Quick-FDS [16650-56533-12473-014633] - 2013-08-01 - 15:42:13

SAFETY DATA SHEET

Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or
designation of the mixture
CLB F5/AC
- Registration number
Synonyms None.
Product code C00856
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Not available.
Uses advised against Not available.
1.3. Details of the supplier of the safety data sheet
CONDAT
Avenue Frdric Mistral - B.P. 16
38760 CHASSE-SUR-RHONE
Supplier
Company name
Address
FR
Tel.: 33 (0)4 78.07.38.38 Telephone
Fax: 33 (0)4 78.07.38.00
e-mail
Contact person
arp@condat.fr
Products Regulatory Affairs Department
1.4. Emergency telephone
number
Emergency Tel. (Office hours): 33 (0) 4 78 07 37 18
Emergency Tel. (France) ORFILA (INRS) :
+ 33 (0)1 45 42 59 59
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification
applies.
Classification according to Directive 67/548/EEC or 1999/45/EC as amended
Classification Xi;R38-41
The full text for all R-phrases is displayed in section 16.
Hazard summary
Physical hazards Not classified for physical hazards.
Health hazards Irritating to skin. Risk of serious damage to eyes.
Environmental hazards Not classified for hazards to the environment.
Specific hazards Risk of serious damage to eyes. Irritating to mouth, throat, and stomach. Irritating to skin.
Main symptoms Irritation of eyes and mucous membranes. Permanent eye damage including blindness could
result. Irritating to mouth, throat, and stomach. Skin irritation.
2.2. Label elements
Label according to Directive 67/548/EEC or 1999/45/EC as amended
EC number -
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
EC label
Irritant
R-phrases R38 Irritating to skin.
R41 Risk of serious damage to eyes.
S-phrases S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, Rinse immediately with plenty of water and seek medical advice.
S37/39 Wear suitable gloves and eye/face protection.
S46 If swallowed, seek medical advice immediately and show this container or label.
Not available. Authorisation number
Supplemental label
information
Not applicable.
2.3. Other hazards Not assigned.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Notes INDEX No. REACH Registration No. CAS-No. / EC No. % Chemical name
General information
Classification: DSD: Xi;R36/38
Skin Irrit. 2;H315, Eye Irrit. 2;H319 CLP:
603-053-00-3 01-2119539582-35 107-41-5
203-489-0
2,4-Pentanediol, 2-methyl- 5 - < 10
Classification: DSD: Xi;R38-41
Skin Irrit. 2;H315, Eye Dam. 1;H318 CLP:
- - 68585-34-2
-
Alcohols, C10-16, ethoxylated,
sulfates, sodium salts.
5 - < 10
Classification: DSD: Xi;R38-41
Skin Irrit. 2;H315, Eye Dam. 1;H318 CLP:
- - 68585-47-7
271-557-7
Mono-C10-16-alkyl, Sodium sulfate 5 - < 10
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
Notes INDEX No. REACH Registration No. CAS-No. / EC No. % Chemical name
Classification: DSD: Xi;R36, N;R50
Eye Irrit. 2;H319, Aquatic Acute 1;H400 CLP:
- - 85711-71-3
288-332-4
Alcohols, C10-18 < 1
CLP: Regulation No. 1272/2008. "-" = Not available or this substance does not meet the criteria for classification according to
Regulation (EC) 1272/2008 as amended.
DSD: Directive 67/548/EEC.
#: This substance has workplace exposure limit(s).
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.
Composition comments The full text for all R- and H-phrases is displayed in section 16. The full text for all R-phrases is
displayed in Section 16.
SECTION 4: First aid measures
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. If you feel unwell, seek medical advice (show the label where possible). Keep
victim warm. Keep victim under observation.
4.1. Description of first aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off immediately with plenty of water. Get medical attention if irritation develops and persists.
Take off contaminated clothing and wash before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Get medical attention immediately.
Ingestion If swallowed, seek medical advice immediately and show this container or label. Rinse mouth
thoroughly. If swallowed, do NOT induce vomiting.
4.2. Most important
symptoms and effects, both
acute and delayed
Irritation of eyes and mucous membranes. Permanent eye damage including blindness could
result. Irritating to mouth, throat, and stomach. Skin irritation.
4.3. Indication of any
immediate medical attention
and special treatment
needed
Keep victim warm. Keep victim under observation. Symptoms may be delayed.
SECTION 5: Firefighting measures
General fire hazards None known.
5.1. Extinguishing media
Suitable extinguishing
media
Dry chemical, CO2, or water spray. Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Unsuitable extinguishing
media
Not relevant.
5.2. Special hazards arising
from the substance or
mixture
See also section 10.
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
5.3. Advice for firefighters
Special protective
equipment for
firefighters
Wear suitable protective equipment.
Special fire fighting
procedures
In case of fire and/or explosion do not breathe fumes.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
clean-up. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Keep upwind. Keep out of low areas.
For emergency
responders
Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the
MSDS.
6.2. Environmental
precautions
Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant
spillages cannot be contained. Contact local authorities in case of spillage to drain/aquatic
environment. Avoid discharge into drains, water courses or onto the ground.
6.3. Methods and material for
containment and cleaning up
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. For waste disposal, see section 13.
6.4. Reference to other
sections
See Section 8 for personal protective equipment. For waste disposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe
handling
Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Adequate ventilation
should be provided so that exposure limits are not exceeded.
7.2. Conditions for safe
storage, including any
incompatibilities
See also section 10. Store in closed original container in a dry place. Keep from freezing. Storage
temperature: between 5C and 50C.
7.3. Specific end use(s) Not available.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
France. Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984
Value Type Components
VLE 2,4-Pentan ediol, 2-methyl-
(107-41-5)
125 mg/m3
25 ppm
Belgium. Exposure Limit Values.
Value Type Components
TWA 2,4-Pentan ediol, 2-methyl-
(107-41-5)
123 mg/m3
25 ppm
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
Switzerland. SUVA Grenzwerte am Arbeitsplatz
Value Type Components
STEL 2,4-Pentan ediol, 2-methyl-
(107-41-5)
98 mg/m3
20 ppm
TWA 49 mg/m3
10 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring procedures
Additional exposure data Not available.
Recommended monitoring
procedures
Follow standard monitoring procedures.
8.2. Exposure controls
Appropriate engineering
controls
Ensure adequate ventilation, especially in confined areas.
Individual protection measures, such as personal protective equipment
General information Eye wash fountain is recommended.
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles). Safety glasses with
side-shields.
Skin protection
- Hand protection Use protective gloves made of: Nitrile. Polyvinyl chloride (PVC).
- Other Personal protection equipment should be chosen according to the CEN standards and in discussion
with the supplier of the personal protective equipment. Avoid contact with the skin. Wear suitable
protective clothing. Wear protective gloves.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Thermal hazards Not available.
Hygiene measures Wash hands after handling. Handle in accordance with good industrial hygiene and safety
practices.
Environmental exposure
controls
Environmental manager must be informed of all major releases.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state Liquid.
Form Liquid.
Colour Colourless. - Yellow
Odour Slight.
Alcoholic.
Odour threshold Not available.
pH 8 - 9
Melting point/freezing point 0 C (32 F)
Initial boiling point and
boiling range
100 C (212 F)
Flash point > 100,00 C (> 212,00 F)
Evaporation rate Not applicable.
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not applicable.
Flammability limit -
upper (%)
Not applicable.
Vapour pressure Not applicable.
Vapour density Not applicable.
Relative density 1,04
Relative density temperature 20 C (68 F)
Solubility(ies) Soluble
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Explosive properties Not available.
Oxidizing properties Not available.
9.2. Other information
pH in aqueous solution 7 - 8 @5%
SECTION 10: Stability and reactivity
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
10.4. Conditions to avoid Avoid frost.
10.5. Incompatible materials Strong oxidizing agents. Strong acids.
10.6. Hazardous
decomposition products
Under common conditions of use (see technical data sheet): No hazardous decomposition products
are known.
Development of hazardous combustion gases or vapours possible in the event of fire.: Sulphur
compounds. Carbon oxides.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Test results Product Species
CLB F5/AC (Mixture)
LD50 Rat
Oral
Acute
> 2500 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Irritating to skin.
Serious eye
damage/irritation
Risk of serious damage to eyes.
Respiratory sensitisation Not classified.
Skin sensitisation Not classified.
Germ cell mutagenicity Not classified.
Carcinogenicity Not classified.
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
Reproductive toxicity Not classified.
Specific target organ toxicity
- single exposure
Not available.
Specific target organ toxicity
- repeated exposure
Not available.
Aspiration hazard Not classified.
Other information Not available.
SECTION 12: Ecological information
12.1. Toxicity Not expected to be harmful to aquatic organisms.
Product Test results Species
CLB F5/AC (Mixture)
IC50 Algae 142 mg/l, 72 Hours, Growth rate Algae
NOEC 15,6 mg/l, 72 Hours, Growth rate Algae
EC50 Crustacea 48,8 mg/l, 48 Hours Daphnia
NOEC 25 mg/l, 48 Hours Daphnia
LC50 Fish 10 - 48,8 mg/l, 96 Hours Fish
* Estimates for product may be based on additional component data not shown.
NOEC 10 mg/l, 96 Hours Fish
12.2. Persistence and
degradability
readily biodegradable.
12.3. Bioaccumulative
potential
Not available.
Partition coefficient
n-octanol/water (log Kow)
Not available.
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
Mobility in general This product is miscible in water.
12.5. Results of PBT
and vPvB
assessment
Not a PBT or vPvB substance or mixture.
12.6. Other adverse effects Not available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Residual waste Dispose of in accordance with local regulations. Avoid discharge into water courses or onto the
ground.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
EU waste code Waste codes should be assigned by the user based on the application for which the product was
used.
Unused product : 16 03 05*
Aqueous solution @ 5 % : 16 03 06
Disposal
methods/information
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not discharge
into drains, water courses or onto the ground. Dispose in accordance with all applicable
regulations.
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
SECTION 14: Transport information
ADR
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I
Not listed.
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II
Not listed.
Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as
amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as
amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as
amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorisation
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as
amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and
mutagens at work
Not regulated.
Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or
are breastfeeding
Not regulated.
Other EU regulations
Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances
Not regulated.
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SAFETY DATA SHEET
Product : CLB F5/AC
Revision : 28-May-2013 Version : 1.1 Code : C00856
Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical
agents at work
2,4-Pentanediol, 2-methyl- (CAS 107-41-5)
Directive 94/33/EC on the protection of young people at work
Not regulated.
Other regulations The product is classified and labelled in accordance with EC directives or respective national laws.
This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006.
National regulations Not available.
15.2. Chemical safety
assessment
No Chemical Safety Assessment has been carried out.
SECTION 16: Other information
List of abbreviations Not available.
References Not available.
Information on evaluation
method leading to the
classification of mixture
Not available.
Full text of any statements or
R-phrases and H-statements
under Sections 2 to 15
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
H315 - Causes skin irritation.
H318 - Causes serious eye damage.
H319 - Causes serious eye irritation.
H400 - Very toxic to aquatic life.
Revision information SECTION 10: Stability and reactivity: 10,6. Hazardous decomposition products
SECTION 13: Disposal considerations: Disposal methods/information
SECTION 13: Disposal considerations: EU waste code
Training information Not available.
The information in the sheet was written based on the best knowledge and experience currently available. This document complements the technical
sheets but does not replace them. The information contained herein is based on our knowledge of the concerned product on the date indicated. It is
offered in good faith. Furthermore, the regulatory requirements referred to must not be considered as exhaustive. They do not exempt in any form the
user from knowing and applying all regulations related to the possession and use of the product. The user takes as their sole responsibility the
implementation of precautions relating to storage and their use of the product.
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