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Observations were made of substructures called "striations" that formed in lead crystals grown by zone melting. Striations are arrays of dislocations that form depending on impurity concentration, freezing rate, and temperature gradient at the solid-liquid interface. Crystals grown at higher ambient temperatures, and thus lower temperature gradients, were less likely to exhibit visible striations. Striation formation was also inhibited at both very high freezing rates and very low temperature gradients. The width and misorientation of striations decreased with lower temperature gradient over freezing rate. Pure materials did not form striations even at low gradients, while alloys developed cellular substructures instead of striations under extreme conditions.
Observations were made of substructures called "striations" that formed in lead crystals grown by zone melting. Striations are arrays of dislocations that form depending on impurity concentration, freezing rate, and temperature gradient at the solid-liquid interface. Crystals grown at higher ambient temperatures, and thus lower temperature gradients, were less likely to exhibit visible striations. Striation formation was also inhibited at both very high freezing rates and very low temperature gradients. The width and misorientation of striations decreased with lower temperature gradient over freezing rate. Pure materials did not form striations even at low gradients, while alloys developed cellular substructures instead of striations under extreme conditions.
Observations were made of substructures called "striations" that formed in lead crystals grown by zone melting. Striations are arrays of dislocations that form depending on impurity concentration, freezing rate, and temperature gradient at the solid-liquid interface. Crystals grown at higher ambient temperatures, and thus lower temperature gradients, were less likely to exhibit visible striations. Striation formation was also inhibited at both very high freezing rates and very low temperature gradients. The width and misorientation of striations decreased with lower temperature gradient over freezing rate. Pure materials did not form striations even at low gradients, while alloys developed cellular substructures instead of striations under extreme conditions.
An Apparent Solar Periodicity in Radio Star Scintillation
From the beginning of December 1957 t o the end of November 1958, the radio sources Cassiopeia-A, Cygnus-A, Taurus-A, and Virgo-A were observed a t upper culmination from the Radio Observatory of Queen's University, Kingston, Ontario. The scintillation charac- teristics of each of the sources were studied a t 50 Mc/s and significant correlations were obtained with local magnetic indices. I t is generally accepted t hat the geomagnetic field exhibits cyclic changes which are related t o the period of rotation of the photosphere (Chapman 1940). The high correlation between scintillation and magnetic activity obtained by the authors and others (Dagg 1957) would suggest a similar periodicity ill scintillation data. In an at t empt t o discover if such periodicity exists in the present records, an autocorrelation function was calculated for the scintillation Index for Cygnus-A, the source showing highest correlation with magnetic activity. The scintillation index used was a lneasure of both amplitude and rat e of scintillation. This function is shown in the accolllpanying figure, for intervals up t o 33 sidereal days. The limits shown are probable errors based solely on the number of observations. The solid line is a 5-day running mean t o indicate the trend of the data. I t can be seen t hat a significant correlation is obtained after about 27 days. A quasi-period of 27.6 sidereal days has been estimated from the running meall, but this is subject to considerable error. These results strongly suggest t hat solar activity contributes directly t o t he ionospheric processes responsible for the scintillation of radio stars, a t least a t locations in or near t he auroral zone. CHAPLIAN. S. 1940. Geomagnetism. 1'01. I (Clarendon Press. Oxford), pp. 370-381. DAGC. M. 1957. J. Atmospheric and Terrest. Phys. 10. 191. RECEIVED APRIL 19. 1960. ASTRONOMY GROUP. QUEEN'S UNIVERSITY. KIXGSTON. ONTARIO. *Row at Queen's University. Belfast. N. Irelancl. \V. D. RYAK* AND G. A. HARROWER Observations of Macromosaic Substructures in Lead Previous investigations on lnacrolnosaic substructures called "striations" (Teghtsoonian and Chalmers 1951, 1952; Atwater and Chalmers 1957) have illustrated the effects of freezing velocity, impurity type and content, and crystal orientation upon the formation and charac- teristics of these dislocation arrays. The present investigation illustrates the effects produced by the temperature distribution in the liquid and solid a t t he interface. Single crystals of lead and lead-silver alloys in the range 10-"-10-2 at.% Ag were grown horizontally in graphite-coated lavite boats by the zone-melting technique illustrated in Fig. 1. The unique feature of this s t ~l dy is t hat the crystals were grown under varying amblent temperatures as illustrated. By varying the ambient temperature, TA, relative t o the melting temperature, T,, the etfect of the telnperature distribution on array formation could be studied. Two sizes of crystals were grown, each 2 in. wide and 7 in. long, some in. deep and others 2 in. deep. The thicker crystals were solidified with the solid-liquid interface perpendicular Can. J. Pl~ys. Vol. 38 (1960) C a n .
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CANADIAN JOURNAL OF PHYSICS. VOL. 38. 19GO Temperature Distribution l ~ y c o r Tube Furnace --=zone Heoter Specimen Arrangement FIG. 1. Zone melting apparat us and temperature distribution throughout specimen. t o the crystal axis, whereas it was not always possible to maintain this interface orientation for the thinner crystals a t the highest ambient temperature. The main body of experiments were carried out a t a freezing velocity, v, of 2 mm/ n~i n and the results are presented in Table I. At each ambient temperature two crystals were grown. TABLE I Striation formation Conditions Puri t y Alloy concentration at.% Ag AT,,,. OC Size Z.R.* 99.9999 10-4 10-1 10-2 13 Snlali - - (+) - - - 32 Large - - + + - - - - - - 40 Small + + + - - - 60 Large + + + + - - Small loo Large + + + + + + 102 + + + + + + NOTE: - indicates no striations visible; + indicates striations visible. *This lead was zone-refined from a st art i ns material of 99.999970 quoted purity. An additional experi~nent was performed with CO = at . % Ag and A T = 100" C using various v. Two crystals were grown a t v = 8 mm/min yielding visible arrays but much narrower striations than a t v = 2 mm/min. Two crystals were grown a t v = 20 mm/min and no striation arrays were evident even though a \veil-developed cellular substructure (Rutter and Chalmers 1953) was visible. ------ None G/V oC-sec/ crn2 FIG. 2. Scheniatic illustration of the dependence of striation formation on the solute concentration. Ca, and the ratio of temperature gradient. G, t o growth velocity. 1,. C a n .
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LETTERS TO THE EDITOR 885 Since decreasing AT decreases the temperature gradient in the solid a t t he interface and consequently the gradient in the liquid a t the interface, G, the results of Table I can be illustrated schematically a s in Fig. 2. With very pure material no striations are produced even with low G, whereas, for crystals containing some measurable solute concentration, striation formation is inhibited only under extremes of high v or low G. However, it was noted t hat under such extremes a well-developed cellular substructure was observed in the crystals. I t was also observed t hat (i) the incubation distance for striations, i.e. the amount of crystal grown before striation arrays appear, increased as G decreased, (ii) the width of the striations decreased a s G/u decreased, and (iii) the misorientation decreased as G/v decreased. These results suggest t hat , in high purity lead, insufficient dislocations were grown into the crystals to cause array formation and in lead-silver alloys, if the cellular substructure is well developed, the solute segregation decreases the mobility of dislocations to the point t hat array formation cannot occur. ATWATER. H. A. and CHALMERS. B. 1957. Can. J. Phys. 35, 208. RUTTER. J. W. and CAALMERS, B. 1953. Can. J. Phys. 31, 15. TEGHTSOONI~\N. E. and CHALMERS. B. 1051. Can. J. Phys. 29, 370. - 1952. Can. J. Phys. 30. 388. C a n .
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This article has been cited by: 1. G. F. Bolling, D. Fainstein. 1972. On vacancy condensation and the origin of dislocations in growth from the melt. Philosophical Magazine 25:1, 45-66. [CrossRef] 2. M.D. Hunt, J.A. Spittle, R.W. Smith. 1968. Microsegregation and crystal perfection in metals. Journal of Crystal Growth 3-4, 656-662. [CrossRef] C a n .
B. R. M N H.R. R, P. E. J. N A. C. E, N. W. M, R. A. M, A. N. V, F. C, A. C. F, P. S, C.C. K, S. A. B, J. N. B, M. D, E. E, S. H, C. P. O'd, J.B.R. O, G. T, G.M. V