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AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14

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1





ANSWERS, HINTS & SOLUTIONS
CRTI
(Paper-1)




Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
C C D
2.
A D A
3.
B D B
4.
B C A
5.
A B B
6.
D D A
7.
B C

C
8.
A. C A
9.
B B C
10.
C B A
11.
A, B, C A, C A, B, C
12.
A, B, C, D B, C A, B, C, D
13.
B, C, D A, C A, D
14.
A, B, C A, B, C B, C
15.
A, B, C A, C B, C
1.
2 2 4
2.
1 1 2
3.
5 4 6
4.
1 3 2
5.
2 6 3

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AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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2
P P h hy ys si i c cs s PART I


SECTION A

1.
rel
U g t 10 1 = =
=10 m/s

1
1
S g(1) 5m
2
= =

2
rel 1 re re
1
S S u a t
2
= + +

=5 +10 3 +0 =35 m

2. sin u =
h


mgh = mg cos u(/2)

h cos
2
u
=


tan u =
2




/2
/2



3. Centre of mass does not move in the absence of external force so
m
1
x
1
=m
2
x
2

1 2
2 1
x m
x m
=

4.
2 2
1
dA r d r
A
dt 2 dt 2
u
= = = e
L =
2
Mr e
L =2MA

5. F
2
Gm(M m)
0
r

= =

2
dF G
(M 2m) 0
dm r
= =
M =2m
m =(M/2)

6.
A g
s
A



s
g
=



7.
h
2
0
gh r (2 rdh) gh t = t
}


2
2
h
gh r 2 r g
2
t = t

h
r 2
2
=
r =h



AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
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3
8. Avg. speed
2 2
r mr
(v t) (v t)
3
t
+
=

2
r
v 5 9 + =

r
v 2m/ s =

9.
avg
1 t 1
v v
3v
2 2 2
v
t 4
+
= =

10.
m m
g T a
2 2
= (i)
T cos 60 =
ma
cos 60
(ii)
Solving (i) and (ii) acceleration of ring =
2g
9


11.
2 2
2
2kq mv
mg T
R R
+ = (i)
mgR +
2 2
1 1
mu mgR mv
2 2
= + (ii)
if T =0
2
min
2Kq
u 5gR
mR
=

12.
dU
F 5(2x 4)
dx
= =
At mean position F =0 x =2m

min
U 20 J =
a =50 2(x 2)
e =10 rad/sec
T =t/5 sec

13. If the volume immersed initially is (V/3). Then
V
g mg
3
= (i)
If the volume immersed when the system accelerates is V' then

g mg
V' g mg
2 2
| |
+ =
|
\ .

V
V'
3
=

14. The potential of the two surface will be equal when the whole charge Q flows from inner to other
shell.

SECTION C

1. Consideration refraction at glass-water interface

R u v
1 2 2

=

1


r
) 2 / 3 ( ) 3 / 4 (
r 2
3
v 3
4
=




r
(4/5)r
(27r/20)


AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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4

r 6
1
r 2
3
v 3
4
= +
v =
r
5

Now refraction at water air surface
u =-
5
r 9
r
5
4
r = |
.
|

\
|
+

1 2 1 2
u v

+
) 3 / 4 ( 1
r 9 3
5 4
v
1


r 27
20
v
1
=
v =-
20
r 27

so height above centre =2r -
20
r 27

=
20
r 27 r 40
=
20
13
r =13 cm.

2. Mg T =Ma (i)
T mg =ma (ii)
T =
2Mmg
(M m) +


9
T 2Mmg 2mg
2 10
m A A(M m)
A 1
M
= = =
+ | |
+
|
\ .

M =1.86 Kg

m
M


3. Relative motion between block and table
will start when

2 2
m r sin (mg m r cos ) e u = + e u (i)
t e = o (ii)
solving (i) and (ii)
t 500 22.4 sec = = .


4 cm
3 cm


m
2
r

4. e =
g
R

=1 rad/sec

5. N
1
+N
2
=mg . . . (1)
N
1
=N
2
. . . (2)
N
2
=
( )
2
mg
1+

N
1
=
( )
2
mg
1

+

N1
N2
N1
N2
mg

Torque about centre of mass

AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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5
(N
1
+N
2
)R =
2
1
mR
2
o
o =
( )
1 2
2 N N
mR
+
=
( )
( )
2
2 1 g
1 R
+
+

e
2
=
2
0
2 e ou
u =
2
0
2
e
o

u =
( )
( )
2 2
0
1 R
2 2 1 g
e +
+

Hence number of turns
N =
2
u
t
=
( )
( )
2 2
0
R 1
4 1 g.2
e +
+ t

N =
( )
( )
2 2
0
R 1
8 g 1
e +
t +


C Ch he em mi i s st tr r y y PART II


SECTION A

1. In A t bond is at bridge head which is not stabilized in the given structure;
In B the product is
CN
ACOH +
;
In D the product is

2.
O

H
2
N OH
O
NH
2
OH
IMPT

O H NH
O H
2
H O

N
OH
N
OH
2
H
+

2
H O

N
2
H O
H
+

N
OH


5. CH
3
Cl is formed by S
N
2 while CH
3
CHClC
2
H
5
is formed by S
N
i.

6.
( ) ( ) ( )
( ) ( )
5 3 2
PCl g PCl g Cl g
Let initially no. of moles x
at equilibrium volume V x 1 x x
+

o o o




AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
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6

( )
2 2
c
x
K
x 1 V
o
=
o
, also K
p
=K
c
(RT)
g
n A

on reducing volume to
V
2
, initial concentration of PCl
5
doubles and its degree of dissociation is
increased but K
p
does not change, as it is characteristic constant for a reaction at constant
temperature.

7. ( )
2 6 2 3
6
Al Cl 12H O 2H Al OH 6HCl ( + +

;

10. In blast furnace,
In combustion zone, CO is produced ultimately which reduce Fe
2
O
3
to Fe
3
O
4
in reduction zone,
which is uppermost zone.

11. O
O
3 2 5
CH COOH C H OH +
O
O
P =
Q =
R =
S =
Oxidation by XO
2 5 3
C H OH CH CHO

;


12. Due to hydrogen bonding Gauche conformation of H
2
C CH
2
NH
2
NH
2
and

H
2
C CH
2
F
OH

are more stable than their anti-conformations.
In case of ClCH
2
CH
2
Cl, on increasing temperature, % of Gauche conformation increases. Hence
dipole moment increases. In case of option (D) boat conformation is most stable.

13. Mn appears colourless in reducing flame in Borax Bead Test.
( ) ( )
3
4 4
6 6
3
Prussianblue
Fe K Fe CN Fe Fe CN K
+ +
( ( + + +



2 2 3 2 2 5 2 4 2
Na S O .5H O Na S Na SO H O
A
+ +

14. At pH =pI, amino acid exists as Zwitter Ion, they are highly soluble in polar solvents.


AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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7
15. pH of 10
8
M HCl (aq) is 6.96 and pH of 10
8
M NaOH (aq) is 7.04

SECTION C
1. t =CRT i
hence i =1.1; so o =0.1
hence [H
+
] =co =0.1 0.1 =10
2
M
pH =2

2. It has only one CH
2
OH group.

3. Three equivalents to remove three hydrogens from CH
3
group and one for attack on C of CHO
group.

4. BaCrO
4
Yellow, soluble in dil HNO
3

Hg
2
CrO
4
Red, soluble in conc. HNO
3

ZnS White, soluble in Conc. HNO
3

BaSO
4
White, insoluble in all mineral acids
BaS
2
O
3
, CH
3
COOAg and AgNO
2
all are white solid and are soluble in dilute HNO
3
solution.

5. Except
Cl
and
Cl




M Ma at th he em ma at ti i c cs s PART III


SECTION A


1. [y +[y]] =2 cosx [y] =cosx
y =
1
3
[sinx +[sinx +[sinx]]] =[sinx]
[sinx] =cosx
Number of solution in [0, 2t] is 0
Hence total solution is 0.
both are periodic with period 2t

2. (x 0)
2
+(y k)
2
=k
2

x
2
+(y k)
2
=k
2

2x +2 (y k)
dy
0
dx
=

dy x
dx y k
=


y k =
xdx
dy

k =y +
xdx
dy


AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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8
x
2
+
2 2
xdx xdx
y y y
dy dy
| | | | | |
+ = +
| | |
\ . \ . \ .

x
2
+
2 2
2 2 2
dx dx 2xydx
x y x
dy dy dy
| | | |
= + +
| |
\ . \ .

x
2
=y
2
+
2xydx
dy

(x
2
+y
2
)
dy
2xy 0
dx
=

3. Given o <| < <o also sin o =sin | =sin =sin o =k
and o, |, , o are smallest positive angles
| =t o, =2t +o, o =3t o
as sin | =sin o and | >o
sin | =sin and >|
sin =sin o and o >
Putting these values in the given expansion, we have given expression
=2 sin cos 2 1 sin 2 1 k
2 2
o o | |
+ = + o = +
|
\ .


4. x
3
x < a
2
+a
2
3 3

f(x) =x
3
x
f'(x) =3x
2
1 =0
x =
1
3

In positive region minimum value of f(x) =
1 1 2
3 3 3 3 3
=
So, a
2
+a
2
3 3
>
2
3 3

a
2
a <0
a e (0, 1)

5. 3x 2 4x 4 5x 1 4x 5 + + = + + (1)
v u p q
u
2
v
2
=x +6 =p
2
q
2

u v =p q (2)
solving (1) and (2)
we get, 2 4x 4 2 5x 1 + = +
x =3

6. Limit be equal to y
logy =
n
1
n 1 n 2
lim
log log ...
n
n n

(
+ + | | | |
+ + (
| |
\ . \ .

=
n
n
r 1
1
n r
lim
log
n
n

=
(
+ | |
(
|
\ .

= ( )
1
n
n
r 1
0
1 r
lim log log dx 1 1 x
n n

=
| |
= + + |
\ .

}


AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
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9
= . 2
1
log2
2
(

(

=[log4 loge] = log
4
e
| |
|
\ .

logy =log
4
e

| |
|
\ .


7. 0 s argz s
4
t
, represent the region of complex plane lying in the first quadrant and bounded by x-
axis and the line y =x
|2z 4i| =2|z 2i|
least value of |z 2i| is length of perpendicular from (0, 2) to y =x, which is 2
So the least value of 2 |2z 4i| is 4

8. Let f(x) =2x
3
+3x
2
12x +3
f(x) =0 has three real roots (o, |, )
o +| + =
3
2

Centroid = , ,
3 3 3
| |
o o o
|
|
\ .

=
1 1 1
, ,
2 2 2
| |

|
\ .
which lies on x =y =z.

9. If a >b >c and a
2
=b = c then b <1 cot
1
x <1 x >cot1

10. a s 4sinA
a
4
sinA
s R s 2
so for any point (x, y) inside the circumcircle, x
2
+y
2
<4
|xy| <2

11. a, b and ZA are given in AABC,
cos A =
2 2 2
b c a
2bc
+

c
2
2bc cos A +(b
2
a
2
) =0
c
2
(2b cos A)c +(b
2
a
2
) =0
which is quadratic in c and gives two values of c and let these are c
1
and c
2

c
1
+c
2
=2b cos A
and c
1
c
2
=(b
2
a
2
)

2 2
1 2 1 2
c c 2c c cos2A +
=(c
1
+c
2
)
2
2c
1
c
2
(1 +cos 2A)
=4b
2
cos
2
A 2 (b
2
a
2
) (2 cos
2
A)
=4b
2
cos
2
A 4b
2
cos
2
A +4a
2
cos
2
A
=4a
2
cos
2
A

12.
1 1 1
2 5 5 8 8 11
+ + +
+ + +
n terms
=
5 (n 1)3 2 (n 1)3 5 2 8 5 11 8
3 3 3 3
+ +
+ + + +
=
( )
3n 2 2 3n 2 2 n
3
3n 2 2 3 3n 2 2
+ +
= =
+ + + +


AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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10
=
n n
n
2 3n 2 3n
< <
+ +


13.
2
sin
24 R 2
t
=


R 2 1 cosec
24
t | |
= +
|
\ .

(A) is true
2
sin cos
2 2
1 cosec
sinA
o o | |
+
|
\ .
= + o
(D) is true

14. x
2
+x +1 =|[x]|
Hence only 2 solutions exist
i.e. x = 1 and another lie 2 <x < 1

15. sin x +cos x =1 a sin x cos x
a
2
sin
2
x cos
2
x 2(a +1) sin x cos x =0
sin2x
( )
2
a
sin2x 2
a 1
2
| |
| +
\ .
=0
Hence sin2x =0 a e R
x =
n
2
t
, n e I
And sin2x =
( )
2
4
a 1
a
+
a e (, 2 2 2 ] [2 +2 2 , )

SECTION C

1. a =
2 2
r 1 r 1
1 1
, b
r (2r 1)

= =
=



a =
2 2 2 2
1 1 1 1
...
1 2 3 4
+ + + + and b =
2 2 2 2
1 1 1 1
...
1 3 5 7
+ + + +
b =
2 2 2 2 2 2 2
1 1 1 1 1 1 1
... ...
1 2 3 4 2 4 6
| | | |
+ + + + + + +
| |
\ . \ .

b =
2 2 2 2 2 2 2
1 1 1 1 1 1 1
... 1 ...
1 2 3 4 2 2 3
| | | |
+ + + + + + +
| |
\ . \ .

b =a
1
4
a
b =
3
a
4


a 4
b 3
=

2.
1
0 0
f (x)dx tf (t)dt
t t

' =
} }


AITS-CRT-I(Paper-1)-PCM (Sol )-JEE (Adv)/14
FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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11
=
( ) | | ( )
0
0
t f t t sint dt
t
t
+
}

=
2
2
1 1
2
t
t
=
2
2
2
t

k =2

3. Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers
=3
4
P
4
=72
Case II: When we use 5 at ten thousand place and 6, 7 or 8 at thousand place then number of
numbers is
=1 3
3
P
3
=18
hence the required numbers of numbers is 72 +18 =90

4. f(x) is an odd function
g(x) is f
1
(x)
Area = ( )
( )
2 2
1
0 0
f y dy x f x dx
t t

' =
} }

=
( ) ( ) ( )
2
2
0
0
x f x x sinx dx
t
t
(
( +
(

}
=2t
2


5.
2 2
2
a b b c c a + +


=
( ) ( )
2 2 2
2 a b c 2 a b b c c a + + + +



=2(4 +9 +16) 2
( )
a b b c c a + +



=58 2
( )
a b b c c a + +


.
Now
( )
2
a b c 0 + + >



a
2
+b
2
+c
2
> 2
( )
a b b c c a + +



2
( )
a b b c c a + +


s 29

2 2
2
a b b c c a + +


s 87

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