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Membranes for Post-Combustion Carbon Capture --- Current state and Future Prospects. DOE Target by 2020 - have technologies that achieve: 90% CO 2 capture 35% increase in COE (cost of electricity)
Membranes for Post-Combustion Carbon Capture --- Current state and Future Prospects. DOE Target by 2020 - have technologies that achieve: 90% CO 2 capture 35% increase in COE (cost of electricity)
Membranes for Post-Combustion Carbon Capture --- Current state and Future Prospects. DOE Target by 2020 - have technologies that achieve: 90% CO 2 capture 35% increase in COE (cost of electricity)
Da-Ming Wang a,c , Chien-Chieh Hu b,c , Kueir-Rarn Lee b,c
Kuo-Lun Tung a,c , Juin-Yih Lai b,c
a Department of Chemical Engineering, National Taiwan University b Department of Chemical Engineering, Chung Yuan University c R&D Center for Membrane Technology, Chung Yuan University Carbon Capture DOE Target By 2020 have available for commercial deployment, technologies that achieve: 90% CO 2 capture < 35% increase in COE (cost of electricity) Source: DOE Fossil Energy (FE) about US$ 25/ ton CO2 Economics of Carbon Capture by MEA absorption Source: G.T. Rochelle, Science, 325,2009 Carbon Capture by Membranes Mechanisms for Membrane Gas Separation Source: Basic research needs for carbon capture: beyond 2020 Advantages of Membrane Processes Lower energy use because no phase change occurs during separation
Small footprint
Characterization of Membrane Performance d ) ( / , , A perm A feed A A p p P j d ) ( / , , B perm B feed B B p p P j d d / A P permeance of A d / B P permeance of B B A P P / membrane selectivity of A over B Membrane Development Source: Merkel et al., Journal of Membrane Science, 359, 2010 Membrane Development Source: Merkel et al., Journal of Membrane Science, 359, 2010 Membrane Development Poly(ether-block-ester) less than 50 nm thick silica membrane zeolite membrane slicalite zeolite membrane SAPO-34 carbon molecular sieve metal organic framework MgMOF-74 30000 gpu, selctivity 30 Current state of CO2 capture membrane in CMT under the support of Nation S&T program-Energy
CMT-1 membrane Selectivity=120 Permeance=500gpu
CMT-3 membrane Selectivity=22 Permeance=1100gpu CMT-2 membrane Selectivity=56 Permeance=590gpu CMT- 1 CMT- 2 CMT- 3 Challenge of High Throughput For a 600 MW plant, 90% CO 2 capture, 11.6 % CO 2 in the feed, 2.1 million m 2 membranes (1000 gpu, selectivity 50) are needed Source: Merkel et al., Journal of Membrane Science, 359, 2010 Challenge of High Throughput Membrane modules with high packing density are needed
Plate and Frame ---- 200 m 2 /m 3
Hollow Fiber ---- 10,000 m 2 /m 3
1 million m 2 corresponds to 1000 m 3
Asymmetric composite membrane Continuous flat-sheet membrane fabrication facility U.S. patent 7,823,530 B2 2010 Hollow fiber fabrication facility Future perspective --- I Develop membranes with higher CO 2 permeance Source: Merkel et al., Journal of Membrane Science, 359, 2010 to meet DOE target Future perspective --- II Lower the membrane cost To meet DOE target 3000 gpu selectivity 100 US$ 30/m 2 Future perspective --- III Efficient process design enrich CO2 in the flue gas from 12% to 18% reduce membrane area from 2.1 to 1.3 million m 2
Source: Merkel et al., Journal of Membrane Science, 359, 2010 Future perspective --- IV To reduce footprint, hollow fiber modules are needed Large-scale demonstration is needed The largest membrane unit under test is 20 tons CO 2 /day Source: CO2 capture technology, Global CCS Institute Membrane contactor for CO2 capture Hydrophobic hollow-fiber membranes are used to provide the gas-liquid contact surface area Set up a membrane contactor unit capacity 5 m 3 /h Stretching system Preparation of PP hollow-fiber membranes Research work at R&D center for membrane technology, Chung Yuan University II Current State and future perspective of CO 2 capture by membrane processes I Conclusions Acknowledgement National Science and Technology Program -- Energy Ministry of Economic Affairs, Taiwan LCY company, Taiwan R&D Center for Membrane Technology Awarded CoE Program on Membrane Technology from Ministry of Education in 2006 R&D enter for embrane echnology