Chem 6A 2011 (Sailor) QUIZ #1

Name: VERSION A KEY

Student ID Number:
Section Number:

1 18
1 2
H 2 13 14 15 16 17 He
1.0079 4.0026
3 4 5 6 7 8 9 10
Li Be B C N O F Ne
6.941 9.01218 10.811 12.011 14.0067 15.9994 18.9984 20.1797
11 12 13 14 15 16 17 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.9898 24.305 26.9815 28.0855 30.9738 32.066 35.4527 39.948
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.0983 40.078 44.9559 47.88 50.9415 51.9961 54.9381 55.847 58.9332 58.69 63.546 65.39 69.723 72.61 74.9216 78.96 79.904 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.4578 87.62 88.9059 91.224 92.9064 95.94 98.9063 101.07 102.906 106.42 107.868 112.411 114.82 118.71 121.75 127.6 126.905 131.29
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.905 137.327 138.906 178.49 180.948 183.85 186.207 190.2 192.22 195.08 196.967 200.59 204.383 207.2 208.98 208.982 209.987 222.018
87 88 89 104 105 106 107 108 109
Fr Ra Ac
223.02 226.025 227.028 - - - - - -
58 59 60 61 62 63 64 65 66 67 68 69 70 71
Lanthanides Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 146.92 150.35 151.96 157.25 158.92 162.5 164.93 167.26 168.93 173.04 174.97
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Actinides Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.038 231.04 238.03 237.05 239.05 241.06 247.07 249.08 251.08 254.09 257.1 258.1 255 262.1


Some useful constants and relationships:
Specific heat capacities (in J/g
.
K): H
2
O
(l)
= 4.184; Al
(s)
= 0.900; Cu
(s)
= 0.387; Steel
(s)
= 0.45
101.325 J = 1 L
.
atm 1 atm = 760 Torr 1J = 1kg
.
m
2
/s
2
1 eV = 1.6022 x 10
-19
J
R = Ideal gas constant: 0.08206 L
.
atm
.
mol
-1 .
K
-1
= 8.31451 J
.
mol
-1 .
K
-1
Avogadro constant: 6.022 x 10
23
mole
-1
Planck's constant = h = 6.6261 x 10
-34
J
.
s
c = speed of light: 3.00 x 10
8
m/s R
H
= 1.097 x 10
-2
nm
-1

C
2
= second radiation constant = 1.44 x 10
-2
K
.
m
!
T"
max
=
1
5
C
2

Emitted power (W)
Surface area (m
2
)
= (constant)T
4
e = mc
2
c = "#
1
"
= R
H
1
n
1
2
$
1
n
2
2
%
&
'
(
)
*
E = h# E =
hc
"
E(in Joules) = $2.18 +10
$18
Z
2
n
2
%
&
'
(
)
*



Chem 6A 2011 (Sailor) QUIZ #1


1. Fill in the blanks in the following table: (4 pts ea)

Symbol (including
the mass number)
Number of Protons Number of Neutrons Number of
Electrons
28
Si
14 14 14
88
Sr
2+

38 50 36

2. A mass spectrometer was used to measure the mass of an unknown isotope. The ratio
of the mass of the unknown isotope to the mass of
12
C (i.e., the mass ratio) is 2.3314.
The relative abundance of the unknown isotope is 92.1%, and the relative abundance
of
12
C is 98.9%. What is the mass of the unknown isotope? Set up the problem but do
not solve it. (10 pts)


Mass (amu) = (mass of
12
C) x (mass unknown/mass
12
C) = (12.00 x 2.3314)

Numerically the answer is 27.9768 AMU

+2 points if 12.00 (not 12.011 is used)
+2 points if 2.3314 is there (even if they divide by it instead of multiplying)
+6 points if their answer calculates to 27.9868
most common error will be to include the % abundance numbers in the calcultion. If that
is the case, they should get only 2 points if they use 12 and not 12.011 (they recognize
that
12
C is the standard mass reference). Otherwise they should get 0 points.






3. Give the name and the empirical formula for the ionic compound formed from the
following pairs of elements. The first one is done for you (4 pts each):

Elements Formula Name
Magnesium and nitrogen Mg
3
N
2
Magnesium nitride
Iodine and cadmium CdI
2
Cadmium iodide
Strontium and fluorine SrF
2
Strontium fluoride
Sulfur and cesium Cs
2
S Cesium sulfide