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Short Notes: Form 5 Chemistry
Rate or Reaction
Calculation
Rate of Reaction (Average Rate)
Quantity change oI reactants/products
Rates oI reaction
Total time Ior the reaction
If the quantity change is immeasurable
1
Rates oI reaction
Total time Ior the reaction
Find the Rate From a Graph
Average Rate Rates At an Instant
The rate oI reaction is equal to the slope oI the graph
oI quantity against time.
(Product)
Rate oI Reaction
(Time)
The rate oI reaction at an instant, t, is equal to the
slope oI tangent at that instant.
(Product)
Rate oI Reaction
(Time)
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Chemical Reaction
Precipitation of Sulphur
2HCl
(aq)
Na
2
S
2
O
3(aq)
2NaCl
(aq)
S
(s)
SO
2(g)
H
2
O
(l)
Notes:
1. Yellow precipitate (sulphur) is Iormed.
2. The reaction is slow.
Na
2
S
2
O
3
: Sodium thiosulphate
Potassium Dichromate (VI) with Ethanedioic Acid
Cr
2
O
7
2-
14H
3C
2
O
4
2-
6CO
2
7H
2
O 2Cr
3
Notes:
1. In the reaction, the orange colour oI the solution
turns into green.
Cr
2
O
7
2-
: dichromate(VI) ion (Orange)
C
2
O
4
2-
: ethanedioate ion (Colourless)
Cr
3
: Chromium(III) ion (green)
Potassium Manganate(VII) with Ethanedioic Acid
2MnO
4
-
16H
5C
2
O
4
2-
10CO
2
8H
2
O 2Mn
2
Notes:
1. Mn
2
is colourless
2. In the reaction, the purple colour oI the solution
turns into colourless.
MnO
4
-
: Manganate(VII) ion (Purple)
Mn
2
: Manganese(II) ion colourless
Decomposition of Hydrogen Peroxide
2H
2
O
2
-
2H
2
O O
2
Catalyst: manganese(IV) oxide(MnO
2
), Iron(III) oxide (Fe
2
O
3
), silver (Ag)
Haber Process (Manufacture Ammonia)
N
2
3H
2
2NH
3
(More detail in Form 4 Chapter 9)
Contact Process(Manufacture Sulphuric Acid)
2SO
2
O
2
2SO
3
(More detail in Form 4 Chapter 9)
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Ostwald Process (Manufacture Nitric Acid)
Stage 1
4NH
3(g)
5O
2(g)
4NO
(g)
6H
2
O
(g)
Notes:
1. Temperature 900oC
2. Pressure 4-10 atm
3. Catalyse Platinum (Pt)
Stage 2
2NO
(g)
O
2(g)
2NO
2(g)
Dissolve in water
3NO
2(g)
H
2
O
(l)
2HNO
3(aq)
NO
(g)
Carbon Compound
Alkane
Alkane
Combustion
Complete
Combustion
Incomplete
Combustion
Substitution
Reaction
(Halogenation)
Combustion
Complete combustion
C
2
H
6
+
7
2
O
2
2CO
2
+ 3H
2
O
Incomplete combustion
C
2
H
6
+
5
2
O
2
2CO + 3H
2
O
C
2
H
6
+
3
2
O
2
2C + 3H
2
O
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Substitution Reaction
Alkene
Alkene
Combustion
Complete
Combustion
Incomplete
Combustion
Addition Reaction
+ Bromine/Chlorine
+ Potassium
Manganate(VII)
+ Hydrogen
+ Hydrogen Halide
+ Steam
Polymerization
Alkane Alcohol
Craking Dehydration
Preparation of Alkene
Cracking of Alkane
2C
4
H
10
CH
4
C
2
H
4
C
2
H
6
C
3
H
6
Dehydration of Alchohol
C
2
H
5
OH C
2
H
4
H
2
O
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Combustion:
Complete combustion:
C
2
H
4
3O
2
2CO
2
2H
2
O
Incomplete combustion
C
2
H
4
2O
2
2CO 2H
2
O
C
2
H
4
O
2
2C 2H
2
O
Addition Reaction:
+ Bromine:
+ Potassium Manganate(VII):
+ Hydrohen:
(Catalyst: platinum/nickel)
+ Hydrogen Halide:
+ Steam (H
2
O):
(Catalyst: phosphoric acid; Temperature: 300
o
C; Pressure: 60atm)
Polymerization
(Catalyst: oxygen; Temperature: 200
o
C; Pressure: 1200atm)
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Alcohol
Alkene Carbohydrate
Alcohol fermentation Addition
+ Sodium dehydration Combustion
Oxidation
(+K
2
CrO
7
/KMnO
4
)
Preparation of alchohol
Fermentation of Carbohydrate (Glucose)
C
6
H
12
O
6
2C
2
H
5
OH 2CO
2
Addition of Alkene
C
2
H
4
H
2
O C
2
H
5
OH
|Catalyst:Phosphoric acid; Temperature:300
o
C; Pressure: 60atm |
or
C
2
H
4
H
2
SO
4
CH
3
CH
2
OSO
3
H
CH
3
CH
2
OSO
3
H H
2
O CH
3
CH
2
OH H
2
SO
4
Combustion of Alcohol
C
2
H
5
OH 3O
2
2CO
2
3H
2
O
Dehydration of Alcohol
C
2
H
5
OH C
2
H
4
H
2
O
Alcohol + Sodium
2C
2
H
5
OH 2Na 2C
2
H
5
ONa H
2
Oxidation of Alcohol
C
2
H
5
OH 2|O| CH
3
COOH H
2
O
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Carboxylic Acid
Aldehydes Alchohol
Carboxylic acid Oxidation Oxidation
+ Metal + oxide base + alkali + Metal carbonate + Alchohol
Salt + H
2
O Salt + H
2
O Salt + H
2
Salt + CO
2
+ H
2
O
Esther
Preparation of Carboxylic acid
Oxidation of Alcohol
C
2
H
5
OH 2|O| CH
3
COOH H
2
O
Oxidation of Aldehyde
C
2
H
6
O |O| CH
3
COOH
Reaction
Carboxylic Acid + Alkali
CH
3
COOH NaOH CH
3
COONa H
2
O
Carboxylic Acid + Metal Oxide
2CH
3
COOH MgO Mg(CH
3
COO)
2
H
2
O
Carboxylic Acid + Metal
2CH
3
COOH Mg Mg(CH
3
COO)
2
H
2
Carboxylic Acid + Metal Carbonate
2CH
3
COOH CaCO
3
Ca(CH
3
COO)
2
CO
2
H
2
O
Carboxylic Acid + Alchohol
CH
3
COOH C
2
H
5
OH CH
3
COOC
2
H
5
H
2
O
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Summary of The Reaction
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Oxidation and Reduction
Iron(II) to Iron(III)
Oxidising agent: Chlorine or Bromine
Fe
2
Fe
3
e
Cl
2
2e 2Cl
2Fe
2
Cl
2
2Fe
3
2Cl
Fe
2
Fe
3
e
Br
2
2e 2Br
2Fe
2
Br
2
2Fe
3
2Cl
Observation:
1. The green colour oI Fe
2
solution turns brown
Observation:
1. The green colour oI Fe
2
solution turn brown
2. The brown colour oI bromine water turns into
colourless.
Oxidising agent: Potassium Permanganate(VII)
Fe
2
Fe
3
e
MnO
4
8H
5e Mn
2
4H
2
O
5Fe
2
MnO
4
8H
5Fe
3
Mn
2
4H
2
O
Observation:
1. The green colour oI solution Fe
2
turns brown
2. The purple colour oI the MnO
4
6e 2Cr
3
7H
2
O
6Fe
2
MnO
4
8H
6Fe
3
Mn
2
4H
2
O
Observation:
1. The green colour oI solution Fe
2
turns brown.
2. The orange colour oI the Cr
2
O
7
2-
solution turns green.
Oxidising agent: Hidrogen Peroxide
Fe
2
Fe
3
e
H
2
O
2
2H
2e 2H
2
O
2Fe
2
H
2
O
2
2H
2Fe
3
2H
2
O
Observation:
1. The green colour oI solution Fe
2
turns brown
Oxidising agent: Concentrated Nitric Acid
Fe
2
Fe
3
e
NO
3
-
4H
3e NO 2H
2
O
3Fe
2
NO
3
-
4H
3Fe
3
NO 2H
2
O
Observation:
1. The green colour oI solution Fe
2
turns brown
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Iron(III) to Iron(II)
Reducing Agent: More reactive Metal
Fe
3
e Fe
2
Zn Zn
2
2e
2Fe
3
Zn 2Fe
2
Zn
2
Observation:
1. The brown colour oI the iron(III) solution turn green.
2. Zinc powder dissolve in the solution.
Reducing Agent: Sulphur Dioxide
Fe
3
e Fe
2
SO
2
2H
2
O SO
4
2-
4H
2e
2Fe
3
SO
2
2H
2
O 2Fe
2
SO
4
2-
4H
Observation:
1. The brown colour oI the iron(III) solution turn green.
Reducing Agent: Hydrogen Sulphide
Fe
3
e Fe
2
H
2
S 2H
S 2e
2Fe
3
H
2
S 2Fe
2
2H
S
Observation:
1. The brown colour oI the iron(III) solution turn green.
2. Yellow precipitate Iorms in the solution.
Reducing Agent: Sodium Sulphite
Fe
3
e Fe
2
SO
3
2-
H
2
O SO
4
2-
2H
2e
2Fe
3
SO
3
2-
H
2
O 2Fe
2
SO
4
2-
2H
Observation:
1. The brown colour oI the iron(III) solution turn green.
Reducing Agent: Tin(II) Chloride
Fe
3
e Fe
2
Sn
2
Sn
4
2e
2Fe
3
Sn
2
2Fe
2
Sn
4
Observation:
1. The brown colour oI the iron(III) solution turn green.
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Displacement of Metal
|A more reactive metal can displace a less reactive ion oI metal Irom its compound.|
Example:
Mg PbCl
2
MgCl
2
Pb
3Zn Fe
2
O
3
3ZnO 2Fe
Al CuSO
4
Al
2
(SO
4
)
3
Cu
Electrochemical Series
Reactivity Series
Displacement of Halogen
|A more reactive halogen can displace a less reactive halide Irom its compound.|
Example:
Cl
2
KBr KCl Br
2
Br
2
NaI NaBr I
2
F
2
KI KF I
2
Reactivity of Halogen
Colour of Halogen and Halide
Halogen Colour in
water
Colour in
CCl
4
Chlorine (Cl
2
) Pale Yellow Pale Yellow
Bromine (Br
2
) Brown/Orange/
Yellow
Brown/Orange/
Yellow
Iodine (I
2
) Brown/Orange/
Yellow
Purple
Halogen Colour in
water
Colour in
CCl
4
Chloride (Cl
-
) Colourless Colourless
Bromide (Br
-
) Colourless Colourless
Iodide (I
-
) Colourless Colourless
More reactive
F
2
~ Cl
2
~ Br
2
~ I
2
~ At
2
More reactive
K, Na, Ca, Mg, Al, C, Zn, H, Fe, Sn, Pb, Cu, Ag
More electropositive
K, Na, Ca, Mg, Al, Zn, Fe, Sn, Pb, H, Cu, Ag
Kalau Nak Cari Makanan Ada Zat Ferum Seperti Papaya Harus Cari di Argentina
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The Oxidising Agent and Reducing Agent
Oxidising Agent (Reduction) Redusing Agent (Oxidation)
Halogen
Cl
2
2e 2Cl
Br
2
2e 2Br
I
2
2e 2I
Metal
Mg Mg
2
2e
Zn Zn
2
2e
Al Al
3
2e
Metal Ion
Mg
2
2e Mg
Pb
2
2e Pb
Sn
2
2e Sn
Halide Ion
2Cl
Cl
2
2e
2Br
Br
2
2e
2I
I
2
2e
Fe
3+
Fe
3
e Fe
2
Fe
2+
Fe
2
Fe
3
e
Potassium Manganate(VII)
MnO
4
8H
5e Mn
2
4H
2
O
Sulphur Dioxide
SO
2
2H
2
O SO
4
2-
4H
2e
Potassium Dicromate(VI)
Cr
2
O
7
2-
14 H
6e 2Cr
3
7H
2
O
Hydrogen Sulphide
H
2
S 2H
S 2e
Hydrogen Peroxide
H
2
O
2
2H
2e 2H
2
O
Sodium Sulphite Aqueous
SO
3
2-
H
2
O SO
4
2-
2H
2e
Concentrated Nitric Acid
NO
3
-
4H
3e NO 2H
2
O
Tin(II) Chloride Aqueous
Sn
2
Sn
4
2e
Rusting
Step 1: Formation pf Ion
Anode:
Fe Fe
2
2e
Cathode:
O
2
H
2
O 4OH
-
4e
Step 2: Corrosion of Iron
Fe
2
2OH
-
Fe(OH)
2
Step 3: Formation of iron(III) hydroxide
4Fe(OH)
2
H
2
O O
2
4Fe(OH)
3
Step 4: Formation of Hydrated Iron(III) Oxide
Fe(OH)
3
Fe
2
O
3
xH
2
O
General Equation
4Fe 3O
2
xH
2
O 2Fe
2
O
3
xH
2
O
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Preparation of Oxygen Gas
Decomposition of Potassium Manganate (VII)
2KMnO
4
K
2
MnO
4
MnO
2
O
2
Decomposition of Potassium Chlorate (V)
2KClO
3
2KCl 3O
2
|Manganese(IV) Oxide as catalyst|
Decomposition of Potassium Nitrate
2KNO
3
2KNO
2
O
2
Extraction of Iron From Its Ore
Production of Carbon Dioxide
C O
2
CO
2
Production of Carbon Monoxide
CaCO
3
CaO CO
Reduction of Iron Ore to Iron
Upper Section oI the Ballast Furnace
Fe
2
O
3
3CO 2Fe 3CO
2
Fe
3
O
4
4 CO 3Fe 4CO
2
Lower Section oI the Ballast Furnace
Fe
2
O
3
3C 2Fe 3CO
Fe
3
O
4
4 C 3Fe 4CO
2
Removal of Impurities
CaO SiO
2
CaSiO
3
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Thermochemistry
Calculation
Heat of Reaction
Thermal Energy Change
Number oI Mole
H A =
Thermal Energy Change
Q mcAu
m mass oI solution volume oI solution
c speciIic heat capacity oI solution
Number of Mole
For solution
1000
MV
n =
For gas (When volume is given)
3 3
Volume oI gas
Molar volume oI gas (22.4dm at stp / 24dm at rtp)
n =
For solid, liquid or gas ( When mass is given )
mass
Molar mass (RAM/RMM)
n =
Chemical Reaction
Exothermic Reaction
Dissolving Alkali or Acid
-
2
NaOH Na OH
H O +
+
2
2
2 4 4
H SO H SO
H O
+
+
Dissolving of Anhydrous Salt
2 2
2
4 4
CuSO Cu SO
H O
+
+
2
2
2 3 3
Na CO 2Na CO
H O
+
+
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Combustion of Fuel
Example:
Combustion of Carbon
C O
2
CO
2
Combustion of Hydrogen
2H
2
O
2
2H
2
O
Combustion of Ethane
C
2
H
6
7
2
O
2
2CO
2
3H
2
O
Reaction of Acid
Neutralisation
HCl NaOH NaCl H
2
O
2HNO
3
CaO Ca(NO
3
)
2
H
2
O
Acid + Reactive Metal
H
2
SO
4
Zn ZnSO
4
H
2
Acid + Carbonate Acid
HCl CaCO
3
CaCl
2
CO
2
HCl
Displacement Reaction
Zn CuSO
4
ZnSO
4
Cu
Endothermic Reaction
Dissolving of Ammonium Chloride, Ammonium Nitrate and Ammonium Sulphate
-
2
4 4
NH Cl NH Cl
H O
+
+
2
4 3 4 3
NH NO NH NO
H O
+
+
2
2
4 4 4 4
(NH )SO 2NH SO
H O
+
+
Dissolving of Hydrated Salt
CuSO
4
-xH
2
O Cu
2
SO
4
2-
xH
2
O
Na
2
CO
3
-xH
2
O 2Na CO
3
2-
xH
2
O
Thermal Decomposition of salts
CaCO
3
CaO CO
2
2Ca(NO
3
)
2
2CaO 4NO
2
O
2