Beruflich Dokumente
Kultur Dokumente
VADE-MECUM
3. QUALITY
Rev. 2002
SECTION 3 QUALITY
Table of Contents
1. Chemical Characterization..................................................................... 3.1
1.1 Ignition Loss ................................................................................... 3.1
1.2 Silica Ratio...................................................................................... 3.1
1.3 Alumina-Iron Ratio ......................................................................... 3.1
1.4 Lime Saturation............................................................................... 3.1
1.5 Total Alkalies as Na2O .................................................................... 3.1
1.6 Percent Liquid ................................................................................. 3.2
1.7 Bogue Formulas .............................................................................. 3.2
1.8 Lafarge K 1450 Burnability Index.................................................... 3.2
1.9 Other Indicators............................................................................... 3.4
1.10 57 Clinker Average.......................................................................... 3.4
2. Particles Size Distribution....................................................................... 3.5
2.1 Rosin-Rammler Number.................................................................. 3.5
2.2 Specific Surface Area ...................................................................... 3.5
2.3 Blaine Surface Area......................................................................... 3.6
3. Grindability............................................................................................. 3.6
3.1 BB10 Test ....................................................................................... 3.6
3.2 Bond Formula ................................................................................. 3.7
3.3 Parameters Affecting the Clinker Grindability.................................. 3.7
4. Sulfate...................................................................................................... 3.8
4.1 Clinker Sulfates ............................................................................... 3.8
4.2 Sulfate Addition .............................................................................. 3.8
4.3 Water Spray .................................................................................. 3.10
5. Others Quality Issues............................................................................ 3.10
5.1 Cement Strength............................................................................ 3.10
5.2 Color ............................................................................................. 3.10
5.3 Microscopy ................................................................................... 3.11
6. 10 Basic Facts on Clinker...................................................................... 3.12
7. Raw Mix & Clinker Uniformity ........................................................... 3.13
7.1 TYTP Indicators............................................................................ 3.13
7.2 Lafarge Corp Results ..................................................................... 3.13
8. ASTM Standards .................................................................................. 3.14
Index - i
Rev. 2002
1. Chemical Characterization
SECTION 3 QUALITY
LSF vs C3S
120
R2 = 0.9485
100
S
(2.3 to 3.1)
A+ F
If SR high, hard to burn, low coating (wall
losses), poor clinker reactivity, higher SHC.
90
80
SR =
y = 0.3367x + 71.6
110
44
%CaO
56
100 * ( C + 0.75 M )
2.8 S + 1.18 A + 0.65 F
It takes MgO into account (when MgO <
2%).
KSt III =
LSF
100C
2.8 S + 1.1 A + 0.7 F
where:
A includes ( TiO 2 + P2 O 5 )
KSt I ( Kuhl ) =
70
60
0
20
40
A
(1.3 to 2.0 )
F
If AR high with low F then lower liquid
phase, poor viscosity.
AR =
30
25
20
15
10
5
0
-5 0
-10
-15
-20
100 120
bc vs C3S
y = -0.2734x + 21.552
2
R = 0.9606
bc
60 80
C3S
20
40
60
80
100 120
C3S
100C
LSF =
2.8 S + 1.18 A + 0.65 F
100 * ( 2.8 S + 1.65 A + 0.3 F C )
S + A+ F + C
It should range between 4 and +4
depending on ashes and quality target.
bc =
-
Total as Na 2 O eq = Na 2 O + 0.658 K 2 O
Rule of thumb
+ 0.1% Total Alkalies in clinker : -0.5 to -1MPa
at 28days.
3.1
Rev. 2002
SECTION 3 QUALITY
@ 1338C
A/F<1.38:
A/F>1.38 :
% liquid = 6.1 F + M + N + K
PL at 1338C influences the clinker granulation.
@ 1400C
% liquid = 2.95 A + 2.25 F + M + N + K
@ 1450C
% liquid = 3 A + 2.25 F + M + N + K
1450 C is most frequently used within Lafarge.
Optimum at 1450C: 25%.
@ 1470 C
% liquid = 1.13 C 3 A + 1.35 C 4 AF + M + N + K
b) Liquid phase impact
If liquid phase too high:
Clinker porosity
Grindability (harder)
1-day strength
If liquid phase too low:
C3S formation speed
Clinker granulation
Liquid Phase Constituent Impact
% free CAO
14
12
10
8
6
1%
18 % 5 %
b) SO3 combination
Step #1:
K 2O
< 1.176 not all SO3 combined as
If
SO3
K 2 SO4 then SO3 in K 2 SO4 = 0.85 K 2 O
Step #2:
Remaining SO3 = SO3 SO3 in K 2 SO4
Na 2 O
If
< 1.176 not all SO3
SO3 ( remaining )
combined as Na 2 SO4 :
SO3 in Na s SO4 = 1.292 Na 2 O
Step #3:
CaO combined with SO3
= 0.7 * (SO3 (SO3 in K 2 SO4 + SO3 in Na 2 SO4 ))
0%
5 % 18 % 1 %
5 % 18 % 0 %
a) Calculation
This index is representative of the ability of the raw
material to combine.
The sample is heated
(1000C/h) in a lab furnace at 1450 C for 30
minutes. After burning, the remaining free lime is
measured. The ability to combine is determined by
the reaction time of the following reaction:
C 2 S + C C3 S
4
2
0
1250 1300 1350 1400 1450 1500 1550
temperature C
3.2
Rev. 2002
8
6
4
2
0
-2
-4
-6
-8
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
00000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
Heat consumption
difference (%)
20
40
60
d[C ]
= k [C 2 S ] [C ]
dt
with:
[C2S] is the C 2 S concentration at t
[C] is the lime concentration at t
k is a constant (function of temp).
[C o ] [C ] = [C 2 S o ] [C 2 S ]
56
172
with:
[C] is the concentration of lime at t
-
[C ] + c = [C2 S ]
56
172
[ ]
[C ] + c . C o
1
K=
ln o
3.07 c
C + c [C ]
S + A+ F +C
= bc.
100 LOI
c
with:
[Co] = CaO - 1.87 SiO2
[C] = The remaining free lime in a lab test
in which the raw material is burned for 30
minutes at 1450C
Rule of thumb
K < 30:
30 < K < 45:
45 < K < 70:
70 < K < 100:
SECTION 3 QUALITY
Rules of thumb
K 2 SO4 improves the burnability;
+1% SO3 lower the combination temperature
by 60C;
+1%
increases the combination
K2O
temperature bu 35C;
increase from 2 to 3% of silica reject at 63
microns lower the K1450 by 30 points (cf
graph);
+ 0.3% CaF2 addition in the raw mix (or 0.23F
in the clinker) improves the K1450 by 10 to 60
points, lowering the burning temp by 30 to
130C. Unfortunately, it lengers the setting time
by 40min +/-20min (for+0.1%F in the clinker).
Impact of fineness
Free Lime = [C ] 1.89 + 0.48( LSF 100 ) +
2.84 (SR 1.8 ) + 0.27 Q45 + 0.12C125 + 0.12 Aq 45
where:
- Q45 = % quartz >45 m
-
Rule of thumb:
%(quartz>63m)<2%, %(quartz>45m)<2.5%
3.3
Rev. 2002
% free CaO
6
5
SECTION 3 QUALITY
% free CaO
6
5
25 %
3
10 %
25 %
0
1350
10 %
0
1350
1400
5%
1400
1450
1500
1550
temperature C
1450
1500
1550
temperature C
1.10
Hydraulic Module
S + A+ F
HM =
C+M
Cementation Index
2.8 S + 1.1 A + 0.7 F
Cl =
C + 1.4 M
57 Clinker Average
The results obtained from 57 production clinkers including 2 white cements and 4 Oil-Well cements are
reported below:
S/(A+F)
Minimum
Average
Maximum
Raw Mix
K 1450
21
75
324
2.1
2.9
7.8
2.1
Alite
%
45.6
66.0
81.1
Alite/C3S
Minimum
Average
Maximum
C3 S
%
43.0
61.9
75.9
Minimum
Average
Maximum
C4AF
%
0.8
9.3
16.8
Ferrit.
%
0.0
8.9
15.0
Minimum
Average
Maximum
S/(A+F)
A/F
Exc. HTS, SB
A/F
Exc. OW, SB
Liq. phase
At 1450 %
10.5
24.0
29.4
-0.8
5.3
10.2
Free CaO
%
0.05
0.68
2.2
0.15
0.93
1.91
C3 A
%
0.0
7.6
12.6
Alum.
%
0.7
5.2
11.0
P2O5
%
0.01
0.12
0.39
Mn2O3
%
0.01
0.06
0.19
kk SO3
%
0.2
0.84
2.5
0.6
2.0
11.6
0.7
Belite
%
0.7
15.0
35.0
Belite/C2S
0.9
1.07
1.4
C2 S
%
1.9
15.7
31.5
MgO
%
0.39
1.80S
4.53
Fluor
%
0.02
0.08
0.19
TiO2
%
0.10
0.23
0.39
2.7
3.6
Total K2O
%
0.25
0.74
1.40
1.7
2.9
nc
Exc.SO3
/s. alk. %
-0.16
0.29
1.86
3.4
Rev. 2002
SECTION 3 QUALITY
or
n ln
R = 100e
d
do
100
R
= n (In( d ) In( d o ))
R
-
Rules of thumb
RR# for high efficiency separator cement: 1.1 - 1.2
- RR# for Sturtevant circuit (raw or cement): 0.9 - 1.0
- RR# for open circuit cement: 0.8 - 0.9,
dO = 12-36 m
+ 0.15 point #RR increases the water demand by 2-3% (ref. Les Cahiers Techniques)
The following can calculate the Specific Surface Area (SSA). For particles assumed to be spheres:
4
S i = 4ri2
M i = ri3 p
3
Si = the particle surface area
-
Str =
3 M tr
ri
Mtr = ni *
4 3
ri
3
3.5
Rev. 2002
16
j =0
R j R j +1
d j + d j +1
do = 0.1 m
d6 = 4 m
d1 = 0.3 m
d7 = 6 m
Ri
d2 = 1 m
d8 = 8 m
- di =
d3 = 1.5 m
d9 = 12 m
d4 = 2 m
d10 = 16 m
d5 = 3 m
d11 = 24 m
The 0-3 m fraction of normal Portland cement accounts for 60% of total surface.
-
6f
SSA =
SECTION 3 QUALITY
=
=
=
d12= 48 m
d13 = 64 m
d14 = 96 m
d15 = 128 m
d16 = 196 m
SSB = Blaine Surface Area (in cm2/g). Its a permeability test. SSB is inversely proportional to the ability to
pass air through a bed of particles. The correlation between calculated SSA and SSB is:
SSA = 807 + 1.2 * SSB
For cements with n=1 Anselm found:
where:
4
36.8 * 10
- do, n Rosin-Rammler distribution
SSA =
- = specific density = 3.2 x103 kg/m3
do * n *
3. Grindability
3.1 BB10 Test
Idea:
Correlate the number of revolutions of a lab mill for a given fineness with the industrial energy to obtain the
same fineness. The material is crushed to everything passing 3.15 mm. The number of mill revolutions is
measured to obtain a given fineness. Revolutions are converted to industrial power consumption.
Lab Mill Characteristics:
Diameter: 40 cm
Length: 12 cm
Speed: 55 rpm
Ball volume load: 14 %
Ball weight: 10 kg
3.6
Rev. 2002
SECTION 3 QUALITY
Lafarge Data
25 Canadian clinkers @ 3500 Blaine averaged 55.7 kWh/t and 35 French averaged 50.7 kWh/t. Typical
results are 48-60 kWh/t.
BB10
kWh/t
Minimum
Average
Maximum
10
d p 80
10
d f 80
44.5
Wi =
Developed to predict energy requirements of 2.44m diameter, wet, closed circuit, ball mill at a fineness of
either 65 mesh (220 m) or 100 mesh(150 m).
Pre-crush feed to #6 (3.35 mm). Maintain 700g sample in test mill. Turn mill 100-150 rev.
Remove undersize (dp100 65 or 100 mesh) and replace with fresh feed (300 400 g). 1st cycle is now
completed. Repeat procedure until steady state is reached. Typically 6-8 cycles so that 200 g are removed at
each cycle, which equals 250% circulating load or 30% of P.
In the statistical study of the 57 clinkers, grinding energy was correlated with different parameters.
1 point increase of
a variation of
W250 (kWh/t)
W300
W350
W400
produces
C3S
-0.3
-0.5
-0.6
-0.7
4
4
5
5
CaOl
(%)
-0.9
D75 alite
(m)
0.1
0.1
0.2
0.2
Alite C3S
x100
-0.1
-0.2
-0.3
3.7
Rev. 2002
SECTION 3 QUALITY
4. Sulfate
4.1 Clinker Sulfates
alkali sulfates
Cubic C3A
orthorhombic
C3A
alkali
sulfates
Cubic C 3A
alkali
sulfates
Cubic C3 A
Clinker harder
to grind
On the basis of the content of sulfur with respect to alkalies, and the relative proportions of
sodium and potassium, alkali sulfates may be found under different forms:
-
Gypsum and/or anhydrite - sulfates are added to control the setting process of the cement, primarily the rapid
setting of the C3A component.
a) False set:
Early development of stiffness without the evolution of much heat. It can be dispelled and plasticity
regained by further mixing without the addition of water [also called "grap set", "premature stiffening",
"hesitation set", "rubber set"].
b) Flash set:
Early development of stiffness usually with considerable evolution of heat. It cannot be dispelled nor
plasticity regained by further mixing without adding water [also called "quick set"]. Reaction is:
C 3 A + nH 2 O + C C 4 A( H 2 O )n .
3.8
Rev. 2002
SECTION 3 QUALITY
Components
Hemihydrate and the anhydrites are the dehydrated forms of gypsum.
CaSO4 . 2 H 2 O
- Gypsum
- -hemihydrate (plaster of Paris)
CaSO4 .0.5 H 2 O
- Soluble anhydrite ( CaSO4 .III)
CaSO4 . ( 0.001 _ 0.5 ) H 2 O
- Insoluble (natural) anhydrite
CaSO4
They react differently than gypsum when added to cement.
Reactions
4.5
4
Sulfate solubility
2.5
2
80
% Dehydr.
SO3 solution
(g/l)
100
Gypsum
Hemihydrate
Soluble Anhydrite
Natural Anhydrite
1.5
1
0.
0
1 2. 6 1 2 3
Time - Minutes
60
40
20
0
00 00 00 0 00
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
0000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
0000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
3.5
60
80
100
120
140
Temp. C
160
180
Dehydration in the milling process can be thought as beginning at about 80 C. However, gypsum
dehydration is also a function of the time and % humidity of the surrounding atmosphere. Hemihydrate
reacts differently than gypsum or anhydrite when water is added to cement, due to the differences in
solubility. In the case of too much hemihydrate, which dissolves very quickly and in substantial quantities in
the mix water, false set will occur. While too much hemihydrate will cause false set, not having enough SO3
available in solution will cause much more serious flash set.
Available
sulphate in
solution
Low
C3A
Hydration time
10 min
Normal
set
set
Accelerated
set
set
set
Flash
set
Low
SO3
set
Low
C3A
workable
High
SO3
workable
High
C3A
3 hours
Low
SO3
workable
High
C3A
1 hour
Type
of
set
set
set
False
set
High
SO3
set
set
set
3.9
Rev. 2002
SECTION 3 QUALITY
Optimum sulfate
One method to control the mill temperature and thus gypsum dehydration is through the use of water spray.
For reasons of cement quality (C3S hydration), the water vapor dew-point temperature in the mill air must
not exceed about 70 C. The decomposition enthalpy of crystalline water in gypsum is much less (628
kJ/kg) than the evaporation enthalpy of water (2257 kJ/kg).
Thus theoretically one can:
Reduce Preliminary Hydration - use anhydrite (no crystalline water) instead of gypsum and keep the
water spray constant. This will decrease the water content of the air. The mill outlet temperature will
increase in this case.
Reduce The Mill Outlet Temperature - use anhydrite and increase the water spray, keeping the dew-point
constant. The preliminary hydration will remain the same because the water content of the air remains
constant.
Reduce Temperature and Preliminary Hydration - use anhydrite and substitute some, but not all, of the
crystalline water for more water spray.
Theoretical water required to totally hydrate the cement: 35% weight of cement.
Warning: Here, MPa are French standard (1.45 French MPa= 1 US/Can MPa)
Parameters influencing the cement strength
1-d fc 2-dfc
A variation of? Mpa
Strength is produced by (MPa) (MPa)
an increase of 1 point of:
Sol Na2Eq (%)
Tot Na2Eq (%)
C3S (%)
C2S(%)
C3A (%)
C4AF (%)
MgO (%)
SO3/totAlk Excess
FcaO (%)
D75Belite (m)
7-d fc
(MPa)
28-d fc
(MPa)
60
10
10
0.1
0.3
0.4
0.5
0.3
0.7
-1.1
1.1
1.1
-0.2
-1.0
1.3
-0.8
-10
0.6
0.5
-0.3
C2S
50
40
30
-0.5
-0.6
1.5
20
-0.3
C12A7
C3A
10
0
-0.2
C3S
70
C4AF
7 28
90
180
360 days
5.2 Color
If % Fe 2 O3 is combined with Blaine specific surface (m2/kg), it is possible to explain 97% of the observed
color variations.
3.10
Rev. 2002
SECTION 3 QUALITY
5.3 Microscopy
a) Interpretation
Case
1) Raw Mix
Raw mix fineness
Raw Mix
Homogeneity
Lime saturation
Of raw mix
Raw mix chemistry
Observations
Siliceous rejects
Shaly rejects
Calcareous rejects
Heterogenous
Homogenous
Overdosage
Underdosage
Alkalies
2) Burning
Under burning
Low Temperature
Rapid Zone Passage
Over burning
High Temperature
Slow zone passage at
high To
Reduced
Atmosphere
3) Cooling
Cooling rate
alite :
belite :
10
8
6
4
2
0
+ 0,4% 1
Sol.Na O
2
Equiv.
1
-1%1
Norm al
Exc SO 3 ./ hard
T ot. alk.
burning
+1
1%
Free CaO
+1
4%
C 3A
3.11
Rev. 2002
SECTION 3 QUALITY
9)
Clinker alkali
content
Clinker alkalies
and sulfates
Alkali saturation
3.12
Rev. 2002
SECTION 3 QUALITY
1
N
i =1
(C 3 S i C 3 ST )2
N
(C3 S i C3 S average )2
CUI .(clkC 3S ) =
SO3
KSUI =
100
fCaO.UI =
1 + x SO3
1
N
i =1
Target < 16
Target < 10
fCaO
Target < 1
KFUI measures the ability to follow a raw mix C3S target. Clinker uniformity indicators measure the
variation from an average.
Use first scheduled grab sample per day, with no calculation if there is less than 10 days production.
Exception: Lafarge Corp. recommends KFUI calculation based on all samples.
Indicators are calculated on a monthly and annual (12-month rolling average) basis for kiln main product
only. The 12MRA KFUI is an average of the monthly results weighted by clinker tonnage, while clinker
12MRAs use 12-month variances and averages (C3S, SO3, f-CaO).
Combining indices for an aggregate plant index is done by weighting clinker tonnage.
BTH
BFD
ESW
KAM
RMD
SEA
STC
WSK
All CDN
ALP
DAV
FDA
JPA
PDG
SCK
WHL
All U.S.
All N.A.
Kiln Pf
1998
86.1
87.7
94.7
91.5
79.0
<10
1999
11.8
12.4
6.8
13.3
18.3
19.2
12.6
5.7
11.5
11.6
9.5
14.3
20.8
5.4
18.7
7.6
12.4
12.0
KSUI
1998
14.1
9.5
7.1
6.2
13.2
15.0
12.2
12.0
19.1
11.8
15.5
27.8
19.9
23.4
16.1
19.0
16.2
3.13
Rev. 2002
SECTION 3 QUALITY
8. ASTM Standards
Comparison of Portland Cement Specifications
Updated - Nov. 21, 2000
CHEMICAL REQUIREMENTS
ASTM
NORMAL
(I/10)
AASHTO
MODERATE (II/20)
CSA
ASTM
AASHTO
Si02, min., %
20.0
6.0
ASTM
AASHTO
CSA (a)
CSA
SULFATE RESISTAT
(V/50)
ASTM
AASHTO
CSA
6.0
Fe203, max., %
CSA
LOW HEAT
(IV/40)
ASTM
AASHTO
20.0
Al203, max., %
6.0
Mg0, max., %
6.0
6.5
6.5
6.0
6.0
5.0
6.0
6.0
5.0
6.0
6.0
5.0
6.0
6.0
5.0
6.0
6.0
5.0
2.5
3.0
3.0
3.0
3.0
3.0
3.0
3.5
3.5
3.5
2.3
2.3
2.5
2.3
2.3
3.5
3.5
3.5
(g)
(g)
(g)
4.5
4.5
4.5
(g)
(g)
(g)
(g)
(g)
(g)
3.0
3.0
3.0 (e)
3.0
3.0
3.0
3.0
3.0
3.0 (e)
3.0
3.0
3.0
3.0
3.0
3.0
0.75
0.75
1.5
0.75
0.75
0.7
0.75
0.75
1.5
0.7
0.75
0.75
0.7
5.5
5 (k)
5 (k)
3.5
C3S, max., %
0.75
C2S, min., %
0.75
35 (h)
55
35 (h)
40 (h)
0.60 (b)
0.60 (b)
40 (h)
15
15
7 (h)
7 (h)
0.60 (b)
0.60 (b)
0.60 (b)
0.60 (b)
7.5
(C4AF+2(C3A), or
(C4AF+C2F) as applicable, max., %
Na20+0.658 K20, max. %
25 (k)
0.60 (b)
0.60 (b)
Limestone, max., %
5 (a)
25 (k)
0.60 (b)
0.60 (b)
5 (a)
NORMAL
(I/10)
AASHTO
160
150
280
PHYSICAL REQUIREMENTS
CSA
ASTM
MODERATE
(II/20)
AASHTO
CSA
ASTM
HIGH EARLY
(III/30)
AASHTO
CSA (a)
ASTM
LOW HEAT
(IV/40)
AASHTO
CSA
ASTM
SULFATE RESISTAT
(V/50)
AASHTO
CSA
230
260
150
160
230
280
260
150
160
230
280
260
150
230
280
260
420
420
420
420
280
280
280
280
3.14
SECTION 3 QUALITY
400
400
72
400
400
72
72
0.80
0.80
1.0
0.80
0.80
1.0
0.80
0.80
1.0
0.80
0.80
1.0
0.80
0.80
1.0
45
45
45
45
45
60
45
45
45
45
45
90
45
45
60
375
375
360
375
375
360
375
375
250
375
375
360
375
375
360
Vicat Test -
60
60
60
60
60
60
60
60
60
60
600
600
600
600
600
600
600
600
600
600
12
12
12
12
12
12
12
12
12
12
1740
(12.0)
1800 (12.4)
1-day minimum
1-day maximum
13.5 MPa
36 MPa (v)
3-day minimum
3-day maximum
7-day minimum
7-day maximum
28-day minimum
28-day maximum
28-day, C.V., max., %
14.5
MPa
32.5
MPa
20.0
MPa
40.0
MPa
26.5
MPa
51.0
MPa
8
1450(10.0)
2470(12.0)
1500(10.3)
2500 (17.2)
14.5
MPa
32.5
MPa
20.0
MPa
40.0
MPa
26.5
MPa
51.0
MPa
8
24.0 MPa
14.5 MPa
32.5 MPa
(v)
20.0 MPa
43.0 MPa
(v)
1020(7.0)
38.0 MPa
1000 (6.9)
25.0
MPa
3050
(21.0)
3000 (20.7)
60.0 MPa
(v)
51.0 MPa
(v)
8
91-day minimum
40.0 MPa
(v)
26.5 MPa
33.0
MPa
Heat of Hydration:
7-day,
max.,
kJ/kg
290 (70)
(p)
(cal/g)
28-day, max., kJ/kg
(cal/g)
Paste False Set (early stiffening),
min., %
Sulfate Expansion, (j):
14-day, max. %
50 (x)
50 (x)
0.020
0.020
290(70) (p)
50 (x)
0.020
50 (x)
0.020
0.020
300 (s)
50 (x)
0.020
50 (v)
0.020
0.020
250 (60)
(q)
290 (70)
(q)
50 (v)
0.020
250 (60)
290 (70)
0.020
0.020
275
50 (v)
50 (v)
0.020
50 (v)
0.020
0.020
0.040 (t)
0.040 (t)
Sulfate Resistance:
14-day, max., %
0.050 (s)
0.035
3.15
SECTION 3 QUALITY
CSA A5 recognizes the existence of an optimum carbonate addition for some Portland cements. Therefore, a maximum of 5% addition of
limestone is permitted for Type 10 and Type 30 cement.
(b)
This optional limit may be specified when the cement is to be used in concrete with aggregates that may be deleteriously reactive.
(d)
(e)
For C3A calculation, ASTM, AASHTO and CSA use Al2O3 only without TiO2 and P2O5.
A loss on ignition of 3.5% is allowed for Type 10 and Type 30 Portland cements provided that such cements when tested in accordance with
the CSA Standard, but at a furnace temperature of 550oC, show a loss in mass of no more than 3.0%.
(f)
(g)
(h)
(i)
(j)
(k)
(n)
The optional limit for heat of hydration shall not be requested when this optional limit is specified.
Not applicable.
Does not apply when the heat of hydration limit is specified.
ASTM & AASHTO allow 16-22% air in Types IA, IIA, IIIA.
Required if SO3 exceeds the table limits.
Does not apply when the sulfate resistance limit is specified.
Either of the two alternative fineness methods may be used at the option of the testing laboratory. However, in the case of ASTM, the
turbidimeter is the referee method; average value shall be determined on the last consecutive five samples from a source.
(o)
The purchaser should specify the type of setting time test required. In case he does not so specify, the requirements of the Vicat test only
shall govern; CSA only specifies Vicat test.
The optional limit for the sum of the C3S and C3A shall not be requested when this optional limit is requested. These strength requirements
apply when either heat of hydration or the sum of C3S and C3A requirements are requested.
(p)
(q)
When heat of hydration limit is specified, it shall be instead of the limits of C3S, C2S and C3A.
(s)
The requirement of either heat of hydration or sulfate resistance may be specified at the option of the purchaser.
(t)
Optional, it shall be instead of the limits of C3A and C4AF+2C3A.
(v)
This value indicates requirement to be specified at the option of the purchaser.
CTS - Products and Quality,
Nov. 21, 2000
3.16
Ia
II
4000
2200
50
50
4000
2200
50
50
70
-
70
-
4000
3200
IIa
III
IIIa
IV
50
50
4000
2200
50
4000
2200
50
60
70
0.045
4000 3200
3200* 2560*
-
Apply when either the heat of hydration or C3S + C3A are specified.
**
I
12
-
Ia
22
16
II
12
-
IIa
22
16
III
12
-
IIIa
22
16
IV
12
-
V
12
-
160
280
160
280
160
280
160
280
160
280
160
280
1800
1450
1450
2800
1200
2250
-
1200
800*
2000
1350
-
1800
3500
2800
-
1500
1000*
2500
1700
-
1000
2200
2500
3000
60
10
45
8
60
10
45
8
60
10
45
8
60
10
45
8
60
10
45
8
60
10
45
8
60
10
45
8
60
10
45
8
II
Iia
-
III
IIIa
8
IV
Iva
-
V
Va
-
C3 S
C3 A + C3 S
58
0.60
0.60
0.60
0.60
Cement Type
C3 A
Na2O + 0.658 K 2O
Remarks
Moderate sulphate resistance
3.17
SECTION 3 QUALITY
ASTM C-1157-94a
GU
HE
MS
HS
ASTM C-595-94a
MH
LH
L(SM)
IS
<25
25-70
AASHTO M240-92
>70
Pozzolan content, %
L(PM)
15-40
I(SM)
IS
<25
<15
IP
25-70
CSA-A362-93
>70
>40?
L(PM)
15-40
10SM
10S
<25
<15
IP
25-70
10F
<15
>40?
10FM
15-40
10SF
<10
CHEMICAL REQUIREMENTS
SiO2, min., %
Al 2O3, max., %
CaO, max., %
6.0
6.0
6.0
5.0
5.0
5.0
4.0 (d)
4.0 (d)
4.0 (d)
4.0 (d)
4.0 (d)
4.0 (d)
MgO, max., %
SO3, max., %
3.0 (d)
3.0 (d)
4.0 (d)
3.0 (d)
3.0 (d)
4.0 (d)
5.0
3.0 (e)
3.0 (e)
Sulfide S, max, %
2.0
2.0
2.0
2.0
2.0
2.0
1.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
1.0
1.0
4.0
1.0
1.0
4.0
1.0
5.0
3.0 (e)
3.0 (e)
4.5
6.0
3.5
2.0
5.0
3.0 (e)
1.0
0.03 (l)
5.0
5.0
5.0
5.0
5.0
5.0
0.03 (l)
3.18
SECTION 3 QUALITY
Heat of hydration:
7-day, max., kJ/kg (cal/g)
ASTM C-1157-94a
MS
HS
MH
GU
HE
b
b
b
b
b
b
b
b
0.80
0.80
0.80
0.80
0.80
0.80
45
7
b
45
7
b
45
7
b
ASTM C-595-94a
S
L(PM)
IP
LH
L(SM)
IS
b
b
b
b
b
b
b
b
b
b
b
b
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.20
0.80
0.20
0.80
0.20
45
7
b
45
7
b
45
7
b
45
7
12
45
7
12
45
7
12
AASHTO M240-92
S
L(PM)
IP
I(SM)
IS
b
b
b
b
b
b
b
b
b
b
b
b
0.80
0.20
0.80
0.20
0.80
0.20
0.50
0.20
0.50
0.20
0.50
0.20
45
7
12
45
7
12
45
7
12
45
7
12
45
7
12
45
7
12
CSA-A362-93
10S 10FM 10F
10SF
24.0
24.0
24.0
24.0
24.0
0.50
0.20
0.8
0.8
0.8
0.8
0.8
45
7
12
45
6
45
8
45
6
45
8
45
6
12.0
9.0
12.0
9.0
12.0
18.0
15.0
18.0
15.0
13.0
26.0
26.0
(j)
26.0
26.0
(j)
26.0
10SM
b
b
b
b
0.50
0.20
0.50
0.20
45
7
12
45
7
12
12
(1740)
12
24
10
8
7
12.4
12.4
12.4
12.4
12.4
12.4
12.4
12.4
(1740) (3480) (1450) (1160) (1015)
(1800) (1800)
(1800) (1800)
(1800) (1800)
(1800) (1800)
20
17
15
12
7
19.3
19.3
4.1
19.3
19.3
10.3
19.3
19.3
4.1
19.3
19.3
10.3
(2900)
(2465) (2175) (1740) (1015) (2800) (2800) (600) (2800) (2800) (1500) (2800) (2800) (600) (2800) (2800) (1500)
28
28
20
22
17
24.1
24.1
10.3
24.1
24.1
20.7
24.1
24.1
10.3
24.1
24.1
20.7
(4060)
(4060) (2900) (3190) (2465) (3500) (3500) (1500) (3500) (3500) (3000) (3500) (3500) (1500) (3500) (3500) (3000)
(m)
(m)
(m)
290
(70)
250
(60)
290
(70)
293
(70)
(f)
335
(80)
(f)
293
(70)
(f)
335
(80)
(f)
293
(70)
(f)
335
(80)
(f)
293
(70)
(f)
335
(80)
(f)
251
(60)
(f)
293
(70)
(f)
293
(70)
(f)
335
(80)
(f)
293
(70)
(f)
335
(80)
(f)
293
(70)
(f)
335
(80)
(f)
293
(70)
(f)
335
(80)
(f)
251
(60)
(f)
293
(70)
(f)
64
300
(g)
64
0.15
300
(g)
0.15
3.19
SECTION 3 QUALITY
GU
HE
PHYSICAL REQUIREMENTS
Mortar expansion(I):
14-day, max. %
8-week, max. %
Sulfate resistance at 6 months:
Moderate resistance, max., %
0.020
0.060
0.020
0.060
ASTM C-1157-94a
MS
HS
MH
0.020
0.060
0.020
0.060
0.10
0.05
0.020
0.060
LH
L(SM)
IS
0.020
0.060
0.020
0.060
0.020
0.060
ASTM C-595-94a
S
L(PM)
IP
0.020
0.060
0.020
0.060
0.020
0.060
AASHTO M240-92
S
L(PM)
IP
I(SM)
IS
0.020
0.060
0.020
0.060
0.020
0.060
0.020
0.060
0.020
0.060
0.020
0.060
10SM
CSA-A362-93
10S 10FM 10F
10SF
0.020
0.060
0.10(k 0.10(k 0.10(k 0.10(k 0.10(k
)
)
)
)
)
0.05(k 0.05(k 0.05(k 0.05(k 0.05(k
)
)
)
)
)
3.20