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2.1.3 ALKENES
ASSESSED HOMEWORK
Answer all questions
Max 63 marks
Name
..
Mark
../63
Paddington Academy
....%
Grade
1.
cyclohexene
cyclohexane
2.
C H 3C H
C
+ B r2
H
(i)
C H 3C H
C H 2C H 2O H
C H 2C H 2O H
Br
Br
State what you would see when bromine reacts with leaf alcohol.
.........................................................................................................................
[1]
(ii)
Complete, with the aid of curly arrows, the mechanism involved in the reaction
between leaf alcohol and bromine. Show any relevant dipoles, charges and lone
pairs of electrons.
C H 3C H
C H 2C H 2O H
C H 3C H
H
C H 2C H 2O H
Br
Br
Br
Br
[4]
[Total 5 marks]
Paddington Academy
3.
(a)
(ii)
(b)
C H
H
H
C
+
H
C
C H
H
s te p 2
(i)
s te p 1
O
+
H
H
C H
H
s te p 3
(ii)
Paddington Academy
4.
Propene, CH3CH==CH2, also reacts with HBr to produce two bromoalkanes that are
structural isomers.
C H 3C H B rC H
C H 3C H
C H
+ H Br
C H 3C H 2C H 2B r
Propyne, CH3CCH, reacts like propene. It reacts with HBr to give three isomers with
molecular formula C3H6Br2.
Draw the three isomers with molecular formula C3H6Br2.
[Total 3 marks]
Paddington Academy
5.
C 2H
C 2H
C 2H
C 2H
A
polymer A
(i)
(ii)
(iii)
(iv)
Name polymer A.
.........................................................................................................................
[1]
[Total 4 marks]
6.
But-1-ene can undergo polymerisation. Draw a section of the polymer that can be
formed from but-1-ene. Show two repeat units.
[Total 2 marks]
Paddington Academy
7.
Long chain alkanes, such as nonane, can be cracked into shorter chain alkanes and
alkenes.
(i)
Write a balanced equation for the cracking of nonane into heptane and ethene.
.........................................................................................................................
[1]
(ii)
conditions ........................................................................................................
.........................................................................................................................
[2]
[Total 4 marks]
8.
State what you would see when propene reacts with bromine.
.........................................................................................................................
[1]
(ii)
Complete, with the aid of curly arrows, the mechanism involved in the reaction
between propene and bromine. Show any relevant dipoles and charges.
H3C CH ==CH2
Br
Br
[4]
[Total 5 marks]
Paddington Academy
9.
(a)
H
C
C 2H
C 2H
C
C 2H
Br
Br
C 2H
Br
Br
Intermediate
3,4-dibromohexane
[4]
(b)
................................................................................................................
................................................................................................................
[1]
(ii)
Explain why both cis and trans hex-3-ene react with Br2 to produce the
same structural isomer.
................................................................................................................
................................................................................................................
................................................................................................................
[1]
[Total 6 marks]
Paddington Academy
10.
Draw a section of pvc showing three repeat units. Put a bracket round one repeat
unit.
[2]
(ii)
Polymers such as pvc are difficult to dispose of because they are nonbiodegradable. Increasingly, they are disposed of by combustion.
State the problem associated with the combustion of polymers such as pvc.
.........................................................................................................................
.........................................................................................................................
[1]
(iii)
State two ways in which chemists are trying to minimise the damage to the
environment caused by the disposal of halogenated plastics such as pvc.
.........................................................................................................................
.........................................................................................................................
.........................................................................................................................
[2]
[Total 5 marks]
Paddington Academy
11.
Body odour often begins with secretions from glands called apocrine glands, which are
most numerous in the armpits. Bacteria, which live in the armpits, use these secretions
to produce energy and many different waste products. Scientists have isolated one of
these waste products, compound E, which is shown below.
H 3C
H
C
C H 3C H 2C H
C H 2O H
com pound E
Name the other functional group and state how you could test for it.
name of the other functional group .................................................................
test ..................................................................................................................
observation .....................................................................................................
[3]
(ii)
12.
(a)
[2]
(ii)
[2]
Paddington Academy
(b)
C H 2C l
C
C l
C H
C
C l
is o m e r 1
(i)
C l
C l
C
C l
is o m e r 2
[2]
(ii)
Paddington Academy
10
(c)
polymer P
[2]
(ii)
Paddington Academy
11
13.
C H
H 3C
CH
s te p 1
C H 3C H
Br
C H 2B r
s te p 2
C H 3C H
C H 2B r
C
Br
Br
Br
(i)
(ii)
Label any relevant dipoles and add curly arrows to the mechanism to show the
movement of electron pairs in step 1 and in step 2.
[3]
[Total 4 marks]
Paddington Academy
12