EXP 1)

2.8.2 Materials Required:

3 (wt%/vol) SLS surfactant, stirring motor, L shaped Baffles, support for baffles,
spinning disc, Standardized NaOH solution (0.1 mol/L) in 4 litre distilled water,
Phenolphthalein indicator solution,

2-50 mL Burets, Universal Stand, Titration

Clamp, 250 mL Erlenmeyer flask, 25 ml HCl for each titration, H2S gas from the
kipps apparatus

2.8.3 Experimental procedure:

1. 0.163 Mol/L NaOH solution was taken in cylinder. H2S gas was taken from
the Kipps apparatus.
2. Add surfactant to the NaOH solution and Stirrer was started for reaction.
3. After every 5 min sample was taken for 1 hour and titration was done with
HCl solution to finding out the concentration of NaOH with time.
2.8.4 Observations:
Table1:
S.No

Time (min)

Vol (ml)

Conc (Mol/Lit.)

5.5

0.163

10

5.7

0.157

15

5.8

0.155

20

5.9

0.152

25

0.150

30

6.1

0.147

35

6.5

0.138

40

6.6

0.136

45

6.7

0.134

10

50

6.8

0.132

11

55

6.8

0.132

12

60

6.9

0.130

Plot1:
0.18
0.16
0.14

Conc.

0.12
0.1
0.08
0.06
0.04
0.02
0
5

10

15

20

25

30

35

40

45

50

55

60

Time (min)

EXP 2)
Table2:
S.No

Time (min)

Vol (ml)

Conc (Mol/Lit.)

5.5

0.154

10

5.6

0.152

15

5.6

0.152

20

5.7

0.149

25

5.9

0.144

30

5.8

0.146

35

6.0

0.142

40

6.1

0.139

45

6.3

0.135

10

50

6.4

0.133

11

55

6.7

0.127

12

60

6.8

0.125

Plot2
0.18
0.16
0.14
Conc.

0.12
0.1
0.08
0.06
0.04
0.02
0
5

10

15

20

25

30

35

40

45

50

55

60

Time (min)

EXP 3)
Table3:
S.No

Time (min)

Vol (ml)

Conc (Mol/Lit.)

4.8

0.177

10

4.9

0.173

15

4.9

0.173

20

0.170

25

5.2

0.163

30

5.3

0.160

35

5.2

0.163

40

5.3

0.160

45

5.4

0.157

10

50

5.6

0.152

11

55

5.6

0.152

12

60

5.8

0.146

Plot 3:

0.2

0.18
0.16

Conc.

0.14
0.12
0.1
0.08
0.06
0.04
0.02
0
5

10

15

20

25

30

35

40

45

50

55

60

Time (min)

EXP 4)
Table4:
S.No

Plot4:

Time (min)

Vol (ml)

Conc (Mol/Lit.)

4.8

0.177

10

4.8

0.177

15

4.9

0.173

20

5.0

0.170

25

5.1

0.166

30

5.2

0.163

35

5.3

0.160

40

5.2

0.163

45

5.3

0.160

10

50

5.5

0.154

11

55

5.6

0.153

12

60

5.7

0.149

0.18
0.175
0.17
Conc.

0.165
0.16
0.155
0.15
0.145
0.14
0.135
5

10

15

20

25

30

35

40

45

50

55

60

Time (min)

EXP 5)
S.No

Time (min)

Vol (ml)

Conc (Mol/Lit.)

2.5

0.340

10

2.6

0.327

15

2.6

0.327

20

2.7

0.315

25

2.8

0.303

30

2.9

0.293

35

2.9

0.293

40

3.0

0.283

45

3.1

0.274

10

50

3.0

0.283

11

55

3.1

0.274

12

60

3.2

0.265