1. An advantage of the Homogeneous Charge Compression Ignition (HCCI) engine is that
combustion temperatures are kept below 1800 K where nitrogen oxides (NOx), begin to form. Consider an HCCI engine fueled with n-heptane (C7H16) and mixed with air at an equivalence ratio = 0.3.
a) Balance the chemical equation for stoichiometric combustion of n-heptane in air.
b) Assuming products comprise only complete combustion products and excess air, balance the chemical equation representing the global combustion process with = 0.3.
c) Using the enthalpy tables provided, calculate the enthalpy of the products, per mole of fuel, at a temperature of 1800 K (= 0.3).
d) At the end of compression, prior to combustion, the = 0.3 n-heptane/air mixture temperature is 800 K. Will the constant volume adiabatic flame temperature exceed 1800 K? Show calculations to support your answer.
716
@800 =-55.298 MJ /kmol.
2. Assuming isentropic compression and expansion processes, consider an ideal Diesel air cycle under the following conditions:
a) Calculate the temperature and pressure at each state of the cycle using the air tables provided. b) Calculate the mep of the cycle. c) Calculate the thermodynamic efficiency of the cycle. d) If the displacement volume of the engine is 7.2 Liters, how much power is produced if 750 cycles are occurring per minute? e) If a constant specific heat ratio value of =1.4 is used, what would be the peak temperature of the cycle?
3. A single-cylinder diesel engine has a bore dimension of 85 mm, stroke of 90 mm, and a compression ratio of 15. At a certain operating condition, a P-V diagram has been measured as shown below.
a) Use the measured cylinder pressure and volume values at the points shown to determine the value of the polytropic expansion exponent that describes the expansion process.
b) Consider that the average charge temperature has been determined to be 938 K when the cylinder pressure is 20 bar and cylinder volume 0.0873 Liters, and that the exhaust valves open when the cylinder volume is 0.536 Liters. Estimate the initial exhaust gas temperature (charge temperature as the exhaust valves open).
c) What would account for the slopes of the log P-log V lines to be different for the compression and expansion process? Briefly explain.
d) A ringing vibration shows up as noise in the measured cylinder pressure signal at the location indicated on the graph. State which valve timing event is most likely responsible for this signal (Intake Valve Opening, Intake Valve Closing, Exhaust Valve Opening, Exhaust Valve Closing).
0.1 0.08 0.2 0.3 0.4 0.5 0.6 0.8 1 Normalized Volume [V/Vswept] P C Y L 1
[ b a r ] 0.1 0.2 0.5 1 2 5 10 20 50 100 PCYL1 bar 3.979 20.091 16.113 Normalized Volume [V/Vswept] deg 0.371 0.100 -0.272 0.371 0.171 -0.200 0.369 0.649 0.651 Cycl e Number: 218 Cylinder Volume=0.0873 Liter P=20 bar, T=938 K. Cylinder Volume=0.332 Liter P=4 bar Exhaust Valve Opens Cylinder Volume=0.536 Liter Discernible Valve Noise 4. Consider the reaction of isopropyl alcohol (C 3 H 7 OH) in air (O2 and N2).
a) Calculate the stoichiometric Air-fuel ratio (by mass). b) Determine the equivalence ratio if one mole of isopropyl alcohol reacts with 23.8 moles of air to form products comprising only CO2, H2O, N2 and O2. c) What is the mole fraction of CO2 in the products?
5. Using the thermodynamic tables provided, consider the global reaction of formaldehyde in air: 1 2 + 1( 2 + 3.76 2 ) 1 2 + 1 2 + 3.76 2
a) If the reaction takes place at 1,000K, at which temperature the molar enthalpy of formaldehyde is -81.053 kJ /mol, determine the heat of reaction.
b) Is the reaction exothermic or endothermic?
6. Assuming isentropic compression and expansion processes, consider an ideal dual air cycle under the following conditions:
T1: 300K P1: 1bar Compression Ratio: 15 Heat Addition: 1330 kJ /kg air 75% of heat addition at constant volume 25% of heat addition at constant pressure
Note: the specific heat ratio is NOT constant.
f) Calculate the temperature and pressure at each state of the cycle using the air tables provided. g) Calculate the mep of the cycle. h) Calculate the thermodynamic efficiency of the cycle. i) If the displacement volume of the engine is 0.5 Liters, how much power is produced if 600 cycles are occurring per minute?
7. Consider the P-V diagram shown below:
a) Use the measured cylinder pressure and volume values at the points shown to determine the value of the polytropic expansion exponent that describes the expansion process.
b) Using the polytropic exponent found in a), find the mass exhaust gas fraction. Assume the exhaust pressure is 1 bar.
0.1 0.08 0.2 0.3 0.4 0.5 0.6 0.8 1 Normalized Volume [V/Vswept] P C Y L 1
[ b a r ] 0.1 0.2 0.5 1 2 5 10 20 50 100 PCYL1 bar 3.979 20.091 16.113 Normalized Volume [V/Vswept] deg 0.371 0.100 -0.272 0.371 0.171 -0.200 0.369 0.649 0.651 Cycl e Number: 218 Cylinder Volume=0.0873 Liter P=20 bar, T=938 K. Cylinder Volume=0.332 Liter P=4 bar Exhaust Valve Opens Cylinder Volume=0.536 Liter Discernible Valve Noise TDC Cylinder Volume=0.0365 Liter Short Answer
8. In the below expression for engine power output, which term is primarily responsible for the positive slope on the left side of the attached engine power curve? (circle one) ( ) R i a HV d vol f n A F Q V N P
= ,
9. In the below expression for engine power output, which term is primarily responsible for the sharp fall-off in the engine power output at higher RPM as shown on the attached engine power curve? (circle one)
( ) R i a HV d vol f n A F Q V N P
= ,
10. Other condition equal, do you expect to get a higher flame temperature with the fuel in a gaseous or liquid state? (circle one)
11. As the ignition timing in a spark-ignited engine is advanced into the compression side of TDC, is the peak cylinder temperature expected to increase or decrease? (circle one)
12. The heat transfer rate during compression is predicted by the Woschni model to be:
= 3.26() 0.2 () 0.8 () 0.55
0.8 . If the engine speed is doubled, do you expect the net heat transfer per cycle to increase or decrease? (circle one)