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= -
h (3)
Although Schrdinger had shown that his theory was mathematically equivalent to
matrix mechanics, [3] he had not revealed the direct relations between wave
mechanics and matrix mechanics.
In fact, from (3) and (37)-(38),
2
2
2
2
1 1
4 2 2
1 2
1 3
2
4 2 2
2 1 3
1 1
1
2
1 1
2
2
1
( , 0)
2
x
x
s s s
x xe
x x e
s
x s
a
a
y p a y
a
y p a y y
a a
y y y
a
- -
- -
- +
= =
= = +
-
=
(4)
According to the inverse law of matrix multiplication, [1] (4) can be represented as
[ ] [ ]
1 2 1 1 2 1
s s s s
x y y y y y y y y
- -
=
0 1 0 0
1 0 0 0
1
2
0 0 0 1
0 0 1 0
s
s
a
-
-
(5)
The square matrix in (5) is just (1).
In 1930, Paul Dirac published his book Principles of Quantum Mechanics. In that
book, the measurable quantities are associated with operators acting on the Hilbert
space of vectors that describe the state of a physical system. [4] The ladder operators
are defined as
2
1
( )
2
i
a x p a
a
= +
h
(6)
2
1
( )
2
i
a x p a
a
+
= -
h
(7)
Combining with (17-20),
1
2
( ) H a a w
+
= + h ,
[ , ] H a a w = -h ,
[ , ] H a a w
+ +
= h , [ , ] 1 a a
+
= (8)
Let H be an eigenvalue of
| ( ) | Ha H H a H w = - h ,
| ( ) | Ha H H a H w
+ +
= + h
This means
| | a H a H w = - h , | | a H c H w
+
= + h (10)
1
( )
2
H n w = + h ( 0,1, , n s = ) (11)
From (10),
*
| ( | ) ( | ) | H a a H a H H a w w
+ + +
= = - = - h h (12)
2
| | | | a H a a H n
+
= = ,
2
| | | | 1 c H aa H n
+
= = +
Thus
| | a H n H w = - h (13)
| 1| a H n H w
+
= + + h (14)
It is Diracs great contribution to associate the measurable quantities with operators.
However, his space of state vectors is so abstract that it is difficult to understand it. In
this study, we offer the following new concepts and approaches to improve Diracs
system.
I. A set of orthonormal wave functions describe the quantum state of a physical
system. A quantum state corresponds to a specific wave function.
Similarly to (5), the operator, wave functions and square matrix can be represented in
the same representation. Now that it is easy to associate the square matrix in matrix
mechanics with the operator and wave functions in wave mechanics, why do we have
to introduce state vector to describe quantum states? We do not need the state vector
which describes quantum states. Dirac had given Bra-ket notation too many meanings.
For example,
| | A A
+
= (15)
In our system, Bra-ket notation is only used for the inner product and has formal
meaning, given by two definitions in reference 1.
II. The operators are simply some derivative and function symbols. When an operator
acts on a function, it holds the numerical meaning.
In Dirac system, | | A A is regard as an operator and the operator can operate on not
only ket vector but also bra vector such as (12).
In our system, an operator can operator only on the function. Those concepts such as
| | A A and
A
+
was also given the meaning of
conjugate transpose belonging to the matrix.
In our system, only the matrices have the meaning of conjugate transpose. According
to the forward and inverse law of matrix multiplication,
[ ] [ ]
1 1 2
1 2 1 2
2 1 2
A a b a c
A
b d
A c d
y y y
y y y y
y y y
= +
=
= +
(16)
Thus, the differential equations can be associated with the matrix. The property of the
operator
This is just so-called matrix representation of the operator
A in representation
theory in Diracs system.
IV. The following postulates of quantum mechanics become naturally the starting
points in our system.
1). Born's probability interpretation.
2). There are the eigenequations including the Schrdinger equation.
3). The principle of superposition states.
4). In quantum mechanics, the operators that describe mechanical quantities are
Hermitain operators.
One-dimensional nondegenerate harmonic oscillator
The Hamiltonian operator of one-dimensional nondegenerate harmonic oscillator is
written as
2
1
2 2
2 2
p
H x mw
m
= +
(17)
Combining with (3), we can show that
[ , ] x p i = h
(18)
[ , ] x H i p
m
=
h
(19)
2
[ , ] p H i x mw = - h (20)
The Schrdinger equation is
H E y y =
The energy levels are discrete in quantum mechanics. Thus, let
1 2
, , ,
s
E E E be the
eigenvalues of
H and
1 2
, , ,
s
y y y the orthonormalized eigenfunctions belonging
to it in terms of Born's probability interpretation, then
1
2
1 2 1 2
0 0
0 0
[ ] [ ]
0 0
s s
s
E
E
H
E
y y y y y y
=
(21)
where
1 2
, , ,
s
E E E and
1 2
, , ,
s
y y y are all unknown.
Because x is a Hermitian operator, according to the theorem in reference 1 which
based on the above four postulates of quantum mechanics, it is assumed that
* *
11 21 1
*
21 22 2
1 2 1 2
1 2
[ ] [ ]
s
s
s s
s s ss
X X X
X X X
x
X X X
y y y y y y
=
(22)
where
11 22
, , ,
ss
X X X are real number and these matrix elements in the square
matrix are all unknown. From (19), (21) and (22),
1 2 1 2
[ ] [ ]
s s
p y y y y y y =
* *
1 2 21 1 1
*
2 1 21 2 2
1 1 2 2
0 ( ) ( )
( ) 0 ( )
( ) ( ) 0
s s
s s
s s s s
E E X E E X
E E X E E X i
E E X E E X
m
- -
- -
- -
h
(23)
From (20) (21) and (23),
1 2 1 2
[ ] [ ]
s s
x y y y y y y =
2 * 2 *
2 1 21 1 1
2 2 *
2 1 21 2 2
2 2
2 2
1 1 2 2
0 ( ) ( )
( ) 0 ( ) 1
( ) ( ) 0
s s
s s
s s s s
E E X E E X
E E X E E X
E E X E E X
w
- -
- -
- -
h
(24)
Comparison of (22) with (24) yields
2 * 2 * 2 *
2 1 21 3 1 31 1 1
2 2 * 2 *
2 1 21 3 2 32 2 2
2 2 2 *
3 1 31 3 2 32 3 3
2 2 2
1 1 2 2 3 3
0 ( ) ( ) ( )
( ) 0 ( ) ( )
( ) ( ) 0 ( )
( ) ( ) ( ) 0
s s
s s
s s
s s s s s s
E E X E E X E E X
E E X E E X E E X
E E X E E X E E X
E E X E E X E E X
- - -
- - -
- - -
- - -
* * *
11 21 31 1
* *
21 22 32 2
2 2 *
31 32 33 3
1 2 3
s
s
s
s s s ss
X X X X
X X X X
X X X X
X X X X
w
=
h
Therefore
11
X =
22
X = =
ss
X =0
Because
1 2 3 1
, , , , ,
s s
E E E E E
-
are real number and it is clear that
s
E >
1 3 2 1 s
E E E E
-
> > > > therefore
2 1
E E w - = h
3 2 31
, 0 E E X w - = = h
1 1 2
, 0
s s s ss
E E X X w
- -
- = = = = h
Thus, (22) and (24) become
[ ] [ ]
1 2 3 2 1 1 2 3 2 1
s s s s s s
x y y y y y y y y y y y y
- - - -
=
*
21
*
21 32
32
*
1 2
*
1 2 1
1
0 0 0 0 0
0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0
0
0 0 0 0 0
s s
s s ss
ss
X
X X
X
X
X X
X
- -
- - -
-
(25)
[ ] [ ]
1 2 3 2 1 1 2 3 2 1
s s s s s s
p y y y y y y y y y y y y
- - - -
=
*
21
*
21 32
32
*
1 2
*
1 2 1
1
0 0 0 0 0
0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0
0
0 0 0 0 0
s s
s s ss
ss
X
X X
X
i
X
X X
X
mw
- -
- - -
-
-
-
-
-
(26)
Thus, from (18), (25) and (26),
2 2 2
21 32 1 2 2 2
1 1 1
| | ,| | , ,| |
2 2
ss
s
X X X
a a a
-
-
= = = (
mw
a =
h
) (27)
2
1 2
1
| | 0
2
ss s s s
X y y y
a
-
- = = (28)
From (17), (21) and (25)-(27),
1
1
2
E w = h ,
2
3
2
E w = h , ,
1
( )
2
s
E s w = - h (29)
From (6), (7) and (25)-(26),
[ ] [ ]
1 2 1 1 2 1
s s s s
a y y y y y y y y
- -
=
*
21
*
1
0 0 0
0 0 0 0
2
0 0 0
0 0 0 0
ss
X
X
a
-
(30)
[ ] [ ]
1 2 1 1 2 1
s s s s
a y y y y y y y y
+
- -
=
21
1
0 0 0 0
0 0 0
2
0 0 0 0
0 0 0
ss
X
X
a
-
(31)
If we take positive real solutions from (27), then we have
21 32 1
1 2 1
, , ,
2 2 2
ss
s
X X X
a a a
-
-
= = = (32)
Thus, (30) and (31) become
[ ] [ ]
1 2 1 1 2 1
s s s s
a y y y y y y y y
- -
=
0 1 0 0
0 0 0 0
0 0 0 1
0 0 0 0
s
-
(33)
[ ] [ ]
1 2 1 1 2 1
s s s s
a y y y y y y y y
+
- -
=
0 0 0 0
1 0 0 0
0 0 0 0
0 0 1 0 s
-
(34)
Thus:
1 2 1 1
0, , , 1
s s
a a a s y y y y y
-
= = = - (35)
1 2 2 3 1
, 2 , , 1 , 0
s s s
a a a s a y y y y y y y
+ + + +
-
= = = - = (36)
From (35),
2
2
1 1
4 2 2
1
x
e
a
y p a
- -
= (37)
It can be followed by the other wave functions in terms of (36)
2 2
2 2
1 3 1 1 1 1
4 2 2 2 2 4 2 2
2 1
2 , , 2 [( 1)!] ( )
s
x x
s s
x e s H x e
a a
y p a y a p a
-
- - - - - -
-
= = - (38)
The functions
1
( )
s
H x a
-
are the Hermite polynomials.
2 2
1
1
1 1
( ) ( 1) ( )
s
s z z
s s
d
H z e e z x
dz
a
-
- -
- -
= - =
whens , 0
s
y =
Discussion
I. In Diracs system, he tried to represent | | a H a H w = - h in (10) as
[ ]
| / 2 |3 / 2 |(2 1) / 2 |(2 1) / 2 a s s w w w w - + h h h h
[ ] | / 2 |3 / 2 |(2 1) / 2 |(2 1) / 2 s s w w w w = - + h h h h
*
1
*
0 0 0
0 0 0 0
0 0 0
0 0 0 0
s
a
a
(39)
Furthermore, from (12),
1
0 0 0 0 / 2| / 2|
0 0 0 3 / 2| 3 / 2|
0 0 0 0 (2 1) / 2| (2 1) / 2|
0 0 0 (2 1) / 2| (2 1) / 2|
s
a
a
s s
a s s
w w
w w
w w
w w
+
=
- -
+ +
h h
h h
h h
h h
(40)
In fact, (39) corresponds to (30). (40) depends on | ( | ) H a a H
+ +
= and the
definition of the operator operating on bra vector | H a
+
.
In our system, (31) is derived from (22).
II. Dirac introduced Schrdingers representation with x diagonal and obtained the
representatives of the stationary states. He regarded |0 x as the ground state wave
function. Furthermore, with the help of the following expression
1 1
| |
n r n
r
x x p i x x
x
= -
h ,
he obtained the ground state wave function.
In fact, according to (13) and (35), the state vector |0 corresponds to the wave
function
1
y . We obtained (37) without invoking assistance from the Dirac concepts
of the state vectors. Similarly, for the angular momentum, the state vector | jm
corresponds to the wave function
jm
Y . [1]
1
1
( 1)( )
( )( 1)
jm jm
z jm jm
jm jm
L Y j m j m Y
L Y m Y
L Y j m j m Y
+ +
- -
= + + -
= + - +
h
h
h
( ,1 , , ; 0,1, ) m j j j j = - - =
We can get the solutions of these differential equations [1] which are also the
solutions of the following differential equations.
2
2 2 2
2 2
1 1
[ (sin ) ] ( , ) ( , ) ( , )
sin sin
( , ) ( , ) ( , )
z z
Y L Y Y
i Y L Y L Y
q q j q j l q j
q q q q j
q j q j q j
j
- + = =
- = =
h h
h
For example
00 00
00
00
00
( cot ) 0
0
i
z
Y Y
e i L Y
Y
i L Y
j
q
q j
j
+
+ = =
- = =
h
h
The solution of the differential equations is
00
1/ 4 Y p = .
The concepts, processes and the results in our system do not depend on those in
Diracs system. Therefore, we obtained the results of matrix mechanics and wave
mechanics without Diarcs abstract concepts and definitions and unified the
description of them.
Acknowledgments: thank Ph. D Dinghan Chen for some advices.
Reference
1. Yongqin Wang, Lifeng Kang, Unified Description of Matrix Mechanics and Wave
Mechanics on Hydrogen Atom, http://arxiv.org/abs/1201.0136
2B.L.van der Waerden, Sources of Quantum Mechanics, pp. 297-306. Dover
Publications, Inc., New York (1968)
3. Schrdinger, E., ber das Verhltnis der Heisenberg Born J ordanischen
Quantenmechanik zu der meinen, Annalen der Physik. Leipzig 79 (1926) 734
4. P.A.M. Dirac, the Principle of Quantum Mechanics (Fourth Edition), pp. 136-139.
Oxford at the Clarendon Press, London (1958)