Beruflich Dokumente
Kultur Dokumente
, Yen Wei
b
a
Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, P. R. China
b
Department of Chemistry, Drexel University, Philadelphia, PA 19104, USA
Received 4 April 2006; accepted 13 July 2006
Available online 1 August 2006
Abstract
Microrods of poly(o-phenylenediamine) (PoPD) were synthesized by a templateless method using ferric chloride as an oxidant. The microrod
morphologies of the resulting PoPD were confirmed by scanning electron microscopic (SEM) and transmission electron microscopic (TEM)
images. When the concentration of o-phenylenediamine (oPD) was 0.03 M, the microrods of PoPD had a diameter in the range of 0.52 m and a
length from 2 m to 20 m. It was found that the concentration of oPD monomer had much influence on the morphology of the obtained PoPD.
When the concentration of oPD was lower than 0.03 M, long microrods could be observed. However, when the concentration of oPD monomer
was higher than 0.12 M, the length of the microrods became very short and the diameter became bigger. Fourier transform infrared spectroscopy
(FTIR), UVvis absorption spectra and X-ray diffraction (XRD) were used to characterize the structure of the obtained PoPD microrods.
2006 Elsevier B.V. All rights reserved.
Keywords: Poly(o-phenylenediamine); Microrods; Ferric chloride
1. Introduction
In the past decades, conducting polymers have become well-
known because of its useful electronic, photonic, and electrolu-
minescence properties, as well as potential applications in elec-
trode materials, microelectronics, electrochromic materials and
antisepsis [13]. In recent years, one-dimensional nanostructures
including nanofibers, nanotubes, nanorods and nanobelts of
conducting polymers have been studied extensively. These 1D
nanostructured materials have distinctive geometries, and novel
physical and chemical properties, which are probably applicable
in nanodevices [4]. There are many methods to be developed for
synthesizing 1D conducting polymers. For example, a hard-tem-
plate based method to prepare 1D conducting polymers was first
investigated [57]. Micelles, surfactants, liquid crystals, thiolated
cyclodextrins and polyacids were also used as a soft-template to
prepare nanofibers and nanotubes of conducting polymers [8
14]. Recently, interfacial polymerization, dilute polymerization
and fiber seeding methods were developed to prepare PANI
nanofibers [1517]. However, the major disadvantage of PANI is
its insolubility in common organic solvents and its infusibility
because of its stiffness of the PANI backbone and the hydrogen-
bonding interactions between the amine moieties of adjacent
chains. Therefore, polymers based on aniline derivatives have
also been extensively investigated.
Poly(o-phenylenediamine), PoPD, is a polyaniline derivative
which can be achieved through substituting hydrogens by an
amino group in an aniline nucleus. Compared with PANI, the
oxidative polymer of oPDhas apparently shown different charac-
teristics of molecular structure and properties. It has been used as
an electrochemical reduction catalyst for dioxygen, anticorrosion
coatings for metals, sensors for some chemical species and im-
munosorbent assays [1821]. PoPD is usually prepared by
electrochemical polymerization. In this polymerization method,
the obtained PoPDusually has an irregular morphology. Recently,
Sun et al. prepared 1Dnanostructures of PoPDby directly mixing
HAuCl
4
and oPD aqueous solutions at room temperature without
using any template or surfactant [22]. However, the resulting
precipitates are not pure, and there are some Au nanoparticles in
the final product.
Materials Letters 61 (2007) 14001403
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