Algae-based Biofuels as Substitute for Environmentally
Friendly Fuel Fource to Cover Nations Demands of Energy
The consumption and demand of energy in the world is exploding, but proven fuel reserves especially fossil fuel which usually consumed daily has been declined ever since. As petroleum fuel costs rise and supplies dwindle, alternatives fuels will become more attractive to both investors and consumer. World is forced to search for alternatives concerning its energy supply because the upcoming shortage of fossil fuels. Today, huge efforts are made to maximize the productivity of biofuel and identify new species of organism to fulfill the future demand of energy. BP's "Statistical Review of World Energy" published in mid 2013 says that the world has in reserves 1669 billion barrels of crude oil, and by 2065 there will be no reserves of crude oil. This fact leads to a quest for an alternative source of energy. One of the alternative way to substitute fossil fuel energy is biofuel. According to Biofuels Association of Australia, Biofuels are liquid fuels which have been derived from other materials such as waste plant and animal matter. There are two main types of biofuels bioethanol, to substitute gasoline and biodiesel, to substitute diesel or solar. The first generation biodiesel markets in Europe and the US have reached impressive biodiesel production capacity levels, but remain constrained by feedstock availability. In 2014, Indonesian biodiesel producers may export 2.2 million kilolitres of biodiesel, up from 1.833 million kilolitres last year, and the production capacity is likely to hit 8.8 million kilolitres in 2015, to support the demands from its biggest biodiesel export customer, the European Union. Biofuel can be made from various resource, either land-based or water-based. The potential resource from water-based to make biofuel is very profitable since the start of the Aquatic Species Program (ASP). One of attractive water-based resource is algae, algae usage for biofuel production has become an important issue. Beside that, the technology for making biofuel for algae is currently continous developing. The utilization of algae is seen as one of these possible alternatives. Algae is a feedstock that have certain advantages when compared with land-based feedstock. Under favorable conditions, the growth rate of algae is estimated to be 510-times higher compared with land-based crops, implying a higher production rate of theoretically convertible biomass. Additionally, certain species may have a high fraction of lipids or carbohydrates of up to 7080 wt%. The algae that are used in biodiesel production are usually aquatic unicellular green algae, which has a photosynthetic eukaryote characterized by high growth rates and high population densities. Additionally, green algae can have huge lipid content, frequently over 50%. This high yield, high density biomass is ideal for intensive agriculture and may be an excellent source for biodiesel production. Quality of the alga to produced biofuel depending on its composition differs in terms of lipid, starch and protein content. Nannochloropsis sp., is one of the superior candidate for making biofuel. It is unicellular, non- motile, of about 2-5m cell size, golden green algae belonging to the class Eustigmatophyceae. This microalgae is one of the most interesting phytoplankton in the field of marine biotechnology because it represents a valuable source of various natural products which have several applications. Due to their high oil content, Nannochloropsis sp. was used as raw materials for biofuel production. Oil content of Nannochloropsis sp. based on dry weight is up to 68%. World usage of algae to make biofuel is quite promising, seen from the fact that current technology of algae processing to biofuel could produce the fuel with price as low as $1.27 per gallon, compared to gasoline skyrocketing to more than $4 a gallon in 2008, this algae biofuel is tremendously promising. The highly efficient technology to make biofuel from algae, is processed through hydrothermal liquefaction (HTL) of algae in a continous-flow reactor. This process would results on high levels of carbon conversion to gravity sp.earable biocrude product at relatively low temperature (350 o C), pressurized at 20 MPa. High conversions would be obtained even with high slurry feed concentrations of up to 35% wt of dry solids. The product after hyrotreating with temperature 105-401 o C would have the range of carbon %wt dry up to 84-85%, and hydrogen 13-15%. This Viewed from the side effectiveness fuel combustion, the usage of biofuel which has a higher oxygen content (usually 10 to 12 percent) than petroleum diesel. This biofuel source is urgently in need to be developed, especially in Indonesia, which already has a great start on producing biofuels as alternative source of energy. Keyword: algae, biofuels, biodiesels, hydrothermal liquefaction, Nannochloropsis sp.,