uids
d. much larger than the molar %olumes of li?uids and solids
(d)
Q. 12. The beha%ior of a gas is nonLideal at
a. lo2w temperature and low pressure
b. high temperature and high pressure
c. high temperature and low pressure
d. low temperature and high pressure
(d)
Q. 1#. mmonium Perchlorate is used as solid fuel in roc)ets. +uring the process it decomposes
according to the reaction gi%en below
&D9&CI@&(g) 2CI2(g) 4$92@(g) 42D2@(g) 4#@2(g)
The total %olume of all the gases produced at F.T.P by the decomposition of $ moles of
mmonium Perchlorate will be
a. #! G
b. 1/2 G
c. 1/-.! G
d. 1! G
(b)
Q. 1&. Compressed natural gas (CDM) contains mainly methane C9
&
. Eethane gas burns in air
according to the following reaction.
C9&(g) 4 2@2(g) C@2(g) 4 292@(g)
If $ g of methane is burnt( what %olume of C@
2
measured at F.T.P. will be produced:
a. !.* G
b. 22 G
c. 22.& G
d. 11.2 G
(d)
Q. 1*. )id has a helium filled balloon which deflates at the rate of 1.!! liter3day by 9e gas
lea)ing through the relati%ely porous s)in of the balloon. 9ow fast would carbon dio"ide
(C@
2
) lea) from a balloon made of the same material:
a. #.! G3day
b. !.# G3day
c. 1.## G3day
d. #.## G3day
(b)
Q. 11. ll of the following statements are false e"cept
a. gas molecules do not attract each other at %ery low temperature
b. all of the gases cannot be li?uefied
c. increase in pressure will not decrease the intermolecular distance in a gas
d. actual %olume of a gas is not negligible at %ery high pressure
(d)
Q. 1/. t the same temperature and pressure helium is more ideal than hydrogen due to
a. greater molar mass
b. less molar mass
c. greater molecular si8e
d. less molecular si8e
(d)
Q. 1$. container with a porous wall has a mi"ture of 9
2
( 9e( D
2
and @
2
. 2hich of these gases will
ta)e ma"imum time in getting out of the container:
a. 9
2
b. 9e
c. D
2
d. @
2
(d)
Q. 1-. The %alue of
nT
PV
for an un)nown gas is e?ual to
a. !.!$2 G.atm.mol
L1
.,
b. !.!$2 G.atm.mol
L1
.,
L1
c. !.$2 G.atm.mol.,
L1
d. !.$2 G.atm.mol.,
(b)
Q. 2!. If the temperature of the atmosphere is #!
o
C then which of the following will ha%e highest
a%erage speed
a. @
2
b. 9
2
c. De
d. D
2
(b)
CHAPTER 3
L!"#S A$# S%L#S
Q.1. I heard Islamian genius saying that glass must be a super cooled li?uid. The reason that he
might ha%e in his mind is that glass has
a. definite %olume
b. definite shape
c. crystalline structure
d. no crystalline structure
(d)
Q. 2. Fome substances are good conductor of electricity in both the solid and li?uid states. These
substances are generally
a. ionic substances
b. metallic substances
c. molecular solids
d. co%alent networ) solids
(b)
Q. #. ir can be distilled fractionally because the constituents of the air
a. can be li?uefied
b. ha%e different boiling points
c. are gases at room temperature
d. ha%e different densities
(b)
Q. &. There are three different substances( rgon( 9ydrochloric acid and 9ydroiodic acid. The
correct se?uence in which the boiling point increases is
a. r N 9CI N 9I
b. 9I O 9CI O r
c. 9CI N 9I N r
d. 9I O r O 9CI
(a)
Q. *. student put two eggs and 7 in 9CI solution. fter * minutes he too) them out for
weighing but egg dropped in water accidentally. The student was able to ta)e it out after #!
minutes. 9e weighed it. Its weight was &!.## grams. 2eight of egg ;7< was also &!.##
grams. Islamian genius told him that if both eggs ha%e been dropped in water( the weight of
egg ;7< would ha%e been
a. greater than that of egg ;<
b. less than that of egg ;<
c. e?ual to that of egg ;<
d. unaffected instead
(a)
Q. 1. ,eeping in mind different factors which affect the melting point of a substance( the
compound ha%ing highest melting point among the following is
a. DaCI
b. >bCI
c. GiCI
d. CsCI
(a)
Q. /. Islamian genius told his follows that in a crystal the atoms are located at the position of
a. 8ero potential energy
b. infinite potential energy
c. ma"imum potential energy
d. minimum potential energy
()
Q. $. ,eeping in mind the concept of charge density( compound ha%ing highest lattice energy is
a. ,CI
b. Eg@
c. Gi7r
d. Da=
(b)
Q. -. Eeniscus is the shape of the surface of a li?uid in a cylindrical container. It may be
conca%e( con%e" or plane. =or molten metals
a. meniscus is conca%e
b. meniscus is con%e"
c. meniscus is plane
d. meniscus may be conca%e or con%e" depending on the nature of the metal
(b)
Q. 1!. ll of the following substances are crystalline e"cept
a. Ice
b. Carbon (diamond)
c. Fucrose
d. Plastic
(d)
Q. 11. ll of the following ha%e clea%age planes e"cept
a. ionic crystals
b. co%alent crystals
c. molecular crystals
d. metallic crystals
(d)
Q. 12. Coordination number of Da
4
in DaCI is
a. 1
b. &
c. 2
d. 1
(d)
Q. 1#. =or a crystal system a b c and the e"ample for this crystal system is
a. CuF@
&
. *9
2
@
b. Da
2
7
&
@/. 1!9
2
@
c. InF@
&
. /9
2
@
d. 7aF@
&
. &9
2
@
(a)
Q. 1&. student said I will preser%e my father dead body in a time capsule for 1!!! years.
Islamian genius told him that the atmosphere of the capsule must contain
a. @
2
b. F@
2
c. C@
2
d. r
(d)
Q. 1*. ll of the following ha%e crystals e"cept
a. diamond
b. DaCI
c. ,7r
d. CdF
(d)
Q. 11. ,erosene is li?uid at room temperature due to
a. hydrogen bonding
b. organic nature
c. dipoleLdipole forces
d. molecular si8e
(d)
Q. 1/. ll of the following are networ) solids e"cept
a. Fi@
2
b. Mraphite
c. F
$
d. +iamond
(c)
Q. 1$. 9oney contain glucose and fructose along with some other ingredients( it has greater
%iscosity due to
a. hydrogen bonding
b. irregular shape of the molecules
c. irregular shape of the molecules and strong intermolecular forces
d. greater molecular si8e (c)
Q. 1-. 7oiling point of phosphine (P9
#
) is L$/.$
o
C while that of silane (Fi9&) is
L111
o
C. Phosphine has greater boiling point because
a. dipole moment of P9
#
is greater than that of Fi9
&
b. P9
#
has greater molecular si8e
c. Eolecular weight of Fi9
&
is less than that of P9
#
d. ctually the boiling of Fi9
&
is greater than that of P9
#
(a)
Q. 2!. >ate of e%aporation of petrol is greater than that of water at room temperature because
a. petrol molecules do not ha%e any hydrogen bond
b. petrol is an organic compound
c. water molecules ha%e small si8e
d. petrol molecules ha%e greater si8e
(a)
Q. 21. Fubstance ha%ing highest boiling point among the following is
a. 9=
b. 9CI
c. 7r
2
d. 97r
(c)
Q. 22. 7oiling points of different substances are gi%en below
C9
&
C L 111
o
C
C
2
9
1
C L$-
o
C
CI
2
C L#&.1
o
C
=
2
C L1$$
o
C
The data shows that %apour pressure of
a. CI
2
O C
2
9
1
O C9
&
O =
2
b. CI
2
O =
2
O C9
&
O C
2
9
1
c. C
2
9
1
O C9
&
O =
2
O CI
2
d. =
2
O C9
&
O C
2
9
1
O CI
2
(d)
Q. 2#. 2hich of the following statements is correct for the statement
;Kapour pressure of water at !
o
C is * mm9g<
a. boiling point of water will be !
o
C at * mm9g
b. boiling point of water will be !
o
C
c. if e"ternal pressure is * mm9g then water will boil at !
o
C
d. boiling point of water is 1!!
o
C at /1! mm9g pressure
(c)
Q. 2&. 2hat is the typical range of the hydrogen bond
a. * P 2* )Q per mole of bonds
b. * P 2* )Q per molecule
c. *!! )Q per mole of bonds
d. 1 P 2 )Q per mole of bonds
(a)
Q. 2*. 9ydrogen bond is unimportant in
a. +D structure
b. The li?uid properties of water
c. Gi?uid 9=
d. Gi?uid C9
&
(d)
Q. 21. ll of the following acids ha%e hydrogen bond in li?uid state e"cept
a. sulfuric acid
b. nitric acid
c. hydrofluoric acid
d. hydrochloric acid
(d)
Q. 2/. 2hich of the following statements is incorrect:
a. dispersion force is the wea)est type of intermolecular interactions
b. the strong intermolecular attractions in 9
2
@ result from hydrogen bonding
c. boiling point of 9
2
F is less than 9
2
@
d. boiling point of nonLpolar substances tends to decrease with increasing molecular
weight
(d)
Q. 2$. white substance melts with some decomposition at /#!
o
C. s a solid( it is non conductor
of electricity but it dissol%es in water to from a conducting solution. The white substance is
a. a co%alent networ) solid
b. an ionic solid
c. a molecular solid
d. a metallic solid
(b)
Q. 2-. ,eeping in mind different factors which affect the boiling point of a substance( element
ha%ing highest boiling among the following is
a. 9e
b. =2
c. De
d. 7r
2
(d)
Q. #!. The increasing %apor pressure caused by heating a li?uid is due to
a. increase intermolecular interactions
b. increasing potential energy of molecules
c. increasing )inetic energy of molecules
d. decreasing surface tension
(c)
Q. #1. Co%alent networ) crystals ha%e
a. higher melting point then molecular crystals
b. lower melting point then molecular crystals
c. discrete molecules lin)ed by Kan der waals forces
d. hydrogen bonding
(a)
Q. #2. ,eeping in mind different factors which affect the boiling point of a li?uid( element ha%ing
lowest boiling point among the following is
a. =
2
b. CI
2
c. 7r
2
d. I
2
(a)
Q. ##. chemist was able to measure the %alue of lattice energy of ,CI to be 1-! )Q3mol. =rom
this e"periment he concluded that
a. lattice energy of ,7r is 1#! )Q3mol and that of ,I is 11* )Q3mol
b. lattice energy of ,7r is 11* )Q3mol and that of ,I is 1#! )Q3mol
c. lattice energy of ,7r is /1* )Q3mol and that of ,I is /#! )Q3mol
d. lattice energy of ,7r is /#! )Q3mol and that of ,I is /1* )Q3mol
(b)
CHAPTER &
AT%'C STR"CT"RE
Q.1. Color of the glow produced in the discharge tube
a. depends on the pressure in the discharge tube
b. depends on the metal used as cathode
c. depends on the gas used in the discharge tube
d. does not depend on the nature of the gas used in the discharge tube
(c)
Q. 2. +r. ,han told his students that if charge on electrons in a chamber is #.*! " 1!
11
coulomb
than mass of electrons must be
a. -.1 " 1!
L#1
)g
b. $ )g
c. & )g
d. 2 )g
(d)
Q. #. e3m ratio of the canal rays is less than that of cathode rays. The reason is
a. greater mass of canal ray particles
b. greater charge of the canal ray particles
c. greater mass and charge of the canal ray particles
d. actually e3m ratio of canal rays is greater than that of the cathode rays
(a)
Q. &. Duclear radiation is emitted by those elements whose
a. molecules are stable
b. molecules are unstable
c. nuclei are stable
d. nuclei are unstable
(d)
Q. *. Lrays are good ioni8ers of gases because they
a. ha%e greater mass
b. ha%e positi%e charge
c. ha%e greater mass and positi%e charge
d. are helium nuclei
(c)
Q. 1. Consider the following reaction
7e 4 9e C 4 n
This reaction is
a. a chemical reaction
b. a nuclear reaction
c. an e"ample of artificial radioacti%ity
d. an e"othermic reaction
(c)
Q. /. >oentgen disco%ered ALrays and Eosley found that the fre?uency of the ALrays emitted
from anode increases with the
a. increase in the mass number of the metal used as anode
b. decrease in the mass number of the metal used as anode
c. decrease in the proton number of the metal used as anode
d. increase in the proton number of the metal used as anode
(d)
Q. $. >adiation emitted by e"ited atoms is
a. in the form of continuous wa%es
b. in the form of ?uanta
c. nuclear radiations
d. ultra%iolet radiation
(b)
Q. -. If the electron of hydrogen atom 'umps of ;E< shell then the radius of this e"cited hydrogen
atom will be
a. $.&1&
o
b. &./11
o
c. 2.111
o
d. !.*2-
o
(b)
Q. 1!. If a particle of mass !.1gram mo%es with a %elocity of 1!(!!! m3s then the wa%elength of
the wa%e associated with this particle is
a. 1.121 " 1!
L#&
m
b. 2.1&* " 1!
L#-
m
c. #.#1# " 1!
L21
m
d. 1.#2* " 1!
L1$
m
(a)
9
4
4
2
12
6
1
8
Q. 11. Fecond ioni8ation energy
a. is always less than first ioni8ation energy
b. is always greater than first ioni8ation energy
c. is e?ual to the first ioni8ation energy
d. may be greater or less than the first ioni8ation energy depending on the nature of the
element
(b)
Q. 12. ;Ioni8ation energies of the elements of the *
th
group are greater than those of 1
th
group<. It is
because
a. *
th
group elements ha%e less electronegati%ity
b. 1
th
group of elements ha%e greater shielding effect
c. *
th
group element ha%e greater shielding effect
d. *
th
group elements ha%e half filled atomic orbitals
(d)
Q. 1#. sodium lamp emits yellow light with a wa%elength of *$- nm. 2hat is the energy of a
single photon in this light:

a. #.#/ " 1!
L1-
Qoules
b. 1.12 " 1!
L2*
Qoules
c. 1.1/ " 1!
L##
Qoules
d. *.!- " 1!
1*
Qoules
(a)
Q. 1&. The energy associated with the transition of an electron from the nC1 state to the nC# state
of 9 atoms isJ
a. 41./& " 1!
L1/
Qoules
b. 41.-& " 1!
L1$
Qoules
c. 41.-& " 1!
L1$
Qoules
d. L1./& " 1!
L1/
Qoules
(b)
Q. 1*. ll of the following are electromagnetic radiations e"cept
a. red light
b. sound wa%es
c. "Lrays
d. photon
(b)
Q. 11. This shape of a 2s orbital resemblesJ
a. a hoc)ey puc)
b. an (merican) football
c. an ellipse
d. a sphere
(d)
Q. 1/. 2hich orbital of the following has a principal ?uantum number of # and an angular
momentum ?uantum number of 2/
a. #s
b. #d
c. &f
d. #f (b)
Q. 1$. 2hich of the following has the highest energy:
a. gamma rays
b. ALrays
c. .ltraL%iolet radiation
d. Rradio wa%es
(a)
Q. 1-. ll of the following elements are correct for atomic orbitals e"cept
a. pLsub energy le%el has # orbitals
b. sLorbital has spherical shape
c. energy of &s is less than that of &d
d. ll d orbitals ha%e & lobes
(d)
Q. 2!. Karious %alues of the ?uantum numbers (n( 3( m( m
s
) are listed below. 2hich is a possible
set of %alues for one of the d electrons in an iron atom in its ground state:
a. (1( 1( !( H)
b. (&( !( 1( H)
c. (&( 1( !( L132)
d. (#( 2( 1( L132)
(d)
Q. 21. 9ow many orbitals are allowed for principal ?uantum number (n) of #:
a. -
b. $
c. 1
d. &
(a)
Q. 22. 2hich of the following orbitals are degenerate in a multielectron atom:
a. #d orbitals
b. #s( #p( #d orbitals
c. 1s( 2s orbitals
d. 2d orbitals
(a)
Q. 2#. The ?uantum number that specifies the way the orbital is oriented in space isJ
a. the electron spin ?uantum number
b. the magnetic ?uantum number
c. the angular momentum ?uantum number
d. the principal ?uantum number
(b)
Q. 2&. 2hich of the following has the largest wa%elength:
a. %isible light
b. "Lrays
c. infrared light
d. ultra%iolet radiation
(c)
Q. 2*. Felect the arrangement of electromagnetic radiation which starts with the lowest energy
and increases to greatest energy.
a. radio( %isible( infrared( %isible( ultra%iolet
b. microwa%e( infrared( %isible( ultra%iolet
c. %isible( ultra%iolet( infrared( gamma rays
d. ALradiation( %isible( infrared( microwa%e
(b)
Q. 21. radio station broadcasts music at --.1 E98. The wa%elength of these wa%es is
a. 1.$$ " 1!
L2
m
b. !.##! m
c. #.!# m
d. *.## " 1!
2
m
(c)
Q. 2/. Mreen light has a wa%elength of *2!!. Calculate the energy of one photon of green light.
a. #.& " 1!
L&!
Q
b. #.& " 1!
L#!
Q
c. #.$ " 1!
L21
Q
d. #.$ " 1!
L1-
Q (d)
Q. 2$. The si8e of an atomic orbital is associated with
a. principal ?uantum number (n)
b. angular momentum ?uantum number (I)
c. magnetic ?uantum number (m
I
)
d. spin ?uantum number (m
s
)
(a)
Q. 2-. 2hich of the following is a correct set of ?uantum numbers for an electron in a *f orbital:
a. n C *( I C #( m
I
C 41
b. n C *( I C 2( m
I
C 4#
c. n C &( I C #( m
I
C !
d. n C &( I C 2( m
I
C 41
(a)
Q. #!. In the ?uantum mechanical treatment of the hydrogen atom( which one of the following
combinations of ?uantum numbers is not allowd:
a. #( 1( L1
b. #( 2( 2
c. #( 2( L1
d. #( #( 2
(d)
Q. #1. ;5ach electron in an atom must ha%e its own uni?ue set of ?uantum numbers< is a
statement of
a. ufbau principle
b. Pauli e"clusion principle
c. 9und6s rule
d. Periodic law
(b)
Q. #2. The effecti%e nuclear charge for an atom is less than the actual nuclear charge due to
a. Fhielding
b. Penetration
c. Paramagnetism
d. 5lectronLpair repulsion
(a)
Q. ##. ;5lectrons added to atomic orbitals of the same energy will remain unpaired with parallel
spins until the subshell is more than halfLfilled< is a statement of
a. ufbau principle
b. Pauli e"clusion principle
c. 9und6s rule
d. Periodic law
(c)
Q. #&. ll of the following statements are correct for atomic structure and ?uantum numbers
e"cept
a. In a gi%en atom( the ma"imum number of electrons ha%ing principal ?uantum number n
C #( is 1$
b. The number of orbitals in a gi%en f subshell is /
c. =or nC&( the largest possible %alue of I is #
d. =or nC&( the largest possible %alue of m
I
is 2
(d)
Q. #*. Felect the correct electron configuration for Cu (IC2-)
a. SrT &s
2
#d
-
b. SrT&s
1
#d
1!
c. SrT&s
2
&p
1
#d
#
d. SrT&s
1
&d
-
(b)
Q. #1. rrange potassium( rubidium( calcium and barium in order of increasing atomic si8e.
a. , N Ca N >b N 7a
b. Ca N , N >b N 7a
c. Ca N , N 7a N >b
d. , N Ca N 7a N >b
(b)
Q. #/. 5lement ha%ing smallest atomic radius among the following is
a. Gi
b. De
c. >b
d. Fr
(b)
Q. #$. The arrangement of sodium( o"ygen( fluorine and strontium on the basis of increasing first
ioni8ation energy is
a. Da N Fr N @ N =
b. Fr N Da N @ N =
c. Fr N Da N = N @
d. Da N Fr N = N @
(b)
Q. #-. 5lements with UUUUU first ioni8ation energies and UUUUUUU electron affinities generally form
cations.
a. low( %ery negati%e
b. high( positi%e or slightly negati%e
c. low( positi%e or slightly negati%e
d. high( %ery negati%e
(c)
Q. &!. In a Eilli)an oilLdrop e"periment( the charges on se%eral different oil drops were as followsJ
L*.-2V L&.&&V L2.-1V L$.$$. The units are arbitrary. 2hat is the li)ely %alue of the electronic
charge in these arbitrary units:
a. L1.11
b. L1.&$
c. L2.22
d. L2.-1
(b)
CHAPTER (
CHE'CAL )%$#$G
Q. 1. 2hich of the following compounds has ma"imum ionic character:
a. DaCI
b. Cs=
c. ,7r
d. EgCI
2
(b)
Q. 2. 2hich of the following molecules or ions is nonplanar( i.e.( has at least one atom that is not
in the same plane as the others:
a. 79
#
b. D=
#
c. F@
#
d. C@
#
2L
(b)
Q.#. 2hich of the following best describes the shape and polarity of the carbon disulfide( CF
2
(
molecule:
a. bent and polar
b. linear and nonLpolar
c. pyramidal and polar
d. bent and nonLpolar
(b)
Q. &. 2hich of the following molecules has the smallest angle between ad'acent bonds:
a. C@
2
b. C9
&
c. 9
2
@
d. D9
#
(c)
Q.*. The shape of hydronium ion 9
#
@
4
isJ
a. planar
b. seeLsaw
c. trigonal planar
d. trigonal pyramidal
(d)
Q. 1. 2hich of the following pairs of atoms are least li)ely to form an ionic compound:
a. Di( @
b. Da( =
c. Cu( CI
d. Gi( Eg
(d)
Q. /. 2hich of the following pairs of atoms are most li)ely to form a co%alent compound:
a. Da( =
b. Cu( CI
c. C( @
d. Gi( =
(c)
Q. $. 2hich molecule has one pair of nonbonding electrons on the central atom:
a. PCI
#
b. C@
2
c. F@
#
d. 7=
#
(a)
Q. -. 2hich of the following will ha%e the largest dipole moment:
a. 9=
b. 9CI
c. 97r
d. =
2
(a)
Q. 1!. C@
2
is a nonpolar molecular (WC!) whereas F@
2
is polar (WC1.12+). This difference is due
to the fact thatJ
a. C@
2
has an e%en number of double bonds whereas F@
2
has an odd number of
double bonds
b. C and @ are in different groups whereas F and @ are in the same group
c. The CL@ bond is nonpolar while the FL@ bond is polar
d. C@
2
is linear whereas F@
2
is not linear
(d)
Q. 11. 2hat is the state of hybridi8ation of the carbon atoms in ethylene( C
2
9
2
:
a. sp
2
b. sp
c. sp
#
d. sp
#
d
2
(a)
Q. 12. The type(s) of bonding present in a sample of sodium nitrated( DaD@
#
( areJ
a. co%alent bonds only
b. ionic bonds only
c. co%alent and ionic bonds
d. ionic and metallic bonds
(c)
Q. 1#. The CCC double bond in ethane C
2
9
&
( is consist ofJ
a. two X bonds
b. co%alent bonds
c. two sigma bonds
d. one X bond 4 one sigma bond
(d)
Q. 1&. ll of the following statements are false e"cept
a. The number of E@6s in a molecule e?uals twice the number of constituent atomic
orbitals
b. s bonding E@6s become e?ually less stable
c. In E@6s( the number of bonding electrons e?uals the number of antibonding
electrons
d. 5ach bonding E@ can accommodate only one electron
(b)
Q. 1*. ll of the following statements are false e"cept
a. The E@6s in a molecule e?uals twice the number of constituent atomic orbitals.
b. s bonding E@6s become more stable( antibonding E@6s become e?ually less
stable.
c. In E@6s( the number of bonding electrons e?uals the number of antibonding
electrons.
d. 5ach bonding E@ can accommodate only one electron.
(b)
Q. 11. 2hat is the hybridi8ation of phosphorus in PCI
#
:
a. sp
2
b. sp
#
c. sp
d. sp
#
d
2
(b)
Q. 1/. nalysis of an un)nown substance showed that it has a high boiling point and is brittle. It is
an insulator as a solid but conducts electricity when melted. 2hich of the following
substances would ha%e those characteristics:
a. 9CI
b. I
c. ,7r
d. Fi=
&
(c)
Q. 1$. rrange the following bonds in order of increasing bond strength.
CL=( CL7r( CLI( CLCI
a. CL= N CLCI N CL7r N CLI
b. CLI N CL7r N CLCI N CL=
c. CL7r N CLI N CLCI N CL=
d. CLI N CL7r N CL= N CLCI
(b)
Q. 1-. 7ased on electronegati%ity trends in the periodic table( predict which of the following
compounds will ha%e the greatest 0 ionic character in its bonds.
a. 9
2
@
b. GiI
c. >b=
d. 9CI
(c)
Q. 2!. ccording to KF5P> theory( a molecule with the general formula A
#
will ha%e a UUUUU
molecular shape.
a. linear
b. bent
c. trigonal planar
d. tetrahedral
(c)
Q. 21. ccording to KF5P> theory( a molecule with the general formula A
#
5 will ha%e a UUUU
molecular shape.
a. bent
b. trigonal planar
c. trigonal pyramidal
d. tetrahedral
(c)
Q. 22. Predict the ideal bond angles around carbon in C
2
I
2
using the molecular shape gi%en by the
KF5P> theory.
a. -!
o
b. 1!-
o
c. 12!
o
d. 1$!
o
(d)
Q. 2#. Predict the actual bond angles in 7r=
#
using the KF5P> theory.
a. more than 12!
o
b. between 1!-
o
and 12!
o
c. between -!
o
and 1!-
o
d. less than -!
o
(d)
Q. 2&. 2hich of the following has no net dipole moment:
a. D
2
@
b. D=
#
c. 9
2
Fe
d. Te@
#
(d)
Q. 2*. molecule with the formula A
2
uses YYY. To form its bonds.
a. sp hybrid orbitals
b. sp
2
hybrid orbitals
c. sp
3
hybrid orbitals
d. sp
3
d hybrid orbitals
(a)
Q. 21. Kalence bond theory predicts that carbon will use LLLLLLLL hybrid orbitals in the carbonate
anion( C@
#
2L
a. sp
b. sp
2
c. sp
#
d. sp
#
d
(b)
Q. 2/. Kalence bond theory predicts that sulfur will use LLLLLLLL hybrid orbitals in sulfur dio"ide( F@
2
.
a. sp
b. sp
2
c. sp
#
d. sp
#
d

(b)
Q. 2$. 2hich one of the following statements about orbital hybridi8ation is incorrect:
a. The carbon atom is C@2 is sp hybridi8ed
b. The nitrogen atom in D9
#
is sp
#
hybridi8ed.
c. sp
2
hybrid orbitals are coplanar( and at 12!
o
to each other.
d. sp hybrid orbitals lie at 1$!
o
to each other.
(b)
Q. 2-. =or which one of the following molecules is the indicated type of hybridi8ation not
appropriate for the central atom:
a. 7eCI
2
sp
2
b. Fi9
&
sp
#
c. 7=
#
sp
2
d. C
2
9
2
sp
(a)
Q. #!. ccording to molecular orbital (E@) theory( the twel%e outermost electrons in the @2
molecule are distributed as followsJ
a. 12 in bonding E@F( @ in antibonding E@s.
b. 1! in bonding E@s( 2 in antibonding E@s.
c. - in bonding E@s( # in antibonding E@s.
d. $ in bonding E@s( & in antibonding E@s.
(d)
Q. #1. ccording to molecular orbital theory( what is the bond order in the @
2
4
ion:
a. *.*
b. *
c. &
d. 2.*
(d)
Q. #2. 2hich of the following statements relating to molecular orbital (E@) theory is incorrect:
a. bonding E@ is lower in energy than the two atomic orbitals from which it is formed.
b. Combination of two 2p orbitals may result in either Z E@s.
c. species with a bond order of 8ero will be stable
d. In a stable molecule ha%ing an e%en number of electrons( all electrons must be
paired.
(d)
Q. ##. @ne can safely assume that the #sL and spL orbitals will form molecular orbitals similar to
those formed when 2sL and spLorbitals interact. ccording to molecular orbital theory( what
will be the bond order for the CI
2
4
ion:
a. !.*
b. 1
c. 1.*
d. 2
(c)
CHAPTER *
ELECTRCS %F CHE'CAL REACT%$S
Q.1. ll of the following are state functions e"cept
a. P
b. K
c. ?
d. 9
(c)
Q. 2. Fuppose you ha%e a balloon of gi%en %olume( K1( containing a gas at temperature( T
1
.
2hen you place the balloon in a colder room at temperature( T
2
( the balloon6s temperature
starts to drop. 2hat are the signs of the system6s ?( w( and 5 for this process:
a. 4?( 4w( 4 5
b. L?( Lw( 4 5
c. 4?( Lw( L 5
d. P?( 4w( L 5
(d)
Q. #. The melting of ice at body temperature is an endothermic processJ
92@(s) 92@(I) [9C 41.!)Q 3 mol
Thus eating ice counteracts the e"othermic processes of metaboli8ing food. 9ow much ice
(in grams) would you ha%e to eat to counteract the energy gained by eating 2$.#g of
peanuts (1# )Q3g):
a. /$ g
b. 11! g
c. #/! g
d. 11!! g
(d)
Q. &. ll of the following statements are false e"cept
a. ? C 9 at constant TV ? C 5 at constant K
b. ? C 9 at constant KV ? C 5 at constant P
c. ? C 9 at constant PV ? C 5 at constant K
d. ? C 9 C 5 at constant P or at constant K
(c)
Q. *. 9
o
of which of the following reactions is e?ual to the standard enthalpy of formation of D9
#
:
a. #9
2(g)
4 D
2(g)
2D9
#(g)
b. 2D9
#(g)
#9
2(g)
4 D
2(g)
c.
2
3
9
2(g)
4
2
1
D
2(g)
D9
#(g)
d. D9
#(g)

2
3
9
2(g)
4
2
1
D
2(g)
(c)
Q. 1. Calculate the standards molar enthalpy of formation of C@2(g) in the reactionJ
C
(g)
4@
2(g)
C@
2(g)
Mi%en the following standard enthalpy changesJ
2C
(s)
4@
2(g)
2C@
(g)
( [9
o
C L221)Q
2C@(g) 4 @2(g) 2C@2(g)( [9o C L*11)Q
a. L#-#.* )Q
b. 4#-#.* )Q
c. 4/$/.! )Q
d. L/$/.! )Q
(a)
Q. /. ll of the following chemical reactions are endothermic e"cept
a. 9
2
@
(s)
9
2
@
(I)
b. 29
2
@
(g)
29
2(g)
4@
2(g)
c. 9
2
@
(g)
9
2
@
(I)
d. I
2
@
#(I)
4 2=e
(I)
2I
(s)
4 =e
2
@
#(s)
(c)
Q. $. ll of the followings are incorrect e"cept
a. 9%apri8aiton N 9sublimation N 9fusion N 9condensation
b. 9fusion N 9condensation N sublimation N 9%apori8ation
c. 9condensation N 9fusion N 9%apori8ation N 9sublimation
d. 9condensation N 9sublimation N 9fusion N 9%apori8ation
(c)
Q. -. n en%ironmental chemist got an idea that two serious pollutants (C@ and D@) of the
automobile e"haust can be con%erted to less harmful gases C@
2
and D
2
. The reaction is
C@
(g)
4 D@
(g)
C@
2(g)
4
2
1
D
2(g)(
[9
o
C :
The enthalpy of this reaction as calculated from the following date is
C@(g) 4
2
1
@
2(g)
C@
2(g)(
[9
o
C L2$#)Q 3 mol
C@(g) 4 @
2(g)
2D@
2(g)(
[9
o
C 1$!.1)Q 3 mol
a. L1!2.& )Q
b. L#22.1 )Q
c. L#/#.# )Q
d. L&!!.! )Q
(c)
Q. 1!. chemist heated a balloon by supplying 1!! Q of heat. The balloon e"pands doing 2!! Q of
wor) against the atmospheric pressure. The change in internal energy of
a. L$!! Q
b. L&!! Q
c. @ Q
d. 4&!! Q
(d)
Q. 11. Fpontaneous reactions are those which
a. continue to occur once started
b. re?uire acti%ation energy
c. are endothermic
d. are e"othermic
(a)
Q. 12. ll of the following processes are spontaneous e"cept
a. reaction of 9
2
with @2 to form 9
2
@
b. combustion of natural gas
c. neutrali8ation of 9CI by Da@9
d. synthesis of glucose by plants
(d)
Q. 1#. 5%ery one )nows about the importance of water. Though it is abundant in nature( yet it can
be produced in laboratory by the following reaction
29
2
4 @
2
29
2
@
If 9
f
is the heat of formation of 9
2
@ and 9
r
is the heat of this reaction, then
a. H
f
= H
r
b. H
r
=
2
r
H
c. H
r
=
2
r
H
d. H
f
= 2H
r
(b)
Q. 14. The followin table !ro"ide different t#!es of s#ste$ and their e%a$!les b&t in irre&lar $anner.
'#ste$ (%a$!le
). *!en a. water in cor+ fitted titration flas+
)). ,losed b. !ieon
))). isolated c. ice in ther$os bottle
-hich of the followin is a best $atch of both col&$ns.
a. (), a), ()), b), ())), c)
b. (), b), ()), a), ())), c)
c. (), c), ()), a), ())), b)
d. (), b), ()), c), ())), a)
(b)
Q. 1/. '&bli$ation, "a!ori0ation, $eltin and !hotos#nthesis all are e%a$!les of
a. che$ical !rocesses
b. !h#sical !rocesses
c. bioche$ical !rocesses
d. endother$ic !rocesses
(d)
Q. 16. 1 $i%t&re of ice and water contains 62 of ice and 62 of water. )f 623 of heat ener# is re$o"ed
fro$ this $i%t&re then so$e of the
a. water will "a!ori0e
b. ice will s&bli$e
c. ice will $elt
d. water will free0e
(d)
Q. 14. 5ieces of fo&r different $etals are !resent on a table. These $etals are 6a, 1), - and Ti. Their
$eltin !oints are 98, 662, 3412 and 1662
o
, res!ecti"el#. 7etal ha"in $a%i$&$ enthal!# of
f&sion is
a. Ti
b. 1)
c. -
d. 6a
(c)
Q. 18. )f "ol&$e of a s#ste$ is +e!t constant and heat is s&!!lied to the s#ste$ then
a. internal ener# of the s#ste$ increases and no wor+ is done on the s&rro&ndin
b. internal ener# of the s#ste$ increases and wor+ is done on the s&rro&ndin
c. no chane in internal ener# occ&rs
d. no wor+ is done on the s&rro&ndin
(a)
Q. 19. 7eltin of ice at roo$ te$!erat&re is
a. s!ontaneo&s e%other$ic !rocess
b. s!ontaneo&s endother$ic !rocess
c. non8s!ontaneo&s e%other$ic !rocess
d. non8s!ontaneo&s endother$ic !rocess
(b)
CHAPTER 7
CHEMICAL EQUILIBRIUM
Q. 1. 1t 1222 ,, the e9&ilibri&$ constant for the reaction of carbon $ono%ide and o%#en to !rod&ce
carbon dio%ide is "er# lare (:
c
= 1.2 % 12
22
). -hen the reaction is at e9&ilibri&$ the;
a. concentration of carbon dio%ide will be $&ch larer than one or both reactants
b. concentration of carbon dio%ide will be $&ch s$aller than concentrations of both reactants
c. concentration of carbon $ono%ide will be $&ch larer than the concentration of carbon dio%ide
d. concentrations of both reactants $&st be $&ch s$aller than the concentration of carbon dio%ide
(a)
Q. 2. 1 c#linder contains a &n+nown as <=>. -hen the c#linder is heated a reddish brown color
de"elo!s. )t $eans that the as !resent in the c#linder was
a. 6*
2
b. 6
2
*
c. 6
2
*
/
d. 6
2
*
4
(d)
Q. 3. 1 bea+er contains a sat&rated sol&tion of !otassi&$ 5erchlorate. -hen !otassi&$ chloride (:,)) is
added to this sol&tion, so$e of the !otassi&$ 5erchlorate is !reci!itated. )t $eans that
a. :,)*
4
is stron electrol#te that :,)
b. 'ol&bilit# of :,)*
4
is reater than that of :,)
c. ?oth :,)*
4
and :,) are sol&ble in water to so$e e%tent
d. :,) is a stron electrol#te as co$!ared with :,)*
4
(d)
Q. 4. )n salt anal#sis 3
rd
ro&! basic radicals (1l
3@
, Ae
3@
etc) are detected b# addin 6H
4
,) to the salt
sol&tion and then 6H
4
*H. 3
rd
ro&! radicals are !reci!itated as h#dro%ide. )n this !rocess
a. 6H
4
,) will ioni0e to a lesser e%tent in !resence of 6H
4
,)
b. 6H
4
,) will !reci!itate
c. 6H
4
,) will react with 6H
4
,)
d. 1B
3@
will !reci!itate as 1),)
3
(a)
CHAPTER 8
SOLUTIONS AND ELECTROLYTES
Q. 1. )sla$ian eni&s !re!ared a salt b# the ne&trali0ation reaction of a wea+ acid and wea+ base. )f 5+
a
"al&e for acid is reater than the 5+
b
"al&e for the base then salt !re!ared will be
a. sol&ble in water
b. insol&ble in water
c. acidic
d. basic
(d)
Q. 2. (9&i"alent weih of s&lf&ric acid is 49, th&s 16 sol&tion of s&lf&ric acid will contain
a. 98 of H
2
'*
4
in 1lit of sol&tion
b. 49 of H
2
'*
4
in 1+ of sol"ent
c. 49 of H
2
'*
4
in 1lit of sol"ent
d. 49 of H
2
'*
4
in 1lit of sol&tion
(d)
Q. 3. 2./ 7olar sol&tion of 6a*H contains
a. 42 of 6a*H in 1lit of sol&tion
b. 22 of 6a*H in 1lit of sol&tion
c. 82 of 6a*H in 1lit of sol&tion
d. 12 of 6a*H in 1+ of sol"ent
(b)
Q. 4. 2/. $olal sol&tion
a. is less concentrated than 2./ $olar sol&tion
b. has co$e concentration as that of 2./ $olar sol&tion
c. is 2./ ti$es $ore concentrated than 2./ $olar sol&tion
d. has concentration e9&al to 1 $olar sol&tion
(a)
Q. /. 7ole fraction of water in ta! water will be
a. e9&al to 1
b. less than 1
c. reater than 1
d. will be so$ewhat e9&al to 2
(b)
Q. 6. 7olalit# of !&re water is
a. 36
b. //./
c. 18
d. 1
(b)
Q. 4. 1ll of the followin are !ost&lates of 1rrheni&s theor# of ioni0ation e%ce!t
a. electrol#tes ioni0e in water to !rod&ce cations and anions
b. ioni0ation is re"ersible !rocesses
c. electrical cond&cti"it# of a sol&tion of an electrol#te de!ends on the e%tent to which the
electrol#te ioni0e in the sol&tion
d. stron electrol#te ioni0e to a reater e%tent in water
(d)
Q. 8. )f <=> $oles of 1
2
,r
2
*
4
are dissol"ed in water to !rod&ce a sat&rated sol&tion then :s! will be
a. 2=
2
b. 2=
3
c. 4=
3
d. =
3
(c)
Q. 9. 1 salt was dissol"ed in water. )t was fo&nd that ionic !rod&ct is reater than the sol&bilit# !rod&ct. )t
$eans that the
a. sol&tion is &nsat&rated
b. sol&tion is sat&rated
c. sol&tion is s&!ersat&rated
d. we cannot !redict the sat&ration or &nsat&ration of the sol&tion for this data
(c)
Q. 12. (no&h lead chloride 5b,)
2
was dissol"ed in water at 2/
o
to !rod&ce a sat&rated sol&tion.
,oncentration of 5b
2@
in the sol&tion will be
a.
3
4
Ksp
b.
4
Ksp
c.
3
2
Ksp
d.
3
3
Ksp
(a)
Q. 11. ,onsider the followin cell reaction
5b @ 21
@
5b
2@
@ 21
)f a cell is $ade based on this e9&ation then
a. lead will act as anode and sil"er as cathode
b. lead will act as cathode and sil"er as anode
c. sil"er will act as cathode beca&se it has reater red&ction !otential
d. lead will act as anode beca&se it has lesser red&ction !otential
(a)
Q. 12. ,onsider the followin s!ontaneo&s reaction
6i
2@
@ 7n 6i @ 7n
2@
)f a "oltaic cell is $ade based on this reaction then con"entional re!resentation of the cell will be
a. 6i , 6i
2@
C 7n
2@
, 7n
b. 7n , 7n
2@
C 6i
2@
, 6i
c. 7n
2@
, 6i C 6i , 6i
2@
d. 6i , 6i C 7n , 7n
2@
(b)
Q. 13. 2.2/ $olar H
2
'*
4
sol&tion was !resent in the laborator# of )sla$ia ,ollee. )sla$ian eni&s told his
friends that 5H of this sol&tion $&st be
a. 2.2/
b. 2./
c. 1
d. 2
(c)
Q. 14. ?&ffer is a sol&tion
a. whose 5H is constant
b. which resists chane in its 5H
c. which is stron eno&h to $aintain its 5H
d. whose 5H $a# or $a# not chane d&rin a che$ical reaction
(b)
Consider the foo!in" ist of indi#$tors of the ne%t t!o &'estions
). Aerroin )). 7eth#l red
))). Di!hen#l a$ine
)E. 1lli0arian #ellow
E. ?ro$th#$ol bl&e
Q. 1/. )n this list acid base indicators are
a. ) and ))
b. )), ))) and E
c. ))), )E and E
d. )), )E and E
(d)
Q. 16. )n this list redo% indicators are
a. ) and ))
b. )) and )))
c. ) and E
d. ))) and )E
(a)
Q. 14. ,onsider the followin fo&r acids.
H2'*
4
, H6*
3
, H,)*
4
and H,)
The correct order in which the strenth of these acids increases
a. H
2
'*
4
F H6*
3
F H,) F H,)*
4
b. H,)*
4
F H,) F H6*
3
F H
2
'*
4
c. H6*
3
F H
2
'*
4
F H,) F H,)*
4
d. H,)*
4
F H,) F H
2
'*
4
F H6*
3
(c)
Q. 18. 1n &n+nown acid is !resent in a container. )f the acid is wea+ then
a. it will ha"e low 5H and low 5+a "al&e
b. it will ha"e hih 5h and hih 5+a "al&e
c. it will ha"e low 5H b&t hih 5+a "al&e
d. it will ha"e hih 5H b&t low 5+a "al&e
(b)
Q. 19. Dr. :han dissol"ed three salts ,&(6*
3
)
2
, 6aH,*
3
and (6H
4
)
2
'*
4
in water to $a+e a sat&rated
sol&tion. )sla$ian eni&s told hi$ that the res&lt sol&tion
a. $&st be ne&tral
b. $&st be basic
c. $&st be acidic
d. $a# be acidic, basic or ne&tral de!endin on the te$!erat&re
(c)
Q. 22. Ao&r state$ents are i"en below. The correct state$ent is
a. o%idation state of 6 in 6* and 6
2
*
/
is @/ and @2 res!ecti"el#
b. o%idation state of 6 in 6* and 6
2
*
/
is @1 and @/ res!ecti"el#
c. o%idation state of 6 in 6* and 6
2
*
/
is @2 and @/ res!ecti"el#
d. o%idation state of 6 in 6* and 6
2
*
/
is @2 and @4 res!ecti"el#
(c)
Q. 21. )sla$ian eni&s told his roo$$ate that for !&re water at roo$ te$!erat&re
a. $olarit# is slihtl# reater then 7olalit#
b. $olarit# is slihtl# less then 7olalit#
c. $olarit# is e9&al to its 7olalit#
d. conce!t of 7olalit# and $olarit# does not a!!lies
(b)
Q. 22. *ne of the followin wa#s of e%!ressin the concentration of a sol&tion does not de!end on
te$!erat&re. )t is
a. $olarit#
b. 7olalit#
c. 6or$alit#
d. Aor$alit#
(b)
Q. 23. 7ole fraction of !&re water is
a. slihtl# less then one
b. slihtl# reater then one
c. e%actl# e9&al to one
d. $a# be an# one of the abo"e de!endin on the te$!erat&re of water
(c)
Q. 24. 1 sol&tion contains 3 $oles of eth#l alcohol and 4 $oles of water. The $ole fraction of eth#l alcohol
and water will be
a. 2.4 and 2.3 res!ecti"el#
b. 2.3 and 2.4 res!ecti"el#
c. 2.6 and 2.4 res!ecti"el#
d. 2.2 and 2.8 res!ecti"el#
(b)
Q. 2/. -hich of the followin state$ents is correct for the life !eriod of a al"anic cell
a. it increases with increase in concentration of cathodic sol&tion
b. it increases with increase in concentration of anodic sol&tion
c. it increases with increase in the si0e of the cathode
d. it increases with decrease in the si0e of the anode
(a)
Q. 26. ,onsider the followin s!ontaneo&s reaction
1 @ 2?
@
1
2@
@ 2?
The standard red&ction !otentials are
1
2@
G1 82.13E
?
@
G? @2.82E
The "oltae of this cell will be
a. 2.26E
b. 1.6E
c. 2.64E
d. 2.93E
(d)
Q. 24. 1 s!ontaneo&s reaction is for a al"anic cell as a non s!ontaneo&s reaction is for
a. 6elsonHs cell
b. DownHs cell
c. (lectrol#tic cell
d. Daniel cell
(c)
Q. 28. 1cetic acid is a wea+ electrol#te. )ts concentrated a9&eo&s sol&tion will contain
a. ,H
3
,**H and H
3
*
@
b. ,H
3
,**8, *H
8
and H
@
c. ,H
3
,**H, ,H
3
,**
8
and H
@
d. ,H
3
,**H, ,H
3
,**8 and H
3
*
@
(d)
Q. 29. The stronest base a$on the followin is
a. Ib*H
b. :*H
c. 6a*H
d. Bi*H
(a)
Q. 32. ,onsider the followin b&ffers
a. 1)(*H)
3
@ 1)
2
('*
4
)
3
b. Ae(*H)
3
@ Ae,)
3
c. 6H
4
,) @ 6a
2
'*
4
d. 6a*H @ 6a
2
'*
4
(b)
Q. 31. 1 sol&tion contains two co$!o&nds 1)(*H)
3
and Jn (*H)
2
. 'ol&bilit# !rod&cts for these co$!o&nds
are 8./%12
823
and 1.8 % 12
84
res!ecti"el#. )f 6H
4
*H is added to this sol&tion then
a. both will !reci!itate at the sa$e ti$e
b. Jn(*H)
2
will !reci!itate first
c. 1) (*H)
3
will !reci!itate first
d. Jn (*H)
2
or 1) (*H)
3
will !reci!itate first de!endin on the te$!erat&re of the sol&tion
(c)
CHAPTER (
INTRODUCTION TO CHEMICAL )INETICS
Q. 1. The n&$ber of ato$s or $olec&les whose concentration deter$ines the rate of a che$ical reaction is
called the
a. $olec&larit# of the reaction
b. order of the reaction
c. s!ecific acti"it# of the reaction
d. rate constant of the reaction
(b)
Q. 2. 1 scientist !re!ared a co$!o&nd in laborator#. He fo&nd that it has two for$s, one a$or!ho&s for$
and another cr#stalline for$ ,. ?oth 1 and , reacts with s&lf&ric acid. *ne !ossible !redication is
that
a. increases with increase in concentration of the reactants
b. decreases with increase in concentration of the reactants
c. increases with increase in concentration of the !rod&cts
d. decreases with increase in concentration of the !rod&cts
(a)
Q. 3. The rate of an irre"ersible reaction
a. increase with increase in concentration of the reactants
b. decreases with increase in concentration of the reactants
c. increases with increase in concentration of the !rod&cts
d. decreases with increase in concentration of the !rod&cts
(a)
Q. 4. ,onsider the followin e9&ation
: = 1 e
8
RT
Ea
)n this e9&ation
a. 1 is a $olec&le of the reactant
b. 1 is a $olec&le of the !rod&ct
c. 1 is !ro!ortionalit# constant
d. 1 is 1rrheni&s constant
(d)
Q. /. ,onsider the followin reactions
). 6
2
*
/
26*
2
@
2
1

*
2
)). '*
2
,)
2
'*
2
@ ,)
2
))). H
2
@ )
2
2H)
The correct state$ent abo&t these reactions is
a. ) is a second order reaction
b. )) and ))) are first order reactions
c. ))) is a first order reaction
d. ) and )) are first order reactions
(d)
Q. 6. 1 s&bstance which increases the efficienc# of a catal#st is ter$ed as
a. 5ro$oter
b. 1cti"ator
c. Ietarder
d. '&!er catal#st
(a)
Q. 4. <Iancidit# !rod&ced in b&tter can be decreased b# addin 9&inoline to the b&tter>. This state$ents
shows that
a. nothin is i$!ossible
b. 9&inoline is an inhibitor
c. 9&inoline is a catal#st
d. 9&inoline is an acti"ator
(b)
Q. 8. 1$$onia can be !rod&ce accordin to the followin reaction
6
2
@ 3H
2
Ae
2
*
3
26H
3

11
2
*
3
, :
2
*
)n this reaction
a. Ae
2
*
3
and 1)
2
*
3
are catal#sts while :
2
* is a !ro$oter
b. Ae2*3 is catal#st while 1B2*3 and :
2
* are !ro$oters
c. 1)
2
*
3
and :
2
* are catal#sts while 1)
2
*
3
is a !ro$oter
d. Ae
2
*
3
and :
2
* are catal#sts while 1)
2
*
3
is a !ro$oter
(b)
Q. 9. )n s!ecified conditions the rate of cons&$!tion of 62*/ in the reaction
26
2
*
/
46*
2
@ *
2
is 2./ $ol 6
2
*
/
B
81
.'
81
. The rate of for$ation of 6*
2
is
a. 2./
b. 4
c. 2
d. 1
(d)