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Textile Colouration
Suitable for:
ACTIVITY MASTERS
SOCIETY OF DYERS AND COLOURISTS
AUSTRALIA AND NEW ZEALAND
DYEING
D
yeing is the process whereby dye and an Auxochrome which gives a dye its
molecules, thoroughly dissolved or solubility and ability to attach itself to a fibre.
dispersed in water or some other
Dyestuffs can be grouped according to the fibres
carrier, are able to penetrate and colour
with which they can be used. Different dyes are
textile materials.
attracted to different fibres. The strength of the
Dyeing can be carried out at the polymer, fibre, dye-fibre attraction is called Affinity.
yarn, fabric and garment or product stage.
Each class of dye has a unique chemistry,
Dyes are substances with a special capacity structure and way of bonding to the fibre.
for reflecting light. They have a distinctive Some dyes react chemically with the fibre
structure and are made up of a colour forming strong bonds others are held by
bearing component called a Chromophore physical forces.
CLASSES OF DYES
Direct Dyes Vat Dyes
Direct dyes are a relatively inexpensive and easy Vat dyes are used to dye cotton and viscose rayon.
way of dyeing natural cellulosic fibres like cotton Vat dyes are insoluble and so cannot penetrate the
and regenerated cellulosic fibres like viscose rayon fibres in solution. They can however be reduced to a
although they do not have good fastness to washing soluble form called the leuco form in the presence of
or other wet processes. Direct dye molecules are alkali and a reducing agent. Vat dyeing is a multi-
large and enter the cotton or viscose fibre from the stage process:
dyebath seeking a place to bind to the fibre.
Hydrogen bonding and Van der Waals forces help n the insoluble vat dye is reduced to a soluble
bind the dye to the fibre. leuco form to be applied to the textile;
Fastness properties may be improved by after n the leuco molecules are then oxidised to be
treatment a post dyeing chemical treatment. insoluble once more and develop the colour
inside the fibre. Vat dyes have excellent
Reactive Dyes washfastness properties but the colour range is
Reactive dyes form strong covalent bonds with more limited and more expensive.
cellulosic fibres like cotton and regenerated
cellulosics like viscose rayon. The formation of the Sulphur dyes are similar to vat dyes but are cheaper,
covalent bond between dye and fibre means less environmentally friendly and are limited to flat
reactive dyes give extremely high wash and wet dull colours. They also have poor fastness to sodium
fastness properties. hypochlorite.
continued
continued
Since the dye molecules are large and insoluble, they Basic Dyes
have excellent wash fastness properties. Poor rub Acrylic fibres are dyed with the
fastness can be a problem due to dye formation on the brilliant and intense modified basic
textile surface. Insufficient afterwashing will give poor dyes. Basic dyes are positively
fastness to wet treatments. charged or cationic. These positively
charged cations are attracted to
Acid Dyes negatively charged anions in the
Acid dyes have a direct affinity for protein fibres and acrylic fibre. The reaction of the
are the main class of dyestuff for dyeing wool. cation and anion form salt linkages
Nylon also has an affinity for acid dyes. The and the fibre is coloured with good
attraction between dye and fibre is the result of wash and light fastness properties.
negatively charged dye particles called anions
associating with positively charged basic groups in Pigments
the fibre generally under acid conditions. Pigments are water insoluble colourants that can be
applied to most fibre types. They are coloured
Disperse Dyes particles dispersed in an aqueous paste containing
Disperse dyes are applied to polyester. Polyester has a a binder. Through various methods, the pigment
tightly packed molecular structure called a crystalline paste is then applied to the surface of the textile and
structure. It is hydrophobic or water hating. Heat opens the binder is then cured.
I
nformation gathering and the Once the information is gathered and assimilated,
generation of ideas are key samples can be generated. In the lab, colour
elements in the design process. At swatches either collated by designers or
the information gathering stage, supplied by customers are placed in a
market research what the market is spectrophotometer an instrument used to
doing and what it is seeking is measure the amount of light reflected from a
undertaken. Working with customers to sample at a number of wavelengths in the
ensure their needs are met is essential. visible spectrum in comparison to a white
standard.
Almost all product is subject to seasonal
variation and demand. Dyes used in When the sample is placed in the
Industrial textiles must rise to meet new and spectrophotometer and a reading obtained,
exacting technical requirements, whilst apparel the reflected light is specified mathematically.
must meet the ever changing and fickle fashion Different combinations of dyestuffs can be mixed to
markets. assimilate the colour of the sample.
continued
continued
The information from the spectrophotometer is A recipe sheet is printed and laboratory trials are
transferred to the computer. The computer assesses undertaken to ensure a good colour match and that
the reading and then seeks to find and name a the recipe formulated will produce properties that
combination of dyestuffs that will match the sample. meet the customers end use specifications. Once a
The computer gives a number of dye recipe options trial is successful, the recipe is ready for use in the
that very closely resemble the original sample. The dyehouse and production begins.
most suitable recipe is chosen but choice will be
based on such things as price, colour fastness to
washing and light, migration and exhaustion rates
and levelling properties.
PRINCIPLES OF DYEING
n Migration of dye molecule from liquor to fibre. This process is assisted by increasing
temperatures and using auxiliaries substances that help the dyeing process.
n Diffusion of dye from the fibre surface into the fibre. This process is assisted by agitation of
the fibre, dyebath or both together with heat.
n Fixation ensures the dye molecule is attached to the fibre either by physical forces or chemical
bonding. These forces may be weak or strong.
Most dyeing processes need heat to provide the energy for the dyeing to take place. This is
commonly supplied by direct or indirect steam.
A P P LY I N G D Y E S T U F F S
MACHINERY USED
Package Dyeing or exhausted. The perforations in the tube allow the
Dyeing may take place at the yarn stage. Yarn dye to flow through the yarn package.
dyeing is generally carried out on package dyeing
Once exhaustion is achieved, the carrier of coloured
machinery where the yarn is destined for sewing
yarn is removed from the vessel. Excess water is
threads or knitting and weaving into striped or
removed from the packages in a large centrifuge.
patterned fabrics. Yarn may also be dyed in the
The yarn is then dried in an infra red drying oven.
hank form. This form is most commonly used in the
wool industry, particularly where the yarn is destined Winch Dyeing
for carpet manufacturing. Winch dyeing machines are a low cost design that is
Package dyeing is a method of dyeing textiles in simple to operate and maintain, yet versatile in
yarn form. The yarn is first wound onto perforated application proving invaluable for preparation,
plastic tubes or spiral springs. In this form the yarn washing or after treatments as well as the dyeing
is known as a package. The undyed yarn packages stage itself.
are loaded onto a carrier ready for dyeing in a In all winch dyeing machines a series of fabric ropes
package dyeing machine. When the carrier is full, of equal length are immersed in the dye bath but
the packages are compressed and secured. The part of each rope is taken over two reels or the
carrier holding the yarn is lowered into the dye winch itself. The rope of fabric is circulated through
vessel via an overhead crane. The vessel is closed the dye bath being hauled up and over the winch
so that it can be pressurised. Premixed dye is added throughout the course of the dyeing operation.
to a tank at the side of the machine. During the
dyeing cycle, the dye liquor will circulate constantly Dyestuff and auxiliaries may be dosed manually or
through the vessel and tank until all the dye is used automatically in accordance with the recipe method.
continued
continued
The high temperature jig works in much the Pigments are generally applied via a white
same way as the atmospheric jig but is a binder or printing paste. This is prepared by
pressurised vessel designed to operate at 130 mixing in a large vat. The colours to be printed
C. It is used for dyeing synthetic fibred woven are specified on a sheet for the operator. The
goods with disperse dyes. various pigments specified in the printing recipe
are added to the white binder and mixed
Beam Dyeing thoroughly to achieve the required colour.
In beam dyeing, fabric in open width is rolled onto
In rotary screen printing the printing paste is
a perforated beam. The beam is slid into a vessel
supplied through a pipe inside the screen itself. A
that can be closed and pressurised. The dye liquor
squeegee forces the paste through the holes in the
is circulated through the preformations in the beam
screen and onto the fabric passing below.
and colour thus impregnates the fabric.
In flat bed printing, the printing paste is poured into
Padding one side of the screen. The squeegee is then drawn
In cold pad batch padding fabric is passed through across the screen to force the paste through the
a dyebath in open width or tubular form and then design and onto the fabric.
through padding mangles which squeeze out the
excess dye. It is important that the fabric picks up a The printed fabric is dried in an oven at the end of the
constant amount of dye liquor otherwise the depth printing line. This process is similar for both flat bed
of shade will vary from one part of the fabric to the and rotary screen printing techniques. After drying,
other. After padding the fabric in open width form is pigments are then cured and dyestuffs are heat fixed.
taken up on an A-frame, wrapped in plastic and left
continued
continued
Direct
Reactive
Vat
Sulphur
Azoic
Acid 4
Disperse
Modified Basic
Pigment
A C T I V I T Y M A S T E R 2
continued
continued
METHOD
The aim of this test is to see how much colour 4. Add 150mls of washing solution to the glass
(dyestuff) runs from a test sample during washing jar. There should be a separate jar for each
causing staining to a white control fabric. fabric to be tested.
1. Cut a sample of fabric from each of the dyed In a commercial laboratory the test sample is
fabrics to be tested. Each sample must be 5cm added to the container of a testing machine
x 5cm. such as the Laundrometer. The container is
normally filled with washing solution in a
liquor to specimen ratio of 50:1.
When fabrics have been dyed they water. The standards used by a particular
must be tested to ensure the colour is fast to company may be international or specific to
water. This test is designed to simulate the country in which the product is dyed.
conditions in the home once fabrics have been
washed and rinsed. Sometimes, wet clothing ACTIVITY
If you work in Industry, collect samples from fabrics
or products may be left in the washing
that have been dyed and follow the standard test
machine or in a basket for a period of time procedures carried out in your place of work or watch
before hanging on the clothesline or placed in the laboratory technician as they carry out the test.
the tumble dryer. Dyes that have poor fastness If you are studying colouration and dont have
access to standards and textile laboratory
to water may leach out of the textile and stain
conditions, then follow the simple test procedure
the textile lying next to it. There are standard detailed below.
test methods for checking colourfastness to
n Fabric samples dyed from different n White undyed polyester fabric (enough to
dyestuffs for testing measuring 50mm x cut samples for each test fabric of
50mm dimension 5cm x 5cm)
n Control sample of each fabric to be n Small dish or glass weight
tested n Large petri dish
n White undyed cotton fabric (enough to n Needle and thread
cut samples for each test fabric of
dimension 5cm x 5cm) n Distilled water
n Warm Oven (40°C ± 2°C)
continued
continued
METHOD
The aim of this test is to see how much colour 6. Place the petrie dish with the prepared sample
(dyestuff) runs from a test sample in contact with into a preheated oven at 40°C ± 2°C. Leave
undyed cloths when exposed to water. for 4 hours.
CROSSWORD
2
A C R O S S 1 2 3 4 5 6 7
of an azoic dye. 12
a dye.
26. Item of finishing equipment. 30 31
Stick sample
here
Stick sample
here
Stick sample
here
Stick sample
here
VIDEO REVIEW CHECKSHEET
............................................................. ...........................................
continued
continued
13. Disperse dyes are applied ............................... 8. What are the two main methods of pad
dyeing?
...........................................
.............................................................
14. Disperse dyes are trapped in the fibre upon
cooling and held by ........................................ .............................................................
15. Modified basic dyes are used to dye 9. How is a design developed on a printing
.................................................... screen?
8. auxochrome 4. knitted
loosely woven fabrics
Dye-Fibre Affinity 5. more economical
1. cotton, viscose rayon uses less water, dyes, chemicals and energy
more gentle on the fabric
2. van der waals forces
6. heavy or tightly woven fabrics in open width
3. washfastness form to avoid creasing
ACTIVITY M A S T E R 5
CROSSWORD SOLUTION
1 2 3 4 5 6 7
C O U P L I N G C O M P O U N D S
X E R I
8
C P
9
J I G U E G
10
F
11
P O E
D C Y R
12
A C R Y L I C
13 14
C A T I O N D A S E O T
T I T T C U R
I A
15 16
F I X A T I O N I R O
O Z Z O E P A P
17 18 19
A N I O N L O N S I T H C
F I E T S T I O A
20
F C V I D A O T R
I E S O T N O R
21
N A P H T
22
O L E P
23
I E M I
I H 24
D Y E I N G E E
T 25
R E C I P E F 26
S T E N T E R
Y R R E
27 28 29
M O D I F I E D B A S I C D R Y
O A
30
A F T E R T R E A T M E N T
31
R
I I N
32 33
A U X I L I A R Y E X H A U S T
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