Running head: ORGANIC PAINT VERSUS INORGANIC PAINT 1
Organic Paint Versus Inorganic Paint
Mary J. Pearson Global High School
ORGANIC PAINT VS. INORGANIC PAINT 2 Table of Contents Abstract.............................................................................................................................3 Introduction.......................................................................................................................4 Denition of Organic Paint............................................................................................... 4 Components of Paint....................................................................................................... 5 Casein Binders................................................................................................................ 5 Figure 1. Components of Powdered Milk.............................................................. 6 Organic Pigments............................................................................................................ 6 Glob colors............................................................................................................ 7 The Earth Pigments Company.............................................................................. 7 Figure 2. Most Vibrant of Each Pigment Type............................................ 7 Homemade Paint............................................................................................................. 8 Health Risks of Inorganic Paint........................................................................................ 8 Outgassing and VOCs.......................................................................................... 8 Possible side effects of inorganic paints............................................................... 9 Organic Alternative to Inorganic Solvents...................................................................... 10 Conclusion......................................................................................................................10 References.................................................................................................................... 12 Appendix A......................................................................................................................14 Figure A.1 Percent of Natural Substances in EarthPigmentsCompany Pigments..14
ORGANIC PAINT VS. INORGANIC PAINT 3 Abstract Organic paint is made from pure, natural ingredients (Elaun, 2011). Paint is made from a pigment, which is the color in the paint, and a binder, which is the glue that pigments are suspended in (Steen, 2006). Natural pigments help ght against adverse health effects found in inorganic paint. The Earth Pigments Company and Glob Colors are two companies that produce completely organic, natural pigments (Phelps, 2013). Inorganic manufactured paints contain solvents that outgas Volatile Organic Compounds (VOCs) as they dry. VOCs can cause a range of health hazards, such as drowsiness, headaches, dizziness, feelings of intoxication, fatigue, mental confusion, increased heart rate, nausea, loss of coordination, convulsions, and even death (Spandorfer, Curtiss, & Snyder, 2010). The VOCs in wall paint alone contribute 9% of the pollutants in the air that cause greenhouse gases and smog. The South Coast Air Quality Management District in California has the strictest limits on VOCs in wall paint, with the allowable amount of VOCs in wall paint as 50 g/L. The EPA has proposed cutting the amount of VOCs allowed in paint in half for most nishes (Casa Verde Paint, 2011). An organic alternative to these volatile inorganic solvents is an orange oil (d-Limonene), which is a natural solvent contains no carcinogenic or neurotoxin hazards (Florida Chemical Company, Inc., n.d.). Keywords: VOCs, casein, binders, solvents, pigments, inorganic manufactured, homemade paint
ORGANIC PAINT VS. INORGANIC PAINT 4 Introduction Organic paint is made from biodegradable, pure ingredients (Elaun, 2011). All paint goes through the drying and curing process called outgassing. This is what causes the odor of fresh paint, and is the reason you should wait to move into a newly painted room (Dex Media, Inc., n.d.). Mixing your own paint is benecial for your health and the environment. Natural ingredients like egg yolks and milk casein allow for the moisture in paint to be released naturally (Steen, 2006). Some companies, such as The Earth Pigments Company and Glob Colors specialize in making organic pigments for paint. Glob Colors uses fruits and vegetables, where The Earth Pigments Company uses soils (Phelps, 2013; The Earth Pigments Company, 2013). Different paints have different ingredients and therefore have varying degrees of health effects. There is less outgassing in natural paint and therefore less impact on the environment and your health (Benivia LLC, n.d.). Inorganic manufactured paints contain Volatile Organic Compounds (VOCs), which help the paint dry, but cause massive damage to the environment and to human health (Casa Verde Paint, 2011; Steen, 2006). Denition of Organic Paint There are many denitions of what organic paint means. Spramani Elaun (2011) describes it as: ...made with ingredients that are biodegradable and pure ingredients. Simply stated, ingredients grown without pesticides, synthetic fertilizers, sewage#sludge, genetically modied organisms or without ionizing radiation. It could also be described as: ...made from substances naturally found in nature... (with) no toxic chemicals, (Dex Media, Inc., n.d.). By either of these denitions, organic paint is easier on your home ORGANIC PAINT VS. INORGANIC PAINT 5 than manufactured inorganic paint, which is energy-intensive to produce (Steen, 2006). Despite common misconceptions, organic paints can stand up to everyday use. They can perform with similar amounts of durability and coverage as traditional manufactured paints (Dex Media, Inc., n.d.). Components of Paint The most basic paint is made up of a pigment and a binder. Pigments provide the color, and the binder is the glue the pigment is suspended in. Without the binder, pigments would not remain glued to a surface. Fillers and solvents are an optional additive to paint. Fillers add different textures and bulk to paint. Common llers include whiting (powdered chalk), talcum, limestone, silica and marble. Solvents are thinners that allow paint consistency to be easily controlled. Solvents are what cause VOCs to be emitted. Natural solvents, such as citrus thinners and natural turpentine, still emit VOCs, but at a very low level (Steen, 2006). (See the Outgassing and VOCs section of this paper for more on VOCs in paint). Casein Binders There are many natural binders, such as linseed oil, starch (from ower), egg yolk tempura, and casein (a protein found in milk). Casein binders make great paint for interior surfaces, exterior surfaces in mild and non-humid climates, bare wood, stone, bare drywall, wallpaper, masonry, and even previously painted surfaces. After drying, casein paint will last indenitely without being prone to fungal growth (Steen, 2006). ORGANIC PAINT VS. INORGANIC PAINT 6 Casein can be harvested from milk a number of ways. Adding distilled white vinegar to nonfat milk causes the milk to curdle by isolating the casein protein, separating from the liquid whey in the milk. A cream of hydrated lime and water will dissolve the curds, creating a smooth syrup-like solution that is known as quark (Alan, 2011). Since the quark is made from natural, fresh ingredients without added preservatives, it only keeps for ten days at the most. Other methods for making a milk casein binder include adding borax to the curds instead of lime to induce hydrolysis to occur (Fraley, 2011). An alternative source of casein is dried nonfat milk. This nonfat milk powder is made from depredating milk that has been removed of most of its fat content. Casein protein is the most abundant protein in nonfat milk powder. Approximately 36% of the milk powder is protein and the other 54% is lactose, as shown in Figure 1 (Lee, 2011). Organic Pigments The most common sources of pigments include: Inorganic minerals and metals, (natural or manufactured) ground into a ne powder, organic (animal and plant) substances, and synthetic (chemical) manufactured (Spandorfer, Curtiss, & Snyder, 2010). Different companies, such as Glob Colors and The Earth Pigments Company, specialize in natural paints.
Figure 1. Components of Powdered Milk ORGANIC PAINT VS. INORGANIC PAINT 7 Glob Colors Glob Colors was founded by Ashley Phelps, an artist that was tired of chemical additives in paint and their adverse reactions to her skin and body. She heard about natural products used to make wall paint and cosmetics, and she wondered why there werent natural alternatives for the arts. She developed Glob paint, which only uses natural, botanical sources for the colors. The pigments in beets, purple carrots, turmeric, and red cabbage, as well as beta-carotene from oranges, tomatoes, carrots, and marigolds, produce vibrant pigment powders (Phelps, 2013). The Earth Pigments Company The Earth Pigments Company provide a wide variety of powdered pigments. 1 The Natural Earth & Ocher Pigments, as well as the Colonial Natural Pigments, are 100% natural, made from soils native to the Earth, and contain no man-made colorants. The colors are moderately vibrant, with some blues and greens, but mostly reds, yellows, and browns. The most vibrant color of each pigment type is displayed in Figure 2. The French Mineral Pigments are over 90% Figure 2. Most Vibrant of Each Pigment Type
Comparison graph in Appendix A
1 ORGANIC PAINT VS. INORGANIC PAINT 8 natural, and have vibrant blues, greens, reds, and yellows. The Mayan Pigments are made with the same processes used by the Mayans to make pigments, making them 100% natural. They are intensely vibrant, even to the point of bold neon. The only non- natural pigments offered by The Earth Pigments Company is the Oxide Pigments, which are inorganic manufactured pigments made from natural components such as iron and clay (The Earth Pigments Company, 2013). Homemade Paint Organic paint can be bought or made. Homemade paint provides complete control over color selection, and has a range of unique nishes that are not found in manufactured paint. Different binders create different paint textures, and llers create manipulable textures depending on the ller and the amount added. (Steen, 2006) Health Risks of Inorganic Paint Outgassing and VOCs Outgassing is, ...that new smell in wood, furniture, carpet and that nice fresh coat of paint on the wall. It is part of the drying and curing process of paint. (Dex Media, Inc., n.d.). VOCs in wall paint alone make up 9% of the pollutants in the air that cause greenhouse gases and smog, which contribute directly to global warming. Many areas have enforced stricter limits on wall paint. Californias South Coast Air Quality Management District dropped the allowable amount of VOCs in wall paint to 50 g/L, and charges fees to companies that exceed this limit. The EPA has proposed cutting the maximum amount of VOCs allowed in half (Casa Verde Paint, 2011). Solvents, which ORGANIC PAINT VS. INORGANIC PAINT 9 control the consistency of paints, outgas and evaporate VOCs as the paint drys, which can cause many side effects, ranging from mild to fatal (Steen, 2006). Possible side effects of inorganic paints Prolonged inhalation, ingestion, or absorption of solvents (found in inorganic manufactured paint) in large amounts can lead to drowsiness, headaches, dizziness, feelings of intoxication, fatigue, mental confusion, increased heart rate, nausea, and loss of coordination. High-level exposure may also cause breathing difculty, convulsions, kidney damage, and even death. Painting in a non-enclosed space with plenty of ventilation will help ght against the side effects of VOC emissions. Jackson Pollock, also known as Jack the Dripper, suffered neurological disorders from working in a VOC-lled studio from his paints. Aromatic, chlorinated, and aliphatic hydrocarbons are easily absorbed by the skin and can cause both short-term and long-term effects on the nervous system (Spandorfer, Curtiss, & Snyder, 2010). Epoxy paint contains isocyanates which outgas off for several hours to several days. Without proper ventilation, it can cause many adverse health effects (Benivia LLC, n.d.). Low odor or pleasant odor in solvents does not correlate with low VOC emissions. Deodorized solvents may be less toxic, but may still cause headaches and drowsiness. Solvents also can cause rapid deterioration of contact lenses (Spandorfer, Curtiss, & Snyder, 2010).
ORGANIC PAINT VS. INORGANIC PAINT 10 Organic Alternative to Inorganic Solvents Orange oil (d-Limonene) solvents are extracted from orange, as well as other citrus fruit, peels. It is readily available and can be purchased from hardware stores, or directly from the citrus industry. More powerful than mineral spirits or petrochemical solvents, this natural alternative contains no carcinogenic or neurotoxin hazards, and is biodegradable (Spandorfer, Curtiss, & Snyder, 2010). The orange oil is pressed out of orange peels and then distilled, forming food grade d-Limonene. After this process, the orange peals are conveyed to a steam extractor. When the steam is condensed, and there is oil oating on the surface, which is technical grade d-Limonene. d-Limonene has solubility properties that resemble the traditional solvents, but is natural and extremely safe (Florida Chemical Company, Inc., n.d.). Conclusion Inorganic manufactured paint causes great harm to the health of humans and the environment (Casa Verde Paint, 2011; Steen, 2006). VOCs in paint cause a range of health affects, from headaches to neurological disorders (Spandorfer, Curtiss, & Snyder, 2010), and contribute 9% of the pollutants greenhouse gases that are harming the environment (Casa Verde Paint, 2011). There are many organic alternatives, from homemade to organic manufactured paint. Natural paint binders include linseed oil, starch (from ower), egg yolk tempura, and casein (a protein found in milk). Casein binders specically adhere cleanly to many interior and exterior surfaces, including but not limited to bare wood, stone, bare drywall, and wallpaper (Steen, 2006). The most ORGANIC PAINT VS. INORGANIC PAINT 11 harmful part of inorganic manufactured paint is the solvent, which is what allows the paint to dry as it evaporates (Spandorfer, Curtiss, & Snyder, 2010). An organic alternative to these harmful solvents is orange oil (d-Limonene), which is more powerful than typical mineral spirits or petrochemical solvents, and contains no carcinogenic or neurotoxin hazards (Florida Chemical Company, Inc., n.d.). There are many healthy alternatives to these harmful chemicals that do not require vibrancy or texture to be compromised, which can lower the adverse effects on human health and the environment.
ORGANIC PAINT VS. INORGANIC PAINT 12 References Alan, E. [EarthPigmentsCompany]. (2011, May 3). Homemade Milk Paint. [Video File]. Retrieved from https://www.youtube.com/watch?v=nb2pE6Ge-0Q Benivia, LLC. (n.d.). Paint and your health. Environment, Health and Safety Online. Retrieved from http://www.ehso.com/ehshome/epoxypaint.htm Casa Verde Paint. (2011). Clearing the air: Understanding VOCs. Casa Verde Paint. Retrieved from http://www.casaverdepaint.com/clearing-the-air-understand.html Dex Media, Inc. (n.d.). What is organic paint? SuperTips. Retrieved from http:// www.superpages.com/supertips/organic-paint.html Elaun, S. (2011). What does organic, non-toxic or natural art supplies mean? Nature of Art for Kids. Retrieved from http://www.ecokidsart.com/what-does-organic-non- toxic-or-natural-art-supplies-mean/ Florida Chemical Company, Inc. (n.d.). What is d-limonene? Inside Florida Chemical. Retrieved from http://www.oridachemical.com/whatisd-limonene.htm Fraley, M. (2011). Recipe for the casein binder. Casein Painting. Retrieved from http:// caseinpainting.blogspot.com/2011/05/simple-recipe-for-casein-binder.html Lee, M. (2011). Skim milk powder vs. whey protein powder. Live Strong. Retrieved from http://www.livestrong.com/article/387006-skim-milk-powder-vs-whey/ Phelps, A. (2013). All natural food colors. Glob Colors. Retrieved from http:// globiton.com/blogs/blog?page=2 ORGANIC PAINT VS. INORGANIC PAINT 13 Spandorfer, M., Curtiss, D., & Snyder, J. (2010). Safe painting (ne art). Nontoxicprint. Retrieved from http://www.nontoxicprint.com/safepainting.htm Steen, B. (2006). Make safe, natural paint. Mother Earth News. Retrieved from http:// www.motherearthnews.com/diy/make-safe-natural-paint.aspx
ORGANIC PAINT VS. INORGANIC PAINT 14 Appendix A Figure A.1 Percent of Natural Substances in EarthPigmentsCompany Pigments All types of The Earth Pigments Company Pigments, except for Oxide Pigments which is 0% natural, are over 90% natural (EarthPigmentsCompany, 2011).
P e r c e n t a g e
o f
N a t u r a l
S u b s t a n c e s
( % ) 0 25 50 75 100 Pigment Type Natural Earth & Ocher Colonial Natural French Mineral Mayan Oxide "#$%& '$()&*+ ,- ".(/*$0