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w seawater
w
solid
solid
W
W
M T
+ =
in meters. (1)
where M
solid
is the OOC Model-predicted seabed loading,
) 1000 ( 1 ppt ppt + =
For a complete derivation of equation (1) see Appendix
A.
T
Ambient
Sediment
Deposited
Cuttings
Area of surface
A
Figure 1. Schematic diagram used for drilling solids deposition
thickness estimate.
Hydrocarbon Concentration in Seabed Sediments. The
following assumptions simplify conversion of model-predicted
seabed loading to sediment hydrocarbon concentration:
The WBM solids contain no hydrocarbons.
The NAF drilling solids accumulated on the seabed re-
main on top of all drilling discharges.
The ambient sediments contain no hydrocarbons.
The NAF base fluids remain adhered to the NAF cut-
tings.
The deposited hydrocarbons do not degrade over time.
The NAF cuttings includes the cuttings, the base fluid
adhering to the cuttings, and the barite in the NAF.
In addition, assumptions must be made regarding the
following:
The thickness of a hypothetical control volume (see Fig-
ure 2)a common thickness used for field sampling is
the top 2 cm
The wet-weight percent hydrocarbons adhering to the
deposited NAF drilling solidsan average value for
base fluid retained on cuttings for wells drilled with
similar cuttings cleaning equipment can be used.
The composition of the NAFthe composition should
be based on project-specific mud or, if not available, use
the EPA generic mud from EPA
(8)
(47% base fluid, 33%
solids as barite, and 20% brine by weight).
The density of benthic sedimentsin the absence of
site-specific data, assume the density is the same as that
of the WBM drilling solids.
The porosity of the ambient sediments and non-NAF
drilling depositsin the absence of site-specific infor-
mation, a porosity of 0.4 can be used.
The calculation of hydrocarbon concentration in sediment
is developed using a control volume consisting of an area A
CV
and total thickness T
CV
. This volume is intended to represent
the sediment material sampled for analysis during a hypotheti-
cal field sampling operation. The equation to calculate
hydrocarbon concentration in sediments containing NAF
cuttings is as follows:
For the control volume shown in Figure 2, the hydrocar-
bon concentration can be calculated using the following
equation:
l CV M T
x M
ppm HC
l
) 1 ( ) (
) 10 1 (
) (
6
+ + +
=
(2)
where M
l
=the OOC Model-predicted NAF-cuttings and
associated drilling fluid loading
) ( SW oil BF oil BF F F F F F =
)) 100 ( ( 1 w seawater w solid W W + =
) 1 ( p amb =
pSal seawater =
) 100 ( w w w W W W =
F
BF
=fraction base fluid in NAF
F
oil
=fraction base fluid adhering to cuttings
F
seawater
=fraction of saltwater in NAF
p=porosity of ambient sediments or WBM deposits
Sal=is seawater salinity (kg salt/kg seawater)
Sal Sal) 1 ( =
For a complete derivation of equation (2) see Appendix A.
T
cv
Ambient
Sediment/
WBM
Deposits
Deposited
Cuttings
Area of surface
A
cv
T
NAF
Figure 2. Conceptual control volume needed for converting
model-predicted seabed loading to seabed-sediment hydrocar-
bon concentration. A
cv
should correspond to the area of a
model grid cell as specified in the model input.
Contour Plot Examples. The figures below provide examples
of the type of visuals that can be generated from model
predictions. The plots were generated from modeling the
surface and seabed discharges of a single exploration well in
SPE 86699 5
625 m of water. The bathymetry was simulated as a flat plane.
The concentration of base fluid on the cuttings at the seabed
was assumed to be 10%.
-500 -400 -300 -200 -100 0 100 200 300 400 500
Distance East-West (m)
-500
-400
-300
-200
-100
0
100
200
300
400
500
D
i
s
t
a
n
c
e
N
o
r
t
h
-
S
o
u
t
h
(
m
)
Figure 3. Thickness contours for the discharge of all drilling
solids in 625 m water. The cross marks the discharge point.
Thickness contours are in centimeters and the maximum
thickness is 57 cm.
-500 -400 -300 -200 -100 0 100 200 300 400 500
Distance East-West (m)
-500
-400
-300
-200
-100
0
100
200
300
400
500
D
i
s
t
a
n
c
e
N
o
r
t
h
-
S
o
u
t
h
(
m
)
Figure 4. NAF base fluid concentration (ppm) contours for the
discharge of all drilling solids in 625 m water. The cross marks
the discharge point. Hydrocarbon concentration contours are in
parts per million and maximum concentration is 100,000 ppm.
References
1. Policastro, A.: Evaluation of Selected Models. In: An Evaluation
of Effluent Dispersion and Fate Models for OCS Platforms. Vol-
ume I, Summary and Recommendations. U.S. Dept. of Interior,
Minerals Management Service. Workshop Proceedings. 7-10
February. Santa Barbara, California (1983) 33.
2. Brandsma, M.G., Smith, J .P., O'Reilly, J .E., Ayers, R.C.,Jr.,
Holmquist, A.L.: Modeling Offshore Discharges of Produced
Water. In: Produced Water. J .P. Ray and F.R. Engelhart, Eds.
Plenum Press. New York (1992) 59.
3. Nedwed, T. J., Smith, J . P., Brandsma, M. G.: Verification of the
OOC Mud and Produced Water Discharge Model Using Lab-Scale
Plume Behavior Experiments. J. of Marine Science, in press.
4. O'Reilly, J .E., Sauer, T.C., Ayers, R.C. J r., Brandsma, M.G., Meek,
R.: Field Verification of the OOC Mud Discharge Model. In:
Drilling Fluids. F.R. Engelhart, J .P. Ray, A.H. Gillam, Eds.,
Elsevier Applied Science. New York (1989) 647.
5. Smith, J .P., Mairs, H.L., Brandsma, M.G., Meek, R.P., Ayers, R.C.,
J r. 1994. Field Validation of the Offshore Operators Committee
(OOC) Produced Water Discharge Model. Proceedings of SPE
Annual Technical Conference. SPE28350. New Orleans. (25-28
September 1994).
6. Smith J . P., Brandsma, M. G., Nedwed, T. J .: Field Validation of
the Offshore Operators Committee (OOC) Mud and Produced
Water Discharge Model J. of Marine Science, in press
7. Brandsma, M.G. and Smith, J .P.: Offshore Operators Committee
Mud and Produced Water Discharge Model -- Report and User
Guide. Offshore Operators CommitteeP.O. Box 50751New
Orleans, LA 70150-0751 www.offshoreoperators.com (1999).
8. EPA: "Development Document for Proposed Effluent Limitations
Guidelines and Standards for Synthetic Based Drilling Fluids and
other Non-Aqeuous Drilling Fluids in the Oil and Gas Extraction
Point Source Category" EPA-821-B-98-021 (19990) VII-6.
Appendix A
Derivation of Drilling Solid Accumulation Thickness
Equation. Using the assumptions and parameters described in
the main body of the report and with reference to Figure 1, the
volume of drilling solids over A with thickness T is
) ) ( (
seawater salt water solid solid
M M M A A T V + + = = (1)
Therefore
seawater salt water solid solid
M M M T ) ( + + = (2)
where M represents the loading (kg/m
2
) of the individual
components making up the drill solid accumulations; either
cuttings solid (solid), pure water (water), or salt in pore water
(salt). M
solid
is the OOC Model-predicted seabed loading.
The M
salt
can be determined using the assumed pore water
salinity (35.03 g/kg) and the assumed weight percent water.
) 1000 ( ppt M ppt M
water salt
=
(3)
Express M
water
in terms of W
w
(weight percent water) and
M
solids.
) ( 100
salt water solid water w
M M M M W + + = (4)
Substituting M
salt
into (4) gives
)
1000
1 (
100
ppt
ppt
M M
M
W
water solid
water
w
+ +
=
(5)
Let
) 1000 ( 1 ppt ppt + = (6)
then
) 100 (
w solid w water
W M W M = (7)
Substituting M
water
and M
salt
into thickness equation gives
)
) 100 (
1
(
w seawater
w
solid
solid
W
W
M T
+ =
in m. (8)
0363 . 1 = for kg g ppt 03 . 35 =
The following values can be used as an equation check.
If M
solid
=1000 kg/m
2
, W
w
=30%, ppt =35.03 g/kg,
solid
=2650
kg/m
3
, and
seawater
=1020 kg/m
3
then T=0.8197 m.
Derivation of Hydrocarbon Concentration in Seabed
Sediments Equation. Using the assumptions and parameters
described in the main body of the report and with reference to
Figure 2, the equation to calculate hydrocarbon concentration
in sediments containing NAF cuttings is derived as follows:
6 SPE 86699
saltsed saltamb amb Ba BF C
BF
M M M M M M
x M
ppm HC
+ + + + +
=
) 10 1 (
) (
6
(9)
where M
BF
is the loading of base fluid in the control volume,
M
C
is the loading of cuttings in the control volume,
M
Ba
is the loading of barite in the control volume,
M
amb
is the loading of ambient sediment in the control
volume,
M
saltamb
is the loading of salt in the control volume
ambient sediment or WBM solids pore water,
M
saltsed
is loading of salt in the NAF sediment in the
control volume.
Transform (9) into a function of the model predicted NAF
cuttings loading (M
l
) starting with an expression for F
oil
, the
wet-weight fraction of NAF base fluid retained on the cuttings.
) (
SW Ba BF c BF oil
M M M M M F + + + = (10)
where F
oil
is fraction oil in discharged NAF cuttings (oil on
cuttings by retort test), and
M
SW
is mass of the aqueous phase in the NAF that is
discharged with the cuttings.
Ba BF C l
M M M M + + = (11)
Substituting (11) into (10) gives
) (
SW l BF oil
M M M F + = (12)
also
NAF Ba Ba NAF BF BF NAF SW SW
M F M and M F M M F M = = = , ,
(13)
where F
SW
is fraction seawater in the NAF,
M
NAF
is the loading of whole NAF in the discharged
NAF cuttings (M
NAF
=M
BF
+M
Ba
+M
SW
), (14)
F
BF
and F
Ba
are the fractions of base fluid and barite in
the NAF.
Combining equations in (13) and rearranging gives
BF BF SW SW
F M F M = (15)
Substituting (15) into (12) gives
) (
BF
BF
SW
l BF oil
M
F
F
M M F + =
(16)
Solve (16) for M
BF
to give
l SW oil BF l oil BF BF
M F F F M F F M = = ) ( (17)
Now determine M
amb
as a function of M
l
.
) )( 1 (
NAF CV amb amb
T T p M =
(18)
for T
CV
>T
NAF
, zero otherwise
where
amb
is density of ambient sediments,
p is porosity of ambient sediments or WBM drilling
deposits,
T
CV
is the thickness of the control volume,
T
NAF
is the thickness of NAF drilling deposits as defined
in (8).
l w seawater w solid l NAF
M W W M T = + = ) )) 100 ( ( 1 (
(19)
where , W
w
, and
seawater
are defined in the previous thickness
derivation. The value of
solid
is determined based on the
composition of the NAF solids, i.e., the relative loadings of M
c
,
M
BF
, and M
Ba
in M
l
determined by (12) and (13). The determi-
nation of
solid
is as follows:
Ba
Ba
BF
BF
c
C
Ba BF C
Ba BF C
Ba BF C
solid
M M M
M M M
V V V
M M M
+ +
+ +
=
+ +
+ +
=
(20)
where
c
,
BF
, and
Ba
are the densities of dry cuttings, base
fluid and barite, respectively, and V
C
, V
BF
, and V
Ba
rep-
resent the volume of dry cuttings, base fluid, and barite,
respectively, in the discharged drilling solids.
From (10) and (13)
) ( ) (
NAF c oil SW Ba BF c oil NAF BF BF
M M F M M M M F M F M + = + + + = =
(21)
Rearranging gives
) (
oil BF c oil NAF
F F M F M =
(22)
Since
solid
is constant if we assume the ratio of cuttings,
base fluid, and barite is constant, we can let M
c
=1 lb/grid cell
to simplify (20) and (22).
Then
) (
oil BF oil NAF
F F F M =
(23)
Substituting into (20) gives
Ba
NAF Ba
BF
NAF BF
c
NAF Ba NAF BF
solid
M F M F
M F M F
+ +
+ +
=
1
1
(24)
Now, substituting (19) into (18) gives
) )( 1 (
l CV amb amb
M T p M =
(25)
for T
CV
>M
l
, zero otherwise
Next determine M
saltamb
as a function of M
l
.
Sal M M
amb
SW saltamb
=
(26)
where M
SWamb
is mass seawater in ambient sediment or WBM
drilling deposits,
Sal is salinity of seawater (kg salt/kg seawater).
) ( ) (
l CV seawater NAF CV seawater SW
M T p T T p M
amb
= =
(27)
Substituing (27) into (26) gives
Sal M T p M
l CV seawater saltamb
) ( =
(28)
for T
CV
>M
l
, zero otherwise
Finally determine M
saltsed
as a function of M
l
.
saltsed w l
w
saltsed w Ba BF c
w
w
M M M
M
M M M M M
M
W
+ +
=
+ + + +
=
100 100
(29)
) 1 ( Sal SalM M
w saltsed
=
(30)
rearrange (30) to give
Sal M Sal M
saltsed w
) 1 ( = (31)
Substitute (31) into (29) and solve for M
saltsed
.
Sal
Sal
where
W W
M W
M
w w
l w
saltsed
=
=
1
100
(32)
Now substitute (32), (28), (25), (17), & (11) into (9).
l CV M T
e M
ppm HC
l
) 1 ( ) (
) 6 1 (
) (
+ + +
=
(33)
where ) 1 ( p amb = , pSal seawater = , and
) 100 ( w w w W W W =
The following values can be used to check equation (33):
F
oil
0.100
amb
2650 kg/m
3
F
BF
0.47
c
2650 kg/m
3
F
Ba
0.33
solid
(eqtn. 23 & 24) 2166 kg/m
3
F
sw
0.20 p 0.400
sw
1020 kg/m
3
Sal 0.03503 kg
salt
/kg
seawater
BF
780 kg/m
3
Ww 30%
Ba
4200 kg/m
3
T
cv
0.02 m
M
l
HC (ppm) from eqtn (33)
20 89,275
15 61,269
10 37,648
1 3,300