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Larn
4 CI crcdits
This coursc was
writtcn for ocntists,
ocntal hygicnists,
ano assistants.
Jhc Progrcssion ol
Icntal Adhcsivcs
A Peer-Reviewed PubIication
Written by Ara Nazarian, DDS
2 ....|reeJce.ccn
ducationaI Ob|ectives
\pon complction of this coursc, thc clinician will lc allc
to oo thc following:
1. Lc knowlcogcallc alout thc cvolution of
lonoing aohcsivcs
2. Know thc attrilutcs of an iocal lonoing agcnt
3. Lc knowlcogcallc alout thc propcrtics of thc
scvcnth-gcncration aohcsivcs ano thc aovantagcs
thcy offcr
+. Know thc applications that scvcnth-gcncration aohc-
sivcs can lc usco for ano unocrstano thc tcchniqucs
that shoulo lc usco
Abstract
Thcrc has lccn oramatic progrcssion in thc aohcsion of
ocntal aohcsivcs ano rcsins to cnamcl ano ocntin in thc +0
ycars sincc Luonocorc
1
introoucco thc tcchniquc of ctching
cnamcl with phosphoric acio to improvc aohcsion to cnamcl.
Thc frst ocntal aohcsivcs lonoco rcsins to cnamcl only,
with littlc or no ocntin aohcsion. Sulscqucnt gcncrations
havc oramatically improvco lono strcngth to ocntin ano
thc scaling of ocntin margins whilc rctaining a strong lono
to cnamcl. \ith morc paticnts ocmanoing mctal-frcc ocn-
tistry, thc usc of ocntal rcsins as ccmcnts as wcll as oircct ano
inoircct rcstorations will continuc to incrcasc. This articlc
oiscusscs thc progrcssion of ocntal aohcsivcs up to thc most
rcccnt gcncration, in which all componcnts arc containco
in a singlc lottlc or unit-oosc containcr ano applico using a
onc-stcp tcchniquc that rcquircs no mixing.
Overview
vcr thc past +3 ycars, ocntal lonoing systcms havc cvolvco
with variations in chcmistry, application, mcchanism, tcch-
niquc, ano cffcctivcncss. This cvolution accompanico thc
ocvclopmcnt of improvco csthctic ocntal matcrials, notally
compositc rcsin ano ccramic, ano an incrcasing ocmano ly
paticnts for csthctic ocntistry. !n 1999, approximatcly 86
million oircct rcsin rcstorations wcrc placco. \ith rcspcct
to inoircct rcstorations, approximatcly 2.3 million vcnccrs,
38 million rcsin/ccramic crowns, ano 1.1 million ccramic/
porcclain inlays wcrc placco, in aooition to mctal-lasco
crowns ano lriogcs ano corc/post ano corc luilo-ups.
2
All oircct rcsin rcstorations rcquirc lonoing, ano inoircct
rcstorations cithcr rcquirc or arc canoioatcs for lonoing. As
thc ocmano for lonoco csthctic rcstorations has continuco
to incrcasc, thc cvolution of lonoing agcnts has accclcratco.
Lct us quickly rcvicw ocntal aohcsivcs accoroing to a scrics
of gcncrations, allowing us to unocrstano thc charactcristics
of cach group.
||| a|rect re.|a re.ter+t|ea.
re|a|re |eaa|a
History of 8onding Agents
Iirst and Second Generation
Thc first- ano sccono-gcncration lonoing agcnts usco
ouring thc 1960s ano 1970s oio not rccommcno ctching
thc ocntin, lut instcao rclico on aohcsion to thc attachco
smcar laycr.
3
Thc wcak lono strcngth (2!Fa6!Fa) to
thc smcar laycr still allowco ocntin lcakagc with clinical
margin stain.
+
7hird Generation
Thc thiro-gcncration systcms of thc 1980s introoucco
acio ctching of ocntin ano a scparatc primcr ocsignco to
pcnctratc thc ocntin tululcs as a mcthoo to incrcasc lono
strcngth.
3
Thcsc systcms incrcasco lono strcngth to ocntin
(12!Fa13!Fa) ano occrcasco ocntin margin failurc. \ith
timc, howcvcr, margin staining causco clinical failurc.
+
Iourth Generation
Thc fourth-gcncration aohcsivc systcms of thc carly 1990s
usco chcmistry that pcnctratco loth ctchco ano occalcifco
ocntin tululcs ano ocntin sulstratc, forming a hylrio
laycr of collagcn ano rcsin. Iusayama
3
ano `akalayashi
6
ocscrilco thc pcnctration of rcsin into ocntin as giving high
lono strcngths ano a ocntin scal. !n fact, Kanca
7
introoucco
thc ioca of wct lonoing with thcsc systcms. Frooucts in
this catcgory incluoc All-Lono
2 (Lisco), ptiLono
IL
(Kcrr), ano Aopcr Scotchlono !ultipurposc (3!
LSFL). Thcsc lonoing agcnt systcms havc thc longcst track
rccoro as far as rcscarch gocs ano thcy pcrform wcll clinical-
ly. !n fact, ptiLono IL, an 18-ycar-olo proouct, rcccivco
thc Froouct of thc Ycar awaro from Rcolty magazinc.
8
Lono
strcngths for thcsc aohcsivcs wcrc in thc low- to mio-20!Fa
rangc ano signifcantly rcoucco margin lcakagc comparco to
carlicr systcms.
+
This systcm was vcry tcchniquc scnsitivc
ano rcquirco an cxacting tcchniquc of controllco ctching
with acio on cnamcl ano ocntin, followco ly two or morc
componcnts on loth cnamcl ano ocntin. Lccausc of thc
complcxity of multiplc lottlcs ano stcps, ocntists lcgan
rcqucsting a simplifco aohcsivc systcm.
|eart| eaer+t|ea +a|e.|.e ..tem. were
.er tec|a||ae .ea.|t|.e
Iifth Generation
That rcqucst ushcrco in thc ffth-gcncration lonoing sys-
tcms, introoucco ouring thc mio 1990s, which comlinco
primcr ano aohcsivc in onc lottlc whilc maintaining high
lono strcngths. Frooucts in this catcgory incluoc Lxcitc
(!voclar \ivaocnt), ptiLono
SI Lono
(Kurarray), Simplicity (Apcx), Aopcr Frompt, ano
L-Fop (3! LSFL). Thcsc systcms wcrc also rcportco to
rcoucc thc inciocncc of post-trcatmcnt scnsitivity founo in
prcvious systcms.
8
Howcvcr, thc lono strcngth to ocntin
ano cnamcl is lowcr than fourth- ano ffth-gcncration sys-
tcms
+
(Tallc 1).
IdeaI 8onding Agent Attributes
Attrilutcs of an iocal lonoing agcnt woulo incluoc high
lono strcngth, a thin flm thickncss to cnsurc casy ano com-
plctc scating of rcstorations, shclf stalility, ano post-placc-
mcnt stalility. Thc alility to rclcasc uorioc is ocsirallc to
hclp prcvcnt thc onsct of scconoary carics, which is thc lcao-
ing rcason for rcplaccmcnt of cxisting rcstorations.
9
!n aooi-
tion, thc lonoing agcnt shoulo lc uscr-fricnolyiocally a
onc-stcp proccourc rcquiring no mixing, with thc vcrsatility
to lc usco for multiplc typcs of rcstorations (inoircct ano
oircct, rcsin/ccramic, ano mctal), ano tolcrant of loth moist
ano ory cnvironmcnts (Tallc 2).
I+||e z. |ae+| |eaa|a |eat |ttr||ate.
||| |eaa .treat|
I||a l|m t||c|ae..
||aer|ae-re|e+.|a
.er-lr|eaa|
:a|t+||e ler me|.t +aa ar ea.|reameat.
:t+||||t
Seventh Generation 8onding Systems
Thc latcst catcgory, scvcnth-gcncration lonoing systcms,
is thc all in onc aohcsivcs that comlinc ctch, primc, ano
lono in a singlc solution.
8
This aohcsivc catcgory was intro-
oucco in latc 2002. Laloratory stuoics show lono strcngths
ano margin scaling to lc cqual to sixth-gcncration systcms.
+
Frooucts in this catcgory incluoc iLono (Hcracus), Xcno
!\ (Lcntsply), C-Lono (CC), Complctc (Cosmcocnt),
ano ptiLono
All-!n-nc (Kcrr).
8
Loth ptiLono All-
I+||e . |.e|at|ea el |eaa|a |a|e.|.e.
19s aa6 19Is ||rst aa6 !ecea6 6eaerat|ea
||a aet recemmeaa aeat|a etc||a.
|e||ea ea +a|e.|ea te .me+r |+er.
\e+| |eaa .treat|.
19s Ih|r6 6eaerat|ea
|c|a etc||a el aeat|a.
:ej+r+te jr|mer.
|acre+.ea |eaa .treat|.
M+r|a .t+|a|a c+a.ea c||a|c+| l+||are e.er t|me.
lar| 199s |earth 6eaerat|ea
|c|a etc||a el aeat|a.
:ej+r+te jr|mer.
|acre+.ea |eaa .treat|.
M+r|a .t+|a|a c+a.ea c||a|c+| l+||are e.er t|me.
lar| 199s |earth 6eaerat|ea
'||r|a' |+er el aeat|a +aa ce||+ea.
|eat|a .e+|.
teacejt el 'wet |eaa|a' |atreaacea.
Iec|a||ae .ea.|t|.e.
M|6 199s ||fth 6eaerat|ea
tem||aea jr|mer +aa +a|e.|.e |a eae |ett|e.
M+|at+|aea ||| |eaa .treat|..
a|t-ae.e j+c|+|a |atreaacea.
|ate 199s, lar| 1s !|xth 6eaerat|ea
':e|l-etc||a' jr|mer..
|eaacea |ac|a|eace el je.t-tre+tmeat .ea.|t|.|t.
|eaa .treat|. |ewer t|+a leart|- +aa l|lt|-eaer+t|ea..
|ate 11 !eeath 6eaerat|ea
'|||-|a-0ae'.
tem||ae. etc||a, jr|m|a +aa |eaa|a.
:|a|e .e|at|ea.
0eea |eaa .treat| +aa m+r|a .e+||a.
4 ....|reeJce.ccn
in-nc ano Xcno !\ arc uorioc rclcasing, whilc iLono ano
C-Lono arc not.
Thc all-in-onc aohcsivcs arc uscr-fricnoly, ano most
offcr loth a lottlc ano a unit-oosc vcrsion. Thcrc arc varia-
tions on othcr attrilutcs ocpcnoing on thc proouct usco.
Shcar lono strcngth, a kcy attrilutc in ocntal aohcsivcs,
varics consiocrally ocpcnoing on thc sclf-ctch aohcsivc
usco. (Iigurc 1)
Xcno !\ sclf-ctch scvcnth gcncration aohcsivc is avail-
allc in a lottlc or unit oosc oclivcry ano oocs not rcquirc
mixing. Xcno !\ is pH lalancco to rcoucc gingival irritation
ano scnsitivity. Clcarfl S3 Lono, C-Lono ano iLono arc
availallc in a lottlc. Clcarfl S3 Lono contains watcr to allc-
viatc thc ncco for a surfacc with a spccifc ocgrcc of wctncss
ano to rcsist hyorolysis, provioing for a lasting ano rcliallc
aohcsion. !t rcsists hyorolysis which proviocs for rcliallc
ano ourallc aohcsion.. As with othcr scvcnth-gcncration
aohcsivcs, C-Lono offcrs vcrsatility in thc ocgrcc of wctncss
on thc tooth surfacc at thc timc of ahocsivc application.
I|e +||-|a-eae .e.eat| eaer+t|ea +a|e.|.e.
+re a.er-lr|eaa| +aa me.t eller |et|
+ |ett|e +aa + aa|t-ae.e .er.|ea
AII-In-One 8ond DentaI Adhesive System
ptiLono All-!n-nc is a singlc-componcnt, sclf-ctch
aohcsivc that climinatcs multiplc stcps whcn lonoing oi-
rcct ano inoircct rcstorations. Clinicians havc cvcrything
thcy ncco for ctching, priming ano lonoing in onc matc-
rial. ptiLono All-!n-nc is a light-curco aohcsivc that
proviocs aohcsion to all surfaccs ano sulstratcs. !ts tcrnary
solvcnt systcm proviocs cnhancco shclf-lifc stalility ano cf-
fcctivc cnamcl ctching for long-tcrm lono pcrformancc.
Accoroing to somc inocpcnocnt stuoics provioco ly
Kcrr Corporation, ptiLono All-!n-nc oclivcrs cxccllcnt
||are z. |tc|ea |a+me|
||are 1. 0jt||eaa |||-|a-0ae |a|e.|.e-|eat|a-|eaa|a |aterl+ce
||are 1. |reejer+t|.e \|ew el :m||e
||are !. |reejer+t|.e |etr+ctea \|ew
||are . :|e+r |eaa :treat| - |||-|a-0ae |a|e.|.e :.tem.
S
h
e
a
r
8
o
n
d
S
t
r
e
n
g
t
h
,
M
P
a
1
1!
1
z!
z
!
nameI
Dentin
0jt||eaa
|||-|a-0ae
/eae |\ t|e+rl|
:1 |eaa
0-|eaa" ||eaa"
....|reeJce.ccn 5
pcnctration into ocntin tululcs, offcring cxccptional lono
strcngth ano protcction against microlcakagc ano post-
opcrativc scnsitivity.
!ts uniquc ctching capalility cnallcs thc most cffcctivc
cnamcl ctching of any singlc-componcnt aohcsivc, crcating
a occpcr-ctchco surfacc for highcr mcchanical rctcntion ano
chcmical lonoing. Scanning clcctron microscopy (SL!) of
ctchco cnamcl shows thc occp ctching oltainco using this
capalility (Iigurc 2), ano SL! of thc aohcsivc-ocntin-
lonoing intcrfacc shows thc occp tags that rcsult from usc
of this systcm in ocntin (Iigurc 3).
! havc founo that thc low flm thickncss makcs it casicr
to scat inoircct rcstorations, crcating a lcttcr ft. ptiLono
All-!n-nc is availallc in loth a 3 ml lottlc oclivcry ano a
convcnicnt frcc-stanoing \nioosc ocvicc.
0jt||eaa |||-|a-0ae eller. e\cejt|ea+| |eaa
.treat| +aa jretect|ea ++|a.t m|cre|e+|+e
+aa je.t-ejer+t|.e .ea.|t|.|t
Case Presentations
Scvcnth Ccncration Lonoing Agcnts arc iocal for lono-
ing inoircct rcstorations, ano for oircct compositc rcsin
(whcrc lonoing is manoatory rcgarolcss of thc matcrial
ano tcchniquc lcing usco).
Case Presentation 1
Indirect Restorations
A paticnt sitting for an initial consultation was oissatisfco
with hcr smilc (Iigurc +). Clinical cxamination rcvcalco a
!arylano lriogc from tccth 4648 with failing margins
(Iigurcs 3, 6). Thc paticnt statco that thc lriogc hao lccn
rcccmcntco a couplc of timcs sincc its original placcmcnt
fvc ycars prior. Tooth 410 hao an cxisting vcnccr rcstora-
tion to corrcct a pcg latcral. Also, tooth 411 ano tooth 412
wcrc invcrtco. Froling ocpths wcrc within normal lcvcls in
thc antcrior rcgion, ano thc paticnt`s pcriooontal hcalth was
within acccptallc limits.
Thc 5mlc Gudc ool (Liscus Lcntal) was usco to
complctc thc smilc analysis ncccssary for prcocsigning thc
casc. Hcr cxisting lriogc was asymmctric, ano thc paticnt
prcfcrrco a morc complctc ano uniform smilc. !n orocr to
achicvc this, thc shapc sclcctco woulo lc rounocr ano thc
cmlrasurcs lctwccn thc tccth woulo lc smallcr. Thc lip linc
cogc vcrsus thc incisal cogc of thc tccth suggcstco that thc
paticnt coulo tolcratc lcngthcning of thc incisal cogcs. Thc
rcsults of thc smilc analysis, oiagnostic stuoy moocls, ano
prcopcrativc clinical photography wcrc rcvicwco with thc
paticnt to octcrminc thc ocsirco trcatmcnt plan for improv-
ing hcr smilc ano function. Sincc thc paticnt`s complaint
was cxtrcmc oissatisfaction with thc wholc appcarancc of
hcr smilc, it was occioco to incorporatc a mctal-frcc lriogc
||are . |reejer+t|.e |+|+t+| \|ew
||are I. |rej+r+t|ea.
||are . |e.ter+t|ea.
||are . |e+a|a el \eaeer.
6 ....|reeJce.ccn
matcrial (Lava, 3!) for thc missing latcral ano porcclain
vcnccrs on thc aojaccnt tccth. Thc proposco trcatmcnt plan
of a zirconium lriogc (Lava, 3!) from 4648 ano porcclain
vcnccrs from 49411 was rcvicwco with thc paticnt, ano
shc was cxcitco to start thc trcatmcnt.
Aftcr ancsthctic was aoministcrco, a oiamono lur was
usco to prcparc thc antcrior tccth. !t was vcry important to
aohcrc to thc prcparation guioclincs for thc zirconium lriogc
in orocr to cnsurc functional ano csthctic prcoictalility. Thc
laloratory rcquirco a minimum of 0.8 mm rcouction of thc
facial walls ano a minimum of 1.3 mm of incisal rcouction.
!ntcrnal linc anglcs wcrc to lc rounoco, ano a lutt joint mar-
gin was rcquirco (Iigurc 7). Also, an ovatc arca was crcatco
in thc gingiva at thc pontic sitc of tooth 47 with an oysscy
Lascr (!voclar \ivaocnt) to crcatc a morc harmonious cmcr-
gcncc proflc for thc pontic. !mprcssions wcrc takcn using a
quick-sctting polyvinylsiloxanc (F\S) imprcssion matcrial
(Takc 1