Batch : Impulse & Momentum Date : 27/01/2014

Time : 3 hour Max. Marks : 360

INSTRUCTIONS
Please ensure that the Question Paper you have received contains all the QUESTIONS and Pages.
If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.
1. The question paper contains 90 questions. All of them are compulsory.
Q.1 to Q.90 have only one correct alternative and carry 4 marks each.
There is NEGATIVE marking and 1 mark will be deducted for each wrong answer.
2. Indicate the correct answer(s) for each question by filling appropriate bubble(s) in your OMR sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. For example if only 'B' choice is correct then, the correct method for filling the bubble is
A B C D
For example if only 'B & D' choices are correct then, the correct method for filling the bubbles is
A B C D
The answer of the question in any other manner (such as putting , cross , or partial shading
etc.) will be treated as wrong.
USEFUL DATA
Atomic Mass: Al =27, Mg =24, Cu =63.5, Mn =55, Cl =35.5, O =16, H =1, P = 31, Ag =108, N =14,
Li =7, I =127, Cr =52, K=39, S =32, Na =23, C =12, Br =80, Fe =56, Ca =40, Zn =65.4, Ba =137,
Co =59, Hg =200, Pb =207, He =4, F=19, Ar =40.
Radius of nucleus =10
14
m; h =6.626 10
34

Js; m
e
=9.1 10
31
kg, R
H
=109637 cm
1
.
Take g = 10 m/s
2
where ever required.
TEST PAPER
A-49, Moulana Azad Sarani, City Centre, Durgapur-16, Ph: 7699999929 www.iitjeeguru.in
Q.1 If (1, 2) is one of the points of intersection of the graphs of ax
2
+by
2
=5 and bx
2
+ay
2
=5, then
find a +b.
(A) 2 (B) 3 (C) 4 (D) 5
Q.2 The continued fraction
. .......... 2
1
2
1
2
1
2

, has the value equal to

(A) 1 (B) 5/4 (C) 3/2 (D) 7/4
Q.3 If 0 <x <2t and 2
tan x
=4
sin x
then the number of value of x is ________.
(A) 1 (B) 2 (C) 3 (D) 4
Q.4 Given the following system of equations
3
1
y
1
x
1
= +
;
5
1
z
1
x
1
= +
;
7
1
z
1
y
1
= +
The value of the ratio
y
z
is
(A) 17 (B) 23 (C) 29 (D) 31
Q.5 The equation
2
x
2 =16
2x 3
has two solutions. Their sum is
(A) 0 (B) 2 (C) 6 (D) 8
Q.6 If sin
2
x +sin x cos x 6cos
2
x =0 and 0 x
2
< <
t
, then the value of tan x, is
(A) 0 (B) 3 (C) 2 (D) 6
Q.7 If sin o =
13
5
and o is in Quadrant III, then the value of |
.
|

\
| o
2
cos , is
(A)
13
6

(B)
26
1
(C)
12
5
(D)
26
26

SPACE FOR ROUGH WORK

MATHEMATICS
Q.8 The value of the parameter m for which the equation
1 x 3
2 x
+
+
=
m x 6
1 x 2

has no solution for x,

is
(A) 12 (B) 18 (C) 14 (D) 13
Q.9 The value of x such that 4(1 +y)x
2
4x +1 y =0 is true for all real values of y, is
(A) 1/2 (B) 2/3 (C) 2/3 (D) 1/2
Q.10 Knowing that 2 is a solution of the equation 6x
3
25x
2
+32x 12 =0, the sum of the other
two solutions, is
(A) 12/5 (B) 12/5 (C) 13/6 (D) 13/6
Q.11 Suppose that x & y are numbers such that sin (x +y) =3/10 and sin (x y) =1/2. The value of
sinxcosy is
(A) 0.1 (B) 0.2 (C) 0.3 (D) 0.4
Q.12 If a +b =1 and a
2
+b
2
=85, then the value of (a
3
+b
3
), is
(A) 127 (B) 173 (C) 154 (D) 321
Q.13 The set of values of k for which the sum of the roots of P(x) =4x
2
+k
2
x +k is equal to twice
the product of the roots is
(A) {2} (B) {2, 0} (C) {0} (D) {2}
Q.14 If b a = 4 3 and c b = 9 8 and d c = 3 2 , then
2
b ad
is equal to
(A)
81
64
(B)
84
61
(C)
64
81
(D)
61
84
Q.15 Number of diagonals in a regular polygon with 20 sides, is
(A) 170 (B) 180 (C) 190 (D) 200
Q.16 The value of m for the zeros of the polynomial P(x) =2x
2
mx 8 differ by (m 1) is
(A) 4,
3
10
(B) 6,
3
10
(C) 6,
3
10
(D) 6,
3
10
Q.17 If f(4) =g(4) =2 ; f

'

(4) =9 ; g

'

(4) =6 then
Limit
x 4
f x g x
x
( ) ( )
2
is equal to :
(A) 3 2 (B)
3
2
(C) 0 (D) none
Q.18 The value of x satisfying the equation, x =
x 2 2 2 + +
is
(A) 2 cos 10 (B) 2 cos 20 (C) 2 cos 40 (D) 2 cos 80
SPACE FOR ROUGH WORK
Q.19 log
3
1
1
3
+
|
\

|
.
| +log
3
1
1
4
+
|
\

|
.
| +log
3
1
1
5
+
|
\

|
.
| +.............. +log
3
1
1
242
+
|
\

|
.
| when simplified has the
value equal to
(A) 1 (B) 3 (C) 4 (D) 5
Q.20 In the inequality below the value of the angle is expressed in radian measure. Which one of the
inequalities below is true?
(A) sin 1 <sin 2 <sin 3 (B) sin 3 <sin 2 <sin 1
(C) sin 2 <sin 1 <sin 3 (D) sin 3 <sin 1 <sin 2
Q.21 The locus of z, for arg z = 3 t is
(A) same as the locus of z for arg z = 3 2t
(B) same as the locus of z for arg z = 3 t
(C) the part of the straight line
y x 3 +
=0 with (y <0, x >0)
(D) the part of the straight line
y x 3 +
=0 with (y >0, x <0)
Q.22 For R xe , the difference between the greatest and the least value of y =
1 x
x
2
+
is
(A) 1 (B) 2 (C) 3 (D)
2
1
Q.23 The equation (x e R)
x
x
2
2
1
1
5
3
+

=x
(A) has no root (B) exactly one root (C) two roots (D) four roots
Q.24 Let f (x) =

<


>

2 x if
2 x 3 x
4 x
2 x if
2 2
6 2 2
2
x 1 x
x 3 x
then
(A) f (2) =8 f is continuous at x =2 (B) f (2) =16 f is continuous at x =2
(C) f (2

) = f (2
+
) f is discontinuous (D) f has a removable discontinuity at x =2
SPACE FOR ROUGH WORK
Q.25 Consider 8 vertices of a regular octagon and its centre. If T denotes the number of triangles and
S denotes the number of straight lines that can be formed with these 9 points then T S has the
value equal to
(A) 44 (B) 48 (C) 52 (D) 56
Q.26
n
r
n
r
n
r
r
n
C
C C +
+
=

1
0
1
is equal to :
(A)
n
2
(B)
n n
n
( )
( )

+
1
2 1
(C)
n+1
2
(D)
n n ( ) +1
2
Q.27 If the roots of the quadratic equation (4p p
2
5)x
2
(2p 1)x +3p =0 lie on either side of
unity then the number of integral values of p is
(A) 0 (B) 1 (C) 2 (D) infinite
Q.28

The absolute term in the quadratic expression

=
|
.
|

\
|

|
.
|

\
|
+

n
1 k
2 k 3
1
x
1 k 3
1
x
as n is
(A) zero (B) 1 (C)
3
2
(D)
3
1
Q.29 Starting with a unit square, a sequence of square is generated. Each square in the sequence
has half the side length of its predecessor and two of its sides bisected by its predecessor's
sides as shown. This process is repeated indefinitely. The total area enclosed by all the squares
in limiting situation, is
(A)
4
5
sq. units (B)
64
79
sq. units
(C)
64
75
sq. units (D)
12
1
sq. units
Q.30 What is the radius of the smallest circle that contains both of the circles x
2
+y
2
=4 and
(x 3)
2
+(y 3)
2
=9?
(A)
2
5 3 3 +
(B)
2
7 3 3 +
(C)
2
5 2 3 +
(D)
2
7 2 3 +
SPACE FOR ROUGH WORK
Q.31 Three projectiles A, B and C are thrown simultaneously from the
same point in the same vertical plane. Their trajectories are shown
in the figure. Then which of the following statement is false.
(A) The time of flight is the same for all the three.
(B) The launch speed is greatest for particle C.
(C) The vertical velocity component for particle C is greater than that for the other particles
(D) Ycoordinate of all particles is always same
Q.32 Suppose a player hits several baseballs. Which baseball will be in the air for the longest time?
(A) The one with the farthest range.
(B) The one which reaches maximum height.
(C) The one with the greatest initial velocity.
(D) The one leaving the bat at 45 with respect to the ground.
Q.33 Two blocks are arranged as shown in the figure. The
relation between acceleration a
1
and a
2
is :
(A) a
1
=a
2
(B) a
1
=6a
2
(C) a
1
=3a
2
(D) a
1
=4a
2
Q.34 To man running at a speed of 5 m/sec,the rain drops appear to be falling at an angle of 45 from
the vertical. If the rain drops are actually falling vertically downwards, then velocity in m/s is
(A) 5 (B)
5 3
(C)
5 2
(D) 4
Q.35 Three blocks are connected as shown in the figure, on a horizontal
frictionless table and pulled to the right with a force at 60N. if
M=10kg, M
2
=20kg and M
3
=30 kg then the value of T
2
is
(A) 40N (B) 30N (C) 20N (D) 10N
PHYSICS
SPACE FOR ROUGH WORK
Q.36 Find the time in which 2 kg mass will strikes the pulley
after being released from rest.
(A) 10 sec (B) 2 sec
(C) 5 sec (D) 4 sec
Q.37 The wedge is moved with constant horizontal acceleration a. For which
of the following values of a will the acceleration of the block be different
from its acceleration in other three cases.
(A) 2 g (B) 3g (C) g (D)
10
g
Q.38 A trolley is accelerating down an incline of angle u with
acceleration g sinu. Which of the following is correct.
(o is the angle made by the string with vertical).
(A) o =u (B) o =0
0
(C) Tension in the string, T =mg (D) Tension in the string, T =mg sec u
Q.39 Which of the following is correct about kinetic friction?
(A) Always acts in opposite direction of the applied force.
(B) total work done by this force on the system may be zero.
(C) direction of friction is always apposite to direction of velocity.
(D) it can increase velocity.
Q.40 The net contact force on the 1 kg block is
(A) 5 4 N (B) 10 3 N
(C) 20 3 N (D) 10 N
SPACE FOR ROUGH WORK
Q.41 An object moves counter-clockwise along the circular path shown below.
As it moves along the path its acceleration vector continuously points towards
point S. The object
(A) speeds up at P, Q and R
(B) slows down at P, Q and R
(C) speeds up at P and slows down at R.
(D) slows down at P and speeds up at R.
Q.42 The work done by a force
) i

x 6 ( F
3
=

N in displacing a particle from x =4 m to x =2 m is

(A) 240 J (B) 360 J (C) 420 J (D) will depend upon the path
Q.43 Consider the configuration (shown below) of a rope that is half
hanging over the edge of a frictionless table. Suppose the rope
has a mass per unit length of kg/m. How much work is done
by a force that slowly pulls the entire rope up onto the table?
Select the correct answer.
(A) L
2
g (B)
8
g L
2

(C)
4
g L
2

(D) None
Q.44 A particle parallel to x-axis as shown in the figure such that at all instant
the y-axis component of it's position vector is constant and is equal to
'b'. The angular velocity of the particle about the origin is
(A)
b
v
sin
2
u (B)
b
v
(C)
b
v
sin u (D) vb
Q.45 A particle of mass m rotates in a circle of radius R with a uniformangular speed e. It is observed
from a frame rotating about the same axis with a uniform angular speed e
0
in same sense. The
acceleration of particle as observed in the rotating frame is
(A) e
2
R R
2
0
e (B) (ee
0
)
2
R (C) R
2
0
e (D) e
2
R
SPACE FOR ROUGH WORK
Q.46 A particle of mass m is going along surface of smooth hemisphere of
radius R. At the moment shown its speed is v.Choose correct option.
(A) mg Nsinu =m(gcos
2
u
R
v
2
sinu ) (B) mg Nsinu =0
(C) mg Nsinu =
R
mv
2
(D) None of these
Q.47 Which of the following best illustrates the acceleration of a pendulum bob at points a through
e?
(A) (B) (C) (D)
Q.48 Three men A, B & C of mass 40kg, 50kg & 60kg are standing
on a plank of mass 90kg, which is kept on a smooth horizontal
plane. If A & C exchange their positions then mass B will shift
(A) 1/3m towards left (B) 1/3m towards right
(C) will not move w.r.t. ground (D) 5/3 m towards left
Q.49 A ball is thrown downwards with initial speed =6 m/s, from a point at height =3.2 mabove a
horizontal floor. If the ball rebounds back to the same height then coefficient of restitution equalto
(A) 1/2 (B) 0.75 (C) 0.8 (D) None
Q.50 A ball of mass 1kg strikes a heavy platform, elastically, moving upwards
with a velocity of 5m/s. The speed of the ball just before the collision is
10m/s downwards. Then the impulse imparted by the platform on the
ball is
(A) 15 N s (B) 10 N s (C) 20 N s (D) 30 N s
SPACE FOR ROUGH WORK
Q.51 A small ball is dropped from a height h onto a rigid frictionless plate at
B and rebounds. Find the maximum height reached after rebound if the
coefficient of restitution between the ball and the plate is e =0.75:
(A) 0 (B) 3h /25
(C) 3h/125 (D) 9h/625
Q.52 AB and CD are two identical rods each of length L and mass M
joined to form a cross. Find the M.I. of the system about a
bisector of the angle between the rods (XY)
(A)
12
ML
2
(B)
6
ML
2
(C)
3
ML
2
(D)
3
ML 4
2
Q.53 A wheel is made to roll without slipping, towards right, by pulling
a string wrapped round a coaxial spool as shown in figure. With
what velocity the string should be pulled so that the centre of the
wheel moves with a velocity of 3 m/s?
(A) 3 m/s (B) 1 m/s (C) 3/2 m/s (D) 2 m/s
Q.54 If 100 g of ice at 0C is mixed with 100 g of boiling water at 100C, which of the following
graphs would best represent the temperature v/s time of the two components of the mixture?
(A) (B) (C) (D)
Q.55 Suppose there is a hole is a copper plate. Upon heating the plate, diameter of hole, would :
(A) always increase (B) always decrease
(C) always remain the same (D) none of these
SPACE FOR ROUGH WORK
Q.56 A particle moves along the x-axis according to : x =A.[1 +sin et]. What distance does is travel
between t =0 and t =2.5t/e?
(A) 4A (B) 6A (C) 5A (D) None
Q.57 An infinite number of masses, each of one kg are placed on the +ve X axis at 1m, 2m, 4m,
______ fromthe origin. The magnitude of the gravitational field at origin due to this distribution
of masses is:
(A) 2G (B)
3
G 4
(C)
4
G 3
(D)
Q.58 Two point masses of mass 4m and m respectively separated by d distance are revolving under
mutual force of attraction. Ratio of their kinetic energies will be :
(A) 1 : 4 (B) 1 : 5 (C) 1 : 1 (D) 1 : 2
Q.59 A simple harmonic motion having an amplitude A and time period T is represented by the
equation y =5 sin t(t +4) m Then the values of A (in m) and T (in sec) are :
(A) A =5; T =2 (B) A =10 ; T =1 (C) A =5 ; T =1 (D) A =10 ; T =2
Q.60 A composite rod made of three rods of equal length and cross-section as shown in the fig. The
thermal conductivities of the materials of the rods are K/2, 5K and K respectively. The end A
and end B are at constant temperatures. All heat entering the face A goes out of the end B
there being no loss of heat from the sides of the bar. The effective thermal conductivity of the
bar is
B
A
K 5K K/2
(A) 15K/16 (B) 6K/13 (C) 5K/16 (D) 2K/13.
SPACE FOR ROUGH WORK
Q.61 2Pentene contains
(A) 15 o & one t bonds (B) 14 o & one t bonds
(C) 13 o & two t bonds (B) 14 o & no t bonds
Q.62 The number of isomers of formula C
4
H
10
is
(A) 1 (B) 2 (C) 3 (D) 4
Q.63 An isomer of propanal is
(A) Acetone (B) Propane (C) Ethanol (D) Propanol
Q.64 Which one of the following is strongest acid
(A) 2chloropentanoic acid (B) 3chloropentanoic acid
(C) 5chloropentanoic acid (D) 4chlorpentanoic acid
Q.65 For which carboxylic acid, the pKa value is the lowest:
(A) CH
3
CH
2
COOH (B) CH CCOOH
(C) CH
3
CH
2
CH
2
COOH (D) CH
2
=CHCOOH
Q.66The correct arrangement of acid strength in decreasing order is
(A) (CH
3
)
3
CCOOH >CH
3
COOH >CCl
3
COOH >O
2
NCH
2
COOH
(B) CH
3
COOH >(CH
3
)
3
CCOOH >O
2
NCH
2
COOH >CCl
3
COOH
(C) O
2
NCH
2
COOH >(CH
3
)
3
CCOOH >CH
3
COOH >CCl
3
COOH
(D) CCl
3
COOH >O
2
NCH
2
COOH >CH
3
COOH >(CH
3
)
3
CCOOH
Q.67Basic strength of CH C
O
(I), CH
2
=CH
O
(II), CH
3
CH
O
2
(III) will be in order :
(A) I <II <III (B) II <III <I (C) III <II <I (D) III <I <II
Q.68What is the correct order of acidity of the following hydra-acid?
(A) HF >HCl >HBr >HI (B) H
2
O >H
2
S >H
2
Se >H
2
Te
(C) H
2
O <H
2
S <H
2
Se <H
2
Te (D) HI >HBr >HCl >HF
Q.69Which of the follwing acting as electrophile?
(A) H

(B) NH
3
(C) H
2
O (D) BF
3
CHEMISTRY
SPACE FOR ROUGH WORK
Q.70 24 mL of HI are produced from the reaction of 15 mL of
2
H and 17.1 mL of
2
I vapour at 444
o
C
The equilibrium constant for the reactionH
2
+I
2
=2HI at 444
o
C
(A)27.5 (B)37.647 (C)73.647 (D) 57.25
Q.71 For the gas phase reaction, C
2
H
4
+H
2
C
2
H
6
(AH = 32.7 kcal), carried out in a closed vessel,
the equilibrium concentration of C
2
H
4
can be increased by
(A) increasing the temperature (B) decreasing the pressure
(C) removing some H
2
(D) adding some C
2
H
6
Q.72 An exothermic reaction is represented by the graph :
(A) (B) (C) (D)
Q.73 The correct relationship between free energy change in a reaction and the corresponding equilibrium
constant K is
(A) AG =RT ln K (B) AG =RT ln K (C) AG =RT ln K (D) AG =RT ln K
Q.74 The conjugate acid of

2
NH is
(A) NH
3
(B) NH
2
OH (C)
+
4
NH
(D) N
2
H
4
Q.75 pH of an aqeous solution of NaCl at 85C should be
(A) 7 (B) >7 (C) <7 (D) 0
Q.76 1 CC of 0.1 N HCl is added to 99 CC solution of NaCl. The pH of the resulting solution will be
(A) 7 (B) 3 (C) 4 (D) 1
Q.77 10 ml of
200
M
H
2
SO
4
is mixed with 40 ml of
200
M
H
2
SO
4
. The pH of the resulting solution is
(A) 1 (B) 2 (C) 2.3 (D) none of these
Q.78 The pH of an aqueous solution of 1.0 M solution of a weak monoprotic acid which is 1% ionised
is
(A) 1 (B) 2 (C) 3 (D) 11
SPACE FOR ROUGH WORK
Q.79 If K
1
& K
2
be first and second ionisation constant of H
3
PO
4
and K
1
>>K
2
which is incorrect.
(A) [H
+
] =[

4 2
PO H ] (B) [H
+
] = ] PO H [ K
4 3 1
(C) K
2
= ] HPO [
4

(D) [H
+
] = ] PO [ 3
3
4

Q.80 The compound whose 0.1 M solution is basic is

(A) Ammonium acetate (B) Ammonium chloride
(C) Ammonium sulphate (D) Sodium acetate
Q.81 Which of the following solution will have pH close to 1.0?
(A) 100 ml of M/100 HCl +100 ml of M/10 NaOH
(B) 55 ml of M/10 HCl +45 ml of M/10 NaOH
(C) 10 ml of M/10 HCl +90 ml of M/10 NaOH
(D) 75 ml of M/5 HCl +25 ml of M/5 NaOH
Q.82 The partial pressure of CH
3
OH, CO and H
2
in the equilibrium mixture for the reaction
CO +2H
2
CH
3
OH at 427
0
C are 2.0, 1.0 and 0.1 atm. respectively. The value of k
P
for
the decomposition of CH
3
OH to CO and H
2
is
(A) 1 X 10
-2
atm (B) 2 X 10
2
atm
-1
(C) 50 atm
2
(D) 5 X 10
-3
atm
2
Q.83 From separate solution of four sodium salts NaW, NaX, NaY and NaZ had pH 7.0, 9.0,10.0
and 11.0 respectively. When each solution was 0.1M, the strongest acid is
(A)HW (B)HX (C)HY (D)HZ
Q.84 To prepare a buffer of pH 8.26, amount of (NH
4
)
2
SO
4
to be added into 500 ml of 0.01 M
NH
4
OH solution [pK
a
(NH
4
+
) =9.26] :
(A) 0.05 mol (B) 0.025 mol (C) 0.10 mol (D) 0.005 mol
Q.85The pH of the solution when 0.2 mole of HCl is added to one litre of a solution containing
0.1 M CH
3
COOH and 0.1 M CH
3
COO

is
(A) 0.7 (B) 4.57 (C) 3.8 (D) 1.0
SPACE FOR ROUGH WORK
Q.86 When 0.4 g of NaOH is dissolved in one litre of solution, the pH of the solution is
(A) 12 (B) 2 (C) 6 (D) 10
Q.87 pH of the solution obtain on mixing 300 ml of solution having pH =2, 800 ml of solution
having pH =12 and 900 ml of solution having pH =13 is
(A) 12.67 (B) 2 (C) 11.67 (D) 13
Q.88 How many times (approximately) should an extremely weak monobasic acid, HA, be diluted,
so that the hydrogen ion concentration is reduced to
4
1
of that in the original solution?
(A) 16 (B) 2 (C) 4 (D) 8
Q.89 If 50 ml of 0.2 M KOH is added to 40 ml of 0.5 M HCOOH, the pH of the resulting solution
is : (K
a
=1.8 10
4
)
(A) 3.75 (B) 5.6 (C) 7.5 (D) 3.4
Q.90 Among the following compounds which has the largest dipole moment
(A) CH
3
OH (B) CH
4
(C) CF
4
(D) CH
3
F
SPACE FOR ROUGH WORK